CN111992018A - Yellow tobacco treatment easy preparation and preparation method thereof - Google Patents
Yellow tobacco treatment easy preparation and preparation method thereof Download PDFInfo
- Publication number
- CN111992018A CN111992018A CN202010851170.6A CN202010851170A CN111992018A CN 111992018 A CN111992018 A CN 111992018A CN 202010851170 A CN202010851170 A CN 202010851170A CN 111992018 A CN111992018 A CN 111992018A
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- CN
- China
- Prior art keywords
- yellow
- easy preparation
- treatment easy
- treatment
- day
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title claims abstract description 63
- 241000208125 Nicotiana Species 0.000 title claims abstract description 38
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 63
- 229910052979 sodium sulfide Inorganic materials 0.000 claims abstract description 26
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000779 smoke Substances 0.000 claims description 46
- 239000007921 spray Substances 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 15
- 238000009472 formulation Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 5
- 229910002651 NO3 Inorganic materials 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 3
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- -1 nitrate ions Chemical class 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/025—Other waste gases from metallurgy plants
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The invention discloses a yellow tobacco treatment easy preparation and a preparation method thereof, wherein every 100 kg of sodium sulfide is dissolved in 200L of water, then sodium hydroxide is added, the dosage of the sodium hydroxide is such that the pH value of the solution is 11.8-12.2, and the yellow tobacco treatment easy preparation is obtained.
Description
Technical Field
The invention relates to the technical field of waste gas treatment, in particular to a yellow tobacco treatment easy-to-prepare method and a preparation method thereof.
Background
The stripping is an indispensable procedure in the electroplating process, most electroplating enterprises adopt the stripping process of taking nitrate as an oxidant at present, and the oxidability of nitrate ions is utilized to dissolve and strip the metal on the plated part, thereby achieving the purpose of stripping the plating layer. When the metal is oxidized to metal ions into solution, nitrate ions are reduced to form NO and N02The gas is discharged into the air to form yellow smoke, which is commonly called yellow smoke. Yellow smoke has direct harm to the health of operators who strip the plating, and more importantly, the high-concentration nitrogen oxide entering the air can cause a series of more extensive harm, such as ozone layer destruction, acid rain formation, dust adhesion and human body respiratory tract entering. Therefore, it is necessary to effectively control the generation of yellow smoke during the deplating process.
The traditional yellow smoke treatment method adopts an air draft tower for spraying and sodium hydroxide is added for treatment, and the method has poor yellow smoke treatment effect and cannot meet the environmental protection requirement, particularly cannot treat yellow smoke with high nitrogen dioxide concentration.
Disclosure of Invention
The invention aims to provide a yellow tobacco treatment easy preparation capable of effectively absorbing yellow tobacco and a preparation method thereof.
In order to achieve the purpose, the invention adopts the technical scheme that:
a preparation method of a yellow tobacco treatment easy preparation comprises the following steps: dissolving every 100 kg of sodium sulfide in 200L of water, and then adding sodium hydroxide, wherein the amount of the sodium hydroxide is such that the pH value of the solution is 11.8-12.2, thus obtaining the yellow tobacco treatment easy preparation.
The application method of the yellow tobacco treatment easy preparation provided by the invention comprises the following steps: collecting yellow smoke generated by deplating into a spray tower, adding a yellow smoke treatment easy preparation into a spray groove of the spray tower, pumping the yellow smoke treatment easy preparation in the spray groove into the spray tower through a water pump, absorbing the yellow smoke by utilizing the sprayed yellow smoke treatment easy preparation, adding the yellow smoke treatment easy preparation for 4 times in a treatment period of one week, adding the yellow smoke treatment easy preparation containing 100 kg of sodium sulfide for the first time, and adding the yellow smoke treatment easy preparation containing 4-6 kg of sodium sulfide for the other three times respectively.
Preferably, in a treatment period of one week, the yellow tobacco treatment easy preparation is added for 4 times on the first day, the third day, the fifth day and the seventh day, the yellow tobacco treatment easy preparation containing 100 kg of sodium sulfide is added for the first time, and the yellow tobacco treatment easy preparation containing 5 kg of sodium sulfide is added for the other three times.
In the prior art, the effect of treating yellow smoke by only adopting sodium hydroxide is not ideal, particularly yellow smoke with high nitrogen dioxide concentration cannot be treated, and when the yellow smoke is treated by only adopting sodium sulfide, the sodium sulfide is easy to generate nitrate precipitate in the use process, so that the nozzle of a spray tower is blocked, and the treatment effect is reduced. By adopting the technical scheme, the yellow smoke treatment easy preparation is prepared from sodium sulfide and sodium hydroxide, the pH value is 11.8-12.0, the yellow smoke generated by nitric acid can be completely removed, the phenomenon of nozzle blockage is avoided, and the environment-friendly requirement is met. The yellow tobacco treatment easy preparation is simple in preparation method, high in yellow tobacco removal efficiency and suitable for popularization and application.
Detailed Description
Example 1
The application method of the yellow tobacco treatment easy preparation comprises the following steps: collecting yellow smoke generated by deplating into a spray tower, adding the yellow smoke treatment easy preparation into a spray groove of the spray tower, pumping the yellow smoke treatment easy preparation in the spray groove into the spray tower through a water pump, absorbing the yellow smoke by utilizing the sprayed yellow smoke treatment easy preparation, adding the yellow smoke treatment easy preparation for 4 times in the first day, the third day, the fifth day and the seventh day respectively in a treatment period of one week,
yellow tobacco treatment easy preparation added on the first day: 100 kg of sodium sulfide and 200L of water were added to a spray tank, followed by sodium hydroxide in such an amount that the solution had a pH of 12.0.
Yellow tobacco treatment easy formulation added on day three: 5 kg of sodium sulfide and 10L of water were added to the spray tank, followed by sodium hydroxide in such an amount that the pH of the solution was 12.0.
Yellow tobacco treatment easy preparation added on the fifth day: 5 kg of sodium sulfide and 10L of water were added to the spray tank, followed by sodium hydroxide in such an amount that the pH of the solution was 12.0.
Yellow tobacco treatment easy preparation added on the seventh day: 5 kg of sodium sulfide and 10L of water were added to the spray tank, followed by sodium hydroxide in such an amount that the pH of the solution was 12.0.
Example 2
The application method of the yellow tobacco treatment easy preparation comprises the following steps: collecting yellow smoke generated by deplating into a spray tower, adding the yellow smoke treatment easy preparation into a spray groove of the spray tower, pumping the yellow smoke treatment easy preparation in the spray groove into the spray tower through a water pump, absorbing the yellow smoke by utilizing the sprayed yellow smoke treatment easy preparation, adding the yellow smoke treatment easy preparation for 4 times in the first day, the second day, the fourth day and the sixth day respectively in a treatment period of one week,
yellow tobacco treatment easy preparation added on the first day: 100 kg of sodium sulfide and 200L of water were added to the spray tank, followed by sodium hydroxide in such an amount that the pH of the solution was 11.8.
Yellow tobacco treatment easy preparation added the next day: 6 kg of sodium sulfide and 12L of water were added to the spray tank, followed by sodium hydroxide, which was used in such an amount that the pH of the solution was 11.8.
Yellow tobacco treatment easy preparation added on the fourth day: 4 kg of sodium sulfide and 8L of water were added to the spray tank, followed by sodium hydroxide, which was used in such an amount that the pH of the solution was 11.8.
Yellow tobacco treatment easy preparation added on the sixth day: 4 kg of sodium sulfide and 8L of water were added to the spray tank, followed by sodium hydroxide, which was used in such an amount that the pH of the solution was 11.8.
Example 3
The application method of the yellow tobacco treatment easy preparation comprises the following steps: collecting yellow smoke generated by deplating into a spray tower, adding the yellow smoke treatment easy preparation into a spray groove of the spray tower, pumping the yellow smoke treatment easy preparation in the spray groove into the spray tower through a water pump, absorbing the yellow smoke by utilizing the sprayed yellow smoke treatment easy preparation, adding the yellow smoke treatment easy preparation for 4 times in the first day, the third day, the fifth day and the seventh day respectively in a treatment period of one week,
yellow tobacco treatment easy preparation added on the first day: 100 kg of sodium sulfide and 200L of water were added to the spray tank, followed by sodium hydroxide in such an amount that the solution had a pH of 12.2.
Yellow tobacco treatment easy formulation added on day three: 6 kg of sodium sulfide and 12L of water were added to the spray tank, followed by sodium hydroxide, which was used in such an amount that the pH of the solution was 12.2.
Yellow tobacco treatment easy preparation added on the fifth day: 5 kg of sodium sulfide and 10L of water were added to the spray tank, followed by sodium hydroxide in such an amount that the pH of the solution was 12.2.
Yellow tobacco treatment easy preparation added on the seventh day: 4 kg of sodium sulfide and 8L of water were added to the spray tank, followed by sodium hydroxide in such an amount that the pH of the solution was 12.2.
Claims (4)
1. A preparation method of a yellow tobacco treatment easy preparation is characterized by comprising the following steps: dissolving every 100 kg of sodium sulfide in 200L of water, and then adding sodium hydroxide, wherein the amount of the sodium hydroxide is such that the pH value of the solution is 11.8-12.2, thus obtaining the yellow tobacco treatment easy preparation.
2. A yellow tobacco treatment susceptible formulation obtained according to the process of claim 1.
3. The method of using the yellow tobacco treatment susceptible formulation of claim 2, wherein: collecting yellow smoke generated by deplating into a spray tower, adding a yellow smoke treatment easy preparation into a spray groove of the spray tower, pumping the yellow smoke treatment easy preparation in the spray groove into the spray tower through a water pump, absorbing the yellow smoke by utilizing the sprayed yellow smoke treatment easy preparation, adding the yellow smoke treatment easy preparation for 4 times in a treatment period of one week, adding the yellow smoke treatment easy preparation containing 100 kg of sodium sulfide for the first time, and adding the yellow smoke treatment easy preparation containing 4-6 kg of sodium sulfide for the other three times respectively.
4. The method of using the yellow tobacco treatment susceptible formulation according to claim 2, characterized in that: in a treatment period of one week, the yellow tobacco treatment easy preparation is added for 4 times on the first day, the third day, the fifth day and the seventh day respectively, the yellow tobacco treatment easy preparation containing 100 kg of sodium sulfide is added for the first time, and the yellow tobacco treatment easy preparation containing 5 kg of sodium sulfide is added for the other three times respectively.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202010851170.6A CN111992018A (en) | 2020-08-21 | 2020-08-21 | Yellow tobacco treatment easy preparation and preparation method thereof |
Applications Claiming Priority (1)
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CN202010851170.6A CN111992018A (en) | 2020-08-21 | 2020-08-21 | Yellow tobacco treatment easy preparation and preparation method thereof |
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CN111992018A true CN111992018A (en) | 2020-11-27 |
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CN202010851170.6A Pending CN111992018A (en) | 2020-08-21 | 2020-08-21 | Yellow tobacco treatment easy preparation and preparation method thereof |
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Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20000042033A (en) * | 1998-12-24 | 2000-07-15 | 이구택 | Improved wet removing method of nitrogen oxide contained in exhaust gas |
CN1287874A (en) * | 2000-06-20 | 2001-03-21 | 陈福利 | Liquid for treating waste gas contg. nitrogen oxides |
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KR101558130B1 (en) * | 2015-02-10 | 2015-10-06 | 엔티베이스 주식회사 | apparatus for treating nitrogen oxide gas with multi-stage gas separation tower for treating NOx gas stage by stage |
CN105169906A (en) * | 2015-09-17 | 2015-12-23 | 昆明理工大学 | Method for injecting sodium sulfide into ozone to denitrate |
CN204952620U (en) * | 2015-07-29 | 2016-01-13 | 浙江富春江环保热电股份有限公司 | Double tower type plasma coupling sodium base absorbs flue gas deep purification device |
CN205760557U (en) * | 2016-05-26 | 2016-12-07 | 苏州仕净环保科技股份有限公司 | A kind of denitration of boiler smoke tower |
CN206762633U (en) * | 2017-05-11 | 2017-12-19 | 苏州宝士杰塑料科技有限公司 | A kind of spiral-flow plate-type chiasma type handles nitrous oxides exhaust gas washing, purifying tower |
CN108380017A (en) * | 2018-02-11 | 2018-08-10 | 浙江天蓝环保工程有限公司 | A kind of alkali kiln gas wet denitration technique that absorbent recycles and device |
-
2020
- 2020-08-21 CN CN202010851170.6A patent/CN111992018A/en active Pending
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20000042033A (en) * | 1998-12-24 | 2000-07-15 | 이구택 | Improved wet removing method of nitrogen oxide contained in exhaust gas |
CN1287874A (en) * | 2000-06-20 | 2001-03-21 | 陈福利 | Liquid for treating waste gas contg. nitrogen oxides |
US20040062697A1 (en) * | 2002-10-01 | 2004-04-01 | Airborne Pollution Control Inc. | Flue gas purification method |
US20140060323A1 (en) * | 2011-03-22 | 2014-03-06 | Keppel Offshore & Marine Technology Centre Pte Ltd | Systems and methods for exhaust gas cleaning and/or ballast water treatment |
KR20130058532A (en) * | 2011-11-25 | 2013-06-04 | 주식회사 뉴프로테크 | Method for removing harmful gases using the conversion reagent of white plume |
CN104906931A (en) * | 2014-05-30 | 2015-09-16 | 黄石华鸿科技有限公司 | Nitrogen oxide waste gas treatment method and treatment system thereof |
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Application publication date: 20201127 |