CN1119317A - Label continuum and its manufacturing method - Google Patents
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- CN1119317A CN1119317A CN 95116857 CN95116857A CN1119317A CN 1119317 A CN1119317 A CN 1119317A CN 95116857 CN95116857 CN 95116857 CN 95116857 A CN95116857 A CN 95116857A CN 1119317 A CN1119317 A CN 1119317A
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Abstract
本发明涉及一种标签连续体,它包括:长条状标签基材、在标签基材的里面形成的粘结剂层、在标签基材的表面侧上形成的热敏显色层、和标签基材卷叠起来时在与上述粘结剂层相对置的标签基材的表面侧上形成的剥离层。该标签连续体的制造方法包括:准备至少其中一侧的表面具有剥离性的工程薄板,并在工程薄板具有剥离性的表面上形成粘结剂层的步骤1,准备粘结剂层转移后即具备可粘结的里面的长条状标签基材,并使该标签基材的里面与工程薄板的粘结剂层重合的步骤2,在标签基材的表面形成剥离层的步骤3,从粘结剂表面剥离工程薄板的步骤4和卷叠标签基材的步骤5。The present invention relates to a label continuum, which includes: a strip-shaped label substrate, an adhesive layer formed inside the label substrate, a heat-sensitive color-developing layer formed on the surface side of the label substrate, and a label The peeling layer formed on the surface side of the label substrate facing the above-mentioned adhesive layer when the substrate is rolled up. The manufacturing method of the label continuum includes: preparing an engineering sheet with peeling properties on at least one side of the surface, and forming an adhesive layer on the surface of the engineering sheet with peeling properties. Step 1, preparing the adhesive layer after transfer Step 2 of forming a strip-shaped label base material with a bondable inner side and overlapping the inside of the label base material with the adhesive layer of the engineering sheet, and step 3 of forming a peeling layer on the surface of the label base material, from the adhesive Step 4 of Bond Surface Peeling Engineered Sheet and Step 5 of Rolling Label Substrate.
Description
本发明涉及许多个标签连续起来形成的标签连续体及其制造方法,尤其涉及,例如作为价格标码和条形码标签等适用的所谓没有剥离纸的非分离(ノソセパ)型连续体及其制造方法。The present invention relates to a label continuum formed by a plurality of continuous labels and a manufacturing method thereof, and more particularly to a so-called non-separation (nososepa) type continuum without release paper, which is suitable for price tags and barcode labels, and a manufacturing method thereof.
以前,称之为所谓非分离型的没有剥离纸的标签,常常是在具有耐热性基材的里面形成由延迟胶粘型(テイレ一トタツク型)的热粘结性粘结剂组成的压敏性粘结剂层。In the past, the so-called non-separation type labels without release paper often formed a pressure-delayed adhesive type (Tylay-totaku-type) heat-adhesive adhesive on the inside of a heat-resistant substrate. Sensitive adhesive layer.
形成这种所谓热活性型的压敏型粘结剂层的情况下,即使根本不使用剥离纸,卷叠起来后也可以利用。也就是说,在加热使粘结性粘结剂熔融从而赋予压敏性前,由于不具有粘结性,因而即使卷成圆筒状也不会粘结。然而,以前的这种非分离型标签,制造设备必须是大型的,设备投资高,而且为了使热粘结性粘结剂活化而必须加热,因而作为标签的基材,必须选择耐热性优良的纸等,例如像,极薄带状的标签连续体那样的耐热性小的物质是不能满足要求的。In the case of forming such a so-called heat-activated pressure-sensitive adhesive layer, even if no release paper is used at all, it can be used after being rolled up. That is, it does not have adhesiveness until the adhesive adhesive is melted by heating to impart pressure sensitivity, so that it does not stick even if it is rolled into a cylindrical shape. However, the conventional non-separable label requires large-scale manufacturing equipment, high equipment investment, and heating is required to activate the thermal adhesive adhesive. Therefore, it is necessary to select a label with excellent heat resistance as the base material of the label. Paper, etc., for example, materials with low heat resistance such as ultra-thin strip-shaped label continuums cannot meet the requirements.
此外,还必须选择不受形成粘结层的粘结剂中所含成分影响的那些物质,因此,其选择范围受到很大限制。In addition, it is also necessary to select those substances which are not affected by the components contained in the adhesive forming the adhesive layer, and therefore, the range of selection thereof is greatly limited.
因此,本发明的目的是提供一种可扩大标签基材和粘结剂层的选择范围,并可多品种小批量生产的标签连续体及其制造方法。Therefore, the object of the present invention is to provide a label continuous body and a manufacturing method thereof that can expand the selection range of label substrates and adhesive layers, and can produce multiple varieties in small batches.
第1个发明是一种标签连续体,它包括长条状标签基材和,在标签的基材里面形成的粘结剂层和,在标签基材的表面侧形成的热敏显色层和,当标签基材卷叠起来时,在与上述粘结剂层侧相对的标签基材的表面上形成的剥离层。第1个发明中,标签基材,由于在与粘结剂的相反侧的表面上形成热敏显色层,因而通过加热即可显色。按照第1个发明,由于在标签基材的里面形成粘结剂层,因此常温下可在标签基材的表面上形成粘结剂层。所以,选择标签基材时,即使是耐热性较小的极薄的带,也可满足要求,而且,由于原来在形成粘结剂层之前处于溶解状态的粘结剂的溶剂等在转移之前就除去了,因此,与标签基材的性质没关系,由此可以扩大形成粘结剂层的粘结剂的选择范围。尤其是,还可以选择热纸等的热显色这类材料作为标签基材,而且对于通过需要加热的这类复制箔片来印字的打印机等及所有打印机都可以适用。The first invention is a label continuum comprising a strip-shaped label base material, an adhesive layer formed inside the label base material, a heat-sensitive color-developing layer formed on the surface side of the label base material, and , When the label substrate is rolled up, the release layer is formed on the surface of the label substrate opposite to the above-mentioned adhesive layer side. In the first invention, since the label substrate has a heat-sensitive color-developing layer formed on the surface opposite to the adhesive, it can develop color by heating. According to the first invention, since the adhesive layer is formed inside the label base material, the adhesive layer can be formed on the surface of the label base material at normal temperature. Therefore, when selecting a label base material, even an extremely thin tape with low heat resistance can meet the requirements. Moreover, since the solvent of the adhesive that was in a dissolved state before the adhesive layer was originally formed is It is removed, therefore, regardless of the properties of the label substrate, thereby expanding the range of options for the adhesive forming the adhesive layer. In particular, thermochromic materials such as thermal paper can also be selected as the label base material, and it is applicable to printers and other printers that print on such duplication foils that require heating.
第2个发明是一种标签连续体,它包括长条状标签基材和,在标签基材的里面形成的粘结剂层和,在标签基材的表面侧的热敏显色层的表面上形成的印刷层和,标签基材卷叠时,在与粘结剂层相对的标签基材的表面侧形成的剥离层。第2个发明中,标签基材,由于在与粘结剂的相反侧的表面上形成热敏显色层,因而通过加热即可显色。按照第2个发明,由于在标签基材的里面形成粘结剂层,因而常温下可在标签基材的表面上形成粘结剂层。所以,选择标签基材时,即使是耐热性较小的极薄的带,也可满足要求,而且,由于原来在形成粘结剂层之前处于溶解状态的粘结剂的溶剂等在转移之前就除去了,因此,与标签基材的性质没有关系由此可以扩大形成粘结剂层的粘结剂的选择范围。尤其是,还可以选择像热纸等可热显色的这类材料作为标签基材,而且对于通过需要加热的这类复制箔片来印字的打印机等,及所有打印机都可适用。The second invention is a label continuum comprising a strip-shaped label base material, an adhesive layer formed inside the label base material, and a heat-sensitive color-developing layer on the surface side of the label base material. The printing layer formed on the adhesive layer and the peeling layer formed on the surface side of the label substrate opposite to the adhesive layer when the label substrate is rolled. In the second invention, since the label base material has a thermosensitive color-developing layer formed on the surface opposite to the adhesive, it can develop color by heating. According to the second invention, since the adhesive layer is formed inside the label base material, the adhesive layer can be formed on the surface of the label base material at normal temperature. Therefore, when selecting a label base material, even an extremely thin tape with low heat resistance can meet the requirements. Moreover, since the solvent of the adhesive that was in a dissolved state before the adhesive layer was originally formed is It is removed, therefore, regardless of the nature of the label substrate and thus the choice of adhesives for forming the adhesive layer can be expanded. In particular, heat-developable materials such as thermal paper can also be selected as label substrates, and it is applicable to printers that print on such duplicating foils that require heating, etc., and all printers.
在第1个发明或第2个发明中,剥离层也可以通过印刷、涂覆剥离剂形成。本发明中,在标签基材的表面侧形成的剥离层和在标签基材的里面侧形成的粘结剂层是以对置呈虚附着状态卷叠标签基材,因此可以开卷。按照该发明,可以在标签基材的表面或印刷层的表面印刷、涂覆剥离剂,形成剥离层,因此即使是在标签基材的里面形成的粘结剂层和在其表面上形成的剥离层对置呈虚附着状态地卷叠起来,也可开卷,可以将一张一张的标签从标签连续体上切断加以利用。In the first invention or the second invention, the release layer may be formed by printing or applying a release agent. In the present invention, the release layer formed on the front side of the label base material and the adhesive layer formed on the back side of the label base material are opposed to each other and the label base material is rolled up in a virtual adhesion state, so that unwinding is possible. According to this invention, a release agent can be printed and coated on the surface of the label substrate or the surface of the printed layer to form a release layer. The layers are stacked in a falsely attached state, and the roll can also be unrolled, and the labels can be cut off from the label continuum one by one for use.
在第1个发明或第2个发明中,剥离层也可以是由剥离性优良的薄膜或薄片层叠而形成。在本发明中,由于标签基材的剥离层侧和粘结剂层侧是以对置呈虚附着状态卷叠标签基材,因此被卷叠的基材可以开卷。按照本发明,由于可在标签基材的表面层叠剥离性优良的薄膜或薄片从而形成剥离层,因而即使在标签基材的表面侧形成的剥离层和在里面侧形成的粘结剂层是以对置呈虚附着状态卷叠标签基材,也可以开卷,可以从标签连续体上一张张地切下标签后再利用。In the first invention or the second invention, the release layer may be formed by laminating films or sheets excellent in release properties. In the present invention, since the release layer side and the adhesive layer side of the label base material are facing each other and the label base material is rolled up in a virtual adhesion state, the rolled up base material can be unwound. According to the present invention, since the release layer can be formed by laminating a film or sheet with excellent peelability on the surface of the label base material, even if the release layer formed on the front side of the label base material and the adhesive layer formed on the back side are separated The label base material can be rolled up in a falsely attached state, and can also be unrolled, and the labels can be cut from the label continuum one by one and reused.
第3个发明是一种标签连续体,它包括长条状标签基材和,在标签基材的里面形成的粘结剂层和,在标签基材的表面侧形成的热敏显色层和,标签基材卷叠时,在与粘结剂层侧相对的标签基材的表面侧上形成的剥离性优良的印刷层。在第3个发明中,标签基材,由于在与粘结剂层的反对侧的表面上形成热敏显色层,因而通过加热即可显色。按照第3个发明,由于在标签基材的里面形成粘结剂层,因而常温下可在标签基材的表面上形成粘结剂层。所以,选择标签基材时,即使是耐热性小的极薄带,也可以满足要求,而且,由于原来在形成粘结剂层之前处于溶解状态的粘结剂的溶剂等在转移之前就除去了,因此与标签基材的性质没有关系,由此可以扩大形成粘结剂层的粘结剂的选择范围。尤其是,还可以选择像热纸等可热显色的这类材料,而且对于通过需要加热的这类复制箔片来印字的打印机等,及所有打印机都可适用。The third invention is a label continuum comprising a long label base material, an adhesive layer formed inside the label base material, a heat-sensitive color-developing layer formed on the surface side of the label base material, and , When the label substrate is rolled up, a printed layer with excellent peelability is formed on the surface side of the label substrate opposite to the adhesive layer side. In the third invention, since the label substrate has a heat-sensitive color-developing layer formed on the surface opposite to the adhesive layer, it can develop color by heating. According to the third invention, since the adhesive layer is formed inside the label base material, the adhesive layer can be formed on the surface of the label base material at normal temperature. Therefore, when selecting a label base material, even an extremely thin tape with low heat resistance can meet the requirements. Moreover, since the solvent of the adhesive that is in a dissolved state before the adhesive layer is formed is removed before transfer. Therefore, it has nothing to do with the properties of the label base material, thereby expanding the selection range of the adhesive for forming the adhesive layer. In particular, materials such as thermal paper that can develop color can also be selected, and it is suitable for printers that print on such replica foils that require heating, etc., and all printers.
在第3个发明中,印刷层也可以通过印刷,涂覆印刷油墨而形成。本发明中,在标签基材的表面侧形成的剥离性优良的印刷层侧和在标签基材的里面侧形成的粘结剂层以对置呈虚附着状态卷叠标签基材,因而可以开卷。按照本发明,由于在标签基材的表面上形成剥离性优良的印刷层,因而即使在标签基材的里面形成的粘结剂层和在其表面上形成的印刷层是以对置呈虚附着状态卷叠标签基材,也可以开卷,可以从标签连续体上一张一张地切成标签后加以利用。In the third invention, the printing layer can also be formed by printing and applying printing ink. In the present invention, the printed layer side formed on the front side of the label base material with excellent peelability and the adhesive layer formed on the back side of the label base material face each other in a falsely adhered state, and the label base material can be unwound. . According to the present invention, since the printed layer with excellent peelability is formed on the surface of the label base material, even if the adhesive layer formed on the inside of the label base material and the printed layer formed on the surface are opposed to each other, they are virtually attached. The label base material can be unrolled in the rolled state, and can be cut into labels one by one from the label continuous body and used.
在第3个发明中,剥离层也可以与印刷层一起,在标签基材卷叠时,在与粘结剂层侧相对的标签基材的表面侧形成。本发明中,由于在标签的基材的表面上形成印刷层,且与印刷层一起在标签的基材表面上形成剥离层,因此被卷叠的标签基材可以开卷。按照本发明,由于在标签的表面形成印刷层,而且在标签基材的表面形成剥离性优良的剥离层,因此即使在标签基材的表面侧形成的印刷层和/或剥离层和在其里面侧上形成的粘结剂层是以对置呈虚附着状态卷叠标签基材,也可以开卷,并可从标签连续体上一张一张地切断下来加以利用。In the third invention, the release layer may be formed together with the printing layer on the surface side of the label base material opposite to the adhesive layer side when the label base material is rolled up. In the present invention, since the printed layer is formed on the surface of the label base material and the peeling layer is formed on the surface of the label base material together with the printed layer, the rolled label base material can be unwound. According to the present invention, since the printed layer is formed on the surface of the label, and the release layer with excellent releasability is formed on the surface of the label base material, even if the printed layer and/or release layer formed on the surface side of the label base material and the inside thereof The adhesive layer formed on the side can be rolled up with the label base material in a state of facing each other in a virtual adhesion state, and can also be unrolled, and can be cut off one by one from the continuous label body for use.
第4个发明是一种标签连续体,它包括长条状标签基材和,转移到标签基材的里面而形成的粘结剂层和,在标签基材的里面侧形成的剥离层;剥离层侧和上述粘结剂层对置呈虚附着状态地将标签基材卷叠而成标签连续体。第4个发明中,由于在标签基材的表面侧形成的剥离层侧和在标签基材的里面侧形成的粘结剂层是以对置呈虚附着状态卷叠标签基材,因而可以开卷。按照第4个发明,由天在标签基材的里面形成粘结剂层,因而常温下可在标签基材的表面上形成粘结剂层。所以,选择标签基材时,即使是耐热性小的极薄带,也可以满足要求,而且,由于原来在形成粘结剂层之前处于溶解状态的粘结剂的溶剂等在转移之前就被除去了,因而与标签基材的性质没有关系,由此可以扩大形成粘结剂层的粘结剂的选择范围。尤其是,还可以选择像热纸等可热显色的这类材料,而且对于通过需要加热的这类复制箔片来印字的打印机等,及所有打印机等也都可适用。The fourth invention is a label continuum comprising a strip-shaped label base material, an adhesive layer transferred to the inside of the label base material, and a release layer formed on the inner side of the label base material; The layer side and the above-mentioned adhesive layer are opposed to each other, and the label base material is rolled up in a virtual adhesion state to form a continuous label body. In the fourth invention, since the release layer formed on the front side of the label base material and the adhesive layer formed on the back side of the label base material are stacked in a falsely attached state facing each other, unwinding is possible. . According to the fourth invention, since the adhesive layer is formed on the inside of the label base material, the adhesive layer can be formed on the surface of the label base material at normal temperature. Therefore, when selecting a label base material, even an extremely thin tape with low heat resistance can meet the requirements. Moreover, since the solvent of the adhesive that is in a dissolved state before the adhesive layer is formed, it is removed before transfer. Since it is removed, it is not related to the properties of the label base material, thereby expanding the selection range of the adhesive for forming the adhesive layer. In particular, materials such as thermal paper that can develop color can also be selected, and it is also applicable to printers and the like that print on such duplicating foils that require heating, and all printers and the like.
在第4个发明中,也可以在标签基材的表面形成印刷层,在印刷层的表面形成剥离层。本发明中,由于在标签基材的表面形成印刷层,在印刷层的表面形成剥离层,因而被卷叠起来的标签基材可以开卷。按照本发明,由于在标签基材的表面形成印刷层,在印刷层的表面形成剥离层,因而即使在标签基材的里面形成的粘结层和在其表面上形成的剥离层是以对置呈虚附着状态卷叠标签基材,也可以开卷,可以从标签连续体上一张一张地切成标签后加以利用。In the fourth invention, a printing layer may be formed on the surface of the label substrate, and a release layer may be formed on the surface of the printing layer. In the present invention, since the printed layer is formed on the surface of the label base material and the release layer is formed on the surface of the printed layer, the rolled label base material can be unrolled. According to the present invention, since the printing layer is formed on the surface of the label substrate, and the peeling layer is formed on the surface of the printing layer, even if the adhesive layer formed on the inside of the label substrate and the peeling layer formed on its surface are opposite The label base material can be rolled up in a virtual adhesion state, and can also be unrolled, and can be cut into labels one by one from the label continuous body and used.
在第4个发明中,印刷层也可以是标签基材的表面,在剥离层的表面形成,并且可以用剥离性优良的印刷油墨形成。本发明中,由于印刷层是在作为标签基材表面的剥离层的表面上形成,而且是用剥离性优良的印刷油墨形成,因此被卷叠起来的标签基材可以开卷。按照本发明,由于印刷层是在作为标签基材表面的剥离层的表面上形成,而且是用剥离性优良的印刷油墨形成,因此即使在标签基材的表面侧形成的剥离层和里面侧形成的粘结剂层是以对置呈虚附着状态将标签基材卷叠起来,也可以开卷,可以从标签连续体上一张张地切成标签加以利用。In the fourth invention, the printing layer may be the surface of the label substrate, formed on the surface of the peeling layer, and may be formed with a printing ink having excellent peelability. In the present invention, since the printing layer is formed on the surface of the release layer which is the surface of the label base material, and is formed with printing ink having excellent releasability, the rolled label base material can be unrolled. According to the present invention, since the printing layer is formed on the surface of the release layer which is the surface of the label base material, and is formed with printing ink with excellent releasability, even if the release layer formed on the surface side of the label base material and the back side are formed The adhesive layer of the label base material is stacked in a virtual adhesion state facing each other, and it can also be unrolled, and can be cut into labels one by one from the label continuous body for use.
在第4个发明中,标签基材也可以在与粘结剂层的相反侧的表面上形成热敏显色层。本发明中,由于标签基材,在与粘结剂层相反侧的表面上形成热敏显色层因而可通过加热来显色。按照本发明,由于标签基材在与粘结剂层相反侧的表面上形成热敏显色层,因而通过热打印机等就能较简便地进行印字。In the fourth invention, the label substrate may have a heat-sensitive color-developing layer formed on the surface opposite to the adhesive layer. In the present invention, since the label base material has a heat-sensitive color-developing layer formed on the surface opposite to the adhesive layer, color can be developed by heating. According to the present invention, since the thermosensitive color-developing layer is formed on the surface of the label substrate opposite to the adhesive layer, printing can be performed relatively easily by a thermal printer or the like.
在第4个发明中,剥离层也可以通过印刷,涂覆剥离剂和/或印刷油墨而形成。本发明中,由于在标签基材的表面上形成印刷层,在印刷层的表面上形成剥离层,因而被卷叠起来的标签连续体可以开卷。按照本发明,由于在标签基材的表面上形成剥离层。,因而即使在标签基材的里面形成的粘结剂层和在其表面上形成的剥离层是以对置呈虚附着状态将标签基材卷叠起来,也可以开卷,可以从标签连续体上一张一张切成标签加以利用。In the fourth invention, the peeling layer can also be formed by printing, coating a peeling agent and/or printing ink. In the present invention, since the printed layer is formed on the surface of the label substrate and the release layer is formed on the surface of the printed layer, the rolled continuous label can be unrolled. According to the present invention, since the release layer is formed on the surface of the label substrate. , so even if the adhesive layer formed inside the label substrate and the release layer formed on its surface are stacked in a falsely attached state, the label substrate can be unrolled and can be removed from the continuous label. Cut them into labels one by one and use them.
在第4个发明中,剥离层也可以是由剥离性优良的薄膜或薄片层叠形成。本发明中,由于印刷层是在标签基材的表面上形成剥离层,因而被卷叠起来的标签连续体可以开卷。按照本发明,由于在标签基材的表面上用剥离性优良的薄膜或薄片形成剥离层,因而即使在标签基材的表面侧形成的剥离层和里面侧形成的粘结剂层以对置呈虚附着状态将标签基材卷叠起来,也可以开卷,可以从标签连续体上一张张地切成标签加以利用。In the fourth invention, the release layer may be formed by laminating films or sheets excellent in release properties. In the present invention, since the printed layer forms the peeling layer on the surface of the label substrate, the rolled continuous label can be unrolled. According to the present invention, since the release layer is formed on the surface of the label base material with a film or sheet with excellent peelability, even if the release layer formed on the surface side of the label base material and the adhesive layer formed on the back side face each other to form a In the virtual adhesion state, the label base material can be rolled up or unrolled, and can be cut into labels one by one from the label continuous body for use.
第5个发明是一种标签连续体的制造方法,它包括:准备至少其中一侧的表面具有剥离性的工程薄板、并在工程薄板具有剥离性的表面上形成粘结剂层的步骤1和,准备因粘结剂层被转移的从而具有可粘结里面的长条状标签基材、并将该标签基材的里面和工程薄板的粘结剂层重合的步骤2和,在标签基材的里面上形成剥离层的步骤3和,只将工程薄板从转移到标签基材里面上的粘结剂层表面剥离下来的步骤4和,将剥离层和粘结剂层以对置呈虚附着状态卷叠标签基材的步骤5。第5个发明中,由于在薄板表面上具有剥离性的工程薄板并形成粘结剂层,因此,当粘结剂层与长条状标签基材重合时就从工程薄板转移到长条状标签基材的表面上。按照第5个发明,由于将在工程薄板具有剥离性的表面上形成的粘结剂层和、因粘结剂层转移从而具备可粘结表面的长条状标签基材表面重合,常温下,粘结剂层从工程薄板转移到长条状标签基材的里面,因此即使是耐热性较小的极薄的标签基材,也可以形成粘结剂层。而且由于形成粘结剂层的粘结剂在乳胶状时所含的溶剂以除去状态使之从工程薄板的表面转移后形成粘结剂层,因此不会因为溶剂等对标签基材带来影响。所以,标签基材及形成粘结剂层的粘结剂选择范围极大地扩宽,而且,适于多品种少量的生产。此外,工程薄板可重复使用,因此不会浪费,可谋求资源的再利用。The fifth invention is a method for manufacturing a label continuum, which includes: preparing an engineering sheet having a peelable surface on at least one side thereof, and forming an adhesive layer on the peelable surface of the engineering sheet; and , prepare a strip-shaped label base material that has a bondable inside due to the transfer of the adhesive layer, and overlap the inside of the label base material with the adhesive layer of the engineering sheet. Step 2 and, on the label base material Step 3 of forming the release layer on the inner side of the label substrate and step 4 of peeling only the engineered sheet from the surface of the adhesive layer transferred to the inner side of the label substrate and placing the release layer and the adhesive layer in a dummy attachment Step 5 of the state roll label substrate. In the fifth invention, since the peelable engineered sheet is formed on the sheet surface to form an adhesive layer, the adhesive layer is transferred from the engineered sheet to the elongated label when the adhesive layer overlaps with the elongated label substrate on the surface of the substrate. According to the fifth invention, since the adhesive layer formed on the detachable surface of the engineering sheet is superimposed on the surface of the strip-shaped label substrate having an adhesive surface due to the transfer of the adhesive layer, at normal temperature, The adhesive layer is transferred from the engineered sheet to the inside of the long label substrate, so even an extremely thin label substrate with low heat resistance can form an adhesive layer. In addition, since the solvent contained in the latex form of the adhesive that forms the adhesive layer is transferred from the surface of the process sheet in a removed state to form an adhesive layer, there is no effect on the label base material due to solvents, etc. . Therefore, the selection range of the label substrate and the adhesive forming the adhesive layer is greatly expanded, and it is suitable for the production of many varieties and small quantities. In addition, the engineered sheet can be reused, so there is no waste, and resources can be reused.
第6个发明是一种标签连续体的制造方法,它包括:准备至少其中一侧的表面具有剥离性的工程薄板、并在工程薄板具有剥离性的表面上形成粘结剂层的步骤1和,准备因粘结剂层转移从而具有可粘结的里面的长条状标签基材、并将该标签基材的里面和工程薄板的粘结剂层重合的步骤2和,在标签基材的表面上形成印刷层的步骤3和,在标签基材的表面上形成剥离层的步骤4和,只将工程薄板从转移到标签基材里面上的粘结剂层表面剥离下来的步骤5和,将剥离层和粘结剂层以对置呈虚附着状态卷叠标签基材的步骤6。第6个发明中,由于在薄板表面上具备有剥离性的工程薄板并形成粘结剂层,因此,粘结剂层,当与长条状标签基材重合时就从工程薄板转移到长条状标签基材的表面上。按照第6个发明,由于将在工程薄板具有剥离性的表面上形成的粘结剂层和,因粘结剂层转移从而具备可粘结的表面的长条状标签表面重合,常温下,粘结剂层从工程薄板转移到长条状标签基材的里面,因此即使是耐热性较小的极薄的标签基材,也可以形成粘结剂层。而且由于形成粘结剂层的粘结剂在乳胶状时所含的溶剂以除去状态从工程薄板的表面转移后形成粘结剂层,因此不会因溶剂等对标签基材带来影响。所以,标签基材及形成粘结剂层的粘结剂的选择范围极大地扩宽,而且,适于多品种少量的生产。此外,工程薄板可重复使用,因此不会浪费,可以谋求资源的再利用。The sixth invention is a method for manufacturing a label continuum, which includes: preparing an engineering sheet having a releasable surface on at least one side thereof, and forming an adhesive layer on the releasable surface of the engineering sheet; and , preparing a strip-shaped label base material with a bondable inside due to the transfer of the adhesive layer, and superimposing the inside of the label base material with the adhesive layer of the engineering sheet 2 and, in the label base material Step 3 of forming a print layer on the surface and step 4 of forming a release layer on the surface of the label substrate and step 5 of peeling only the engineered sheet from the surface of the adhesive layer transferred to the inside of the label substrate and, Step 6: Roll up the label base material with the release layer and the adhesive layer facing each other in a state of virtual adhesion. In the sixth invention, since the peelable engineering sheet is provided on the surface of the sheet to form an adhesive layer, the adhesive layer is transferred from the engineering sheet to the strip when superimposed on the strip-shaped label substrate. on the surface of the label substrate. According to the sixth invention, since the adhesive layer formed on the detachable surface of the engineering sheet is superimposed on the surface of the strip-shaped label having a bondable surface due to the transfer of the adhesive layer, the adhesive layer can be adhered at room temperature. The adhesive layer is transferred from the engineered sheet to the inside of the long label substrate, so even very thin label substrates with low heat resistance can form an adhesive layer. In addition, since the solvent contained in the latex form of the adhesive forming the adhesive layer is transferred from the surface of the process sheet in a removed state to form the adhesive layer, the label base material will not be affected by the solvent or the like. Therefore, the selection range of the label substrate and the adhesive forming the adhesive layer is greatly expanded, and it is suitable for the production of many varieties and small quantities. In addition, the engineered sheet is reusable, so there is no waste, and resources can be reused.
在第5个发明和第6个发明中,只将工程薄板从转移到标签基材里面上的粘结剂层表面上剥离下来的步骤中,还可以包括将由前面步骤形成的层叠的标签基材和工程薄板的其它层一起分割成适宜宽度的步骤。在本发明中,工程薄板和长条状标签基材与其它层一起被切断。如果从一开始就按照各种期望目的宽度的标签基材形成粘结剂层,则在各标签基材的两侧边缘会各自产生浪费的部分,但按照本发明,首先以比期望目的的标签基材宽度更宽的幅度准备长条状的标签基材和工程薄板,带有粘结剂层后使之重合,并且将它们分割成适宜的宽度以形成符合目的的标签基材,这样,就可使在工程薄板的具有剥离性的表面上形成的粘结剂层,在工程薄板的左右端以有若干残余的状态形成,而两侧边缘的浪费部份却很少,可以更多地形成符合最初目的宽度的标签基材,极为有用。In the fifth invention and the sixth invention, in the step of peeling only the engineered sheet from the surface of the adhesive layer transferred to the inside of the label base material, the laminated label base material formed in the preceding steps may also be included. The step of splitting into appropriate widths along with other layers of engineered sheet. In the present invention, engineered sheets and strip label substrates are cut along with other layers. If the adhesive layer is formed from the beginning according to the label substrates of various desired purpose widths, wasteful parts will be generated on both side edges of each label substrate respectively, but according to the present invention, firstly, the adhesive layer is formed with labels wider than the desired purpose. The width of the substrate is wider. Prepare long strips of label substrates and engineering sheets, overlap them with an adhesive layer, and divide them into appropriate widths to form label substrates that meet the purpose. In this way, The adhesive layer formed on the peelable surface of the engineering sheet can be formed with some residues on the left and right ends of the engineering sheet, while the waste parts on both sides of the sheet are small, and more can be formed It is extremely useful to have a label substrate that fits the width of the original purpose.
在第5个或第6个发明中,只将工程薄板从转移到标签基材里面上的粘结剂层表面剥离下来的步骤,还可以包括将由前面步骤层叠的标签基材与形成的其他层一起冲切成适宜宽度的步骤。本发明中,工程薄板不被切断,标签基材和其它层一起被切断。按照本发明,如果按幅度准备长条状的标签基材和工程薄板,带有粘结层后使之重合,并且将上述标签基材冲切成适宜的标签宽度,就可以适宜地形成符合初期目的的标签,极为有用。In the 5th or 6th invention, the step of peeling only the engineered sheet from the surface of the adhesive layer transferred to the inside of the label base material may also include the step of separating the label base material laminated in the previous step with other layers formed Die together into steps of appropriate width. In the present invention, the engineered sheet is not cut, the label substrate is cut along with the other layers. According to the present invention, if the strip-shaped label base material and engineering sheet are prepared according to the width, they are superimposed after having an adhesive layer, and the above-mentioned label base material is punched into a suitable label width, it can be suitably formed to meet the initial label width. The label of the purpose is extremely useful.
在第5个发明或第6个发明中,在标签基材的表面形成剥离层的步骤,还可包括通过在标签基材的表面上印刷。涂覆剥离层从而形成剥离层的步骤。本发明中,由于标签基材的剥离层侧和粘结剂层侧是以对置呈虚附着状态卷叠标签基材,因此被卷叠起来的标签连续体可以开卷。按照本发明,如果在工程薄板具有剥离性的表面上形成粘结剂层,与粘结剂层转移后面被粘结的长条状标签基材的里面重合,就可以通过工程薄板的作用使粘结剂层从工程薄板转移到长条状标签基材的里面。In the fifth invention or the sixth invention, the step of forming the release layer on the surface of the label base material may include printing on the surface of the label base material. The step of applying a release layer to form a release layer. In the present invention, since the release layer side and the adhesive layer side of the label base are stacked in a state of facing each other in a virtual adhesion state, the rolled continuous label can be unrolled. According to the present invention, if an adhesive layer is formed on the peelable surface of the engineering sheet, and overlaps with the inside of the bonded elongated label substrate after the adhesive layer is transferred, the adhesive layer can be made by the action of the engineering sheet. The binder layer is transferred from the engineered sheet to the inside of the strip label substrate.
在第5个或第6个发明中,在标签基材的表面形成剥离层的步骤,还可包括在上述标签基材的表面上层叠剥离性优良的薄膜或薄片从而形成剥离层的步骤。本发明中,由于标签基材的剥离层侧和粘结利层侧是以对置呈虚附着状态将标签基材卷叠起来,因而被卷叠起来的标签连续体可以开卷。按照本发明,如果在工程薄板具有剥离性的表面上形成粘结剂层,与粘结剂层转移后面被粘结的长条状标签基材的里面重合,就可以通过剥离性优良的工程薄板的作用使粘结剂层从工程薄板转移到长条状标签的里面。In the fifth or sixth invention, the step of forming the release layer on the surface of the label base may further include the step of forming a release layer by laminating a film or sheet having excellent peelability on the surface of the label base. In the present invention, since the peeling layer side and the adhesive layer side of the label base material are facing each other and the label base material is rolled up in a state of virtual adhesion, the rolled label continuous body can be unrolled. According to the present invention, if an adhesive layer is formed on the peelable surface of the engineering sheet, and overlaps with the inside of the strip-shaped label substrate to be bonded after the adhesive layer is transferred, the engineering sheet with excellent peelability can be passed. The action of the adhesive transfers the adhesive layer from the engineered sheet to the inside of the strip label.
第7个发明是一种标签连续体的制造方法,它包括:准备至少其中一侧的表面具有剥离性的工程薄板,并在工程薄板具有剥离性的表面上形成粘结剂层的步骤1和,准备因粘结剂转移从而具有可粘结的里面的长条状标签基材、并将该标签基材的里面与工程薄板的粘结剂层重合的步骤2和,在标签基材的表面上形成剥离性优良的印刷层的步骤3和,只将工程薄板从转移到标签基材里面上的粘结剂层表面剥离下来的步骤4和,剥离层和粘结剂层以对置呈虚附着状态将标签基材卷叠起来的步骤5。第7个发明中,由于在薄板的表面具备具有剥离性的工程薄板以形成粘结剂层,因而当粘结剂层与长条状标签基材重合时就从工程薄板转移到长条状标签基材的表面。按照第7个发明,由于将工程薄板具有剥离性的表面上形成的粘结剂层,和因粘结层转移而具备可粘结的表面的长条状标签基材表面重合,常温下,粘结剂层从工程薄板的表面转移到长条状标签基材的里面,因此即使是耐热性较小的极薄的标签基材,也可以形成粘结剂层。此外由于形成粘结剂层的粘结剂在乳胶状态时所含的溶剂以除去状态使之从工程薄板的表面转移而形成粘结剂层,因此不会因溶剂等对标签基材带来影响。所以,标签基材及形成粘结剂层的粘结剂的选择范围极大地扩宽,而且,适于多品种少量的生产。此外,工程薄板可重复使用,因此不会浪费,可谋求资源的再利用。The seventh invention is a method for manufacturing a label continuum, which includes: preparing an engineering sheet having a peelable surface on at least one side thereof, and forming an adhesive layer on the peelable surface of the engineering sheet; and , the step 2 of preparing a strip-shaped label substrate with a bondable inside due to adhesive transfer, and superimposing the inside of the label substrate with the adhesive layer of the engineering sheet and, on the surface of the label substrate Step 3 of forming a print layer with excellent peelability and step 4 of peeling off only the engineered sheet from the surface of the adhesive layer transferred to the inside of the label base material, the release layer and the adhesive layer face each other in a virtual Attached state Step 5 of rolling up the label substrate. In the seventh invention, since the peelable engineering sheet is provided on the surface of the sheet to form the adhesive layer, the adhesive layer is transferred from the engineering sheet to the elongated label when the adhesive layer overlaps with the elongated label substrate the surface of the substrate. According to the seventh invention, since the adhesive layer formed on the detachable surface of the engineering sheet is superimposed on the surface of the strip-shaped label base material having a bondable surface due to the transfer of the adhesive layer, the adhesive layer can be adhered at normal temperature. The adhesive layer is transferred from the surface of the engineered sheet to the inside of the long label substrate, so even an extremely thin label substrate with low heat resistance can form an adhesive layer. In addition, since the solvent contained in the latex state of the adhesive that forms the adhesive layer is transferred from the surface of the process sheet in a removed state to form an adhesive layer, there is no effect on the label base material due to solvents, etc. . Therefore, the selection range of the label substrate and the adhesive forming the adhesive layer is greatly expanded, and it is suitable for the production of many varieties and small quantities. In addition, the engineered sheet can be reused, so there is no waste, and resources can be reused.
在第7个发明中,步骤5,还可以包括将由步骤1至4层叠的标签基材和工程薄板与形成的其它层一起切割成适宜宽度的步骤。本发明中,工程薄板和,长条状标签基材,与其它层一起被切断。如果从一开始就按照各种期望目的宽度的标签基材来形成粘结剂层,则在各标签基材的两侧边缘会各自产生浪费的部分,但按照本发明,首先以比期望目的的标签基材宽度宽的幅度准备长条状的标签基材和工程薄板,然后使之带有粘结剂层并重合,并且将它们分割成适宜宽度以形成符合目的的标签基材,这样,就可以使工程薄板具有剥离性的表面上形成的粘结剂层在工程薄板的左右端以有若干残余的状态形成,而两侧边缘的浪费部分都很少,可以更多地形成符合最初目的宽度的标签基材,极为有用。In the seventh invention, step 5 may further include a step of cutting the label substrate and engineering sheet laminated in steps 1 to 4 into appropriate widths together with other layers formed. In the present invention, the engineered sheet and the strip-shaped label substrate are cut together with other layers. If the adhesive layer is formed from the beginning according to the label base materials of various desired purpose widths, wasteful parts will be generated on both side edges of each label base material, but according to the present invention, firstly, the adhesive layer is formed with different widths than the desired purpose. The width of the label base material is wide. Prepare a long label base material and an engineering sheet, then make them overlap with an adhesive layer, and divide them into appropriate widths to form a label base material suitable for the purpose. In this way, The adhesive layer formed on the peelable surface of the process sheet can be formed with a little residue on the left and right ends of the process sheet, and there is little waste on both sides of the edge, and more can be formed to meet the original width very useful label substrate.
在第7个发明中,步骤5,还可以包括将由步骤1至4层叠的标签基材与形成的其它层一起冲切成适宜宽度的步骤。本发明中,工程薄板不被切断,标签基材与其它层一起被切断。按照本发明,如果以宽幅准备长条状标签基材和工程薄板,带有粘结剂层后使之重合,并且将上述标签基材冲切成适宜宽度从而形成适宜的标签宽度,就可以适宜地形成符合初期目的的标签,极其有用。In the seventh invention, step 5 may further include a step of die-cutting the label substrate laminated in steps 1 to 4 and other layers formed into an appropriate width. In the present invention, the engineered sheet is not cut, the label substrate is cut along with the other layers. According to the present invention, if the strip-shaped label base material and the engineering sheet are prepared in a wide width, overlapped with an adhesive layer, and the above-mentioned label base material is punched into an appropriate width to form an appropriate label width, it can be It is extremely useful to properly form a label that meets the original purpose.
在第7个发明中,步骤4,还可包括在标签基材的表面上通过印刷。涂覆剥离性优良的印刷油墨而形成印刷的步骤。在本发明中,由于标签基材的印刷层和/或剥离层侧和粘结剂层侧以对置呈虚附着状态将标签基材卷叠起来,因此被卷叠起来的标签连续体可以开卷。按照本发明,如果在工程薄板具有剥离性的表面形成粘结剂层,与粘结剂层转移后而被粘结的长条状标签基材的里面重合,就可以通过剥离性优良的工程薄板的作用使粘结剂层从工程薄板转移到长条状标签基材的里面。In the seventh invention, step 4 may further include printing on the surface of the label substrate. A step of printing by applying printing ink with excellent releasability. In the present invention, since the printed layer and/or the peeling layer side of the label base material and the adhesive layer side are facing each other and the label base material is rolled up in a virtual adhesion state, the rolled label continuous body can be unrolled. . According to the present invention, if an adhesive layer is formed on the peelable surface of the engineering sheet, and overlapped with the inside of the strip-shaped label base material bonded after the adhesive layer is transferred, the engineering sheet with excellent peelability can be passed. The action of the adhesive transfers the adhesive layer from the engineered sheet to the inside of the elongated label substrate.
在第7个发明中,步骤4还可包括与印刷层一起在上述标签基材的表面上形成剥离性优良的剥离层的步骤。本发明中,由于标签基材的印刷层及/或剥离层侧和粘结剂层侧以对置呈虚附着状态卷叠标签基材,因此被卷叠起来的标签连续体可以开卷。按照本发明,如果在工程薄板具有剥离性的表面形成粘结剂层,使其与因粘结利层被转移而被粘结的长条状标签基材的里面重合,就可以通过剥离性优良的工程薄片的作用使粘结剂层从工程薄板转移到长条状标签基材的里面。In the seventh invention, step 4 may further include the step of forming a peeling layer excellent in peelability on the surface of the label base material together with the printing layer. In the present invention, since the printed layer and/or release layer side of the label base material and the adhesive layer side are facing each other and the label base material is rolled up in a virtual adhesion state, the rolled continuous label can be unrolled. According to the present invention, if an adhesive layer is formed on the peelable surface of the engineering sheet so that it overlaps with the inside of the strip-shaped label base material bonded due to the transfer of the adhesive layer, it can be achieved by excellent peelability. The action of the engineered sheet transfers the adhesive layer from the engineered sheet to the inside of the elongated label substrate.
第8个发明是标签连续体的制造方法,它包括:准备至少其中一侧的表面具有剥离性的工程薄板,并在工程薄板具有剥离性的表面上形成粘结剂层的步骤1和,准备因粘结剂层转移从而具有可粘结的里面的长条状标签基材,并将该标签基材的里面与工程薄板的粘结剂层重合的步骤2和,在标签基材的表面上形成剥离层的步骤3和,只将工程薄板从转移到标签基材里面上的粘结剂层表面剥离下来的步骤4和,剥离层和粘结剂层以对置呈虚附着状态将标签基材卷叠起来的步骤5。第8个发明中,由于在薄板的表面具备具有剥离性的工程薄板以形成粘结剂层,因此,当粘结剂层一长条状标签基材重合时就从工程薄板转移到长条状标签基材的表面。按照第8个发明,由于将工程薄板具有剥离性的表面上形成的粘结剂层和,因粘结剂层转移而具有具备可粘结的表面的长条状标签基材的表面重合,于是常温下粘结剂层从工程薄板的表面转移到长条状标签基材的里面,因此即使是耐热性较小的极薄的标签基材,也可以形成粘结剂层。而且,由于形成粘结剂层的粘结剂在乳胶状态时所含的溶剂以除去状态使之从工程薄板的表面转移而形成粘结剂层,因此不会因溶剂等对标签基材带来影响。所以,标签基材及形成粘结剂层的粘结剂的选择范围极大地扩宽,而且,适于多品种少量的生产。此外,工程薄板可重复使用,因此不会浪费,可谋求资源的再利用。The eighth invention is a method for manufacturing a label continuum, comprising: preparing a process sheet having a peelable surface on at least one side thereof, and forming an adhesive layer on the peelable surface of the process sheet; and preparing Step 2 of superimposing the inside of the label substrate with the adhesive layer of the engineered sheet on the elongated label substrate having a bondable inside due to the transfer of the adhesive layer and, on the surface of the label substrate The step 3 of forming the release layer and the step 4 of peeling off only the engineering sheet from the surface of the adhesive layer transferred to the inside of the label base material, and the release layer and the adhesive layer are placed in a virtual adhesion state on the label base Step 5 of stacking the rolls. In the eighth invention, since the surface of the sheet is provided with a peelable engineering sheet to form an adhesive layer, when the adhesive layer and the strip-shaped label substrate are overlapped, they are transferred from the engineering sheet to the strip-shaped label substrate. The surface of the label substrate. According to the eighth invention, since the adhesive layer formed on the detachable surface of the engineering sheet is superimposed on the surface of the strip-shaped label base material having a bondable surface due to the transfer of the adhesive layer, The adhesive layer is transferred from the surface of the engineering sheet to the inside of the long label substrate at room temperature, so even an extremely thin label substrate with low heat resistance can form an adhesive layer. Moreover, since the solvent contained in the adhesive that forms the adhesive layer is in the latex state, it is transferred from the surface of the engineering sheet in a removed state to form an adhesive layer, so there is no impact on the label base material due to solvents, etc. Influence. Therefore, the selection range of the label substrate and the adhesive forming the adhesive layer is greatly expanded, and it is suitable for the production of many varieties and small quantities. In addition, the engineered sheet can be reused, so there is no waste, and resources can be reused.
在第8个发明中,步骤1,还可包括在薄板表面上印刷。涂覆剥离剂、准备被赋予了剥离性的工程薄板的步骤。本发明中,由于是在因表面印刷。涂覆有剥离剂而被赋予剥离性的工程薄板的表面上形成粘结剂层,因而,粘结剂层,当与长条状标签基材重合时就从工程薄板转移到长条状标签基材的表面。按照本发明,如果在工程薄板具有剥离性的表面上形成的粘结剂层与因粘结剂层转移后即可粘结的长条状标签基材的里面重合,则可通过剥离剂的作用使粘结剂层从工程薄板转移到长条状标签基材的里面。In the eighth invention, step 1 may further include printing on the surface of the sheet. A step of applying a release agent to prepare a process sheet endowed with release properties. In the present invention, because it is printed on the surface of the cause. An adhesive layer is formed on the surface of the engineered sheet coated with a release agent and endowed with peelability. Therefore, the adhesive layer is transferred from the engineered sheet to the elongated label base when it overlaps with the elongated label substrate. surface of the material. According to the present invention, if the adhesive layer formed on the peelable surface of the engineering sheet overlaps with the inside of the strip-shaped label substrate that can be bonded after the adhesive layer is transferred, it can be removed by the action of the release agent. Transfers the adhesive layer from the engineered sheet to the inside of the strip label substrate.
在第8个发明中,步骤2还可包括按宽幅准备长条状标签基材,使该标签基材的里面和工程薄板的粘结剂层重合,切成适宜的宽度后,再卷叠的步骤。本发明中,在工程薄板上形成的粘结剂层可转移到标签基材的里面。如果从一开始就按照各种期望目的宽度的标签基材来形成粘结剂层,则在各标签基材的两侧边缘会各自产生浪费的部分,但是按照本发明,首先以比期望目的的标签基材宽度更宽的幅度准备长条状标签基材和工程薄板,然后带有粘结剂层后使之重合,而且将它们分割成适宜的宽度以形成符合目的的标签基材,这样,就可以使在工程薄板具有剥离性的表面上形成的粘结剂层是以在工程薄板的左右端有若干残余的状态形成,而两侧边缘的浪费部分却很少,可以更多地形成符合最初目的宽度的标签基材,极为有用。In the eighth invention, step 2 may also include preparing a strip-shaped label substrate according to a wide width, overlapping the inside of the label substrate with the adhesive layer of the engineering sheet, cutting it into a suitable width, and then rolling it up A step of. In the present invention, the adhesive layer formed on the engineered sheet can be transferred to the inside of the label substrate. If the adhesive layer is formed from the beginning according to the label base materials of various desired purpose widths, wasteful parts will be generated on both side edges of each label base material respectively, but according to the present invention, firstly, the adhesive layer is formed with different widths than the desired purpose. The width of the label base material is wider. Prepare a long label base material and a process sheet, then overlap them with an adhesive layer, and divide them into appropriate widths to form a suitable label base material. In this way, It is possible to make the adhesive layer formed on the peelable surface of the engineering sheet be formed in a state where there are some residues at the left and right ends of the engineering sheet, while there are very few waste parts on both sides of the edge, and more conforming adhesive layers can be formed. Very useful for label substrates of the original intended width.
在第8个发明中,步骤3和步骤4,还可包括将重合的标签基材开卷后,形成印刷层和/或剥离层的步骤。在本发明中,标签基材和工程薄板之间夹有粘结剂层而层叠起来的滚筒状层叠物开卷,并形成印刷层和/或剥离层。按照本发明,可在符合初期目的的部位适宜地形成印刷层和/或剥离层,极为有用。In the eighth invention, steps 3 and 4 may further include a step of forming a printing layer and/or a peeling layer after unrolling the overlapped label substrates. In the present invention, a roll-shaped laminate stacked with an adhesive layer interposed between the label base material and the process sheet is unwound to form a printing layer and/or a peeling layer. According to the present invention, it is very useful that a printing layer and/or a peeling layer can be appropriately formed at a position that meets the initial purpose.
在第8个发明中,步骤3还可包括通过在标签基材的表面印刷。涂覆剥离剂和/或剥离性优良的印刷油墨以形成剥离层的步骤。本发明中,由于标签基材的剥离层侧和粘结剂层侧是以对置呈虚附着状态卷叠标签基材,因此被卷叠起来的标签连续体可以开卷。按照本发明,在工程薄板具有剥离性的表面形成粘结剂层,如果粘结剂层转移后即可与粘结的长条状标签基材的里面重合,就可以通过剥离剂和/或剥离性优良的印刷油墨的作用使粘结剂层从工程薄片转移到标签基材的里面。In the eighth invention, step 3 may also include printing on the surface of the label substrate. A step of applying a release agent and/or printing ink excellent in release properties to form a release layer. In the present invention, since the release layer side and the adhesive layer side of the label base are stacked in a state of facing each other in a virtual adhesion state, the rolled continuous label can be unrolled. According to the present invention, an adhesive layer is formed on the peelable surface of the engineering sheet, and if the adhesive layer can be overlapped with the inside of the bonded elongated label substrate after transfer, it can pass through the release agent and/or the release agent. The action of the excellent printing ink transfers the adhesive layer from the engineered sheet to the inside of the label substrate.
在第8个发明中,步骤3还可包括在标签基材的表面层叠剥离性优良的薄膜或薄片来形成剥离层的步骤。本发明中,由于标签基材的剥离层侧和粘结剂层侧是以对置呈虚附着状态卷叠标签基材,因此被卷叠起来的标签连续体可以开卷。按照本发明,在工程薄板具有剥离性的表面形成粘结剂层,如果粘结剂层转移后即可与粘结的长条状标签基材的里面重合,就可以通过剥离性优良的薄膜或薄片的作用使粘结剂层从工程薄板转移到长条状标签基材的里面。In the eighth invention, step 3 may further include a step of laminating a film or sheet having excellent peelability on the surface of the label base to form a release layer. In the present invention, since the release layer side and the adhesive layer side of the label base are stacked in a state of facing each other in a virtual adhesion state, the rolled continuous label can be unrolled. According to the present invention, an adhesive layer is formed on the peelable surface of the engineering sheet. If the adhesive layer can be overlapped with the inside of the bonded strip-shaped label substrate after transfer, it can be passed through a film or a strip with excellent peelability. The foil acts to transfer the adhesive layer from the engineered sheet to the inside of the strip label substrate.
本发明的上述目的及其它目的、特征在、局部及优点,通过参照附图进行的以下实施例的详细说明,可更清楚地了解。The above and other objects, features, parts, and advantages of the present invention will be more clearly understood through the detailed description of the following embodiments with reference to the accompanying drawings.
图1示出作为本发明一个实施例的标签连续体,(A)是其斜视图,(B)是其剖面图。Fig. 1 shows a label continuous body as an embodiment of the present invention, (A) is a perspective view thereof, and (B) is a cross-sectional view thereof.
图2示出的图解图表示图1图示例的制造方法的一例,示出其前一半的工序。The schematic diagram shown in FIG. 2 shows an example of the manufacturing method illustrated in FIG. 1 , and shows the first half of the process.
图3示出的图解图表示图1图示例的制造方法的一例,示出其后一半的工序。The schematic diagram shown in FIG. 3 shows an example of the manufacturing method illustrated in FIG. 1 , and shows the second half of the process.
图4示出的图解图表示图1图示例的制造方法的另一例。FIG. 4 is a diagram showing another example of the manufacturing method illustrated in FIG. 1 .
图5是作为本发明另一实施例的标签连续体的剖面图。Fig. 5 is a cross-sectional view of a label continuum as another embodiment of the present invention.
图6示出的图解图表示图5图示例的制造方法的一例。The diagram shown in FIG. 6 shows an example of the manufacturing method illustrated in FIG. 5 .
图7是作为本发明第3个实施例的标签连续体的剖面图。Fig. 7 is a cross-sectional view of a label continuous body as a third embodiment of the present invention.
图8示出的图解图表示图7图示例的制造方法的一例。The diagram shown in FIG. 8 shows an example of the manufacturing method illustrated in FIG. 7 .
图9是作为本发明第4个实施例的标签连续体的剖面图。Fig. 9 is a sectional view of a label continuous body as a fourth embodiment of the present invention.
图10示出的图解图表示图9图示例的制造方法的一例。The diagram shown in FIG. 10 shows an example of the manufacturing method illustrated in FIG. 9 .
图1示出作为本发明一个实施例的标签连续体,其中,(A)是其斜视图,(B)是其剖面图。Fig. 1 shows a label continuum as an embodiment of the present invention, wherein (A) is a perspective view thereof, and (B) is a cross-sectional view thereof.
图2和图3是表示图1图示例的制造方法之一例的图解图,图2表示其前半部的工序,图3表示后半部工序。2 and 3 are diagrams showing an example of the manufacturing method illustrated in FIG. 1 , wherein FIG. 2 shows the first half of the process, and FIG. 3 shows the second half of the process.
该实施例的标签连续体10,是由许多个标签12呈带状连续地形成的,在各标签12的边界分别切断即各自成为一张标签12加以使用。The label
而且,转移到长条状标签基材14的里面而形成的压敏型粘结剂层,也就是在常温下具有粘结性、并以轻的压力即可与被粘结材料粘结的粘结剂层16被形成,并在上述标签基材14的表面侧形成作为剥离层的剥离剂层18,在与标签基材14之间在标签基材14表面的一部分上形成作为上述标签基材14表面侧的印刷层20。Moreover, the pressure-sensitive adhesive layer formed by transferring to the inside of the elongated
印刷层20,按照中间隔有各标签12的边界来形成各张标签12的表示部的方式,在各张标签12的表示部位以一定的间隔间断地形成。The printed
标签连续体10,如图1(A)所示,作为标签使用前,上述剥离剂层18侧和上述粘结剂层16是以对置呈虚附着状态将标签基材14卷叠成滚筒状。The label
该实施例中,在标签基材14的剥离剂层侧18侧表面上形成热敏显色层22。In this embodiment, the heat-sensitive color-developing
长条状标签基材14,在本实施例中,例如可列举纸、合成纸、玻璃纸、聚苯乙烯、聚酯等塑料薄膜或薄片,或铝箔等长条状体,但为了将没有裂缝的长条带状连续体切成各标签12,必须是可以用手或切断机等机械器具进行切断的原材料。其构成还可以是,按规定间隔穿设缝纫机孔等裂缝(图中未示出),使之能切成规定标签12的小片。The
转移到标签基材14的里面而形成的粘结剂层16,是用于为各张标签12提供粘结力的,例如可来用丙烯共聚合树脂,橡胶系粘结剂等公知的粘结剂。The
在上述标签基材14的表面侧形成的热敏显色层22,例如可通过涂覆含有透明或单色的无色染料、酸性物质及粘结剂的混合物的热敏显色剂,干燥后而形成。此种情况下,作为无色染料,可列举结晶紫内酯、3—吲哚满基—3—对二甲氨基苯基—6—二甲氨基酞酮、3—二乙氨基—7—氯荧烷、2—二乙氨基—7—环己基氨基荧烷、3—二乙氨基—5—甲基—7—叔丁基荧烷、3—二乙氨基—6—甲基—7—苯胺基荧烷、3—二乙氨基—6—甲基—7—对丁基苯胺基荧烷等。The heat-sensitive color-developing
作为酸性物质,例如可列举2,2—双(4’—羟苯基)丙烷、4—苯基苯酚、4—羟基乙酰苯酮、2,2’—二羟基联苯、2,2’—亚甲基双(4—甲基—6—叔丁基苯酚)、4,4’—异亚丙基联苯酚、4,4’—异亚丙基双(2—氯酚)、4,4’—异亚丙基双(2—甲酚)、4,4’—亚乙基双(2—甲酚)、4,4’—硫代双(6—叔丁基—3—甲酚)等。Examples of acidic substances include 2,2-bis(4'-hydroxyphenyl)propane, 4-phenylphenol, 4-hydroxyacetophenone, 2,2'-dihydroxybiphenyl, 2,2'- Methylene bis(4-methyl-6-tert-butylphenol), 4,4'-isopropylidene biphenol, 4,4'-isopropylidene bis(2-chlorophenol), 4,4 '-isopropylidene bis(2-cresol), 4,4'-ethylene bis(2-cresol), 4,4'-thiobis(6-tert-butyl-3-cresol) wait.
作为粘结剂,例如可列举聚乙烯醇、甲氧基纤维素、羟乙基纤维素、羧甲基纤维素、聚丙烯酰胺、聚丙烯酸、淀粉、明胶、聚苯乙烯—乙酸乙烯共聚物等水溶性或水性乳液等。Examples of binders include polyvinyl alcohol, methoxycellulose, hydroxyethylcellulose, carboxymethylcellulose, polyacrylamide, polyacrylic acid, starch, gelatin, polystyrene-vinyl acetate copolymer, etc. Water-soluble or water-based emulsion, etc.
该热敏显色层22,可以通过加热打印机的热敏印刷头等使其显色。The heat-sensitive color-developing
在标签基材14的热敏显色层22侧表面上,按照中间隔有各标签的边界来形成各标签12的表示部位那样的方式,形成印刷层20。该印刷层20可通过使用普通的印刷油墨,用平版、凸版或胶版印刷及其它的公知印刷方法印刷而形成。The
在上述标签基材14的表侧面,即热敏显色层22及印刷层20的表面上形成的剥离层18,例如可通过印刷涂覆在不给热敏显色层22带来影响的温度下能进行固化的硅树脂等剥离剂而形成。The
在该实施例中,作为构成剥离层18的剥离剂,也可以选择像UV硅(即所谓的紫外线固化型硅)和EB硅(即所谓的电子射线固化型硅)之类用紫外线和电子射线即可被固化的,对热敏显色层22不会带来影响的物质。In this embodiment, as the release agent constituting the
剥离层还可是由剥离性优良的薄膜或薄片层叠、粘接而形成。The release layer may also be formed by laminating and bonding films or sheets excellent in release properties.
以下主要根据图2及图3继续对图1图示的制造方法的一例,进行说明。An example of the manufacturing method shown in FIG. 1 will be continued and described below mainly based on FIGS. 2 and 3 .
首先准备卷成滚筒状的纸或将薄膜或薄片状的由塑料等构成的长条带状工程薄板24卷叠成滚筒状的物体。该工程薄板24只在制造过程中使用,在完成了的标签连续体10上并不残留。而且,在工程薄板24的表面印刷。涂覆硅树脂或氟树脂等剥离剂,形成具有剥离性的剥离层24a。Firstly, paper rolled into a roll or a long strip-shaped
然后,在该工程薄板24的剥离层24a的表面上印刷。涂覆用来形成粘结剂层16的粘结剂26。该粘结剂涂覆装置100包括2个滚筒102a及102b。滚筒102a的下部浸渍在槽104中贮存的粘结剂26中。Then, printing is performed on the surface of the
因此通过使滚筒102a及102b旋转,就可以在被导入该部位的工程薄板24的剥离层24a的表面上印刷·涂覆粘结剂26。Therefore, by rotating the
作为粘结剂涂覆装置,可以使用凹版滚筒涂覆机、双面涂覆辊筒、气刀涂覆机等涂覆装置,还可以使用打字印刷机等公知的印刷机。As the adhesive coating device, a coating device such as a gravure roll coater, a double-sided coater roll, and an air knife coater can be used, and a known printing machine such as a typewriter printer can also be used.
然后,印刷涂覆有粘结剂26的工程薄板24,例如导入包括加热器的干燥机106。在干燥机106中,印刷涂覆在工程薄板24上的粘结剂26被干燥而形成粘结剂层16。作为粘结剂,在使用包括EVA系、乙酸乙烯系、丙烯酸系等水溶性树脂的粘结剂或盐酸乙烯、氨基甲酸乙酯、丙烯酸等组成的溶剂型粘结剂的情况下,使用干燥机;在采用橡胶系、EVA系的热熔型粘结剂的情况下,使用冷却机。The engineered
在如此形成粘结剂层16的工程薄板24的剥离层24a一侧,层叠作为标签基材14的原纸14a。The
标签基材14的原纸14a,也形成与工程薄板24同样的宽度,在标签基材14的原纸14a的表面,已经形成有热敏显色层22。The
热敏显色层22在与上述粘结剂层26的相反侧上形成。The thermosensitive color-developing
于是,由工程薄板24、粘结剂层26及标签基材14层叠起来的层叠物30在导入以下的印刷等工序之前,以层叠状态预先按照与作为最终制品的标签连续体10的宽度相近似的宽度,用纵剪切机108切割,分切后卷叠成滚筒状。Then, the
该工程薄板24和标签基材14的连续体带有粘结剂层26层叠起来并被虚附着的层叠物30卷成滚筒状;层叠物30在卷成滚筒状的状态下,被导入图3示出的下一工序的印刷及剥离剂涂覆装置。The continuum of the
随后,层叠物30的被卷成层叠滚筒状的滚筒状层叠物30被装入图3示出的制造装置中,将层叠物30开卷后,导入用于形成印刷层20的印刷装置110中。该装置110用于印刷构成各标签12的表示部位,例如用平版、凸版、或胶版印刷等公知的印刷装置印刷商品名等文字和适宜的图案等构成的图形。Subsequently, the roll-shaped
然后,形成有印刷层20的层叠物30被导入用于在标签基材14的印刷层20的表面上形成剥离层18的剥离剂涂覆装置120。该剥离剂涂覆装置120,包括主滚筒122a和与该主滚筒122a相对而设置的滚筒122b。而且,主滚筒122a,其下部浸渍在槽124中贮存的剥离剂32中,在夹在主滚筒122a和滚筒122b之间的层叠物30的标签基材14的表面上,通过主滚筒122a涂覆剥离剂32。随后,将印刷涂覆过剥离剂32的层叠物30移至例如包括加热器的干燥机126中。在干燥机126中,使印刷涂覆在层叠物上的剥离剂干燥以致形成剥离层18。然后,剥离剂层18和层叠物30层叠而成的标签连续体10被导入下一个工程薄板除去装置130。工程薄板除去装置130,包括滚筒132,从层叠物30的粘结剂层16的表面剥离工程薄板24,卷成滚筒状可再利用于其它用途。Then, the laminate 30 formed with the printed
另一方面,构成标签连续体10的层叠物30,进一步按照最适宜的标签连续体10的宽度一边用纵剪切机140切断加工两侧边缘或一侧边缘,一边卷叠成滚筒状。不过,也可以象仅将粘结剂层16,印刷层10及热敏显色层22切断加工那样进行冲切。On the other hand, the laminate 30 constituting the label
图4是表示图1图示例的制造方法另一例的图解图。在图4示出的例子中,与图2及图3所示例不同,省略了纵剪切机108、在将由工程薄板24、粘结剂层26及标签基材14层叠而成的层叠物30导入下一个印刷等工序之前,不用纵剪切机108分切。而且,层叠物30不卷叠成滚筒状,就被导入下一工序的印刷等以及剥离剂涂覆装置中。Fig. 4 is a diagram showing another example of the manufacturing method illustrated in Fig. 1 . In the example shown in FIG. 4, unlike the examples shown in FIGS. It is not cut by the slitting
图4示出的例子中,替代图2及图3示出例子中的纵剪切机140,形成了冲切机140a。而且,构成标签连续体10的层叠物30,进一步按照最适宜的标签连续体10的宽度用冲切机140a,将标签基材14与其它的印刷层20、热敏显色层22、剥离层18及粘结剂层16一起,一边冲切加工两侧边缘或一侧边缘一边卷叠成滚筒状。In the example shown in FIG. 4 , instead of the slitting
另一方面,工程薄板24由于不用冲切机140a冲切以原来状态残存,在用冲切机140a冲切加工时才进行调整,因而可维持原有的宽幅状态。而且由于粘结剂层16转移到标签基材14侧,因而工程薄板可以重复使用。On the other hand, since the
图5是作为本发明第二个实施例的标签连续体的剖面图,图6是表示图5图示例的制造方法一例的图解图。Fig. 5 is a cross-sectional view of a label continuous body as a second embodiment of the present invention, and Fig. 6 is a schematic view showing an example of the manufacturing method illustrated in Fig. 5 .
在该实施例的标签连续体10中,在标签基材14表面侧不形成剥离剂层18的部位形成具有剥离性优良的印刷油墨的第1印刷层21a,而且,在与标签基材14之间在标签基材14的一部分表面上形成第2印刷层21b。本实施例中,也在标签基材14的剥离剂层侧18的侧表面上形成热敏显色剂层22。也就是,剥离剂层18,是在标签基材14的表面侧即热敏显色层22及第2印刷层21b的表面上形成。In the label
第2印刷层21b,通过普通的印刷油墨形成,按照中间隔有各标签12的边界来形成标签12的表示部那样,在各标签12的表示部之间以一定间隔间断地形成。The
也就是,本实施例中,在标签基材14的热敏显色层22侧表面上还形成中间隔有各标签12的边界形成的具有各标签12的表示部位的第2印刷层21b。该第2印刷层21b,使用一般的印刷油墨,通过平版、凸版,胶版印刷及其它公知的印刷方法印刷而形成。不过,也可以不形成这种2印刷层21b。That is, in the present embodiment, the second printed
图5图示例的标签连续体10,制造工序中承担前半部分的标签基材14和工程薄板24的层叠物30,由与图2图示例相同的装置制造,但该图5图示例的标签连续体10的制造方法中承担后半部分的制造装置,在图6中示出。The
层叠物30被卷成层叠滚筒状的滚筒状层叠物30,装入图6示出的制造装置中,将层叠物30开卷后,导入用于形成第2印刷层21b的印刷装置110。该印刷装置110可印刷构成名标签12的表示部分,例如,通过平版、凸版或胶版印刷等公知的印刷装置印刷商品名等文字和适宜图案等组成的图形。The
继而,形成有第2印刷层21b的层叠物30被导入用于在标签基材14的第2印刷层21b的表面上形成剥离剂层18的剥离剂涂覆装置120中。该剥离剂涂覆装置120包括主滚筒122a和与该主滚筒122a相对而设置的滚筒122b。而且,主滚筒122a,其下部浸渍在槽124中贮存的剥离剂32中,在夹在主滚筒122a和滚筒122b之间的层叠物30的标签基材14的表面上用主滚筒122a涂覆剥离剂32。Next, the laminate 30 formed with the second printed
然后,将印刷涂覆过剥离剂32的层叠物30移到例如包括加热器的干燥机126中。在干燥机126中,印刷涂覆在层叠物上的剥离剂32被干燥从而形成剥离剂层18。The print-coated
然后,导入印刷装置115,以便在层叠物30的不形成剥离层的部位,用剥离性优良的印刷油墨形成第1印刷层21a。然后,将由该印刷装置115形成有印刷层21a的层叠物30送至干燥机117中。Then, it is introduced into the
而且,由第1印刷层21a、剥离层18和层叠物30层叠而成的标签连续体10被导入下一个工程薄板除去装置130中。工程薄板除去装置130包括滚筒132,可用来从层叠物30的粘结剂层16表面剥离工程薄板24,然后将其卷成滚筒状,以供其它用途再利用。And the label
另一方面,构成标签连续体10的层叠物30,进一步按照最适宜的示签连续体10的宽度,用纵剪切机140一边切断加工两侧边缘或一侧边缘,一边将其卷成滚筒状。不过,也可以使用冲切。On the other hand, the
图7是本发明的第3个实施例的标签连续体的剖面图,图8是表示图7图示例的制造方法之一例的图解图。Fig. 7 is a cross-sectional view of a label continuous body according to a third embodiment of the present invention, and Fig. 8 is a schematic diagram showing an example of the manufacturing method illustrated in Fig. 7 .
该标签连续体50,与图1图示例及图5图示例不同,在标签基材54的表面形成剥离剂层58。进而在剥离剂层58的表面形成第1印刷层60。不过,在标签基材54的里面形成粘结剂层56这一点与图1图示例及图5图示例相同,而且在标签基材54的表面形成热敏显色层62这一点也与图1图示例及图5图示例相同。This label
此外,作为形成第1印刷层60的印刷油墨,必须选择其自身具有剥离性的印刷油墨。In addition, as the printing ink for forming the
图7图示例的标签连续体50的构成是,制造工序中承担前半部分的标签基材54和加工薄板64的层叠物70,通过与图2图示例相同的装置制造,而在该图7图示例的标签连续体50的制造方法中承担后半部分的制造装置,如图8图示例所示,通过剥离剂涂覆装置220在层叠物70的标签基材54表面印刷.涂覆剥离剂72的同时,用使印刷涂覆的剥离剂72固化的固化装置使之固化后形成剥离层58,在其下层,通过印刷装置210在剥离剂层58的表面形成印刷层60。The configuration of the label
在该图8图示例中,与图3图示例及图6图示例不同,作为将标签基材54调整成标签连续体50的最适宜宽度装置的纵剪切机240为了能借助工程薄板除去装置230将工程薄板64从粘结剂层56剥离下来后进行分切,被设置在将要被卷叠成滚筒状之前的下层。In the example shown in FIG. 8 , unlike the example shown in FIG. 3 and the example shown in FIG. 6 , the
图9是作为第4个实施例的标签连续体的剖面图。图10是表示图9图示例的制造方法之一例的图解图。Fig. 9 is a cross-sectional view of a label continuous body as a fourth embodiment. FIG. 10 is a schematic view showing an example of the manufacturing method illustrated in FIG. 9 .
该标签连续体50,与图1图示例及图5图示例不同,在标签基材54的表面形成印刷层60。进而在印刷层60的表面形成由剥离性优良的透明薄膜或薄片构成的剥离层58。不过,在标签基材54的里面形成的粘结剂层56这一点与图1图示例及图5图示例相同,而且在标签基材54的表面形成热敏显色层62这一点也与图1图示例及图5图示例相同。This label
图9图示例的标签连续体50的构成是,制造工序中承担前半部分的标签基材54和加工薄板64的层叠物70,通过与图3图示例同样的装置制造,而在该图9图示例的制造方法中承担后半部分的制造装置,如图10图示例,通过印刷装置210在热敏显色层62的表面上形成印刷层60,但要改变成通过剥离剂涂覆装置在层叠物的标签基材表面印刷涂覆剥离剂以形成剥离层的方法。其构成是,使形成剥离层58的透明或半透明薄膜58a卷叠,在薄膜58a的里面形成粘结剂层58b,借助其粘结剂层58的粘结力使薄膜58粘结在印刷层58的表面上从而形成剥离层。The structure of the label
在该图10图示例中,与图3图示例、图4图示例及图6图示例不同,作为将标签基材54调整成标签连续体54的最适宜宽度装置的纵剪切机240,为了能借助工程薄板除去装置230将工程薄板64从粘结剂层56剥离下来后进行分切,被设置在将要被卷叠成滚筒状之前的下层。In the example shown in FIG. 10 , different from the example shown in FIG. 3 , the example shown in FIG. 4 , and the example shown in FIG. The
本发明不受上述实施例的限制,可能进行各种变化。例如,在图1图示例中,还可在作为剥离层的剥离剂层表面,形成兼剥离层的印刷层。此种情况下,作为形成印刷层的印刷油墨,必须选择其自身具有剥离性的印刷油墨以便形成剥离层。The present invention is not limited to the above-described embodiments, and various changes are possible. For example, in the example shown in FIG. 1 , a printed layer also serving as a release layer may be formed on the surface of the release agent layer as the release layer. In this case, as the printing ink for forming the printing layer, it is necessary to select a printing ink which itself has release properties in order to form the release layer.
本发明通过图示进行了详细说明,但它是用简单的图解和一例进行的说明,因此显然不应理解成受此限定,本发明的精神及范围仅由附上的权利要求所限定。Although the present invention has been described in detail by way of illustrations, it is obvious that it should not be construed as being limited thereto, since it is explained by simple illustrations and an example, and the spirit and scope of the present invention are limited only by the appended claims.
Claims (30)
Applications Claiming Priority (18)
Application Number | Priority Date | Filing Date | Title |
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JP247188/94 | 1994-09-14 | ||
JP24718894 | 1994-09-14 | ||
JP247188/1994 | 1994-09-14 | ||
JP257486/1994 | 1994-09-26 | ||
JP6257486A JPH0895494A (en) | 1994-09-26 | 1994-09-26 | Continuous label body and its production |
JP257486/94 | 1994-09-26 | ||
JP33632394A JP3734181B2 (en) | 1994-09-14 | 1994-12-22 | Label continuum and method for producing the same |
JP336321/94 | 1994-12-22 | ||
JP336322/94 | 1994-12-22 | ||
JP33632294A JPH08137400A (en) | 1994-09-14 | 1994-12-22 | Successive label body and its production |
JP336321/1994 | 1994-12-22 | ||
JP336322/1994 | 1994-12-22 | ||
JP336324/1994 | 1994-12-22 | ||
JP33632494A JPH08137402A (en) | 1994-09-14 | 1994-12-22 | Label continuous body and its manufacture |
JP33632194A JPH08137399A (en) | 1994-09-14 | 1994-12-22 | Successive label body and its production |
JP336323/94 | 1994-12-22 | ||
JP336324/94 | 1994-12-22 | ||
JP336323/1994 | 1994-12-22 |
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CN1119317A true CN1119317A (en) | 1996-03-27 |
CN1137456C CN1137456C (en) | 2004-02-04 |
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CNB951168576A Expired - Fee Related CN1137456C (en) | 1994-09-14 | 1995-09-13 | Continous lable body and making of same |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100537211C (en) * | 2007-10-13 | 2009-09-09 | 蔡小如 | Smart card label production technique |
CN101950510A (en) * | 2010-07-27 | 2011-01-19 | 海南亚元防伪技术研究所 | Blowing-open prevention type adhesive sticker seal |
CN101384439B (en) * | 2005-11-30 | 2015-07-29 | Ncr公司 | There is the dual-sided thermal printing of label |
CN107799697A (en) * | 2016-08-31 | 2018-03-13 | 住友化学株式会社 | Membrane winding body, the manufacture method of membrane winding body and label inspection method |
-
1995
- 1995-09-13 CN CNB951168576A patent/CN1137456C/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101384439B (en) * | 2005-11-30 | 2015-07-29 | Ncr公司 | There is the dual-sided thermal printing of label |
CN100537211C (en) * | 2007-10-13 | 2009-09-09 | 蔡小如 | Smart card label production technique |
CN101950510A (en) * | 2010-07-27 | 2011-01-19 | 海南亚元防伪技术研究所 | Blowing-open prevention type adhesive sticker seal |
CN101950510B (en) * | 2010-07-27 | 2012-02-22 | 海南亚元防伪技术研究所 | Blowing-open prevention type adhesive sticker seal |
CN107799697A (en) * | 2016-08-31 | 2018-03-13 | 住友化学株式会社 | Membrane winding body, the manufacture method of membrane winding body and label inspection method |
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