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CN112317555A - Production method of aging-strengthened nickel-based alloy pipe - Google Patents

Production method of aging-strengthened nickel-based alloy pipe Download PDF

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CN112317555A
CN112317555A CN202011018646.4A CN202011018646A CN112317555A CN 112317555 A CN112317555 A CN 112317555A CN 202011018646 A CN202011018646 A CN 202011018646A CN 112317555 A CN112317555 A CN 112317555A
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temperature
furnace
aging
based alloy
nickel
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邵海丽
刘富强
孙海刚
程小虎
杨锴
张艳
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Handan Xinxing Special Pipe Co ltd
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Handan Xinxing Special Pipe Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/06Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B23/00Tube-rolling not restricted to methods provided for in only one of groups B21B17/00, B21B19/00, B21B21/00, e.g. combined processes planetary tube rolling, auxiliary arrangements, e.g. lubricating, special tube blanks, continuous casting combined with tube rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00Extruding metal; Impact extrusion
    • B21C23/02Making uncoated products
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/10Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon

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Abstract

The invention relates to a production method of an aging-strengthened nickel-based alloy pipe, which comprises the following steps: preheating an electric furnace: the furnace temperature is 950 ℃, and the temperature is kept for 2.5h-5 h; the method comprises the following steps of: heating to 1140-1200 ℃; lubricating: lubricating glass powder; fourthly, reaming: reaming force: 4-12 MN; fifthly, secondary induction heating: the heating temperature is 1150-1220 ℃; sixthly, acid washing: mixed acid pickling; chopping: extrusion force: 25-45 NM; cold rolling: rolling for 40-70 times/min; self-supporting solid solution treatment: the solution treatment temperature is 950-1080 ℃, and water cooling is carried out to normal temperature; the method comprises the following steps of: the treatment temperature is 700-770 ℃; straightening: straightening the steel pipe after the aging treatment; performing quality test: and inspecting the specification size, the mechanical property, the impact property and the grain size. The invention optimizes the production process of the nickel-based alloy pipe, improves the production efficiency and improves the product quality by integrating the production flow.

Description

Production method of aging-strengthened nickel-based alloy pipe
Technical Field
The invention belongs to the technical field of seamless steel tube production, and relates to a production method of an aging-strengthened nickel-based alloy tube.
Background
The UNS N09925 alloy is a novel high-strength high-temperature corrosion-resistant alloy developed in recent years, and related research reports at home and abroad are few at present. The UNS N09925 alloy is a Fe-Ni-Cr high-temperature corrosion-resistant alloy which is prepared by properly increasing the contents of Fe and Cr to reduce the content of rare metal nickel on the basis of a nickel-based alloy. Because the alloy components are complex, the corresponding precipitated phases are increased, and higher requirements are put forward on the metallurgy technology and the heat treatment system. Compared with GH4169 nickel-based high-temperature corrosion-resistant alloy, the alloy has the advantages of low nickel content, high toughness, corrosion resistance, easy cutting and the like, has super-excellent alloy performance, can maintain high-temperature and excellent mechanical properties such as fatigue resistance and the like at high temperature, has oxidation resistance and corrosion resistance, and has good plasticity and weldability, and the UNS N09925 alloy is widely concerned at home and abroad.
The UNS N09925 alloy is an aging strengthening type alloy which takes an austenite gamma phase as a matrix and takes intermetallic compounds gamma '[ Ni3(Ti, Al) ] and gamma' [ Ni3(Nb, Ti, Al) ] as strengthening phases, and by adding trace precipitation strengthening elements such as Mo, Cu, Nb, Ti, Al and the like, excellent mechanical, high-temperature resistant and corrosion resistant properties are obtained. Intermetallic compounds γ' and γ ″ have a better strengthening effect than carbides; certain amounts of Mo, Cu, Ti and Al enable the strength and the corrosion resistance of the alloy to be perfectly combined. Sufficient Ni has good effect on resisting stress corrosion cracking caused by a medium containing chloride ions; the addition of Mo and Cu ensures that the alloy has good corrosion resistance in a reducing medium; mo is beneficial to improving the pitting corrosion resistance and the crevice corrosion resistance; cr can greatly improve the high-temperature oxidation resistance of the alloy. The addition of Ti and Al enriches the aging strengthening means of the alloy. The alloy is widely applied to the fields of oil and gas drilling equipment, chemical industry, ocean and the like with higher requirements on comprehensive properties of toughness, heat resistance, corrosion resistance and the like of materials.
Disclosure of Invention
The invention aims to provide a production method of an aging-strengthened nickel-based alloy pipe, which optimizes the production process of the nickel-based alloy pipe, adopts the modes of extrusion cogging and cold rolling to produce, improves the production efficiency and improves the product quality.
The technical scheme of the invention is as follows: the production method of the aging strengthening nickel-based alloy pipe utilizes the production system of the aging strengthening nickel-based alloy pipe to produce. The production process comprises the following steps:
preheating an electric furnace: putting the furnace into the furnace at the furnace temperature of 850 ℃, preserving heat for 1h, heating to 950 ℃, and preserving heat for 2.5-5 h;
the method comprises the following steps of: induction heating temperature (inner hole temperature): 1140-1200 ℃;
lubricating: adopting glass powder for lubrication;
fourthly, reaming: reaming force: 4-12 MN, hole expansion speed: 150 mm-250 mm/s;
fifthly, secondary induction heating: induction heating temperature (inner hole temperature): 1150 ℃ to 1220 ℃;
sixthly, hot extrusion: extrusion force: 25-45 NM, extrusion speed: 100 mm-200 mm/s;
and using mixed acid for pickling, wherein the mixed acid is mixed acid of hydrofluoric acid and nitric acid, and the mixed acid comprises the following components: concentration of nitric acid: 16-20, concentration of hydrofluoric acid: 1-3; acid pickling temperature: 20-40 ℃; the pickling time is 0.5 to 1.5 hours;
cold rolling: the rolling speed is 40-70 times/min, and the feeding amount is 2-5 mm/time;
self-supporting solid solution treatment: the temperature of the solution treatment is 950-1080 ℃, the temperature is kept for 30-80 min, and the water is cooled to the normal temperature;
the method comprises the following steps of: keeping the temperature for 3-9 h at 700-770 ℃, cooling the furnace to 600-650 ℃ in 50-90 min, keeping the temperature for 8-20 h, and cooling the furnace to room temperature;
straightening: carrying out roller straightening on the steel pipe subjected to aging treatment;
performing quality test: and inspecting the specification size, the mechanical property, the impact property and the grain size of the aging strengthening nickel-based alloy pipe.
The nickel-based alloy is UNS N09925 age-strengthened nickel-based alloy. The nickel-based alloy comprises the following components in percentage by mass: 42.0-46.0 parts of Ni, 19.5-22.5 parts of Cr, more than or equal to 22 parts of Fe, 0.08-0.50 part of Nb, 2.50-3.50 parts of Mo, 1.90-2.40 parts of Ti, 0.10-0.50 part of Al, less than or equal to 0.025 part of C, less than or equal to 0.35 part of Si, less than or equal to 1.0 part of Mn, less than or equal to 0.020 part of P, less than or equal to 0.003 part of S, 1.50-3.00 parts of Cu, and the balance of unavoidable impurities. The production system of the aging-strengthened nickel-based alloy pipe comprises an electric heating furnace, an electromagnetic induction heating furnace, a lubricating device, a hole expanding machine, a secondary electromagnetic induction heating furnace, a hot extruding machine, an acid pickling device, a cold rolling mill, a solution treatment furnace, an aging treatment furnace, a straightening machine and a checking device. The electric heating furnace, the electromagnetic induction heating furnace, the lubricating device, the broaching machine, the secondary electromagnetic induction heating furnace, the hot extrusion machine, the pickling device, the cold rolling mill, the solution treatment furnace, the aging treatment furnace, the straightening machine and the inspection device are arranged in sequence.
The production method of the aging-strengthened nickel-based alloy pipe optimizes the production process of the nickel-based alloy pipe by integrating the production flow, adopts the extrusion cogging and cold rolling production mode, and has the advantages of large production group distance, high yield, good surface quality and fast production rhythm compared with the traditional bar boring production mode, improves the production efficiency and improves the product quality. The aging heat treatment adopts a continuous heat treatment method, so that good product comprehensive performance is obtained, and the API 6ACRA standard requirement is met.
Drawings
FIG. 1 is a schematic flow diagram of an age-strengthened nickel-base alloy pipe production system;
FIG. 2 is a metallographic structure diagram of a UNS N09925 seamless steel tube;
wherein: 1-electric heating furnace, 2-electromagnetic induction heating furnace, 3-lubricating device, 4-broaching machine, 5-secondary electromagnetic induction heating furnace, 6-hot extruding machine, 7-acid cleaning device, 8-cold rolling mill, 9-solution treatment furnace, 10-aging treatment furnace, 11-straightening machine and 12-inspection device.
Detailed Description
The present invention will be described in detail with reference to the following examples and drawings. The scope of protection of the invention is not limited to the embodiments, and any modification made by those skilled in the art within the scope defined by the claims also falls within the scope of protection of the invention.
The production system of the aging-strengthened nickel-based alloy pipe comprises an electric heating furnace 1, an electromagnetic induction heating furnace 2, a lubricating device 3, a hole expanding machine 4, a secondary electromagnetic induction heating furnace 5, a heat extruding machine 6, a pickling device 7, a cold rolling machine 8, a solution treatment furnace 9, an aging treatment furnace 10, a straightening machine 11 and a checking device 12, wherein the electric heating furnace, the electromagnetic induction heating furnace, the lubricating device, the hole expanding machine, the secondary electromagnetic induction heating furnace, the heat extruding machine, the pickling device, the cold rolling machine, the solution treatment furnace, the aging treatment furnace, the straightening machine and the checking device are sequentially arranged.
A UNS N09925 seamless steel pipe with a specification of phi 108 multiplied by 9mm is produced. The seamless steel tube comprises the following components in percentage by mass: ni: 44.2, Cr: 20.3, Fe: 27.4, Nb: 0.2, Mo: 3.3, Ti: 2.27, Al: 0.18, C: 0.020, Si: 0.25, Mn: 0.15, P: 0.007, S: 0.0012, Cu: 1.65, the balance being impurities. The production process of the aging strengthening nickel-based alloy pipe comprises the following steps: the method comprises the following steps of electric furnace smelting, vacuum degassing, electroslag remelting, blank inspection, blank processing, deep hole drilling, end face processing, cleaning, preheating, primary induction heating, lubricating, hole expanding, secondary induction heating, extruding, water feeding, head cutting, acid pickling, solid solution, aging, straightening, flat head, acid pickling, inspection and grinding, flaw detection, finishing inspection and label spraying packaging, wherein the solid solution, straightening, acid pickling, grinding, cold rolling and deoiling are cyclic processes. The production process of the aging strengthening nickel-based alloy pipe mainly comprises the following steps:
preheating an electric furnace: feeding the furnace at the furnace temperature of 850 ℃, preserving heat for 1h, heating to 950 ℃, and preserving heat for 2.5h-5 h;
the method comprises the following steps of: induction heating temperature (inner hole temperature): 1160-1180 ℃;
lubricating: and lubricating the outer surface and the inner hole of the blank and the space between the extrusion die and the workpiece in the extrusion process by adopting glass powder. Lubricating the outer surface of the blank in an automatic rolling coating mode, wherein the content of glass powder is 844-7; the inner hole is lubricated by GN26 glass powder, the glass powder is uniformly scattered into the inner hole of the blank, a glass pad is used for lubrication between the hole pattern of the die and the workpiece, and the glass powder used for the glass pad is HDK-5 glass powder;
fourthly, reaming: the reaming head is phi 121mm, and the reaming force is as follows: 6-12 MN, hole expansion speed: 150 mm-250 mm/s;
fifthly, secondary induction heating: induction heating temperature (inner hole temperature): 1150-1200 ℃;
sixthly, hot extrusion: adopting a 63MN horizontal extruder of Italian Dannelli company, selecting 255 series of extrusion cylinders, wherein the inner diameter of an extrusion die is phi 136.3mm, the inner diameter of a core rod is phi 110.6mm, and extrusion force is as follows: 25-35 NM, extrusion speed: 100 mm-200 mm/s, and 20mm of residual pressure;
acid-killing: acid washing is carried out by adopting mixed acid (hydrofluoric acid + nitric acid), wherein the concentration of the nitric acid is as follows: 18, hydrofluoric acid concentration: 2; acid pickling temperature: 30 ℃; pickling time is 48 min;
cold rolling: LG110 mill, cold rolled pass plug φ 133 × 12 → φ 108 × 9: the rolling speed is 45-60 times/minute, and the feeding amount is 3-5 mm/time;
self-supporting solid solution treatment: the solution treatment temperature is 980-1000 ℃, the temperature is kept for 40-60 min, and water cooling is carried out to the normal temperature;
the method comprises the following steps of: treatment temperature: keeping the temperature at 720-740 ℃ for 4-6 h, cooling the furnace for 50-70min to 630-640 ℃, keeping the temperature for 10-120h, and cooling the furnace to the normal temperature;
straightening: carrying out roller straightening on the steel pipe subjected to the aging treatment by using a six-roller straightening machine;
performing quality test: and inspecting the specification size, the mechanical property, the impact property and the grain size of the aging strengthening nickel-based alloy pipe.
The mechanical properties of the UNS N09925 seamless steel tube and the aging-strengthened nickel-based alloy tube are shown in Table 1. The UNS N09925 seamless steel tube has the impact test size of 55 multiplied by 10 multiplied by 5, the transverse direction, the V opening, the test temperature of-60 ℃, the conversion coefficient of 0.55, and the impact performance test results are shown in Table 2. The whole grain size is 6-7 grades, the grain size is shown in Table 3, the structure grain boundary has no continuous harmfulness and conforms to the API 6A requirement, and the metallographic structure is shown in figure 2.
TABLE 1 mechanical properties of UNS N09925 seamless steel pipes
Figure BDA0002699943000000051
Figure BDA0002699943000000061
TABLE 2 impact properties of UNS N09925 seamless steel pipes
Figure BDA0002699943000000062
TABLE 3 grain size of UNS N09925 seamless steel pipes
Figure BDA0002699943000000063
Figure BDA0002699943000000071
The experimental results show that: the structure and the performance of the aging-strengthened nickel-based alloy seamless steel pipe produced by the invention meet the requirements of API 6ACRA standard: the tensile strength is more than or equal to 965MPa, the yield strength is more than or equal to 758MPa, the elongation is more than or equal to 18, and the reduction of area is more than or equal to 25; the hardness is 26HRC-38 HRC; the grain size is 2 grade or finer, the grain boundary has no continuous harmful phase, and the grain size is smaller than or equal to 60 ℃.

Claims (4)

1. The production method of the aging-strengthened nickel-based alloy pipe is characterized in that the aging-strengthened nickel-based alloy pipe is produced by using a production system of the aging-strengthened nickel-based alloy pipe, and the production method comprises the following steps: the production process comprises the following steps:
preheating an electric furnace: putting the furnace into the furnace at the furnace temperature of 850 ℃, preserving heat for 1h, heating to 950 ℃, and preserving heat for 2.5-5 h;
the method comprises the following steps of: induction heating temperature: 1140-1200 ℃;
lubricating: adopting glass powder for lubrication;
fourthly, reaming: reaming force: 4-12 MN, hole expansion speed: 150 mm-250 mm/s;
fifthly, secondary induction heating: induction heating temperature: 1150 ℃ to 1220 ℃;
sixthly, hot extrusion: extrusion force: 25-45 NM, extrusion speed: 100 mm-200 mm/s;
acid-killing: and mixed acid pickling is adopted for pickling, wherein the mixed acid is mixed acid of hydrofluoric acid and nitric acid, and the pickling process comprises the following steps: concentration of nitric acid: 16-20, concentration of hydrofluoric acid: 1-3; acid pickling temperature: 20-40 ℃; the pickling time is 0.5 to 1.5 hours;
cold rolling: the rolling speed is 40-70 times/min, and the feeding amount is 2-5 mm/time;
self-supporting solid solution treatment: the temperature of the solution treatment is 950-1080 ℃, the temperature is kept for 30-80 min, and the water is cooled to the normal temperature;
the method comprises the following steps of: aging treatment temperature: keeping the temperature for 3-9 h at 700-770 ℃, cooling the furnace to 600-650 ℃ in 50-90 min, keeping the temperature for 8-20 h, and cooling the furnace to the normal temperature;
the method has the advantages of straightening: carrying out roller straightening on the steel pipe subjected to aging treatment;
performing quality test: and inspecting the specification size, the mechanical property, the impact property and the grain size of the aging strengthening nickel-based alloy pipe.
2. The method for producing an age-strengthened nickel-base alloy pipe according to claim 1, wherein: the nickel-based alloy is UNS N09925 age-strengthened nickel-based alloy.
3. The production method of the age-strengthened nickel-base alloy pipe according to claim 1 or 2, characterized in that: the nickel-based alloy comprises the following components in percentage by mass: 42.0-46.0 parts of Ni, 19.5-22.5 parts of Cr, more than or equal to 22 parts of Fe, 0.08-0.50 part of Nb, 2.50-3.50 parts of Mo, 1.90-2.40 parts of Ti, 0.10-0.50 part of Al, less than or equal to 0.025 part of C, less than or equal to 0.35 part of Si, less than or equal to 1.0 part of Mn, less than or equal to 0.020 part of P, less than or equal to 0.003 part of S, 1.50-3.00 parts of Cu, and the balance of unavoidable impurities.
4. The production method of the age-strengthened nickel-base alloy pipe according to claim 1 or 2, characterized in that: the production system of the aging-strengthening nickel-based alloy pipe comprises an electric heating furnace (1), an electromagnetic induction heating furnace (2), a lubricating device (3), a hole expanding machine (4), a secondary electromagnetic induction heating furnace (5), a heat extruding machine (6), a pickling device (7), a cold rolling machine (8), a solution treatment furnace (9), an aging treatment furnace (10), a straightening machine (11) and a checking device (12), wherein the electric heating furnace, the electromagnetic induction heating furnace, the lubricating device, the hole expanding machine, the secondary electromagnetic induction heating furnace, the heat extruding machine, the pickling device, the cold rolling machine, the solution treatment furnace, the aging treatment furnace, the straightening machine and the checking device are sequentially arranged.
CN202011018646.4A 2020-09-24 2020-09-24 Production method of aging-strengthened nickel-based alloy pipe Pending CN112317555A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113025796A (en) * 2021-03-04 2021-06-25 上海核工程研究设计院有限公司 Preparation method of small-diameter thick-wall pipe of control rod driving mechanism driving rod of nuclear power station
CN113649431A (en) * 2021-08-12 2021-11-16 江苏隆达超合金股份有限公司 Nickel pipe for aviation nacelle and manufacturing process thereof
CN114183448A (en) * 2021-12-14 2022-03-15 苏州昭伍亿精密五金有限公司 A kind of high-strength corrosion-resistant bolt and its production process
CN115449725A (en) * 2022-08-10 2022-12-09 四川英拓金属材料有限公司 Heat treatment method for improving impact toughness of nickel-based high-temperature alloy material

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CN104174683A (en) * 2014-07-17 2014-12-03 太原钢铁(集团)有限公司 Induction heating temperature control method for nickel-base superalloy hot extrusion tubulation
CN104962836A (en) * 2015-06-05 2015-10-07 山西太钢不锈钢股份有限公司 Corrosion-resistance iron-based austenite oil well pipe and manufacturing method thereof
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US4020312A (en) * 1974-11-27 1977-04-26 Nippon Kokan Kabushiki Kaisha Method of manufacturing thick, high-strength steel pipe for low temperature service
JP2003340518A (en) * 2002-05-24 2003-12-02 Nippon Steel Corp Method of manufacturing UOE steel pipe with excellent crushing strength
CN102463273A (en) * 2010-11-08 2012-05-23 北京有色金属研究总院 Preparation method of large-caliber nickel-based alloy thin-walled tube
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113025796A (en) * 2021-03-04 2021-06-25 上海核工程研究设计院有限公司 Preparation method of small-diameter thick-wall pipe of control rod driving mechanism driving rod of nuclear power station
CN113649431A (en) * 2021-08-12 2021-11-16 江苏隆达超合金股份有限公司 Nickel pipe for aviation nacelle and manufacturing process thereof
CN114183448A (en) * 2021-12-14 2022-03-15 苏州昭伍亿精密五金有限公司 A kind of high-strength corrosion-resistant bolt and its production process
CN115449725A (en) * 2022-08-10 2022-12-09 四川英拓金属材料有限公司 Heat treatment method for improving impact toughness of nickel-based high-temperature alloy material

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Application publication date: 20210205