CN112226294A - Gel-shaped descaling and rust removing cleaning agent and preparation method thereof - Google Patents
Gel-shaped descaling and rust removing cleaning agent and preparation method thereof Download PDFInfo
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- CN112226294A CN112226294A CN202011312560.2A CN202011312560A CN112226294A CN 112226294 A CN112226294 A CN 112226294A CN 202011312560 A CN202011312560 A CN 202011312560A CN 112226294 A CN112226294 A CN 112226294A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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Abstract
The invention provides a jelly-shaped descaling and rust removing cleaning agent which comprises the following raw materials in parts by weight: 2-15 parts of nonionic surfactant, 2-5 parts of disodium ethylene diamine tetraacetate, 2-15 parts of glycolic acid, 0.1-0.3 part of propionyl chloride, 5-18 parts of phosphoric acid, 5-18 parts of citric acid, 0.5-1.5 parts of sodium tartrate, 0.1-0.3 part of benzotriazole, 2-15 parts of sulfamic acid, 0.5-1.5 parts of thickener, 2-5 parts of hydroxyethylidene diphosphate, 0.5-1.5 parts of sodium gluconate and 200-350 parts of deionized water; the cleaning agent has the beneficial effects of good cleaning effect and difficulty in causing damage to appliances, and is suitable for the field of cleaning agents.
Description
Technical Field
The invention relates to the technical field of cleaning agents, in particular to a jelly-shaped descaling and rust removing cleaning agent and a preparation method thereof.
Background
The dirt and rust stains are formed by the deposition residues of calcium ions, magnesium ions, iron ions, calcium carbonate, carbonate and other substances in water, and long-term uncleanness can cause mildew spots on the surface of an object, and the dirt and rust spots deepen and expand, are not easy to clean and affect the appearance, and even can be corroded and damaged.
In order to solve the problems of difficult cleaning, influence on appearance and corrosion damage caused by dirt, rust and mildew, the invention provides a liquid detergent composition for hard surfaces, which comprises a phosphoric acid chelating agent, other chelating agents, a surfactant and water, and is simple in preparation raw materials, the cleaning rate can reach 80-90%, but the prepared raw materials can cause irritation to skin, damage to appliances such as stainless steel parts and the like, and the liquid detergent composition is not suitable for long-term use.
Most of the existing descaling and rust removing cleaning agents are liquid and solid, and no relevant research on jelly-shaped descaling and rust removing cleaning agents exists.
Disclosure of Invention
Aiming at the defects in the related technology, the technical problem to be solved by the invention is as follows: provides a jelly-shaped descaling and rust removing cleaning agent which has good cleaning effect and is not easy to cause the damage of appliances.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: a jelly-shaped descaling and rust removing cleaning agent comprises the following raw materials in parts by weight: 2-15 parts of nonionic surfactant, 2-5 parts of disodium ethylene diamine tetraacetate, 2-15 parts of glycolic acid, 0.1-0.3 part of propionyl chloride, 5-18 parts of phosphoric acid, 5-18 parts of citric acid, 0.5-1.5 parts of sodium tartrate, 0.1-0.3 part of benzotriazole, 2-15 parts of sulfamic acid, 0.5-1.5 parts of thickener, 2-5 parts of hydroxyethylidene diphosphate, 0.5-1.5 parts of sodium gluconate and 200-350 parts of deionized water.
Preferably, the feed comprises the following raw materials in parts by weight: 8 parts of nonionic surfactant, 3 parts of ethylene diamine tetraacetic acid, 10 parts of glycolic acid, 0.1 part of propionyl chloride, 15 parts of phosphoric acid, 10 parts of citric acid, 1.0 part of sodium tartrate, 0.2 part of benzotriazole, 10 parts of sulfamic acid, 1.0 part of thickener, 5 parts of hydroxyethylidene diphosphate, 1.0 part of sodium gluconate and 300 parts of deionized water.
Preferably, the thickener is one or more of acrylic acid and acrylate.
Preferably, the feed also comprises the following raw materials in parts by weight: 2-5 parts of plant fragrance.
Preferably, the plant fragrance is one of lavender extract, peppermint extract, jasmine extract and rose extract.
The invention also provides a preparation method of the jelly-shaped descaling and rust removing cleaning agent, which comprises the following steps: (1) heating deionized water to 55-60 ℃, adding the deionized water into a reaction kettle, adding a nonionic surfactant into the reaction kettle, cooling the temperature in the reaction kettle to normal temperature, sequentially adding disodium ethylene diamine tetraacetate, glycolic acid and propionyl chloride, uniformly stirring, and standing for 15-20 min to obtain a mixed solution 1; (2) sequentially adding phosphoric acid, citric acid and sodium tartrate into the mixed solution 1 to obtain a mixed solution 2, and stirring all the time in the adding process; (3) and finally, mixing benzotriazole, sulfamic acid, hydroxyethylidene diphosphate, sodium gluconate and a thickening agent, adding the mixture into the mixed solution 2, uniformly mixing, cooling to room temperature, and packaging.
Preferably, the thickener is one or more of acrylic acid and acrylate.
Preferably, in the step (3), benzotriazole, sulfamic acid, hydroxy ethylidene diphosphate, sodium gluconate and a thickening agent are mixed and then added into the mixed solution 2 to be uniformly mixed, and the plant fragrance is dropwise added while the mixture is uniformly mixed.
Preferably, the plant fragrance is one of lavender extract, peppermint extract, jasmine extract and rose extract.
The invention has the beneficial technical effects that:
1. the descaling and rust removing cleaning agent is prepared from 2-15 parts of nonionic surfactant, 2-5 parts of disodium ethylene diamine tetraacetate, 2-15 parts of glycolic acid, 0.1-0.3 part of propionyl chloride, 5-18 parts of phosphoric acid, 5-18 parts of citric acid, 0.5-1.5 parts of sodium tartrate, 0.1-0.3 part of benzotriazole, 2-15 parts of sulfamic acid, 0.5-1.5 parts of thickening agent, 5 parts of hydroxyethylidene diphosphate, 1.0 part of sodium gluconate and 200-350 parts of deionized water. All the raw materials are matched with each other, so that the utensil can be effectively cleaned, and dirt, rust and mildew on the utensil can be quickly removed; the raw materials do not contain any stimulating component, do not hurt the skin, do not damage the appliances such as stainless steel parts, chromium-plated parts and the like, and are suitable for long-term use.
The descaling and rust removing cleaning agent prepared by the invention is in a jelly shape, and the jelly-shaped gel is easy to operate and convenient to use, so that the cleaning is more thorough.
2. The thickening agent in the raw material provided by the invention is one or more of acrylic acid and acrylate. Acrylic acid and acrylic ester have excellent polymerization esterification capability, can be well mixed with other raw materials, and can improve the cleaning effect of the jelly-shaped descaling and rust removing cleaning agent.
3. The raw materials provided by the invention also comprise 2-5 parts of plant fragrance. The plant fragrance contains various plants and is refined, the method is safe and environment-friendly, and the prepared descaling and rust removing cleaning agent has fragrance and is not pungent.
4. The invention provides a preparation method of a jelly-shaped descaling and rust removing cleaning agent, which comprises the following steps: (1) heating deionized water to 55-60 ℃, adding the deionized water into a reaction kettle, adding a nonionic surfactant into the reaction kettle, cooling the temperature in the reaction kettle to normal temperature, sequentially adding disodium ethylene diamine tetraacetate, glycolic acid and propionyl chloride, uniformly stirring, and standing for 15-20 min to obtain a mixed solution 1; (2) sequentially adding phosphoric acid, citric acid and sodium tartrate into the mixed solution 1 to obtain a mixed solution 2, and stirring all the time in the adding process; (3) and finally, mixing benzotriazole, sulfamic acid, hydroxyethylidene diphosphate, sodium gluconate and a thickening agent, adding the mixture into the mixed solution 2, uniformly mixing, cooling to room temperature, and packaging.
The preparation method adopted by the invention is simple and convenient to operate, and the descaling and rust removing cleaning agent prepared by the preparation method provided by the invention can effectively clean the utensil and quickly remove dirt, rust and mildew on the utensil.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments, and it is obvious that the described embodiments are some embodiments, but not all embodiments, of the present invention; all other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the actual preparation process, the weight parts of the raw materials correspond to the grams.
In the actual preparation process, 1 part of the descaling and rust removing cleaning agent is prepared according to the proportion of 1 g.
Examples one to five descaling and rust removing cleaners were prepared according to the components and their contents specified in table 1.
The raw materials adopted in the invention are matched with each other, so that the utensil can be effectively cleaned, and dirt, rust and mildew on the utensil can be quickly removed; the raw materials do not contain any stimulating component, do not hurt the skin, do not damage the appliances such as stainless steel parts, chromium-plated parts and the like, and are suitable for long-term use.
The descaling and rust removing cleaning agent prepared by the invention is in a jelly shape, and the jelly-shaped gel is easy to operate and convenient to use, so that the cleaning is more thorough.
Acrylic acid and acrylic ester have excellent polymerization esterification capability, can be well mixed with other raw materials, and can improve the cleaning effect of the jelly-shaped descaling and rust removing cleaning agent.
The plant fragrance contains various plants and is refined, the method is safe and environment-friendly, and the prepared descaling and rust removing cleaning agent has fragrance and is not pungent.
Further, the thickening agent is one or more of acrylic acid and acrylate.
Acrylic acid and acrylic ester have excellent polymerization esterification capability, can be well mixed with other raw materials, and can improve the cleaning effect of the jelly-shaped descaling and rust removing cleaning agent.
Further, the feed also comprises the following raw materials in parts by weight: 2-5 parts of plant fragrance.
The plant fragrance contains various plants and is refined, the method is safe and environment-friendly, and the prepared descaling and rust removing cleaning agent has fragrance and is not pungent.
Further, the plant fragrance is one of lavender extract, mint extract, jasmine extract and rose extract.
Specifically, the plant fragrance may also be one or more of fructus Cnidii extract, radix Sophorae Flavescentis extract, radix Isatidis extract, Glycyrrhrizae radix extract, flos Lonicerae extract, fructus Canarii albi extract, herba Agastaches extract and Coptidis rhizoma extract.
Specifically, the nonionic surfactant is one of polyoxyethylene alkylamine, polyoxyethylene fatty acid ester and polyoxyethylene alkylolamide.
One of polyoxyethylene alkylamine, fatty acid polyoxyethylene ester and polyoxyethylene alkylolamide is used as the nonionic surfactant, so that the reaction between the raw materials can be promoted, and the reaction speed is further increased.
More specifically, the concentration of the nonionic surfactant is 1-2 wt.%.
Specifically, the concentration of the glycolic acid is 2-5 wt.%.
Specifically, the concentration of the propionyl chloride is 1-2 wt.%.
Specifically, the concentration of the phosphoric acid is 1-2 wt.%.
Specifically, the concentration of the citric acid is 2-5 wt.%.
Specifically, the concentration of the sulfamic acid is 1-2 wt.%.
Specifically, the concentration of the hydroxyethylidene diphosphate is 1.5-2.5 wt.%.
Specifically, the concentration of the sodium gluconate is 0.5-1.2 wt.%.
Specifically, the concentration of the thickening agent is 1-2 wt.%.
Specifically, the concentration of the plant fragrance is 45-60 wt.%.
The descaling and rust removing cleaning agent prepared from the raw materials with the concentrations has better cleaning effect, and can quickly remove dirt, rust and mildew on an appliance.
The phosphoric acid, the citric acid, the sulfamic acid and the glycolic acid adopted by the invention are all food-grade or common cosmetic raw materials, are safe and environment-friendly, and cannot cause damage to skin.
Example one
A preparation method of jelly-shaped descaling and rust removing cleaning agent comprises the following steps:
(1) heating deionized water to 55 ℃, adding the deionized water into a reaction kettle, adding a nonionic surfactant into the reaction kettle, cooling the temperature in the reaction kettle to normal temperature, sequentially adding disodium ethylene diamine tetraacetate, glycolic acid and propionyl chloride, uniformly stirring, and standing for 15-20 min to obtain a mixed solution 1;
(2) sequentially adding phosphoric acid, citric acid and sodium tartrate into the mixed solution 1 to obtain a mixed solution 2, and stirring all the time in the adding process;
(3) and finally, mixing benzotriazole, sulfamic acid, hydroxyethylidene diphosphate, sodium gluconate and a thickening agent, adding the mixture into the mixed solution 2, uniformly mixing, cooling to room temperature, and packaging.
Further, the thickener is acrylic acid.
Further, the plant fragrance is lavender extract.
Specifically, the nonionic surfactant is polyoxyethylene alkylamine.
Example two
A preparation method of jelly-shaped descaling and rust removing cleaning agent comprises the following steps:
(1) heating deionized water to 60 ℃, adding the deionized water into a reaction kettle, adding a nonionic surfactant into the reaction kettle, cooling the temperature in the reaction kettle to normal temperature, sequentially adding disodium ethylene diamine tetraacetate, glycolic acid and propionyl chloride, uniformly stirring, and standing for 15-20 min to obtain a mixed solution 1;
(2) sequentially adding phosphoric acid, citric acid and sodium tartrate into the mixed solution 1 to obtain a mixed solution 2, and stirring all the time in the adding process;
(3) and finally, mixing benzotriazole, sulfamic acid, hydroxyethylidene diphosphate, sodium gluconate and a thickening agent, adding the mixture into the mixed solution 2, uniformly mixing, cooling to room temperature, and packaging.
Further, the thickener is acrylic acid.
Further, the plant fragrance is rose extract.
Specifically, the nonionic surfactant is polyoxyethylene fatty acid ester.
EXAMPLE III
A preparation method of jelly-shaped descaling and rust removing cleaning agent comprises the following steps:
(1) heating deionized water to 58 ℃, adding the deionized water into a reaction kettle, adding a nonionic surfactant into the reaction kettle, cooling the temperature in the reaction kettle to normal temperature, sequentially adding disodium ethylene diamine tetraacetate, glycolic acid and propionyl chloride, uniformly stirring, and standing for 15-20 min to obtain a mixed solution 1;
(2) sequentially adding phosphoric acid, citric acid and sodium tartrate into the mixed solution 1 to obtain a mixed solution 2, and stirring all the time in the adding process;
(3) and finally, mixing benzotriazole, sulfamic acid, hydroxyethylidene diphosphate, sodium gluconate and a thickening agent, adding the mixture into the mixed solution 2, uniformly mixing, cooling to room temperature, and packaging.
Further, the thickener is an acrylate.
Further, the plant fragrance is a mint extracting solution.
Specifically, the nonionic surfactant is polyoxyethylene alkylamine.
Example four
A preparation method of jelly-shaped descaling and rust removing cleaning agent comprises the following steps:
(1) heating deionized water to 58 ℃, adding the deionized water into a reaction kettle, adding a nonionic surfactant into the reaction kettle, cooling the temperature in the reaction kettle to normal temperature, sequentially adding disodium ethylene diamine tetraacetate, glycolic acid and propionyl chloride, uniformly stirring, and standing for 15-20 min to obtain a mixed solution 1;
(2) sequentially adding phosphoric acid, citric acid and sodium tartrate into the mixed solution 1 to obtain a mixed solution 2, and stirring all the time in the adding process;
(3) and finally, mixing benzotriazole, sulfamic acid, hydroxyethylidene diphosphate, sodium gluconate and a thickening agent, adding the mixture into the mixed solution 2, uniformly mixing, cooling to room temperature, and packaging.
Further, the thickener is acrylic acid and acrylate.
Further, the plant fragrance is jasmine extraction liquid.
Specifically, the nonionic surfactant is polyoxyethylene alkylolamide.
EXAMPLE five
A preparation method of jelly-shaped descaling and rust removing cleaning agent comprises the following steps:
(1) heating deionized water to 60 ℃, adding the deionized water into a reaction kettle, adding a nonionic surfactant into the reaction kettle, cooling the temperature in the reaction kettle to normal temperature, sequentially adding disodium ethylene diamine tetraacetate, glycolic acid and propionyl chloride, uniformly stirring, and standing for 15-20 min to obtain a mixed solution 1;
(2) sequentially adding phosphoric acid, citric acid and sodium tartrate into the mixed solution 1 to obtain a mixed solution 2, and stirring all the time in the adding process;
(3) and finally, mixing benzotriazole, sulfamic acid, hydroxyethylidene diphosphate, sodium gluconate and a thickening agent, adding the mixture into the mixed solution 2, uniformly mixing, cooling to room temperature, and packaging.
Further, the thickener is an acrylate.
Further, the plant fragrance is lavender extract.
Specifically, the nonionic surfactant is polyoxyethylene fatty acid ester.
The preparation method adopted by the invention is simple and convenient to operate, and the descaling and rust removing cleaning agent prepared by the preparation method provided by the invention can effectively clean the utensil and quickly remove dirt, rust and mildew on the utensil.
The most preferable cleaning device of the descaling and rust removing cleaning agent prepared by the invention is ceramic tiles, metal surfaces, stainless steel, glass, plastic products and vehicle paint surfaces.
Comparative example 1
Compared with the first embodiment, the comparative example is different in that: the raw materials do not include: disodium ethylene diamine tetraacetate, propionyl chloride, hydroxyethylidene diphosphate and sodium gluconate.
Comparative example No. two
Compared with the three phases of the example, the comparative example is different in that: the raw materials do not include: sodium tartrate, benzotriazole and sulfamic acid.
Instructions for use: applying the product on the surface of the utensil; standing for 5-15 minutes according to the light degree of dirt and rust stains, and then wiping the dirt and rust stains with a wipe; the cleaned surface of the instrument is wiped by a clean wet towel to completely remove residues. If necessary, the construction can be repeated according to the degree of the dirt.
The descaling and rust-removing cleaning agents prepared in the first to fifth examples, the first comparative example and the second comparative example clean stainless steel parts with the same degree of dirt, rust and mildew according to the above description, and the cleaning effect is shown in table 1.
TABLE 1
As can be seen from Table 1, the descaling and rust removing cleaning agent prepared by the invention has the cleaning rate of 83.6-88.5% on dirt, rust and mildew. Compared with the comparative example I and the comparative example II, the improvement of the comparative example I and the comparative example II is 11-13%.
The descaling and rust removing cleaning agent prepared in the embodiment of the application can achieve a good cleaning effect on ceramic tiles, metal surfaces, stainless steel, glass, plastic products and vehicle paint surfaces, and in order to save space and achieve the purposes of conciseness and conciseness, the stainless steel part is cleaned in the embodiment of the invention.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
In the foregoing embodiments, the descriptions of the respective embodiments have respective emphasis, and for parts that are not described in detail in a certain embodiment, reference may be made to related descriptions of other embodiments.
In addition, "first", "second", and the like in the above embodiments are for distinguishing the embodiments, and do not represent merits of the embodiments.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
Claims (9)
1. A jelly-shaped descaling and rust removing cleaning agent is characterized in that: the feed comprises the following raw materials in parts by weight: 2-15 parts of nonionic surfactant, 2-5 parts of disodium ethylene diamine tetraacetate, 2-15 parts of glycolic acid, 0.1-0.3 part of propionyl chloride, 5-18 parts of phosphoric acid, 5-18 parts of citric acid, 0.5-1.5 parts of sodium tartrate, 0.1-0.3 part of benzotriazole, 2-15 parts of sulfamic acid, 0.5-1.5 parts of thickener, 2-5 parts of hydroxyethylidene diphosphate, 0.5-1.5 parts of sodium gluconate and 200-350 parts of deionized water.
2. The jelly-like descaling and rust removing detergent as claimed in claim 1, wherein: the feed comprises the following raw materials in parts by weight: 8 parts of nonionic surfactant, 3 parts of ethylene diamine tetraacetic acid, 10 parts of glycolic acid, 0.1 part of propionyl chloride, 15 parts of phosphoric acid, 10 parts of citric acid, 1.0 part of sodium tartrate, 0.2 part of benzotriazole, 10 parts of sulfamic acid, 1.0 part of thickener, 5 parts of hydroxyethylidene diphosphate, 1.0 part of sodium gluconate and 300 parts of deionized water.
3. The jelly-like descaling and rust removing detergent as claimed in claim 1 or 2, wherein: the thickening agent is one or more of acrylic acid and acrylate.
4. The jelly-like descaling and rust removing detergent as claimed in claim 1, wherein: the feed also comprises the following raw materials in parts by weight: 2-5 parts of plant fragrance.
5. The jelly-like descaling and rust removing detergent as claimed in claim 4, wherein: the plant fragrance is one of lavender extract, mint extract, jasmine extract and rose extract.
6. The method for preparing jelly-like detergent for removing scale and rust as claimed in claim 1, characterized in that: the method comprises the following steps:
(1) heating deionized water to 55-60 ℃, adding the deionized water into a reaction kettle, adding a nonionic surfactant into the reaction kettle, cooling the temperature in the reaction kettle to normal temperature, sequentially adding disodium ethylene diamine tetraacetate, glycolic acid and propionyl chloride, uniformly stirring, and standing for 15-20 min to obtain a mixed solution 1;
(2) sequentially adding phosphoric acid, citric acid and sodium tartrate into the mixed solution 1 to obtain a mixed solution 2, and stirring all the time in the adding process;
(3) and finally, mixing benzotriazole, sulfamic acid, hydroxyethylidene diphosphate, sodium gluconate and a thickening agent, adding the mixture into the mixed solution 2, uniformly mixing, cooling to room temperature, and packaging.
7. The method for preparing jelly-like detergent for removing scale and rust according to claim 6, which is characterized in that: the thickening agent is one or more of acrylic acid and acrylate.
8. The method for preparing jelly-like detergent for removing scale and rust according to claim 6, which is characterized in that: in the step (3), benzotriazole, sulfamic acid, hydroxy ethylidene diphosphate, sodium gluconate and a thickening agent are mixed and then added into the mixed solution 2 to be uniformly mixed, and the plant fragrance is dropwise added while the mixture is uniformly mixed.
9. The method for preparing jelly-like detergent for removing scale and rust according to claim 8, which is characterized in that: the plant fragrance is one of lavender extract, mint extract, jasmine extract and rose extract.
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| CN202011312560.2A CN112226294A (en) | 2020-11-20 | 2020-11-20 | Gel-shaped descaling and rust removing cleaning agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112980593A (en) * | 2021-02-08 | 2021-06-18 | 辽宁大学 | Active descaling powder |
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| CN111349527A (en) * | 2020-04-15 | 2020-06-30 | 广州立白企业集团有限公司 | Mildew-removing gel and preparation method thereof |
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| CN101029281A (en) * | 2007-03-11 | 2007-09-05 | 李泽潜 | Cleaner and its production |
| CN103194343A (en) * | 2013-03-06 | 2013-07-10 | 江苏雪豹日化有限公司 | Gel-type pipeline dredge agent and preparation method thereof |
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Application publication date: 20210115 |