CN1117066A - Ceramic imitating and colouring method for fireproof paint - Google Patents
Ceramic imitating and colouring method for fireproof paint Download PDFInfo
- Publication number
- CN1117066A CN1117066A CN 94114883 CN94114883A CN1117066A CN 1117066 A CN1117066 A CN 1117066A CN 94114883 CN94114883 CN 94114883 CN 94114883 A CN94114883 A CN 94114883A CN 1117066 A CN1117066 A CN 1117066A
- Authority
- CN
- China
- Prior art keywords
- grams
- frie retardant
- retardant coating
- coating
- porcelain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000000919 ceramic Substances 0.000 title claims abstract description 5
- 239000003973 paint Substances 0.000 title abstract description 3
- 238000004040 coloring Methods 0.000 title description 3
- 229920003023 plastic Polymers 0.000 claims abstract description 8
- 239000004033 plastic Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 claims description 46
- 238000000576 coating method Methods 0.000 claims description 46
- 229910052573 porcelain Inorganic materials 0.000 claims description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 9
- 230000002265 prevention Effects 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 7
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 7
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 7
- 239000006260 foam Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 230000009970 fire resistant effect Effects 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 4
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 4
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 4
- 229940037003 alum Drugs 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 4
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 4
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 4
- 239000004571 lime Substances 0.000 claims description 4
- 229940059574 pentaerithrityl Drugs 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 229940080314 sodium bentonite Drugs 0.000 claims description 4
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 4
- 241000276489 Merlangius merlangus Species 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000010419 fine particle Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 2
- 230000006641 stabilisation Effects 0.000 claims description 2
- 238000011105 stabilization Methods 0.000 claims description 2
- 239000002699 waste material Substances 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 description 12
- 238000003825 pressing Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a new-type color pulp prepn method, which makes incompatible components form a colouring center via capsulation. In this way, fireproof component and ceramic imitating component become compatible and coloured to produce a new multifunctional paint. The present invention adopts the waste foamed plastics as material, and thus has obvious social and economical utilities.
Description
The invention belongs to the chemistry painting industry technology, specifically relate to a kind of manufacture method of ceramic imitating and colouring of frie retardant coating.That is to say and make a kind of porcelain sense that has, the technology of the frie retardant coating of colorful property is arranged again.Than CN1076211A more function is arranged---fire prevention, and utilize used foam plastics, so bigger social benefit and economic benefit are arranged.
At present, expanding fire-proof paint is to be base-material with the resin, and interpolation catalyzer, carbon source agent, whipping agent form through mixed grinding.The used fire-resistant composition of the present invention is:
Polyvinyl alcohol 4-6 grams
Polyphosphoric acid is by 20-24 grams
Tetramethylolmethane 8-10 grams
Trimeric cyanamide 8-12 grams
Titanium dioxide 5-7 grams
Aluminium hydroxide 6-8 grams
Water 40-48 grams
Method for making of the present invention is that polyvinyl alcohol is added in the water, and reheat to 90 ℃ dissolving is cooled to each component that adds after the room temperature except that ammonium polyphosphate, grinds at last to filter to form the matrix of preventing fires.
Now, porcelain-imitated coating is a base-material with the polyvinyl alcohol often, adds calcareous inorganics, talcum powder, pigment etc., forms through mixed grinding.The used imitative porcelain component of the present invention is:
Polyvinyl alcohol 2-4 grams
Xylo-Mucine 1-1.5 grams
Lime powder 8-12 grams
Alum 1-1.5 grams
Lime carbonate (the fine particle calcium carbonate type is 1 with coarse whiting type ratio) 27-33 grams
Sodium bentonite 1-1.5 grams
Titanium dioxide 5-7 grams
Talcum powder 3-5 grams
Water 41-49 grams
Method for making of the present invention is that polyvinyl alcohol is added in the water: and be heated to 90 ℃, wait to dissolve postcooling and add the Xylo-Mucine dissolving again to room temperature, at last other components in the above-mentioned prescription are added in regular turn through mixing, grind, filter the imitative porcelain component of formation.
If with above-mentioned fire prevention matrix, porcelain-imitated coating, even add ammonium polyphosphate in the fire-resistant composition again, can not obtain imitative porcelain frie retardant coating so, can only obtain a kind ofly having imitative porcelain sense and not having the coating of fire resistance.
The objective of the invention is to make above-mentioned two kinds of difference in functionality coating, on its plinth that keeps original fire prevention and imitative porcelain function, have colorful property.Make a kind of coating mill base for this reason, come coated ammonium polyphosphate to make it encapsulated and form painted center with it.The component that coats mill base is:
Used foam plastics 5-6 grams
Dimethylbenzene 12-14 grams
Pigment is an amount of
The method for making that coats mill base is with used foam plastics, uses xylene soluble, adds pigment grind, filtration again, promptly gets and coats mill base.The also available polyvinyl chloride of above-mentioned used foam plastics replaces.Flame retardant resistance is more expensive also high as a result for it.
The method that the present invention makes the color porcelain-like frie retardant coating is following steps:
The first, get above-mentioned made a kind of color and coat mill base 8-10 grams (be above-mentioned coating mill base composition weight 1/2) and mix with ammonium polyphosphate in the fire-resistant composition, make it encapsulated, become a kind of painted center.Be added to then in the fire prevention matrix and obtain the full of stains or spots frie retardant coating of a kind of color dot.
Second, under remaining coating mill base 8-10 grams (be above-mentioned coating mill base composition weight 1/2) 50-200 rev/mins of conditions of low whipping speed, add with 0.5-0.1 gram/minute, make original look grain in frie retardant coating become size appropriateness, the look grain that form is colourful.
The 3rd, when the frie retardant coating that has big or small appropriate look grain forms, add the frie retardant coating that imitative porcelain component makes look grain stabilization and the porcelain sense is arranged immediately.
The 4th, change the kind and the quantity that coat used pigment in the mill base, repeat above-mentioned first to third step, then can obtain the imitative porcelain frie retardant coating of another kind of color look grain.According to user's requirement, press different ratios, the blend of not homochromy grain then required color porcelain-like frie retardant coating.
The made color porcelain-like frie retardant coating of the present invention has following character and function:
At condition in container: there is not the look grain (appearance method) that even cloth in the paste coating of caking different colours, shape and different sizes.
Solid content: 42-50% (pressing GB1725-79 test)
Application property: can criticize and scrape, add water and transfer rare then can the brush maybe to spray.
Time of drying: surface drying 2-3 hours, do solid work 12-15 hours (pressing GB1728-79 test)
Appearance of coat has the porcelain sense, and colorful property (appearance method) is arranged again
Water tolerance: soaked in 48 hours, nothing is peeled off, wrinkle resistant (pressing GB1733-79 test)
Wet-rub resistance: (press the GB9266 test) more than 200 times
Shock-resistance: 0.25Ncm above (pressing GB1732-79 test)
Sticking power: 0.25MPa above (pressing the 2BQ24001 test)
Flame retardant resistance: on plank, execute cloth 750 gram/rice
2The time fire-proof function be: fire resistance period: more than 30 minutes.Below weightless 5 grams.2 centimetres of charings
3Following propagation of flame (is pressed the GB1244 test) below 15 centimetres
Color porcelain-like frie retardant coating cost of the present invention only is coated with for it 1/2-1/3 for multicolor finish or fire prevention.
Embodiment:
Fire-resistant composition:
Polyvinyl alcohol 4 grams
Ammonium polyphosphate 20 grams
Tetramethylolmethane 8 grams
Trimeric cyanamide 10 grams
Titanium dioxide 6 grams
Aluminium hydroxide 6 grams
Water 40 grams
Method for making is after 90 ℃ of following waters are with the polyvinyl alcohol dissolving, adds tetramethylolmethane, trimeric cyanamide, titanium dioxide and aluminium hydroxide grinding behind the cool to room temperature and filters to such an extent that the fire prevention matrix is standby.
Imitative porcelain component:
Polyvinyl alcohol 3 grams
Xylo-Mucine 1 gram
Lime powder 12 grams
Alum 1 gram
Lime carbonate (the fine particle calcium carbonate type is 1 with coarse whiting type ratio) 33 grams
Sodium bentonite 1 gram
Titanium dioxide 6 grams
Talcum powder 4 grams
Water 45 grams
Method for making be at 90 ℃ of following waters after the polyvinyl alcohol dissolving, cool to room temperature again with the Xylo-Mucine dissolving, adds lime powder, alum, lime carbonate, sodium bentonite, titanium dioxide, talcum powder at last and grinds to filter and obtain imitative porcelain component with standby.
Coat the mill base component:
Used foam plastics 5 grams
Dimethylbenzene 13 grams
Phthalocyanine green 0.6 gram
Method for making be with dimethylbenzene with used foam plastics, be dissolved into transparent glue.Add phthalocyanine green grinding filtration and become the coating mill base.
The method for making of band look grain frie retardant coating is that the green mill base and 20 that coats of 9.3 grams is restrained the ammonium polyphosphate blend, is added in the fire prevention matrix again and stirs.Be added dropwise to the green mill base that coats of remaining 9.3 grams with 0.2 gram/minute at last under 50 rev/mins of stirrings and obtain the size appropriateness, colourful green is striven the frie retardant coating of the even cloth of grain.
Imitative method for making of watering frie retardant coating: will imitate in the frie retardant coating that the porcelain component adds the band chromoplastid is the stable imitative porcelain frie retardant coating of Dry Sack grain.
The method for making of color porcelain-like frie retardant coating is to change above-mentioned phthalocyanine green into toluidine red, and repeats the stable imitative porcelain frie retardant coating that each step can get the even cloth of the colourful red look grain of big or small appropriateness.
With above two kinds of green and red imitative porcelain frie retardant coating blend be and the color porcelain-like frie retardant coating.
If make behind the imitative porcelain frie retardant coating, blend of more kinds of monochromatic look grains then the color porcelain-like frie retardant coating of masstone more.
Claims (4)
1, a kind of color porcelain-like frie retardant coating is characterized in that with fire-resistant composition, and imitative porcelain component and mill base component are made.
Fire-resistant composition:
Polyvinyl alcohol 4-6 grams
Polyphosphoric acid is by 20-24 grams
Tetramethylolmethane 8-10 grams
Trimeric cyanamide 8-12 grams
Titanium dioxide 5-7 grams
Aluminium hydroxide 6-8 grams
Water 40-48 grams
Imitative porcelain component:
Polyvinyl alcohol 2-4 grams
Xylo-Mucine 1-1.5 grams
Lime powder 8-12 grams
Alum 1-1.5 grams
Lime carbonate (the fine particle calcium carbonate type is 1 with coarse whiting type ratio) 27-33 grams
Sodium bentonite 1-1.5 grams
Titanium dioxide 5-7 grams
Talcum powder 3-5 grams
Water 41-49 grams
The mill base component:
Used foam plastics 5-6 grams
Dimethylbenzene 12-14 grams
Pigment is an amount of
2, according to the described coating of claim 1, the feature of its manufacturing is as encapsulated painted center material with the mill base coated ammonium polyphosphate. be added to then in the fire prevention matrix, form the frie retardant coating of band chromoplastid.
3, according to claim 1 and 2 described coating, change the look grain size of the frie retardant coating of being with chromoplastid and the method for shape, it is characterized in that adding again the mill base component, regulate stirring velocity and be 50-200 rev/mins, feed rate is 0.5-0.1 gram/minute, makes look grain size appropriateness, and form is colourful.
4, according to claim 1 and 3 described coating, the feature of the stabilization of look grain and the ceramic imitating of coating is in time to add imitative porcelain component in the frie retardant coating of band chromoplastid, make look grain size and form stable, make coating have imitative porcelain, form the imitative porcelain frie retardant coating of monochromatic look grain, the imitative porcelain frie retardant coating of multiple monochromatic look grain is pressed the different ratios blend and is promptly got a kind of color porcelain-like frie retardant coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94114883 CN1117066A (en) | 1994-08-17 | 1994-08-17 | Ceramic imitating and colouring method for fireproof paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94114883 CN1117066A (en) | 1994-08-17 | 1994-08-17 | Ceramic imitating and colouring method for fireproof paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1117066A true CN1117066A (en) | 1996-02-21 |
Family
ID=5037254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94114883 Pending CN1117066A (en) | 1994-08-17 | 1994-08-17 | Ceramic imitating and colouring method for fireproof paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1117066A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100368493C (en) * | 2006-02-16 | 2008-02-13 | 刘玉生 | Environment-friendly type decoration paste |
| CN100556859C (en) * | 2007-09-12 | 2009-11-04 | 诸葛剑锋 | A method for manufacturing imitation porcelain with cracking effect |
| CN102190460A (en) * | 2010-03-11 | 2011-09-21 | 梁振华 | Toughened tile-like coating |
| CN102850869A (en) * | 2012-09-03 | 2013-01-02 | 南通市兴宇漆业有限责任公司 | Aqueous porcelain imitating coating material |
| CN110157284A (en) * | 2019-06-12 | 2019-08-23 | 应急管理部四川消防研究所 | Transparent fireproof coating and its processing method |
-
1994
- 1994-08-17 CN CN 94114883 patent/CN1117066A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100368493C (en) * | 2006-02-16 | 2008-02-13 | 刘玉生 | Environment-friendly type decoration paste |
| CN100556859C (en) * | 2007-09-12 | 2009-11-04 | 诸葛剑锋 | A method for manufacturing imitation porcelain with cracking effect |
| CN102190460A (en) * | 2010-03-11 | 2011-09-21 | 梁振华 | Toughened tile-like coating |
| CN102190460B (en) * | 2010-03-11 | 2012-09-26 | 梁振华 | Toughened tile-like coating |
| CN102850869A (en) * | 2012-09-03 | 2013-01-02 | 南通市兴宇漆业有限责任公司 | Aqueous porcelain imitating coating material |
| CN110157284A (en) * | 2019-06-12 | 2019-08-23 | 应急管理部四川消防研究所 | Transparent fireproof coating and its processing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101230214B (en) | A cement-based luminous porcelain imitation dry powder coating and its preparation method | |
| CN100519680C (en) | Water epoxy paint for ground floor and its mfg. process and construction technology | |
| CN110527384B (en) | Application of expanded and vitrified micro bubbles in sand-in-water base paint, preparation method and sand-in-water coating | |
| CN1169892C (en) | Production process of colar glaze guartz paint | |
| CN106084927B (en) | Powder decorative paint and its preparation, construction method | |
| CN100584787C (en) | Method for producing glass lamp-shade surface coating | |
| CN107955425A (en) | Building coating and preparation method thereof and construction method | |
| CN110204277A (en) | A kind of anti-caking glue for tile and preparation method thereof | |
| CN101343436A (en) | Novel water-covering water gorgeous paint and preparation thereof | |
| CN100547038C (en) | A kind of preparation method of titania-silica color glaze pigment-filler for ceramic | |
| CN1117066A (en) | Ceramic imitating and colouring method for fireproof paint | |
| CN101659822A (en) | Water-based water transfer varnish paint and preparation method thereof | |
| CN102762677A (en) | Ceramic mediums and inks in powder form | |
| CN109796824A (en) | A kind of emulation mineral varnish color grain, emulation mineral varnish and its preparation method and application | |
| CN1038042C (en) | Enamel-imitating multicolour paint and preparing process thereof | |
| CN1548483A (en) | Expanding heat-insulating fireproof putty powder | |
| CN102181196A (en) | Water-in-water colorful stone simulated paint | |
| CN113956077B (en) | Decorative ceramic tile using baking-free glaze and manufacturing process thereof | |
| CN105647262A (en) | Colorfast mineral pigment for painting | |
| CN1667061A (en) | Decoration paint for stereo wall art | |
| CN115710437B (en) | Composite clay and preparation method and application thereof | |
| CN1024354C (en) | Composite building paint of polyvinyl alcohol and bentonite | |
| CN1100115A (en) | Production of sprayed wall decorating material | |
| CN1844040A (en) | Heat-insulating energy-saving temperature-constant ceramic brick and manufacturing process thereof | |
| CN101591481A (en) | A kind of inorganic dry powder painting |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |