CN111777964A - A kind of self-adhesive modified asphalt building waterproofing membrane and preparation method and construction method - Google Patents
A kind of self-adhesive modified asphalt building waterproofing membrane and preparation method and construction method Download PDFInfo
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- 239000010426 asphalt Substances 0.000 title claims abstract description 96
- 238000004078 waterproofing Methods 0.000 title claims abstract description 75
- 239000012528 membrane Substances 0.000 title claims abstract description 69
- 239000000853 adhesive Substances 0.000 title claims abstract description 50
- 238000010276 construction Methods 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000010410 layer Substances 0.000 claims abstract description 34
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract description 23
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 20
- 229920000570 polyether Polymers 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000012790 adhesive layer Substances 0.000 claims abstract description 16
- 238000002955 isolation Methods 0.000 claims abstract description 13
- 230000001681 protective effect Effects 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 150000001412 amines Chemical class 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims description 16
- 235000015110 jellies Nutrition 0.000 claims description 16
- 239000008274 jelly Substances 0.000 claims description 16
- 229920001971 elastomer Polymers 0.000 claims description 13
- 239000005060 rubber Substances 0.000 claims description 13
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 9
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 9
- 239000010425 asbestos Substances 0.000 claims description 8
- 239000000440 bentonite Substances 0.000 claims description 8
- 229910000278 bentonite Inorganic materials 0.000 claims description 8
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 8
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- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 claims description 5
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- 229920005862 polyol Polymers 0.000 claims description 4
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- 238000000227 grinding Methods 0.000 claims description 3
- AOFIWCXMXPVSAZ-UHFFFAOYSA-N 4-methyl-2,6-bis(methylsulfanyl)benzene-1,3-diamine Chemical compound CSC1=CC(C)=C(N)C(SC)=C1N AOFIWCXMXPVSAZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002799 BoPET Polymers 0.000 claims description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000010920 waste tyre Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 1
- DYFFAVRFJWYYQO-UHFFFAOYSA-N n-methyl-n-phenylaniline Chemical class C=1C=CC=CC=1N(C)C1=CC=CC=C1 DYFFAVRFJWYYQO-UHFFFAOYSA-N 0.000 claims 1
- 229920002396 Polyurea Polymers 0.000 abstract description 6
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- 230000007613 environmental effect Effects 0.000 abstract description 4
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- 230000000052 comparative effect Effects 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
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- 230000007423 decrease Effects 0.000 description 2
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- 239000012943 hotmelt Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
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- 238000005096 rolling process Methods 0.000 description 2
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- 239000002904 solvent Substances 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- BWLKKFSDKDJGDZ-UHFFFAOYSA-N [isocyanato(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(N=C=O)C1=CC=CC=C1 BWLKKFSDKDJGDZ-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- 239000003292 glue Substances 0.000 description 1
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- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
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- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
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- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02B—HYDRAULIC ENGINEERING
- E02B3/00—Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
- E02B3/16—Sealings or joints
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- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D31/00—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
- E02D31/02—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution against ground humidity or ground water
- E02D31/025—Draining membranes, sheets or fabric specially adapted therefor, e.g. with dimples
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
本发明属于建筑防水材料领域,公开一种自粘性改性沥青建筑防水卷材及制备方法和施工方法;自粘性改性沥青建筑防水卷材:包括改性沥青层、粘接层以及敷于粘接层的隔离防护膜;其中,粘接层在丁基橡胶自粘层中预先植入了聚氨酯预聚体,其在施工时,通过在建筑基面预先喷洒一层端氨基聚醚与液态胺的分散液,使得在丁基橡胶粘接的同时,聚氨酯预聚体迅速与建筑基面的端氨基聚醚、液态胺扩链形成聚脲层,聚脲疏水性极强,对环境湿度不敏感,在极端恶劣的环境条件下可正常施工,从而有效地将防水卷材粘合在建筑基面而不受基面含水的影响。
The invention belongs to the field of building waterproof materials, and discloses a self-adhesive modified bitumen building waterproofing membrane, a preparation method and a construction method; The isolation protective film of the bonding layer; wherein, the bonding layer is pre-implanted with a polyurethane prepolymer in the butyl rubber self-adhesive layer. During construction, a layer of amino-terminated polyether and liquid amine is pre-sprayed on the building base surface. The dispersion liquid of the butyl rubber makes the polyurethane prepolymer rapidly expand with the amino-terminated polyether and liquid amine on the building base surface to form a polyurea layer while the butyl rubber is bonded. The polyurea is extremely hydrophobic and insensitive to environmental humidity. , It can be constructed normally under extremely harsh environmental conditions, so as to effectively bond the waterproof membrane to the building base without being affected by the water on the base.
Description
技术领域technical field
本发明属于建筑防水材料领域,具体涉及建筑工程用的防水卷材,特别涉及一种自粘性改性沥青建筑防水卷材及制备方法和施工方法。The invention belongs to the field of building waterproof materials, in particular to a waterproof roll material for construction projects, in particular to a self-adhesive modified bitumen building waterproof roll material and a preparation method and a construction method.
背景技术Background technique
建筑防水作为目前建筑工程重要的施工部分,其防水效果随着新型材料技术的发展在防水性能、施工便利性等方面取得了巨大的突破。如刚性的砂浆防水剂、水泥基(刚性)防水涂料、渗透结晶性防水涂料;柔性的聚合物防水涂料、防水卷材在建筑物防水工程方面大规模应用。As an important construction part of current construction projects, building waterproofing has made great breakthroughs in waterproofing performance and construction convenience with the development of new material technology. Such as rigid mortar waterproofing agent, cement-based (rigid) waterproofing coating, permeable crystalline waterproofing coating; flexible polymer waterproofing coating and waterproofing membrane are widely used in building waterproofing engineering.
防水卷材作为可以大面积施工、高效隔水的材料,在建筑物地下室、隧道等防水要求高的领域使用量大。特别是防水卷材具有的柔性可以有效防止地下变形等造成的开裂,这是其他刚性防水材料难以达到的。目前常用的防水卷材主要有改性沥青防水卷材、聚乙烯丙纶防水卷材、PVC防水卷材、三元乙丙橡胶防水卷材等。根据使用实践,在大型地下工程、隧道等建筑防水施工中,改性沥青防水卷材成为首选。其主要原因是沥青防水卷材相比于其他卷材在自愈合方面表现优异,能够适应地下沉降变形等的防水。在出现破损微裂纹后,沥青的自流动可以实现自修复。As a material that can be constructed in a large area and has high water resistance, waterproof membrane is widely used in areas with high waterproof requirements such as building basements and tunnels. In particular, the flexibility of the waterproof membrane can effectively prevent cracking caused by underground deformation, which is difficult to achieve with other rigid waterproof materials. At present, the commonly used waterproofing membranes mainly include modified asphalt waterproofing membranes, polyethylene polypropylene waterproofing membranes, PVC waterproofing membranes, EPDM waterproofing membranes, etc. According to the use practice, in the waterproof construction of large-scale underground projects, tunnels and other buildings, the modified bitumen waterproofing membrane has become the first choice. The main reason is that the asphalt waterproofing membrane is superior in self-healing compared with other membranes, and can adapt to waterproofing such as underground subsidence deformation. After the occurrence of damaged micro-cracks, the self-flow of asphalt can achieve self-healing.
沥青卷材与建筑基面牢固的结合直接决定防水效果和防水耐久性。卷材与建筑基面紧密贴合粘接后,即使建筑基面开裂,沥青防水卷材会微变形密实修复裂纹;然而如果粘接不牢,则会使得卷材与建筑基面脱离形成空鼓,很容易窜水渗水。防水卷材在使用过程中的最大障碍是与基面之间的粘接问题。传统的沥青防水卷材施工主要是通过热喷枪加热卷材使表面热熔然后与建筑基层粘合。热熔法施工虽然成本低廉,但容易对卷材造成损伤,使表面老化;而且与建筑基面为一次性粘接,一旦粘接接触不紧密,会造成空鼓,难以修复,在空鼓处很容易窜水。The firm combination of the asphalt membrane and the building base directly determines the waterproof effect and waterproof durability. After the membrane and the building base are closely bonded and bonded, even if the building base is cracked, the asphalt waterproofing membrane will be slightly deformed and dense to repair the crack; however, if the bonding is not strong, the membrane will be separated from the building base to form an empty drum. , it is easy to channel water seepage. The biggest obstacle in the use of the waterproofing membrane is the bonding problem with the base surface. The traditional construction of asphalt waterproofing membrane is mainly to heat the membrane through a thermal spray gun to make the surface hot melt and then bond with the building base. Although the cost of hot-melt construction is low, it is easy to cause damage to the coil and make the surface aging; and it is one-time bonding with the building base. Once the bonding contact is not tight, it will cause hollowing, which is difficult to repair. It's easy to get water.
冷粘法是目前沥青防水卷材发展的主要方向。通过在卷材面设置粘接层,实现卷材自粘。目前在市场上自粘型的改性沥青基防水卷材被逐步推广使用。自粘型改性沥青基防水卷材一方面施工简单方便;另一方面与建筑基面粘合密实,不会形成空鼓;即使形成空鼓也可以通过后期检查补救排除。The cold bonding method is the main direction of the development of the asphalt waterproofing membrane at present. The self-adhesion of the coil is realized by setting the adhesive layer on the surface of the coil. At present, self-adhesive modified asphalt-based waterproofing membranes are gradually popularized and used in the market. On the one hand, the self-adhesive modified bitumen-based waterproofing membrane is simple and convenient to construct; on the other hand, it is tightly bonded to the building base surface and will not form hollow;
然而,现有自粘性改性沥青建筑防水卷材的粘接层主要是丁基橡胶、萜烯树脂、氢化松香、环烷油等的形成的胶黏物。粘接力主要是依靠粘结层与混凝土表面之间的范德华力或者氢键等次级键,是一种物理作用力,随着时间的增加,粘接力下降,最终产生鼓包、窜水问题;再者,自粘性沥青防水卷材对防水基面的施工要求比较严格,必须在完全平整、光洁、无水的基面上施工,否则就会出现分层、起鼓、窜水的状况。而大多数施工环境很难达到这些要求。特别是大部分施基面含水,会造成粘接牢固度的下降。However, the adhesive layer of the existing self-adhesive modified asphalt building waterproofing membrane is mainly an adhesive formed by butyl rubber, terpene resin, hydrogenated rosin, naphthenic oil and the like. The adhesive force mainly depends on the secondary bonds such as van der Waals force or hydrogen bond between the bonding layer and the concrete surface. Furthermore, the self-adhesive asphalt waterproofing membrane has strict requirements on the construction of the waterproof base surface. It is difficult for most construction environments to meet these requirements. In particular, most of the base surface contains water, which will cause a decrease in the bond strength.
发明内容SUMMARY OF THE INVENTION
针对目前自粘性改性沥青建筑防水卷材与建筑基面粘接牢固度不佳,以及在粘接施工时对建筑基面含水苛刻的要求;为了提升自粘性改性沥青建筑防水卷材的粘接性以及施工适应性,本发明提出一种自粘性改性沥青建筑防水卷材;进一步,提供自粘性改性沥青建筑防水卷材的制备方法和施工方法。In view of the poor bonding firmness between the self-adhesive modified asphalt building waterproofing membrane and the building base, and the harsh requirements for the water content of the building base during bonding construction; in order to improve the adhesion of the self-adhesive modified asphalt building waterproofing membrane The present invention provides a self-adhesive modified asphalt building waterproofing membrane material; furthermore, provides a preparation method and a construction method of the self-adhesive modified bitumen building waterproofing membrane material.
首先,本发明第一目的为一种自粘性改性沥青建筑防水卷材,其特征为:包括改性沥青层、粘接层以及敷于粘接层的隔离防护膜;其中:First of all, the first object of the present invention is a self-adhesive modified asphalt building waterproofing membrane, which is characterized by: comprising a modified asphalt layer, an adhesive layer and an isolation protective film applied to the adhesive layer; wherein:
所述改性沥青层由如下方法制备得到:The modified asphalt layer is prepared by the following method:
将3-5重量份石棉、1-3重量份纳米二氧化硅、5-10重量份再生橡胶粉、10-15重量份SBS、1-2重量份古马隆树脂、马来酸酐0.01-0.03重量份、抗氧化剂0.1-0.3重量份、3-5重量份膨润土、80-100重量份90号沥青材料加入混合机混合均匀,然后送入双螺杆挤出机熔融混炼,经“T”型模口挤出、三辊压延,得到厚度为1.0-2.0mm的改性沥青层;3-5 parts by weight of asbestos, 1-3 parts by weight of nano-silicon dioxide, 5-10 parts by weight of recycled rubber powder, 10-15 parts by weight of SBS, 1-2 parts by weight of coumarone resin, 0.01-0.03 parts by weight of maleic anhydride parts by weight, 0.1-0.3 parts by weight of antioxidants, 3-5 parts by weight of bentonite, 80-100 parts by weight of No. 90 bitumen materials are added to the mixer and mixed evenly, and then sent to a twin-screw extruder for melting and kneading. Die extrusion and three-roll calendering to obtain a modified asphalt layer with a thickness of 1.0-2.0 mm;
所述粘接层由如下方法制备得到:The adhesive layer is prepared by the following method:
将10-15重量份聚醚多元醇加入搅拌容器中,加热至110℃,然后真空脱水1h,降温至40-50℃,加入15-20重量份多异氰酸酯,在80℃反应1-2小时,在50℃保温1-3h,得到聚氨酯预聚物;将聚氨酯预聚物输入胶体研磨机,然后加入30-40重量份130号沥青、10-15重量份丁苯橡胶、5-10重量份松香树脂、15-20重量份芳烃油研磨为胶状物,作为粘接层;Add 10-15 parts by weight of polyether polyol into a stirring vessel, heat it to 110°C, then dehydrate in a vacuum for 1 hour, cool down to 40-50°C, add 15-20 parts by weight of polyisocyanate, and react at 80°C for 1-2 hours, Keep the temperature at 50°C for 1-3 hours to obtain a polyurethane prepolymer; input the polyurethane prepolymer into a colloid mill, and then add 30-40 parts by weight of No. 130 asphalt, 10-15 parts by weight of styrene-butadiene rubber, and 5-10 parts by weight of rosin The resin and 15-20 parts by weight of aromatic hydrocarbon oil are ground into a jelly, which is used as an adhesive layer;
所述隔离防护膜为PET 膜、PVC 膜、PP膜中的一种。The isolation protective film is one of PET film, PVC film and PP film.
优选的,所述抗氧化剂选用抗氧剂1010、抗氧剂168中的一种或两者的复合物。Preferably, the antioxidant is selected from one of antioxidant 1010 and antioxidant 168 or a combination of both.
优选的,所述再生胶橡胶粉为粒度小于100目的废旧轮胎研磨制备的再生橡胶,其主要是降低成本,增加卷材的韧性。Preferably, the reclaimed rubber rubber powder is reclaimed rubber prepared by grinding waste tires with a particle size of less than 100 mesh, which mainly reduces costs and increases the toughness of the coil.
优选的,所述纳米二氧化硅一方面可以增加卷材的致密性,纳米二氧化硅的加入利于与混凝土的结合。Preferably, on the one hand, the nano-silica can increase the compactness of the coil, and the addition of nano-silica is beneficial to the combination with concrete.
本发明第二目的为一种自粘性改性沥青建筑防水卷材的制备方法,其特征在于,具体制备方法如下:The second object of the present invention is a kind of preparation method of self-adhesive modified bitumen building waterproofing membrane, it is characterized in that, the concrete preparation method is as follows:
(1)将10-15重量份聚醚多元醇加入搅拌容器中,加热至110℃,然后真空脱水1h,降温至40-50℃,加入15-20重量份多异氰酸酯,在80℃反应1-2小时,在50℃保温1-3h,得到聚氨酯预聚物;将聚氨酯预聚物输入胶体研磨机,然后加入30-40重量份130号沥青、10-15重量份丁苯橡胶、5-10重量份松香树脂、15-20重量份芳烃油研磨为胶状物;(1) Add 10-15 parts by weight of polyether polyol into a stirring vessel, heat to 110°C, then dehydrate in vacuum for 1 hour, cool down to 40-50°C, add 15-20 parts by weight of polyisocyanate, and react at 80°C for 1- For 2 hours, keep the temperature at 50 °C for 1-3 hours to obtain a polyurethane prepolymer; input the polyurethane prepolymer into a colloid mill, and then add 30-40 parts by weight of No. 130 asphalt, 10-15 parts by weight of styrene-butadiene rubber, 5-10 parts by weight 15-20 parts by weight of rosin resin and 15-20 parts by weight of aromatic hydrocarbon oil are ground into jelly;
(2)将3-5重量份石棉、1-3重量份纳米二氧化硅、5-10重量份再生橡胶粉、10-15重量份SBS、1-2重量份古马隆树脂、马来酸酐0.01-0.03重量份、抗氧化剂0.1-0.3重量份、3-5重量份膨润土、80-100重量份90号沥青材料加入混合机混合均匀,然后送入双螺杆挤出机熔融混炼,经“T”型模口挤出、三辊压延,得到厚度为1.0-2.0mm的改性沥青层;(2) 3-5 parts by weight of asbestos, 1-3 parts by weight of nano-silicon dioxide, 5-10 parts by weight of recycled rubber powder, 10-15 parts by weight of SBS, 1-2 parts by weight of coumarone resin, maleic anhydride 0.01-0.03 parts by weight, 0.1-0.3 parts by weight of antioxidants, 3-5 parts by weight of bentonite, 80-100 parts by weight of No. 90 asphalt materials are added to the mixer and mixed evenly, and then sent to the twin-screw extruder for melting and kneading. T"-shaped die extrusion and three-roll calendering to obtain a modified asphalt layer with a thickness of 1.0-2.0mm;
(3)步骤(2)压延的改性沥青层趁热温将步骤(1)得到的胶状物刮涂在改性沥青层;然后敷隔离保护膜,滚筒平整,卷取,密封包装,得到一种自粘性改性沥青建筑防水卷材。(3) Step (2) The calendered modified asphalt layer is scraped and coated on the modified asphalt layer with the jelly obtained in step (1) while it is still hot; then an isolation protective film is applied, the roller is flattened, coiled, sealed and packaged to obtain A self-adhesive modified asphalt building waterproofing membrane.
优选的,所述双螺杆挤出机熔融混炼温度设置在130-140℃;所述三辊温度控制在50-60℃,温度过高会造成粘辊;温度过低会影响后序胶状物的粘合性。Preferably, the melting and kneading temperature of the twin-screw extruder is set at 130-140°C; the temperature of the three-roller is controlled at 50-60°C, if the temperature is too high, the rollers will stick; if the temperature is too low, the subsequent glue will be affected adhesiveness of the material.
进一步优选的,所述胶状物刮涂在改性沥青层,刮涂厚度为0.3-0.5mm。Further preferably, the jelly is blade-coated on the modified asphalt layer, and the blade-coating thickness is 0.3-0.5mm.
本发明第三目的为一种自粘性改性沥青建筑防水卷材的施工方法,其特征在于,具体施工方法为:The third object of the present invention is a kind of construction method of self-adhesive modified bitumen building waterproofing membrane, it is characterized in that, the concrete construction method is:
(1)清理施工基面的杂物、浮尘、水渍;(1) Clean up the sundries, floating dust and water stains on the construction base surface;
(2)将20-30重量份端氨基聚醚、10-15重量份液态胺分散均匀,在建筑基面喷覆湿润;(2) Disperse 20-30 parts by weight of amino-terminated polyether and 10-15 parts by weight of liquid amine evenly, and spray and wet the building base surface;
(3)揭去自粘性改性沥青建筑防水卷材的隔离防护膜,快速粘贴在基面,压实平整,完成铺贴。(3) Remove the isolation protective film of the self-adhesive modified asphalt building waterproofing membrane, quickly paste it on the base surface, compact and smooth, and complete the paving.
优选的,所述端氨基聚醚选用D-2000端氨基聚醚,由巴斯夫生产,D-2000端氨基聚醚是一种聚氨酯用活性扩链剂,可以快速扩链聚氨酯预聚体。Preferably, the amino-terminated polyether is D-2000 amino-terminated polyether produced by BASF. D-2000 amino-terminated polyether is an active chain extender for polyurethane, which can rapidly extend the chain of the polyurethane prepolymer.
优选的,所述液态胺选用二乙基甲苯二胺、二甲硫基甲苯二胺、N ,N’-二烷基甲基二苯胺中的一种。Preferably, the liquid amine is selected from the one in diethyltoluenediamine, dimethylthiotoluenediamine, N,N'-dialkylmethyldiphenylamine.
不同于常规的自粘沥青防水卷材,为了增加改性沥青防水卷材与建筑基面粘接牢固度,以及避免建筑基面含有的水分对粘接性的影响,本发明在丁基橡胶自粘层中预先植入了聚氨酯预聚体,其在施工时,通过在建筑基面预先喷洒一层端氨基聚醚与液态胺的分散液,使得在丁基橡胶粘接的同时,聚氨酯预聚体迅速与建筑基面的端氨基聚醚、液态胺扩链形成聚脲层,聚脲疏水性极强,对环境湿度不敏感,甚至可以在水上成膜,在极端恶劣的环境条件下可正常施工,从而有效地将卷材粘合在建筑基面而不受基面含水的影响。本发明得到的自粘性改性沥青建筑防水卷材适应性宽,特别适合在潮湿环境的施工,适用于地下室、人工湖、涵洞、隧洞、地铁等她下防水工程的防水以及环境复杂的防水施工。Different from the conventional self-adhesive bitumen waterproofing membrane, in order to increase the bonding firmness between the modified bitumen waterproofing membrane and the building base surface, and avoid the influence of the moisture contained in the building base surface on the adhesion, the present invention uses a butyl rubber self-adhesive solution. A polyurethane prepolymer is pre-implanted in the adhesive layer. During construction, a dispersion of amino-terminated polyether and liquid amine is pre-sprayed on the base surface of the building, so that when the butyl rubber is bonded, the polyurethane prepolymer is The body quickly expands with the amino-terminated polyether and liquid amine on the building base surface to form a polyurea layer. Polyurea is extremely hydrophobic and insensitive to environmental humidity. Construction, so as to effectively bond the coil to the building base without being affected by the moisture of the base. The self-adhesive modified asphalt building waterproofing membrane obtained by the invention has wide adaptability, is especially suitable for construction in humid environment, and is suitable for waterproofing of basements, artificial lakes, culverts, tunnels, subways and other underground waterproofing projects as well as waterproofing construction in complex environments .
一种自粘性改性沥青建筑防水卷材,与自粘性防水卷材相比,突出的技术优势体现在:A self-adhesive modified asphalt building waterproofing membrane, compared with the self-adhesive waterproofing membrane, the outstanding technical advantages are reflected in:
(1)本发明通过在自粘层预植聚氨酯预聚体,在施工时在建筑基面喷涂一层端氨基聚醚、液态胺分散液,其可以迅速使聚氨酯预聚体形成聚脲粘接在基面,其在潮湿环境适应性强,不会因环境潮湿影响粘接性。(1) In the present invention, the polyurethane prepolymer is pre-planted in the self-adhesive layer, and a layer of amino-terminated polyether and liquid amine dispersion is sprayed on the base surface of the building during construction, which can quickly make the polyurethane prepolymer form polyurea bonding On the base surface, it has strong adaptability in humid environment and will not affect the adhesion due to environmental humidity.
(2)本发明自粘性改性沥青建筑防水卷材适应性宽,特别适合在潮湿环境的施工,适用于地下室、人工湖、涵洞、隧洞、地铁等她下防水工程的防水以及环境复杂的防水施工。铺贴后不会因环境潮湿等鼓包、窜水,有效防止了水的渗入,即使渗入水也不会乱窜。(2) The self-adhesive modified asphalt building waterproofing membrane of the present invention has wide adaptability, is especially suitable for construction in humid environment, and is suitable for waterproofing of basements, artificial lakes, culverts, tunnels, subways and other underground waterproofing projects as well as waterproofing in complex environments construction. After paving, there will be no bulging or water channeling due to the humidity of the environment, which effectively prevents the infiltration of water, and even if it penetrates into the water, it will not run around.
(3)本发明自粘性改性沥青建筑防水卷材进一步拓展了防水卷材的使用环境,使得施工不再对建筑基面提出苛刻的要求,使得施工进度大幅提升。(3) The self-adhesive modified asphalt building waterproofing membrane of the present invention further expands the use environment of the waterproofing membrane, so that the construction no longer puts forward harsh requirements on the building base surface, and the construction progress is greatly improved.
附图说明Description of drawings
以下结合附图对本发明做进一步说明:The present invention will be further described below in conjunction with the accompanying drawings:
图1 是本发明一种自粘性改性沥青建筑防水卷材的示意图。1:改性沥青层;2:粘接层;3:隔离防护膜。Fig. 1 is a schematic diagram of a self-adhesive modified asphalt building waterproofing membrane of the present invention. 1: Modified asphalt layer; 2: Adhesive layer; 3: Isolation protective film.
具体实施方式Detailed ways
下面通过实施例旨在进一步描述本发明内容,而不是对本发明权利要求的保护范围的限制。The following examples are intended to further describe the content of the present invention, rather than limit the protection scope of the claims of the present invention.
实施例1Example 1
一种自粘性改性沥青建筑防水卷材的制备方法:A preparation method of self-adhesive modified asphalt building waterproofing membrane:
(1)将15重量份分子量3000的聚乙二醇醚聚加入搅拌容器中,加热至110℃,然后真空脱水1h,降温至40℃,加入20重量份4 ,4’-二苯基甲烷二异氰酸酯,在80℃反应2小时,在50℃保温1h,得到聚氨酯预聚物;将聚氨酯预聚物输入胶体研磨机,然后加入30重量份130号沥青、10重量份丁苯橡胶、10重量份松香树脂、20重量份芳烃油研磨为胶状物;(1) 15 parts by weight of polyethylene glycol ether with a molecular weight of 3000 was added to a stirring vessel, heated to 110°C, then dehydrated in a vacuum for 1 hour, cooled to 40°C, and added with 20 parts by weight of 4,4'-diphenylmethane diphenylmethane Isocyanate was reacted at 80 °C for 2 hours, and kept at 50 °C for 1 hour to obtain a polyurethane prepolymer; the polyurethane prepolymer was input into a colloid mill, and then 30 parts by weight of No. 130 asphalt, 10 parts by weight of styrene-butadiene rubber, 10 parts by weight of styrene-butadiene rubber were added. Rosin resin and 20 parts by weight of aromatic oil are ground into jelly;
(2)将5重量份石棉、1重量份纳米二氧化硅、5重量份再生橡胶粉、15重量份SBS、2重量份古马隆树脂、马来酸酐0.01重量份、1010抗氧化剂0.1重量份、3重量份膨润土、100重量份90号沥青材料加入混合机混合均匀,然后送入双螺杆挤出机在130-140℃熔融混炼,经“T”型模口挤出、三辊压延,三辊温度控制在50-60℃,得到厚度为2.0mm的改性沥青层;(2) 5 parts by weight of asbestos, 1 part by weight of nano-silica, 5 parts by weight of recycled rubber powder, 15 parts by weight of SBS, 2 parts by weight of coumarone resin, 0.01 part by weight of maleic anhydride, 0.1 part by weight of 1010 antioxidants , 3 parts by weight of bentonite, and 100 parts by weight of No. 90 bitumen material were added to the mixer to mix evenly, then sent to a twin-screw extruder for melting and kneading at 130-140°C, extruded through a "T" die, and rolled with three rolls. The temperature of the three rolls is controlled at 50-60°C to obtain a modified asphalt layer with a thickness of 2.0mm;
(3)步骤(2)压延的改性沥青层趁热温将步骤(1)得到的胶状物刮涂在改性沥青层,刮涂厚度为0.5mm;然后敷PET 膜,滚筒平整,卷取,密封包装,得到一种自粘性改性沥青建筑防水卷材。(3) Step (2) The calendered modified asphalt layer is scraped on the modified asphalt layer with the jelly obtained in step (1) while it is still hot, with a thickness of 0.5mm; Take, seal and package to obtain a self-adhesive modified asphalt building waterproofing membrane.
施工方法:Construction method:
(1)清理施工基面的杂物、浮尘、水渍;(1) Clean up the sundries, floating dust and water stains on the construction base surface;
(2)将30重量份D-2000端氨基聚醚、15重量份二乙基甲苯二胺分散均匀,在建筑基面喷覆湿润;(2) Disperse 30 parts by weight of D-2000 amino-terminated polyether and 15 parts by weight of diethyltoluenediamine evenly, and spray and wet the base surface of the building;
(3)揭去自粘性改性沥青建筑防水卷材的隔离防护膜,快速粘贴在基面,压实平整,完成铺贴。(3) Remove the isolation protective film of the self-adhesive modified asphalt building waterproofing membrane, quickly paste it on the base surface, compact and smooth, and complete the paving.
实施例2Example 2
一种自粘性改性沥青建筑防水卷材的制备方法:A preparation method of self-adhesive modified asphalt building waterproofing membrane:
(1)将10重量份分子量2000聚丙二醇醚加入搅拌容器中,加热至110℃,然后真空脱水1h,降温至50℃,加入15重量份4 ,4’-二苯基甲烷二异氰酸酯,在80℃反应1小时,在50℃保温1h,得到聚氨酯预聚物;将聚氨酯预聚物输入胶体研磨机,然后加入40重量份130号沥青、15重量份丁苯橡胶、5重量份松香树脂、15重量份芳烃油研磨为胶状物;(1) 10 parts by weight of polypropylene glycol ether with a molecular weight of 2000 were added to a stirring vessel, heated to 110°C, then dehydrated in a vacuum for 1 hour, cooled to 50°C, added 15 parts by weight of 4,4'-diphenylmethane diisocyanate, and heated to 80°C. ℃ reaction for 1 hour, kept at 50 ℃ for 1 hour to obtain a polyurethane prepolymer; input the polyurethane prepolymer into a colloid mill, and then add 40 parts by weight of No. 130 asphalt, 15 parts by weight styrene-butadiene rubber, 5 parts by weight rosin resin, 15 parts by weight Aromatic oil in parts by weight is ground into a jelly;
(2)将3重量份石棉、1重量份纳米二氧化硅、10重量份再生橡胶粉、15重量份SBS、2重量份古马隆树脂、马来酸酐0.01重量份、1010抗氧化剂0.2重量份、5重量份膨润土、90重量份90号沥青材料加入混合机混合均匀,然后送入双螺杆挤出机在130-140℃熔融混炼,经“T”型模口挤出、三辊压延,三辊温度控制在50-60℃,得到厚度为2.0mm的改性沥青层;(2) 3 parts by weight of asbestos, 1 part by weight of nano-silica, 10 parts by weight of recycled rubber powder, 15 parts by weight of SBS, 2 parts by weight of coumarone resin, 0.01 part by weight of maleic anhydride, 0.2 part by weight of 1010 antioxidants , 5 parts by weight of bentonite, and 90 parts by weight of No. 90 bituminous materials are added to the mixer and mixed evenly, and then sent to a twin-screw extruder for melting and kneading at 130-140 ℃, extruded through a "T" die, and rolled with three rolls. The temperature of the three rolls is controlled at 50-60°C to obtain a modified asphalt layer with a thickness of 2.0mm;
(3)步骤(2)压延的改性沥青层趁热温将步骤(1)得到的胶状物刮涂在改性沥青层,刮涂厚度为0.4mm;然后敷隔离保护膜PET 膜,滚筒平整,卷取,密封包装,得到一种自粘性改性沥青建筑防水卷材。(3) Step (2) The calendered modified asphalt layer is scraped on the modified asphalt layer with the jelly obtained in step (1) while it is still hot, with a thickness of 0.4 mm; Flattening, coiling, sealing and packaging to obtain a self-adhesive modified bitumen building waterproofing membrane.
施工方法:Construction method:
(1)清理施工基面的杂物、浮尘、水渍;(1) Clean up the sundries, floating dust and water stains on the construction base surface;
(2)将20重量份D-2000端氨基聚醚、15重量份N ,N’-二烷基甲基二苯胺分散均匀,在建筑基面喷覆湿润;(2) Disperse 20 parts by weight of D-2000 amino-terminated polyether and 15 parts by weight of N,N'-dialkylmethyldiphenylamine evenly, and spray and wet the base surface of the building;
(3)揭去自粘性改性沥青建筑防水卷材的隔离防护膜,快速粘贴在基面,压实平整,完成铺贴。(3) Remove the isolation protective film of the self-adhesive modified asphalt building waterproofing membrane, quickly paste it on the base surface, compact and smooth, and complete the paving.
实施例3Example 3
一种自粘性改性沥青建筑防水卷材的制备方法:A preparation method of self-adhesive modified asphalt building waterproofing membrane:
(1)将12重量份分子量2000的聚乙二醇醚聚加入搅拌容器中,加热至110℃,然后真空脱水1h,降温至40℃,加入20重量份4 ,4’-二苯基甲烷二异氰酸酯,在80℃反应2小时,在50℃保温3h,得到聚氨酯预聚物;将聚氨酯预聚物输入胶体研磨机,然后加入40重量份130号沥青、10重量份丁苯橡胶、8重量份松香树脂、18重量份芳烃油研磨为胶状物;(1) 12 parts by weight of polyethylene glycol ether with a molecular weight of 2000 were added into a stirring vessel, heated to 110°C, then dehydrated in vacuum for 1 hour, cooled to 40°C, and added with 20 parts by weight of 4,4'-diphenylmethane diphenylmethane The isocyanate was reacted at 80°C for 2 hours, and kept at 50°C for 3 hours to obtain a polyurethane prepolymer; the polyurethane prepolymer was input into a colloid mill, and then 40 parts by weight of No. 130 asphalt, 10 parts by weight of styrene-butadiene rubber, and 8 parts by weight were added. Rosin resin and 18 parts by weight of aromatic hydrocarbon oil are ground into jelly;
(2)将5重量份石棉、2重量份纳米二氧化硅、7重量份再生橡胶粉、15重量份SBS、2重量份古马隆树脂、马来酸酐0.01重量份、1010抗氧化剂0.3重量份、3重量份膨润土、100重量份90号沥青材料加入混合机混合均匀,然后送入双螺杆挤出机在130-140℃熔融混炼,经“T”型模口挤出、三辊压延,三辊温度控制在50-60℃,得到厚度为2.0mm的改性沥青层;(2) 5 parts by weight of asbestos, 2 parts by weight of nano-silicon dioxide, 7 parts by weight of recycled rubber powder, 15 parts by weight of SBS, 2 parts by weight of coumarone resin, 0.01 part by weight of maleic anhydride, 0.3 part by weight of 1010 antioxidants , 3 parts by weight of bentonite, and 100 parts by weight of No. 90 bitumen material were added to the mixer to mix evenly, then sent to a twin-screw extruder for melting and kneading at 130-140°C, extruded through a "T" die, and rolled with three rolls. The temperature of the three rolls is controlled at 50-60°C to obtain a modified asphalt layer with a thickness of 2.0mm;
(3)步骤(2)压延的改性沥青层趁热温将步骤(1)得到的胶状物刮涂在改性沥青层,刮涂厚度为0.3mm;然后敷隔离保护膜PET 膜,滚筒平整,卷取,密封包装,得到一种自粘性改性沥青建筑防水卷材。(3) Step (2) The calendered modified asphalt layer is scraped on the modified asphalt layer with the jelly obtained in step (1) while it is still hot, with a thickness of 0.3mm; Flattening, coiling, sealing and packaging to obtain a self-adhesive modified bitumen building waterproofing membrane.
施工方法:Construction method:
(1)清理施工基面的杂物、浮尘、水渍;(1) Clean up the sundries, floating dust and water stains on the construction base surface;
(2)将25重量份D-2000端氨基聚醚、15重量份二乙基甲苯二胺分散均匀,在建筑基面喷覆湿润;(2) Disperse 25 parts by weight of D-2000 amino-terminated polyether and 15 parts by weight of diethyltoluenediamine evenly, and spray and wet the base surface of the building;
(3)揭去自粘性改性沥青建筑防水卷材的隔离防护膜,快速粘贴在基面,压实平整,完成铺贴。(3) Remove the isolation protective film of the self-adhesive modified asphalt building waterproofing membrane, quickly paste it on the base surface, compact and smooth, and complete the paving.
对比例1Comparative Example 1
一种自粘性改性沥青建筑防水卷材的制备方法:A preparation method of self-adhesive modified asphalt building waterproofing membrane:
(1)将30重量份130号沥青、10重量份丁苯橡胶、10重量份松香树脂、20重量份芳烃油研磨为胶状物;(1) Grinding 30 parts by weight of No. 130 asphalt, 10 parts by weight of styrene-butadiene rubber, 10 parts by weight of rosin resin, and 20 parts by weight of aromatic hydrocarbon oil into a jelly;
(2)将5重量份石棉、1重量份纳米二氧化硅、5重量份再生橡胶粉、15重量份SBS、2重量份古马隆树脂、马来酸酐0.01重量份、1010抗氧化剂0.1重量份、3重量份膨润土、100重量份90号沥青材料加入混合机混合均匀,然后送入双螺杆挤出机在130-140℃熔融混炼,经“T”型模口挤出、三辊压延,三辊温度控制在50-60℃,得到厚度为2.0mm的改性沥青层;(2) 5 parts by weight of asbestos, 1 part by weight of nano-silica, 5 parts by weight of recycled rubber powder, 15 parts by weight of SBS, 2 parts by weight of coumarone resin, 0.01 part by weight of maleic anhydride, 0.1 part by weight of 1010 antioxidants , 3 parts by weight of bentonite, and 100 parts by weight of No. 90 bitumen material were added to the mixer to mix evenly, then sent to a twin-screw extruder for melting and kneading at 130-140°C, extruded through a "T" die, and rolled with three rolls. The temperature of the three rolls is controlled at 50-60°C to obtain a modified asphalt layer with a thickness of 2.0mm;
(3)步骤(2)压延的改性沥青层趁热温将步骤(1)得到的胶状物刮涂在改性沥青层,刮涂厚度为0.5mm;然后敷PET 膜,滚筒平整,卷取,密封包装,得到一种自粘性改性沥青建筑防水卷材。(3) Step (2) The calendered modified asphalt layer is scraped on the modified asphalt layer with the jelly obtained in step (1) while it is still hot, with a thickness of 0.5mm; Take, seal and package to obtain a self-adhesive modified asphalt building waterproofing membrane.
粘接剥离强度测试:Adhesive peel strength test:
参考GB/T23260-2009(带自粘层的防水卷材)的要求测试实施例1-3、对比例1-2得到的防水卷材粘接性。Referring to the requirements of GB/T23260-2009 (waterproofing membrane with self-adhesive layer), test the adhesiveness of the waterproofing membrane obtained in Example 1-3 and Comparative Example 1-2.
将实施例1-3、对比例1的防水卷材裁切为50×75mm的测试样,按照GB/T 328.20-2007制样,将卷材粘贴在经溶剂清洁的光滑铝板,然后用2kg重、宽度为50mm的辊压3次,静置24h,测剥离强度,测试结果见表1。Cut the waterproof coils of Examples 1-3 and Comparative Example 1 into test samples of 50 × 75mm, prepare samples according to GB/T 328.20-2007, and paste the coils on a smooth aluminum plate cleaned by a solvent, and then use a 2kg weight. , 3 times of rolling with a width of 50mm, stand for 24h, and measure the peel strength. The test results are shown in Table 1.
将实施例1-3、对比例1的防水卷材裁切为50×75mm的测试样,按照GB/T 328.20-2007制样,将卷材粘贴在经溶剂清洁的光滑铝板,然后用2kg重、宽度为50mm的辊压3次,静置24h,在23℃水中浸泡7d,然后取出,放置24h,测剥离强度,测试结果见表1。Cut the waterproof coils of Examples 1-3 and Comparative Example 1 into test samples of 50 × 75mm, prepare samples according to GB/T 328.20-2007, and paste the coils on a smooth aluminum plate cleaned by a solvent, and then use a 2kg weight. , 3 times of rolling with a width of 50mm, stand for 24h, soak in 23 ℃ water for 7d, then take it out, put it for 24h, and measure the peel strength. The test results are shown in Table 1.
将实施例1-3、对比例1的防水卷材裁切为50×75mm的测试样,在光滑铝板擦拭水渍,将卷材粘贴,然后用2kg重、宽度为50mm的辊压3次,静置24h,测剥离强度,测试结果见表1。Cut the waterproof coils of Examples 1-3 and Comparative Example 1 into test samples of 50×75mm, wipe the water stains on the smooth aluminum plate, paste the coils, and then press 3 times with a 2kg roller with a width of 50mm, After standing for 24h, the peel strength was measured. The test results are shown in Table 1.
将实施例1-3、对比例1的防水卷材裁切为50×75mm的测试样,在光滑铝板擦拭水后喷涂端氨基聚醚、二乙基甲苯二胺组合的分散液,将卷材粘贴然后用2kg重、宽度为50mm的辊压3次,静置24h,测剥离强度,测试结果见表1。Cut the waterproof coils of Examples 1-3 and Comparative Example 1 into test samples of 50 × 75 mm, and spray the dispersion of amino-terminated polyether and diethyltoluenediamine combination after wiping water on the smooth aluminum plate, and the coils After pasting, it was pressed 3 times with a roller with a weight of 2 kg and a width of 50 mm, and it was allowed to stand for 24 hours to measure the peel strength. The test results are shown in Table 1.
表1:Table 1:
通过上述测试,本发明得到的自粘性改性沥青建筑防水卷材在擦拭水并喷涂分散液的铝板粘接性能提升明显。在一般情况下,本发明与未加预聚聚氨酯粘结层的对比例1粘接性能相近;但在湿环境,喷涂的分散液不但迅速使聚氨酯预聚体形成聚脲粘接在基面,不受在潮湿环境影响,而且粘接强度提升明显。对比例1没有预植聚氨酯预聚体,在潮湿环境粘接性下降明显。难以达到标准要求(大于1.5N/mm)。Through the above test, the self-adhesive modified bitumen waterproofing membrane obtained by the present invention has obvious improvement in the adhesion performance of the aluminum plate after wiping the water and spraying the dispersion liquid. In general, the present invention has similar adhesion performance to Comparative Example 1 without prepolymerized polyurethane adhesive layer; but in a wet environment, the sprayed dispersion not only quickly makes the polyurethane prepolymer form polyurea to bond to the base surface, It is not affected by the humid environment, and the bonding strength is significantly improved. Comparative Example 1 does not have a pre-planted polyurethane prepolymer, and the adhesiveness decreases significantly in a humid environment. It is difficult to meet the standard requirements (greater than 1.5N/mm).
应当理解,本文所述的示例性实施方案应当被认为是说明性的而非限制性的。而且,应可将各实施方案中关于各特征或方面的描述适用于其他实施方案中的其他类似特征或方面。It is to be understood that the exemplary embodiments described herein are to be regarded as illustrative and not restrictive. Furthermore, descriptions of each feature or aspect in each embodiment shall be applicable to other similar features or aspects in other embodiments.
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