CN112144004A - A kind of blade tip wear-resistant cutting coating with saturated mosaic structure and preparation method thereof - Google Patents
A kind of blade tip wear-resistant cutting coating with saturated mosaic structure and preparation method thereof Download PDFInfo
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- 238000000576 coating method Methods 0.000 title claims abstract description 83
- 239000011248 coating agent Substances 0.000 title claims abstract description 73
- 238000005520 cutting process Methods 0.000 title claims abstract description 39
- 229920006395 saturated elastomer Polymers 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 113
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 86
- 239000000956 alloy Substances 0.000 claims abstract description 86
- 239000000919 ceramic Substances 0.000 claims abstract description 56
- 238000010438 heat treatment Methods 0.000 claims abstract description 50
- 239000000758 substrate Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 19
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- 238000009826 distribution Methods 0.000 claims description 11
- 230000006698 induction Effects 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 238000004372 laser cladding Methods 0.000 claims description 8
- 238000010290 vacuum plasma spraying Methods 0.000 claims description 6
- 230000001360 synchronised effect Effects 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 238000005253 cladding Methods 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 3
- 230000017525 heat dissipation Effects 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims 1
- 238000003892 spreading Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- 238000007789 sealing Methods 0.000 abstract description 5
- 238000012986 modification Methods 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 47
- 229910003460 diamond Inorganic materials 0.000 description 21
- 239000010432 diamond Substances 0.000 description 21
- 229910052582 BN Inorganic materials 0.000 description 10
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 10
- 238000001035 drying Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 239000002356 single layer Substances 0.000 description 6
- 238000004506 ultrasonic cleaning Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910000601 superalloy Inorganic materials 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/134—Plasma spraying
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/10—Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
- C23C24/103—Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
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Abstract
本发明公开了一种具有饱和镶嵌结构的叶尖抗磨切削涂层及其制备方法,属于材料表面改性和涂层技术领域,本发明的涂层是将硬质陶瓷颗粒离散分布并通过粘结合金结合在叶尖端面上,粘结合金层与叶尖合金形成牢固冶金结合,并将硬质陶瓷颗粒紧紧包裹住,涂层的硬质陶瓷颗粒棱角尖锐暴露且与叶尖端面结合牢固。饱和镶嵌结构使得涂层在具有超高硬度的前提下,又具有良好的结合强度。涂层外棱角尖锐,可以用来快速切削可磨耗封严涂层,防止叶尖剧烈升温。
The invention discloses a blade tip anti-wear cutting coating with a saturated mosaic structure and a preparation method thereof, belonging to the technical field of material surface modification and coating. The bonding alloy is bonded to the blade tip surface, and the bonding alloy layer forms a strong metallurgical bond with the blade tip alloy, and tightly wraps the hard ceramic particles. The hard ceramic particles of the coating are sharply exposed and firmly bonded to the blade tip surface. . The saturated damascene structure enables the coating to have good bonding strength on the premise of ultra-high hardness. The outer edges and corners of the coating are sharp, which can be used to quickly cut the wearable sealing coating to prevent the blade tip from heating up violently.
Description
技术领域technical field
本发明属于材料表面改性和涂层技术领域,具体涉及一种具有饱和镶嵌结构的叶尖抗磨切削涂层及其制备方法。The invention belongs to the technical field of material surface modification and coating, and in particular relates to a blade tip wear-resistant cutting coating with a saturated mosaic structure and a preparation method thereof.
背景技术Background technique
高性能航空发动机对效率和安全性都有更高的要求,而机匣与叶尖之间的间隙大小是影响发动机性能的关键因素。为保证发动机的高效,该间隙不宜过大。而间隙过小时,发动机运行过程中离心、喘振等因素会使得叶尖与机匣内壁发生碰摩而损坏叶尖。因此,常采用封严技术达到提高效率、保护叶尖的目的。即在发动机机匣内壁制备一层可磨耗封严涂层,在叶尖制备一层耐磨涂层,两种涂层相互配合形成合适间隙。High-performance aero-engines have higher requirements for efficiency and safety, and the size of the gap between the casing and the blade tip is a key factor affecting the performance of the engine. To ensure the high efficiency of the engine, the clearance should not be too large. If the clearance is too small, factors such as centrifugal and surge during engine operation will cause the blade tip to rub against the inner wall of the casing and damage the blade tip. Therefore, sealing technology is often used to improve efficiency and protect the blade tip. That is, a layer of wearable sealing coating is prepared on the inner wall of the engine casing, and a layer of wear-resistant coating is prepared on the blade tip, and the two coatings cooperate with each other to form a suitable gap.
叶尖耐磨涂层常采用金属基陶瓷复合材料,陶瓷颗粒通过合金粘结相固定在叶尖端面,从而提高叶尖的硬度及耐磨性。目前,叶尖耐磨涂层的常用制备方法为激光熔覆技术和电镀方法。用激光熔覆技术制备出的叶尖涂层能大幅度提高基体的硬度和耐磨性,但存在对基体热损伤严重的问题。用电镀法制备的叶尖涂层可有效控制厚度,但涂层与基体结合强度不高,涂层易脱落。The wear-resistant coating of the blade tip is often made of metal-based ceramic composite materials, and the ceramic particles are fixed on the tip surface of the blade through the alloy binder phase, thereby improving the hardness and wear resistance of the blade tip. At present, the commonly used preparation methods of blade tip wear-resistant coatings are laser cladding technology and electroplating method. The blade tip coating prepared by laser cladding technology can greatly improve the hardness and wear resistance of the substrate, but there is a problem of serious thermal damage to the substrate. The thickness of the blade tip coating prepared by electroplating can be effectively controlled, but the bonding strength between the coating and the substrate is not high, and the coating is easy to fall off.
发动机转速可达50000r/min,叶尖切削涂层与可磨耗涂层以极大的相对速度发生碰摩产生巨大的热量,导致叶尖升温剧烈。由于叶尖材料本身耐磨性能差,在服役过程中与可磨耗涂层碰摩易发生擦伤,单纯提高叶尖的硬度和耐磨性无法起到保护叶尖的目的。The engine speed can reach 50000r/min, and the blade tip cutting coating and the abradable coating rub against each other at a great relative speed to generate huge heat, resulting in the sharp heating of the blade tip. Due to the poor wear resistance of the blade tip material itself, it is easy to rub against the abradable coating during service, and simply improving the hardness and wear resistance of the blade tip cannot protect the blade tip.
发明内容SUMMARY OF THE INVENTION
为了解决叶尖切削涂层与可磨耗封严涂层高速碰摩时发热严重的技术问题,本发明提出了一种具有饱和镶嵌结构的叶尖抗磨切削涂层及其制备方法,当叶尖涂层对可磨耗涂层产生切削作用时,可有效降低摩擦生热,降低叶尖升温速率,从而防止叶尖磨损。In order to solve the technical problem of serious heat generation when the blade tip cutting coating and the abradable sealing coating are rubbed at high speed, the present invention proposes a blade tip anti-wear cutting coating with a saturated mosaic structure and a preparation method thereof. When the coating has a cutting effect on the abradable coating, it can effectively reduce frictional heat generation and reduce the heating rate of the blade tip, thereby preventing blade tip wear.
为了达到上述目的,本发明采用以下技术方案予以实现:In order to achieve the above object, the present invention adopts the following technical solutions to be realized:
本发明公开了一种具有饱和镶嵌结构的叶尖抗磨切削涂层,其特征在于,由硬质陶瓷颗粒与粘结合金层构成,硬质陶瓷颗粒离散分布并通过粘结合金层结合在叶尖基体的端面上,粘结合金层与叶尖基体的合金形成牢固冶金结合,并将硬质陶瓷颗粒自身高度的0.5-0.9倍包裹住,形成硬质陶瓷颗粒棱角尖锐暴露、且与叶尖基体端面结合牢固的叶尖抗磨切削涂层。The invention discloses a blade tip wear-resistant cutting coating with a saturated mosaic structure, which is characterized in that it is composed of hard ceramic particles and a bonding alloy layer, and the hard ceramic particles are discretely distributed and bonded on the blade through the bonding alloy layer. On the end face of the tip base, the bonding alloy layer forms a firm metallurgical bond with the alloy of the blade tip base, and wraps 0.5-0.9 times the height of the hard ceramic particles itself, forming the sharp exposed edges and corners of the hard ceramic particles, which are closely connected with the blade tip. The end face of the base body is combined with a strong anti-wear cutting coating on the blade tip.
本发明进一步的改进在于,所述硬质陶瓷颗粒优选立方氮化硼颗粒。A further improvement of the present invention is that the hard ceramic particles are preferably cubic boron nitride particles.
本发明进一步的改进在于,所述硬质陶瓷颗粒优选金刚石颗粒。A further improvement of the present invention is that the hard ceramic particles are preferably diamond particles.
本发明进一步的改进在于,所述硬质陶瓷颗粒平均粒径优选50-120μm,满足切削性能需求。A further improvement of the present invention is that the average particle size of the hard ceramic particles is preferably 50-120 μm, which meets the requirements of cutting performance.
本发明进一步的改进在于,所述硬质陶瓷颗粒平均粒径优选121-350μm,满足散热性能需求。A further improvement of the present invention is that the average particle size of the hard ceramic particles is preferably 121-350 μm, which meets the requirements of heat dissipation performance.
本发明进一步的改进在于,所述尖角朝外的硬质陶瓷颗粒,指单个颗粒的最小方向尺寸超过颗粒平均粒径0.05倍的暴露面,与叶尖端面外法线的角度均介于0-60°之间。其中,最小方向尺寸是指颗粒在不同方向上的尺寸中最小的那个,例如:上下尺寸比左右尺寸大则最小方向尺寸指左右尺寸。A further improvement of the present invention is that the hard ceramic particles with sharp corners facing outwards refer to the exposed surfaces whose smallest directional dimension of a single particle exceeds 0.05 times the average particle size of the particles, and the angle with the outer normal of the blade tip surface is all 0 -60°. Wherein, the minimum directional size refers to the smallest size of the particles in different directions. For example, if the up-down size is larger than the left-right size, the minimum directional size refers to the left-right size.
本发明进一步的改进在于,所述尖角朝外的硬质陶瓷颗粒所占百分比大于50%。A further improvement of the present invention is that the percentage of the hard ceramic particles with sharp corners facing outward is greater than 50%.
本发明进一步的改进在于,所述硬质陶瓷颗粒朝向叶尖外表面外法线的一侧顶端高度差不高于颗粒自身平均粒径的0.2-0.5倍。A further improvement of the present invention is that the height difference between the tops of the hard ceramic particles facing the outer normal of the outer surface of the blade tip is not higher than 0.2-0.5 times the average particle size of the particles themselves.
本发明进一步的改进在于,所述相邻两个陶瓷颗粒的分布间距优选颗粒自身平均粒径的1-2.5倍,具有高的分布密度,可实现快速切削。A further improvement of the present invention is that the distribution spacing of the two adjacent ceramic particles is preferably 1-2.5 times the average particle size of the particles themselves, which has a high distribution density and can realize rapid cutting.
本发明进一步的改进在于,所述相邻两个陶瓷颗粒的分布间距优选颗粒自身平均粒径的3-10倍,具有充分散热的能力。A further improvement of the present invention lies in that the distribution spacing of the two adjacent ceramic particles is preferably 3-10 times the average particle size of the particles themselves, and has the ability to sufficiently dissipate heat.
本发明进一步的改进在于,所述粘结合金中Cr、Al和Si元素的总摩尔含量不低于13%且不高于48%。A further improvement of the present invention is that the total molar content of Cr, Al and Si elements in the bonding alloy is not lower than 13% and not higher than 48%.
本发明进一步的改进在于,所述粘结合金成分优选质量百分比为含镍大于53.0%,含铬6%-28%的镍基合金。A further improvement of the present invention lies in that the preferred mass percentage of the bonding alloy is a nickel-based alloy containing more than 53.0% of nickel and 6% to 28% of chromium.
本发明进一步的改进在于,所述粘结合金成分优选质量百分比为含钛大于40%,含锆18%-30%,含铜10%-25%,含镍5%-10%的钛基合金。A further improvement of the present invention is that the preferred mass percentage of the bonding alloy composition is a titanium-based alloy containing more than 40% titanium, 18%-30% zirconium, 10%-25% copper, and 5%-10% nickel. .
本发明进一步的改进在于,所述粘结合金熔点低于叶尖基体熔点按开尔文温度计算的0.9倍。A further improvement of the present invention is that the melting point of the bonding alloy is lower than 0.9 times the melting point of the blade tip base in Kelvin temperature.
一种具有饱和镶嵌结构的叶尖抗磨涂层及其制备方法,包括以下步骤:A blade tip anti-wear coating with a saturated mosaic structure and a preparation method thereof, comprising the following steps:
基体表面预处理:去油污和污染后,通过预处理去除基体表面氧化层,提高粘结合金层与基体间的结合力。Substrate surface pretreatment: After degreasing and pollution, the oxide layer on the surface of the substrate is removed by pretreatment to improve the bonding force between the bonding alloy layer and the substrate.
预涂覆粘结合金层:对预处理后的叶片尖端基体表面涂覆粘结合金层,粘结合金层厚度优选陶瓷颗粒平均粒径的0.4-0.8倍。Pre-coating the bonding alloy layer: The pre-treated blade tip base surface is coated with a bonding alloy layer, and the thickness of the bonding alloy layer is preferably 0.4-0.8 times the average particle size of the ceramic particles.
在粘结合金层表面撒布硬质陶瓷颗粒。Sprinkle hard ceramic particles on the surface of the bonding alloy layer.
加热重熔:对撒有硬质颗粒的粘结合金层加热使其重新熔化,使得粘结合金将硬质陶瓷颗粒紧紧包裹并与基体之间形成牢固的冶金结合,粘结合金层与基体结合强度超过60MPa。Heating and remelting: heating the bonding alloy layer sprinkled with hard particles to make it re-melted, so that the bonding alloy tightly wraps the hard ceramic particles and forms a firm metallurgical bond with the substrate, bonding the alloy layer and the substrate. The bonding strength exceeds 60MPa.
本发明进一步的改进在于,所述步骤中,涂覆方法优选真空等离子喷涂,喷涂功率优选25-55kW,喷涂距离优选100-400mm。A further improvement of the present invention is that, in the step, the coating method is preferably vacuum plasma spraying, the spraying power is preferably 25-55kW, and the spraying distance is preferably 100-400mm.
本发明进一步的改进在于,所述步骤中,涂覆方法优选激光熔覆,熔敷速度优选6-60mm/s,送粉方式优选同步同轴送粉,送粉率优选10-60g/min。A further improvement of the present invention is that, in the steps, the coating method is preferably laser cladding, the welding speed is preferably 6-60 mm/s, the powder feeding method is preferably synchronous coaxial powder feeding, and the powder feeding rate is preferably 10-60 g/min.
本发明进一步的改进在于,所述步骤中,加热温度优选粘结合金熔点的1.02-1.3倍,且保证低于叶尖基体熔点,低于的温度优选超过叶尖基体与粘结合金熔点之差的0.5倍。A further improvement of the present invention is that, in the step, the heating temperature is preferably 1.02-1.3 times the melting point of the bonding alloy, and is guaranteed to be lower than the melting point of the tip base, and the lower temperature preferably exceeds the difference between the melting point of the tip base and the bonding alloy 0.5 times.
本发明进一步的改进在于,所述步骤中,加热方式优选真空炉加热,炉内真空度优选低于5×10-2Pa,加热速率优选5-10℃/min,保温时间优选3-30min。A further improvement of the present invention is that, in the step, the heating method is preferably vacuum furnace heating, the vacuum degree in the furnace is preferably lower than 5×10 -2 Pa, the heating rate is preferably 5-10°C/min, and the holding time is preferably 3-30min.
本发明进一步的改进在于,所述步骤中,加热方式优选感应加热,感应电流优选20-65A,加热距离优选2.5-8mm,加热时间优选2-15s。A further improvement of the present invention is that in the step, the heating method is preferably induction heating, the induction current is preferably 20-65A, the heating distance is preferably 2.5-8mm, and the heating time is preferably 2-15s.
与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:
本发明公开的叶尖抗磨切削涂层,将硬质陶瓷颗粒离散分布并通过粘结合金结合在叶尖端面上,粘结合金层与叶尖合金形成牢固冶金结合,并将硬质陶瓷颗粒紧紧包裹住,涂层的硬质陶瓷颗粒棱角尖锐暴露且与叶尖端面结合牢固。饱和镶嵌结构使得涂层在具有超高硬度的前提下,又具有良好的结合强度。涂层外棱角尖锐,可以用来快速切削可磨耗封严涂层,防止叶尖剧烈升温。The blade tip wear-resistant cutting coating disclosed by the invention distributes the hard ceramic particles discretely and combines them on the blade tip surface through a bonding alloy, the bonding alloy layer and the blade tip alloy form a firm metallurgical bond, and the hard ceramic particles are Tightly wrapped, the hard ceramic particles of the coating have sharply exposed edges and corners and are firmly bonded to the blade tip surface. The saturated damascene structure enables the coating to have good bonding strength on the premise of ultra-high hardness. The outer edges and corners of the coating are sharp, which can be used to quickly cut the wearable sealing coating to prevent the blade tip from heating up violently.
附图说明Description of drawings
图1为本发明实施例提供的一种具有饱和镶嵌结构的叶尖抗磨涂层的结构图;1 is a structural diagram of a blade tip anti-wear coating with a saturated mosaic structure provided by an embodiment of the present invention;
其中:1为叶尖基体;2为粘结合金层;3为硬质陶瓷颗粒。Among them: 1 is the blade tip base; 2 is the bonding alloy layer; 3 is the hard ceramic particles.
具体实施方式Detailed ways
为了使本技术领域的人员更好地理解本发明方案,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分的实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。In order to make those skilled in the art better understand the solutions of the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only Embodiments are part of the present invention, but not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
需要说明的是,本发明的说明书和权利要求书及上述附图中的术语“第一”、“第二”等是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的本发明的实施例能够以除了在这里图示或描述的那些以外的顺序实施。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元的过程、方法、系统、产品或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。It should be noted that the terms "first", "second" and the like in the description and claims of the present invention and the above drawings are used to distinguish similar objects, and are not necessarily used to describe a specific sequence or sequence. It is to be understood that the data so used may be interchanged under appropriate circumstances such that the embodiments of the invention described herein can be practiced in sequences other than those illustrated or described herein. Furthermore, the terms "comprising" and "having", and any variations thereof, are intended to cover non-exclusive inclusion, for example, a process, method, system, product or device comprising a series of steps or units is not necessarily limited to those expressly listed Rather, those steps or units may include other steps or units not expressly listed or inherent to these processes, methods, products or devices.
下面结合附图对本发明做进一步详细描述:Below in conjunction with accompanying drawing, the present invention is described in further detail:
参见图1,本发明的、一种具有饱和镶嵌结构的叶尖抗磨切削涂层,由硬质陶瓷颗粒3与粘结合金层2构成,硬质陶瓷颗粒3离散分布并通过粘结合金层2结合在叶尖基体1的端面上,粘结合金层2与叶尖基体1的合金形成牢固冶金结合,并将硬质陶瓷颗粒3自身高度的0.5-0.9倍包裹住,形成硬质陶瓷颗粒棱角尖锐暴露、且与叶尖基体1端面结合牢固的叶尖抗磨切削涂层。Referring to FIG. 1, a blade tip wear-resistant cutting coating with a saturated mosaic structure of the present invention is composed of hard
实施例1Example 1
平均粒径为50μm的金刚石颗粒通过Ni71CrSi粘结合金结合在镍基高温合金GH4037叶尖基体的端面上,Ni71CrSi粘结合金层与GH4037叶尖形成牢固冶金结合并将金刚石颗粒高度的0.5倍包裹住,相邻两个陶瓷颗粒的平均分布间距约为500μm,形成金刚石颗粒棱角尖锐暴露、与GH4037叶尖端面结合牢固的切削涂层。该涂层具体制备方法,包括以下步骤:The diamond particles with an average particle size of 50μm are bonded to the end face of the nickel-based superalloy GH4037 blade tip through the Ni71CrSi bonding alloy. The Ni71CrSi bonding alloy layer forms a strong metallurgical bond with the GH4037 blade tip and wraps 0.5 times the height of the diamond particles. , the average distribution spacing of two adjacent ceramic particles is about 500 μm, forming a cutting coating with sharply exposed diamond particles and a firm combination with the tip surface of GH4037 blades. The specific preparation method of the coating comprises the following steps:
1)基体表面预处理:选用GH4037材质的合金叶片作为基体,先用水砂纸对基体进行打磨,去污染除油污,然后放入有机溶剂中进行超声波清洗,吹干放入干燥皿中。1) Pretreatment of the surface of the substrate: The alloy blade made of GH4037 is used as the substrate. First, the substrate is ground with water sandpaper to remove pollution and oil stains. Then, it is placed in an organic solvent for ultrasonic cleaning, dried and placed in a drying dish.
2)预涂覆粘结合金层:采用精度为0.1mg的精密电子天平称量粘结合金粉末,然后采用真空等离子喷涂的工艺在叶片基体的端面沉积100μm厚的Ni71CrSi层,喷涂工艺参数为电流500A,电压50V,送粉率15g/min,喷涂距离100mm。2) Pre-coating bonding alloy layer: The bonding alloy powder is weighed with a precision electronic balance with an accuracy of 0.1 mg, and then a 100 μm thick Ni71CrSi layer is deposited on the end face of the blade substrate by vacuum plasma spraying. The spraying process parameter is current 500A, voltage 50V, powder feeding rate 15g/min, spraying distance 100mm.
3)撒布硬质陶瓷颗粒:随后在粘结合金层上撒布单层金刚石颗粒。3) Sprinkling of hard ceramic particles: A single layer of diamond particles is then sprinkled on the bond alloy layer.
4)加热重熔:采用真空炉加热使得Ni71CrSi层重新熔化,与GH4037基体和金刚石颗粒之间形成冶金结合,真空炉加热工艺参数为炉内真空度4×10-2Pa,加热速率5℃/min,保温时间3min。4) Heating and remelting: The Ni71CrSi layer is remelted by heating in a vacuum furnace, forming a metallurgical bond with the GH4037 matrix and the diamond particles. The heating process parameters of the vacuum furnace are the vacuum degree in the furnace 4×10 -2 Pa, and the heating rate is 5℃/ min, holding time 3min.
本实施例制得的叶尖抗磨切削涂层的硬度为300-340HV0.2,涂层间结合强度在60-65MPa之间。The hardness of the blade tip anti-wear cutting coating prepared in this example is 300-340HV 0.2 , and the bonding strength between the coatings is between 60-65MPa.
实施例2Example 2
平均粒径为80μm的金刚石颗粒通过Ti20Zr25Cu10Ni粘结合金结合在TC4叶尖基体的端面上,Ti20Zr25Cu10Ni粘结合金层与TC4叶尖形成牢固冶金结合并将金刚石颗粒高度的0.5倍包裹住,相邻两个陶瓷颗粒的平均分布间距约为120μm,形成金刚石颗粒棱角尖锐暴露、与TC4叶尖端面结合牢固的切削涂层。该涂层具体制备方法,包括以下步骤:The diamond particles with an average particle size of 80μm are bonded to the end face of the TC4 tip base through the Ti20Zr25Cu10Ni bonding alloy. The Ti20Zr25Cu10Ni bonding alloy layer forms a firm metallurgical bond with the TC4 tip and wraps 0.5 times the height of the diamond particles. The average distribution spacing of each ceramic particle is about 120 μm, forming a cutting coating with sharply exposed diamond particle edges and corners, which is firmly bonded to the tip surface of the TC4 blade. The specific preparation method of the coating comprises the following steps:
1)基体表面预处理:选用TC4材质的合金叶片作为基体,先用水砂纸对基体进行打磨,去污染除油污,然后放入有机溶剂中进行超声波清洗,吹干放入干燥皿中。1) Pretreatment of the surface of the substrate: choose the alloy blade of TC4 material as the substrate, first grind the substrate with water sandpaper to remove pollution and oil, then put it in an organic solvent for ultrasonic cleaning, dry it and put it in a drying dish.
2)预涂覆粘结合金层:采用精度为0.1mg的精密电子天平称量粘结合金,然后采用激光熔覆的工艺在叶片基体的端面沉积100μm厚的Ti20Zr25Cu10Ni层,工艺参数为熔敷速度6mm/s,送粉方式为同步同轴送粉,送粉率10g/min。2) Pre-coating bonding alloy layer: The bonding alloy is weighed with a precision electronic balance with an accuracy of 0.1 mg, and then a 100 μm thick Ti20Zr25Cu10Ni layer is deposited on the end face of the blade base by a laser cladding process. The process parameter is the cladding speed. 6mm/s, the powder feeding method is synchronous coaxial powder feeding, and the powder feeding rate is 10g/min.
3)撒布硬质陶瓷颗粒:随后在粘结合金层上撒布单层金刚石颗粒。;3) Sprinkling of hard ceramic particles: A single layer of diamond particles is then sprinkled on the bond alloy layer. ;
4)加热重熔:采用真空炉加热使得Ti20Zr25Cu10Ni层重新熔化,与TC4基体和金刚石颗粒之间形成冶金结合,真空炉加热工艺参数为炉内真空度3×10-2Pa,加热速率8℃/min,保温时间15min。4) Heating and remelting: The Ti20Zr25Cu10Ni layer is remelted by heating in a vacuum furnace, forming a metallurgical bond with the TC4 matrix and the diamond particles. The heating process parameters of the vacuum furnace are the vacuum degree in the
本实施例制得的叶尖抗磨切削涂层的硬度为320-370HV0.2,涂层间结合强度在63-68MPa之间。The hardness of the blade tip anti-wear cutting coating prepared in this example is 320-370HV 0.2 , and the bonding strength between the coatings is between 63-68MPa.
实施例3Example 3
平均粒径为120μm的金刚石颗粒通过Ni71CrSi粘结合金结合在镍基高温合金GH4037叶尖基体的端面上,Ni71CrSi粘结合金层与GH4037叶尖形成牢固冶金结合并将金刚石颗粒高度的0.7倍包裹住,相邻两个陶瓷颗粒的平均分布间距约为360μm,形成金刚石颗粒棱角尖锐暴露、与GH4037叶尖端面结合牢固的切削涂层。该涂层具体制备方法,包括以下步骤:The diamond particles with an average particle size of 120μm are bonded to the end face of the nickel-based superalloy GH4037 tip body through the Ni71CrSi bonding alloy. The Ni71CrSi bonding alloy layer forms a strong metallurgical bond with the GH4037 blade tip and wraps 0.7 times the height of the diamond particles. , the average distribution distance of two adjacent ceramic particles is about 360 μm, forming a cutting coating with sharply exposed diamond particles and a firm bond with the tip surface of the GH4037 blade. The specific preparation method of the coating comprises the following steps:
1)基体表面预处理:选用GH4037材质的合金叶片作为基体,先用水砂纸对基体进行打磨,去污染除油污,然后放入有机溶剂中进行超声波清洗,吹干放入干燥皿中。1) Pretreatment of the surface of the substrate: The alloy blade made of GH4037 is used as the substrate. First, the substrate is ground with water sandpaper to remove pollution and oil stains. Then, it is placed in an organic solvent for ultrasonic cleaning, dried and placed in a drying dish.
2)预涂覆粘结合金层:采用精度为0.1mg的精密电子天平称量粘结合金,然后采用真空等离子喷涂的工艺在叶片基体的端面沉积200μm厚的Ni71CrSi层,喷涂工艺参数为电流600A,电压60V,送粉率15g/min,喷涂距离200mm。2) Pre-coating bonding alloy layer: The bonding alloy is weighed with a precision electronic balance with an accuracy of 0.1 mg, and then a 200 μm thick Ni71CrSi layer is deposited on the end face of the blade substrate by vacuum plasma spraying, and the spraying process parameter is a current of 600A , Voltage 60V, powder feeding rate 15g/min, spraying distance 200mm.
3)撒布硬质陶瓷颗粒:随后在粘结合金层上撒布单层金刚石颗粒。3) Sprinkling of hard ceramic particles: A single layer of diamond particles is then sprinkled on the bond alloy layer.
4)加热重熔:采用真空炉加热使得Ni71CrSi层重新熔化,与GH4037基体和金刚石颗粒之间形成冶金结合,真空炉加热工艺参数为炉内真空度1×10-2Pa,加热速率10℃/min,保温时间30min。4) Heating and remelting: The Ni71CrSi layer is remelted by heating in a vacuum furnace, forming a metallurgical bond with the GH4037 matrix and the diamond particles. The heating process parameters of the vacuum furnace are the vacuum degree in the furnace 1×10 -2 Pa, and the heating rate is 10℃/ min, holding time 30min.
本实施例制得的叶尖抗磨切削涂层的硬度为360-410HV0.2,涂层间结合强度在61-66MPa之间。The hardness of the blade tip anti-wear cutting coating prepared in this example is 360-410HV 0.2 , and the bonding strength between the coatings is between 61-66MPa.
实施例4Example 4
平均粒径为150μm的金刚石颗粒通过Ti20Zr25Cu10Ni粘结合金结合在TC4叶尖端面上,Ti20Zr25Cu10Ni粘结合金层与TC4叶尖形成牢固冶金结合并将金刚石颗粒高度的0.7倍包裹住,相邻两个陶瓷颗粒的平均分布间距约为450μm,形成金刚石颗粒棱角尖锐暴露、与TC4叶尖端面结合牢固的切削涂层。该涂层具体制备方法,包括以下步骤:The diamond particles with an average particle size of 150μm are bonded to the tip surface of the TC4 blade through the Ti20Zr25Cu10Ni bonding alloy. The Ti20Zr25Cu10Ni bonding alloy layer forms a firm metallurgical bond with the TC4 blade tip and wraps the diamond particles 0.7 times the height of the two adjacent ceramics. The average distribution spacing of the particles is about 450 μm, forming a cutting coating with sharply exposed diamond particle edges and corners, which is firmly bonded to the tip surface of the TC4 blade. The specific preparation method of the coating comprises the following steps:
1)基体表面预处理:选用TC4材质的合金叶片作为基体,先用水砂纸对基体进行打磨,去污染除油污,然后放入有机溶剂中进行超声波清洗,吹干放入干燥皿中。1) Pretreatment of the surface of the substrate: choose the alloy blade of TC4 material as the substrate, first grind the substrate with water sandpaper to remove pollution and oil, then put it in an organic solvent for ultrasonic cleaning, dry it and put it in a drying dish.
2)预涂覆粘结合金层:采用精度为0.1mg的精密电子天平称量粘结合金,然后采用激光熔覆的工艺在叶片基体的端面沉积200μm厚的Ti20Zr25Cu10Ni层,工艺参数为熔敷速度30mm/s,送粉方式为同步同轴送粉,送粉率30g/min。2) Pre-coating bonding alloy layer: The bonding alloy is weighed with a precision electronic balance with an accuracy of 0.1 mg, and then a 200 μm thick Ti20Zr25Cu10Ni layer is deposited on the end face of the blade base by the laser cladding process. The process parameter is the cladding speed. 30mm/s, the powder feeding method is synchronous coaxial powder feeding, and the powder feeding rate is 30g/min.
3)撒布硬质陶瓷颗粒:随后在粘结合金层上撒布单层金刚石颗粒。;3) Sprinkling of hard ceramic particles: A single layer of diamond particles is then sprinkled on the bond alloy layer. ;
4)加热重熔:采用感应加热技术使得Ti20Zr25Cu10Ni层重新熔化,与TC4基体和金刚石颗粒之间形成冶金结合,感应加热工艺参数为:感应电流20A,加热距离2.5mm,加热时间15s。4) Heating and remelting: The Ti20Zr25Cu10Ni layer is remelted by induction heating technology to form a metallurgical bond between the TC4 matrix and the diamond particles. The induction heating process parameters are: induction current 20A, heating distance 2.5mm, heating time 15s.
本实施例制得的叶尖抗磨切削涂层的硬度为350-400HV0.2,涂层间结合强度在65-70MPa之间。The hardness of the blade tip anti-wear cutting coating prepared in this example is 350-400HV 0.2 , and the bonding strength between the coatings is between 65-70MPa.
实施例5Example 5
平均粒径为200μm的立方氮化硼颗粒通过Ni71CrSi粘结合金结合在镍基高温合金IN738叶尖端面上,Ni71CrSi粘结合金层与IN738叶尖形成牢固冶金结合并将立方氮化硼颗粒高度的0.9倍包裹住,相邻两个陶瓷颗粒的平均分布间距约为1000μm,形成立方氮化硼颗粒棱角尖锐暴露、与IN738叶尖端面结合牢固的切削涂层。该涂层具体方法,包括以下步骤如下:The cubic boron nitride particles with an average particle size of 200 μm are bonded to the tip surface of the nickel-based superalloy IN738 through the Ni71CrSi bonding alloy. 0.9 times wrapping, the average distribution distance of two adjacent ceramic particles is about 1000μm, forming a cutting coating with sharply exposed cubic boron nitride particles and strong bonding with the IN738 blade tip surface. The specific method of the coating includes the following steps:
1)基体表面预处理:选用IN738材质的合金叶片作为基体,先用水砂纸对基体进行打磨,去污染除油污,然后放入有机溶剂中进行超声波清洗,吹干放入干燥皿中。1) Pretreatment of the surface of the substrate: choose the alloy blade of IN738 material as the substrate, first grind the substrate with water sandpaper to remove pollution and oil, then put it into an organic solvent for ultrasonic cleaning, dry it and put it in a drying dish.
2)预涂覆粘结合金层:采用精度为0.1mg的精密电子天平称量粘结合金,然后采用真空等离子喷涂的工艺在叶片基体的端面沉积300μm厚的Ni71CrSi层,,喷涂工艺参数为电流750A,电压70V,送粉率40g/min,喷涂距离400mm。2) Pre-coating bonding alloy layer: The bonding alloy is weighed with a precision electronic balance with an accuracy of 0.1 mg, and then a 300 μm thick Ni71CrSi layer is deposited on the end face of the blade base by a vacuum plasma spraying process. The spraying process parameter is current 750A, voltage 70V, powder feeding rate 40g/min, spraying distance 400mm.
3)撒布硬质陶瓷颗粒:随后在粘结合金层上撒布单层立方氮化硼颗粒。;3) Sprinkling of hard ceramic particles: A single layer of cubic boron nitride particles is then sprinkled on the bonding alloy layer. ;
4)加热重熔:采用感应加热技术使得Ni71CrSi层重新熔化,与IN738基体和立方氮化硼颗粒之间形成冶金结合,感应电流45A,加热距离5mm,加热时间8s。4) Heating and remelting: The Ni71CrSi layer is remelted by induction heating technology, forming a metallurgical bond between the IN738 matrix and the cubic boron nitride particles. The induction current is 45A, the heating distance is 5mm, and the heating time is 8s.
本实施例制得的叶尖抗磨切削涂层的硬度为330-360HV0.2,涂层间结合强度在66-71MPa之间。The hardness of the blade tip anti-wear cutting coating prepared in this example is 330-360HV 0.2 , and the bonding strength between the coatings is between 66-71MPa.
实施例6Example 6
平均粒径为350μm的立方氮化硼颗粒通过Ti20Zr25Cu10Ni粘结合金结合在TC11叶尖端面上,Ti20Zr25Cu10Ni粘结合金层与TC11叶尖形成牢固冶金结合并将立方氮化硼颗粒高度的0.9倍包裹住,相邻两个陶瓷颗粒的平均分布间距约为350μm,形成立方氮化硼颗粒棱角尖锐暴露、与TC11叶尖端面结合牢固的切削涂层。该涂层具体制备方法,包括以下步骤:The cubic boron nitride particles with an average particle size of 350μm are bonded to the tip surface of the TC11 blade through the Ti20Zr25Cu10Ni bonding alloy. The Ti20Zr25Cu10Ni bonding alloy layer forms a strong metallurgical bond with the TC11 blade tip and wraps the cubic boron nitride particles 0.9 times the height of the blade. , and the average distribution distance of two adjacent ceramic particles is about 350 μm, forming a cutting coating with sharply exposed cubic boron nitride particles and sharply exposed edges and corners of the TC11 blade tip surface. The specific preparation method of the coating comprises the following steps:
1)基体表面预处理:选用TC11材质的合金叶片作为基体,先用水砂纸对基体进行打磨,去污染除油污,然后放入有机溶剂中进行超声波清洗,吹干放入干燥皿中。1) Substrate surface pretreatment: choose TC11 alloy blade as the substrate, first grind the substrate with water sandpaper to remove pollution and oil, then put it in an organic solvent for ultrasonic cleaning, dry it and put it in a drying dish.
2)预涂覆粘结合金层:采用精度为0.1mg的精密电子天平称量粘结合金,然后采用激光熔覆的工艺在叶片基体的端面沉积300μm厚的Ti20Zr25Cu10Ni层,工艺参数为熔敷速度60mm/s,送粉方式为同步同轴送粉,送粉率60g/min。2) Pre-coating bonding alloy layer: The bonding alloy is weighed with a precision electronic balance with an accuracy of 0.1 mg, and then a 300 μm thick Ti20Zr25Cu10Ni layer is deposited on the end face of the blade base by the laser cladding process. The process parameter is the cladding speed. 60mm/s, the powder feeding method is synchronous coaxial powder feeding, and the powder feeding rate is 60g/min.
3)撒布硬质陶瓷颗粒:随后在粘结合金层上撒布单层立方氮化硼颗粒。;3) Sprinkling of hard ceramic particles: A single layer of cubic boron nitride particles is then sprinkled on the bonding alloy layer. ;
4)加热重熔:采用感应加热技术使得Ti20Zr25Cu10Ni层重新熔化,与TC11基体和立方氮化硼颗粒之间形成冶金结合,感应电流65A,加热距离8mm,加热时间2s。4) Heating and remelting: The Ti20Zr25Cu10Ni layer is remelted by induction heating technology, forming a metallurgical bond between the TC11 matrix and the cubic boron nitride particles. The induced current is 65A, the heating distance is 8mm, and the heating time is 2s.
本实施例制得的叶尖抗磨切削涂层的硬度为350-390HV0.2,涂层间结合强度在64-70MPa之间。The hardness of the blade tip anti-wear cutting coating prepared in this example is 350-390HV 0.2 , and the bonding strength between the coatings is between 64-70MPa.
以上内容仅为说明本发明的技术思想,不能以此限定本发明的保护范围,凡是按照本发明提出的技术思想,在技术方案基础上所做的任何改动,均落入本发明权利要求书的保护范围之内。The above content is only to illustrate the technical idea of the present invention, and cannot limit the protection scope of the present invention. Any changes made on the basis of the technical solution according to the technical idea proposed by the present invention all fall within the scope of the claims of the present invention. within the scope of protection.
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CN107138878A (en) * | 2017-04-19 | 2017-09-08 | 天津职业技术师范大学 | A kind of preparation method of titanium-fire-preventing coating |
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