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CN111768920B - Method for representing processing uniformity of Bi-system high-temperature superconducting wire or strip - Google Patents

Method for representing processing uniformity of Bi-system high-temperature superconducting wire or strip Download PDF

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CN111768920B
CN111768920B CN202010749819.3A CN202010749819A CN111768920B CN 111768920 B CN111768920 B CN 111768920B CN 202010749819 A CN202010749819 A CN 202010749819A CN 111768920 B CN111768920 B CN 111768920B
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strip
temperature superconducting
profile
resistance
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CN111768920A (en
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李珍宝
白利峰
徐晓燕
焦高峰
郝清滨
李成山
张胜楠
邵柏淘
冯建情
吴怡芳
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Northwest Institute for Non Ferrous Metal Research
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B12/00Superconductive or hyperconductive conductors, cables, or transmission lines
    • H01B12/02Superconductive or hyperconductive conductors, cables, or transmission lines characterised by their form
    • H01B12/04Single wire
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

The invention discloses a method for representing the processing uniformity of a Bi-based high-temperature superconducting wire or strip, which is used for testing the resistance of the Bi-based high-temperature superconducting wire or strip at different positions based on a room-temperature resistance testing principle by a four-wire method and then representing the processing uniformity of the Bi-based high-temperature superconducting wire or strip through the resistance difference at different positions. The method for testing the room temperature resistance based on the four-wire method is adopted to detect the samples of the primary wire, the secondary wire, the composite wire or the strip or the Bi-system high-temperature superconducting composite wire or the strip in the processing process of the Bi-system high-temperature superconducting wire or the strip, and the processing uniformity in different processing stages is represented by the resistance difference at different positions, so that the real-time monitoring of the processing uniformity in the preparation process of the Bi-system high-temperature superconducting wire or the strip is realized, and a guide direction is provided for optimizing the processing parameters in the preparation process of the Bi-system high-temperature superconducting wire or the strip and improving the processing uniformity of the wire.

Description

一种表征Bi系高温超导线材或带材加工均匀性的方法A method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips

技术领域technical field

本发明属于高温超导线带材性能测试与表征领域,具体涉及一种表征Bi系高温超导线材或带材加工均匀性的方法。The invention belongs to the field of performance testing and characterization of high-temperature superconducting wire strips, and particularly relates to a method for characterizing the processing uniformity of Bi-series high-temperature superconducting wire rods or strips.

背景技术Background technique

Bi系高温超导线带材的宏观载流性能及力学性能的均匀性是其工程化应用的关键。此外,芯丝渗漏是阻碍Bi系高温超导线带材能否应用于磁体技术的关键问题。而良好的线材或者带材加工均匀性能够有效减少断芯率,对改善Bi系高温超导线带材宏观载流性能、力学性能的均匀性至关重要;同时,良好的加工均匀性能够保证银基体变形的均匀性,有效减少芯丝渗漏的概率。The macroscopic current-carrying properties and uniformity of mechanical properties of Bi-based high-temperature superconducting wires are the key to their engineering applications. In addition, core wire leakage is a key problem that hinders the application of Bi-based high-temperature superconducting tapes to magnet technology. And good wire or strip processing uniformity can effectively reduce the core break rate, which is very important to improve the macroscopic current-carrying performance and mechanical properties uniformity of Bi-based high-temperature superconducting wire strips; at the same time, good processing uniformity can ensure silver The uniformity of matrix deformation effectively reduces the probability of core wire leakage.

线材或者带材加工的均匀性很大程度上取决于银基体变形的均匀性。同一根线材或带材不同位置中银的横截面大小是反映线材或带材加工均匀性的一个重要参数;同时,调整线材或带材中银的横截面大小也是改善线带材加工均匀性的一个重要方法。因此,对比不同线材或者带材中银的横截面大小能够为改善线材或者带材的加工均匀性提供基础数据支撑。The uniformity of wire or strip processing depends to a large extent on the uniformity of the deformation of the silver matrix. The cross-sectional size of silver in different positions of the same wire or strip is an important parameter to reflect the processing uniformity of the wire or strip; at the same time, adjusting the cross-sectional size of silver in the wire or strip is also an important factor to improve the processing uniformity of the wire or strip. method. Therefore, comparing the cross-sectional size of silver in different wires or strips can provide basic data support for improving the processing uniformity of wires or strips.

目前公开报道的Bi系高温超导线材或带材加工均匀性的测试方法非常有限。Currently, there are very limited methods for testing the processing uniformity of Bi-based HTS wires or strips.

发明内容SUMMARY OF THE INVENTION

本发明所要解决的技术问题在于针对上述现有技术的不足,提供一种表征Bi系高温超导线材或带材加工均匀性的方法。该方法基于四线法测试室温电阻的方法,对Bi系高温超导线材或带材加工过程中的一次线材、二次线材、复合线材或带材、或者Bi系高温超导复合线材或带材样品进行检测,通过不同位置处的电阻差异表征不同加工阶段的加工均匀性,实现了Bi系高温超导线材或带材制备过程中加工均匀性的实时监测,为优选Bi系高温超导线材或带材制备过程中的加工参数、改善线材的加工均匀性提供指导方向。The technical problem to be solved by the present invention is to provide a method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips in view of the above-mentioned deficiencies of the prior art. This method is based on the method of testing room temperature resistance by the four-wire method. The samples were tested, and the resistance difference at different positions was used to characterize the processing uniformity of different processing stages, and real-time monitoring of the processing uniformity during the preparation of Bi-based high-temperature superconducting wires or strips was realized. Processing parameters during strip preparation and improving wire processing uniformity provide guidance.

为解决上述技术问题,本发明采用的技术方案是:一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,该方法基于四线法测试室温电阻原理对Bi系高温超导线材或带材不同位置处的电阻进行测试,然后通过不同位置处的电阻差异表征Bi系高温超导线材或带材加工均匀性。In order to solve the above-mentioned technical problems, the technical solution adopted in the present invention is: a method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips, characterized in that the method is based on the principle of four-wire method to test room temperature resistance for Bi-based high-temperature superconducting wires. The resistance at different positions of the superconducting wire or strip is tested, and then the processing uniformity of the Bi-based high-temperature superconducting wire or strip is characterized by the resistance difference at different positions.

本发明采用四线法测试室温电阻的方法,通过获得Bi系高温超导线材或带材不同位置处的室温电阻,并进行对比,通过不同位置处的电阻差异表征Bi系高温超导线材或带材加工均匀性,该方法准确快速,操作简单,安全无损。The invention adopts the method of testing the room temperature resistance by the four-wire method. By obtaining the room temperature resistance of the Bi-series high-temperature superconducting wire or strip at different positions, and comparing them, the Bi-series high-temperature superconducting wire or strip is characterized by the resistance difference at different positions. The method is accurate, fast, simple to operate, safe and non-destructive.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,该方法包括以下步骤:The above-mentioned method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips is characterized in that the method comprises the following steps:

步骤一、将第一导线、第二导线、第三导线和第四导线依次缠绕固定在型材上,将第一导线、第二导线、第三导线和第四导线在型材上的固定位置定为第1位置,确定第二导线在型材上的固定点与第三导线在型材上的固定点之间的距离为L;所述型材为Bi系高温超导线材或带材;Step 1: The first wire, the second wire, the third wire and the fourth wire are wound and fixed on the profile in turn, and the fixed positions of the first wire, the second wire, the third wire and the fourth wire on the profile are set as: In the first position, determine the distance between the fixing point of the second wire on the profile and the fixing point of the third wire on the profile as L; the profile is a Bi-series high temperature superconducting wire or strip;

步骤二、通过第一导线和第四导线加载电流I并与型材形成回路,然后测量第二导线和第三导线之间的电压U,根据欧姆定律R=U/I,计算得到第1位置处长度为L的型材的电阻R1Step 2: Load the current I through the first wire and the fourth wire and form a loop with the profile, and then measure the voltage U between the second wire and the third wire. According to Ohm's law R=U/I, the first position is calculated. the resistance R 1 of the profile of length L;

步骤三、依次对第一导线、第二导线、第三导线和第四导线在型材上的缠绕固定位置进行整体调整,并确保第二导线在型材上的固定点与第三导线在型材上的固定点之间的距离L不变,直至调整到第i位置,其中,i为自然数且i≥2,按照步骤二中的加载和测量过程,分别计算调整后不同位置处长度为L的型材的电阻,直至得到电阻RiStep 3: Adjust the winding and fixing positions of the first wire, the second wire, the third wire and the fourth wire on the profile in turn, and ensure that the fixing point of the second wire on the profile and the third wire on the profile are fixed. The distance L between the fixed points remains unchanged until it is adjusted to the i-th position, where i is a natural number and i≥2. According to the loading and measurement process in step 2, calculate the length of the profile at different positions after adjustment. resistance, until the resistance R i is obtained;

步骤四、根据步骤二和步骤三中得到的电阻R1~Ri,计算得到长度为L的型材的电阻平均值Ra,然后计算每一位置处长度为L的型材的电阻与电阻平均值Ra的偏离度Di,其中,Di=|Ra-Ri|/Ra×100%,且偏离度Di中的最大值为最大偏离度Dm,选用最大偏离度Dm表征型材来源的Bi系高温超导线材或带材的加工均匀性。Step 4: According to the resistances R 1 ˜R i obtained in Step 2 and Step 3, calculate the average resistance value R a of the profile with length L, and then calculate the resistance and average resistance of the profile with length L at each position The degree of deviation D i of Ra , where Di=|R a -R i |/R a ×100%, and the maximum value of the degree of deviation D i is the degree of maximum deviation D m , and the maximum degree of deviation D m is selected to characterize the profile Processing uniformity of source Bi-based HTS wire or strip.

本发明采用四线法测试Bi系高温超导线材或带材中不同位置处的室温电阻,然后获得该Bi系高温超导线材或带材的电阻的最大偏离度Dm,用以表征Bi系高温超导线材或带材的加工均匀性,从而通过监测、对比加工参数相同、但银套管厚度不同的Bi系高温超导线材或带材的加工均匀性,为调整加工参数中的银超比提供依据,或者通过监测、对比不同加工参数制备的Bi系高温超导线材或带材的加工均匀性,为调整加工参数提供指导方向,最终提高了Bi系高温超导线材或带材的加工均匀性,改善了Bi系高温超导线带材整体载流性能及其力学性能,促进其工程化应用过程;另外,采用导线测量适用的型材长度范围较大,操作简单,取样勺,方便灵活,对设备要求不高。In the present invention, the four-wire method is used to test the room temperature resistance of the Bi-series high-temperature superconducting wire or strip at different positions, and then the maximum deviation D m of the resistance of the Bi-series high-temperature superconducting wire or strip is obtained to characterize the Bi-series high temperature superconducting wire or strip. The processing uniformity of high temperature superconducting wires or strips, so that by monitoring and comparing the processing uniformity of Bi-based high temperature superconducting wires or strips with the same processing parameters but different thicknesses of silver sleeves, it is necessary to adjust the processing parameters of silver superconducting wires or strips. ratio, or by monitoring and comparing the processing uniformity of Bi-based high-temperature superconducting wires or strips prepared with different processing parameters, providing guidance for adjusting processing parameters, and ultimately improving the processing of Bi-based high-temperature superconducting wires or strips. Uniformity improves the overall current-carrying performance and mechanical properties of Bi-series high-temperature superconducting wire strips, and promotes its engineering application process; in addition, the use of wire measurement is suitable for a wide range of profile lengths, simple operation, sampling spoon, convenient and flexible, The equipment requirements are not high.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,步骤一中所述第一导线、第二导线、第三导线和第四导线的材质均为铜;所述型材的长度不小于5cm,且型材为Bi系高温超导线材或带材加工过程中的一次线材、二次线材、复合线材或带材、或者Bi系高温超导复合线材或带材上的截取样品;步骤一中所述L≥1cm,且当1cm≤L<10cm时,L的测量精度不低于0.01cm,当L≥10cm时,L的测量精度不低于0.1cm。该优选材质的导线导电性能好,且容易获得;该优选长度的型材在后续表征过程中的整体误差小,提高了各参数测试结果的精度;本发明的方法适用于Bi系高温超导线材或带材加工后的每一道工序线材,通过检测每一道工序线材的均匀性,建立过程检测工序,从而保证了终产品的加工均匀性;根据型材灵活选择测量长度,方便获得不同型材的加工均匀性;同时根据测量长度选择测量精度,以尽量减少测量引入的误差,保证本发明表征方法的准确性。The above-mentioned method for characterizing the processing uniformity of Bi-series high-temperature superconducting wires or strips, is characterized in that, the materials of the first wire, the second wire, the third wire and the fourth wire described in step 1 are all copper; The length of the profile is not less than 5cm, and the profile is a primary wire, secondary wire, composite wire or strip, or Bi-based high-temperature superconducting composite wire or strip in the process of Bi-series high-temperature superconducting wire or strip. The intercepted sample; in step 1, L≥1cm, and when 1cm≤L<10cm, the measurement accuracy of L is not less than 0.01cm, and when L≥10cm, the measurement accuracy of L is not less than 0.1cm. The wire of the preferred material has good electrical conductivity and is easy to obtain; the overall error of the profile of the preferred length in the subsequent characterization process is small, which improves the accuracy of the test results of each parameter; the method of the present invention is suitable for Bi series high temperature superconducting wire or For each process wire rod after strip processing, the process detection process is established by detecting the uniformity of each process wire rod, thereby ensuring the processing uniformity of the final product; flexibly select the measurement length according to the profile, which is convenient to obtain the processing uniformity of different profiles At the same time, the measurement accuracy is selected according to the measurement length, so as to minimize the errors introduced by the measurement and ensure the accuracy of the characterization method of the present invention.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,步骤二中所述电流I为变化电流,则电压U为变化电压,对U-I进行拟合得到拟合曲线,拟合曲线的斜率为第1位置处长度为L的型材的电阻R1。本发明的电阻测量方法多样。The above-mentioned method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips is characterized in that, the current I described in step 2 is a changing current, then the voltage U is a changing voltage, and the UI is fitted to obtain a fitting curve, the slope of the fitted curve is the resistance R 1 of the profile of length L at the first position. The resistance measurement methods of the present invention are various.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,步骤二中所述电流I为变化电流,所述第一导线和第四导线与型材形成的回路中串联设置有电阻值为r的分压电阻,则串联电阻的电压U0与U均为变化电压,对U-(U0/r)进行拟合得到拟合曲线,则拟合曲线的斜率为第1位置处长度为L的型材的电阻R1。上述优选的电阻测量方法多样,进一步提高了本发明的表征方法的适用范围。The above-mentioned method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips is characterized in that, in step 2, the current I is a variable current, and the loop formed by the first wire and the fourth wire and the profile is A voltage dividing resistor with a resistance value of r is set in series, then the voltages U 0 and U of the series resistor are both changing voltages, and the fitting curve is obtained by fitting U-(U 0 /r), then the slope of the fitting curve is The resistance R 1 of the profile of length L at the 1st position. The above-mentioned preferred resistance measurement methods are various, which further improves the applicable scope of the characterization method of the present invention.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,当步骤四中最大偏离度Dm大于Bi系高温超导线材或带材加工均匀性的预设值5%时,说明型材来源的Bi系高温超导线材或带材加工均匀性较差,当最大偏离度Dm小于Bi系高温超导线材或带材加工均匀性的预设值5%时,说明型材来源的Bi系高温超导线材或带材加工均匀性良好。The above-mentioned method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips is characterized in that when the maximum deviation D m in step 4 is greater than the preset value of the processing uniformity of Bi-based high-temperature superconducting wires or strips When it is 5%, it means that the processing uniformity of the Bi-series high-temperature superconducting wire or strip from the profile is poor. When the maximum deviation D m is less than 5% of the preset value of the processing uniformity of the Bi-series high-temperature superconducting wire or strip, It shows that the Bi-series high-temperature superconducting wires or strips from profiles have good processing uniformity.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,该方法包括以下步骤:The above-mentioned method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips is characterized in that the method comprises the following steps:

步骤一、将型材依次缠绕固定在收线盘、第一轴导体、第二轴导体、第三轴导体、第四轴导体和放线盘上,将第一轴导体、第二轴导体、第三轴导体、第四轴导体在型材上的固定位置定为第1位置,确定第二轴导体在型材上的接触切点与第三轴导体在型材上的接触切点之间的距离为L′;所述型材为Bi系高温超导线材或带材;Step 1. Wind and fix the profiles on the take-up reel, the first axis conductor, the second axis conductor, the third axis conductor, the fourth axis conductor and the pay-off plate in turn, and wrap the first axis conductor, the second axis conductor, the The fixed position of the triaxial conductor and the fourth axis conductor on the profile is set as the first position, and the distance between the contact tangent point of the second axis conductor on the profile and the contact tangent point of the third axis conductor on the profile is determined as L '; the profiles are Bi-series high temperature superconducting wires or strips;

步骤二、通过第一轴导体和第四轴导体加载电流I′并与型材形成回路,然后测量第二轴导体和第三轴导体之间的电压U′,根据欧姆定律R=U/I,计算得到第1位置处长度为L′的型材的电阻R1′;Step 2: Load current I' through the first and fourth axis conductors and form a loop with the profile, and then measure the voltage U' between the second and third axis conductors. According to Ohm's law R=U/I, Calculate the resistance R 1 ' of the profile with length L' at the first position;

步骤三、依次同时转动收线盘和放线盘,分别对第一轴导体、第二轴导体、第三轴导体和第四轴导体在型材上的缠绕固定位置进行整体调整,并确保第二轴导体在型材上的接触切点与第三轴导体在型材上的接触切点之间的距离L′不变,直至调整到第j位置,其中,j为自然数且j≥2,按照步骤二中的加载和测量过程,分别计算调整后不同位置处长度为L′的型材的电阻,直至得到电阻Rj′;Step 3: Rotate the take-up reel and the pay-out reel simultaneously in order to adjust the winding and fixing positions of the first axis conductor, the second axis conductor, the third axis conductor and the fourth axis conductor respectively on the profile, and ensure that the second axis The distance L' between the contact tangent point of the shaft conductor on the profile and the contact tangent point of the third shaft conductor on the profile remains unchanged until it is adjusted to the jth position, where j is a natural number and j≥2, according to step 2 During the loading and measurement process in , calculate the resistance of the profiles with length L' at different positions after adjustment, until the resistance R j ' is obtained;

步骤四、根据步骤二和步骤三中得到的电阻R1′~Rj′,计算得到长度为L′的型材的电阻平均值Ra′,然后计算每一位置的电阻与电阻平均值Ra′的偏离度Di′,其中,Di′=|Ra′-Rj′|/Ra′×100%,且偏离度Di′中的最大值为最大偏离度Dm′,选用最大偏离度Dm′表征型材来源的Bi系高温超导线材或带材的加工均匀性。Step 4: According to the resistances R 1 ′~R j ′ obtained in Step 2 and Step 3, calculate the average resistance value R a ′ of the profile with a length of L′, and then calculate the resistance and average resistance value Ra at each position. ' deviation degree D i ', in which, D i '=|R a '-R j '|/R a '×100%, and the maximum value in the deviation degree D i ' is the maximum deviation degree D m ', select The maximum deviation D m ′ characterizes the processing uniformity of the Bi-based high-temperature superconducting wire or strip from the profile.

本发明采用四线法测试Bi系高温超导线材或带材中不同位置处的室温电阻,利用轴导体代替导线进行测量,通过固定各轴导体的位置,使得型材进行收放从而测量型材不同位置处的电阻,从而方便了型材的连续测量,适用于长度较大的型材。The invention adopts the four-wire method to test the room temperature resistance at different positions in the Bi series high temperature superconducting wire or strip, uses the shaft conductor to replace the wire for measurement, and fixes the position of each shaft conductor, so that the profile is retracted and placed to measure the different positions of the profile The resistance at the place is convenient for the continuous measurement of the profile, and it is suitable for the profile with a large length.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,所述第一轴导体、第二轴导体、第三轴导体和第四轴导体的材质均为铜;所述型材的长度不小于50cm,且型材为Bi系高温超导线材或带材加工过程中的一次线材、二次线材、复合线材或带材、或者Bi系高温超导复合线材或带材上的截取样品;所述L′≥1cm,且当1cm≤L′<10cm时,L′的测量精度不低于0.01cm,当L′≥10cm时,L′的测量精度不低于0.1cm。该优选材质轴导体的导电性能好,且容易获得;由于采用轴导体适用于连续测量,因此该优选长度的型材在后续表征过程中的整体误差小,提高了各参数测试结果的精度;本发明的方法适用于Bi系高温超导线材或带材加工后的每一道工序线材,通过检测每一道工序线材的均匀性,建立过程检测工序,从而保证了终产品的加工均匀性;根据型材灵活选择测量长度,方便获得不同型材的加工均匀性;同时根据测量长度选择测量精度,以尽量减少测量引入的误差,保证本发明表征方法的准确性。The above-mentioned method for characterizing the processing uniformity of Bi-based high temperature superconducting wires or strips is characterized in that the materials of the first axis conductor, the second axis conductor, the third axis conductor and the fourth axis conductor are all copper ; The length of the profile is not less than 50cm, and the profile is a primary wire, secondary wire, composite wire or strip, or Bi-based high-temperature superconducting composite wire or strip in the process of Bi-series high-temperature superconducting wire or strip. The intercepted sample from above; the L'≥1cm, and when 1cm≤L'<10cm, the measurement accuracy of L' is not less than 0.01cm, and when L'≥10cm, the measurement accuracy of L' is not less than 0.1cm . The shaft conductor of the preferred material has good electrical conductivity and is easy to obtain; since the shaft conductor is used for continuous measurement, the overall error of the profile of the preferred length in the subsequent characterization process is small, and the accuracy of the test results of each parameter is improved; the present invention The method is suitable for each process wire after the Bi series high temperature superconducting wire or strip is processed. By detecting the uniformity of each process wire, a process detection process is established to ensure the processing uniformity of the final product; flexible selection according to profiles Measuring the length is convenient to obtain the processing uniformity of different profiles; at the same time, the measuring accuracy is selected according to the measuring length, so as to minimize the error introduced by the measurement and ensure the accuracy of the characterization method of the present invention.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,步骤二中所述电流I′为变化电流,则电压U′为变化电压,对U′-I′进行拟合得到拟合曲线,拟合曲线的斜率为第1位置处长度为L′的型材的电阻R1′。The above-mentioned method for characterizing the processing uniformity of Bi-series high-temperature superconducting wires or strips is characterized in that, in step 2, the current I' is a changing current, then the voltage U' is a changing voltage, and for U'-I' Fitting is performed to obtain a fitting curve, and the slope of the fitting curve is the resistance R 1 ' of the profile with the length L' at the first position.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,步骤二中所述电流I′为变化电流,所述第一轴导体和第四轴导体与型材形成的回路中串联设置有电阻值为r的分压电阻,则串联电阻的电压U0′与U′均为变化电压,对U′-(U0′/r)进行拟合得到拟合曲线,则拟合曲线的斜率为第1位置处长度为L′的型材的电阻R1′。The above-mentioned method for characterizing the processing uniformity of Bi-series high-temperature superconducting wires or strips is characterized in that in step 2, the current I' is a variable current, and the first axis conductor and the fourth axis conductor are formed with the profiles. A voltage dividing resistor with a resistance value of r is set in series in the loop of , then the voltages U 0 ' and U' of the series resistors are both changing voltages, and the fitting curve is obtained by fitting U'-(U 0 '/r), Then the slope of the fitting curve is the resistance R 1 ' of the profile with length L' at the first position.

上述的一种表征Bi系高温超导线材或带材加工均匀性的方法,其特征在于,当步骤四中最大偏离度Dm′大于Bi系高温超导线材或带材加工均匀性的预设值5%时,说明型材来源的Bi系高温超导线材或带材加工均匀性较差,当最大偏离度Dm′小于Bi系高温超导线材或带材加工均匀性的预设值5%时,说明型材来源的Bi系高温超导线材或带材加工均匀性良好。The above-mentioned method for characterizing the processing uniformity of Bi-based high-temperature superconducting wires or strips is characterized in that when the maximum deviation D m ′ in step 4 is greater than the preset processing uniformity of Bi-based high-temperature superconducting wires or strips When the value is 5%, it means that the processing uniformity of the Bi-series high-temperature superconducting wire or strip from the profile is poor. When the maximum deviation D m ′ is less than the preset value of 5% of the processing uniformity of the Bi-series high-temperature superconducting wire or strip , indicating that the Bi-based high-temperature superconducting wire or strip from the profile has good processing uniformity.

本发明中Bi系高温超导线材的加工工艺为:将Bi系粉末装入一次银管中后经拉拔得到一次线材,一次线材装入二次银管中组装后经拉拔得到二次线材,二次线材装入三次银合金管中组装后经拉拔得到复合线材,经热处理后形成织构组织,得到Bi系高温超导线材。In the present invention, the processing technology of the Bi series high temperature superconducting wire is as follows: the Bi series powder is loaded into the primary silver tube and then drawn to obtain the primary wire, and the primary wire is loaded into the secondary silver tube and assembled and then drawn to obtain the secondary wire , the secondary wire rod is assembled into the tertiary silver alloy tube and then drawn to obtain a composite wire rod. After heat treatment, a textured structure is formed to obtain a Bi series high temperature superconducting wire.

本发明中Bi系高温超导带材的加工工艺为:将Bi系粉末装入一次银管中后经拉拔得到一次线材,一次线材装入二次银合金管中组装后经拉拔得到二次线材,二次线材经过轧机轧制后得到复合带材,经热处理后形成织构组织,得到Bi系高温超导带材。The processing technology of the Bi-based high-temperature superconducting tape in the present invention is as follows: the Bi-based powder is loaded into a primary silver tube and then drawn to obtain a primary wire, and the primary wire is loaded into a secondary silver alloy tube for assembly and then drawn to obtain a secondary wire. The secondary wire rod and the secondary wire rod are rolled by a rolling mill to obtain a composite strip, and after heat treatment, a textured structure is formed, and a Bi-based high temperature superconducting strip is obtained.

本发明与现有技术相比具有以下优点:Compared with the prior art, the present invention has the following advantages:

1、本发明基于四线法测试室温电阻的方法,对Bi系高温超导线材或带材加工过程中的一次线材、二次线材、复合线材或带材、或者Bi系高温超导复合线材或带材样品进行检测,通过不同位置处的电阻差异表征不同加工阶段中的加工均匀性,实现了Bi系高温超导线材或带材制备过程中加工均匀性的实时监测,为优选Bi系高温超导线材或带材制备过程中的加工参数、改善线材的加工均匀性提供指导方向。1. The present invention is based on the method of testing room temperature resistance by the four-wire method, and is used for primary wires, secondary wires, composite wires or strips, or Bi-based high-temperature superconducting composite wires or The strip samples are tested, and the processing uniformity in different processing stages is characterized by the resistance difference at different positions, which realizes the real-time monitoring of the processing uniformity during the preparation of Bi-based high-temperature superconducting wires or strips. Processing parameters during wire rod or strip preparation, providing guidance for improving wire processing uniformity.

2、本发明的方法准确快速,操作简单,安全无损,其中结合轴导体的测量方法可实现Bi系高温超导线材或带材加工均匀性的在线连续监测,方便了Bi系高温超导线材或带材加工的均匀性评价。2. The method of the present invention is accurate, fast, simple to operate, safe and non-destructive, and the measurement method combined with the shaft conductor can realize on-line continuous monitoring of the processing uniformity of Bi-series high-temperature superconducting wires or strips, which is convenient for Bi-series high-temperature superconducting wires or strips. Uniformity evaluation of strip processing.

3、本发明提出了评价Bi系高温超导线材或带材加工均匀性的有效量化指标,即线材电阻的最大偏离度Dm,为评价线材或带材加工均匀性提供了可量化的确切指标,方便了不同线材或带材加工均匀性的对比分析。3. The present invention proposes an effective quantitative index for evaluating the processing uniformity of Bi-series high-temperature superconducting wires or strips, that is, the maximum deviation of wire resistance Dm, which provides a quantifiable exact index for evaluating the processing uniformity of wires or strips. It is convenient to compare and analyze the processing uniformity of different wires or strips.

4、本发明通过监测、对比不同Bi系高温超导线材或带材的加工均匀性,为优化Bi系高温超导线材或带材加工过程中的加工参数、银管尺寸提供依据和指导方向,有利于提高Bi系高温超导线材或带材的加工均匀性,改善Bi系高温超导线带材整体载流性能及其力学性能,促进其工程化应用过程。4. By monitoring and comparing the processing uniformity of different Bi-series high-temperature superconducting wires or strips, the present invention provides a basis and guiding direction for optimizing the processing parameters and silver tube dimensions in the processing of Bi-series high-temperature superconducting wires or strips. It is beneficial to improve the processing uniformity of Bi-based high-temperature superconducting wires or strips, improve the overall current-carrying properties and mechanical properties of Bi-based high-temperature superconducting wires, and promote their engineering application process.

下面通过附图和实施例对本发明的技术方案作进一步的详细描述。The technical solutions of the present invention will be further described in detail below through the accompanying drawings and embodiments.

附图说明Description of drawings

图1为本发明实施例1、3、4、5、7和9的Bi系高温超导线材的测试示意图。FIG. 1 is a schematic diagram of testing the Bi-based high temperature superconducting wires of Examples 1, 3, 4, 5, 7 and 9 of the present invention.

图2为本发明实施例2的Bi系高温超导线材的测试示意图。FIG. 2 is a schematic diagram of the test of the Bi-based high temperature superconducting wire of Example 2 of the present invention.

图3为本发明实施例6的Bi系高温超导线材的测试示意图。3 is a schematic diagram of the test of the Bi-based high temperature superconducting wire of Example 6 of the present invention.

图4为本发明实施例8的Bi系高温超导带材的测试示意图。4 is a schematic diagram of a test of the Bi-based high temperature superconducting tape of Example 8 of the present invention.

附图标记说明:Explanation of reference numbers:

1—第一导线; 2—第二导线; 3—第三导线;1—the first wire; 2—the second wire; 3—the third wire;

4—第四导线; 5—型材; 6—第一轴导体;4—the fourth wire; 5—the profile; 6—the first axis conductor;

7—第二轴导体; 8—第三轴导体; 9—第四轴导体;7—the second axis conductor; 8—the third axis conductor; 9—the fourth axis conductor;

10—收线盘; 11—放线盘。10—Reel reel; 11—Reel reel.

具体实施方式Detailed ways

实施例1Example 1

本实施例包括以下步骤:This embodiment includes the following steps:

步骤一、在Bi2212高温超导线材加工过程中的一次线材(长度为10m)的头端截取长度为100cm的样品作为型材5,然后将第一导线1、第二导线2、第三导线3和第四导线4依次缠绕固定在型材5上,将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的固定位置定为第1位置(型材5的头端起0~20cm范围内),并确定第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm;所述第一导线1、第二导线2、第三导线3和第四导线4的材质均为铜;Step 1. Cut a sample with a length of 100cm from the head end of the primary wire (10m in length) in the Bi2212 high temperature superconducting wire processing process as a profile 5, and then connect the first wire 1, the second wire 2, the third wire 3 and the The fourth wire 4 is wound and fixed on the profile 5 in turn, and the fixed positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 are set as the first position (the head end of the profile 5). The distance L between the fixing point of the second wire 2 on the profile 5 and the fixing point of the third wire 3 on the profile 5 is 10.0 cm; the first wire 1, the first wire The materials of the second wire 2, the third wire 3 and the fourth wire 4 are all copper;

步骤二、通过第一导线1和第四导线4加载电流I并与型材5形成回路,然后测量第二导线2和第三导线3之间的电压U,电流I为匀速增加的电流,电流I为0~1A,增加幅度0.1A/s,对应得到的电压U为变化电压,对U-I进行拟合得到拟合曲线,拟合曲线的斜率为0.00211,即第1位置处长度为10.0cm的型材5的电阻R1=0.00211Ω;本实施例的测试示意图如图1所示;Step 2, load current I through the first wire 1 and the fourth wire 4 and form a loop with the profile 5, then measure the voltage U between the second wire 2 and the third wire 3, the current I is a constant increasing current, and the current I is 0~1A, the increase range is 0.1A/s, the corresponding voltage U is the changing voltage, and the fitting curve is obtained by fitting the UI. The slope of the fitting curve is 0.00211, that is, the length of the profile at the first position is 10.0cm The resistance R 1 of 5 = 0.00211Ω; the test schematic diagram of this embodiment is shown in FIG. 1 ;

步骤三、依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至第2位置(型材5的头端起20cm~40cm范围内)、第3位置(型材5的头端起40cm~60cm范围内)、第4位置(型材5的头端起60cm~80cm范围内)和第5位置(型材5的头端起80cm~100cm范围内),并确保第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm不变,按照步骤二中的加载和测量过程,分别计算得到调整后第2位置~第5位置处长度为10.0cm的型材5的电阻依次为R2=0.00214Ω,R3=0.00234Ω,R4=0.00233Ω和R5=0.00215Ω;Step 3: Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 in turn to the second position (within the range of 20cm to 40cm from the head end of the profile 5). ), the third position (within the range of 40cm-60cm from the head end of the profile 5), the fourth position (within the range of 60cm-80cm from the head end of the profile 5), and the fifth position (within the range of 80cm-100cm from the head end of the profile 5) inside), and ensure that the distance L between the fixed point of the second wire 2 on the profile 5 and the fixed point of the third wire 3 on the profile 5 is 10.0 cm unchanged. According to the loading and measurement process in step 2, respectively It is calculated that the resistance of the profile 5 with a length of 10.0cm from the second position to the fifth position after adjustment is R 2 =0.00214Ω, R 3 =0.00234Ω, R 4 =0.00233Ω and R 5 =0.00215Ω in sequence;

步骤四、根据步骤二和步骤三中得到的电阻R1~R5,计算得到长度为10.0cm的型材5的电阻平均值Ra=0.00221,然后计算每一位置处长度为10.0cm的型材5的电阻与电阻平均值Ra的偏离度Di,其中,Di=|Ra-Ri|/Ra×100%,得到偏离度Di中的最大值即最大偏离度Dm=4.5%,表明型材5来源的Bi2212高温超导线材加工过程中的一次线材的加工均匀性良好。Step 4: According to the resistances R 1 to R 5 obtained in Step 2 and Step 3, calculate the average resistance value Ra = 0.00221 of the profile 5 with a length of 10.0 cm, and then calculate the profile 5 with a length of 10.0 cm at each position. The degree of deviation D i between the resistance and the average value of resistance Ra , wherein, D i =|R a -R i |/R a ×100%, the maximum value of the degree of deviation D i is obtained, that is, the maximum degree of deviation D m =4.5 %, indicating that the processing uniformity of the primary wire rod during the processing of the Bi2212 high-temperature superconducting wire rod sourced from Profile 5 is good.

实施例2Example 2

本实施例包括以下步骤:This embodiment includes the following steps:

步骤一、在Bi2212高温超导线材加工过程中的二次线材(长度为6m)的头端截取长度为60cm的样品作为型材5,然后将第一导线1、第二导线2、第三导线3和第四导线4依次缠绕固定在型材5上,将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的固定位置定为第1位置(型材5的头端起0~20cm范围内),并确定第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm;所述第一导线1、第二导线2、第三导线3和第四导线4的材质均为铜;Step 1. Cut a sample with a length of 60cm from the head end of the secondary wire (6m in length) during the Bi2212 high temperature superconducting wire processing process as a profile 5, and then connect the first wire 1, the second wire 2, and the third wire 3. and the fourth wire 4 are wound and fixed on the profile 5 in turn, and the fixed position of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 is set as the first position (the head of the profile 5). The distance L between the fixing point of the second wire 2 on the profile 5 and the fixing point of the third wire 3 on the profile 5 is 10.0 cm; the first wire 1, The materials of the second wire 2, the third wire 3 and the fourth wire 4 are all copper;

步骤二、在第一铜导线1、第四铜导线4以及与型材5的回路中加入电阻值r=0.001Ω的分压电阻,通过第一导线1和第四导线4加载电流I并与型材5形成回路,然后测量分压电阻两端的电压为U0,测量第二导线2和第三导线3之间的电压U,电流I为匀速增加的电流,电流I为0~1A,增加幅度0.1A/s,对应得到的电压U为变化电压,对U-(U0/r)进行拟合得到拟合曲线,拟合曲线的斜率为7.91384×10-4,即第1位置处长度为10.0cm的型材5的电阻R1=7.91384×10-4Ω;本实施例的测试示意图如图2所示;Step 2: Add a voltage divider resistor with resistance value r=0.001Ω to the first copper wire 1, the fourth copper wire 4 and the loop with the profile 5, load the current I through the first wire 1 and the fourth wire 4 and connect with the profile. 5. Form a loop, then measure the voltage at both ends of the voltage dividing resistor as U 0 , measure the voltage U between the second wire 2 and the third wire 3, the current I is a current that increases at a constant speed, the current I is 0-1A, and the increase range is 0.1 A/s, corresponding to the obtained voltage U is the changing voltage, fitting U-(U 0 /r) to get the fitting curve, the slope of the fitting curve is 7.91384×10 -4 , that is, the length at the first position is 10.0 The resistance R 1 of the profile 5 of cm is 7.91384×10 -4 Ω; the test schematic diagram of this embodiment is shown in FIG. 2 ;

步骤三、依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至第2位置(型材5的头端起20cm~40cm范围内)、第3位置(型材5的头端起40cm~60cm范围内),并确保第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm不变,按照步骤二中的加载和测量过程,分别计算得到调整后第2位置和第3位置处长度为10.0cm的型材5的电阻依次为R2=8.08842×10-4Ω,R3=8.15882×10-4Ω;Step 3: Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 in turn to the second position (within the range of 20cm to 40cm from the head end of the profile 5). ), the third position (within the range of 40cm to 60cm from the head end of the profile 5), and ensure that the distance L between the fixing point of the second wire 2 on the profile 5 and the fixing point of the third wire 3 on the profile 5 is 10.0cm remains unchanged. According to the loading and measurement process in step 2, the resistances of the profile 5 with a length of 10.0cm at the second and third positions after adjustment are calculated as R 2 =8.08842×10 -4 Ω, R 2 =8.08842×10 -4 Ω 3 = 8.15882 × 10 -4 Ω;

步骤四、根据步骤二和步骤三中得到的电阻R1~R3,计算得到长度为10.0cm的型材5的电阻平均值Ra=8.05369×10-4Ω,然后计算每一位置处长度为10.0cm的型材5的电阻与电阻平均值Ra的偏离度Di,其中,Di=|Ra-Ri|/Ra×100%,得到偏离度Di中的最大值即最大偏离度Dm=1.74%,表明型材5来源的Bi2212高温超导线材加工过程中的二次线材的加工均匀性良好。Step 4: According to the resistances R 1 to R 3 obtained in Step 2 and Step 3, calculate the average resistance value Ra = 8.05369×10 -4 Ω of the profile 5 with a length of 10.0 cm, and then calculate the length at each position as The degree of deviation D i between the resistance of the 10.0 cm profile 5 and the average resistance value Ra , wherein, D i =|R a -R i |/R a ×100%, the maximum value in the degree of deviation D i is obtained, that is, the maximum deviation The degree of D m =1.74%, indicating that the processing uniformity of the secondary wire rod during the processing of the Bi2212 high temperature superconducting wire rod sourced from Profile 5 is good.

本实施例的各导线还可采用对应轴导体代替,采用的型材5可以使用加工完成后的二次线材(长度为6m),即型材5依次缠绕固定在收线盘10、第一轴导体6、第二轴导体7、第三轴导体8、第四轴导体9和放线盘11上,通过同时转动收线盘10和放线盘1,分别调整第一轴导体6、第二轴导体7、第三轴导体8和第四轴导体9在型材5上的缠绕固定位置,然后进行对应的电阻测量及二次线材的加工均匀性表征。The wires in this embodiment can also be replaced by corresponding shaft conductors, and the used profiles 5 can be processed secondary wires (6m in length). , the second axis conductor 7, the third axis conductor 8, the fourth axis conductor 9 and the pay-off reel 11, by rotating the take-up reel 10 and the pay-off reel 1 at the same time, adjust the first axis conductor 6, the second axis conductor respectively 7. The winding and fixing positions of the third axis conductor 8 and the fourth axis conductor 9 on the profile 5, and then carry out the corresponding resistance measurement and the processing uniformity characterization of the secondary wire.

实施例3Example 3

本实施例包括以下步骤:This embodiment includes the following steps:

步骤一、在Bi2212高温超导线材加工过程中的三次线材(长度为14m)的头端和尾端分别截取长度为20cm的样品作为型材5,然后将第一导线1、第二导线2、第三导线3和第四导线4依次缠绕固定在型材5上,将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的固定位置定为第1位置(三次线材头端长度为20cm的样品),并保证第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm;所述第一导线1、第二导线2、第三导线3和第四导线4的材质均为铜;Step 1. In the process of Bi2212 high-temperature superconducting wire processing, the head end and the tail end of the third wire rod (length is 14m) are respectively cut out samples with a length of 20cm as profile 5, and then the first wire 1, the second wire 2, the first wire 2, the first wire The three wires 3 and the fourth wire 4 are wound and fixed on the profile 5 in turn, and the fixed positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 are set as the first position (three times The length of the wire head end is 20cm), and ensure that the distance L between the fixing point of the second wire 2 on the profile 5 and the fixing point of the third wire 3 on the profile 5 is 10.0cm; the first wire 1 , the material of the second wire 2, the third wire 3 and the fourth wire 4 are all copper;

步骤二、通过第一导线1和第四导线4加载电流I并与型材5形成回路,然后测量第二导线2和第三导线3之间的电压U,电流I为匀速增加的电流,电流I为0~1A,增加幅度0.1A/s,对应得到的电压U为变化电压,对U-I进行拟合得到拟合曲线,拟合曲线的斜率为0.00311,即第1位置处长度为10.0cm的型材5的电阻R1=0.00311Ω;本实施例的测试示意图如图1所示;Step 2, load current I through the first wire 1 and the fourth wire 4 and form a loop with the profile 5, then measure the voltage U between the second wire 2 and the third wire 3, the current I is a constant increasing current, and the current I It is 0~1A, the increase range is 0.1A/s, the corresponding voltage U is the changing voltage, and the fitting curve is obtained by fitting UI. The slope of the fitting curve is 0.00311, that is, the length of the profile at the first position is 10.0cm. The resistance R 1 of 5 = 0.00311Ω; the test schematic diagram of this embodiment is shown in FIG. 1 ;

步骤三、依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至第2位置(三次线材尾端长度为20cm的样品),并确保第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm不变,按照步骤二中的加载和测量过程,分别计算得到调整后第2位置处长度为10.0cm的型材5的电阻为R2=0.00315Ω;Step 3: Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 to the second position in turn (the sample with the end length of the third wire 20cm), And ensure that the distance L between the fixed point of the second wire 2 on the profile 5 and the fixed point of the third wire 3 on the profile 5 is 10.0cm unchanged, according to the loading and measurement process in step 2, respectively. Calculated and adjusted The resistance of the profile 5 with a length of 10.0 cm at the second position is R 2 =0.00315Ω;

步骤四、根据步骤二和步骤三中得到的电阻R1和R2,计算得到长度为10.0cm的型材5的电阻平均值Ra=0.00313,然后计算每一位置处长度为10.0cm的型材5的电阻与电阻平均值Ra的偏离度Di,其中,Di=|Ra-Ri|/Ra×100%,得到偏离度Di中的最大值即最大偏离度Dm=0.64%,表明型材5来源的Bi2212高温超导线材加工过程中的三次线材的加工均匀性良好。Step 4: According to the resistances R 1 and R 2 obtained in Step 2 and Step 3, calculate the average resistance value Ra = 0.00313 of the profile 5 with a length of 10.0 cm, and then calculate the profile 5 with a length of 10.0 cm at each position. The degree of deviation D i between the resistance and the average value of resistance Ra , wherein, D i =|R a -R i |/R a ×100%, the maximum value of the degree of deviation D i is obtained, that is, the maximum degree of deviation D m =0.64 %, indicating that the processing uniformity of the tertiary wire rod during the processing of the Bi2212 high temperature superconducting wire rod from Profile 5 is good.

实施例4Example 4

本实施例包括以下步骤:This embodiment includes the following steps:

步骤一、将加工参数相同但一次银管厚度不同且二次银管、三次银合金管相同的两根Bi2212高温超导线材(分别记为A和B,其中,A的一次银管厚度小于B的一次银管厚度)加工过程中的三次线材(长度均为50m)的头端和尾端均截取长度为40cm的样品(记为A1、A2和B1、B2)作为型材5,然后将第一导线1、第二导线2、第三导线3和第四导线4依次缠绕固定在型材5中A上,将第一导线1、第二导线2、第三导线3和第四导线4在型材5中A上的固定位置定为第1位置(即A1的头端0~20cm范围内),并保证第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm;所述第一导线1、第二导线2、第三导线3和第四导线4的材质均为铜;Step 1. Two Bi2212 high-temperature superconducting wires with the same processing parameters but different primary silver tube thickness and the same secondary silver tube and tertiary silver alloy tube (respectively marked as A and B, wherein the primary silver tube thickness of A is less than B The head end and the tail end of the third wire (all 50m in length) during the processing of the thickness of the primary silver tube) were cut with samples with a length of 40cm (denoted as A 1 , A 2 and B 1 , B 2 ) as profile 5, Then, the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 are wound and fixed on the A in the profile 5 in turn, and the first wire 1, the second wire 2, the third wire 3 and the fourth wire are 4. The fixed position of A on the profile 5 is set as the first position (that is, within the range of 0-20cm from the head end of A1), and ensure that the fixed point of the second wire 2 on the profile 5 and the third wire 3 on the profile 5. The distance L between the fixed points is 10.0cm; the materials of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 are all copper;

步骤二、通过第一导线1和第四导线4加载电流I并与型材5形成回路,然后测量第二导线2和第三导线3之间的电压U,电流I为匀速增加的电流,电流I为0~1A,增加幅度0.1A/s,对应得到的电压U为变化电压,对U-I进行拟合得到拟合曲线,拟合曲线的斜率为0.00389,即A的第1位置处长度为10.0cm的型材5的电阻R1=0.00389Ω;本实施例的测试示意图如图1所示;Step 2, load current I through the first wire 1 and the fourth wire 4 and form a loop with the profile 5, then measure the voltage U between the second wire 2 and the third wire 3, the current I is a constant increasing current, and the current I is 0~1A, the increase range is 0.1A/s, the corresponding voltage U is the changing voltage, and the fitting curve is obtained by fitting UI. The slope of the fitting curve is 0.00389, that is, the length of the first position of A is 10.0cm The resistance R 1 =0.00389Ω of the profile 5; the test schematic diagram of this embodiment is shown in Figure 1;

步骤三、依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至A的第2位置(即A1的头端20cm~40cm范围内)、第3位置(即A2的头端0~20cm范围内)和第4位置(即A2的头端20cm~40cm范围内),并确保第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm不变,按照步骤二中的加载和测量过程,分别计算得到调整后第2位置~第4位置处长度为10.0cm的型材5的电阻依次为R2=0.00389Ω,R3=0.00393Ω和R4=0.00394Ω;Step 3: Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 in turn to the second position of A (that is, the head end of A 1 is 20cm ~ 40cm) range), the 3rd position (that is, the head end of A 2 is within the range of 0-20cm) and the 4th position (that is, the head end of A 2 is within the range of 20cm-40cm), and ensure that the second wire 2 is fixed on the profile 5 The distance L between the point and the fixed point of the third wire 3 on the profile 5 is 10.0 cm unchanged. According to the loading and measurement process in step 2, the length from the second position to the fourth position after adjustment is calculated to be 10.0 cm. The resistance of the profile 5 of cm is R 2 =0.00389Ω, R 3 =0.00393Ω and R 4 =0.00394Ω in sequence;

依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至B的第1位置(即B1的头端0cm~20cm范围内)、第2位置(即B1的头端20cm~40cm范围内)、第3位置(即B2的头端0~20cm范围内)和第4位置(即B2的头端20cm~40cm范围内),并确保第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm不变,按照步骤二中的加载和测量过程,分别计算得到B的第1位置~第4位置处长度为10.0cm的型材5的电阻依次为R1=0.00351Ω,R2=0.00352Ω,R3=0.00352Ω和R4=0.00352Ω;Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 in turn to the first position of B (that is, within the range of 0cm to 20cm at the head end of B1) , the second position (that is, within the range of 20cm to 40cm of the head end of B1), the third position (that is, within the range of 0 to 20cm of the head end of B2), and the fourth position (that is, within the range of 20cm to 40cm of the head end of B2 ) ), and ensure that the distance L between the fixed point of the second wire 2 on the profile 5 and the fixed point of the third wire 3 on the profile 5 is 10.0 cm unchanged, according to the loading and measurement process in step 2, respectively calculate The resistances of the profile 5 with a length of 10.0cm at the first position to the fourth position of B are R 1 =0.00351Ω, R 2 =0.00352Ω, R 3 =0.00352Ω and R 4 =0.00352Ω in sequence;

步骤四、根据步骤二和步骤三中得到A和B的电阻R1~R4,计算得到A的长度为10.0cm的型材5的电阻平均值Ra=0.00391,B的长度为10.0cm的型材5的电阻平均值Ra=0.00352,然后计算A和B中每一位置处长度为10.0cm的型材5的电阻与电阻平均值Ra的偏离度Di,其中,Di=|Ra-Ri|/Ra×100%,得到A的偏离度Di中的最大值即最大偏离度Dm=0.70%,B的偏离度Di中的最大值即最大偏离度Dm=0.21%,表明型材5中A来源和B来源的Bi系高温超导线材的加工均匀性均较好,其中,B来源的Bi系高温超导线材的加工均匀性更好,从而说明一次银管壁厚的增加有利于提高Bi系高温超导线材加工的均匀性。Step 4: According to the resistances R 1 to R 4 of A and B obtained in Step 2 and Step 3, the average resistance value of the profile 5 with a length of A of 10.0 cm is calculated to be R a = 0.00391, and the length of B is a profile of 10.0 cm. The average value of resistance of 5 is Ra = 0.00352, and then the degree of deviation D i of the resistance of the profile 5 with a length of 10.0 cm at each position in A and B from the average value of resistance Ra is calculated, where D i = |R a - R i |/R a ×100%, the maximum value of the deviation degree D i of A, that is, the maximum deviation degree D m =0.70%, and the maximum value of the deviation degree D i of B, that is, the maximum deviation degree D m =0.21% , indicating that the processing uniformity of the Bi-based high-temperature superconducting wire from A source and B-source in profile 5 is better, and the processing uniformity of the Bi-based high-temperature superconducting wire from B source is better, which indicates that the primary silver tube wall thickness The increase of α is beneficial to improve the processing uniformity of Bi-based high-temperature superconducting wires.

实施例5Example 5

本实施例包括以下步骤:This embodiment includes the following steps:

步骤一、在两根加工参数不同且银管厚度相近的Bi2212高温超导线材(分别记为A和B,其中,A采用八模拉丝机加工,B采用单模拉丝机加工)加工过程中的三次线材(长度均为50m)的头端和尾端均截取长度为40cm的样品(记为A1、A2和B1、B2)作为型材5,然后将第一导线1、第二导线2、第三导线3和第四导线4依次缠绕固定在型材5中A上,将第一导线1、第二导线2、第三导线3和第四导线4固定在型材5中A上位置定为第1位置(即A1的头端0~20cm范围内),并确定第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm;所述第一导线1、第二导线2、第三导线3和第四导线4的材质均为铜;Step 1. During the processing of two Bi2212 high-temperature superconducting wires with different processing parameters and similar thickness of silver tubes (respectively denoted as A and B, where A is processed by an eight-die wire drawing machine, and B is processed by a single-die wire drawing machine). Samples with a length of 40cm (denoted as A 1 , A 2 and B 1 , B 2 ) were taken from the head and tail ends of the third wire (both 50m in length) as profile 5, and then the first wire 1 and the second wire were 2. The third wire 3 and the fourth wire 4 are wound and fixed on A in the profile 5 in turn, and the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 are fixed on the A in the profile 5 at a fixed position. It is the first position (that is, the head end of A1 is within the range of 0-20cm), and the distance L between the fixed point of the second wire 2 on the profile 5 and the fixed point of the third wire 3 on the profile 5 is determined to be 10.0 cm; the materials of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 are all copper;

步骤二、通过第一导线1和第四导线4加载电流I并与型材5形成回路,然后测量第二导线2和第三导线3之间的电压U,电流I为匀速增加的电流,电流I为0~1A,增加幅度0.1A/s,对应得到的电压U为变化电压,对U-I进行拟合得到拟合曲线,拟合曲线的斜率为0.00336,即A的第1位置处长度为10.0cm的型材5的电阻R1=0.00336Ω;本实施例的测试示意图如图1所示;Step 2, load current I through the first wire 1 and the fourth wire 4 and form a loop with the profile 5, then measure the voltage U between the second wire 2 and the third wire 3, the current I is a constant increasing current, and the current I is 0 to 1A, the increase range is 0.1A/s, the corresponding voltage U is the changing voltage, and the fitting curve is obtained by fitting UI. The slope of the fitting curve is 0.00336, that is, the length of the first position of A is 10.0cm The resistance R 1 =0.00336Ω of the profile 5; the test schematic diagram of this embodiment is shown in Figure 1;

步骤三、依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至A的第2位置(即A1的头端20cm~40cm范围内)、第3位置(即A2的头端0~20cm范围内)和第4位置(即A2的头端20cm~40cm范围内),并确保第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm不变,按照步骤二中的加载和测量过程,分别计算得到调整后第2位置~第4位置处长度为10.0cm的型材5的电阻依次为R2=0.00336Ω,R3=0.00369Ω和R4=0.00362Ω;Step 3: Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 in turn to the second position of A (that is, the head end of A 1 is 20cm ~ 40cm) range), the 3rd position (that is, the head end of A 2 is within the range of 0-20cm) and the 4th position (that is, the head end of A 2 is within the range of 20cm-40cm), and ensure that the second wire 2 is fixed on the profile 5 The distance L between the point and the fixed point of the third wire 3 on the profile 5 is 10.0 cm unchanged. According to the loading and measurement process in step 2, the length from the second position to the fourth position after adjustment is calculated to be 10.0 cm. The resistance of the profile 5 of cm is R 2 =0.00336Ω, R 3 =0.00369Ω and R 4 =0.00362Ω in sequence;

依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至B的第2位置(即B1的头端0cm~20cm范围内)、第2位置(即B1的头端20cm~40cm范围内)、第3位置(即B2的头端0~20cm范围内)和第4位置(即B2的头端20cm~40cm范围内),并保证第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.0cm不变,按照步骤二中的加载和测量过程,分别计算得到B的第1位置~第4位置处长度为10.0cm的型材5的电阻依次为R1=0.00351Ω,R2=0.00352Ω,R3=0.00352Ω和R4=0.00352Ω;Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 in turn to the second position of B (that is, within the range of 0cm to 20cm of the head end of B1) , the second position (that is, within the range of 20cm to 40cm of the head end of B1), the third position (that is, within the range of 0 to 20cm of the head end of B2), and the fourth position (that is, within the range of 20cm to 40cm of the head end of B2 ) ), and ensure that the distance L between the fixed point of the second wire 2 on the profile 5 and the fixed point of the third wire 3 on the profile 5 is 10.0 cm unchanged. According to the loading and measurement process in step 2, calculate The resistances of the profile 5 with a length of 10.0cm at the first position to the fourth position of B are R 1 =0.00351Ω, R 2 =0.00352Ω, R 3 =0.00352Ω and R 4 =0.00352Ω in sequence;

步骤四、根据步骤二和步骤三中得到A和B的电阻R1~R4,计算得到A的长度为10.0cm的型材5的电阻平均值Ra=0.00336,B的长度为10.0cm的型材5的电阻平均值Ra=0.00352,然后计算A和B中每一位置处长度为10.0cm的型材5的电阻与电阻平均值Ra的偏离度Di,其中,Di=|Ra-Ri|/Ra×100%,得到A的偏离度Di中的最大值即最大偏离度Dm=5.20%,B的偏离度Di中的最大值即最大偏离度Dm=0.21%,表明型材5中B来源的Bi系高温超导线材的加工均匀性良好,从而说明采用单模拉丝机有利于提高Bi系高温超导线材加工的均匀性。Step 4: According to the resistances R 1 to R 4 of A and B obtained in Step 2 and Step 3, the average resistance value of the profile 5 with a length of A of 10.0 cm is calculated to be R a = 0.00336, and the length of B is a profile of 10.0 cm. The average value of resistance of 5 is Ra = 0.00352, and then the degree of deviation D i of the resistance of the profile 5 with a length of 10.0 cm at each position in A and B from the average value of resistance Ra is calculated, where D i = |R a - R i |/R a ×100%, the maximum value of the deviation degree D i of A, that is, the maximum deviation degree D m =5.20%, and the maximum value of the deviation degree D i of B, that is, the maximum deviation degree D m =0.21% , indicating that the processing uniformity of the Bi-based high-temperature superconducting wire derived from B in profile 5 is good, indicating that the use of a single-die wire drawing machine is beneficial to improve the processing uniformity of the Bi-based high-temperature superconducting wire.

实施例6Example 6

步骤一、在Bi2212高温超导线材加工过程中的三次线材(长度为500m)上截取长度为600cm的样品作为型材5,然后将型材5依次缠绕固定在收线盘10、第一轴导体6、第二轴导体7、第三轴导体8、第四轴导体9和放线盘11上,将第一轴导体6、第二轴导体7、第三轴导体8、第四轴导体9在型材5上的固定位置定为第1位置(收线盘端起90.0cm~210.0cm),并确定第二轴导体7在型材5上的接触切点与第三轴导体8在型材5上的接触切点之间的距离L′为100.0cm;所述第一轴导体6、第二轴导体7、第三轴导体8、第四轴导体9的材质均为铜;Step 1. Take a sample with a length of 600cm from the tertiary wire (500m in length) in the Bi2212 high temperature superconducting wire processing process as the profile 5, and then the profile 5 is wound and fixed on the take-up reel 10, the first axis conductor 6, On the second axis conductor 7, the third axis conductor 8, the fourth axis conductor 9 and the pay-off reel 11, place the first axis conductor 6, the second axis conductor 7, the third axis conductor 8 and the fourth axis conductor 9 on the profile The fixed position on the The distance L' between the tangent points is 100.0 cm; the materials of the first axis conductor 6, the second axis conductor 7, the third axis conductor 8, and the fourth axis conductor 9 are all copper;

步骤二、通过第一轴导体6和第四轴导体9加载电流I′并与型材5形成回路,然后测量第二轴导体7和第三轴导体8之间的电压U′,电流I′为匀速增加的电流,电流I′为0~1A,增加幅度0.1A/s,对应得到的电压U′为变化电压,对U′-I′进行拟合得到拟合曲线,拟合曲线的斜率为0.03881,即第1位置处长度为100.0cm的型材5的电阻R1′=0.03881Ω;本实施例的测试示意图如图3所示;Step 2: Load current I' through the first shaft conductor 6 and the fourth shaft conductor 9 and form a loop with the profile 5, and then measure the voltage U' between the second shaft conductor 7 and the third shaft conductor 8, the current I' is The current that increases at a constant speed, the current I' is 0-1A, the increase range is 0.1A/s, the corresponding voltage U' is the changing voltage, and the fitting curve is obtained by fitting U'-I', and the slope of the fitting curve is 0.03881, that is, the resistance R 1 ′=0.03881Ω of the profile 5 with a length of 100.0cm at the first position; the test schematic diagram of this embodiment is shown in FIG. 3 ;

步骤三、依次同时转动收线盘10和放线盘1,分别将第一轴导体6、第二轴导体7、第三轴导体8和第四轴导体9在型材5上的缠绕固定位置调整至第2位置(收线盘端起190.0cm~310.0cm)、第3位置(收线盘端起290.0cm~410.0cm)和第4位置(收线盘端起390.0cm~510.0cm),并确保第二轴导体7在型材5上的接触切点与第三轴导体8在型材5上的接触切点之间的距离L′为1000.0cm不变,按照步骤二中的加载和测量过程,分别计算调整后第2位置~第4位置处长度为100.0cm的型材5的电阻依次为R2′=0.03963Ω,R3′=0.03311Ω,和R4′=0.03037Ω;Step 3: Rotate the take-up reel 10 and the pay-out reel 1 simultaneously in turn, and adjust the winding and fixing positions of the first axis conductor 6, the second axis conductor 7, the third axis conductor 8 and the fourth axis conductor 9 on the profile 5 respectively. to the second position (190.0cm~310.0cm from the end of the take-up reel), the third position (290.0cm~410.0cm from the end of the take-up reel) and the fourth position (390.0cm~510.0cm from the end of the take-up reel), and Make sure that the distance L' between the contact tangent point of the second axis conductor 7 on the profile 5 and the contact tangent point of the third axis conductor 8 on the profile 5 is 1000.0 cm unchanged. According to the loading and measurement process in step 2, The resistances of the profiles 5 with a length of 100.0 cm at positions 2 to 4 after adjustment are calculated as R 2 ′=0.03963Ω, R 3 ′=0.03311Ω, and R 4 ′=0.03037Ω in sequence;

步骤四、根据步骤二和步骤三中得到的电阻R1′~R4′,计算得到长度为1000.0cm的型材5的电阻平均值Ra′=0.03548,然后计算每一位置长度为1000.0cm的型材5的电阻与电阻平均值Ra的偏离度Di′,其中,Di′=|Ra′-Rj′|/Ra′×100%,得到偏离值Di′中的最大值即最大偏离值Dm′=14.40%,表明型材5来源的Bi系高温超导线材的加工均匀性差。Step 4: According to the resistances R 1 ′~R 4 ′ obtained in Step 2 and Step 3, calculate the average resistance value R a ′=0.03548 of the profile 5 with a length of 1000.0cm, and then calculate the resistance value of each position with a length of 1000.0cm. The degree of deviation D i ' between the resistance of the profile 5 and the average resistance value Ra , wherein, D i '=|R a '-R j '|/R a '×100%, the maximum value of the deviation value D i ' is obtained That is, the maximum deviation value D m ′=14.40%, which indicates that the processing uniformity of the Bi-based high-temperature superconducting wire from Profile 5 is poor.

实施例7Example 7

本实施例包括以下步骤:This embodiment includes the following steps:

步骤一、在Bi2212复合线材经高压热处理后的高温超导线材上截取长度为50cm的样品作为型材5,然后将第一导线1、第二导线2、第三导线3和第四导线4依次缠绕固定在型材5上,将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的固定位置定为第1位置(型材5的头端起0~5cm范围内),并确定第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为3.00cm;所述第一导线1、第二导线2、第三导线3和第四导线4的材质均为铜;Step 1. Take a sample with a length of 50 cm from the high-temperature superconducting wire after the high-pressure heat treatment of the Bi2212 composite wire as the profile 5, and then wrap the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 in turn. Fixed on the profile 5, the fixed position of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 is set as the first position (within the range of 0-5cm from the head end of the profile 5 ), and determine the distance L between the fixed point of the second wire 2 on the profile 5 and the fixed point of the third wire 3 on the profile 5 to be 3.00cm; the first wire 1, the second wire 2, the third wire The material of the wire 3 and the fourth wire 4 is copper;

步骤二、通过第一导线1和第四导线4加载电流I并与型材5形成回路,然后测量第二导线2和第三导线3之间的电压U,电流I为匀速增加的电流,电流I为0~1A,增加幅度0.1A/s,对应得到的电压U为变化电压,对U-I进行拟合得到拟合曲线,拟合曲线的斜率为0.00102,即第1位置处长度为3.00cm的型材5的电阻R1=0.00102Ω;本实施例的测试示意图如图4所示;Step 2, load current I through the first wire 1 and the fourth wire 4 and form a loop with the profile 5, then measure the voltage U between the second wire 2 and the third wire 3, the current I is a constant increasing current, and the current I is 0~1A, the increase range is 0.1A/s, the corresponding voltage U is the changing voltage, and the fitting curve is obtained by fitting the UI. The slope of the fitting curve is 0.00102, that is, the length of the profile at the first position is 3.00cm. The resistance R 1 of 5 = 0.00102Ω; the test schematic diagram of this embodiment is shown in FIG. 4 ;

步骤三、依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至第2位置(型材5的头端起5cm~10cm范围内)、第3位置(型材5的头端起10cm~15cm范围内)、第4位置(型材5的头端起15cm~20cm范围内)、第5位置(型材5的头端起20cm~25cm范围内)、第6位置(型材5的头端起25cm~30cm范围内)、第7位置(型材5的头端起30cm~35cm范围内)、第8位置(型材5的头端起35cm~40cm范围内)、第9位置(型材5的头端起40cm~45cm范围内)和第10位置(型材5的头端起45cm~50cm范围内),并保证第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为3.00cm不变,按照步骤二中的加载和测量过程,分别计算得到调整后第2位置~第10位置处长度为3.00cm的型材5的电阻依次为R2=0.00103Ω,R3=0.00108Ω,R4=0.00103Ω,R5=0.00103Ω,R6=0.00104Ω,R7=0.00106Ω,R8=0.00108Ω,R9=0.00104Ω和R10=0.00104Ω;Step 3: Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 to the second position in turn (within the range of 5cm to 10cm from the head end of the profile 5). ), the third position (within the range of 10cm to 15cm from the head end of the profile 5), the fourth position (within the range of 15cm to 20cm from the head end of the profile 5), the fifth position (within the range of 20cm to 25cm from the head end of the profile 5) inside), the 6th position (within the range of 25cm to 30cm from the head end of the profile 5), the 7th position (within the range of 30cm to 35cm from the head end of the profile 5), the 8th position (35cm to 40cm from the head end of the profile 5) range), the 9th position (within the range of 40cm-45cm from the head end of the profile 5) and the 10th position (within the range of 45cm-50cm from the head end of the profile 5), and ensure that the second wire 2 is fixed on the profile 5 The distance L between the point and the fixed point of the third wire 3 on the profile 5 is 3.00cm unchanged. According to the loading and measurement process in step 2, the length from the second position to the tenth position after adjustment is calculated to be 3.00 cm. The resistance of the profile 5 of cm is R 2 =0.00103Ω, R 3 =0.00108Ω, R 4 =0.00103Ω, R 5 =0.00103Ω, R 6 =0.00104Ω, R 7 =0.00106Ω, R 8 =0.00108Ω, R 9 =0.00104Ω and R 10 =0.00104Ω;

步骤四、根据步骤二和步骤三中得到的电阻R1~R10,计算得到长度为3.00cm的型材5的电阻平均值Ra=0.00105,然后计算每一位置处长度为3.00cm的型材5的电阻与电阻平均值Ra的偏离度Di,其中,Di=|Ra-Ri|/Ra×100%,得到偏离度Di中的最大值即最大偏离度Dm=3.35%,表明型材5来源的复合线材的加工均匀性良好。Step 4: According to the resistances R 1 to R 10 obtained in Step 2 and Step 3, calculate the average resistance value Ra = 0.00105 of the profile 5 with a length of 3.00 cm, and then calculate the profile 5 with a length of 3.00 cm at each position. The degree of deviation D i between the resistance and the average value of resistance Ra , where, D i =|R a -R i |/R a ×100%, the maximum value of the degree of deviation D i is obtained, that is, the maximum degree of deviation D m =3.35 %, indicating that the processing uniformity of the composite wire from Profile 5 is good.

实施例8Example 8

本实施例包括以下步骤:This embodiment includes the following steps:

步骤一、在Bi2223高温超导带材上随机截取6根长度为20cm的样品作为型材5,然后将第一导线1、第二导线2、第三导线3和第四导线4依次缠绕固定在型材5的第1根样品上,将第一导线1、第二导线2、第三导线3和第四导线4固定在型材5上的位置定为第1位置,并确定第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.00cm;所述第一导线1、第二导线2、第三导线3和第四导线4的材质均为铜;Step 1. Randomly cut 6 samples with a length of 20cm on the Bi2223 high-temperature superconducting tape as profile 5, and then wrap the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 in turn and fix them on the profile. On the first sample of The distance L between the fixed point on the upper part and the fixed point of the third wire 3 on the profile 5 is 10.00cm; the materials of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 are all copper;

步骤二、通过第一导线1和第四导线4加载电流I并与型材5形成回路,然后测量第二导线2和第三导线3之间的电压U,所述电流I为匀速增加的电流,电流I为0~1A,增加幅度0.1A/s,对应得到的电压U为变化电压,对U-I进行拟合得到拟合曲线,拟合曲线的斜率为0.00216,即第1位置处长度为10.00cm的型材5的电阻R1=0.00216Ω;本实施例的测试示意图如图1所示;Step 2: Load current I through the first wire 1 and the fourth wire 4 and form a loop with the profile 5, and then measure the voltage U between the second wire 2 and the third wire 3, the current I is a constant increasing current, The current I is 0-1A, the increase range is 0.1A/s, the corresponding voltage U is the changing voltage, and the fitting curve is obtained by fitting UI. The slope of the fitting curve is 0.00216, that is, the length at the first position is 10.00cm The resistance R 1 =0.00216Ω of the profile 5; the test schematic diagram of this embodiment is shown in Figure 1;

步骤三、依次将第一导线1、第二导线2、第三导线3和第四导线4在型材5上的缠绕固定位置整体调整至第2位置(即第2根样品)、第3位置(即第3根样品)、第4位置(即第4根样品)、第5位置(即第5根样品)和第6位置(即第6根样品),并确保第二导线2在型材5上的固定点与第三导线3在型材5上的固定点之间的距离L为10.00cm不变,按照步骤二中的加载和测量过程,分别计算得到调整后第2位置~第6位置处长度为10.00cm的型材5的电阻依次为R2=0.00218Ω,R3=0.00216Ω,R4=0.00218Ω、R5=0.00218Ω和R6=0.00217Ω;Step 3: Adjust the winding and fixing positions of the first wire 1, the second wire 2, the third wire 3 and the fourth wire 4 on the profile 5 to the second position (ie the second sample), the third position ( i.e. 3rd sample), 4th position (i.e. 4th sample), 5th position (i.e. 5th sample) and 6th position (i.e. 6th sample), and make sure that the second wire 2 is on the profile 5 The distance L between the fixed point of the third wire 3 and the fixed point of the third wire 3 on the profile 5 is 10.00cm unchanged. According to the loading and measurement process in step 2, the lengths from the second position to the sixth position after adjustment are calculated respectively. The resistance of the 10.00cm profile 5 is R 2 =0.00218Ω, R 3 =0.00216Ω, R 4 =0.00218Ω, R 5 =0.00218Ω and R 6 =0.00217Ω;

步骤四、根据步骤二和步骤三中得到的电阻R1~R6,计算得到长度为10.00cm的型材5的电阻平均值Ra=0.00217,然后计算每一位置处长度为10.00cm的型材5的电阻与电阻平均值Ra的偏离度Di,其中,Di=|Ra-Ri|/Ra×100%,得到偏离度Di中的最大值即最大偏离度Dm=0.54%,表明型材5来源的Bi2223高温超导带材的加工均匀性良好。Step 4: According to the resistances R 1 to R 6 obtained in Step 2 and Step 3, calculate the average resistance value of the profile 5 with a length of 10.00 cm R a = 0.00217, and then calculate the profile 5 with a length of 10.00 cm at each position. The degree of deviation D i between the resistance and the average value of resistance Ra , where, D i =|R a -R i |/R a ×100%, the maximum value of the degree of deviation D i is obtained, that is, the maximum degree of deviation D m =0.54 %, indicating that the processing uniformity of the Bi2223 high-temperature superconducting tape from Profile 5 is good.

实施例9Example 9

本实施例与实施例1的不同之处在于:步骤一中第二导线2、第三导线3在型材5上的固定点之间的距离为1.00cm。The difference between this embodiment and Embodiment 1 is that in step 1, the distance between the fixing points of the second wire 2 and the third wire 3 on the profile 5 is 1.00 cm.

以上所述,仅是本发明的较佳实施例,并非对本发明作任何限制。凡是根据发明技术实质对以上实施例所作的任何简单修改、变更以及等效变化,均仍属于本发明技术方案的保护范围内。The above descriptions are only preferred embodiments of the present invention, and do not limit the present invention in any way. Any simple modifications, changes and equivalent changes made to the above embodiments according to the technical essence of the invention still fall within the protection scope of the technical solutions of the present invention.

Claims (9)

1. A method for representing the processing uniformity of a Bi-based high-temperature superconducting wire or strip is characterized in that the method tests the resistance of the Bi-based high-temperature superconducting wire or strip at different positions based on a room-temperature resistance testing principle by a four-wire method, and then represents the processing uniformity of the Bi-based high-temperature superconducting wire or strip through the resistance difference at different positions;
the method comprises the following steps:
firstly, a first lead (1), a second lead (2), a third lead (3) and a fourth lead (4) are sequentially wound and fixed on a section bar (5), the fixed positions of the first lead (1), the second lead (2), the third lead (3) and the fourth lead (4) on the section bar (5) are determined as a 1 st position, and the distance between the fixed point of the second lead (2) on the section bar (5) and the fixed point of the third lead (3) on the section bar (5) is determined as L; the section (5) is a Bi-series high-temperature superconducting wire or strip;
step two, loading current I through the first lead (1) and the fourth lead (4) and forming a loop with the section bar (5), then measuring voltage U between the second lead (2) and the third lead (3), and calculating resistance R of the section bar (5) with the length of L at the 1 st position according to ohm law R ═ U/I to obtain resistance R of the section bar (5)1
Step three, the winding fixing positions of the first lead (1), the second lead (2), the third lead (3) and the fourth lead (4) on the section bar (5) are adjusted integrally in sequence, the distance L between the fixing point of the second lead (2) on the section bar (5) and the fixing point of the third lead (3) on the section bar (5) is ensured to be unchanged until the position i is adjusted, wherein i is a natural number and i is not less than 2, the resistances of the section bar (5) with the length L at different positions after adjustment are respectively calculated according to the loading and measuring processes in the step two until the resistance R is obtainedi
Step four, obtaining the resistance R according to the step two and the step three1~RiAnd calculating the average resistance value R of the section bar (5) with the length LaThen, the resistance of the profile (5) of length L at each position is calculated together with the average value R of the resistanceaDegree of deviation D ofiWherein Di is ═ Ra-Ri|/RaX 100% and degree of deviation DiMaximum value of (1) is the maximum deviation degree DmSelecting the maximum deviation DmCharacterizing the processing uniformity of the Bi-based high-temperature superconducting wire or strip from the profile (5);
or the method comprises the following steps:
the method comprises the following steps of firstly, winding and fixing a section bar (5) on a take-up reel (10), a first shaft conductor (6), a second shaft conductor (7), a third shaft conductor (8), a fourth shaft conductor (9) and a pay-off reel (11) in sequence, setting the fixed positions of the first shaft conductor (6), the second shaft conductor (7), the third shaft conductor (8) and the fourth shaft conductor (9) on the section bar (5) as a position 1, and determining the distance between a contact tangent point of the second shaft conductor (7) on the section bar (5) and a contact tangent point of the third shaft conductor (8) on the section bar (5) to be L'; the section (5) is a Bi-series high-temperature superconducting wire or strip;
step two, loading current I 'through the first shaft conductor (6) and the fourth shaft conductor (9) to form a loop with the profile (5), measuring the voltage U' between the second shaft conductor (7) and the third shaft conductor (8), and calculating the resistance R 'of the profile (5) with the length L' at the 1 st position according to the ohm law R which is U/I1′;
Step three, sequentially and simultaneously rotating a take-up reel (10) and a pay-off reel (11), integrally adjusting the winding fixing positions of the first shaft conductor (6), the second shaft conductor (7), the third shaft conductor (8) and the fourth shaft conductor (9) on the section bar (5) respectively, ensuring that the distance L 'between the contact tangent point of the second shaft conductor (7) on the section bar (5) and the contact tangent point of the third shaft conductor (8) on the section bar (5) is unchanged until the j position is adjusted, wherein j is a natural number and is not less than 2, respectively calculating the resistance of the section bar (5) with the length L' at different positions after adjustment according to the loading and measuring processes in the step two until the resistance R is obtainedj′;
Step four, obtaining the resistance R according to the step two and the step three1′~Rj', calculating the average value R of the resistance of the profile (5) of length La' then calculating the resistance at each position and the average value of the resistance RaDegree of deviation D of `i', wherein Di′=|Ra′-Rj′|/Ra'. times.100%, and degree of deviation DiThe maximum value in is the maximum deviation Dm', selecting the maximum deviation Dm' characterizing the processing uniformity of the Bi-based high-temperature superconducting wire or strip from the profile (5).
2. The method for characterizing the processing uniformity of the Bi-based high-temperature superconducting wire or strip according to claim 1, wherein in the first step, the first conducting wire (1), the second conducting wire (2), the third conducting wire (3) and the fourth conducting wire (4) are all made of copper; the length of the section (5) is not less than 5cm, and the section (5) is a sample cut from a primary wire, a secondary wire, a composite wire or strip in the processing process of the Bi-based high-temperature superconducting wire or strip, or the Bi-based high-temperature superconducting composite wire or strip; in the step one, L is more than or equal to 1cm, the measurement precision of L is not less than 0.01cm when L is more than or equal to 1cm and less than 10cm, and the measurement precision of L is not less than 0.1cm when L is more than or equal to 10 cm.
3. The method for characterizing the processing uniformity of the Bi-based high-temperature superconducting wire or strip according to claim 1, wherein in the second step, if the current I is a variable current and the voltage U is a variable voltage, the U-I is fitted to obtain a fitted curve, and the slope of the fitted curve is the resistance R of the section (5) with the length L at the 1 st position1
4. The method according to claim 1, wherein the current I in step two is a variable current, and a divider resistor with a resistance r is arranged in series in a loop formed by the first lead (1), the fourth lead (4) and the profile (5), so that a voltage U of the series resistor is a voltage U of the series resistor0And U are both variable voltage, for U- (U)0/R) is fitted to obtain a fitted curve, the slope of which is the resistance R of the section (5) of length L at the 1 st position1
5. The method according to claim 1, wherein the maximum deviation D in the fourth step ismWhen the processing uniformity of the Bi-based high-temperature superconducting wire or strip is more than 5 percent of the preset value of the processing uniformity of the Bi-based high-temperature superconducting wire or strip, the processing uniformity of the Bi-based high-temperature superconducting wire or strip from the section (5) is poor, and when the maximum deviation degree D is higher than the preset value of the processing uniformity of the Bi-based high-temperature superconducting wire or strip, the maximum deviation degree D ismIs less than BiWhen the preset value of the processing uniformity of the high-temperature superconducting wire or strip is 5%, the processing uniformity of the Bi system high-temperature superconducting wire or strip from the section (5) is good.
6. The method for characterizing the processing uniformity of the Bi-based high-temperature superconducting wire or strip according to claim 1, wherein the first axial conductor (6), the second axial conductor (7), the third axial conductor (8) and the fourth axial conductor (9) are all made of copper; the length of the section (5) is not less than 50cm, and the section (5) is a primary wire, a secondary wire, a composite wire or strip in the processing process of the Bi-system high-temperature superconducting wire or strip, or a intercepted sample on the Bi-system high-temperature superconducting composite wire or strip; the L ' is not less than 1cm, the measurement precision of the L ' is not lower than 0.01cm when the L ' is not less than 1cm and not more than 10cm, and the measurement precision of the L ' is not lower than 0.1cm when the L ' is not less than 10 cm.
7. The method for characterizing the processing uniformity of the Bi-based high-temperature superconducting wire or strip according to claim 1, wherein in the second step, if the current I ' is a variable current and the voltage U ' is a variable voltage, the U ' -I ' is fitted to obtain a fitted curve, and the slope of the fitted curve is the resistance R of the section (5) with the length L ' at the 1 st position1′。
8. The method according to claim 1, wherein the current I' in step two is a variable current, and a divider resistor with a resistance r is arranged in series in a loop formed by the first axial conductor (6), the fourth axial conductor (9) and the profile (5), so that a voltage U of the series resistor is a voltage U of the series resistor0Both ' and U ' are of varying voltage, for U ' - (U)0'/R) is fitted to obtain a fitted curve, the slope of which is the resistance R of the profile (5) of length L' at position 11′。
9. The method according to claim 1, wherein the step four is performedMean maximum deviation DmWhen the value is more than 5 percent of the preset value of the processing uniformity of the Bi-based high-temperature superconducting wire or strip, the processing uniformity of the Bi-based high-temperature superconducting wire or strip from the section (5) is poor, and when the maximum deviation D is reachedmWhen the processing uniformity of the Bi-based high-temperature superconducting wire or strip is less than 5% of the preset value of the processing uniformity of the Bi-based high-temperature superconducting wire or strip, the processing uniformity of the Bi-based high-temperature superconducting wire or strip from the profile (5) is good.
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