CN112227112A - Processing method of thermal sublimation transfer paper with high absorption performance - Google Patents
Processing method of thermal sublimation transfer paper with high absorption performance Download PDFInfo
- Publication number
- CN112227112A CN112227112A CN202010983529.5A CN202010983529A CN112227112A CN 112227112 A CN112227112 A CN 112227112A CN 202010983529 A CN202010983529 A CN 202010983529A CN 112227112 A CN112227112 A CN 112227112A
- Authority
- CN
- China
- Prior art keywords
- thermal sublimation
- paper
- sublimation transfer
- absorption performance
- high absorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000859 sublimation Methods 0.000 title claims abstract description 34
- 230000008022 sublimation Effects 0.000 title claims abstract description 34
- 238000012546 transfer Methods 0.000 title claims abstract description 26
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 20
- 238000003672 processing method Methods 0.000 title claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims abstract description 19
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 15
- 238000001035 drying Methods 0.000 claims description 23
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- 238000010023 transfer printing Methods 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000839 emulsion Substances 0.000 claims description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002250 absorbent Substances 0.000 claims description 6
- 230000002745 absorbent Effects 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 6
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 229920002319 Poly(methyl acrylate) Polymers 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 3
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 3
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- XVUDRSZQKGTCPH-UHFFFAOYSA-N acetic acid;n,n-dimethylformamide Chemical compound CC(O)=O.CN(C)C=O XVUDRSZQKGTCPH-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 239000011425 bamboo Substances 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 229910052570 clay Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000002425 crystallisation Methods 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- 238000004809 thin layer chromatography Methods 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- 239000011667 zinc carbonate Substances 0.000 claims description 3
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 3
- 235000004416 zinc carbonate Nutrition 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- -1 acrylic ester Chemical group 0.000 claims description 2
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000002245 particle Substances 0.000 description 8
- 239000012466 permeate Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 241001330002 Bambuseae Species 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 239000013074 reference sample Substances 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- NOZAVIHXELGKOE-UHFFFAOYSA-J [C+4].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C Chemical group [C+4].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C NOZAVIHXELGKOE-UHFFFAOYSA-J 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
- B41M5/0355—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the macromolecular coating or impregnation used to obtain dye receptive properties
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention discloses a processing method of thermal sublimation transfer paper with high absorption performance, which comprises a preparation process of (E) -N' - (4, 6-bis (((E) -4-hydroxybenzylidene) amino) -1,3, 5-triazine-2-yl) -N, N-dimethylformamide, a treatment process of a first coating, a treatment process of a second coating and a finished product post-treatment method.
Description
Technical Field
The invention relates to the field of thermal sublimation transfer printing paper, in particular to a processing method of thermal sublimation transfer printing paper with high absorption performance.
Background
The color of the pattern is one of the most visual measuring standards for expressing the quality of the transfer printing effect, the pattern with high color vividness has better visual effect, the attractiveness of the product can be improved, and the quality of the product can be displayed. In order to provide high vividness to the transfer pattern, it is necessary to print the thermal sublimation transfer paper using a large amount of ink jet. At present, the thermal sublimation transfer printing paper on the market is easy to cause the phenomenon of picture abrasion due to large ink quantity and low drying speed when high ink jet quantity is printed. Meanwhile, in the printing of the existing transfer printing paper in the market at high ink jet amount, the ink is seriously permeated, a large amount of ink permeates into a paper fiber layer and cannot be completely sublimated, so that the transfer rate is low, and the color vividness of the obtained pattern is greatly different from the expected color vividness.
Disclosure of Invention
The invention mainly solves the technical problem of providing a processing method of thermal sublimation transfer paper with high absorption performance, which has the characteristic of quick drying, can obviously weaken the situation that dye particles and water simultaneously permeate into base paper fibers, fully improves the water permeability of the thermal sublimation transfer paper, and effectively improves the dye adsorption capacity.
In order to solve the technical problems, the invention adopts a technical scheme that: the processing method of the thermal sublimation transfer printing paper with high absorption performance comprises the following steps:
step one, adding 4-hydroxyanisole (1.6g,3.3equiv.) and 0.2mL of acetic acid into a 5mLN, N-dimethylformamide solution, and uniformly stirring for later use;
step two, adding 1,3, 5-triazine-2, 4, 6-triamine (0.5g,1.0equiv.) into 40mLN, N-dimethylformamide for mixing, stirring, heating a reaction system to 120 ℃, dropwise adding the N, N-dimethylformamide-acetic acid mixed solution of the 4-hydroxyanisole obtained in the step one, and reacting for 6 hours at 120 ℃;
monitoring the reaction through thin-layer chromatography, and cooling to room temperature after the reaction is finished;
and step four, adding toluene, stirring, separating out solids, filtering, and purifying the solids with methanol: toluene 1:1 crystallization;
step five, filtering and drying to obtain (E) -N' - (4, 6-bis ((((E) -4-hydroxybenzylidene) amino) -1,3, 5-triazine-2-yl) -N, N-dimethylformamide;
mixing and stirring the product obtained in the fifth step with 10-20 parts by weight of filler and 20-35 parts by weight of film-forming agent by weight for 60min at room temperature according to 50-75 parts by weight to obtain uniform glue solution, applying 1-5 g of glue to the front surface of the base paper, and drying to form a first coating;
seventhly, stirring and mixing 55-75 parts by weight of absorbent, 15-30 parts by weight of second film-forming agent and 1-5 parts by weight of dispersing agent at room temperature for 60min, weighing 2-8 g, and coating the mixture on the first coating;
and step eight, conveying the paper to a plurality of drying ovens for drying, conveying the paper to a drying cylinder, and finally rolling the paper to obtain the finished product of the thermal sublimation transfer paper.
In a preferred embodiment of the invention, the absorbent is one or more of talcum powder, bentonite, calcium carbonate, silicon dioxide, aluminum silicate, nano magnesium oxide, bamboo wood powder, clay, calcium sulfate, calcium carbonate, aluminum oxide, aluminum silicate, magnesium hydroxide, titanium dioxide, zinc oxide, zinc sulfate and zinc carbonate.
In a preferred embodiment of the invention, the film forming agent I is one or more of guar gum, gelatin, hydroxypropyl cellulose, sodium carboxymethyl cellulose, tertiary acrylic ester emulsion and tertiary ethylene carbonate-vinyl acetate copolymer emulsion.
In a preferred embodiment of the present invention, the dispersant is one or more of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, and sodium polymethacrylate.
In a preferred embodiment of the present invention, the filler is one or more of alumina, nano-magnesia, magnesium hydroxide, magnesium carbonate, nano-titania and nano-silica.
In a preferred embodiment of the invention, the film forming agent II is one or more of pure acrylic emulsion, vinyl acetate emulsion, polymethyl acrylate and poly-2-ethylhexyl acrylate.
The invention has the beneficial effects that: the processing method of the thermal sublimation transfer paper with the high absorption performance, provided by the invention, has the characteristic of quick drying, can obviously weaken the condition that dye particles and water simultaneously permeate into base paper fibers, fully improves the water permeability of the thermal sublimation transfer paper, and effectively improves the dye adsorption amount.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the description of the embodiments are briefly introduced below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and other drawings can be obtained by those skilled in the art without inventive efforts, wherein:
FIG. 1 is a chemical structural formula of a small molecule material according to a preferred embodiment of a method for processing a thermal sublimation transfer printing paper with high absorption performance;
FIG. 2 is a diagram of a small molecule material characterization spectrum of a preferred embodiment of a method for processing a thermal sublimation transfer printing paper with high absorption performance according to the invention;
FIG. 3 is a diagram of performance tests of a preferred embodiment of a method for processing a thermal sublimation transfer printing paper with high absorption performance according to the invention;
fig. 4 is a performance test chart of a preferred embodiment of the method for processing the thermal sublimation transfer printing paper with high absorption performance according to the invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The embodiment of the invention is as follows:
in order to obtain the processing method of the thermal sublimation transfer printing paper with high absorption performance, the following process method is adopted:
step one, adding 4-hydroxyanisole (1.6g,3.3equiv.) and 0.2mL of acetic acid into a 5mLN, N-dimethylformamide solution, and uniformly stirring for later use;
step two, adding 1,3, 5-triazine-2, 4, 6-triamine (0.5g,1.0equiv.) into 40mLN, N-dimethylformamide for mixing, stirring, heating a reaction system to 120 ℃, dropwise adding the N, N-dimethylformamide-acetic acid mixed solution of the 4-hydroxyanisole obtained in the step one, and reacting for 6 hours at 120 ℃;
monitoring the reaction through thin-layer chromatography, and cooling to room temperature after the reaction is finished;
and step four, adding toluene, stirring, separating out solids, filtering, and purifying the solids with methanol: toluene 1:1 crystallization;
step five, filtering and drying to obtain (E) -N' - (4, 6-bis ((((E) -4-hydroxybenzylidene) amino) -1,3, 5-triazine-2-yl) -N, N-dimethylformamide;
mixing and stirring the product obtained in the fifth step with 10-20 parts by weight of filler and 20-35 parts by weight of film-forming agent by weight for 60min at room temperature according to 50-75 parts by weight to obtain uniform glue solution, applying 1-5 g of glue to the front surface of the base paper, and drying to form a first coating;
seventhly, stirring and mixing 55-75 parts by weight of absorbent, 15-30 parts by weight of second film-forming agent and 1-5 parts by weight of dispersing agent at room temperature for 60min, weighing 2-8 g, and coating the mixture on the first coating;
and step eight, conveying the paper to a plurality of drying ovens for drying, conveying the paper to a drying cylinder, and finally rolling the paper to obtain the finished product of the thermal sublimation transfer paper.
Wherein the absorbent is one or more of talcum powder, bentonite, calcium carbonate, silicon dioxide, aluminum silicate, nano magnesium oxide, bamboo wood powder, clay, calcium sulfate, calcium carbonate, aluminum oxide, aluminum silicate, magnesium hydroxide, titanium dioxide, zinc oxide, zinc sulfate and zinc carbonate.
Further, the film forming agent is one or more of pure acrylic emulsion, vinyl acetate-acrylic emulsion, polymethyl acrylate and polyacrylic acid-2-ethylhexyl ester.
Further, the film forming agent is one or more of guar gum, gelatin, hydroxypropyl cellulose, sodium carboxymethyl cellulose, tertiary carbon acrylate emulsion and tertiary ethylene carbonate-vinyl acetate copolymer emulsion.
Further, the dispersing agent is one or more of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate and sodium polymethacrylate.
Further, the filler is one or more of alumina, nano-magnesia, magnesium hydroxide, magnesium carbonate, nano-titanium dioxide and nano-silica.
Further, the second film forming agent is one or more of pure acrylic emulsion, vinyl acetate-acrylic emulsion, polymethyl acrylate and poly-2-ethylhexyl acrylate.
The invention selects micromolecule material (E) -N' - (4, 6-bis (((E) -4-hydroxybenzylidene) amino) -1,3, 5-triazine-2-yl) -N, N-dimethylformamide as the thermal sublimation functional material, the chemical structural formula is shown in figure 1, and the representation spectrogram is shown in figure 2. the micromolecule material is a novel high-efficiency thermal sublimation micromolecule material which has good permeability to water and can ensure that water can rapidly permeate through the coating material, because the interior of molecules has longer conjugate chains and large conjugation range, and a plurality of active sites in the molecular structure can react with dye particles, therefore, the micromolecule material can perform high-efficiency action on the dye particles, has rapid action and large action quantity, can weaken the condition that the dye particles and water simultaneously permeate into base paper fibers, is favorable for improving the ink absorption capacity of the thermal sublimation coating.
The second coating layer is provided with a large amount of porous fillers, a micropore structure is formed in the coating layer, water in ink impacts on micropores during printing and is adsorbed through capillary action, a dry pattern can be quickly formed on the surface of the transfer paper, and the pattern abrasion phenomenon caused by the fact that the pattern on the surface of the transfer paper is not dry is reduced. And meanwhile, the ink is preliminarily fixed, the permeation speed of the ink is reduced, most of dye particles slowly penetrate through the second coating, and the effect of the first coating on the dye is better facilitated.
Based on the principle theory, the inventor combines the experiment to carry out the drying speed test:
coating only a first coating layer on base paper as a reference sample, respectively printing CMYK four colors by using 400% ink jet quantity under the indoor condition that the temperature is 25 ℃ and the humidity is 55%, covering a white paper piece on the surface of a color block of transfer paper at intervals under the condition of no external auxiliary drying condition after printing, applying a weight of 200g on the paper piece to stress, and observing whether the white paper piece has color adhesion after standing for 5 s. And repeatedly selecting color blocks with different natural standing times for testing until no color block of the white paper sheet is adhered, namely indicating that the surface of the color block is dry, wherein the standing time is the printing drying time. Test results for example as can be seen in fig. 3, the drying speed of the transfer paper is significantly increased with the addition of the second coating layer.
Also based on the above principle theory, the inventors conducted a transfer rate test in combination with experiments:
selecting a thermal sublimation coating material taking a cellulose traditional high polymer material as a thermal sublimation functional material as a reference sample, respectively selecting the conditions of the ink-jet amount of 100%, 200%, 300% and 400% to print mixed black under the same environment, and carrying out hot pressing for 30s at 220 ℃ for transfer printing. The color difference before and after transfer was measured using a model NR10QC color difference meter from a 3nh manufacturer and was calculated according to the formula etac1＝(C0-C1)/C0The four color transfer rates were calculated and the data pairs are shown in fig. 4. Therefore, the traditional coating is saturated due to the effect of the traditional high polymer material on the ink, the excessive ink permeates down and is absorbed by the base paper layer, the dye particles are fixed on the base paper layer and cannot be sublimated, the transfer rate is greatly influenced by the ink jet amount, and the transfer rate is obviously reduced along with the increase of the ink jet amount. The novel coating material of the project selects a novel small molecular material (E) -N' - (4, 6-bis ((((E) -4-hydroxybenzylidene) amino) -1,3, 5-triazine-2-yl) -N, N-dimethylformamide to replace a traditional high molecular material as a main thermal sublimation functional material, the transfer rate is slightly influenced by the ink jet amount, and the transfer rate can still be kept above 90% under the condition of 400% of the ink jet amount.
In conclusion, the processing method of the thermal sublimation transfer paper with the high absorption performance has the characteristic of quick drying, can obviously weaken the situation that dye particles and water simultaneously permeate into base paper fibers, fully improves the water seepage performance of the thermal sublimation transfer paper, and effectively improves the dye adsorption amount.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications of equivalent structures and equivalent processes, which are made by the present specification, or directly or indirectly applied to other related technical fields, are included in the scope of the present invention.
Claims (6)
1. A processing method of thermal sublimation transfer printing paper with high absorption performance is characterized by comprising the following steps:
step one, adding 4-hydroxyanisole (1.6g,3.3equiv.) and 0.2mL of acetic acid into 5mL of DMF solution, and uniformly stirring for later use;
step two, adding 1,3, 5-triazine-2, 4, 6-triamine (0.5g,1.0equiv.) into 40mLN, N-dimethylformamide for mixing, stirring, heating a reaction system to 120 ℃, dropwise adding the N, N-dimethylformamide-acetic acid mixed solution of the 4-hydroxyanisole obtained in the step one, and reacting for 6 hours at 120 ℃;
monitoring the reaction through thin-layer chromatography, and cooling to room temperature after the reaction is finished;
and step four, adding toluene, stirring, separating out solids, filtering, and purifying the solids with methanol: toluene 1:1 crystallization;
step five, filtering and drying to obtain (E) -N' - (4, 6-bis ((((E) -4-hydroxybenzylidene) amino) -1,3, 5-triazine-2-yl) -N, N-dimethylformamide;
mixing and stirring the product obtained in the fifth step with 10-20 parts by weight of filler and 20-35 parts by weight of film-forming agent by weight for 60min at room temperature according to 50-75 parts by weight to obtain uniform glue solution, applying 1-5 g of glue to the front surface of the base paper, and drying to form a first coating;
seventhly, stirring and mixing 55-75 parts by weight of absorbent, 15-30 parts by weight of second film-forming agent and 1-5 parts by weight of dispersing agent at room temperature for 60min, weighing 2-8 g, and coating the mixture on the first coating;
and step eight, conveying the paper to a plurality of drying ovens for drying, conveying the paper to a drying cylinder, and finally rolling the paper to obtain the finished product of the thermal sublimation transfer paper.
2. The method for processing thermal sublimation transfer printing paper with high absorption performance according to claim 1, wherein the absorbent is one or more of talcum powder, bentonite, calcium carbonate, silicon dioxide, aluminum silicate, nano magnesium oxide, bamboo wood powder, clay, calcium sulfate, calcium carbonate, aluminum oxide, aluminum silicate, magnesium hydroxide, titanium dioxide, zinc oxide, zinc sulfate and zinc carbonate.
3. The method for processing the thermal sublimation transfer printing paper with high absorption performance according to claim 1, wherein the first film forming agent is one or more of guar gum, gelatin, hydroxypropyl cellulose, sodium carboxymethyl cellulose, tertiary acrylic ester emulsion and tertiary vinyl carbonate-vinyl acetate copolymer emulsion.
4. The method for processing the thermal sublimation transfer printing paper with high absorption performance according to claim 1, wherein the dispersant is one or more of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate and sodium polymethacrylate.
5. The method for processing the thermal sublimation transfer printing paper with high absorption performance according to claim 1, wherein the filler is one or more of alumina, nano-magnesia, magnesium hydroxide, magnesium carbonate, nano-titania and nano-silica.
6. The method for processing the thermal sublimation transfer printing paper with high absorption performance according to claim 1, wherein the film forming agent II is one or more of pure acrylic emulsion, vinyl acetate emulsion, polymethyl acrylate and poly-2-ethylhexyl acrylate.
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