CN111938214A - Volcanic rock spontaneous heating socks and production process thereof - Google Patents
Volcanic rock spontaneous heating socks and production process thereof Download PDFInfo
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- CN111938214A CN111938214A CN202010694192.6A CN202010694192A CN111938214A CN 111938214 A CN111938214 A CN 111938214A CN 202010694192 A CN202010694192 A CN 202010694192A CN 111938214 A CN111938214 A CN 111938214A
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- fiber
- fibers
- socks
- auxiliary agent
- volcanic rock
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 53
- 239000011435 rock Substances 0.000 title claims abstract description 26
- 230000002269 spontaneous effect Effects 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 239000000835 fiber Substances 0.000 claims abstract description 244
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 51
- 229920000728 polyester Polymers 0.000 claims abstract description 33
- 239000002131 composite material Substances 0.000 claims abstract description 31
- 208000003251 Pruritus Diseases 0.000 claims abstract description 27
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 238000011084 recovery Methods 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 17
- 239000002304 perfume Substances 0.000 claims abstract description 16
- 229920000742 Cotton Polymers 0.000 claims abstract description 14
- 241000700143 Castor fiber Species 0.000 claims abstract description 13
- 244000146553 Ceiba pentandra Species 0.000 claims abstract description 13
- 235000003301 Ceiba pentandra Nutrition 0.000 claims abstract description 13
- 229920001131 Pulp (paper) Polymers 0.000 claims abstract description 13
- 229920002334 Spandex Polymers 0.000 claims abstract description 13
- 241000209140 Triticum Species 0.000 claims abstract description 13
- 235000021307 Triticum Nutrition 0.000 claims abstract description 13
- 239000004759 spandex Substances 0.000 claims abstract description 13
- 239000010902 straw Substances 0.000 claims abstract description 13
- 239000003292 glue Substances 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 8
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 8
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims description 70
- 238000009960 carding Methods 0.000 claims description 30
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 28
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 28
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 28
- 239000011425 bamboo Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 15
- 241000220317 Rosa Species 0.000 claims description 14
- 238000010000 carbonizing Methods 0.000 claims description 14
- 239000002562 thickening agent Substances 0.000 claims description 14
- 238000009941 weaving Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- 238000005520 cutting process Methods 0.000 claims description 8
- 240000004510 Agastache rugosa Species 0.000 claims description 7
- 241000205585 Aquilegia canadensis Species 0.000 claims description 7
- 241000758794 Asarum Species 0.000 claims description 7
- 244000306301 Caesalpinia sappan Species 0.000 claims description 7
- 235000015162 Caesalpinia sappan Nutrition 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 244000132059 Carica parviflora Species 0.000 claims description 7
- 235000014653 Carica parviflora Nutrition 0.000 claims description 7
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 7
- 244000189548 Chrysanthemum x morifolium Species 0.000 claims description 7
- 244000303040 Glycyrrhiza glabra Species 0.000 claims description 7
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims description 7
- 241001482471 Hosta plantaginea Species 0.000 claims description 7
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 7
- 240000005385 Jasminum sambac Species 0.000 claims description 7
- 235000006679 Mentha X verticillata Nutrition 0.000 claims description 7
- 235000002899 Mentha suaveolens Nutrition 0.000 claims description 7
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 7
- 240000002853 Nelumbo nucifera Species 0.000 claims description 7
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims description 7
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims description 7
- 241000219925 Oenothera Species 0.000 claims description 7
- 235000004496 Oenothera biennis Nutrition 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 244000197580 Poria cocos Species 0.000 claims description 7
- 235000008599 Poria cocos Nutrition 0.000 claims description 7
- 241001180876 Saposhnikovia Species 0.000 claims description 7
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 claims description 7
- 102000003929 Transaminases Human genes 0.000 claims description 7
- 108090000340 Transaminases Proteins 0.000 claims description 7
- IPBVNPXQWQGGJP-UHFFFAOYSA-N acetic acid phenyl ester Natural products CC(=O)OC1=CC=CC=C1 IPBVNPXQWQGGJP-UHFFFAOYSA-N 0.000 claims description 7
- 229940037003 alum Drugs 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000006229 carbon black Substances 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 7
- 239000003086 colorant Substances 0.000 claims description 7
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- -1 dimethyl phenyl Chemical group 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 150000002736 metal compounds Chemical class 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- MXXDSLLVYZMTFA-UHFFFAOYSA-N octadecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 MXXDSLLVYZMTFA-UHFFFAOYSA-N 0.000 claims description 7
- 229940049953 phenylacetate Drugs 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 238000009965 tatting Methods 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000004902 Softening Agent Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 230000000536 complexating effect Effects 0.000 claims description 5
- 239000011268 mixed slurry Substances 0.000 claims description 5
- 235000013599 spices Nutrition 0.000 claims description 5
- 238000004804 winding Methods 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000004821 distillation Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000005562 fading Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 2
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 claims description 2
- 235000011477 liquorice Nutrition 0.000 claims description 2
- 244000082204 Phyllostachys viridis Species 0.000 claims 4
- 240000001949 Taraxacum officinale Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 239000003205 fragrance Substances 0.000 abstract description 5
- 230000001877 deodorizing effect Effects 0.000 abstract description 3
- 241001330002 Bambuseae Species 0.000 description 24
- 238000002845 discoloration Methods 0.000 description 10
- 241000245665 Taraxacum Species 0.000 description 6
- 230000032683 aging Effects 0.000 description 6
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 description 5
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 229940010454 licorice Drugs 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 210000003127 knee Anatomy 0.000 description 4
- 210000003423 ankle Anatomy 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 210000002683 foot Anatomy 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 210000004177 elastic tissue Anatomy 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 230000000386 athletic effect Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 210000002414 leg Anatomy 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/30—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of articles, e.g. stockings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/36—Deodorising or perfuming
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2500/00—Materials for shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2500/10—Knitted
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/061—Load-responsive characteristics elastic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Materials Engineering (AREA)
- Undergarments, Swaddling Clothes, Handkerchiefs Or Underwear Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Socks And Pantyhose (AREA)
Abstract
The invention discloses a volcanic spontaneous heating sock which comprises the following components in percentage by weight: 2-4% of an antibacterial finishing agent, 4-8% of a discoloration-preventing auxiliary agent, 2-8% of a perfume auxiliary agent, 3-9% of a damp-clearing itching-relieving auxiliary agent, 9-13% of volcanic rock particles, 20-30% of wood pulp, 6-8% of polyvinyl alcohol fibers, 7-9% of polyvinyl chloride fibers, 6-10% of high-elasticity recovery elastic glue, 10-20% of elastic composite fibers, 10-14% of spandex fibers, 12-16% of polyester fibers, 9-15% of kapok fibers, 11-15% of cotton fibers, 9-11% of wheat straw fibers, 8-10% of castor fibers and 6-12% of antistatic polyester fibers. The invention has the technical effects of self-heating, dampness eliminating, itch eliminating, deodorizing and fragrance dispersing, and better mechanical performance.
Description
Technical Field
The invention relates to the technical field of sock formulas and processes, in particular to a volcanic rock spontaneous heating sock and a production process thereof.
Background
The dress is a general term for the articles for decorating human body. Including apparel, shoes, hats, socks, gloves, scarves, ties, bags, umbrellas, hair accessories, and the like. Ancient people are used for covering up the shy, people have continuously improved knowledge of new things, and the materials and the styles of the clothes are various. Along with the improvement of living standard of people, the requirement on the comfort level of clothes is higher and higher, socks are socks, the length is 5 centimeters to the ankle longest, when the socks are worn, the socks cover the whole ankle, and most of the socks are made of cotton or nylon. Reducing foot and shoe friction; keep the feet warm; absorb the foot sweat. Socks are worn when wearing shoes that wrap the ankle of the entire leg, such as athletic shoes, boots, and leather shoes. The conventional socks have single functional effect, are easy to wear out due to friction with shoes, do not have the effect of self-heating in winter, and do not have the effects of dispelling dampness, relieving itching and deodorizing and dispersing fragrance, and the comfort level of the conventional socks also meets the required requirement.
Disclosure of Invention
The invention aims to provide volcanic self-heating socks and a production process thereof, and aims to solve the problems in the background art.
In order to realize the purpose, the invention provides the following technical scheme: the volcanic self-heating sock comprises the following components in percentage by weight: 2-4% of an antibacterial finishing agent, 4-8% of a discoloration-preventing auxiliary agent, 2-8% of a perfume auxiliary agent, 3-9% of a damp-clearing itching-relieving auxiliary agent, 9-13% of volcanic rock particles, 20-30% of wood pulp, 6-8% of polyvinyl alcohol fibers, 7-9% of polyvinyl chloride fibers, 6-10% of high-elasticity recovery elastic glue, 10-20% of elastic composite fibers, 10-14% of spandex fibers, 12-16% of polyester fibers, 9-15% of kapok fibers, 11-15% of cotton fibers, 9-11% of wheat straw fibers, 8-10% of castor fibers and 6-12% of antistatic polyester fibers.
Preferably, the antibacterial finishing agent comprises 15% of organic metal compound, 5% of liquorice, 3% of mint and 77% of water.
Preferably, the anti-decoloration auxiliary agent is prepared by mixing AES, starch transaminase, dimethyl phenyl acetate, AES mate thickener, polyethylene glycol, ramination, sodium octadecyl benzene sulfonate, sodium oleate, cation agglomerate and water.
Preferably, the perfume auxiliary agent comprises 20 g of folium artemisiae argyi, 20 g of thin lotus, 15 g of wrinkled gianthyssop herb, 15 g of asarum, 15 g of dried orange peel, 20 g of chrysanthemum, 20 g of jasmine, 15 g of honeysuckle, 15 g of hosta plantaginea, 20 g of rose, 20 g of fragrant rose and 10 g of evening primrose.
Preferably, the damp-clearing itch-relieving auxiliary agents comprise 40 g of dandelion, 30 g of sappan wood, 20 g of poria cocos, 20 g of alum, 30 g of vine, 20 g of divaricate saposhnikovia root and 20 g of radix stephaniae tetrandrae.
Preferably, the elastic gel with high elastic recovery degree is prepared from hydroxyl silicone oil, a cross-linking agent, a hydrocarbon solvent, a coloring agent, a catalyst and a thickening agent.
Preferably, the antistatic polyester fiber is prepared by weaving conductive fibers into coral velvet in a tatting manner.
Preferably, the preparation method of the conductive fiber comprises the steps of adopting bamboo pulp fiber, manufacturing the conductive fiber by utilizing the conductive property of carbon black, carbonizing the bamboo pulp fiber, and heating and carbonizing the bamboo pulp fiber at the temperature of 200-280 ℃ in inert atmosphere to ensure that the main chain of the bamboo pulp fiber is mainly carbon atoms, so that the carbonized fiber with good inherent fiber density and tensile strength and conductive property is obtained.
A volcanic rock spontaneous heating socks specifically comprises the following steps:
the method comprises the following steps: crushing volcanic rock particles by using a crusher, crushing the volcanic rock particles into powder, adding the powder into a thermocouple reaction kettle, continuously adding wood pulp, keeping the temperature at 30-50 ℃, and continuously stirring for 1-2 hours;
step two: respectively adding the antibacterial finishing agent, the anti-fading auxiliary agent, the perfume auxiliary agent and the dampness and itch removing auxiliary agent into the thermocouple reaction kettle in the step one, and continuously stirring to prepare mixed slurry;
step three: cutting the antistatic polyester fiber, the elastic composite fiber, the spandex fiber and the polyester fiber into short fibers, uniformly mixing, carrying out coarse carding and fine carding by a carding machine, and then carrying out drawing frame and fine winding to obtain a chemical fiber filament yarn A;
step four: cutting kapok fiber, cotton fiber, wheat straw fiber and castor fiber into short fibers, uniformly mixing, carrying out coarse carding and fine carding by a carding machine, and then carrying out drawing frame and fine complexing to obtain chemical fiber filaments B;
step five: placing the chemical fiber filament A prepared in the third step and the chemical fiber filament B prepared in the third step into the thermocouple reaction kettle in the first step at the same time, adding high-elasticity recovery degree elastic glue, continuously stirring for 1-2 hours, keeping the temperature at 20-30 ℃, taking out the chemical fiber filament A and the chemical fiber filament B, and drying the chemical fiber filament A and the chemical fiber filament B;
step six: twisting the chemical fiber filament B prepared in the fifth step outside the chemical fiber filament A into a coating yarn of the chemical fiber filament A by taking the chemical fiber filament A prepared in the fifth step as a core filament to prepare a composite yarn, and finally weaving the composite yarn into a sock by warp and weft;
step seven: adding into dye solution, rotating at room temperature for 15min, heating to 62 deg.C at a heating rate of 1.1 deg.C/min, maintaining for 10min, heating to 98 deg.C at a heating rate of 0.9 deg.C/min, maintaining for 30min, cooling to 52 deg.C at a cooling rate of 2.5 deg.C/min, draining, washing, fixing at 65 deg.C for 10min, washing, adding softening agent, treating at 40 deg.C for 30min, with the concentration of softening agent being 1.35%;
step eight: and (3) dehydrating the dyed socks, then shaping and preserving heat for 30s by using the sock connecting sleeve plate under the pressure of 0.1Mpa and the temperature of 100 ℃.
Preferably, the thermocouple reaction kettle is a thermocouple reaction kettle provided with a stirrer, a distillation column connected with a water-cooled condenser, a nitrogen inlet and a temperature regulator.
Compared with the prior art, the invention has the beneficial effects that:
1. according to the volcanic self-heating socks and the production process thereof, volcanic particles are crushed by a crusher to be crushed into powder, the powder is added into a thermocouple reaction kettle, wood pulp is continuously added, volcanic particles are adhered to a chemical fiber filament A and a chemical fiber filament B which are woven in a warp-weft mode, then the chemical fiber filament A is used as a core wire, the chemical fiber filament B is twisted outside the chemical fiber filament A to be coated yarns of the chemical fiber filament A, composite yarns are prepared, and finally the composite yarns are woven in the warp-weft mode to be woven into socks, so that the socks have the self-heating effect from outside to inside.
2. The volcanic self-heating socks and the production process thereof are characterized in that an antibacterial finishing agent, an anti-discoloration aid, a spice aid and a dampness and itch removing aid are respectively added into a thermocouple reaction kettle in the first step, mixed slurry is continuously prepared by stirring, antibacterial, discoloration preventing, spice and dampness and itch removing aids are adhered to a chemical fiber filament A and a chemical fiber filament B which are woven in a warp and weft mode, then the chemical fiber filament A is used as a core filament, the chemical fiber filament B is twisted outside the chemical fiber filament A into a coated yarn of the chemical fiber filament A to prepare a composite yarn, finally the composite yarn is woven in a warp and weft mode to form the socks, and the prepared socks have the effects of dampness and itch removing, deodorization and fragrance dispersing and the effect of difficult discoloration.
3. The volcanic self-heating socks and the production process thereof are characterized in that antistatic polyester fibers, elastic composite fibers, spandex fibers and polyester fibers are cut into short fibers, the short fibers are uniformly mixed, coarse carding and fine carding are carried out by a carding machine, and then chemical fiber filaments A are formed by drawing and fine winding; the method comprises the following steps of cutting kapok fiber, cotton fiber, wheat straw fiber and castor fiber into short fibers, uniformly mixing, carding in a carding machine to obtain coarse and fine carding, drawing and fine complexing to obtain chemical fiber filament A, twisting the chemical fiber filament B outside the chemical fiber filament A to obtain coated yarn of the chemical fiber filament A to obtain composite yarn, and finally weaving the composite yarn in a warp-weft manner to obtain the socks, wherein the elastic elasticity, hard object scratch resistance, water washing resistance, ageing resistance and wear resistance of the socks are improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The volcanic self-heating sock comprises the following components in percentage by weight: 2% of antibacterial finishing agent, 4% of anti-discoloration auxiliary agent, 2% of perfume auxiliary agent, 3% of damp-clearing and itch-relieving auxiliary agent, 9% of volcanic rock particles, 20% of wood pulp, 6% of polyvinyl alcohol fiber, 7% of polyvinyl chloride fiber, 6% of high-elasticity recovery degree elastic glue, 10% of elastic composite fiber, 10% of spandex fiber, 12% of polyester fiber, 9% of kapok fiber, 11% of cotton fiber, 9% of wheat straw fiber, 8% of castor fiber and 6% of anti-static polyester fiber.
In this embodiment, the antibacterial finishing agent includes 15% of organic metal compound, 5% of licorice, 3% of mint and 77% of water.
In this embodiment, the anti-decoloring auxiliary agent is prepared by mixing AES, starch transaminase, dimethyl phenyl acetate, an AES partner thickener, polyethylene glycol, ramination, sodium octadecyl benzene sulfonate, sodium oleate, a cationic agglomerate, and water.
In the embodiment, the perfume auxiliary agent comprises 20 g of folium artemisiae argyi, 20 g of thin lotus, 15 g of wrinkled gianthyssop herb, 15 g of asarum, 15 g of dried orange peel, 20 g of chrysanthemum, 20 g of jasmine, 15 g of honeysuckle, 15 g of hosta plantaginea, 20 g of rose, 20 g of fragrant rose and 10 g of evening primrose.
In the embodiment, the damp-clearing itch-relieving auxiliary agents comprise 40 g of dandelion, 30 g of sappan wood, 20 g of poria cocos, 20 g of alum, 30 g of vine, 20 g of divaricate saposhnikovia root and 20 g of radix stephaniae tetrandrae.
In this embodiment, the elastic gel with high elastic recovery degree is prepared from hydroxyl silicone oil, a cross-linking agent, a hydrocarbon solvent, a colorant, a catalyst and a thickener.
In this embodiment, the antistatic polyester fiber is prepared by weaving conductive fibers into coral velvet in a tatting manner.
In the embodiment, the preparation method of the conductive fiber comprises the steps of adopting bamboo pulp fiber, manufacturing the conductive fiber by utilizing the conductive property of carbon black, carbonizing the bamboo pulp fiber, and heating and carbonizing the bamboo pulp fiber at the temperature of 200-280 ℃ in inert atmosphere to enable the main chain of the bamboo pulp fiber to be mainly carbon atoms, so that the carbonized fiber with good inherent fiber density and tensile strength and conductive property is obtained.
Example 2
The volcanic self-heating sock comprises the following components in percentage by weight: 4% of antibacterial finishing agent, 8% of anti-discoloration auxiliary agent, 8% of perfume auxiliary agent, 9% of damp-clearing and itch-relieving auxiliary agent, 13% of volcanic rock particles, 30% of wood pulp, 8% of polyvinyl alcohol fiber, 9% of polyvinyl chloride fiber, 10% of high-elasticity recovery degree elastic glue, 20% of elastic composite fiber, 14% of spandex fiber, 16% of polyester fiber, 15% of kapok fiber, 15% of cotton fiber, 11% of wheat straw fiber, 10% of castor fiber and 12% of anti-static polyester fiber.
In this embodiment, the antibacterial finishing agent includes 15% of organic metal compound, 5% of licorice, 3% of mint and 77% of water.
In this embodiment, the anti-decoloring auxiliary agent is prepared by mixing AES, starch transaminase, dimethyl phenyl acetate, an AES partner thickener, polyethylene glycol, ramination, sodium octadecyl benzene sulfonate, sodium oleate, a cationic agglomerate, and water.
In the embodiment, the perfume auxiliary agent comprises 20 g of folium artemisiae argyi, 20 g of thin lotus, 15 g of wrinkled gianthyssop herb, 15 g of asarum, 15 g of dried orange peel, 20 g of chrysanthemum, 20 g of jasmine, 15 g of honeysuckle, 15 g of hosta plantaginea, 20 g of rose, 20 g of fragrant rose and 10 g of evening primrose.
In the embodiment, the damp-clearing itch-relieving auxiliary agents comprise 40 g of dandelion, 30 g of sappan wood, 20 g of poria cocos, 20 g of alum, 30 g of vine, 20 g of divaricate saposhnikovia root and 20 g of radix stephaniae tetrandrae.
In this embodiment, the elastic gel with high elastic recovery degree is prepared from hydroxyl silicone oil, a cross-linking agent, a hydrocarbon solvent, a colorant, a catalyst and a thickener.
In this embodiment, the antistatic polyester fiber is prepared by weaving conductive fibers into coral velvet in a tatting manner.
In the embodiment, the preparation method of the conductive fiber comprises the steps of adopting bamboo pulp fiber, manufacturing the conductive fiber by utilizing the conductive property of carbon black, carbonizing the bamboo pulp fiber, and heating and carbonizing the bamboo pulp fiber at the temperature of 200-280 ℃ in inert atmosphere to enable the main chain of the bamboo pulp fiber to be mainly carbon atoms, so that the carbonized fiber with good inherent fiber density and tensile strength and conductive property is obtained.
Example 3
The volcanic self-heating sock comprises the following components in percentage by weight: 3% of antibacterial finishing agent, 6% of anti-discoloration auxiliary agent, 5% of perfume auxiliary agent, 6% of damp-clearing and itch-relieving auxiliary agent, 11% of volcanic rock particles, 25% of wood pulp, 7% of polyvinyl alcohol fiber, 8% of polyvinyl chloride fiber, 8% of high-elasticity recovery degree elastic glue, 15% of elastic composite fiber, 12% of spandex fiber, 14% of polyester fiber, 12% of kapok fiber, 13% of cotton fiber, 10% of wheat straw fiber, 9% of castor fiber and 9% of anti-static polyester fiber.
In this embodiment, the antibacterial finishing agent includes 15% of organic metal compound, 5% of licorice, 3% of mint and 77% of water.
In this embodiment, the anti-decoloring auxiliary agent is prepared by mixing AES, starch transaminase, dimethyl phenyl acetate, an AES partner thickener, polyethylene glycol, ramination, sodium octadecyl benzene sulfonate, sodium oleate, a cationic agglomerate, and water.
In the embodiment, the perfume auxiliary agent comprises 20 g of folium artemisiae argyi, 20 g of thin lotus, 15 g of wrinkled gianthyssop herb, 15 g of asarum, 15 g of dried orange peel, 20 g of chrysanthemum, 20 g of jasmine, 15 g of honeysuckle, 15 g of hosta plantaginea, 20 g of rose, 20 g of fragrant rose and 10 g of evening primrose.
In the embodiment, the damp-clearing itch-relieving auxiliary agents comprise 40 g of dandelion, 30 g of sappan wood, 20 g of poria cocos, 20 g of alum, 30 g of vine, 20 g of divaricate saposhnikovia root and 20 g of radix stephaniae tetrandrae.
In this embodiment, the elastic gel with high elastic recovery degree is prepared from hydroxyl silicone oil, a cross-linking agent, a hydrocarbon solvent, a colorant, a catalyst and a thickener.
In this embodiment, the antistatic polyester fiber is prepared by weaving conductive fibers into coral velvet in a tatting manner.
In the embodiment, the preparation method of the conductive fiber comprises the steps of adopting bamboo pulp fiber, manufacturing the conductive fiber by utilizing the conductive property of carbon black, carbonizing the bamboo pulp fiber, and heating and carbonizing the bamboo pulp fiber at the temperature of 200-280 ℃ in inert atmosphere to enable the main chain of the bamboo pulp fiber to be mainly carbon atoms, so that the carbonized fiber with good inherent fiber density and tensile strength and conductive property is obtained.
Example 4
The volcanic self-heating sock comprises the following components in percentage by weight: 3% of antibacterial finishing agent, 6% of anti-discoloration auxiliary agent, 5% of perfume auxiliary agent, 6% of damp-clearing and itch-relieving auxiliary agent, 25% of wood pulp, 7% of polyvinyl alcohol fiber, 8% of polyvinyl chloride fiber, 8% of high-elasticity recovery degree elastic glue, 15% of elastic composite fiber, 12% of spandex fiber, 14% of polyester fiber, 12% of kapok fiber, 13% of cotton fiber, 10% of wheat straw fiber, 9% of castor fiber and 9% of anti-static polyester fiber.
In this embodiment, the antibacterial finishing agent includes 15% of organic metal compound, 5% of licorice, 3% of mint and 77% of water.
In this embodiment, the anti-decoloring auxiliary agent is prepared by mixing AES, starch transaminase, dimethyl phenyl acetate, an AES partner thickener, polyethylene glycol, ramination, sodium octadecyl benzene sulfonate, sodium oleate, a cationic agglomerate, and water.
In the embodiment, the perfume auxiliary agent comprises 20 g of folium artemisiae argyi, 20 g of thin lotus, 15 g of wrinkled gianthyssop herb, 15 g of asarum, 15 g of dried orange peel, 20 g of chrysanthemum, 20 g of jasmine, 15 g of honeysuckle, 15 g of hosta plantaginea, 20 g of rose, 20 g of fragrant rose and 10 g of evening primrose.
In the embodiment, the damp-clearing itch-relieving auxiliary agents comprise 40 g of dandelion, 30 g of sappan wood, 20 g of poria cocos, 20 g of alum, 30 g of vine, 20 g of divaricate saposhnikovia root and 20 g of radix stephaniae tetrandrae.
In this embodiment, the elastic gel with high elastic recovery degree is prepared from hydroxyl silicone oil, a cross-linking agent, a hydrocarbon solvent, a colorant, a catalyst and a thickener.
In this embodiment, the antistatic polyester fiber is prepared by weaving conductive fibers into coral velvet in a tatting manner.
In the embodiment, the preparation method of the conductive fiber comprises the steps of adopting bamboo pulp fiber, manufacturing the conductive fiber by utilizing the conductive property of carbon black, carbonizing the bamboo pulp fiber, and heating and carbonizing the bamboo pulp fiber at the temperature of 200-280 ℃ in inert atmosphere to enable the main chain of the bamboo pulp fiber to be mainly carbon atoms, so that the carbonized fiber with good inherent fiber density and tensile strength and conductive property is obtained.
Example 5
The volcanic self-heating sock comprises the following components in percentage by weight: 11% of volcanic rock particles, 25% of wood pulp, 7% of polyvinyl alcohol fiber, 8% of polyvinyl chloride fiber, 8% of high-elasticity recovery degree elastic glue, 15% of elastic composite fiber, 12% of spandex fiber, 14% of polyester fiber, 12% of kapok fiber, 13% of cotton fiber, 10% of wheat straw fiber, 9% of castor fiber and 9% of antistatic polyester fiber.
In this embodiment, the antibacterial finishing agent includes 15% of organic metal compound, 5% of licorice, 3% of mint and 77% of water.
In this embodiment, the anti-decoloring auxiliary agent is prepared by mixing AES, starch transaminase, dimethyl phenyl acetate, an AES partner thickener, polyethylene glycol, ramination, sodium octadecyl benzene sulfonate, sodium oleate, a cationic agglomerate, and water.
In the embodiment, the perfume auxiliary agent comprises 20 g of folium artemisiae argyi, 20 g of thin lotus, 15 g of wrinkled gianthyssop herb, 15 g of asarum, 15 g of dried orange peel, 20 g of chrysanthemum, 20 g of jasmine, 15 g of honeysuckle, 15 g of hosta plantaginea, 20 g of rose, 20 g of fragrant rose and 10 g of evening primrose.
In the embodiment, the damp-clearing itch-relieving auxiliary agents comprise 40 g of dandelion, 30 g of sappan wood, 20 g of poria cocos, 20 g of alum, 30 g of vine, 20 g of divaricate saposhnikovia root and 20 g of radix stephaniae tetrandrae.
In this embodiment, the elastic gel with high elastic recovery degree is prepared from hydroxyl silicone oil, a cross-linking agent, a hydrocarbon solvent, a colorant, a catalyst and a thickener.
In this embodiment, the antistatic polyester fiber is prepared by weaving conductive fibers into coral velvet in a tatting manner.
In the embodiment, the preparation method of the conductive fiber comprises the steps of adopting bamboo pulp fiber, manufacturing the conductive fiber by utilizing the conductive property of carbon black, carbonizing the bamboo pulp fiber, and heating and carbonizing the bamboo pulp fiber at the temperature of 200-280 ℃ in inert atmosphere to enable the main chain of the bamboo pulp fiber to be mainly carbon atoms, so that the carbonized fiber with good inherent fiber density and tensile strength and conductive property is obtained.
A volcanic rock spontaneous heating socks specifically comprises the following steps:
the method comprises the following steps: crushing volcanic rock particles by using a crusher, crushing the volcanic rock particles into powder, adding the powder into a thermocouple reaction kettle, continuously adding wood pulp, keeping the temperature at 30-50 ℃, and continuously stirring for 1-2 hours;
step two: respectively adding the antibacterial finishing agent, the anti-fading auxiliary agent, the perfume auxiliary agent and the dampness and itch removing auxiliary agent into the thermocouple reaction kettle in the step one, and continuously stirring to prepare mixed slurry;
step three: cutting the antistatic polyester fiber, the elastic composite fiber, the spandex fiber and the polyester fiber into short fibers, uniformly mixing, carrying out coarse carding and fine carding by a carding machine, and then carrying out drawing frame and fine winding to obtain a chemical fiber filament yarn A;
step four: cutting kapok fiber, cotton fiber, wheat straw fiber and castor fiber into short fibers, uniformly mixing, carrying out coarse carding and fine carding by a carding machine, and then carrying out drawing frame and fine complexing to obtain chemical fiber filaments B;
step five: placing the chemical fiber filament A prepared in the third step and the chemical fiber filament B prepared in the third step into the thermocouple reaction kettle in the first step at the same time, adding high-elasticity recovery degree elastic glue, continuously stirring for 1-2 hours, keeping the temperature at 20-30 ℃, taking out the chemical fiber filament A and the chemical fiber filament B, and drying the chemical fiber filament A and the chemical fiber filament B;
step six: twisting the chemical fiber filament B prepared in the fifth step outside the chemical fiber filament A into a coating yarn of the chemical fiber filament A by taking the chemical fiber filament A prepared in the fifth step as a core filament to prepare a composite yarn, and finally weaving the composite yarn into a sock by warp and weft;
step seven: adding into dye solution, rotating at room temperature for 15min, heating to 62 deg.C at a heating rate of 1.1 deg.C/min, maintaining for 10min, heating to 98 deg.C at a heating rate of 0.9 deg.C/min, maintaining for 30min, cooling to 52 deg.C at a cooling rate of 2.5 deg.C/min, draining, washing, fixing at 65 deg.C for 10min, washing, adding softening agent, treating at 40 deg.C for 30min, with the concentration of softening agent being 1.35%;
step eight: and (3) dehydrating the dyed socks, then shaping and preserving heat for 30s by using the sock connecting sleeve plate under the pressure of 0.1Mpa and the temperature of 100 ℃.
In this example, the thermocouple reactor was a thermocouple reactor equipped with a stirrer, a distillation column connected to a water-cooled condenser, a nitrogen inlet, and a temperature regulator.
Experiment one: the test of natural heat temperature was conducted for the socks prepared in example 1, example 2, example 3, example 4 and example 5 and the socks of the prior art, the samples to be tested were placed in the same environment, and the temperature of each sample to be tested was measured by a temperature measuring device at regular time every day, and the test data are shown in the following table:
the experimental results are as follows: the self-heating temperatures of the socks prepared in example 1, example 2 and example 3 were equal and significantly higher than those of the socks prepared in example 4 and example 5 and the socks of the prior art.
Experiment two: tests of elasticity, hard scratch resistance, washing resistance, aging resistance and abrasion resistance were carried out on the socks prepared in example 1, in example 2, in example 3, in example 4 and in example 5 and on the socks of the prior art,
(1) the elasticity is good: abrasion resistance > 800N;
(2) the wear resistance is good: abrasion resistance is less than 150mm3；
(3) Good washing resistance: the knee pad rubber is washed by water at 40 ℃ for 5 times, each time is 80 minutes, and the test is continuously carried out for 3 months, so that the knee pad rubber has no damage, falling, peeling or rotting;
(4) the aging resistance is good: after the test is continuously carried out for 3 months for 1 time in 40 minutes, the knee pad rubber has no crack phenomenon and no aging phenomenon;
(5) hard object scratch resistance: the knee pad rubber is subjected to scratch resistance test by adopting a conventional means, and is scratched for more than hundred times without scratches and damage.
The experimental data are shown in the following table:
the experimental results are as follows: the elasticity, scuff resistance, wash resistance, aging resistance and abrasion resistance of the socks prepared for example 1, for example 2, for example 3, for example 4 and for example 5 are significantly higher than those of the socks of the prior art.
Experiment three: tests for the damp and itch repellent, deodorant fragrance and fade resistance days duration were conducted for example 1, for example 2, for example 3, for example 4, for the socks prepared in example 5 and for the socks of the prior art, as shown in the following table:
the experimental results are as follows: the damp-clearing, itching-relieving, deodorizing, fragrance-dissipating and fade-resistant properties of example 1, example 2, example 3 and the socks prepared in example 4 were significantly higher than those of the socks prepared in example 5 and the socks of the prior art.
The invention has the beneficial effects that: according to the volcanic self-heating socks and the production process thereof, volcanic particles are crushed by a crusher to be crushed into powder, the powder is added into a thermocouple reaction kettle, wood pulp is continuously added, volcanic particles are adhered to a chemical fiber filament A and a chemical fiber filament B which are woven in a warp-weft mode, then the chemical fiber filament A is used as a core wire, the chemical fiber filament B is twisted outside the chemical fiber filament A to be coated yarns of the chemical fiber filament A to be prepared into composite yarns, and finally the composite yarns are woven in the warp-weft mode to be woven into socks, so that the socks have the self-heating effect from outside to inside. The volcanic self-heating socks and the production process thereof are characterized in that an antibacterial finishing agent, an anti-discoloration aid, a spice aid and a dampness and itch removing aid are respectively added into a thermocouple reaction kettle in the first step, mixed slurry is continuously prepared by stirring, antibacterial, discoloration preventing, spice and dampness and itch removing aids are adhered to a chemical fiber filament A and a chemical fiber filament B which are woven in a warp and weft mode, then the chemical fiber filament A is used as a core filament, the chemical fiber filament B is twisted outside the chemical fiber filament A into a coated yarn of the chemical fiber filament A to prepare a composite yarn, finally the composite yarn is woven in a warp and weft mode to form the socks, and the prepared socks have the effects of dampness and itch removing, deodorization and fragrance dispersing and the effect of difficult discoloration. The volcanic self-heating socks and the production process thereof are characterized in that antistatic polyester fibers, elastic composite fibers, spandex fibers and polyester fibers are cut into short fibers, the short fibers are uniformly mixed, coarse carding and fine carding are carried out by a carding machine, and then chemical fiber filaments A are formed by drawing and fine winding; the method comprises the following steps of cutting kapok fiber, cotton fiber, wheat straw fiber and castor fiber into short fibers, uniformly mixing, carding in a carding machine to obtain coarse and fine carding, drawing and fine complexing to obtain chemical fiber filament A, twisting the chemical fiber filament B outside the chemical fiber filament A to obtain coated yarn of the chemical fiber filament A to obtain composite yarn, and finally weaving the composite yarn in a warp-weft manner to obtain the socks, wherein the elastic elasticity, hard object scratch resistance, water washing resistance, ageing resistance and wear resistance of the socks are improved.
It will be apparent to those skilled in the art that various changes and modifications may be made in the present invention without departing from the spirit and scope of the invention. Thus, if such modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include such modifications and variations.
Claims (10)
1. A volcanic rock spontaneous heating socks which characterized in that: comprises the following components in percentage by weight: 2-4% of an antibacterial finishing agent, 4-8% of a discoloration-preventing auxiliary agent, 2-8% of a perfume auxiliary agent, 3-9% of a damp-clearing itching-relieving auxiliary agent, 9-13% of volcanic rock particles, 20-30% of wood pulp, 6-8% of polyvinyl alcohol fibers, 7-9% of polyvinyl chloride fibers, 6-10% of high-elasticity recovery elastic glue, 10-20% of elastic composite fibers, 10-14% of spandex fibers, 12-16% of polyester fibers, 9-15% of kapok fibers, 11-15% of cotton fibers, 9-11% of wheat straw fibers, 8-10% of castor fibers and 6-12% of antistatic polyester fibers.
2. The volcanic rock spontaneous heating socks of claim 1, wherein: the antibacterial finishing agent comprises 15% of organic metal compound, 5% of liquorice, 3% of mint and 77% of water.
3. The volcanic rock spontaneous heating socks of claim 1, wherein: the anti-decoloration auxiliary agent is prepared by mixing AES, starch transaminase, dimethyl phenyl acetate, AES mate thickener, polyethylene glycol, ramination, sodium octadecyl benzene sulfonate, sodium oleate, cation agglomerate and water.
4. The volcanic rock spontaneous heating socks of claim 1, wherein: the spice auxiliary agent comprises 20 g of folium artemisiae argyi, 20 g of thin lotus, 15 g of wrinkled gianthyssop herb, 15 g of asarum, 15 g of dried orange peel, 20 g of chrysanthemum, 20 g of jasmine, 15 g of honeysuckle, 15 g of hosta plantaginea, 20 g of rose, 20 g of fragrant rose and 10 g of evening primrose.
5. The volcanic rock spontaneous heating socks of claim 1, wherein: 40 g of damp-clearing itch-relieving auxiliary agent dandelion, 30 g of sappan wood, 20 g of poria cocos, 20 g of alum, 30 g of vine, 20 g of divaricate saposhnikovia root and 20 g of radix stephaniae tetrandrae.
6. The volcanic rock spontaneous heating socks of claim 1, wherein: the elastic rubber with the high elastic recovery degree is prepared from hydroxyl silicone oil, a cross-linking agent, a hydrocarbon solvent, a coloring agent, a catalyst and a thickening agent.
7. The volcanic rock spontaneous heating socks of claim 1, wherein: the antistatic polyester fiber is prepared by weaving conductive fibers into coral velvet in a tatting mode.
8. The volcanic rock spontaneous heating socks of claim 1, wherein: the preparation method of the conductive fiber comprises the steps of adopting bamboo pulp fiber, manufacturing the conductive fiber by utilizing the conductive property of carbon black, carbonizing the bamboo pulp fiber, and heating and carbonizing the bamboo pulp fiber at the temperature of 200-280 ℃ in inert atmosphere to ensure that the main chain of the bamboo pulp fiber is mainly carbon atoms, so that the carbonized fiber with good inherent fiber density and tensile strength and conductive property is obtained.
9. A production process of volcanic spontaneous heating socks is characterized in that: the method specifically comprises the following steps:
the method comprises the following steps: crushing volcanic rock particles by using a crusher, crushing the volcanic rock particles into powder, adding the powder into a thermocouple reaction kettle, continuously adding wood pulp, keeping the temperature at 30-50 ℃, and continuously stirring for 1-2 hours;
step two: respectively adding the antibacterial finishing agent, the anti-fading auxiliary agent, the perfume auxiliary agent and the dampness and itch removing auxiliary agent into the thermocouple reaction kettle in the step one, and continuously stirring to prepare mixed slurry;
step three: cutting the antistatic polyester fiber, the elastic composite fiber, the spandex fiber and the polyester fiber into short fibers, uniformly mixing, carrying out coarse carding and fine carding by a carding machine, and then carrying out drawing frame and fine winding to obtain a chemical fiber filament yarn A;
step four: cutting kapok fiber, cotton fiber, wheat straw fiber and castor fiber into short fibers, uniformly mixing, carrying out coarse carding and fine carding by a carding machine, and then carrying out drawing frame and fine complexing to obtain chemical fiber filaments B;
step five: placing the chemical fiber filament A prepared in the third step and the chemical fiber filament B prepared in the third step into the thermocouple reaction kettle in the first step at the same time, adding high-elasticity recovery degree elastic glue, continuously stirring for 1-2 hours, keeping the temperature at 20-30 ℃, taking out the chemical fiber filament A and the chemical fiber filament B, and drying the chemical fiber filament A and the chemical fiber filament B;
step six: twisting the chemical fiber filament B prepared in the fifth step outside the chemical fiber filament A into a coating yarn of the chemical fiber filament A by taking the chemical fiber filament A prepared in the fifth step as a core filament to prepare a composite yarn, and finally weaving the composite yarn into a sock by warp and weft;
step seven: adding into dye solution, rotating at room temperature for 15min, heating to 62 deg.C at a heating rate of 1.1 deg.C/min, maintaining for 10min, heating to 98 deg.C at a heating rate of 0.9 deg.C/min, maintaining for 30min, cooling to 52 deg.C at a cooling rate of 2.5 deg.C/min, draining, washing, fixing at 65 deg.C for 10min, washing, adding softening agent, treating at 40 deg.C for 30min, with the concentration of softening agent being 1.35%;
step eight: and (3) dehydrating the dyed socks, then shaping and preserving heat for 30s by using the sock connecting sleeve plate under the pressure of 0.1Mpa and the temperature of 100 ℃.
10. The production process of the volcanic spontaneous heating socks as claimed in claim 9, wherein the production process comprises the following steps: the thermocouple reaction kettle is provided with a stirrer, a distillation column connected with a water-cooled condenser, a nitrogen inlet and a thermocouple reaction kettle connected with a temperature regulator.
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| CN113201932A (en) * | 2021-04-28 | 2021-08-03 | 常州市美尔娜服饰有限公司 | Volcanic fabric |
| CN117144535A (en) * | 2023-09-01 | 2023-12-01 | 高梵(浙江)信息技术有限公司 | A kind of volcanic rock antibacterial warm fabric based on down jacket and its preparation method |
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