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CN111880251B - SPP coupler based on asymmetric metal grating structure and manufacturing method - Google Patents

SPP coupler based on asymmetric metal grating structure and manufacturing method Download PDF

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CN111880251B
CN111880251B CN202010850190.1A CN202010850190A CN111880251B CN 111880251 B CN111880251 B CN 111880251B CN 202010850190 A CN202010850190 A CN 202010850190A CN 111880251 B CN111880251 B CN 111880251B
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grating
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asymmetric metal
dielectric
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CN111880251A (en
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刘文杰
卓青霞
刘怡俊
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Guangdong University of Technology
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/008Surface plasmon devices
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/18Diffraction gratings
    • G02B5/1847Manufacturing methods
    • G02B5/1857Manufacturing methods using exposure or etching means, e.g. holography, photolithography, exposure to electron or ion beams
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/18Diffraction gratings
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Abstract

The application discloses an SPP coupler based on an asymmetric metal grating structure and a manufacturing method thereof, wherein the SPP coupler enters a medium grating layer after incident light passes through a medium filling layer, and the asymmetric metal grating structure is arranged to be an inverted L-shaped structure or a Z-shaped structure, so that the incident light can vertically enter a substrate to excite SPP, oblique incidence excitation is not needed, and the complexity of an external light path can be greatly reduced; the medium grating layer is provided with a plurality of periodic medium gratings, the periodic medium grating structure can realize higher optical coupling efficiency, and can better limit incident light in the substrate for one-way transmission, so that the optical coupling efficiency and the one-way ratio can be improved.

Description

基于非对称金属光栅结构的SPP耦合器及制作方法SPP coupler based on asymmetric metal grating structure and fabrication method

技术领域technical field

本申请涉及耦合器技术领域,尤其涉及一种基于非对称金属光栅结构的SPP耦合器以及相应的制作方法。The present application relates to the technical field of couplers, and in particular, to an SPP coupler based on an asymmetric metal grating structure and a corresponding fabrication method.

背景技术Background technique

表面等离激元(Surface Plasmon Polariton,SPP)是由外部电磁场诱导金属结构表面自由电子或束缚电子的集体振荡现象,它可以突破衍射极限制约,在纳米尺度下实现对光的调制以及增强光与物质的相互作用。表面等离激元能够把入射光局域在金属表面亚波长的区域,相对于传统的介质光波导器件而言,可以突破衍射极限的限制,从而进一步缩小器件尺寸。对于实现兼具纳米电子器件的极小特征尺寸和介质光学的超高传输速度具有至关重要的意义。Surface Plasmon Polariton (SPP) is a collective oscillation phenomenon of free electrons or bound electrons on the surface of metal structures induced by an external electromagnetic field. interaction of matter. Surface plasmon can localize the incident light in the sub-wavelength region of the metal surface. Compared with the traditional dielectric optical waveguide device, it can break through the limitation of the diffraction limit, thereby further reducing the size of the device. It is of great significance to realize the ultra-small feature size of nanoelectronic devices and ultra-high transmission speed of dielectric optics.

SPP单向耦合器是集成光路的重要元器件之一,受到研究者的重视。然而,如何设计金属微纳结构,从而将光能够高效地耦合至金属微纳结构,从而形成单向传输的SPP仍然目前存在的重要问题之一。另外,现有SPP耦合器结构通常制备工艺复杂,对设备条件要求高,成为制约其大规模应用的一个主要因素。因此,降低制作难度也是需要考虑的另一个重要问题。The SPP unidirectional coupler is one of the important components of the integrated optical circuit, which has been paid much attention by researchers. However, how to design metal micro-nano structures so that light can be efficiently coupled to metal micro-nano structures to form unidirectional transmission SPPs is still one of the important problems. In addition, the existing SPP coupler structure is usually complicated in preparation process and requires high equipment conditions, which becomes a major factor restricting its large-scale application. Therefore, reducing the difficulty of production is also another important issue to consider.

发明内容SUMMARY OF THE INVENTION

本申请提供了基于非对称金属光栅结构的SPP耦合器及制作方法,用于解决现有的SPP单向耦合器的光耦合效率与SPP单向比较低以及相应的耦合器制作难度较高的技术问题。The present application provides an SPP coupler based on an asymmetric metal grating structure and a manufacturing method, which are used to solve the technology that the optical coupling efficiency of the existing SPP unidirectional coupler is lower than that of the SPP unidirectional and the corresponding coupler is difficult to manufacture. question.

有鉴于此,本申请第一方面提供了一种基于非对称金属光栅结构的SPP耦合器,由下至上依次设有衬底、介质光栅层、非对称金属光栅结构与介质填充层;In view of this, a first aspect of the present application provides an SPP coupler based on an asymmetric metal grating structure, which is provided with a substrate, a dielectric grating layer, an asymmetric metal grating structure and a dielectric filling layer in sequence from bottom to top;

所述介质光栅层包括若干个等距排列的介质光栅;The dielectric grating layer includes several dielectric gratings arranged at equal distances;

所述非对称金属光栅结构部分覆盖所述介质光栅表面,所述非对称金属光栅结构为倒“L”字型结构或“Z”字型结构。The asymmetric metal grating structure partially covers the surface of the dielectric grating, and the asymmetric metal grating structure is an inverted "L" shape structure or a "Z" shape structure.

优选地,所述介质光栅的折射率为1.4~1.7,所述介质光栅的宽度为75~200nm,所述介质光栅的高度为75~300nm,所述介质光栅层的光栅周期为300~800nm。Preferably, the refractive index of the dielectric grating is 1.4-1.7, the width of the dielectric grating is 75-200 nm, the height of the dielectric grating is 75-300 nm, and the grating period of the dielectric grating layer is 300-800 nm.

优选地,所述介质光栅层的所述光栅周期为400-600nm。Preferably, the grating period of the dielectric grating layer is 400-600 nm.

优选地,所述介质填充层相对于所述非对称金属光栅结构表面以上的结构厚度为50-800nm。Preferably, the thickness of the dielectric filling layer above the surface of the asymmetric metal grating structure is 50-800 nm.

优选地,所述非对称金属光栅结构的金属度大于50nm,所述非对称金属光栅结构的金属厚度为70~150nm。Preferably, the metal degree of the asymmetric metal grating structure is greater than 50 nm, and the metal thickness of the asymmetric metal grating structure is 70-150 nm.

另一方面,本申请实施例提供了一种基于非对称金属光栅结构的SPP耦合器的制作方法,包括以下步骤:On the other hand, an embodiment of the present application provides a method for fabricating an SPP coupler based on an asymmetric metal grating structure, including the following steps:

S101:在衬底上形成具有若干个等距排列的介质光栅的介质光栅层;S101: forming a dielectric grating layer having a plurality of dielectric gratings arranged at equal distances on a substrate;

S102:在所述介质光栅层上形成非对称金属光栅结构,所述非对称金属光栅结构部分覆盖所述介质光栅表面,同时,所述非对称金属光栅结构为倒“L”字型结构或“Z”字型结构;S102: Form an asymmetric metal grating structure on the dielectric grating layer, the asymmetric metal grating structure partially covers the surface of the dielectric grating, and at the same time, the asymmetric metal grating structure is an inverted "L" shape structure or "" Z"-shaped structure;

S103:在所述非对称金属光栅结构的所在空间填充介质并形成介质填充层,所述介质填充层覆盖所述非对称金属光栅结构与所述介质光栅层表面;S103: Filling the space where the asymmetric metal grating structure is located with a medium and forming a medium filling layer, the medium filling layer covers the asymmetric metal grating structure and the surface of the dielectric grating layer;

S104:对经所述步骤S103获得的样品通过刻蚀工艺刻蚀出耦合器的独立单元。S104: Etch the independent unit of the coupler through an etching process on the sample obtained in the step S103.

优选地,所述步骤S101中形成所述介质光栅层的制作方法采用下列三种方法的任意一种:Preferably, the manufacturing method for forming the dielectric grating layer in the step S101 adopts any one of the following three methods:

1)首先,在所述衬底的上表面通过旋涂方法形成光刻胶,然后,采用曝光与显影工艺形成具有所述光刻胶制成的所述介质光栅的介质光栅层;1) First, a photoresist is formed on the upper surface of the substrate by a spin coating method, and then an exposure and development process is used to form a dielectric grating layer having the dielectric grating made of the photoresist;

2)首先,在所述衬底的上表面形成介质层,所述介质层采用SiO2、SiNx、ITO或AlN材料制成,然后,在所述介质层上通过旋涂方法形成光刻胶,并通过曝光、显影形成所述光刻胶制成的所述介质光栅,最后,通过干法刻蚀工艺形成所述介质光栅层;2) First, a dielectric layer is formed on the upper surface of the substrate, and the dielectric layer is made of SiO2, SiNx, ITO or AlN material, and then a photoresist is formed on the dielectric layer by a spin coating method, and The dielectric grating made of the photoresist is formed by exposing and developing, and finally, the dielectric grating layer is formed by a dry etching process;

3)首先,在所述衬底的上表面形成介质层,所述介质层采用SiO2、SiNx、ITO或AlN材料制成,然后,在所述介质层上通过旋涂方法形成光刻胶,并通过纳米压印工艺形成所述光刻胶制成的所述介质光栅,最后,通过干法刻蚀工艺形成所述介质光栅层。3) First, a dielectric layer is formed on the upper surface of the substrate, and the dielectric layer is made of SiO2, SiNx, ITO or AlN material, and then a photoresist is formed on the dielectric layer by a spin coating method, and The dielectric grating made of the photoresist is formed by a nano-imprint process, and finally, the dielectric grating layer is formed by a dry etching process.

优选地,所述步骤S102中采用倾斜蒸镀方法形成所述非对称金属光栅结构,具体包括:通过电子束坩埚发出电子束,并将经过所述步骤S101获得的样品以预设的倾斜角度相对所述电子束的出射方向倾斜设置,所述预设的倾斜角度可调,经过蒸镀后,所述介质光栅的表面上形成倒“L”或“Z”字型结构的非对称金属光栅结构。Preferably, the asymmetric metal grating structure is formed by an oblique evaporation method in the step S102, which specifically includes: emitting an electron beam through an electron beam crucible, and aligning the sample obtained in the step S101 with a preset tilt angle relative to each other. The outgoing direction of the electron beam is set obliquely, and the preset inclination angle is adjustable. After evaporation, an asymmetric metal grating structure with an inverted "L" or "Z" shape is formed on the surface of the dielectric grating. .

优选地,所述预设的倾斜角度为30°~60°。Preferably, the preset inclination angle is 30°˜60°.

优选地,所述步骤S103中形成所述介质填充层的具体步骤包括:通过旋涂方法在所述非对称金属光栅结构与所述介质光栅层表面上形成表面平整的所述介质填充层,其中,旋涂的转速为4000~10000转/分钟,旋涂的次数为3~5次,所述介质填充层的介质为氢倍半硅氧烷。Preferably, the specific step of forming the dielectric filling layer in the step S103 includes: forming the dielectric filling layer with a flat surface on the surface of the asymmetric metal grating structure and the dielectric grating layer by a spin coating method, wherein , the rotational speed of the spin coating is 4000-10000 rpm, the number of times of the spin coating is 3-5 times, and the medium of the medium filling layer is hydrogen silsesquioxane.

从以上技术方案可以看出,本申请实施例具有以下优点:As can be seen from the above technical solutions, the embodiments of the present application have the following advantages:

本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器,当入射光通过介质填充层后进入介质光栅层,通过设置非对称金属光栅结构为倒“L”字型结构或“Z”字型结构,从而使得入射光可以垂直射入衬底,激发SPP,无需倾斜入射激发,可大幅降低外置光路的复杂性;而介质光栅层具有若干个周期性的介质光栅,周期性的介质光栅结构可以实现较高的光耦合效率,且可以较好的将入射光限制于衬底内进行单向传播,从而可以提高光耦合效率与单向比,另外,本实施例的SPP耦合器结构简单,制作难度低,适于批量生产。An SPP coupler based on an asymmetric metal grating structure provided by an embodiment of the present application, when incident light enters the dielectric grating layer after passing through the dielectric filling layer, the asymmetric metal grating structure is set as an inverted "L" shape structure or "Z" shape ” shape structure, so that the incident light can enter the substrate vertically to excite the SPP without oblique incident excitation, which can greatly reduce the complexity of the external optical path; while the dielectric grating layer has several periodic dielectric gratings, the periodic The dielectric grating structure can achieve high optical coupling efficiency, and can better confine the incident light in the substrate for unidirectional propagation, so that the ratio of optical coupling efficiency to unidirectional can be improved. In addition, the SPP coupler of this embodiment can The structure is simple, the manufacturing difficulty is low, and the utility model is suitable for mass production.

本申请另一实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法简单易行,降低了制作难度,适用于大批量生产制造,同时,生产后的SPP耦合器与上述实施例的基于非对称金属光栅结构的SPP耦合器的有益效果一致。Another embodiment of the present application provides a method for fabricating an SPP coupler based on an asymmetric metal grating structure, which is simple and feasible, reduces fabrication difficulty, and is suitable for mass production. The beneficial effects of the SPP coupler based on the asymmetric metal grating structure of the example are the same.

附图说明Description of drawings

图1为本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的结构示意图;1 is a schematic structural diagram of a method for fabricating an SPP coupler based on an asymmetric metal grating structure provided by an embodiment of the present application;

图2为本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的示例一中步骤S301的样品截面图;2 is a cross-sectional view of a sample in step S301 of Example 1 of a method for fabricating an SPP coupler based on an asymmetric metal grating structure provided by an embodiment of the present application;

图3为本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的示例一中步骤S302的样品截面图;3 is a cross-sectional view of a sample in step S302 in Example 1 of a method for fabricating an SPP coupler based on an asymmetric metal grating structure provided by an embodiment of the present application;

图4为本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的示例一中步骤S303进行蒸镀的示意图;4 is a schematic diagram of evaporation in step S303 in Example 1 of a method for fabricating an SPP coupler based on an asymmetric metal grating structure provided by an embodiment of the present application;

图5为本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的示例一中步骤S303的样品截面图;5 is a cross-sectional view of a sample in step S303 of Example 1 of a method for fabricating an SPP coupler based on an asymmetric metal grating structure provided by an embodiment of the present application;

图6为本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的示例一中步骤S303的样品俯视图;6 is a top view of a sample in step S303 of Example 1 of a method for fabricating an SPP coupler based on an asymmetric metal grating structure provided by an embodiment of the present application;

图7为本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的示例一的样品的SPP能流分布图;7 is an SPP energy flow distribution diagram of a sample of Example 1 of a method for fabricating an SPP coupler based on an asymmetric metal grating structure provided in an embodiment of the present application;

图8为本申请实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的示例二的样品截面图。FIG. 8 is a cross-sectional view of a sample of Example 2 of a method for fabricating an SPP coupler based on an asymmetric metal grating structure according to an embodiment of the present application.

具体实施方式Detailed ways

为了使本技术领域的人员更好地理解本申请方案,下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make those skilled in the art better understand the solutions of the present application, the technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present application. Obviously, the described embodiments are only It is a part of the embodiments of the present application, but not all of the embodiments. Based on the embodiments in the present application, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present application.

本实施例提供的一种基于非对称金属光栅结构的SPP耦合器,其由下至上依次设有衬底、介质光栅层、非对称金属光栅结构与介质填充层;This embodiment provides an SPP coupler based on an asymmetric metal grating structure, which is provided with a substrate, a dielectric grating layer, an asymmetric metal grating structure, and a dielectric filling layer in sequence from bottom to top;

介质光栅层包括若干个等距排列的介质光栅;The dielectric grating layer includes several dielectric gratings arranged at equal distances;

非对称金属光栅结构部分覆盖介质光栅表面,非对称金属光栅结构为倒“L”字型结构或“Z”字型结构。The asymmetric metal grating structure partially covers the surface of the dielectric grating, and the asymmetric metal grating structure is an inverted "L" shape structure or a "Z" shape structure.

在本实施例中,当入射光通过介质填充层后进入介质光栅层,通过设置非对称金属光栅结构为倒“L”字型结构或“Z”字型结构,从而使得入射光可以垂直射入衬底,激发SPP,无需倾斜入射激发,可大幅降低外置光路的复杂性;而介质光栅层具有若干个周期性的介质光栅,周期性的介质光栅结构可以实现较高的光耦合效率,且可以较好的将入射光限制于衬底内进行单向传播,从而可以提高光耦合效率与单向比,另外,本实施例的SPP耦合器结构简单,制作难度低,适于批量生产。In this embodiment, when the incident light enters the dielectric grating layer after passing through the dielectric filling layer, the asymmetric metal grating structure is set to be an inverted "L"-shaped structure or a "Z"-shaped structure, so that the incident light can enter vertically. The substrate can excite SPP without oblique incident excitation, which can greatly reduce the complexity of the external optical path; while the dielectric grating layer has several periodic dielectric gratings, the periodic dielectric grating structure can achieve high optical coupling efficiency, and The incident light can be better confined in the substrate for unidirectional propagation, thereby improving the optical coupling efficiency and the unidirectional ratio. In addition, the SPP coupler of this embodiment has a simple structure and low manufacturing difficulty, and is suitable for mass production.

以上为本申请提供的一种基于非对称金属光栅结构的SPP耦合器的一个实施例,以下为本申请提供的一种基于非对称金属光栅结构的SPP耦合器的另一个实施例。The above is an embodiment of an SPP coupler based on an asymmetric metal grating structure provided by the present application, and the following is another embodiment of an SPP coupler based on an asymmetric metal grating structure provided by the present application.

本实施例提供的一种基于非对称金属光栅结构的SPP耦合器,其由下至上依次设有衬底、介质光栅层、非对称金属光栅结构与介质填充层;This embodiment provides an SPP coupler based on an asymmetric metal grating structure, which is provided with a substrate, a dielectric grating layer, an asymmetric metal grating structure, and a dielectric filling layer in sequence from bottom to top;

介质光栅层包括若干个等距排列的介质光栅;The dielectric grating layer includes several dielectric gratings arranged at equal distances;

非对称金属光栅结构部分覆盖介质光栅表面,非对称金属光栅结构为倒“L”字型结构或“Z”字型结构。The asymmetric metal grating structure partially covers the surface of the dielectric grating, and the asymmetric metal grating structure is an inverted "L" shape structure or a "Z" shape structure.

进一步地,介质光栅的折射率为1.4~1.7,介质光栅的宽度为75~200nm,介质光栅的高度为75~300nm,介质光栅层的光栅周期为300~800nm。Further, the refractive index of the dielectric grating is 1.4-1.7, the width of the dielectric grating is 75-200 nm, the height of the dielectric grating is 75-300 nm, and the grating period of the dielectric grating layer is 300-800 nm.

进一步地,介质光栅层的光栅周期为400-600nm。Further, the grating period of the dielectric grating layer is 400-600 nm.

进一步地,介质填充层可以起到波导与提高耦合效率的作用,通过限定介质填充层的厚度来限定入射光的单向耦合效率与单向比,调控SPP的传播方向,在本实施例中,介质填充层相对于非对称金属光栅结构表面以上的结构厚度为50-800nm。Further, the dielectric filling layer can play the role of waveguide and improve the coupling efficiency. By limiting the thickness of the dielectric filling layer, the one-way coupling efficiency and one-way ratio of the incident light are limited, and the propagation direction of the SPP is regulated. In this embodiment, The thickness of the dielectric filling layer above the surface of the asymmetric metal grating structure is 50-800 nm.

进一步地,衬底可以为石英、云母、PDMS、蓝宝石或其它波长在300-1600nm范围内的具有高透射率的材料。Further, the substrate may be quartz, mica, PDMS, sapphire or other materials with high transmittance in the wavelength range of 300-1600 nm.

进一步地,介质光栅的介质材料可以采用光刻胶、SiO2、SiNx、ITO或AlN。Further, the dielectric material of the dielectric grating can be photoresist, SiO2, SiNx, ITO or AlN.

进一步地,非对称金属光栅结构的金属度大于50nm,非对称金属光栅结构的金属厚度为70~150nm。Further, the metal degree of the asymmetric metal grating structure is greater than 50 nm, and the metal thickness of the asymmetric metal grating structure is 70-150 nm.

以上为本申请提供的一种基于非对称金属光栅结构的SPP耦合器的另一个实施例,以下为本申请提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的一个实施例。The above is another embodiment of the SPP coupler based on the asymmetric metal grating structure provided by the present application, and the following is an embodiment of the manufacturing method of the SPP coupler based on the asymmetric metal grating structure provided by the present application.

为了方便理解,请参阅图1,本实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法,包括以下步骤:For easy understanding, please refer to FIG. 1 , a method for fabricating an SPP coupler based on an asymmetric metal grating structure provided in this embodiment includes the following steps:

S101:在衬底上形成具有若干个等距排列的介质光栅的介质光栅层;S101: forming a dielectric grating layer having a plurality of dielectric gratings arranged at equal distances on a substrate;

需要说明的是,衬底可以为石英、云母、PDMS、蓝宝石或其它波长在300-1600nm范围内的具有高透射率的材料;同时,介质光栅材料可以采用光刻胶、SiO2、SiNx、ITO或AlN等。It should be noted that the substrate can be quartz, mica, PDMS, sapphire or other materials with high transmittance in the wavelength range of 300-1600nm; meanwhile, the dielectric grating material can be photoresist, SiO2, SiNx, ITO or AlN et al.

S102:在介质光栅层上形成非对称金属光栅结构,非对称金属光栅结构部分覆盖介质光栅表面,同时,非对称金属光栅结构为倒“L”字型结构或“Z”字型结构;S102: forming an asymmetric metal grating structure on the dielectric grating layer, the asymmetric metal grating structure partially covers the surface of the dielectric grating, and at the same time, the asymmetric metal grating structure is an inverted "L" shape structure or a "Z" shape structure;

S103:在非对称金属光栅结构的所在空间填充介质并形成介质填充层,介质填充层覆盖非对称金属光栅结构与介质光栅层表面;S103: filling a medium in the space where the asymmetric metal grating structure is located and forming a medium filling layer, and the medium filling layer covers the surface of the asymmetric metal grating structure and the dielectric grating layer;

S104:对经步骤S103获得的样品通过刻蚀工艺刻蚀出耦合器的独立单元。S104: Etch the independent unit of the coupler through an etching process on the sample obtained in step S103.

需要说明的是,步骤S104也可以在步骤S101或步骤S102后完成。It should be noted that step S104 may also be completed after step S101 or step S102.

本实施例提供的制作方法简单易行,降低了制作难度,适用于大批量生产制造。The manufacturing method provided in this embodiment is simple and easy to implement, reduces the manufacturing difficulty, and is suitable for mass production.

以上为本申请提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法一个实施例,以下为本申请提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法的另一个实施例。The above is an embodiment of the method for fabricating an SPP coupler based on an asymmetric metal grating structure provided by the present application, and the following is another implementation of the method for fabricating an SPP coupler based on an asymmetric metal grating structure provided by the present application. example.

本实施例提供的一种基于非对称金属光栅结构的SPP耦合器的制作方法,包括以下步骤:A method for fabricating an SPP coupler based on an asymmetric metal grating structure provided in this embodiment includes the following steps:

S201:在衬底上形成具有若干个等距排列的介质光栅的介质光栅层;S201: forming a dielectric grating layer having a plurality of dielectric gratings arranged at equal distances on a substrate;

需要说明的是,衬底可以为石英、云母、PDMS、蓝宝石或其它波长在300-1600nm范围内的具有高透射率的材料;同时,介质光栅材料可以采用光刻胶、SiO2、SiNx、ITO或AlN等。It should be noted that the substrate can be quartz, mica, PDMS, sapphire or other materials with high transmittance in the wavelength range of 300-1600nm; meanwhile, the dielectric grating material can be photoresist, SiO2, SiNx, ITO or AlN et al.

S202:在介质光栅层上形成非对称金属光栅结构,非对称金属光栅结构部分覆盖介质光栅表面,同时,非对称金属光栅结构为倒“L”字型结构或“Z”字型结构;S202: an asymmetric metal grating structure is formed on the dielectric grating layer, the asymmetric metal grating structure partially covers the surface of the dielectric grating, and at the same time, the asymmetric metal grating structure is an inverted "L" shape structure or a "Z" shape structure;

S203:在非对称金属光栅结构的所在空间填充介质并形成介质填充层,介质填充层覆盖非对称金属光栅结构与介质光栅层表面;S203 : filling a medium in the space where the asymmetric metal grating structure is located and forming a medium filling layer, and the medium filling layer covers the surface of the asymmetric metal grating structure and the dielectric grating layer;

S204:对经步骤S203获得的样品通过刻蚀工艺刻蚀出耦合器的独立单元。S204: Etch the independent unit of the coupler through an etching process on the sample obtained in step S203.

进一步地,步骤S201中形成介质光栅层的制作方法采用下列三种方法的任意一种:Further, the manufacturing method of forming the dielectric grating layer in step S201 adopts any one of the following three methods:

1)首先,在衬底的上表面通过旋涂方法形成光刻胶,然后,采用曝光与显影工艺形成具有光刻胶制成的介质光栅的介质光栅层;1) First, a photoresist is formed on the upper surface of the substrate by a spin coating method, and then an exposure and development process is used to form a dielectric grating layer with a dielectric grating made of the photoresist;

2)首先,在衬底的上表面形成介质层,介质层采用SiO2、SiNx、ITO或AlN材料制成,然后,在介质层上通过旋涂方法形成光刻胶,并通过曝光、显影形成光刻胶制成的介质光栅,最后,通过干法刻蚀工艺形成介质光栅层;2) First, a dielectric layer is formed on the upper surface of the substrate. The dielectric layer is made of SiO2, SiNx, ITO or AlN materials. Then, a photoresist is formed on the dielectric layer by spin coating, and photoresist is formed by exposure and development. A dielectric grating made of resist, and finally, a dielectric grating layer is formed by a dry etching process;

3)首先,在衬底的上表面形成介质层,介质层采用SiO2、SiNx、ITO或AlN材料制成,然后,在介质层上通过旋涂方法形成光刻胶,并通过纳米压印工艺形成光刻胶制成的介质光栅,最后,通过干法刻蚀工艺形成介质光栅层。3) First, a dielectric layer is formed on the upper surface of the substrate, and the dielectric layer is made of SiO2, SiNx, ITO or AlN materials, and then a photoresist is formed on the dielectric layer by spin coating, and formed by a nano-imprinting process A dielectric grating made of photoresist, and finally, a dielectric grating layer is formed by a dry etching process.

进一步地,步骤S202中采用倾斜蒸镀方法形成非对称金属光栅结构,具体包括:通过电子束坩埚发出电子束,并将经过步骤S201获得的样品以预设的倾斜角度相对电子束的出射方向倾斜设置,预设的倾斜角度可调,经过蒸镀后,介质光栅的表面上形成倒“L”或“Z”字型结构的非对称金属光栅结构。Further, in step S202, an asymmetrical metal grating structure is formed by an oblique evaporation method, which specifically includes: emitting an electron beam through an electron beam crucible, and inclining the sample obtained in step S201 with a preset angle of inclination relative to the outgoing direction of the electron beam Setting, the preset inclination angle can be adjusted, and after evaporation, an asymmetric metal grating structure with an inverted "L" or "Z" shape structure is formed on the surface of the dielectric grating.

需要说明的是,根据光栅的周期和占空比,来调整倾斜角度,优选,预设的倾斜角度为30°~60°。It should be noted that the tilt angle is adjusted according to the period and duty ratio of the grating. Preferably, the preset tilt angle is 30°˜60°.

进一步地,步骤S203中形成介质填充层的具体步骤包括:通过旋涂方法在非对称金属光栅结构与介质光栅层表面上形成表面平整的介质填充层,其中,旋涂的转速为4000~10000转/分钟,旋涂的次数为3~5次,介质填充层的介质为氢倍半硅氧烷。Further, the specific step of forming the dielectric filling layer in step S203 includes: forming a flat surface dielectric filling layer on the surface of the asymmetric metal grating structure and the dielectric grating layer by a spin coating method, wherein the rotation speed of the spin coating is 4000-10000 rpm /min, the times of spin coating are 3 to 5 times, and the medium of the medium filling layer is hydrogen silsesquioxane.

需要说明的是,采用旋涂方法制备介质填充层,使得工艺简单且工艺兼容性较高。It should be noted that the spin coating method is used to prepare the dielectric filling layer, so that the process is simple and the process compatibility is high.

以下为本实施例中的基于非对称金属光栅结构的SPP耦合器中关于介质光栅与非对称金属光栅结构的制作方法的部分实施示例。The following is a partial implementation example of the method for fabricating the dielectric grating and the asymmetric metal grating structure in the SPP coupler based on the asymmetric metal grating structure in this embodiment.

示例一Example 1

本示例提供的基于非对称金属光栅结构的SPP耦合器中关于介质光栅与非对称金属光栅结构的制作方法,包括以下步骤:The method for fabricating the dielectric grating and the asymmetric metal grating structure in the SPP coupler based on the asymmetric metal grating structure provided in this example includes the following steps:

S301:参见图2,在石英衬底11表面通过旋涂方法形成光刻胶12并烘干,其中,光刻胶的厚度为200nm;S301: Referring to FIG. 2, a photoresist 12 is formed on the surface of the quartz substrate 11 by a spin coating method and dried, wherein the thickness of the photoresist is 200 nm;

S302:参见图3,通过双光束干涉曝光和显影,形成具有光刻胶制成的介质光栅21得介质光栅层。其中,光栅周期为550nm,介质光栅的宽度为200nm;S302 : Referring to FIG. 3 , a dielectric grating layer having a dielectric grating 21 made of photoresist is formed through double-beam interference exposure and development. Among them, the grating period is 550nm, and the width of the dielectric grating is 200nm;

S303:参见图4,采用电子束坩埚2发出电子束进行蒸镀,箭头方向为电子束方向,将样品固定于倾斜固定装置31上,并将样品与电子束传输方向以一定倾斜角度相对设置,同时,介质光栅层朝电子束方向设置,同时,倾斜固定装置31的角度连续可调,蒸镀时,可根据非对称金属光栅结构41的厚度变化,通过外置遥控装置随时调整倾斜固定装置51的角度,如图5与图6所示,在介质光栅层上形成倒“L”结构的非对称金属光栅结构41,覆盖介质光栅21的一部分,其中,非对称金属光栅结构41的金属层厚度为200nm。S303: Referring to FIG. 4, the electron beam crucible 2 is used to emit electron beams for vapor deposition, and the arrow direction is the electron beam direction, the sample is fixed on the inclined fixing device 31, and the sample and the electron beam transmission direction are set relative to a certain inclined angle, At the same time, the dielectric grating layer is arranged in the direction of the electron beam, and at the same time, the angle of the tilting fixing device 31 is continuously adjustable. During evaporation, the tilting fixing device 51 can be adjusted at any time through the external remote control device according to the thickness change of the asymmetric metal grating structure 41. As shown in FIG. 5 and FIG. 6 , an asymmetric metal grating structure 41 with an inverted “L” structure is formed on the dielectric grating layer, covering a part of the dielectric grating 21 , wherein the thickness of the metal layer of the asymmetric metal grating structure 41 is is 200nm.

最后,按照上述步骤设计的结构,在工作时,由外置光源(例如单波长激光)垂直入射至结构表面,由“L”型的非对称金属光栅结构将外界光转化为SPP并耦合至衬底中传输,而不需倾斜入射激发,大幅降低了外置光路的复杂性。Finally, according to the structure designed in the above steps, during operation, an external light source (such as a single-wavelength laser) is vertically incident on the surface of the structure, and the "L"-shaped asymmetric metal grating structure converts the external light into SPP and couples it to the substrate Transmission in the bottom without oblique incidence excitation, greatly reducing the complexity of the external optical path.

另外,对上述步骤形成的耦合器的单向传输效果进行模拟,其中,耦合器对应的谐振波长为810nm,光垂直入射至耦合器表面。参见图7所示为周期性介质光栅结构(由于是周期结构,所以图7表示其中一个周期介质光栅结构)在入射光波长为810nm时,SPP的能流分布情况,其中图中右侧标尺表示SPP在x方向的能流强度,由图7可以看出,SPP主要分布于衬底表面约300nm范围内,且沿着x负方向传播。这相对于普通非周期性对称光栅在外界光入射后,其能流沿两个方向传播是不同的。即该本示例中的周期性介质光栅结构达到了SPP单向传输的效果,且可以较好地限制于衬底内约300nm的范围内进行单向传播。另外,在后续SPP信号提取时,只需在特定的位置打破传输条件即可,例如通过在衬底表面刻蚀槽结构,使得SPP通过散射光出射。In addition, the unidirectional transmission effect of the coupler formed in the above steps is simulated, wherein the resonant wavelength corresponding to the coupler is 810 nm, and the light is vertically incident on the surface of the coupler. Figure 7 shows the energy flow distribution of the SPP when the wavelength of the incident light is 810 nm for the periodic dielectric grating structure (because it is a periodic structure, so Figure 7 shows one of the periodic dielectric grating structures), in which the scale on the right side of the figure represents The energy flux intensity of SPP in the x-direction can be seen from Figure 7 that the SPP is mainly distributed in the range of about 300 nm on the surface of the substrate and propagates along the negative x-direction. Compared with ordinary aperiodic symmetric gratings, after the incident light, its energy flow is different in two directions. That is to say, the periodic dielectric grating structure in this example achieves the effect of unidirectional transmission of SPP, and can be better limited to a range of about 300 nm in the substrate for unidirectional transmission. In addition, in the subsequent SPP signal extraction, it is only necessary to break the transmission condition at a specific position, for example, by etching a groove structure on the surface of the substrate, so that the SPP can be emitted through scattered light.

示例二Example 2

为了方便理解,请参见图8,本示例提供的基于非对称金属光栅结构的SPP耦合器中关于介质光栅与非对称金属光栅结构的制作方法,包括以下步骤:For the convenience of understanding, please refer to FIG. 8. The method for fabricating the dielectric grating and the asymmetric metal grating structure in the SPP coupler based on the asymmetric metal grating structure provided in this example includes the following steps:

S401:在石英衬底61上磁控溅射形成SiO2介质层,SiO2介质层的厚度为75nm;S401: magnetron sputtering to form a SiO2 dielectric layer on the quartz substrate 61, and the thickness of the SiO2 dielectric layer is 75 nm;

S402:在SiO2介质层上通过旋涂方法形成PMMA,PMMA的厚度为100nm;S402: PMMA is formed on the SiO2 dielectric layer by spin coating, and the thickness of PMMA is 100 nm;

S403:通过纳米压印的方法形成PMMA的介质光栅,然后利用PMMA作为掩模,通过ICP刻蚀形成具有SiO2材料制成的介质光栅62的介质光栅层;S403 : forming a PMMA dielectric grating by nano-imprinting, and then using PMMA as a mask to form a dielectric grating layer with a dielectric grating 62 made of SiO2 material by ICP etching;

S404:如采用倾斜蒸镀方法,在介质光栅62上形成“Z”字型的非对称金属光栅结构63,其中,非对称金属光栅结构63的金属层厚度为75nm。S404 : For example, by adopting an oblique evaporation method, a "Z"-shaped asymmetric metal grating structure 63 is formed on the dielectric grating 62 , wherein the thickness of the metal layer of the asymmetric metal grating structure 63 is 75 nm.

在本申请所提供的几个实施例中,应该理解到,所揭露的装置和方法,可以通过其它的方式实现。例如,以上所描述的装置实施例仅仅是示意性的,例如,所述单元的划分,仅仅为一种逻辑功能划分,实际实现时可以有另外的划分方式,例如多个单元或组件可以结合或者可以集成到另一个系统,或一些特征可以忽略,或不执行。另一点,所显示或讨论的相互之间的耦合或直接耦合或通信连接可以是通过一些接口,装置或单元的间接耦合或通信连接,可以是电性,机械或其它的形式。In the several embodiments provided in this application, it should be understood that the disclosed apparatus and method may be implemented in other manners. For example, the apparatus embodiments described above are only illustrative. For example, the division of the units is only a logical function division. In actual implementation, there may be other division methods. For example, multiple units or components may be combined or Can be integrated into another system, or some features can be ignored, or not implemented. On the other hand, the shown or discussed mutual coupling or direct coupling or communication connection may be through some interfaces, indirect coupling or communication connection of devices or units, and may be in electrical, mechanical or other forms.

所述作为分离部件说明的单元可以是或者也可以不是物理上分开的,作为单元显示的部件可以是或者也可以不是物理单元,即可以位于一个地方,或者也可以分布到多个网络单元上。可以根据实际的需要选择其中的部分或者全部单元来实现本实施例方案的目的。The units described as separate components may or may not be physically separated, and components displayed as units may or may not be physical units, that is, may be located in one place, or may be distributed to multiple network units. Some or all of the units may be selected according to actual needs to achieve the purpose of the solution in this embodiment.

另外,在本申请各个实施例中的各功能单元可以集成在一个处理单元中,也可以是各个单元单独物理存在,也可以两个或两个以上单元集成在一个单元中。上述集成的单元既可以采用硬件的形式实现,也可以采用软件功能单元的形式实现。In addition, each functional unit in each embodiment of the present application may be integrated into one processing unit, or each unit may exist physically alone, or two or more units may be integrated into one unit. The above-mentioned integrated units may be implemented in the form of hardware, or may be implemented in the form of software functional units.

以上所述,以上实施例仅用以说明本申请的技术方案,而非对其限制;尽管参照前述实施例对本申请进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本申请各实施例技术方案的精神和范围。As mentioned above, the above embodiments are only used to illustrate the technical solutions of the present application, but not to limit them; although the present application has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand: The technical solutions described in the embodiments are modified, or some technical features thereof are equivalently replaced; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the spirit and scope of the technical solutions in the embodiments of the present application.

Claims (8)

1. The SPP coupler based on the asymmetric metal grating structure is characterized in that a substrate, a medium grating layer, the asymmetric metal grating structure and a medium filling layer are sequentially arranged from bottom to top;
the medium grating layer comprises a plurality of medium gratings which are arranged at equal intervals;
the asymmetric metal grating structure partially covers the surface of the medium grating, and is of an inverted L-shaped structure or a Z-shaped structure;
the refractive index of the medium grating is 1.4-1.7, the width of the medium grating is 75-200 nm, the height of the medium grating is 75-300 nm, and the grating period of the medium grating layer is 300-800 nm;
the thickness of the medium filling layer relative to the structure above the surface of the asymmetric metal grating structure is 50-800 nm.
2. The SPP coupler based on the asymmetric metal grating structure as recited in claim 1, wherein the grating period of the medium grating layer is 400-600 nm.
3. The SPP coupler based on the asymmetric metal grating structure of claim 1, wherein the metal degree of the asymmetric metal grating structure is larger than 50nm, and the metal thickness of the asymmetric metal grating structure is 70-150 nm.
4. The manufacturing method of the SPP coupler based on the asymmetric metal grating structure is characterized by comprising the following steps of:
s101: forming a medium grating layer with a plurality of medium gratings arranged at equal intervals on a substrate, wherein the refractive index of the medium grating is 1.4-1.7, the width of the medium grating is 75-200 nm, the height of the medium grating is 75-300 nm, and the grating period of the medium grating layer is 300-800 nm;
s102: forming an asymmetric metal grating structure on the medium grating layer, wherein the asymmetric metal grating structure partially covers the surface of the medium grating, and meanwhile, the asymmetric metal grating structure is an inverted L-shaped structure or a Z-shaped structure;
s103: filling a medium in the space where the asymmetric metal grating structure is located and forming a medium filling layer, wherein the medium filling layer covers the asymmetric metal grating structure and the surface of the medium grating structure, and the thickness of the medium filling layer relative to the structure above the surface of the asymmetric metal grating structure is 50-800 nm;
s104: and etching the independent unit of the coupler by an etching process on the sample obtained in the step S103.
5. The method for manufacturing an SPP coupler based on an asymmetric metal grating structure as claimed in claim 4, wherein the method for manufacturing the medium grating layer in step S101 adopts any one of the following three methods:
1) firstly, forming photoresist on the upper surface of the substrate by a spin coating method, and then forming a medium grating layer with the medium grating made of the photoresist by adopting an exposure and development process;
2) firstly, forming a dielectric layer on the upper surface of the substrate, wherein the dielectric layer is made of SiO2, SiNx, ITO or AlN materials, then forming photoresist on the dielectric layer by a spin coating method, forming the dielectric grating made of the photoresist by exposure and development, and finally forming the dielectric grating layer by a dry etching process;
3) firstly, forming a dielectric layer on the upper surface of the substrate, wherein the dielectric layer is made of SiO2, SiNx, ITO or AlN materials, then forming photoresist on the dielectric layer through a spin coating method, forming the dielectric grating made of the photoresist through a nano-imprinting process, and finally forming the dielectric grating layer through a dry etching process.
6. The method for manufacturing an SPP coupler based on an asymmetric metal grating structure according to claim 4, wherein the step S102 is performed by an oblique evaporation method, and specifically includes: and emitting an electron beam through an electron beam crucible, obliquely arranging the sample obtained in the step S101 relative to the emergent direction of the electron beam at a preset inclination angle, wherein the preset inclination angle is adjustable, and after evaporation, forming an asymmetric metal grating structure with an inverted L-shaped or Z-shaped structure on the surface of the medium grating.
7. The method of claim 6, wherein the predetermined tilt angle is 30 ° to 60 °.
8. The method for manufacturing an SPP coupler based on an asymmetric metal grating structure as claimed in claim 4, wherein the step S103 of forming the dielectric filling layer comprises the following steps: and forming the medium filling layer with a smooth surface on the surface of the asymmetric metal grating structure and the surface of the medium grating layer by a spin coating method, wherein the spin coating speed is 4000-10000 r/min, the spin coating frequency is 3-5 times, and the medium of the medium filling layer is hydrogen silsesquioxane.
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