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CN111850736A - Conductive fiber, spinneret assembly and preparation method thereof - Google Patents

Conductive fiber, spinneret assembly and preparation method thereof Download PDF

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Publication number
CN111850736A
CN111850736A CN201910364989.7A CN201910364989A CN111850736A CN 111850736 A CN111850736 A CN 111850736A CN 201910364989 A CN201910364989 A CN 201910364989A CN 111850736 A CN111850736 A CN 111850736A
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Prior art keywords
spinneret
conductive
fiber
hole
fiber body
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CN201910364989.7A
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Inventor
冯培
杨崇倡
杨芊竹
张荣根
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Donghua University
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Donghua University
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

本发明公开了一种导电纤维、喷丝组件及制备方法,该导电纤维包括纤维本体,所述纤维本体的中部设置有中空部,所述纤维本体的中空部充满有导电物料。本发明的导电纤维,具有纯导电物料形成的连续导电芯,其具有超高的导电性,且其设备成本较低、占用空间小、易于控制。

Figure 201910364989

The invention discloses a conductive fiber, a spinneret assembly and a preparation method. The conductive fiber comprises a fiber body, a hollow part is arranged in the middle of the fiber body, and the hollow part of the fiber body is filled with conductive materials. The conductive fiber of the present invention has a continuous conductive core formed of pure conductive material, has ultra-high conductivity, and has low equipment cost, small occupied space and easy control.

Figure 201910364989

Description

导电纤维、喷丝组件及其制备方法Conductive fiber, spinneret assembly and preparation method thereof

技术领域technical field

本发明涉及一种纤维,特别涉及一种导电纤维、喷丝组件及制备方法。The invention relates to a fiber, in particular to a conductive fiber, a spinneret assembly and a preparation method.

背景技术Background technique

随着生活品质的提高,人们功能纤维的性能要求越来越高,如导电纤维。导电纤维具有远高于抗静电纤维的优异的消除和防止静电的性能。With the improvement of the quality of life, people have higher and higher requirements for the performance of functional fibers, such as conductive fibers. Conductive fibers have far superior performance in eliminating and preventing static electricity than antistatic fibers.

现有碳黑系纤维是将碳黑与成纤物质混合后采用皮芯纺丝法制成的导电纤维,但其缺乏韧性,不耐弯折,无热收缩能力,且涂覆在外层的碳黑易脱落,降低导电性能,且其纺制过程不易控制;现有导电型金属化合物纤维采用金属物料与聚合物熔体共混的方法纺制,其在聚合物熔体中混入导电金属介质,成本高昂,且其纺制过程不易控制;现有导电高分子型纤维,由聚乙炔、聚苯胺、聚吡咯、聚噻吩等高分子导电材料直接纺丝制成的有机导电纤维,但需要专用设备与组件,致使纺丝困难,成本上升。Existing carbon black fiber is a conductive fiber made by mixing carbon black and fiber-forming material by skin-core spinning method, but it lacks toughness, is not resistant to bending, and has no heat shrinkage ability, and the outer layer of carbon black is coated. It is easy to fall off, reducing the electrical conductivity, and the spinning process is not easy to control; the existing conductive metal compound fibers are spun by the method of blending metal materials and polymer melts, and the conductive metal medium is mixed into the polymer melt. High cost, and its spinning process is not easy to control; the existing conductive polymer fibers, organic conductive fibers directly spun from polymer conductive materials such as polyacetylene, polyaniline, polypyrrole, polythiophene, etc., require special equipment and components, making spinning difficult and costs rising.

发明内容SUMMARY OF THE INVENTION

为解决上述问题,本发明提供一种导电纤维,减少导电物料的用量,保证导电性能。本发明还提供导电纤维的喷丝组件及其制备方法。In order to solve the above problems, the present invention provides a conductive fiber, which can reduce the consumption of conductive materials and ensure the conductive performance. The present invention also provides a spinneret assembly of conductive fibers and a preparation method thereof.

为实现上述目的,本发明的导电纤维,包括纤维本体,所述纤维本体的中部设置有中空部,所述纤维本体的中空部充满有导电物料。In order to achieve the above object, the conductive fiber of the present invention includes a fiber body, a hollow portion is provided in the middle of the fiber body, and the hollow portion of the fiber body is filled with conductive material.

优选地,所述纤维本体由聚合物熔体凝固而成。Preferably, the fiber body is solidified from a polymer melt.

优选地,所述导电物料为石墨烯或碳黑或金属。Preferably, the conductive material is graphene or carbon black or metal.

本发明的制备所述导电纤维的喷丝组件,所述喷丝组件具有喷丝孔和入料管,所述喷丝孔包括导孔和与所述导孔底部相连的喷丝微孔,所述入料管的底部设有出料口,所述入料管贯穿所述导孔,所述出料口置于所述喷丝微孔中,所述出料口缩进于所述喷丝微孔的出口。The spinneret assembly of the present invention for preparing the conductive fiber has a spinneret hole and a feeding pipe, the spinneret hole includes a guide hole and a spinneret micro-hole connected to the bottom of the guide hole, so The bottom of the feed pipe is provided with a discharge port, the feed pipe runs through the guide hole, the discharge port is placed in the spinneret micro-hole, and the discharge port is indented in the spinneret Micropore outlet.

本发明的制备所述导电纤维的方法,采用所述喷丝组件,将聚合物熔体通入所述喷丝孔内,将导电物料制成气雾状或液状,然后通入所述入料管内。In the method for preparing the conductive fiber of the present invention, the spinneret assembly is used, the polymer melt is passed into the spinneret hole, the conductive material is made into aerosol or liquid state, and then passed into the feed material inside the tube.

本发明的导电纤维,将导电物料充满在纤维本体内部,在纤维内部形成由导电物料构成的连续导电芯,其具有超高的导电性。且其设备成本较低、占用空间小、易于控制。In the conductive fiber of the present invention, the conductive material is filled in the fiber body, and a continuous conductive core composed of the conductive material is formed in the fiber, which has ultra-high conductivity. And its equipment cost is low, the space is small, and it is easy to control.

附图说明Description of drawings

图1为本发明的导电纤维的结构示意图;Fig. 1 is the structural representation of the conductive fiber of the present invention;

图2为喷丝组件的示意图。Figure 2 is a schematic diagram of a spinneret assembly.

具体实施方式Detailed ways

下面参照附图详细地说明本发明的具体实施方式。Specific embodiments of the present invention will be described in detail below with reference to the accompanying drawings.

如图1所示,本发明的导电纤维,包括纤维本体10,所述纤维本体10的中部设置有中空部,所述纤维本体10的中空部充满有导电物料11。所述导电物料11可以是石墨烯或碳黑,还可以是金属。As shown in FIG. 1 , the conductive fiber of the present invention includes a fiber body 10 , a hollow portion is provided in the middle of the fiber body 10 , and the hollow portion of the fiber body 10 is filled with conductive material 11 . The conductive material 11 can be graphene or carbon black, and can also be metal.

所述纤维本体10由聚合物熔体凝固而成。所述聚合物熔体可以是涤纶、锦纶、丙纶。The fiber body 10 is solidified from a polymer melt. The polymer melt can be polyester, nylon, polypropylene.

如图2所示,本发明的制备所述导电纤维的喷丝组件,所述喷丝组件具有喷丝孔和入料管200,所述喷丝孔包括导孔301和与所述导孔301底部相连的喷丝微孔302,所述入料管200的底部设有出料口203,所述入料管200贯穿所述导孔301,所述出料口203置于所述喷丝微孔302中,所述出料口203缩进于所述喷丝微孔302的出口,为流经出料口203外部的熔体提供外部压力。所述出料口203相对于所述喷丝微孔302的出口的缩进量为0.1~0.5mm。所述入料管200的顶部设有锥销201,与物料流道101内的锥孔相配合。所述物料流道101设于组件内,用于连通组件入料口与入料管200,所述物料流道101与熔体流道100开设在同一分配板的不同区域内,用以形成密闭且相互隔断的流体通路和物料通路,在其入料口处可通入气雾状或液状导电物料,并通过气泵或液泵将其压入物料流道101,所述气泵或液泵可控制导电物料的入料量。所述锥销201顶部设有进料口202,导电物料在压力下历经物料流道101后经进料口202进入入料管200。所述入料管200通过锥销201与物料流道101的配合来实现在所述喷丝组件中的固定。As shown in FIG. 2 , the spinneret assembly for preparing the conductive fiber of the present invention has a spinneret hole and a feeding pipe 200 , and the spinneret hole includes a guide hole 301 and a connection with the guide hole 301 The spinneret micro-holes 302 connected at the bottom, the feed pipe 200 is provided with a discharge port 203 at the bottom, the feed pipe 200 penetrates the guide hole 301, and the discharge port 203 is placed in the spinneret micro-hole 301. In the hole 302 , the discharge port 203 is retracted at the outlet of the spinneret micro-hole 302 to provide external pressure for the melt flowing through the outside of the discharge port 203 . The indentation of the discharge port 203 relative to the outlet of the spinneret micro-hole 302 is 0.1-0.5 mm. The top of the feeding pipe 200 is provided with a tapered pin 201 , which is matched with the tapered hole in the material flow channel 101 . The material flow channel 101 is set in the component and is used to connect the component inlet and the feeding pipe 200. The material flow channel 101 and the melt flow channel 100 are opened in different areas of the same distribution plate to form a closed And the fluid passage and the material passage which are isolated from each other, can pass aerosol or liquid conductive material at the feed port, and press it into the material flow passage 101 through an air pump or a liquid pump, which can be controlled by the air pump or the liquid pump. The feeding amount of conductive material. The top of the taper pin 201 is provided with a feeding port 202 , and the conductive material passes through the material flow channel 101 under pressure and then enters the feeding pipe 200 through the feeding port 202 . The feed pipe 200 is fixed in the spinneret assembly through the cooperation of the tapered pin 201 and the material flow channel 101 .

本发明的制备所述导电纤维的方法,采用所述喷丝组件,将聚合物熔体通过熔体流道100持续通入所述喷丝孔内,将导电物料制成气雾状或液状,然后通过气泵或液泵主动通入所述物料通路101,最后通入入料管200内。In the method for preparing the conductive fiber of the present invention, the spinneret assembly is used to continuously pass the polymer melt into the spinneret hole through the melt flow channel 100, and the conductive material is made into an aerosol or liquid state, Then, it is actively passed into the material passage 101 through an air pump or a liquid pump, and finally passed into the feeding pipe 200 .

原料母粒经由高温融化形成聚合物熔体,经由喷丝组件之后凝固成纤维本体10,所述纤维本体10由同聚合物熔体凝固而成。聚合物熔体从入料管200的周围进入到喷丝孔,导电物料被制成气雾状或液状通入到入料管200内,聚合物熔体在喷丝微孔302的出口处从入料管200的周围流出,导电物料从入料管200的出料口202喷出并填充到聚合物熔体的中部,导电物料不断被填充入聚合物熔体中,形成连续导电芯。The raw material masterbatch is melted at high temperature to form a polymer melt, and after passing through a spinneret assembly, it is solidified into a fiber body 10, and the fiber body 10 is solidified from the same polymer melt. The polymer melt enters the spinneret hole from the periphery of the feed pipe 200 , the conductive material is made into aerosol or liquid and is introduced into the feed pipe 200 , and the polymer melt flows from the outlet of the spinneret microhole 302 . The surrounding of the feeding pipe 200 flows out, and the conductive material is sprayed from the discharge port 202 of the feeding pipe 200 and filled into the middle of the polymer melt, and the conductive material is continuously filled into the polymer melt to form a continuous conductive core.

如上所述,参照附图对本发明的示例性具体实施方式进行了详细的说明。应当了解,本发明并非意在使这些具体细节来构成对本发明保护范围的限制。在不背离根据本发明的精神和范围的情况下,可对示例性具体实施方式的结构和特征进行等同或类似的改变,这些改变将也落在本发明所附的权利要求书所确定的保护范围内。As described above, the exemplary embodiments of the present invention have been described in detail with reference to the accompanying drawings. It should be understood that these specific details are not intended to limit the scope of the invention. Equivalent or similar changes may be made in the structures and features of the exemplary embodiments without departing from the spirit and scope of the invention, and such changes will also fall within the protection defined by the appended claims. within the range.

Claims (5)

1. The conductive fiber is characterized by comprising a fiber body, wherein a hollow part is arranged in the middle of the fiber body, and the hollow part of the fiber body is filled with a conductive material.
2. The conductive fiber of claim 1, wherein the fiber body is solidified from a polymer melt.
3. The conductive fiber of claim 1, wherein the conductive material is graphene or carbon black or a metal.
4. A spinneret assembly for preparing the conductive fiber according to claim 1, wherein said spinneret assembly has a spinneret hole and a feeding tube, said spinneret hole comprises a guiding hole and a spinneret micropore connected with the bottom of said guiding hole, said feeding tube has a discharging hole at the bottom, said feeding tube penetrates said guiding hole, said discharging hole is placed in said spinneret micropore, said discharging hole is retracted in the outlet of said spinneret micropore.
5. A process for preparing the electrically conductive fibers of claim 1, wherein the spinneret pack of claim 4 is used, the polymer melt is passed into the spinneret holes, the electrically conductive material is made into an aerosol or liquid form and then passed into the feed tube.
CN201910364989.7A 2019-04-30 2019-04-30 Conductive fiber, spinneret assembly and preparation method thereof Pending CN111850736A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113235178A (en) * 2021-06-03 2021-08-10 四川亿耐特新材料有限公司 Bi-component spinneret plate
CN114438612A (en) * 2020-11-05 2022-05-06 江苏新视界先进功能纤维创新中心有限公司 Conductive fiber and preparation method thereof

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CN86105231A (en) * 1985-08-27 1987-03-11 帝人株式会社 Electrically conductive composite fibre and preparation method thereof
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JPH02200827A (en) * 1989-01-27 1990-08-09 Toyobo Co Ltd Electroconductive combined filament yarn and production thereof
IE902617A1 (en) * 1989-07-19 1991-02-27 Inventa Ag "Apparatus and method for the spinning of core/sheath fibres"
JPH03104912A (en) * 1989-09-13 1991-05-01 Tanaka Kikinzoku Kogyo Kk Spinneret apparatus for spinning sheath-core conjugate yarn
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CN101050555A (en) * 2007-04-28 2007-10-10 江苏盛虹化纤有限公司 Antistatic short fiber
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114438612A (en) * 2020-11-05 2022-05-06 江苏新视界先进功能纤维创新中心有限公司 Conductive fiber and preparation method thereof
CN113235178A (en) * 2021-06-03 2021-08-10 四川亿耐特新材料有限公司 Bi-component spinneret plate
CN113235178B (en) * 2021-06-03 2022-08-02 四川亿耐特新材料有限公司 Bi-component spinneret assembly

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Application publication date: 20201030