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CN112022744B - A hair dye containing functional surfactant, and its preparation method and application method - Google Patents

A hair dye containing functional surfactant, and its preparation method and application method Download PDF

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CN112022744B
CN112022744B CN202010958231.9A CN202010958231A CN112022744B CN 112022744 B CN112022744 B CN 112022744B CN 202010958231 A CN202010958231 A CN 202010958231A CN 112022744 B CN112022744 B CN 112022744B
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agent
cage
emulsifier
oligomeric silsesquioxane
polyhedral oligomeric
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CN112022744A (en
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李乙文
胡俊飞
郭万才
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Sichuan Meilaning Polymer Material Co ltd
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Sichuan University
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/882—Mixing prior to application

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Abstract

The invention discloses a hair dye containing a functional surfactant, which comprises an agent A and an agent B, wherein the agent A mainly comprises the following components: cage-type polyhedral oligomeric silsesquioxane emulsifier, 5, 6-dihydroxyindole, stearic acid, cetyl alcohol, propylene glycol, cysteine, hydrolyzed keratin, D-panthenol, ammonia water and water; the agent B mainly comprises the following components: cage-type polyhedral oligomeric silsesquioxane emulsifier, hydrogen peroxide, stearic acid, cetyl alcohol, propylene glycol and water; the preparation method comprises the following steps: (1) preparation of an agent A; (2) preparation of agent B; the using method comprises the following steps: cleaning white hair, uniformly mixing the agent A and the agent B according to the ratio of 1:1, smearing on the hair, standing in the air for 30min, washing with shampoo, and air drying. The product of the invention has obvious hair dyeing effect and strong coloring capability. The dye is not easy to wash off.

Description

A hair dye containing functional surfactant, and its preparation method and application method
Technical Field
The invention relates to the technical field of hair dyes, in particular to a hair dye containing a functional surfactant and a preparation method and a use method thereof.
Background
Graying of hair occurs not only in the elderly population but also gradually in youthful age. Therefore, the hair dyeing becomes an important way of modern makeup, which not only enables the middle-aged and the elderly people to get back youth again through hair dyeing, but also enables the hair of young people to be colorful. The primary target of action of hair coloring products is the "inanimate" visible portion of the hair, namely the hair shaft and hair fibers. Hair is a complex biological unit, the protein content in hair is 65% -95% according to the type, and the cuticle scale layer on the hair surface has protection effect on hair. The existing hair dye generally contains p-phenylenediamine which is a carcinogenic substance, which causes obstruction to the development of the hair dye.
The hair dye containing 5, 6-dihydroxyindole melanin gradually exposes the horns, and researches show that tyrosine in a human body is catalyzed and oxidized to form an active intermediate 5, 6-dihydroxyindole, and further oxidized to form melanin. The bionic hair dyeing by using the active intermediate in vitro is not only green but also safe as a permanent hair dye, and the hair dye has the same hair dyeing mechanism with the p-phenylenediamine and the derivatives thereof, and acts on the hair keratin fiber.
The Chinese invention with the invention name of 'a hair dye based on phenylboronic acid and a preparation and use method thereof' of the publication No. CN110200823A discloses a hair dye based on phenylboronic acid and a preparation and use method thereof, wherein the hair dye comprises an agent A and an agent B, and the agent A comprises the following components: 5, 6-dihydroxyindole, phenylboronic acid, oleyl alcohol, oleic acid, propylene glycol, isopropanol, sodium dodecyl sulfate, ammonia water and water; the agent B consists of the following components: hydrogen peroxide, oleyl alcohol, oleic acid, propylene glycol, isopropanol, sodium dodecyl sulfate, phosphoric acid and water.
The Chinese invention with the invention name of 'a hair dye based on macromolecular amine and a preparation and use method thereof' in the publication No. CN110151599A discloses a hair dye based on macromolecular amine and a preparation and use method thereof, which comprises an agent A and an agent B, wherein the agent A comprises the following components: 5, 6-dihydroxyindole, cetostearyl alcohol, oleic acid, propylene glycol, isopropanol, sodium dodecyl sulfate, high molecular amine, ammonia water and water; the agent B consists of the following components: hydrogen peroxide, oleyl alcohol, oleic acid, propylene glycol, isopropanol and sodium dodecyl sulfate.
The Chinese invention with the invention name of 'a dendritic macromolecule catalytic hair dye and a preparation and use method thereof' of the publication No. CN110123670A discloses a dendritic macromolecule catalytic hair dye and a preparation and use method thereof, wherein the preparation and use method comprises an agent A and an agent B, and the agent A comprises the following components: 5, 6-dihydroxyindole, cetostearyl alcohol, oleic acid, propylene glycol, isopropanol, sodium dodecyl sulfate, polyethylene diamine dendrimer, ammonia water and water; the agent B consists of the following components: hydrogen peroxide, cetostearyl alcohol, oleic acid, propylene glycol, isopropanol, sodium dodecyl sulfate, a proper amount of phosphoric acid and the balance of water.
Although the three hair dyes have good overall hair dyeing effect, the three hair dyes are oxidized too quickly in the air and cannot rapidly pass through the epidermal scale layer, so that pigments are easy to gather to cause uneven coloring and infirm coloring.
Disclosure of Invention
Aiming at the defects of the prior art, the invention solves the technical problem of firm coloring.
In order to solve the technical problems, the invention adopts the technical scheme that the hair dye containing the functional surfactant comprises 5, 6-dihydroxyindole and the functional surfactant, wherein the functional surfactant is a cage-type polyhedral oligomeric silsesquioxane emulsifier, a single cage-type polyhedral oligomeric silsesquioxane forms a molecular framework by a Si-O-Si structure, and the vertex can be modified for functional diagram design, so that the hair dye has high functional group density and high stability.
Further, the cage-type polyhedral oligomeric silsesquioxane emulsifier can be a cage-type polyhedral oligomeric silsesquioxane anionic emulsifier, a cage-type polyhedral oligomeric silsesquioxane cationic emulsifier or a cage-type polyhedral oligomeric silsesquioxane nonionic emulsifier.
Still further, the molecular formula structure of the cage-type polyhedral oligomeric silsesquioxane emulsifier is as follows:
Figure BDA0002679328890000021
r is-CH 2COOH in the anionic emulsifier, R is-CH 2CH2NH3Cl in the cationic emulsifier, and R is-CH 2CHOHCH2OH in the nonionic emulsifier.
Preferably, the cage-type polyhedral oligomeric silsesquioxane emulsifier comprises an agent A and an agent B, wherein:
the agent A mainly comprises the following components in percentage by mass:
0.1 to 2 percent of cage-type polyhedral oligomeric silsesquioxane emulsifier,
0.5 to 3 percent of 5, 6-dihydroxyindole,
5 to 10 percent of stearic acid,
5 to 10 percent of cetyl alcohol,
4 to 9 percent of propylene glycol,
3 to 6 percent of cysteine,
1 percent of hydrolyzed keratin,
0.5 percent of D-panthenol,
a proper amount of ammonia water is added,
the balance of water is water,
the mass percentage of each component is 100 percent;
the agent B mainly comprises the following components in percentage by mass:
0.1 to 2 percent of cage-type polyhedral oligomeric silsesquioxane emulsifier,
8 to 20 percent of hydrogen peroxide,
5 to 10 percent of stearic acid,
5 to 10 percent of cetyl alcohol,
4 to 9 percent of propylene glycol,
the balance of water is water,
the mass percentage of each component is 100 percent.
The invention also aims to provide a preparation method of the hair dye containing the functionalized surfactant.
Therefore, the technical scheme provided by the invention is a preparation method of the hair dye containing the functionalized surfactant, which comprises the following steps:
(1) the preparation of the agent A comprises the following steps:
a. mixing stearic acid and cetyl alcohol, and heating to 80 ℃ to obtain an oil phase;
b. mixing and heating a cage-type polyhedral oligomeric silsesquioxane emulsifier, propylene glycol, cysteine, hydrolyzed keratin, D-panthenol and water to 80 ℃ to obtain a water phase;
c. adding the water phase into the oil phase, stirring for 5min, and then cooling to room temperature;
d. adding a proper amount of ammonia water to adjust the pH value to be about 9-10, and adding 5, 6-dihydroxyindole to mix to obtain an agent A;
(2) the preparation of the agent B comprises the following steps:
a. mixing stearic acid and cetyl alcohol, and heating to 80 ℃ to obtain an oil phase;
b. mixing and heating a cage-type polyhedral oligomeric silsesquioxane emulsifier, propylene glycol and water to 80 ℃ to obtain a water phase;
c. adding the water phase into the oil phase, stirring for 5min, and then cooling to room temperature;
d. adding a proper amount of hydrogen peroxide and mixing to obtain the agent B.
Still another object of the present invention is to provide a method for using the above-mentioned hair dye containing a functionalized surfactant.
Therefore, the technical scheme provided by the invention is a method for using the hair dye containing the functionalized surfactant, which comprises the following steps: cleaning white hair, uniformly mixing the agent A and the agent B according to the ratio of 1:1, smearing on the hair, standing in the air for 30min, washing with shampoo, and air drying.
Compared with the prior art, the product of the invention has obvious hair dyeing effect and strong coloring capability.
Detailed Description
The following examples are given to further illustrate the embodiments of the present invention, but are not intended to limit the invention.
Example 1
A hair dye containing a functional surfactant comprises an agent A and an agent B, wherein:
the agent A mainly comprises the following components in percentage by mass:
0.1 to 2 percent of cage-type polyhedral oligomeric silsesquioxane emulsifier,
0.5 percent of 5, 6-dihydroxyindole,
10 percent of stearic acid,
5 percent of cetyl alcohol,
9 percent of propylene glycol,
3 percent of cysteine,
1 percent of hydrolyzed keratin,
0.5 percent of D-panthenol,
a proper amount of ammonia water is added,
the balance of water is water,
the mass percentage of each component is 100 percent;
the agent B mainly comprises the following components in percentage by mass:
0.1 percent of cage-type polyhedral oligomeric silsesquioxane emulsifier,
20 percent of hydrogen peroxide,
5 percent of stearic acid,
10 percent of cetyl alcohol,
4 percent of propylene glycol,
the balance of water is water,
the mass percentage of each component is 100 percent.
Example 2
A hair dye containing a functional surfactant comprises an agent A and an agent B, wherein:
the agent A mainly comprises the following components in percentage by mass:
0.1 to 2 percent of cage-type polyhedral oligomeric silsesquioxane emulsifier,
1 percent of 5, 6-dihydroxyindole,
7 percent of stearic acid,
7 percent of cetyl alcohol,
6 percent of propylene glycol,
4 percent of cysteine,
1 percent of hydrolyzed keratin,
0.5 percent of D-panthenol,
a proper amount of ammonia water is added,
the balance of water is water,
the mass percentage of each component is 100 percent;
the agent B mainly comprises the following components in percentage by mass:
1 percent of cage-type polyhedral oligomeric silsesquioxane emulsifier,
10 percent of hydrogen peroxide,
7 percent of stearic acid,
8 percent of cetyl alcohol,
6 percent of propylene glycol,
the balance of water is water,
the mass percentage of each component is 100 percent.
Example 3
A hair dye containing a functional surfactant comprises an agent A and an agent B, wherein:
the agent A mainly comprises the following components in percentage by mass:
0.1 to 2 percent of cage-type polyhedral oligomeric silsesquioxane emulsifier,
3 percent of 5, 6-dihydroxyindole,
5 percent of stearic acid,
10 percent of cetyl alcohol,
4 percent of propylene glycol,
6 percent of cysteine,
1 percent of hydrolyzed keratin,
0.5 percent of D-panthenol,
a proper amount of ammonia water is added,
the balance of water is water,
the mass percentage of each component is 100 percent;
the agent B mainly comprises the following components in percentage by mass:
2 percent of cage-type polyhedral oligomeric silsesquioxane emulsifier,
8 percent of hydrogen peroxide,
10 percent of stearic acid,
the amount of the cetyl alcohol 5 is less than the total amount of the cetyl alcohol,
9 percent of propylene glycol,
the balance of water is water,
the mass percentage of each component is 100 percent.
The preparation method of the above embodiments 1 to 3, comprising the steps of:
(1) the preparation of the agent A comprises the following steps:
a. mixing stearic acid and cetyl alcohol, and heating to 80 ℃ to obtain an oil phase;
b. mixing and heating a cage-type polyhedral oligomeric silsesquioxane emulsifier, propylene glycol, cysteine, hydrolyzed keratin, D-panthenol and water to 80 ℃ to obtain a water phase;
c. adding the water phase into the oil phase, stirring for 5min, and then cooling to room temperature;
d. adding a proper amount of ammonia water to adjust the pH value to be about 9-10, and adding 5, 6-dihydroxyindole to mix to obtain an agent A;
(2) the preparation of the agent B comprises the following steps:
a. mixing stearic acid and cetyl alcohol, and heating to 80 ℃ to obtain an oil phase;
b. mixing and heating a cage-type polyhedral oligomeric silsesquioxane emulsifier, propylene glycol and water to 80 ℃ to obtain a water phase;
c. adding the water phase into the oil phase, stirring for 5min, and then cooling to room temperature;
d. adding a proper amount of hydrogen peroxide and mixing to obtain the agent B.
Comparative example 1
A hair dye comprises an agent A and an agent B, wherein:
the agent A mainly comprises the following components in percentage by mass:
1 percent of sodium dodecyl sulfate,
1 percent of 5, 6-dihydroxyindole,
6 percent of stearic acid,
the content of the cetyl alcohol is 6 percent,
5 percent of propylene glycol,
4 percent of cysteine,
1 percent of hydrolyzed keratin,
0.5 percent of D-panthenol,
a proper amount of ammonia water is added,
the balance of water is water,
the mass percentage of each component is 100 percent;
the agent B mainly comprises the following components in percentage by mass:
1 percent of sodium dodecyl sulfate,
10 percent of hydrogen peroxide,
6 percent of stearic acid,
the content of the cetyl alcohol is 6 percent,
5 percent of propylene glycol,
the balance of water is water,
the mass percentage of each component is 100 percent.
Comparative example 2
A hair dye comprises an agent A and an agent B, wherein:
the agent A comprises the following components in percentage by mass:
1 percent of hexadecyl trimethyl ammonium bromide,
1 percent of 5, 6-dihydroxyindole,
6 percent of stearic acid,
the content of the cetyl alcohol is 6 percent,
5 percent of propylene glycol,
4 percent of cysteine,
1 percent of hydrolyzed keratin,
0.5 percent of D-panthenol,
a proper amount of ammonia water is added,
the balance of water is water,
the mass percentage of each component is 100 percent;
the agent B comprises the following components in percentage by mass:
1 percent of hexadecyl trimethyl ammonium bromide,
10 percent of hydrogen peroxide,
6 percent of stearic acid,
the content of the cetyl alcohol is 6 percent,
5 percent of propylene glycol,
the balance of water is water,
the mass percentage of each component is 100 percent.
The method of using the above examples 1 to 3 and comparative examples 1, 2, comprising the steps of: cleaning white hair, uniformly mixing the agent A and the agent B according to the ratio of 1:1, smearing on the hair, standing in the air for 30min, washing with shampoo, and air drying.
To better illustrate the beneficial effects of the present invention, the following comparison of the product of the present invention with the performance of the comparative example was performed.
Taking the product of the invention and a comparative product to carry out a hair dyeing blackness L value test, using a color difference meter to test for 3 times, taking an average value to obtain, referring to a chromaticity board, and comparing results as shown in the following table 1:
table 1:
test product Hair dyeing blackness L value (chroma) Durability of effect (times)
Example 1 19.3(2-3) 58
Example 2 20.3(2-3) 57
Example 3 19.7(2-3) 55
Comparative example 1 25.6(4) 31
Comparative example 2 24.1(4) 35
The blackness L value of normal black hair is 16-18 (the chroma is 2-3), and the smaller the blackness L value or chroma is, the darker the hair color is; the effect durability was evaluated by the number of times of water-washing resistance by repeating washing and drying, and one cycle was defined as one washing.
As can be seen from Table 1, the product of the present invention has obvious hair dyeing effect and high dyeing capacity. The cage-type polyhedral oligomeric silsesquioxane emulsifier can rapidly disperse 5, 6-dihydroxyindole pigment molecules, more of the 5, 6-dihydroxyindole pigment molecules enter the hair pith, and the hair pith is not easy to wash away after dyeing.
The embodiments of the present invention have been described in detail with reference to the examples, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention.

Claims (4)

1.一种含有功能化表面活性剂的染发剂，包括组分5,6-二羟基吲哚及笼型多面体低聚倍半硅氧烷乳化剂，所述笼型多面体低聚倍半硅氧烷乳化剂为笼型多面体低聚倍半硅氧烷阴离子型乳化剂或笼型多面体低聚倍半硅氧烷阳离子型乳化剂或笼型多面体低聚倍半硅氧烷非离子型乳化剂，其特征在于，所述笼型多面体低聚倍半硅氧烷乳化剂分子式结构为：
Figure FDA0003053285850000011
所述笼型多面体低聚倍半硅氧烷阴离子型乳化剂中R＝-CH2COOH，所述笼型多面体低聚倍半硅氧烷阳离子型乳化剂中R＝-CH2CH2NH3Cl，所述笼型多面体低聚倍半硅氧烷非离子型乳化剂中R＝-CH2CHOHCH2OH。1. A hair dye containing a functionalized surfactant, comprising a component 5,6-dihydroxyindole and a cage-type polyhedral oligomeric silsesquioxane emulsifier, the cage-type polyhedral oligomeric silsesquioxane The alkane emulsifier is a cage polyhedral oligomeric silsesquioxane anionic emulsifier or a cage polyhedral oligomeric silsesquioxane cationic emulsifier or a cage polyhedral oligomeric silsesquioxane nonionic emulsifier, It is characterized in that, the molecular formula structure of the cage-type polyhedral oligomeric silsesquioxane emulsifier is:
Figure FDA0003053285850000011
R=-CH2COOH in the cage-type polyhedral oligomeric silsesquioxane anionic emulsifier, R=-CH2CH2NH3Cl in the cage-type polyhedron oligomeric silsesquioxane cationic emulsifier, and the cage-type polyhedron is low in In the polysilsesquioxane nonionic emulsifier, R=-CH2CHOHCH2OH. 2.根据权利要求1所述的含有功能化表面活性剂的染发剂，其特征在于，所述笼型多面体低聚倍半硅氧烷乳化剂，包括A剂及B剂，其中：2. The hair dye containing functionalized surfactant according to claim 1, wherein the cage-type polyhedral oligomeric silsesquioxane emulsifier comprises agent A and agent B, wherein: 所述A剂主要由以下组分质量百分比组成：The A agent is mainly composed of the following components by mass percentage: 笼型多面体低聚倍半硅氧烷乳化剂0.1-2％，Cage polyhedral oligomeric silsesquioxane emulsifier 0.1-2%, 5,6-二羟基吲哚0.5-3％，5,6-Dihydroxyindole 0.5-3%, 硬脂酸5-10％，Stearic acid 5-10%, 鲸蜡醇5-10％，cetyl alcohol 5-10%, 丙二醇4-9％，Propylene Glycol 4-9%, 半胱氨酸3-6％，Cysteine 3-6%, 水解角蛋白1％，Hydrolyzed Keratin 1%, D-泛醇0.5％，D-panthenol 0.5%, 氨水适量，Amount of ammonia water, 水余量，water balance, 各组分质量百分比合计为100％；The total mass percentage of each component is 100%; 所述B剂主要由以下组分质量百分比组成：The B agent is mainly composed of the following components by mass percentage: 笼型多面体低聚倍半硅氧烷乳化剂0.1-2％，Cage polyhedral oligomeric silsesquioxane emulsifier 0.1-2%, 过氧化氢8％-20％，Hydrogen peroxide 8%-20%, 硬脂酸5-10％，Stearic acid 5-10%, 鲸蜡醇5-10％，cetyl alcohol 5-10%, 丙二醇4-9％，Propylene Glycol 4-9%, 水余量，water balance, 各组分质量百分比合计为100％。The total mass percentage of each component is 100%. 3.根据权利要求2所述的含有功能化表面活性剂的染发剂的制备方法，其特征在于，包括以下步骤：3. the preparation method of the hair dye containing functionalized surfactant according to claim 2, is characterized in that, comprises the following steps: (1)A剂的制备,包括以下分步骤：(1) Preparation of agent A, including the following steps: a.将硬脂酸和鲸蜡醇混合加热到80摄氏度得到油相；a. Mix and heat stearic acid and cetyl alcohol to 80 degrees Celsius to obtain an oil phase; b.将笼型多面体低聚倍半硅氧烷乳化剂、丙二醇、半胱氨酸、水解角蛋白、D-泛醇、水混合加热到80摄氏度得到水相；b. The cage-type polyhedral oligomeric silsesquioxane emulsifier, propylene glycol, cysteine, hydrolyzed keratin, D-panthenol, and water are mixed and heated to 80 degrees Celsius to obtain an aqueous phase; c.将水相加入到油相中搅拌5min，随后降低至室温；c. The water phase was added to the oil phase and stirred for 5min, then lowered to room temperature; d.加入适量氨水调节pH值约为9-10，并加入5,6-二羟基吲哚混合后得到A剂；d. Add an appropriate amount of ammonia water to adjust the pH value to about 9-10, and add 5,6-dihydroxyindole and mix to obtain agent A; (2)B剂的制备，包括以下分步骤：(2) the preparation of B agent, comprises the following steps: a.将硬脂酸和鲸蜡醇混合加热到80摄氏度得到油相；a. Mix and heat stearic acid and cetyl alcohol to 80 degrees Celsius to obtain an oil phase; b.将笼型多面体低聚倍半硅氧烷乳化剂、丙二醇、水混合加热到80摄氏度得到水相；b. The cage polyhedral oligomeric silsesquioxane emulsifier, propylene glycol and water are mixed and heated to 80 degrees Celsius to obtain a water phase; c.将水相加入到油相中搅拌5min，随后降低至室温；c. The water phase was added to the oil phase and stirred for 5min, then lowered to room temperature; d.加入适量过氧化氢混合后得到B剂。d. Add appropriate amount of hydrogen peroxide and mix to obtain agent B. 4.根据权利要求2所述的含有功能化表面活性剂的染发剂的使用方法，其特征在于，包括以下步骤：先将白发清洗后，将A剂、B剂按比例1:1混合均匀地涂抹在头发上，在空气中停留30min后，用洗发露洗涤风干即可。4. the using method of the hair dye containing functionalized surfactant according to claim 2, is characterized in that, comprises the following steps: after first white hair is cleaned, A agent, B agent are mixed uniformly in proportion 1:1 Apply it on the hair, leave it in the air for 30 minutes, wash it with shampoo and air dry it.
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