[go: up one dir, main page]

CN112126299A - Optical coating for projection screen for laser TV and preparation method thereof - Google Patents

Optical coating for projection screen for laser TV and preparation method thereof Download PDF

Info

Publication number
CN112126299A
CN112126299A CN202011022713.XA CN202011022713A CN112126299A CN 112126299 A CN112126299 A CN 112126299A CN 202011022713 A CN202011022713 A CN 202011022713A CN 112126299 A CN112126299 A CN 112126299A
Authority
CN
China
Prior art keywords
projection screen
optical coating
powder
screen
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011022713.XA
Other languages
Chinese (zh)
Inventor
赵宁
刘乐华
张莹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Polytechnic
Original Assignee
Shenzhen Polytechnic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Polytechnic filed Critical Shenzhen Polytechnic
Priority to CN202011022713.XA priority Critical patent/CN112126299A/en
Publication of CN112126299A publication Critical patent/CN112126299A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03BAPPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
    • G03B21/00Projectors or projection-type viewers; Accessories therefor
    • G03B21/54Accessories
    • G03B21/56Projection screens
    • G03B21/60Projection screens characterised by the nature of the surface
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Overhead Projectors And Projection Screens (AREA)

Abstract

The invention belongs to the technical field of projection screen manufacturing, and particularly relates to a projection screen optical coating for a laser television and a preparation method thereof. The optical coating for the projection screen of the laser television comprises the following components in percentage by mass: 10-15% of reflective powder; 18-21% of barium sulfate; 15-20% of titanium dioxide; 1-5% of polymethyl methacrylate micro powder; 3-8% of spherical organic silicon powder; 3-8% of electroplated aluminum glass microspheres; 0.5-3% of sodium carboxymethylcellulose; 20-30% of water-based acrylic resin; 12-18% of water. The optical coating prepared by the invention is applied to the white screen, so that the brightness, the definition, the gain and the contrast of the white screen are close to those of a special laser composite screen, the light visible angle is large, and the application range of the white screen is greatly expanded.

Description

一种激光电视用投影屏幕光学涂料及其制备方法Optical coating for projection screen for laser TV and preparation method thereof

技术领域technical field

本发明属于投影屏幕制造技术领域,具体涉及一种激光电视用投影屏幕光学涂料及其制备方法。The invention belongs to the technical field of projection screen manufacturing, and in particular relates to an optical coating for a laser TV projection screen and a preparation method thereof.

背景技术Background technique

电视技术经历了黑白电视,彩色电视和以液晶电视、PDP、OLED等为代表的数字电视三次技术迭代,而激光电视为第四代。激光电视具有大幅面、高亮度、高分辨率和高解析度的优势,采用激光光源,当然地,与之配套则需求一种抗光增益屏。TV technology has experienced three technical iterations of black and white TV, color TV and digital TV represented by LCD TV, PDP, OLED, etc., while laser TV is the fourth generation. Laser TV has the advantages of large format, high brightness, high resolution and high resolution. It uses a laser light source. Of course, it needs an anti-light gain screen to match it.

激光电视常搭配的是菲涅尔或黑柵两种类型抗光增益屏,而从画面光反射的效能来看,菲涅尔抗光增益屏通过利用类似同心圆的光学滤镜结构聚集投影光线,具有视觉增加和提高效益的功能,但是菲涅尔抗光增益屏在安装过程中是有方向性的要求,菲涅尔光学结构的同心圆心要朝向激光电视的镜头,因而当我们仔细观察实际的画面效果时,不难发现并不是所有的菲涅尔幕都能有出色的画面还原能力。传统白幕具有安装方便的特性,但是传统的白幕亮度增益较低,一般来说常规的采用漫反射结构的标准白幕增益为1.0,菲涅尔抗光增益屏的增益比1.0要大,表示它相比标准白幕能够保留更多投影机的亮度维持在屏幕上,因而如果能够增大传统白幕的增益,使得其能够与菲涅尔抗光增益屏的增益相接近,甚至大于菲涅尔抗光增益屏的增益,就能替换菲涅尔抗光增益屏。Laser TVs are often equipped with two types of anti-light gain screens, Fresnel or black grid. From the perspective of the efficiency of light reflection on the screen, the Fresnel anti-light gain screen gathers projection light by using an optical filter structure similar to concentric circles. , has the function of increasing vision and improving efficiency, but the Fresnel anti-light gain screen has directional requirements during the installation process. The concentric circle of the Fresnel optical structure should be facing the lens of the laser TV, so when we carefully observe the actual It is not difficult to find that not all Fresnel screens can have excellent picture restoration ability. The traditional white screen has the characteristics of easy installation, but the brightness gain of the traditional white screen is low. Generally speaking, the standard white screen with diffuse reflection structure has a gain of 1.0, and the gain of the Fresnel anti-light gain screen is larger than 1.0. It means that it can retain more projector brightness on the screen than the standard white screen, so if the gain of the traditional white screen can be increased, it can be close to the gain of the Fresnel anti-light gain screen, or even greater than that of the Fresnel anti-light gain screen. The gain of the Nell anti-light gain screen can replace the Fresnel anti-light gain screen.

目前,现有技术出现了一种光学涂料技术,通过在传统白幕进行涂覆得到光学涂层,具有高增益的效果。如中国专利CN107144901A公开了一种光学浆料薄膜制备方法及光学膜,方法包括:步骤1、提供一基板,在基板的其中一面涂布一层制备的第一浆料;步骤2、在第一浆料上涂刷制备的第二浆料;其中,所述第一浆料包括浆料主体和第一溶剂混合;所述第二浆料主要由成膜剂,消泡剂,表面活性剂及第二溶剂、偶联剂以及分散剂所混合搅拌制备合成。但是该复合涂层为2层,工艺较为复杂,同时有些现有技术需要4~5层才能达到理想效果,十分局限光学涂料的发展。At present, an optical coating technology has appeared in the prior art, and an optical coating is obtained by coating on a traditional white screen, which has the effect of high gain. For example, Chinese patent CN107144901A discloses a method for preparing an optical paste film and an optical film. The method includes: step 1, providing a substrate, and coating one side of the substrate with a layer of the prepared first paste; step 2, in the first The second slurry prepared by brushing on the slurry; wherein, the first slurry comprises a slurry main body mixed with a first solvent; the second slurry is mainly composed of a film-forming agent, a defoamer, a surfactant and The second solvent, the coupling agent and the dispersing agent are mixed and stirred to prepare and synthesize. However, the composite coating consists of two layers, and the process is relatively complicated. At the same time, some existing technologies require 4 to 5 layers to achieve the desired effect, which greatly limits the development of optical coatings.

发明内容SUMMARY OF THE INVENTION

本发明旨在提供一种激光电视用投影屏幕光学涂料及其制备方法,本发明制得了一种光学涂料,当其应用于白幕后,使白幕的亮度、清晰度、增益和对比度都接近于专门激光复合屏幕布,可视角度达到140°以上,大大扩大了白幕的使用范围。The present invention aims to provide an optical coating for a projection screen of a laser TV and a preparation method thereof. The present invention prepares an optical coating which, when applied behind a white screen, makes the brightness, clarity, gain and contrast of the white screen close to The special laser composite screen cloth has a viewing angle of more than 140°, which greatly expands the scope of use of the white screen.

为了达到上述目的,本发明采用以下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:

一种激光电视用投影屏幕光学涂料,包括以下质量分数的组分:An optical coating for a projection screen for a laser TV, comprising the components in the following mass fractions:

反光粉10~15%;Reflective powder 10-15%;

硫酸钡18~21%;Barium sulfate 18~21%;

钛白粉15~20%;Titanium dioxide 15~20%;

聚甲基丙烯酸甲酯微粉1~5%;Polymethyl methacrylate micropowder 1~5%;

球型有机硅粉3~8%;Spherical silicone powder 3~8%;

电镀铝玻璃微球3~8%;Electroplated aluminum glass microspheres 3~8%;

羧甲基纤维素钠0.5~3%;Sodium carboxymethyl cellulose 0.5-3%;

水性丙稀酸树脂20~30%;Water-based acrylic resin 20-30%;

水10~18%。Water 10 to 18%.

在本发明中,钛白粉、硫酸钡起到反光作用,反光粉、电镀铝玻璃微球起到增益作用,聚甲基丙烯酸甲酯微粉、球型有机硅粉起到散射作用。In the present invention, titanium dioxide and barium sulfate play a reflective role, reflective powder and electroplated aluminum glass microspheres play a gain role, and polymethyl methacrylate micropowder and spherical organic silicon powder play a scattering role.

进一步地,包括以下质量分数的组分:Further, the following mass fractions of components are included:

反光粉12%;Reflective powder 12%;

硫酸钡20%;Barium sulfate 20%;

钛白粉17%;Titanium dioxide 17%;

聚甲基丙烯酸甲酯微粉2%;Polymethyl methacrylate micropowder 2%;

球型有机硅粉5%;Spherical silicone powder 5%;

电镀铝玻璃微球6%;Electroplated aluminum glass microspheres 6%;

羧甲基纤维素钠1%;Sodium carboxymethyl cellulose 1%;

水性丙稀酸树脂25%;Water-based acrylic resin 25%;

水12%。Water 12%.

进一步地,所述反光粉的粒径为5~15μm。Further, the particle size of the reflective powder is 5-15 μm.

进一步地,所述硫酸钡的粒径为15~200μm。Further, the particle size of the barium sulfate is 15-200 μm.

进一步地,所述钛白粉的粒径为20~80μm。Further, the particle size of the titanium dioxide is 20-80 μm.

进一步地,所述聚甲基丙烯酸甲酯微粉的粒径为1.5~3μm。Further, the particle size of the polymethyl methacrylate micropowder is 1.5-3 μm.

进一步地,所述球型有机硅粉的粒径为1~3μm。Further, the particle size of the spherical organosilicon powder is 1-3 μm.

进一步地,所述球型有机硅粉为球形聚甲基硅倍半氧烷。Further, the spherical organosilicon powder is spherical polymethylsilsesquioxane.

进一步地,所述电镀铝玻璃微球的粒径为5~15μm。Further, the particle size of the electroplated aluminum glass microspheres is 5-15 μm.

进一步地,所述电镀铝玻璃微球是玻璃微球外表面镀一层金属铝,金属铝厚度为0.5~1μm。Further, the electroplated aluminized glass microspheres are coated with a layer of metal aluminum on the outer surface of the glass microspheres, and the thickness of the metal aluminum is 0.5-1 μm.

本发明的另一目的是提供所述激光电视用投影屏幕光学涂料的制备方法,包括以下步骤:Another object of the present invention is to provide the preparation method of the optical coating for the projection screen for the laser TV, comprising the following steps:

S1)将聚甲基丙烯酸甲酯微粉和球型有机硅粉混合后加入到水性丙稀酸树脂中,然后再加入水,超声分散10~15min,得到混合液;S1) after mixing the polymethyl methacrylate micropowder and spherical silicone powder, add it to the water-based acrylic resin, then add water, and ultrasonically disperse for 10 to 15 minutes to obtain a mixed solution;

S2)将反光粉、硫酸钡、钛白粉、电镀铝玻璃微球和羧甲基纤维素钠混合搅拌,并加入到步骤S1的混合液中,机械搅拌5~10min,即得。S2) Mix and stir the reflective powder, barium sulfate, titanium dioxide, electroplated aluminum glass microspheres and sodium carboxymethyl cellulose, add to the mixed solution in step S1, and mechanically stir for 5 to 10 minutes to obtain the result.

与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

(1)本发明制得了一种光学涂料,经实验一表明,光学涂料涂刷于白幕后,使白幕的亮度、清晰度、增益和对比度都接近于专门激光复合屏幕布。(1) The present invention has prepared an optical paint. Experiment 1 shows that the optical paint is painted behind a white screen, so that the brightness, clarity, gain and contrast of the white screen are close to the special laser composite screen cloth.

(2)本发明光学涂料能够进行单层涂刷,经实验二表明,光学涂料涂刷于白幕后的可视角度大,达到140°以上。(2) The optical paint of the present invention can be brushed in a single layer. Experiment 2 shows that the visual angle of the optical paint applied behind the white screen is large, reaching more than 140°.

具体实施方式Detailed ways

以下通过实施例形式的具体实施方式,对本发明的上述内容作进一步的详细说明。但不应将此理解为本发明上述主题的范围仅限于以下实施例。The above-mentioned content of the present invention will be further described in detail below through the specific implementation in the form of examples. However, it should not be understood that the scope of the above-mentioned subject matter of the present invention is limited to the following examples.

在本发明中,反光粉购自3M公司,钛白粉购自杜邦公司,电镀铝玻璃微球购自动盈DY-3869,水性丙稀酸树脂购自佛山市南海双维水性材料有限公司,其他组分可从常规厂家购得。In the present invention, reflective powder was purchased from 3M Company, titanium dioxide was purchased from DuPont Company, electroplated aluminum glass microspheres were purchased from Autowin DY-3869, water-based acrylic resin was purchased from Foshan Nanhai Shuangwei Water-Based Materials Co., Ltd., other groups Fractions can be purchased from conventional manufacturers.

实施例1~5、一种激光电视用投影屏幕光学涂料Embodiments 1-5, a kind of optical coating for laser TV projection screen

包括以下质量分数的组分:Include components in the following mass fractions:

表1Table 1

Figure BDA0002701173750000041
Figure BDA0002701173750000041

激光电视用投影屏幕光学涂料的制备方法,包括以下步骤:A preparation method of an optical coating for a projection screen for a laser TV, comprising the following steps:

S1)将聚甲基丙烯酸甲酯微粉和球型有机硅粉混合后加入到水性丙稀酸树脂中,然后再加入水,超声分散12min,得到混合液;S1) after mixing polymethyl methacrylate micropowder and spherical silicone powder, add it to the water-based acrylic resin, then add water, and ultrasonically disperse for 12 min to obtain a mixed solution;

S2)将反光粉、硫酸钡、钛白粉、电镀铝玻璃微球和羧甲基纤维素钠混合搅拌,并加入到步骤S1的混合液中,机械搅拌6min,即得。S2) Mix and stir the reflective powder, barium sulfate, titanium dioxide, electroplated aluminum glass microspheres and sodium carboxymethyl cellulose, add it to the mixed solution in step S1, and mechanically stir for 6 minutes, to obtain the final product.

对比例1、一种激光电视用投影屏幕光学涂料Comparative Example 1. Optical coating for projection screen for laser TV

与实施例2类似,区别在于,未添加球型有机硅粉。Similar to Example 2, the difference is that no spherical silicone powder is added.

对比例2、一种激光电视用投影屏幕光学涂料Comparative example 2, an optical coating for projection screen for laser TV

与实施例2类似,区别在于,将球型有机硅粉替换成二氧化硅粉。Similar to Example 2, the difference is that the spherical silicone powder is replaced with silica powder.

对比例3、一种激光电视用投影屏幕光学涂料Comparative example 3, an optical coating for projection screen for laser TV

本对比例的组分和实施例2相同。The components of this comparative example are the same as those of Example 2.

激光电视用投影屏幕光学涂料的制备方法,包括以下步骤:A preparation method of an optical coating for a projection screen for a laser TV, comprising the following steps:

S1)将聚甲基丙烯酸甲酯微粉和球型有机硅粉混合后加入到水性丙稀酸树脂中,然后再加入水,机械搅拌12min,得到混合液;S1) after mixing polymethyl methacrylate micropowder and spherical silicone powder, add it to the water-based acrylic resin, then add water, and mechanically stir for 12 min to obtain a mixed solution;

S2)将反光粉、硫酸钡、钛白粉、电镀铝玻璃微球和羧甲基纤维素钠混合搅拌,并加入到步骤S1的混合液中,机械搅拌6min,即得。S2) Mix and stir the reflective powder, barium sulfate, titanium dioxide, electroplated aluminum glass microspheres and sodium carboxymethyl cellulose, add it to the mixed solution in step S1, and mechanically stir for 6 minutes, to obtain the final product.

对比例4、一种激光电视用投影屏幕光学涂料Comparative example 4, an optical coating for projection screen for laser TV

本对比例的组分和实施例4相同。The components of this comparative example are the same as those of Example 4.

激光电视用投影屏幕光学涂料的制备方法,包括以下步骤:A preparation method of an optical coating for a projection screen for a laser TV, comprising the following steps:

S1)将聚甲基丙烯酸甲酯微粉和球型有机硅粉混合后加入到水性丙稀酸树脂中,然后再加入水,机械搅拌12min,得到混合液;S1) after mixing polymethyl methacrylate micropowder and spherical silicone powder, add it to the water-based acrylic resin, then add water, and mechanically stir for 12 min to obtain a mixed solution;

S2将反光粉、硫酸钡、钛白粉、电镀铝玻璃微球和羧甲基纤维素钠混合搅拌,并加入到步骤S1的混合液中,机械搅拌6min,即得。S2 Mix and stir the reflective powder, barium sulfate, titanium dioxide, electroplated aluminum glass microspheres and sodium carboxymethyl cellulose, add it to the mixed solution in step S1, and mechanically stir for 6 minutes to obtain.

对比例5、一种激光电视用投影屏幕光学涂料Comparative example 5, an optical coating for projection screen for laser TV

与实施例2类似,区别在于,未加入羧甲基纤维素钠。Similar to Example 2, except that no sodium carboxymethyl cellulose was added.

实验一、性能测试Experiment 1. Performance test

实验方法:将实施例/对比例涂刷于白幕(东莞市创腾纺织品有限公司软布)一次后,对比以专门激光复合屏幕布数据(深圳市龙岗区坂田特丽银幕厂TD-102)为5.0分为参考依据。Experimental method: After the example/comparative example was painted on a white screen (soft cloth of Dongguan Chuangteng Textile Co., Ltd.), it was compared with the data of a special laser composite screen cloth (TD-102, Bantian Teli Screen Factory, Longgang District, Shenzhen) 5.0 is divided into reference basis.

表2Table 2

组别group 亮度brightness 清晰度clarity 增益gain 对比度Contrast 实施例1Example 1 4.954.95 5.05.0 4.94.9 4.74.7 实施例2Example 2 5.05.0 4.94.9 4.954.95 4.954.95 实施例3Example 3 4.954.95 4.94.9 4.94.9 4.84.8 实施例4Example 4 4.94.9 4.954.95 4.854.85 4.84.8 实施例5Example 5 4.94.9 4.94.9 4.94.9 4.94.9 对比例1Comparative Example 1 3.53.5 3.73.7 3.453.45 3.33.3 对比例2Comparative Example 2 3.653.65 3.53.5 3.63.6 3.33.3 对比例3Comparative Example 3 4.14.1 4.054.05 4.14.1 4.14.1 对比例4Comparative Example 4 4.054.05 4.14.1 3.93.9 3.953.95 对比例5Comparative Example 5 4.94.9 4.854.85 4.94.9 4.954.95 空白例Blank example 3.03.0 3.23.2 2.62.6 2.12.1

注:空白例为只在白幕上喷涂水性丙稀酸树脂和水的混合物。Note: The blank example is to spray the mixture of water-based acrylic resin and water only on the white screen.

从表2可以看出,实施例1~5的光学涂料涂刷于白幕后,使白幕的亮度、清晰度、增益和对比度都接近于专门激光复合屏幕布。As can be seen from Table 2, the optical coatings of Examples 1 to 5 are painted behind the white screen, so that the brightness, clarity, gain and contrast of the white screen are all close to the special laser composite screen cloth.

实验二、水平可视角测试Experiment 2, horizontal viewing angle test

实验方法:将实施例/对比例涂刷于白幕一次后,用投影仪将画面投影到白幕上,投影仪到白幕的距离为2米,用辉度仪测量其水平可视角。Experimental method: After the example/comparative example was painted on the white screen once, the screen was projected onto the white screen with a projector, the distance from the projector to the white screen was 2 meters, and the horizontal viewing angle was measured with a luminance meter.

表3table 3

Figure BDA0002701173750000061
Figure BDA0002701173750000061

Figure BDA0002701173750000071
Figure BDA0002701173750000071

注:空白例为只在白幕上喷涂水性丙稀酸树脂和水的混合物。Note: The blank example is to spray the mixture of water-based acrylic resin and water only on the white screen.

亮度随着屏幕中心的偏离而下降,当亮度下降为1/3时,此时的位置与屏幕中心的角度为可视角,左右可视角的和即为水平可视角。从表3可以看出,实施例1~5的水平可视角大,达到140°以上,其中实施例2为本发明的最佳实施例。The brightness decreases with the deviation from the center of the screen. When the brightness decreases to 1/3, the angle between the position at this time and the center of the screen is the viewing angle, and the sum of the left and right viewing angles is the horizontal viewing angle. It can be seen from Table 3 that the horizontal viewing angles of Examples 1 to 5 are large, reaching more than 140°, and Example 2 is the best embodiment of the present invention.

与实施例2相比,对比例1未添加球型有机硅粉导致水平可视角大大降低,对比例2将球形有机硅粉替换为二氧化硅粉后,光学涂料涂刷于白幕的水平可视角也降低。Compared with Example 2, in Comparative Example 1, no spherical silicone powder was added, which greatly reduced the horizontal viewing angle. In Comparative Example 2, after the spherical silicone powder was replaced with silica powder, the optical coating was painted on a white screen. The viewing angle is also reduced.

对比例3、对比例4调整了光学涂料的制备方法后,导致其涂刷于白幕的水平可视角降低,对比例5未添加羧甲基纤维素钠也使光学涂料涂刷于白幕的水平可视角降低,推测是由于光学涂料中所添加的各种原料粒径大小不均,导致发挥散射作用的聚甲基丙烯酸甲酯微粉和球型有机硅粉没有很好的在白幕上分布而导致的。Comparative Example 3, Comparative Example 4 After adjusting the preparation method of the optical coating, the horizontal viewing angle of the coating on the white screen is reduced. In Comparative Example 5, no sodium carboxymethyl cellulose is added, and the optical coating is painted on the white curtain. The horizontal viewing angle decreases, presumably due to the uneven particle size of the various raw materials added in the optical coating, resulting in the scattering of polymethyl methacrylate micropowder and spherical silicone powder not well distributed on the white screen caused by.

上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。The above-mentioned embodiments merely illustrate the principles and effects of the present invention, but are not intended to limit the present invention. Anyone skilled in the art can modify or change the above embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or changes made by those with ordinary knowledge in the technical field without departing from the spirit and technical idea disclosed in the present invention should still be covered by the claims of the present invention.

Claims (9)

1. The optical coating for the projection screen of the laser television is characterized by comprising the following components in percentage by mass:
10-15% of reflective powder;
18-21% of barium sulfate;
15-20% of titanium dioxide;
1-5% of polymethyl methacrylate micro powder;
3-8% of spherical organic silicon powder;
3-8% of electroplated aluminum glass microspheres;
0.5-3% of sodium carboxymethylcellulose;
20-30% of water-based acrylic resin;
10-18% of water.
2. The optical coating for a projection screen of a laser television according to claim 1, comprising the following components in parts by mass:
12% of reflective powder;
20% of barium sulfate;
17% of titanium dioxide;
2% of polymethyl methacrylate micro powder;
5% of spherical organic silicon powder;
6% of electroplated aluminum glass microspheres;
sodium carboxymethylcellulose 1%;
25% of water-based acrylic resin;
12 percent of water.
3. The optical paint for a projection screen of a laser television as claimed in claim 1 or 2, wherein the particle size of the reflective powder is 5 to 15 μm.
4. The optical coating for a projection screen of a laser television set according to claim 1 or 2, wherein the particle size of the barium sulfate is 15 to 200 μm.
5. The optical paint for the projection screen of the laser television as claimed in claim 1 or 2, wherein the particle size of the titanium dioxide is 20 to 80 μm.
6. The optical coating for a projection screen of a laser television according to claim 1 or 2, wherein the polymethyl methacrylate fine powder has a particle size of 1.5 to 3 μm.
7. The optical coating for the projection screen of the laser television as claimed in claim 1 or 2, wherein the spherical organic silicon powder has a particle size of 1 to 3 μm.
8. The optical coating for the projection screen of the laser television as claimed in claim 1 or 2, wherein the particle size of the electroplated aluminum glass microsphere is 5-15 μm.
9. The method of claim 1, comprising the steps of:
s1) mixing the polymethyl methacrylate micro powder and the spherical organic silicon powder, adding the mixture into water-based acrylic resin, then adding water, and performing ultrasonic dispersion for 10-15 min to obtain a mixed solution;
s2) mixing and stirring the reflective powder, the barium sulfate, the titanium dioxide, the electroplated aluminum glass microspheres and the sodium carboxymethyl cellulose, adding the mixture into the mixed solution obtained in the step S1, and mechanically stirring for 5-10 min to obtain the light-emitting diode.
CN202011022713.XA 2020-09-25 2020-09-25 Optical coating for projection screen for laser TV and preparation method thereof Pending CN112126299A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011022713.XA CN112126299A (en) 2020-09-25 2020-09-25 Optical coating for projection screen for laser TV and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011022713.XA CN112126299A (en) 2020-09-25 2020-09-25 Optical coating for projection screen for laser TV and preparation method thereof

Publications (1)

Publication Number Publication Date
CN112126299A true CN112126299A (en) 2020-12-25

Family

ID=73840029

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011022713.XA Pending CN112126299A (en) 2020-09-25 2020-09-25 Optical coating for projection screen for laser TV and preparation method thereof

Country Status (1)

Country Link
CN (1) CN112126299A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112940575A (en) * 2021-03-15 2021-06-11 董璇 Metallic light-resistant projection imaging paint and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070275208A1 (en) * 2005-08-29 2007-11-29 Browning Gary A Polymer sheet for projection screen
CN203849547U (en) * 2014-05-28 2014-09-24 佛山市王氏光电科技有限公司 Rear-projection optical screen
US20150361270A1 (en) * 2013-02-27 2015-12-17 Asahi Rubber Inc. Ink for White Reflective Film, Powder Coating Material for White Reflective Film, Production Method of White Reflective Film, White Reflective Film, Light Source Mount, and Lighting Device Shade
CN105647311A (en) * 2016-01-14 2016-06-08 四川长虹电器股份有限公司 Projection screen coating paint, preparation method and coating forming method
US20170313896A1 (en) * 2016-05-02 2017-11-02 Koji Katsuragi White ink, printed matter, method of printing, and device for printing
CN108292090A (en) * 2015-12-02 2018-07-17 Jxtg能源株式会社 Reflection-type transparent screen and image projection device with the reflection-type transparent screen
CN110862757A (en) * 2019-12-06 2020-03-06 深圳职业技术学院 Light diffusion coating, light diffusion sheet, preparation method of light diffusion sheet and backlight module
CN112305648A (en) * 2020-11-09 2021-02-02 合肥乐凯科技产业有限公司 High-brightness high-fog light-homogenizing film

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070275208A1 (en) * 2005-08-29 2007-11-29 Browning Gary A Polymer sheet for projection screen
US20150361270A1 (en) * 2013-02-27 2015-12-17 Asahi Rubber Inc. Ink for White Reflective Film, Powder Coating Material for White Reflective Film, Production Method of White Reflective Film, White Reflective Film, Light Source Mount, and Lighting Device Shade
CN203849547U (en) * 2014-05-28 2014-09-24 佛山市王氏光电科技有限公司 Rear-projection optical screen
CN108292090A (en) * 2015-12-02 2018-07-17 Jxtg能源株式会社 Reflection-type transparent screen and image projection device with the reflection-type transparent screen
CN105647311A (en) * 2016-01-14 2016-06-08 四川长虹电器股份有限公司 Projection screen coating paint, preparation method and coating forming method
US20170313896A1 (en) * 2016-05-02 2017-11-02 Koji Katsuragi White ink, printed matter, method of printing, and device for printing
CN110862757A (en) * 2019-12-06 2020-03-06 深圳职业技术学院 Light diffusion coating, light diffusion sheet, preparation method of light diffusion sheet and backlight module
CN112305648A (en) * 2020-11-09 2021-02-02 合肥乐凯科技产业有限公司 High-brightness high-fog light-homogenizing film

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
邓建国等: "《粉体材料》", 31 August 2007, 电子科技大学出版社 *
陆馨等: "PET表面含有聚硅氧烷微球的涂层制备及其光散射性能", 《华东理工大学学报(自然科学版)》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112940575A (en) * 2021-03-15 2021-06-11 董璇 Metallic light-resistant projection imaging paint and preparation method thereof

Similar Documents

Publication Publication Date Title
CN107739159B (en) High-haze low-glossiness anti-glare film and preparation method thereof
CN104090461B (en) Mould projection screen and preparation method thereof in vain
WO2019227937A1 (en) Fresnel screen
CN104090457B (en) Fluorescence projection screen and preparation method thereof
CN101495888A (en) Coating solution for forming light diffusion layer, and light diffusion plate
CN101364039A (en) A nano-coating rear projection display
CN104090459A (en) Grey micro-bead projection screen and manufacturing method thereof
CN104090458A (en) Microbead projection screen and manufacturing method thereof
CN105820743A (en) Wall coating for high definition projection and preparation method thereof
CN112126299A (en) Optical coating for projection screen for laser TV and preparation method thereof
CN104090460A (en) Grey micro-bead curtain surface and manufacturing method thereof
CN113493636B (en) Projection reflection screen paint and preparation method thereof
JP2020067648A (en) Environmentally friendly projection transmissive screen and method of manufacturing the same
CN111748270A (en) Coating for projection screen and preparation method thereof
CN108659658A (en) High brightness moulds the coating material and preparation method thereof of projection screen in vain
CN108676451A (en) Diffusing reflection coating material, high-resolution white plastic curtain cloth and preparation method thereof
KR20190079775A (en) Paint composition for preparing beam projector screen and beam projector screen
WO2020233468A1 (en) Transparent projection coating and front projection screen
CN108803224A (en) Projection screen and preparation method thereof
WO2020233469A1 (en) Anti-glare front-projection coating material and front-projection screen
CN107144901B (en) Optical slurry film preparation method and optical film
CN112230314A (en) High glass diffuser plate of high light that shields nature
CN108504206A (en) A kind of motion picture projection diffusing reflection screen optical coating formula and preparation method thereof
CN110862757A (en) Light diffusion coating, light diffusion sheet, preparation method of light diffusion sheet and backlight module
CN104090462A (en) Microbead screen surface and manufacturing method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information
CB02 Change of applicant information

Country or region after: China

Address after: 518000 Xili street xilihu town xilihu bank, Nanshan District, Shenzhen City, Guangdong Province

Applicant after: Shenzhen Vocational and Technical University

Address before: Shenzhen Vocational and Technical College Shahe West Road Nanshan District Shenzhen Guangdong Province

Applicant before: SHENZHEN POLYTECHNIC

Country or region before: China