CN112266678A - A kind of exterior wall waterproof coating and preparation method thereof - Google Patents
A kind of exterior wall waterproof coating and preparation method thereof Download PDFInfo
- Publication number
- CN112266678A CN112266678A CN202011183755.1A CN202011183755A CN112266678A CN 112266678 A CN112266678 A CN 112266678A CN 202011183755 A CN202011183755 A CN 202011183755A CN 112266678 A CN112266678 A CN 112266678A
- Authority
- CN
- China
- Prior art keywords
- parts
- waterproof coating
- exterior wall
- stirring
- methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 31
- 239000011248 coating agent Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 238000013329 compounding Methods 0.000 claims abstract description 5
- 229920005682 EO-PO block copolymer Polymers 0.000 claims abstract description 3
- 239000013530 defoamer Substances 0.000 claims abstract description 3
- 230000001954 sterilising effect Effects 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 9
- 239000003755 preservative agent Substances 0.000 claims description 9
- 230000002335 preservative effect Effects 0.000 claims description 9
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
- -1 perfluoroalkyl ethyl acrylate Chemical compound 0.000 claims description 8
- 230000000844 anti-bacterial effect Effects 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 239000007798 antifreeze agent Substances 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 6
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 6
- VBHXIMACZBQHPX-UHFFFAOYSA-N 2,2,2-trifluoroethyl prop-2-enoate Chemical compound FC(F)(F)COC(=O)C=C VBHXIMACZBQHPX-UHFFFAOYSA-N 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- FMQPBWHSNCRVQJ-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F FMQPBWHSNCRVQJ-UHFFFAOYSA-N 0.000 claims description 4
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- LCPUCXXYIYXLJY-UHFFFAOYSA-N 1,1,2,4,4,4-hexafluorobutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(F)(F)C(F)CC(F)(F)F LCPUCXXYIYXLJY-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 3
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical group O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 238000004078 waterproofing Methods 0.000 claims 2
- 239000000178 monomer Substances 0.000 abstract description 14
- 239000000919 ceramic Substances 0.000 abstract description 6
- 230000002528 anti-freeze Effects 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 8
- 239000002518 antifoaming agent Substances 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000002159 abnormal effect Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 4
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 4
- QWYSJTTWCUXHQO-UHFFFAOYSA-N [F].OC(=O)C=C Chemical compound [F].OC(=O)C=C QWYSJTTWCUXHQO-UHFFFAOYSA-N 0.000 description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 2
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N ethyl butylhexanol Natural products CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
- C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
本案涉及一种外墙防水涂料及其制备方法，包括0.5～1份pH调节剂、20‑40份水中、30～40份聚合物乳液、0.5～1份表面活性剂、0.1～0.3份杀菌防腐剂、4～8份环氧乙烷‑环氧丙烷嵌段共聚物、28～42份填料、10‑20份水、1.5～2份抗冻剂、3.5～4份成膜助剂和2.5～3.5份消泡剂。本发明利用丙烯酸酯类单体和丙烯酸酯类含氟单体共聚制得乳液后与填料和各种功能性助剂复配制得的防水涂料对瓷砖表面有着优异的附着力，其自清洁和耐玷污性能得到改善，同时涂覆于瓷砖表面具有明显的光泽度，为城市美化起到一定的作用；本发明原料易得，成本低，工艺简单，经济环保。This case relates to a waterproof coating for exterior walls and a preparation method thereof, comprising 0.5-1 part of pH regulator, 20-40 parts of water, 30-40 parts of polymer emulsion, 0.5-1 part of surfactant, 0.1-0.3 part of sterilization and anti-corrosion agent, 4-8 parts of ethylene oxide-propylene oxide block copolymer, 28-42 parts of filler, 10-20 parts of water, 1.5-2 parts of antifreeze, 3.5-4 parts of coalescent 3.5 parts defoamer. The invention utilizes acrylic monomers and acrylic fluorine-containing monomers to copolymerize to obtain an emulsion, and the waterproof coating prepared by compounding with fillers and various functional auxiliaries has excellent adhesion to the ceramic tile surface, and is self-cleaning and resistant to The stain performance is improved, and at the same time, the surface of the ceramic tile has obvious gloss, which plays a certain role in urban beautification.
Description
Technical Field
The invention belongs to the technical field of chemical coatings, and particularly relates to an outer wall waterproof coating and a preparation method thereof.
Background
The building exterior wall tile can play a certain role in beautifying cities, and at the end of the last century, the building exterior wall tile is popular, but after decades of wind blowing and sun drying and acid rain erosion, the brick surface has the problems of dirt, cracking, falling off and the like, so that the attractiveness of the building exterior wall surface is influenced, and the problem of water leakage of buildings comes along with the problem, so that the renovation of the exterior wall tile is particularly important.
At present, there are two ways to renovate exterior wall tiles: 1. removing the ceramic tile and rolling and coating finish paint; 2. directly coating putty on the surface of the ceramic tile and rolling and coating finish paint. Obviously, the first mode is time-consuming and labor-consuming and has high construction strength. Therefore, in recent years, efforts have been made to develop a paint for renovating tiles, which can be directly applied to the surface of old tiles. However, the coating has certain problems, such as low adhesion, easy coating falling off, low surface gloss, insufficient waterproof performance and the like.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the waterproof coating with high adhesive force and high surface gloss, which can be applied to coating and renovating the surface of the exterior wall tile.
In order to achieve the purpose, the invention provides the following technical scheme:
the waterproof coating for the outer wall comprises the following components in parts by weight:
further, the polymer emulsion is prepared by emulsion polymerization of two or more of methyl methacrylate, butyl acrylate, methyl acrylate, hydroxypropyl methacrylate and glycidyl methacrylate and one or more of trifluoroethyl acrylate, hexafluoroisopropyl methacrylate, hexafluorobutyl methacrylate and perfluoroalkyl ethyl acrylate.
Further, the bactericidal preservative is isothiazolinone.
Further, the surfactant is sodium carboxymethyl cellulose.
Further, the filler is formed by compounding micron-sized titanium dioxide, calcium carbonate, mica powder and kaolin according to the mass ratio of 6:2:1: 1.
Further, the antifreeze is one of propylene glycol, ethylene glycol or polyethylene glycol.
Further, the film forming auxiliary agent is one or more of ethylene glycol butyl ether, dodecyl alcohol ester, propylene glycol phenyl ether, dipropylene glycol butyl ether and dibutyl phthalate.
Further, the defoaming agent is a polysiloxane-based defoaming agent.
A method for preparing the exterior wall waterproof coating material, which comprises the following steps:
1) weighing the components according to the proportion;
2) adding a pH regulator into a part of water, regulating the pH value to 8-9, then adding a polymer emulsion, a surfactant and a sterilizing preservative, and stirring and dispersing for 30min at the rotating speed of 1000 r/m;
3) then adding ethylene oxide-propylene oxide block copolymer, filler and another half water, and stirring at a high speed of 1500r/m for 15 min;
4) and finally, reducing the speed to 200r/m, adding the antifreeze agent, the film forming additive and the defoamer while stirring, and uniformly mixing to obtain the waterproof coating.
Compared with the prior art, the invention has the beneficial effects that: the waterproof coating prepared by copolymerizing the acrylate monomer and the acrylate fluorine-containing monomer to prepare the emulsion and compounding the emulsion with the filler and various functional additives has excellent adhesive force on the surface of the ceramic tile, improves the self-cleaning and stain-resistant properties, has obvious glossiness when coated on the surface of the ceramic tile, and plays a certain role in urban beautification; the invention has the advantages of easily obtained raw materials, low cost, simple process, economy and environmental protection.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments, and it should be understood that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In addition, the technical features involved in the different embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Example (b): a process for preparing the waterproof coating for the outer wall comprises the following steps:
1) adding 0.5-1 part of pH regulator into 10-20 parts of water, regulating the pH value to 8-9, then adding 30-40 parts of polymer emulsion, 0.5-1 part of surfactant and 0.1-0.3 part of bactericidal preservative, and stirring and dispersing for 30min at the rotating speed of 1000 r/m;
2) then adding 4-8 parts of ethylene oxide-propylene oxide segmented copolymer, 28-42 parts of filler and 10-20 parts of water, and stirring at a high speed of 1500r/m for 15 min;
3) and finally, reducing the speed to 200r/m, adding 1.5-2 parts of an antifreeze agent, 3.5-4 parts of a film forming additive and 2.5-3.5 parts of a defoaming agent while stirring, and uniformly mixing to obtain the waterproof coating.
The polymer emulsion is prepared by emulsion polymerization of an acrylate monomer and an acrylate fluorine-containing monomer, wherein the acrylate monomer is preferably two or more of methyl methacrylate, butyl acrylate, methyl acrylate, hydroxypropyl methacrylate and glycidyl methacrylate; the acrylate fluorine-containing monomer is preferably one or more of trifluoroethyl acrylate, hexafluoroisopropyl methacrylate, hexafluorobutyl methacrylate and perfluoroalkyl ethyl acrylate.
The emulsion polymerization may be carried out by the following steps: adding 0.5-1 part of initiator, 2-3 parts of emulsifier and 0.1-0.3 part of sodium bicarbonate into a reaction bottle to prepare an aqueous solution, and heating to 70-80 ℃; weighing 10-20 parts of acrylate monomer and 5-15 parts of acrylate fluorine-containing monomer in a glass bottle, uniformly mixing, slowly dropwise adding the mild monomer into the aqueous solution, and stirring for reacting for 1-1.5 h.
Wherein the emulsifier is one of nonylphenol polyoxyethylene ether NP series, octylphenol polyoxyethylene ether OP series and alkylbenzene sulfonate; the initiator is ammonium persulfate or sodium persulfate.
Further, the bactericidal preservative is isothiazolinone.
Furthermore, the surfactant is sodium carboxymethylcellulose which is easily dispersed in water to form a transparent colloidal solution, helps the polymer emulsion and the filler to be dispersed in water, and can be used as a thickening agent, an emulsifying agent and a binder, so that the functions are strong and the dosage is small.
Further, the filler is formed by compounding micron-sized titanium dioxide, calcium carbonate, mica powder and kaolin according to the mass ratio of 6:2:1: 1.
Further, the antifreeze is one of propylene glycol, ethylene glycol or polyethylene glycol.
Further, the film forming auxiliary agent is one or more of ethylene glycol butyl ether, dodecyl alcohol ester, propylene glycol phenyl ether, dipropylene glycol butyl ether and dibutyl phthalate.
Further, the defoaming agent is a polysiloxane-based defoaming agent.
Example 1:
1) adding 0.5 part of pH regulator into 10 parts of water, regulating the pH value to 8-9, then adding 30 parts of polymer emulsion, 0.5 part of sodium carboxymethylcellulose and 0.1 part of bactericidal preservative, and stirring and dispersing for 30min at the rotating speed of 1000 r/m;
2) then adding 5 parts of ethylene oxide-propylene oxide segmented copolymer, 28 parts of filler and 10 parts of water, and stirring at a high speed of 1500r/m for 15 min;
3) and finally, reducing the speed to 200r/m, adding 1.5 parts of antifreeze agent, 3.5 parts of film-forming additive and 2.5 parts of defoaming agent while stirring, and uniformly mixing to obtain the waterproof coating.
Wherein the polymer emulsion: adding 0.5 part of ammonium persulfate, 2 parts of nonylphenol polyoxyethylene ether NP-10 and 0.1 part of sodium bicarbonate into a reaction bottle to prepare an aqueous solution, and heating to 70 ℃; weighing 8 parts of methyl methacrylate, 4 parts of butyl acrylate and 10 parts of trifluoroethyl acrylate in a glass bottle, uniformly mixing, slowly dropwise adding the mild monomer into the aqueous solution, and stirring for reacting for 1 hour.
Example 2:
1) adding 0.6 part of pH regulator into 12 parts of water, regulating the pH value to 8-9, then adding 35 parts of polymer emulsion, 0.6 part of sodium carboxymethylcellulose and 0.1 part of bactericidal preservative, and stirring and dispersing for 30min at the rotating speed of 1000 r/m;
2) then adding 5 parts of ethylene oxide-propylene oxide segmented copolymer, 33 parts of filler and 15 parts of water, and stirring at a high speed of 1500r/m for 15 min;
3) and finally, reducing the speed to 200r/m, adding 1.7 parts of antifreeze agent, 3.8 parts of film-forming additive and 2.7 parts of defoaming agent while stirring, and uniformly mixing to obtain the waterproof coating.
Wherein the polymer emulsion: adding 0.6 part of ammonium persulfate, 2 parts of nonylphenol polyoxyethylene ether OP-10 and 0.1 part of sodium bicarbonate into a reaction bottle to prepare an aqueous solution, and heating to 70 ℃; weighing 7 parts of methyl methacrylate, 5 parts of butyl acrylate and 12 parts of trifluoroethyl acrylate in a glass bottle, uniformly mixing, slowly dropwise adding the mild monomer into the aqueous solution, and stirring for reacting for 1 hour.
Example 3:
1) adding 0.7 part of pH regulator into 16 parts of water, regulating the pH value to 8-9, then adding 38 parts of polymer emulsion, 0.5 part of sodium carboxymethylcellulose and 0.1 part of bactericidal preservative, and stirring and dispersing for 30min at the rotating speed of 1000 r/m;
2) then 6 parts of ethylene oxide-propylene oxide segmented copolymer, 38 parts of filler and 20 parts of water are added and stirred at a high speed of 1500r/m for 15 min;
3) and finally, reducing the speed to 200r/m, adding 2.0 parts of antifreeze agent, 4.0 parts of film forming additive and 3.2 parts of defoaming agent while stirring, and uniformly mixing to obtain the waterproof coating.
Wherein the polymer emulsion: adding 0.8 part of ammonium persulfate, 3 parts of nonylphenol polyoxyethylene ether OP-10 and 0.1 part of sodium bicarbonate into a reaction bottle to prepare an aqueous solution, and heating to 80 ℃; in a glass bottle, 8 parts of methyl methacrylate, 5 parts of methyl acrylate, 2 parts of hydroxypropyl methacrylate and 15 parts of hexafluoroisopropyl methacrylate were weighed and mixed uniformly, the moderating monomer was slowly dropped into the above aqueous solution, and the reaction was stirred for 1 hour.
The primers prepared in examples 1-3 were subjected to performance tests with reference to JG/T210-2018 film-forming exterior wall primer type I standard, and the results are recorded in Table 1.
TABLE 1
| Example 1 | Example 2 | Example 3 | |
| Water resistance | No abnormal condition for 96h | No abnormal condition for 96h | No abnormal condition for 96h |
| Alkali resistance | No abnormal condition for 48 hours | No abnormal condition for 48 hours | No abnormal condition for 48 hours |
| Water permeability/mL | 0.21 | 0.20 | 0.15 |
The exterior wall waterproof coating prepared by the invention has excellent water resistance, alkali resistance and waterproof performance. Meanwhile, the coating has good glossiness, and does not bubble, peel or crack after being coated for six days.
While embodiments of the invention have been disclosed above, it is not limited to the applications listed in the description and the embodiments, which are fully applicable in all kinds of fields of application of the invention, and further modifications may readily be effected by those skilled in the art, so that the invention is not limited to the specific details without departing from the general concept defined by the claims and the scope of equivalents.
Claims (6)
1. The waterproof coating for the outer wall is characterized by comprising the following components in parts by weight:
2. the exterior wall waterproofing coating of claim 1 wherein the polymer emulsion is formed by emulsion polymerization of two or more of methyl methacrylate, butyl acrylate, methyl acrylate, hydroxypropyl methacrylate, glycidyl methacrylate with one or more of trifluoroethyl acrylate, hexafluoroisopropyl methacrylate, hexafluorobutyl methacrylate, perfluoroalkyl ethyl acrylate.
3. The exterior wall waterproof coating material of claim 1, wherein the bactericidal preservative is isothiazolinone.
4. The exterior wall waterproofing coating of claim 1 wherein the surfactant is sodium carboxymethylcellulose.
5. The exterior wall waterproof coating material of claim 1, wherein the filler is formed by compounding micron-sized titanium dioxide, calcium carbonate, mica powder and kaolin according to a mass ratio of 6:2:1: 1.
6. The preparation method of the exterior wall waterproof coating material of claim 1, characterized by comprising the following steps:
1) weighing the components according to the proportion;
2) adding a pH regulator into a part of water, regulating the pH value to 8-9, then adding a polymer emulsion, a surfactant and a sterilizing preservative, and stirring and dispersing for 30min at the rotating speed of 1000 r/m;
3) then adding ethylene oxide-propylene oxide block copolymer, filler and another half water, and stirring at a high speed of 1500r/m for 15 min;
4) and finally, reducing the speed to 200r/m, adding the antifreeze agent, the film forming additive and the defoamer while stirring, and uniformly mixing to obtain the waterproof coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011183755.1A CN112266678A (en) | 2020-10-29 | 2020-10-29 | A kind of exterior wall waterproof coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011183755.1A CN112266678A (en) | 2020-10-29 | 2020-10-29 | A kind of exterior wall waterproof coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112266678A true CN112266678A (en) | 2021-01-26 |
Family
ID=74344747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011183755.1A Pending CN112266678A (en) | 2020-10-29 | 2020-10-29 | A kind of exterior wall waterproof coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112266678A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114106641A (en) * | 2021-12-31 | 2022-03-01 | 贵州文泰防水技术有限公司 | Preparation method of environment-friendly waterproof coating |
| CN115029044A (en) * | 2022-06-07 | 2022-09-09 | 安徽同益净化科技有限公司 | Reinforced acid and alkali resistant coating for constructional engineering and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212301A (en) * | 2011-01-17 | 2011-10-12 | 立邦涂料（中国）有限公司 | Renovating coating for waterborne ceramic tiles and preparation method thereof |
| CN102585625A (en) * | 2011-12-29 | 2012-07-18 | 陕西宝塔山油漆股份有限公司 | Waterborne fluorocarbon self-cleaning tunnel coating |
| CN102964960A (en) * | 2012-11-15 | 2013-03-13 | 中山蓝海洋水性涂料有限公司 | Water-based fluorocarbon coating for exterior wall and preparation method thereof |
| CN103382344A (en) * | 2013-08-07 | 2013-11-06 | 武汉工程大学 | Water-based acrylate resin exterior wall coating containing fluoride and preparation method thereof |
| CN104559520A (en) * | 2013-10-22 | 2015-04-29 | 青岛德固建筑材料有限公司 | Self-cleaning water-based fluorocarbon paint |
| CN105199514A (en) * | 2015-10-27 | 2015-12-30 | 北京东方雨虹防水技术股份有限公司 | Fluorocarbon elastic waterproof paint for metal color steel roofing and preparation method thereof |
| CN108485433A (en) * | 2018-03-28 | 2018-09-04 | 中山市泰莱涂料化工有限公司 | The exterior wall paint of construction and the mould proof alkali resistant cracking resistance of waterproof directly on cement basal plane |
| CN110317505A (en) * | 2019-06-20 | 2019-10-11 | 嘉宝莉化工集团股份有限公司 | A kind of straight painting type aqueous one-component ceramic tile retreading coating and preparation method thereof |
-
2020
- 2020-10-29 CN CN202011183755.1A patent/CN112266678A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212301A (en) * | 2011-01-17 | 2011-10-12 | 立邦涂料（中国）有限公司 | Renovating coating for waterborne ceramic tiles and preparation method thereof |
| CN102585625A (en) * | 2011-12-29 | 2012-07-18 | 陕西宝塔山油漆股份有限公司 | Waterborne fluorocarbon self-cleaning tunnel coating |
| CN102964960A (en) * | 2012-11-15 | 2013-03-13 | 中山蓝海洋水性涂料有限公司 | Water-based fluorocarbon coating for exterior wall and preparation method thereof |
| CN103382344A (en) * | 2013-08-07 | 2013-11-06 | 武汉工程大学 | Water-based acrylate resin exterior wall coating containing fluoride and preparation method thereof |
| CN104559520A (en) * | 2013-10-22 | 2015-04-29 | 青岛德固建筑材料有限公司 | Self-cleaning water-based fluorocarbon paint |
| CN105199514A (en) * | 2015-10-27 | 2015-12-30 | 北京东方雨虹防水技术股份有限公司 | Fluorocarbon elastic waterproof paint for metal color steel roofing and preparation method thereof |
| CN108485433A (en) * | 2018-03-28 | 2018-09-04 | 中山市泰莱涂料化工有限公司 | The exterior wall paint of construction and the mould proof alkali resistant cracking resistance of waterproof directly on cement basal plane |
| CN110317505A (en) * | 2019-06-20 | 2019-10-11 | 嘉宝莉化工集团股份有限公司 | A kind of straight painting type aqueous one-component ceramic tile retreading coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 钱建华: "《精细化学品化学》", 31 December 2010, 东北大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114106641A (en) * | 2021-12-31 | 2022-03-01 | 贵州文泰防水技术有限公司 | Preparation method of environment-friendly waterproof coating |
| CN115029044A (en) * | 2022-06-07 | 2022-09-09 | 安徽同益净化科技有限公司 | Reinforced acid and alkali resistant coating for constructional engineering and preparation method thereof |
| CN115029044B (en) * | 2022-06-07 | 2023-11-10 | 安徽同益净化科技有限公司 | Acid and alkali resistant reinforced paint for building engineering and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110078867B (en) | Core-shell pure acrylic emulsion for exterior wall coating and preparation method and application thereof | |
| CN101724326B (en) | Waterborne organic silicon-acrylic acid self-stratifying coating | |
| CN108250877B (en) | Phosphate modified acrylic water-based industrial coating | |
| CA2841664C (en) | Itaconic acid polymers for improved dirt and water resistance for elastomeric wall and roof coatings | |
| CN102101960A (en) | High-hydroxy silicon-acrylate aqueous glass coating emulsion and synthesis method thereof | |
| CN101709193A (en) | Water-borne acrylic type water-proof heat-insulating paint | |
| CN112266678A (en) | A kind of exterior wall waterproof coating and preparation method thereof | |
| CN112266663A (en) | A kind of quick-drying primer for exterior wall tile renovation and preparation method thereof | |
| CN111500142A (en) | Environment-friendly latex paint capable of removing formaldehyde and preparation method thereof | |
| JP3423830B2 (en) | Resin composition for water-based paint and method for forming coating film excellent in stain resistance | |
| US6433076B1 (en) | Low-staining agent for aqueous paint, low-staining aqueous paint composition, and process for use thereof | |
| US10434539B2 (en) | Baking-type aqueous organic silicon fluorine-containing polymer paint, coating, and method for manufacturing the same | |
| KR101800969B1 (en) | Aqueous Paint Composition | |
| CN109337493A (en) | A kind of Environment-friendlyinternal internal wall paint and preparation method thereof | |
| CN111909565B (en) | A kind of paint with mirror effect and preparation method thereof | |
| CN114806289A (en) | Primer-free water-based exterior wall latex paint and preparation method thereof | |
| CN117487424B (en) | High weather-resistant anti-pollution real stone paint | |
| KR20150067719A (en) | Eifs formulations with enhance rain resistance | |
| CN109370353B (en) | Environment-friendly fluorine modified styrene-acrylic emulsion coating used in winter and preparation method thereof | |
| JP4072781B2 (en) | Acrylic silicone emulsion composition | |
| CN109517509B (en) | Quick-drying type polyurethane waterproof coating | |
| US20220403139A1 (en) | High solids pigmented latex composition comprising a vinyl acetate ethylene dispersion | |
| CN116262800B (en) | Acrylic ester emulsion for building exterior wall coating and preparation method and application thereof | |
| CN113913052B (en) | High-water-resistance single-component waterproof coating and preparation method thereof | |
| CN114410170B (en) | Energy-saving heat-insulating material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210126 |
|
| RJ01 | Rejection of invention patent application after publication |