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CN111670276A - High-performance nylon tire cord - Google Patents

High-performance nylon tire cord Download PDF

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Publication number
CN111670276A
CN111670276A CN201880088931.8A CN201880088931A CN111670276A CN 111670276 A CN111670276 A CN 111670276A CN 201880088931 A CN201880088931 A CN 201880088931A CN 111670276 A CN111670276 A CN 111670276A
Authority
CN
China
Prior art keywords
cord
twist
ply
nylon
high performance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201880088931.8A
Other languages
Chinese (zh)
Inventor
S路璐逛腹
S·费丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kordsa Teknik Tekstil AS
Original Assignee
Kordsa Teknik Tekstil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kordsa Teknik Tekstil AS filed Critical Kordsa Teknik Tekstil AS
Publication of CN111670276A publication Critical patent/CN111670276A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/48Tyre cords
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C9/00Reinforcements or ply arrangement of pneumatic tyres
    • B60C9/0042Reinforcements made of synthetic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C9/00Reinforcements or ply arrangement of pneumatic tyres
    • B60C9/005Reinforcements made of different materials, e.g. hybrid or composite cords
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/26Yarns or threads characterised by constructional features, e.g. blending, filament/fibre with characteristics dependent on the amount or direction of twist
    • D02G3/28Doubled, plied, or cabled threads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C9/00Reinforcements or ply arrangement of pneumatic tyres
    • B60C2009/0071Reinforcements or ply arrangement of pneumatic tyres characterised by special physical properties of the reinforcements
    • B60C2009/0092Twist structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C9/00Reinforcements or ply arrangement of pneumatic tyres
    • B60C9/02Carcasses
    • B60C9/04Carcasses the reinforcing cords of each carcass ply arranged in a substantially parallel relationship
    • B60C2009/0416Physical properties or dimensions of the carcass cords
    • B60C2009/0425Diameters of the cords; Linear density thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C9/00Reinforcements or ply arrangement of pneumatic tyres
    • B60C9/02Carcasses
    • B60C9/04Carcasses the reinforcing cords of each carcass ply arranged in a substantially parallel relationship
    • B60C2009/0416Physical properties or dimensions of the carcass cords
    • B60C2009/0466Twist structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C2200/00Tyres specially adapted for particular applications
    • B60C2200/02Tyres specially adapted for particular applications for aircrafts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C2200/00Tyres specially adapted for particular applications
    • B60C2200/14Tyres specially adapted for particular applications for off-road use
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Tires In General (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

The present invention relates to a two or three ply nylon textile (multifilament) cord having residual twist in the ply yarn in the cord for use as reinforcement in bias and radial aircraft and off-road tires.

Description

High-performance nylon tire cord
Technical Field
The present invention relates to two or three ply (ply) polyester textile (multifilament) cords having residual twist in ply yarns (ply yarns) in cords used as reinforcement in bias and radial aircraft and off-road tires.
Background
Conventional textile tire reinforcement cords consist of yarns (strands) pre-twisted in one direction (Z or S), which are again twisted together in the opposite direction (cable or cord twist in the S or Z direction). Typically, those cords have a balanced twist construction, with yarn or strand twist equal to the cable or cord twist.
In such cord constructions, the residual or synthetic yarn twist in the cord becomes zero due to untwisting during twisting of the cord or cable in the opposite direction. The zero twist or untwisted plied yarns in the cord have loose parallel filament bundles with an open structure.
The main advantages of this cord construction are its simple production, and its high breaking strength (due to the parallel filaments in the cord plies). The breaking strength advantage is only valid for greige or unbleached (undipped) cords. After the dipping process, such cords undergo a significant reduction in breaking strength due to the dipping penetration of the adhesive between the interstices (void passages) of the filament bundles.
According to US 4,877,073, two strands of nylon 6.6 cord, in which the first and second strands (yarns) have a twist different from each other, have been proposed as low angle overlays (cap ply) which improve uniformity due to their high initial ductility (low modulus). Such cords achieve a high process expansion during moulding and curing without forming excessively compact cords, but are not very effective in preventing growth (growth) of the tyre under high speed conditions, due to their low modulus. In addition, such cords have an asymmetric structure, resulting in uneven stress distribution (load sharing) between the cord strands, and also have a tendency to buckle under axial compression, resulting in early cord failure.
According to US 6,959,534, to reduce twisting costs, the yarns (strands) are twisted at a lower level than the cord twist (resulting in internal cord torque), and it has been proposed to alternate S and Z twisted cords in tire cord fabrics to address curling or end lift issues in calendered fabrics. Based on this patent, the yarn twist is always less than the cord twist, and the residual yarn (strand) twist is in the same direction as the cord twist, resulting in high torsional instability.
In our invention, the yarn twist is always higher than the cord twist.
Disclosure of Invention
Conventional textile cords with balanced strand and cord twists (with hundreds of individual parallel filaments) for use as tire reinforcements have an open strand structure in the form of a greige prior to the dipping process.
As previously mentioned, during dipping in an adhesive (RFL) solution, such cords are subject to high levels of dip (adhesive) penetration in the interstices between the filaments in each strand of the cord, even under high cord tensions applied to the cord.
Two major drawbacks of such highly dip-penetrated cords are their high bending stiffness and reduced breaking strength after the dipping and hot-drawing processes. Under cyclic tension and compression, cords with higher bending stiffness are subject to filament damage, which results in reduced retained (retained) strength. On the other hand, lower initial cord strength requires higher cord density (epdm) or thicker cords in the carcass layer in order to provide sufficient burst strength in the tire. A higher cord density (epdm) means a lower cord-to-cord distance in the tire (narrow rivet point (rivet) area), which has a high crack initiation potential between the cords due to high shear stress under dynamic conditions. On the other hand, thicker cords require higher rubber gauge, resulting in increased rolling resistance in the tire.
The High Performance (HP) textile cord structure according to the invention includes a sufficient level of residual ply yarn twist in the opposite direction of the cord twist. In other words, in the preparation step, the strand (yarn) twist is always higher than the cord twist but in the opposite direction. The primary carcass reinforcements in aircraft and off-road tires are nylon cords (e.g., nylon 6 and nylon 6.6).
According to the invention, the filament bundles in such nylon cord strands are not open (zero twist), but are tight at residual twist and have a closed bundle structure.
Detailed description of the invention
During the dipping process of such a greige cord with tight and closed filament bundles as the strands in the cord, the adhesive dip (RFL) cannot penetrate into the depth of the cord strand but accumulates on the cord surface, which results in a low bending stiffness after drying and heat-setting steps, which is important for improved fatigue resistance and breaking strength retention.
The residual twist levels in the strands of the textile cord according to the invention are equal to each other, but in the opposite direction of the cord twist (fig. 1 and 2).
The maximum residual twist difference between the cord plies is less than 15%.
The strands of the high-performance textile cord according to the invention have a cross section of circular shape (9 and 10 in fig. 3, 19, 20 and 21 in fig. 5) or oval shape (12 and 13 in fig. 4, 23, 24 and 25 in fig. 6) instead of crescent-shaped (6 and 7 in fig. 3 and 4) or triangular shape of the 2 and 3 strands of conventional cord.
As can be seen from fig. 3, 4, 5 and 6, the circumference of the high performance cord is much higher than that of the conventional cord. In other words, the high performance cord has a much higher contact surface (adhesion interface) with the rubber matrix in the tire than a conventional cord having the same total cord dtex and strand count. This increase in contact surface achieves more efficient stress transfer between the cord strands and the rubber matrix under dynamic conditions, resulting in improved tire durability.
The strands of high performance cord with residual twist become more closed and tight during the heat-setting process due to their heat shrinkage in the transverse direction, which improves strand stability.
Drawings
Illustrating the cord construction and its strand composition according to the present invention. In the drawings, wherein:
FIG. 1 is a comparison of prior art and S-twisted cords according to the invention, wherein
1-prior art S-twisted cord (balanced twist, Z twist of plied yarn equal to S twist of cord);
2-S-twisted cord with residual Z-twist according to the invention (unbalanced twist, Z-twist of plied yarn is greater than S-twist of cord).
FIG. 2 is a comparison of prior art and Z-twisted cords according to the invention, wherein
3-prior art Z-twisted cord (balanced twist, S twist of plied yarn equal to Z twist of cord);
4-Z-twisted cord with residual S twist according to the invention (unbalanced twist, S twist of plied yarn is greater than Z twist of cord).
Fig. 3 is a cross-sectional view of a 2-ply cord, wherein,
5-2 strands of prior art cord with balanced twist having a circular shape;
6 and 7 are crescent-shaped cord strands;
8-a cross-sectional view of a 2-ply cord according to the invention;
9 and 10-strands with a circular cross section with residual twist in the cord according to the invention.
Fig. 4 is a cross-sectional view of a 2-ply cord, wherein,
11-cross-section view of a 2-ply cord according to the invention (treated under high tension);
12 and 13-strands with an elliptical cross-section with residual twist in the cord according to the invention.
FIG. 5 is a cross-sectional view of a 3 ply cord wherein:
14-3 ply prior art cord with balanced twist with round shape;
15. 16 and 17-triangular shaped strands of prior art cord;
18-cross-section of a 3-ply cord according to the invention;
19. 20 and 21-strands with a circular cross section with residual twist in the cord according to the invention.
FIG. 6 is a cross-sectional view of a 3 ply cord wherein;
22 is a cross-sectional view of a 3-ply cord according to the invention (treated under high tension),
23. 24 and 25 are strands with an elliptical cross-section with residual twist in the cord according to the invention.
Detailed Description
Definition of
Cord (Cord): a reinforcing element formed by twisting together two or more plied yarns.
Cord strand (Cord ply): the basic yarn composition of the cord.
Dtex (Dtex): grammage of a yarn of 10000 meters in length.
Linear density (Linear density): the weight per unit length is given in units of g/dtex or g/d (denier).
6.6 parts of nylon: polyhexamethylene adipamide.
Nylon 6: polycaprolactam.
Nylon 4.6: polytetramethylene adipamide.
Residual twist (Residual twist): the resultant twist of the yarns of the ply yarn of the cord (strand twist-cord twist).
Bus density (Total linear density): the sum of the nominal linear densities of the 5 ply yarns of the cord.
2 ply cord (Two-ply cord): a cord prepared by twisting two plied yarns together.
3 ply cord (Three-ply cord): a cord prepared by twisting together three plied yarns.
Twist (Twist): number of turns per meter (t/m or tpm)
The residual twist can be calculated according to the following formula:
residual twist (tpm) = (strand twist-cord twist) (1)
The overall linear density of the high performance cord according to the invention is more than 2500 dtex and less than 9000 dtex in the opposite direction of the cord twisting direction.
The linear density of the cord plies according to the invention is equal.
The maximum linear density difference between the strands of the cord according to the invention is less than 10%.
The plied yarns in the high performance cord according to the invention consist of nylon 6.6, nylon 6, nylon 4.6 or mixtures thereof.
The high performance cord according to the invention is used as carcass reinforcement in radial and bias aircraft and off-road tires.

Claims (7)

1. A two-or three-ply high performance nylon 6.6 tire cord characterized in that,
-the residual ply yarn twist in the cord is higher than 30 tpm and lower than 120 tpm,
-and the cord twist opposite to said residual twist direction is higher than 200 tpm and lower than 400 tpm.
2. The two or three ply high performance nylon 6.6 tire cord according to claim 1 wherein the total nominal linear density of the cord is above 2500 dtex and below 9000 dtex.
3. The two or three high performance nylon 6.6 tire cord of claim 1 wherein the maximum linear density difference between the plied yarns is less than 10%.
4. The two or three ply high performance nylon 6.6 tire cord of claim 1 wherein the ply yarn in the cord is nylon 6.
5. The two or three ply high performance nylon 6.6 tire cord of claim 1 wherein the ply yarn in the cord is nylon 4.6.
6. The two or three ply high performance nylon 6.6 tire cord according to claim 1, wherein the cord is used as carcass reinforcement in bias and radial aircraft tires.
7. The two or three ply high performance nylon 6.6 tire cord of claim 1 wherein the cord is used as carcass reinforcement in bias and radial off-road tires.
CN201880088931.8A 2017-12-07 2018-11-28 High-performance nylon tire cord Pending CN111670276A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
TR2017/19810A TR201719810A2 (en) 2017-12-07 2017-12-07 HIGH PERFORMANCE NYLON TIRE CORD
TR2017/19810 2017-12-07
PCT/TR2018/050740 WO2019203743A2 (en) 2017-12-07 2018-11-28 High performance nylon tire cords

Publications (1)

Publication Number Publication Date
CN111670276A true CN111670276A (en) 2020-09-15

Family

ID=67952701

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880088931.8A Pending CN111670276A (en) 2017-12-07 2018-11-28 High-performance nylon tire cord

Country Status (5)

Country Link
EP (1) EP3720999A4 (en)
KR (1) KR20200088893A (en)
CN (1) CN111670276A (en)
TR (1) TR201719810A2 (en)
WO (1) WO2019203743A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113550037A (en) * 2021-06-29 2021-10-26 三角轮胎股份有限公司 Nylon cord and tire thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115976701B (en) * 2023-01-11 2025-06-24 厦门正新橡胶工业有限公司 A nylon cord and tire made thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB526163A (en) * 1938-10-25 1940-09-12 Wingfoot Corp Improvements in and relating to cords for reinforcing tyres, belting, hose and other articles
JPH07205609A (en) * 1993-11-30 1995-08-08 Bridgestone Corp Pneumatic tire
JP2004210194A (en) * 2003-01-07 2004-07-29 Bridgestone Corp Radial tire
US20050194081A1 (en) * 2002-01-24 2005-09-08 Takeshi Yano Pneumatic radial tire, and method of producing the same
WO2016124422A1 (en) * 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Radial tyre having an improved belt structure

Family Cites Families (5)

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US3921691A (en) * 1968-10-11 1975-11-25 Ici Ltd Macrofilamentary yarns and rubber structures reinforced therewith
JP2003226112A (en) * 2002-02-06 2003-08-12 Yokohama Rubber Co Ltd:The Pneumatic radial tire for heavy load
DE102010017786A1 (en) * 2010-07-07 2012-01-12 Continental Reifen Deutschland Gmbh Elastomer product containing a linear textile structure for reinforcement
US20120211139A1 (en) * 2011-02-17 2012-08-23 Shulong Li Adhesion Composition and Textile Materials and Articles Treated Therewith
KR101260390B1 (en) * 2011-07-25 2013-05-21 한국타이어 주식회사 Hybride cord comprised of Aramid cord and Nylon 66, and Pneumatic Tire Using it as a Reinforcing Cord

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB526163A (en) * 1938-10-25 1940-09-12 Wingfoot Corp Improvements in and relating to cords for reinforcing tyres, belting, hose and other articles
JPH07205609A (en) * 1993-11-30 1995-08-08 Bridgestone Corp Pneumatic tire
US20050194081A1 (en) * 2002-01-24 2005-09-08 Takeshi Yano Pneumatic radial tire, and method of producing the same
JP2004210194A (en) * 2003-01-07 2004-07-29 Bridgestone Corp Radial tire
WO2016124422A1 (en) * 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Radial tyre having an improved belt structure

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113550037A (en) * 2021-06-29 2021-10-26 三角轮胎股份有限公司 Nylon cord and tire thereof

Also Published As

Publication number Publication date
KR20200088893A (en) 2020-07-23
EP3720999A4 (en) 2021-09-01
TR201719810A2 (en) 2019-06-21
WO2019203743A3 (en) 2020-01-16
WO2019203743A2 (en) 2019-10-24
EP3720999A2 (en) 2020-10-14

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Application publication date: 20200915

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