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CN112071898B - Rapid ionization device and preparation method thereof - Google Patents

Rapid ionization device and preparation method thereof Download PDF

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CN112071898B
CN112071898B CN202010914778.9A CN202010914778A CN112071898B CN 112071898 B CN112071898 B CN 112071898B CN 202010914778 A CN202010914778 A CN 202010914778A CN 112071898 B CN112071898 B CN 112071898B
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梁琳
黄鑫远
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Huazhong University of Science and Technology
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    • HELECTRICITY
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Abstract

本发明属于脉冲功率半导体器件领域,更具体地,涉及一种快速离化器件及其制备方法。该快速离化器件包括依次相邻设置的金属化阴极、高掺杂n+区、阴极侧高掺杂p+短路点、p基区、n‑基区、n型促离化层、阳极侧高掺杂n+短路点、高掺杂p+区、金属化阳极。本发明通过在FID器件结构中引入较n‑基区更高的掺杂浓度的n型促离化层,通过限制n‑基区空间电荷区的扩展,进而限制了碰撞电离前沿需要穿越的区域宽度,减小了碰撞电离前沿穿越的范围,减少了碰撞电离前沿传播的时间,从而提高了器件的开通速度。

Figure 202010914778

The invention belongs to the field of pulsed power semiconductor devices, and more particularly, relates to a fast ionization device and a preparation method thereof. The fast ionization device includes a metallized cathode, a highly doped n+ region, a highly doped p+ short-circuit point on the cathode side, a p base region, an n-base region, an n-type ionization promoting layer, and a highly doped anode side, which are arranged adjacently in sequence. Miscellaneous n+ short-circuit point, highly doped p+ region, metallized anode. By introducing an n-type ionization promoting layer with a higher doping concentration than the n-base region in the FID device structure, the invention limits the expansion of the space charge region of the n-base region, thereby limiting the region that the collision ionization front needs to pass through. The width of the collision ionization front is reduced, and the propagation time of the collision ionization front is reduced, thereby improving the turn-on speed of the device.

Figure 202010914778

Description

一种快速离化器件及其制备方法A kind of fast ionization device and preparation method thereof

技术领域technical field

本发明属于脉冲功率半导体器件领域,更具体地,涉及一种快速离化器件(FastIonization Dynistor,FID)及其制备方法。The invention belongs to the field of pulsed power semiconductor devices, and more particularly, relates to a fast ionization device (FastIonization Dynistor, FID) and a preparation method thereof.

背景技术Background technique

延迟雪崩击穿现象是俄罗斯Ioffe研究院发现的半导体器件内的一种新的物理现象,它揭示了在硅器件两端施加以1012V/s增加的反向电压时,器件内部会产生一个超快碰撞电离前沿,当碰撞电离前沿穿过器件的空间电荷区后,器件就会快速导通。基于延迟雪崩击穿现象设计的器件,其导通时间可以超越自由载流子的饱和漂移速度的限制,从而使器件的导通时间缩短到亚纳秒范围内。The delayed avalanche breakdown phenomenon is a new physical phenomenon in semiconductor devices discovered by the Russian Ioffe Research Institute, which reveals that when a reverse voltage increased by 10 12 V/s is applied across the silicon device, a Ultrafast impact ionization front, when the impact ionization front passes through the space charge region of the device, the device turns on rapidly. Devices designed based on the delayed avalanche breakdown phenomenon can turn on time beyond the limit of the saturation drift velocity of free carriers, thereby shortening the on-time of the device to the sub-nanosecond range.

快速离化器件FID是一种基于延迟雪崩击穿现象的新型器件,它可在数百皮秒内迅速导通,可用于产生电压等级高、上升时间短的脉冲,非常适合应用于脉冲功率系统中。现有的FID器件的结构如图1所示,器件主要包含四层结构,从上至下依次为n+层、p层、n层以及p+层,此外n+层与p+层均包含短路点结构。The fast ionization device FID is a new type of device based on the delayed avalanche breakdown phenomenon. It can be quickly turned on in hundreds of picoseconds and can be used to generate pulses with high voltage levels and short rise times, which are very suitable for pulsed power systems. middle. The structure of the existing FID device is shown in Figure 1. The device mainly includes a four-layer structure, which are n+ layer, p layer, n layer and p+ layer in order from top to bottom. In addition, both the n+ layer and the p+ layer include short-circuit point structures.

FID器件是一种两端器件,即器件只有阴极和阳极。如图2所示的FID器件工作电路,在FID器件工作时,首先直流电源DC对电容C充电,此时FID器件处于正向阻断状态,其阳极(节点2)与阴极(节点1)之间承受正向电压,随后,在需要触发导通时,触发源pulse产生触发脉冲,在FID器件阳极上施加电压上升率大于1kV/ns的触发脉冲,当器件两端电压上升到大于阻断电压的2~3倍时,J2结上电场强度超过临界击穿场强,J2结上发生剧烈的碰撞电离,随后电离区域向器件两电极处传播,从而使器件在数百皮秒内迅速导通,电容C通过FID器件放电,从而在负载RL上高压脉冲。A FID device is a two-terminal device, that is, the device has only a cathode and an anode. As shown in the working circuit of the FID device as shown in Figure 2, when the FID device is working, the DC power supply DC first charges the capacitor C. At this time, the FID device is in a forward blocking state, and the connection between the anode (node 2) and the cathode (node 1) is It is subjected to a forward voltage intermittently, and then, when it needs to be triggered and turned on, the trigger source pulse generates a trigger pulse, and a trigger pulse with a voltage rise rate greater than 1kV/ns is applied to the anode of the FID device. When the voltage across the device rises to greater than the blocking voltage When the electric field strength on the J 2 junction exceeds the critical breakdown field strength, violent collision ionization occurs on the J 2 junction, and then the ionized region propagates to the two electrodes of the device, so that the device can rapidly operate within hundreds of picoseconds. On, the capacitor C discharges through the FID device, thereby pulsing a high voltage across the load RL .

通常,为了实现FID器件较高的阻断电压,在器件设计和制造中会采用电阻率较高的单晶材料,同时会使器件具有较宽的n-基区(即n-层)。然而,在开通前,几乎整个n-基区都会变为耗尽区。因此,开通过程中,器件内部的碰撞电离前沿需要穿过整个n-基区,并在n-基区产生一定浓度的等离子体,之后器件便进入导通状态。由于碰撞电离前沿穿过的区域中产生的电子空穴等离子体浓度有限,因此触发导通后的n-基区仍有较高的电阻率,从而在器件两端产生较高的残余电压。高电阻率、长基区宽度的器件设计导致FID器件开通后,器件两端的残余电压较高,器件通态损耗较大,不利于器件的长期稳定工作。Generally, in order to achieve higher blocking voltage of FID devices, single crystal materials with higher resistivity are used in device design and fabrication, and the device has a wider n-base region (ie, n-layer) at the same time. Before turn-on, however, almost the entire n-base region becomes depleted. Therefore, during the turn-on process, the impact ionization front inside the device needs to pass through the entire n-base region, and a certain concentration of plasma is generated in the n-base region, and then the device enters the conduction state. Due to the limited concentration of electron-hole plasma generated in the region traversed by the impact ionization front, the n-base region still has a high resistivity after being turned on, resulting in a high residual voltage across the device. The device design with high resistivity and long base width leads to high residual voltage at both ends of the device after the FID device is turned on, and the on-state loss of the device is large, which is not conducive to the long-term stable operation of the device.

发明内容SUMMARY OF THE INVENTION

针对现有技术的缺陷或改进需求,本发明提供了一种快速离化器件及其制备方法,通过在FID器件结构中的n-基区与阳极侧高掺杂p+区之间增设n型促离化层,缩短碰撞电离前沿传播范围,加快器件的开通速度;同时还降低了器件导通后的残余电压,降低了器件的通态损耗,从而提高了其开关速度,改善了器件的工作特性。Aiming at the defects or improvement requirements of the prior art, the present invention provides a fast ionization device and a preparation method thereof. By adding an n-type booster between the n-base region and the highly doped p+ region on the anode side in the structure of the FID device The ionization layer shortens the propagation range of the impact ionization front and accelerates the turn-on speed of the device; at the same time, it also reduces the residual voltage after the device is turned on, reduces the on-state loss of the device, thereby increasing its switching speed and improving the device's operating characteristics .

为实现上述目的,本发明提供了一种快速离化器件,包括依次相邻设置的金属化阴极、高掺杂n+区、阴极侧高掺杂p+短路点、p基区、n-基区、n型促离化层、阳极侧高掺杂n+短路点、高掺杂p+区、金属化阳极;In order to achieve the above purpose, the present invention provides a fast ionization device, which includes a metallized cathode, a highly doped n+ region, a highly doped p+ short-circuit point on the cathode side, a p base region, an n- base region, n-type ionization promoting layer, highly doped n+ short-circuit point on anode side, highly doped p+ region, metallized anode;

其中,所述高掺杂n+区以及所述阴极侧高掺杂p+短路点均位于所述p基区与所述金属化阴极之间,且所述高掺杂n+区与所述阴极侧高掺杂p+短路点具有相同的厚度且二者交替设置;Wherein, the highly doped n+ region and the highly doped p+ short-circuit point on the cathode side are located between the p base region and the metallized cathode, and the highly doped n+ region and the cathode side are high The doped p+ short-circuit points have the same thickness and are alternately arranged;

所述高掺杂p+区和所述阳极侧高掺杂n+短路点均位于所述n型促离化层和所述金属化阳极之间,且所述阳极侧高掺杂n+短路点与所述高掺杂p+区具有相同的厚度且二者交替设置。The highly doped p+ region and the highly doped n+ short circuit point on the anode side are both located between the n-type ionization promoting layer and the metallized anode, and the highly doped n+ short circuit point on the anode side is connected to the high doped n+ short circuit point on the anode side. The highly doped p+ regions have the same thickness and are alternately arranged.

优选地,所述n-基区的厚度为400-800μm。Preferably, the thickness of the n-base region is 400-800 μm.

优选地,所述n型促离化层中的掺杂浓度为1016~1018cm-3;该n型促离化层的厚度为10~60μm。Preferably, the doping concentration in the n-type ion-promoting layer is 10 16 -10 18 cm -3 ; the thickness of the n-type ion-promoting layer is 10-60 μm.

优选地,所述n型促离化层中的掺杂浓度为(1~5)*1017cm-3;该n型促离化层的厚度为25~35μm。Preferably, the doping concentration in the n-type ion-promoting layer is (1-5)*10 17 cm -3 ; the thickness of the n-type ion-promoting layer is 25-35 μm.

按照本发明的另一个方面,提供了一种所述的快速离化器件的制备方法,包括如下步骤:According to another aspect of the present invention, there is provided a preparation method of the fast ionization device, comprising the following steps:

(1)在清洗后的n型Si片上进行杂质扩散,形成PNP结构;然后通过减薄机去掉其中一边的p形区域;得到包含p基区和n-基区的PN结构;(1) Impurity diffusion is carried out on the cleaned n-type Si sheet to form a PNP structure; then the p-shaped region on one side is removed by a thinning machine; a PN structure comprising a p-base region and an n-base region is obtained;

(2)对步骤(1)得到的PN结构进行氧化形成SiO2层掩膜层,通过光刻去除N侧的SiO2层掩膜层,通过扩散工艺在n-基区侧形成n型促离化层;(2) Oxidize the PN structure obtained in step (1) to form a SiO 2 mask layer, remove the SiO 2 mask layer on the N side by photolithography, and form an n-type ionization booster on the n-base side by a diffusion process chemical layer;

(3)在上述硅片的上表面和下表面同时氧化形成SiO2层掩膜层;通过双面光刻,将光刻版的图形转移到Si片两极上;腐蚀去除没有光刻胶保护处的SiO2层;然后去除Si片两极的光刻胶;再进行杂质扩散,形成阳极侧的高掺杂n+型短路点以及阴极侧的高掺杂n+区;(3) Simultaneously oxidize the upper surface and the lower surface of the above-mentioned silicon wafer to form a SiO 2 layer mask layer; Through double-sided photolithography, the pattern of the photolithography plate is transferred to the two poles of the Si wafer; The etching removes the place without photoresist protection Then remove the photoresist at the two poles of the Si wafer; then carry out impurity diffusion to form a highly doped n+ type short circuit point on the anode side and a highly doped n+ region on the cathode side;

(4)在上述硅片两极进行杂质扩散,形成阳极侧的高掺杂p+区以及阴极侧的高掺杂p+短路点;(4) Impurity diffusion is carried out at the two poles of the above-mentioned silicon wafer to form a highly doped p+ region on the anode side and a highly doped p+ short circuit point on the cathode side;

(5)对步骤(4)得到的硅片进行割圆,并将Al片冲制成和割圆后的Si片同样大小,再去除Si片和Al片表面氧化膜、有机污垢和玷污杂质;(5) the silicon wafer obtained in step (4) is cut into a circle, and the Al sheet is punched into the same size as the Si sheet after the cut circle, and then the oxide film, organic dirt and contamination impurities on the surface of the Si sheet and the Al sheet are removed;

(6)将多层材料装入模具,每层材料按照石墨-Mo片-Al片-Si片顺序排列,并使Si片阳极与Al片相对,再将装好的模具进行真空烧结;(6) loading the multi-layer material into the mold, each layer of material is arranged in the order of graphite-Mo sheet-Al sheet-Si sheet, and the Si sheet anode is opposite to the Al sheet, and then the loaded mold is vacuum sintered;

(7)在上述Si片阴极面蒸镀一层Al膜作为电极;然后退火,使Si片阴极面和Al膜间形成Si-Al合金,得到快速离化器件。(7) Evaporating an Al film on the cathode surface of the Si sheet as an electrode; then annealing to form a Si-Al alloy between the cathode surface of the Si sheet and the Al film to obtain a rapid ionization device.

优选地,步骤(2)通过低浓度磷扩散工艺在n-基区侧形成n型促离化层。Preferably, in step (2), an n-type ion-promoting layer is formed on the side of the n-base region by a low-concentration phosphorus diffusion process.

优选地,步骤(4)具体为:在硅片两极涂上用氧化硼和硝酸铝配成的酒精源,进行浓硼扩散,形成阳极侧的高掺杂p+区以及阴极侧的高掺杂p+短路点。Preferably, step (4) is specifically as follows: coating the two electrodes of the silicon wafer with an alcohol source made of boron oxide and aluminum nitrate, and diffusing concentrated boron to form a highly doped p+ region on the anode side and a highly doped p+ region on the cathode side short circuit point.

优选地,步骤(6)将装好的模具置于真空烧结炉中,该真空烧结炉中的真空度在10-4Pa以上,控制烧结温度为690~700℃,恒温时间为5-30min,然后以10~20℃/min的速率使烧结炉降温,降温至400℃以下后在空气中自然降温。Preferably, in step (6), the installed mold is placed in a vacuum sintering furnace, the vacuum degree in the vacuum sintering furnace is above 10 -4 Pa, the sintering temperature is controlled to be 690-700°C, and the constant temperature time is 5-30min, Then, the sintering furnace is cooled at a rate of 10-20°C/min, and the temperature is naturally cooled in the air after the temperature is lowered to below 400°C.

通过本发明所构思的以上技术方案,与现有技术相比,能够取得下列有益效果:Through the above technical scheme conceived by the present invention, compared with the prior art, the following beneficial effects can be achieved:

(1)本发明提供的一种快速离化FID器件,其包括依次相邻设置的金属化阴极、高掺杂n+区、阴极侧高掺杂p+短路点、p基区、n-基区、n型促离化层、阳极侧高掺杂n+短路点、高掺杂p+区、金属化阳极,较n-基区更高的掺杂浓度的n型促离化层在FID器件中的引入,通过限制n-基区空间电荷区的扩展,进而限制了碰撞电离前沿需要穿越的区域宽度,减小了碰撞电离前沿穿越的范围,减少了碰撞电离前沿传播的时间,从而提高了器件的开通速度。(1) A fast ionization FID device provided by the present invention includes a metallized cathode, a highly doped n+ region, a highly doped p+ short-circuit point on the cathode side, a p base region, an n- base region, Introduction of n-type ion-promoting layer, highly doped n+ short-circuit point on anode side, highly doped p+ region, metallized anode, and n-type ion-promoting layer with higher doping concentration than n- base region in FID device , by limiting the expansion of the space charge region of the n-base region, thereby limiting the width of the region that the collision ionization front needs to pass through, reducing the range of collision ionization front crossing, and reducing the propagation time of the collision ionization front, thereby improving the turn-on of the device. speed.

(2)本发明提出的快速离化FID器件能够在确保FID器件阻断电压不变的情况下,大大减小n-基区厚度,可以在显著提高开通速度的前提下,将n-基区厚度减小10%。(2) The fast ionization FID device proposed by the present invention can greatly reduce the thickness of the n-base region under the condition that the blocking voltage of the FID device remains unchanged, and can significantly increase the turn-on speed. The thickness is reduced by 10%.

(3)本发明提供的设置有n型促离化层的FID器件导通后,碰撞电离前沿传播区域长度减小,因此器件的导通电阻减小,器件两端的残余电压减小,进而降低器件的通态损耗,更有利于器件在重频状态下工作。(3) After the FID device provided with the n-type ionization promoting layer provided by the present invention is turned on, the length of the propagation region of the collision ionization front is reduced, so the on-resistance of the device is reduced, and the residual voltage at both ends of the device is reduced, thereby reducing the The on-state loss of the device is more favorable for the device to work under the repeated frequency state.

(4)本发明将n型促离化层引入传统的FID器件中,通过优化设置n型促离化层其掺杂浓度及其该层的厚度,配合整体的FID器件结构,使得该器件导通速度显著提高,且器件残压也大大降低。(4) In the present invention, the n-type ionization promoting layer is introduced into the traditional FID device. By optimizing the setting of the doping concentration of the n-type ionization promoting layer and the thickness of the layer, in conjunction with the overall FID device structure, the device conducts The pass speed is significantly improved, and the residual voltage of the device is also greatly reduced.

(5)本发明技术方案的核心在于提供了包含促离化层的FID器件结构,采用此种结构的FID器件相比于传统的FID器件具有提高开通速度,降低通态压降以及降低通态损耗等优点。此外,本发明提供的包含促离化层结构的FID器件的制备方法,制备流程中通过扩散形成n型促离化层,降低了工艺成本,而后通过双面光刻转移阴极和阳极图形,节省了工艺步骤。(5) The core of the technical solution of the present invention is to provide an FID device structure including an ionization-promoting layer. Compared with the traditional FID device, the FID device using this structure has the advantages of improving the turn-on speed, reducing the on-state voltage drop and reducing the on-state voltage. loss, etc. In addition, in the preparation method of the FID device including the ionization-promoting layer structure provided by the present invention, the n-type ionization-promoting layer is formed by diffusion in the preparation process, which reduces the process cost, and then the cathode and anode patterns are transferred by double-sided lithography. process steps.

附图说明Description of drawings

图1为现有的快速离化器件的结构示意图;1 is a schematic structural diagram of an existing rapid ionization device;

图2为FID器件工作电路示意图;Figure 2 is a schematic diagram of the working circuit of the FID device;

图3为本发明提供的包含促离化层的快速离化器件的结构示意图;3 is a schematic structural diagram of a fast ionization device comprising an ionization-promoting layer provided by the present invention;

图4为不同促离化层浓度对器件开通过程的影响;Figure 4 shows the effect of different ionization layer concentrations on the device turn-on process;

图5为不同促离化层厚度对器件开通过程的影响;Figure 5 shows the effect of different ionization-promoting layer thicknesses on the device turn-on process;

图6为有促离化层和无促离化层的快速离化器件的仿真结果;Fig. 6 is the simulation result of the fast ionization device with and without the ionization-promoting layer;

在所有附图中,相同的附图标记用来表示相同的元件或结构,其中,1为金属化阴极,2为高掺杂n+区,3为阴极侧高掺杂p+短路点,4为p基区,5为n-基区,6为n型促离化层,7为阳极侧高掺杂n+短路点,8为高掺杂p+区,9为金属化阳极。Throughout the drawings, the same reference numerals are used to designate the same elements or structures, wherein 1 is a metallized cathode, 2 is a highly doped n+ region, 3 is a cathode side highly doped p+ short circuit, and 4 is a p Base region, 5 is an n-base region, 6 is an n-type ion-promoting layer, 7 is a highly doped n+ short circuit point on the anode side, 8 is a highly doped p+ region, and 9 is a metallized anode.

具体实施方式Detailed ways

为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。In order to make the objectives, technical solutions and advantages of the present invention clearer, the present invention will be further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention, but not to limit the present invention.

本发明提供的一种快速离化器件,如图3所示,其包括依次相邻设置的金属化阴极1、高掺杂n+区2、阴极侧高掺杂p+短路点3、p基区4、n-基区5、n型促离化层6、阳极侧高掺杂n+短路点7、高掺杂p+区8、金属化阳极9;A fast ionization device provided by the present invention, as shown in FIG. 3 , includes a metallized cathode 1, a highly doped n+ region 2, a highly doped p+ short-circuit point 3 on the cathode side, and a p base region 4, which are arranged adjacently in sequence. , n-base region 5, n-type ionization promoting layer 6, anode side highly doped n+ short circuit point 7, highly doped p+ region 8, metallized anode 9;

其中,所述高掺杂n+区2以及所述阴极侧高掺杂p+短路点3均位于所述p基区4与所述金属化阴极1之间,且所述高掺杂n+区2与所述阴极侧高掺杂p+短路点3具有相同的厚度且二者交替设置;Wherein, the highly doped n+ region 2 and the highly doped p+ short circuit point 3 on the cathode side are located between the p base region 4 and the metallized cathode 1, and the highly doped n+ region 2 and The highly doped p+ short-circuit points 3 on the cathode side have the same thickness and are alternately arranged;

所述高掺杂p+区8和所述阳极侧高掺杂n+短路点7均位于所述n型促离化层6和所述金属化阳极9之间,且所述阳极侧高掺杂n+短路点7与所述高掺杂p+区8具有相同的厚度且二者交替设置。The highly doped p+ region 8 and the anode side highly doped n+ short circuit point 7 are both located between the n-type ionization promoting layer 6 and the metallized anode 9, and the anode side highly doped n+ The short-circuit point 7 and the highly doped p+ region 8 have the same thickness and are alternately arranged.

本发明金属化阴极1和金属化阳极9可以采用铝金属。The metallized cathode 1 and the metallized anode 9 of the present invention can use aluminum metal.

本发明根据器件的耐压等级,选择设置各层的厚度以及掺杂浓度。比如一些实施例中,高掺杂n+区2其掺杂浓度为1018~1020cm-3,厚度为20-30μm;p基区4的厚度为60-80μm;n-基区5的掺杂浓度为1013~1014cm-3,厚度为500μm;高掺杂p+区8的掺杂浓度为1017~1019cm-3,厚度为20-30μm。The present invention selects and sets the thickness and doping concentration of each layer according to the withstand voltage level of the device. For example, in some embodiments, the doping concentration of the highly doped n+ region 2 is 10 18 -10 20 cm -3 , and the thickness is 20-30 μm; the thickness of the p-base region 4 is 60-80 μm; The impurity concentration is 10 13 -10 14 cm -3 , and the thickness is 500 μm; the doping concentration of the highly doped p+ region 8 is 10 17 -10 19 cm -3 , and the thickness is 20-30 μm.

本发明n型促离化层的掺杂浓度对器件开通速度以及残余电压下降幅度有较大的影响,但是并非掺杂浓度越高或该促离化层厚度越厚越好。兼顾器件开通速度、残余电压以及工艺实现难易程度,可行的n型促离化层的掺杂浓度为1016~1018cm-3,厚度为10-60μm。另外,根据图4所示促离化层浓度对器件开通过程的影响,可以看出当促离化层浓度达到1*1017cm-3后,器件开通速度以及残余电压不再减小,因此为了保证发射极有较高的注入效率,优选的n型促离化层的掺杂浓度为(1~5)*1017cm-3,由图5所示促离化层厚度对器件开通过程的影响,可以看出当促离化层厚度增加到30μm后,器件残余电压下降幅度很小,为了保证工艺实现较为容易,n型促离化层的厚度优选设置为25~35μm,在该掺杂浓度和厚度设置下,器件的正向阻断能力不会下降,并且可以保证发射极有较高的注入效率,器件的导通速度加快,导通后的器件两端的残压降低。The doping concentration of the n-type ionization promoting layer of the present invention has a great influence on the turn-on speed of the device and the drop range of the residual voltage, but it is not the case that the higher the doping concentration or the thicker the ionization promoting layer, the better. Taking into account the device turn-on speed, residual voltage and ease of process realization, a feasible n-type ionization promoting layer has a doping concentration of 10 16 -10 18 cm -3 and a thickness of 10-60 μm. In addition, according to the effect of the concentration of the ion-promoting layer on the turn-on process of the device shown in Fig. 4, it can be seen that when the concentration of the ion-promoting layer reaches 1*10 17 cm -3 , the turn-on speed and the residual voltage of the device no longer decrease, so In order to ensure the high implantation efficiency of the emitter, the preferred doping concentration of the n-type ionization layer is (1~5)*10 17 cm -3 . The thickness of the ionization layer shown in FIG. 5 affects the device turn-on process. It can be seen that when the thickness of the ion-promoting layer is increased to 30 μm, the residual voltage of the device drops very little. Under the setting of impurity concentration and thickness, the forward blocking ability of the device will not decrease, and the emitter can be guaranteed to have a high injection efficiency, the conduction speed of the device is accelerated, and the residual voltage across the device after conduction is reduced.

本发明还提供了所述的快速离化器件的制备方法,包括如下步骤:The present invention also provides the preparation method of the fast ionization device, comprising the following steps:

(1)在清洗后的n型Si片上进行杂质扩散,形成PNP结构;然后通过减薄机去掉一侧的p区,得到包含p基区4和n-基区5的PN结构;(1) Impurity diffusion is performed on the cleaned n-type Si sheet to form a PNP structure; then the p region on one side is removed by a thinning machine to obtain a PN structure comprising p base region 4 and n-base region 5;

(2)对步骤(1)得到的PN结构进行氧化形成SiO2层掩膜层,通过光刻去除N侧的SiO2层掩膜层,通过扩散工艺在n-基区侧形成n型促离化层6;(2) Oxidize the PN structure obtained in step (1) to form a SiO 2 mask layer, remove the SiO 2 mask layer on the N side by photolithography, and form an n-type ionization booster on the n-base side by a diffusion process chemical layer 6;

(3)在上述硅片的上表面和下表面同时氧化形成SiO2层掩膜层;通过双面光刻,将光刻版的图形转移到Si片两极上;腐蚀去除没有光刻胶保护处的SiO2层;然后去除Si片两极的光刻胶;再进行杂质扩散,形成阳极侧的高掺杂n+型短路点7以及阴极侧的高掺杂n+区2;(3) Simultaneously oxidize the upper surface and the lower surface of the above-mentioned silicon wafer to form a SiO 2 layer mask layer; Through double-sided photolithography, the pattern of the photolithography plate is transferred to the two poles of the Si wafer; The etching removes the place without photoresist protection Then remove the photoresist at the two poles of the Si wafer; then carry out impurity diffusion to form a highly doped n+ type short circuit point 7 on the anode side and a highly doped n+ region 2 on the cathode side;

(4)在上述硅片两极进行杂质扩散,形成阳极侧的高掺杂p+区8以及阴极侧的高掺杂p+短路点3;(4) Impurity diffusion is performed at the two poles of the above-mentioned silicon wafer to form a highly doped p+ region 8 on the anode side and a highly doped p+ short circuit point 3 on the cathode side;

(5)割圆,并将Al片冲制成和割圆后的Si片同样大小,再去除Si片和Al片表面氧化膜、有机污垢和玷污杂质;(5) Cut the circle, and punch the Al sheet into the same size as the Si sheet after the cut circle, and then remove the oxide film, organic dirt and contamination impurities on the surface of the Si sheet and the Al sheet;

(6)将多层材料装入模具,每层材料按照“石墨-Mo片-Al片-Si片”顺序排列,并使Si片阳极与Al片相对,再将装好的模具进行真空烧结;(6) load the multi-layer material into the mold, each layer of material is arranged in the order of "graphite-Mo sheet-Al sheet-Si sheet", and the Si sheet anode is opposite to the Al sheet, and then the loaded mold is vacuum sintered;

(7)在上述Si片阴极面蒸镀一层Al膜作为电极;然后退火,使Si片阴极面和Al膜间形成Si-Al合金,得到快速离化器件。(7) Evaporating an Al film on the cathode surface of the Si sheet as an electrode; then annealing to form a Si-Al alloy between the cathode surface of the Si sheet and the Al film to obtain a rapid ionization device.

一些实施例中,步骤(1)在清洗后的n型Si片上进行Ga、Al扩散,形成PNP结构。In some embodiments, step (1) performs Ga and Al diffusion on the cleaned n-type Si wafer to form a PNP structure.

一些实施例中,步骤(2)通过低浓度磷扩散工艺在步骤(1)硅片的n-基区一侧形成n型促离化层6。In some embodiments, in step (2), an n-type ionization promoting layer 6 is formed on the side of the n-base region of the silicon wafer in step (1) by a low-concentration phosphorus diffusion process.

一些实施例中,步骤(3)进行磷扩散,形成阳极侧的高掺杂n+型短路点7以及阴极侧的高掺杂n+区2。In some embodiments, in step (3), phosphorus diffusion is performed to form a highly doped n+ type short-circuit point 7 on the anode side and a highly doped n+ region 2 on the cathode side.

一些实施例中,步骤(4)具体为:在硅片阳极侧和阴极侧均涂上用氧化硼(B2O3)和硝酸铝(Al(NO3)3)配成的酒精源,进行浓硼扩散,形成阳极侧的高掺杂p+区8以及阴极侧的高掺杂p+短路点3。In some embodiments, step (4) is specifically as follows: coating an alcohol source made of boron oxide (B 2 O 3 ) and aluminum nitrate (Al(NO 3 ) 3 ) on both the anode side and the cathode side of the silicon wafer, and performing the process. Concentrated boron diffuses to form a highly doped p+ region 8 on the anode side and a highly doped p+ short-circuit point 3 on the cathode side.

一些实施例中,步骤(6)将装好的模具置于真空烧结炉中,该真空烧结炉中的真空度在10-4Pa以上,控制烧结温度在690~700℃,恒温时间5-30分钟;然后以10~20℃/min的速率使烧结炉降温,至400℃以下可使其在空气中自然降温。In some embodiments, in step (6), the installed mold is placed in a vacuum sintering furnace, the vacuum degree in the vacuum sintering furnace is above 10 -4 Pa, the sintering temperature is controlled at 690-700 ° C, and the constant temperature time is 5-30 minutes; then cool down the sintering furnace at a rate of 10-20°C/min, and it can be cooled naturally in the air when it is below 400°C.

一些实施例中,还包括步骤:In some embodiments, it also includes the steps of:

(8)磨角以形成正负双斜角终端;然后进行台面腐蚀和台面保护,最后进行管芯封装。(8) Grinding to form positive and negative double bevel terminals; then performing mesa corrosion and mesa protection, and finally performing die packaging.

以下为实施例:The following are examples:

实施例1Example 1

如图3所示,一种快速离化器件结构包括:金属化阴极1、高掺杂n+区2、阴极侧高掺杂p+短路点3、p基区4、n-基区5、n型促离化层6、阳极侧高掺杂n+短路点7、高掺杂p+区8、金属化阳极9。高掺杂p+区8位于金属化阳极9侧,阳极侧高掺杂n+短路点7位于金属化阳极9侧的高掺杂p+区8之间;n型促离化层6位于高掺杂p+层8、阳极侧高掺杂n+短路点7与n-基区5之间,p基区4位于n-基区5上方,高掺杂n+区2位于p基区4与金属化阴极1之间,阴极侧高掺杂p+短路点3位于金属化阴极1侧的高掺杂n+区2之间,且该结构中形成了J1、J2和J3三个PN结。As shown in FIG. 3, a fast ionization device structure includes: metallized cathode 1, highly doped n+ region 2, highly doped p+ short circuit point 3 on the cathode side, p base region 4, n- base region 5, n-type Ionization promoting layer 6 , highly doped n+ short circuit point 7 on anode side, highly doped p+ region 8 , metallized anode 9 . The highly doped p+ region 8 is located on the side of the metallized anode 9, and the highly doped n+ short circuit point 7 on the anode side is located between the highly doped p+ regions 8 on the side of the metallized anode 9; the n-type ionization promoting layer 6 is located on the highly doped p+ Layer 8, between the highly doped n+ short-circuit point 7 on the anode side and the n- base region 5, the p base region 4 is located above the n- base region 5, and the highly doped n+ region 2 is located between the p base region 4 and the metallized cathode 1. During this time, the highly doped p+ short-circuit point 3 on the cathode side is located between the highly doped n+ regions 2 on the metallized cathode 1 side, and three PN junctions J 1 , J 2 and J 3 are formed in the structure.

该快速离化器件的制备过程如下:The preparation process of the fast ionization device is as follows:

(1)选用n型Si单晶;(1) Select n-type Si single crystal;

(2)清洗Si片。用氢氧化铵(NH4OH)、双氧水(H2O2)和水(H2O)按1:2:5配制的清洗液,以及用盐酸(HCl)、双氧水(H2O2)和水(H2O)按1:2:8配制的清洗液,在65℃条件下清洗硅片各10分钟;(2) Cleaning the Si wafer. Wash with ammonium hydroxide (NH 4 OH), hydrogen peroxide (H 2 O 2 ) and water (H 2 O) in a 1:2:5 ratio, and with hydrochloric acid (HCl), hydrogen peroxide (H 2 O 2 ) and The cleaning solution prepared with water (H 2 O) in a ratio of 1:2:8 was used to clean the silicon wafers at 65°C for 10 minutes each;

(3)通过Ga、Al扩散,形成PNP结构,表面浓度为1*1016cm-3,扩散结深设置为100μm;(3) PNP structure is formed through Ga and Al diffusion, the surface concentration is 1*10 16 cm -3 , and the diffusion junction depth is set to 100 μm;

(4)利用晶圆减薄机将一侧p型区域去除,减薄厚度设置为100μm;(4) Use a wafer thinning machine to remove the p-type region on one side, and set the thinning thickness to 100 μm;

(5)通过低浓度磷扩散工艺形成n型促离化层,表面浓度为1*1017cm-3,厚度为30μm;即该n型促离化层到金属阳极的距离为60μm;(5) An n-type ion-promoting layer is formed by a low-concentration phosphorus diffusion process, with a surface concentration of 1*10 17 cm -3 and a thickness of 30 μm; that is, the distance from the n-type ion-promoting layer to the metal anode is 60 μm;

(6)氧化,形成SiO2层掩膜层。在1180℃氧化硅片,通干氧(O2)1小时→湿氧(蒸汽)4小时→干氧(O2)1小时;(6) Oxidation to form a SiO 2 mask layer. Oxidize silicon wafers at 1180°C, pass dry oxygen (O 2 ) for 1 hour → wet oxygen (steam) for 4 hours → dry oxygen (O 2 ) for 1 hour;

(7)双面光刻,将光刻版的图形转移到Si片两极上;(7) Double-sided lithography, transferring the pattern of the lithography plate to the two poles of the Si wafer;

(8)腐蚀,去除没有光刻胶保护处的SiO2层。用氢氟酸(HF)、氟化铵(NH4F)、水(H2O)按3:6:10配制的试剂对光刻后的硅片进行腐蚀,水浴温度65℃,时间3分钟;(8) Etch to remove the SiO 2 layer where there is no photoresist protection. The silicon wafer after photolithography was etched with a reagent prepared by hydrofluoric acid (HF), ammonium fluoride (NH 4 F), and water (H 2 O) in a ratio of 3:6:10. The water bath temperature was 65°C for 3 minutes. ;

(9)去胶。用浓硫酸(H2SO4)去除Si片上残余的光刻胶。(9) Remove glue. The residual photoresist on the Si wafer was removed with concentrated sulfuric acid (H 2 SO 4 ).

(10)磷扩散,形成阴极侧的高掺杂n+区和阳极侧的高掺杂n+短路点。氮气(N2)通过三氯氧磷(POCl3)携带磷源,在硅片上预沉积,时间50分钟,温度从1000℃升至1250℃,在1250℃恒温1.5小时;(10) Phosphorus diffuses to form a highly doped n+ region on the cathode side and a highly doped n+ short-circuit point on the anode side. Nitrogen (N 2 ) carried the phosphorus source through phosphorus oxychloride (POCl 3 ), and pre-deposited on the silicon wafer for 50 minutes, the temperature was raised from 1000°C to 1250°C, and the temperature was kept at 1250°C for 1.5 hours;

(11)割圆。将Si片割圆至要求的大小;(11) Circumcision. Cut the Si wafer to the required size;

(12)将Al片冲制成与Si片同样直径的圆片,Al片厚度30μm;(12) Punching the Al sheet into a wafer with the same diameter as the Si sheet, and the thickness of the Al sheet is 30 μm;

(13)用氢氟酸(HF):硝酸(HNO3)按1:9配制的腐蚀液分别漂洗Al片和Si片4秒,以去除表面氧化膜、残留的有机污垢及玷污杂质,改善Al片和Si片间的沾润,以便形成平坦、均匀大面积合金pn结;(13) Rinse the Al sheet and the Si sheet with a 1:9 etching solution of hydrofluoric acid (HF): nitric acid (HNO 3 ) for 4 seconds to remove the surface oxide film, residual organic dirt and contamination impurities, improve Al Wetting between the sheet and the Si sheet to form a flat, uniform large-area alloy pn junction;

(14)在硅片阳极侧和阴极侧分别涂上用氧化硼(B2O3)和硝酸铝(Al(NO3)3)配成的酒精源,,进行浓硼扩散,在1200℃下扩散30分钟;(14) Coat the anode side and cathode side of the silicon wafer with an alcohol source composed of boron oxide (B 2 O 3 ) and aluminum nitrate (Al(NO 3 ) 3 ), respectively, to carry out concentrated boron diffusion, at 1200° C. Diffusion for 30 minutes;

(15)按照“石墨-Mo片-Al片-Si片-石墨-Mo片-Al片-Si片-…”的顺序叠放后装入模具,将装好片的模具放入真空烧结炉,其中Si片阳极与Al片相对;(15) After stacking in the order of "graphite-Mo sheet-Al sheet-Si sheet-graphite-Mo sheet-Al sheet-Si sheet-...", put the mold into the vacuum sintering furnace, Among them, the Si sheet anode is opposite to the Al sheet;

(16)对烧结炉抽真空,使真空度在10-4Pa以上,控制烧结温度在690℃,恒温时间5~30分钟;(16) Evacuate the sintering furnace to make the vacuum degree above 10 -4 Pa, control the sintering temperature at 690°C, and keep the constant temperature for 5 to 30 minutes;

(17)以15℃/min的速率使烧结炉降温,至400℃以下可使其在空气中自然降温;(17) Cool down the sintering furnace at a rate of 15°C/min, and let it cool down naturally in the air below 400°C;

(18)镀膜。在真空镀膜机中给Si片阴极面蒸镀一层Al膜;(18) Coating. Evaporate a layer of Al film on the cathode surface of the Si wafer in a vacuum coating machine;

(19)退火。在500℃对Si片进行真空退火;(19) Annealing. Vacuum anneal the Si wafer at 500℃;

(20)磨角。形成正负双斜角终端,以减小表面电场,提高耐压;(20) Grinding corners. Form positive and negative double bevel terminals to reduce surface electric field and improve withstand voltage;

(21)腐蚀。用硝酸(HNO3)、氢氟酸(HF)、磷酸(H3PO4)、醋酸(CH3COOH)按3:2:2:2的比例配制腐蚀液,在室温下腐蚀1分钟;(21) Corrosion. Prepare a corrosion solution with nitric acid (HNO 3 ), hydrofluoric acid (HF), phosphoric acid (H 3 PO 4 ), and acetic acid (CH 3 COOH) in a ratio of 3:2:2:2, and etch for 1 minute at room temperature;

(22)台面保护。台面涂硅橡胶保护,室温固化3天;(22) Countertop protection. The countertop is coated with silicone rubber for protection and cured at room temperature for 3 days;

(23)管芯封装。(23) Die package.

对比例1Comparative Example 1

该对比例的离化器件结构如图1所示,与实施例1的快速离化器件相比,仅缺少了n型促离化层,且该对比例的离化器件n-基区长度为560μm,而实施例1的离化器件n-基区长度为500μm,n型促离化层表面浓度为1*1017cm-3,厚度为30μm。其他结构层相同。The structure of the ionization device of this comparative example is shown in Figure 1. Compared with the fast ionization device of Example 1, only the n-type ionization promoting layer is missing, and the length of the n-base region of the ionization device of this comparative example is 560 μm, while the length of the n-base region of the ionization device of Example 1 is 500 μm, the surface concentration of the n-type ionization promoting layer is 1*10 17 cm −3 , and the thickness is 30 μm. Other structural layers are the same.

如图6所示,仿真中FID器件触发导通时,实施例1有促离化层结构的FID器件和对比例1无促离化层结构的FID器件的两端电压的波形,从仿真结果可以看出,有促离化层结构的FID器件两端电压在触发后下降速度更快,残压更低,符合促离化层设计目标。As shown in FIG. 6 , when the FID device is triggered and turned on in the simulation, the waveforms of the voltages at both ends of the FID device with the ionization layer structure in Example 1 and the FID device without the ionization layer structure in Comparative Example 1 are obtained from the simulation results. It can be seen that the voltage across the FID device with the ion-promoting layer structure decreases faster after triggering, and the residual voltage is lower, which is in line with the design goal of the ion-promoting layer.

本发明实施例中的FID器件增加了n型促离化层后,可以在确保FID器件阻断电压不变的情况下,大大减小n-基区厚度。此外,FID器件工作时,金属化阳极接正向电压,金属化阳极与金属化阴极之间的电压差小于器件设计的阻断电压,器件处于正向阻断状态,此时,n-基区与p基区中部分区域形成空间电荷区;触发时,金属化阳极施加电压上升率大于1kV/ns的触发脉冲,阳极电压迅速升高,n-基区的空间电荷区迅速扩展,但由于n型促离化层的浓度明显大于n-基区,因此n-基区的空间电荷区在扩展到n型促离化层后便无法进一步扩展,而且相同阻断电压下,有促离化层的n-基区宽度小于没有促离化层的n-基区宽度,因此大大减小了器件导通前的空间电荷区长度,使n-基区内电场强度分布更加平坦,更有利于器件导通时碰撞电离前沿的传播;当器件两端电压达到器件最大阻断电压的两到三倍时,J2结处电场强度超过临界击穿场强,器件内部开始发生碰撞电离前沿的传播;由于n型促离化层在空间电荷区扩展到整个n-基区后阻止了空间电荷区的进一步扩展,因此限制了碰撞电离前沿需要穿越的区域宽度,减小碰撞电离前沿穿越的范围。After the n-type ionization promoting layer is added to the FID device in the embodiment of the present invention, the thickness of the n-base region can be greatly reduced under the condition that the blocking voltage of the FID device remains unchanged. In addition, when the FID device is working, the metallized anode is connected to the forward voltage, the voltage difference between the metallized anode and the metallized cathode is less than the blocking voltage of the device design, and the device is in a forward blocking state. At this time, the n-base region It forms a space charge region with some regions in the p base region; when triggering, the metallized anode applies a trigger pulse with a voltage rise rate greater than 1kV/ns, the anode voltage rises rapidly, and the space charge region of the n-base region expands rapidly, but due to n The concentration of the ion-promoting layer is significantly higher than that of the n-base region, so the space charge region of the n-base region cannot be further expanded after it extends to the n-type ion-promoting layer. The width of the n-base region is smaller than the width of the n-base region without the ionization layer, so the length of the space charge region before the device is turned on is greatly reduced, and the electric field intensity distribution in the n-base region is flatter, which is more beneficial to the device. Propagation of the impact ionization front during conduction; when the voltage across the device reaches two to three times the maximum blocking voltage of the device, the electric field strength at the J junction exceeds the critical breakdown field strength, and the propagation of the impact ionization front begins inside the device; Since the n-type ionization-promoting layer prevents the further expansion of the space charge region after the space charge region extends to the entire n-base region, the width of the region that the collision ionization front needs to pass through is limited, and the range of the collision ionization front is reduced.

本实施例中n型促离化层通过限制碰撞电离前沿穿越的区域宽度,可以进一步减少碰撞电离前沿传播的时间,从而提高开通速度。由于器件导通后,碰撞电离前沿传播区域长度减小,因此器件的导通电阻减小,器件两端的残余电压减小,进而降低器件的通态损耗,更有利于器件在重频状态下工作。In this embodiment, the n-type ionization promoting layer can further reduce the propagation time of the collision ionization front by limiting the width of the region traversed by the collision ionization front, thereby increasing the turn-on speed. After the device is turned on, the length of the propagation area of the impact ionization front is reduced, so the on-resistance of the device is reduced, and the residual voltage across the device is reduced, thereby reducing the on-state loss of the device, which is more conducive to the device operating in the repeated frequency state. .

本领域的技术人员容易理解,以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。Those skilled in the art can easily understand that the above are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention, etc., All should be included within the protection scope of the present invention.

Claims (5)

1. A rapid ionization device is characterized by comprising a metalized cathode (1), a highly-doped n + region (2), a cathode side highly-doped p + short-circuit point (3), a p base region (4), an n-base region (5), an n-type ionization promoting layer (6), an anode side highly-doped n + short-circuit point (7), a highly-doped p + region (8) and a metalized anode (9) which are arranged adjacently in sequence;
wherein the highly doped n + region (2) and the cathode side highly doped p + short point (3) are both located between the p base region (4) and the metallization cathode (1), and the highly doped n + region (2) and the cathode side highly doped p + short point (3) have the same thickness and are alternately arranged;
the highly doped p + region (8) and the anode-side highly doped n + short-circuit point (7) are both located between the n-type ionization promoting layer (6) and the metallization anode (9), and the anode-side highly doped n + short-circuit point (7) and the highly doped p + region (8) have the same thickness and are arranged alternately;
the doping concentration in the n-type ionization promoting layer (6) is (1-5) × 10 17 cm -3 (ii) a The thickness of the n-type ionization promoting layer (6) is 25-35 μm; the doping concentration of the highly doped p + region is 10 17 ~10 19 cm -3 The thickness is 20-30 μm; the thickness of the n-base region (5) is 400-800 μm.
2. The method for preparing a rapid ionization device according to claim 1, comprising the steps of:
(1) carrying out impurity diffusion on the cleaned n-type Si wafer to form a PNP structure; then removing the p-shaped region on one side of the substrate by a thinning machine; obtaining a PN structure comprising a p base region (4) and an n-base region (5);
(2) oxidizing the PN structure obtained in the step (1) to form SiO 2 A mask layer formed by removing SiO on the N side by photolithography 2 A layer mask layer, wherein an n-type separation promoting layer (6) is formed on the n-base region side through a diffusion process;
(3) oxidizing the upper surface and the lower surface of the silicon wafer simultaneously to form SiO 2 A layer mask layer; transferring the pattern of the photoetching plate to two electrodes of the Si wafer by double-sided photoetching; etching to remove SiO at the position without photoresist protection 2 A layer; then removing the photoresist on the two electrodes of the Si wafer; then, impurity diffusion is performed to form a highly doped n + -type short-circuit point (7) on the anode side and a highly doped n + -type short-circuit point on the cathode sideDoping an n + region (2);
(4) impurity diffusion is carried out on the two poles of the silicon wafer to form a highly doped p + region (8) on the anode side and a highly doped p + short-circuit point (3) on the cathode side;
(5) rounding the silicon wafer obtained in the step (4), punching an Al sheet into the same size as the rounded Si sheet, and removing an oxide film, organic dirt and contamination impurities on the surfaces of the Si sheet and the Al sheet;
(6) loading the multilayer materials into a mold, arranging each layer of material according to the sequence of graphite-Mo sheets-Al sheets-Si sheets, enabling Si sheet anodes to be opposite to the Al sheets, and then carrying out vacuum sintering on the loaded mold;
(7) evaporating an Al film on the cathode surface of the Si sheet to be used as an electrode; and then annealing to form Si-Al alloy between the cathode surface of the Si sheet and the Al film, thereby obtaining the rapid ionization device.
3. A manufacturing method according to claim 2, wherein the step (2) forms the n-type ionization promoting layer (6) on the n-base region side by a low concentration phosphorus diffusion process.
4. The preparation method according to claim 2, wherein the step (4) is specifically: coating an alcohol source prepared from boron oxide and aluminum nitrate on two electrodes of the silicon wafer, and performing concentrated boron diffusion to form a highly doped p + region (8) on the anode side and a highly doped p + short-circuit point (3) on the cathode side.
5. The production method according to claim 2, wherein the step (6) places the assembled mold in a vacuum sintering furnace having a degree of vacuum of 10 -4 And Pa above, controlling the sintering temperature to be 690-700 ℃, keeping the temperature for 5-30min, cooling the sintering furnace at the speed of 10-20 ℃/min, and naturally cooling in the air after the temperature is reduced to below 400 ℃.
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