CN111575127A - Liquid detergent composition with washing and softening functions - Google Patents
Liquid detergent composition with washing and softening functions Download PDFInfo
- Publication number
- CN111575127A CN111575127A CN202010288186.0A CN202010288186A CN111575127A CN 111575127 A CN111575127 A CN 111575127A CN 202010288186 A CN202010288186 A CN 202010288186A CN 111575127 A CN111575127 A CN 111575127A
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- Prior art keywords
- washing
- detergent composition
- liquid detergent
- alkyl
- carbon
- Prior art date
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- 239000003599 detergent Substances 0.000 title claims abstract description 58
- 239000000203 mixture Substances 0.000 title claims abstract description 53
- 238000005406 washing Methods 0.000 title claims abstract description 50
- 239000007788 liquid Substances 0.000 title claims abstract description 37
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical class C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000000194 fatty acid Substances 0.000 claims abstract description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 20
- 229930195729 fatty acid Natural products 0.000 claims abstract description 20
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 15
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- -1 polyoxyethylene sulfate Polymers 0.000 claims description 38
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 31
- 125000000217 alkyl group Chemical group 0.000 claims description 26
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 24
- 150000002191 fatty alcohols Chemical class 0.000 claims description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 125000004122 cyclic group Chemical group 0.000 claims description 16
- 239000002304 perfume Substances 0.000 claims description 15
- 239000000975 dye Substances 0.000 claims description 14
- 125000001424 substituent group Chemical group 0.000 claims description 13
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 13
- 102000004190 Enzymes Human genes 0.000 claims description 12
- 108090000790 Enzymes Proteins 0.000 claims description 12
- 125000001931 aliphatic group Chemical group 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 229940088598 enzyme Drugs 0.000 claims description 12
- 239000003945 anionic surfactant Substances 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 229920002125 Sokalan® Polymers 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229960003168 bronopol Drugs 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 229920003064 carboxyethyl cellulose Polymers 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 6
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 230000003287 optical effect Effects 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000003755 preservative agent Substances 0.000 claims description 6
- 239000006254 rheological additive Substances 0.000 claims description 6
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 239000000375 suspending agent Substances 0.000 claims description 6
- 239000002280 amphoteric surfactant Substances 0.000 claims description 5
- 239000007844 bleaching agent Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 229920003169 water-soluble polymer Polymers 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 4
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 claims description 3
- ZMLPKJYZRQZLDA-UHFFFAOYSA-N 1-(2-phenylethenyl)-4-[4-(2-phenylethenyl)phenyl]benzene Chemical group C=1C=CC=CC=1C=CC(C=C1)=CC=C1C(C=C1)=CC=C1C=CC1=CC=CC=C1 ZMLPKJYZRQZLDA-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004382 Amylase Substances 0.000 claims description 3
- 102000013142 Amylases Human genes 0.000 claims description 3
- 108010065511 Amylases Proteins 0.000 claims description 3
- 102100032487 Beta-mannosidase Human genes 0.000 claims description 3
- CLYLHSGRVGFHCQ-UHFFFAOYSA-N C(C)(=O)O.C(C)(=O)O.C(CCCCCCCCCCC)(=O)N Chemical compound C(C)(=O)O.C(C)(=O)O.C(CCCCCCCCCCC)(=O)N CLYLHSGRVGFHCQ-UHFFFAOYSA-N 0.000 claims description 3
- GDDNLJKTNIEGOQ-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)N.C(C)(=O)O Chemical compound C(CCCCCCCCCCC)(=O)N.C(C)(=O)O GDDNLJKTNIEGOQ-UHFFFAOYSA-N 0.000 claims description 3
- TXNJAVCZNMSELK-UHFFFAOYSA-N CCCCCCCCCCCCOC(=O)CNC Chemical compound CCCCCCCCCCCCOC(=O)CNC TXNJAVCZNMSELK-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 108010059892 Cellulase Proteins 0.000 claims description 3
- 239000004471 Glycine Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 102000004882 Lipase Human genes 0.000 claims description 3
- 239000004367 Lipase Substances 0.000 claims description 3
- 108090001060 Lipase Proteins 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229930182559 Natural dye Natural products 0.000 claims description 3
- 108010029182 Pectin lyase Proteins 0.000 claims description 3
- 108091005804 Peptidases Proteins 0.000 claims description 3
- 229920002873 Polyethylenimine Polymers 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 235000019418 amylase Nutrition 0.000 claims description 3
- 229940077388 benzenesulfonate Drugs 0.000 claims description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 claims description 3
- 108010055059 beta-Mannosidase Proteins 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 125000005619 boric acid group Chemical group 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229960001631 carbomer Drugs 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- 150000001734 carboxylic acid salts Chemical class 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 239000000679 carrageenan Substances 0.000 claims description 3
- 235000010418 carrageenan Nutrition 0.000 claims description 3
- 229920001525 carrageenan Polymers 0.000 claims description 3
- 229940113118 carrageenan Drugs 0.000 claims description 3
- 229940106157 cellulase Drugs 0.000 claims description 3
- 229940065856 cocoyl glycinate Drugs 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical class CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 claims description 3
- CSVGEMRSDNSWRF-UHFFFAOYSA-L disodium;dihydrogen phosphate Chemical compound [Na+].[Na+].OP(O)([O-])=O.OP(O)([O-])=O CSVGEMRSDNSWRF-UHFFFAOYSA-L 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims description 3
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 3
- 229940071085 lauroyl glutamate Drugs 0.000 claims description 3
- 229940071204 lauryl sarcosinate Drugs 0.000 claims description 3
- 235000019421 lipase Nutrition 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 150000004702 methyl esters Chemical class 0.000 claims description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 3
- 239000000978 natural dye Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 230000002335 preservative effect Effects 0.000 claims description 3
- 235000019419 proteases Nutrition 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 3
- 239000004299 sodium benzoate Substances 0.000 claims description 3
- 235000010234 sodium benzoate Nutrition 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- 239000000979 synthetic dye Substances 0.000 claims description 3
- KMZJRCPGGAQHGC-UHFFFAOYSA-N trisodium boric acid borate Chemical compound [Na+].[Na+].[Na+].OB(O)O.[O-]B([O-])[O-] KMZJRCPGGAQHGC-UHFFFAOYSA-N 0.000 claims description 3
- XPFJYKARVSSRHE-UHFFFAOYSA-K trisodium;2-hydroxypropane-1,2,3-tricarboxylate;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Na+].[Na+].[Na+].OC(=O)CC(O)(C(O)=O)CC(O)=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O XPFJYKARVSSRHE-UHFFFAOYSA-K 0.000 claims description 3
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 235000010493 xanthan gum Nutrition 0.000 claims description 3
- 229940082509 xanthan gum Drugs 0.000 claims description 3
- 108010083879 xyloglucan endo(1-4)-beta-D-glucanase Proteins 0.000 claims description 3
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 2
- 229940035437 1,3-propanediol Drugs 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003002 pH adjusting agent Substances 0.000 claims description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 229960004063 propylene glycol Drugs 0.000 claims description 2
- 235000013772 propylene glycol Nutrition 0.000 claims description 2
- XEFAJZOBODPHBG-UHFFFAOYSA-N 1-phenoxyethanol Chemical group CC(O)OC1=CC=CC=C1 XEFAJZOBODPHBG-UHFFFAOYSA-N 0.000 claims 1
- 125000003158 alcohol group Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 16
- 239000004744 fabric Substances 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 9
- 230000000052 comparative effect Effects 0.000 description 12
- 238000013112 stability test Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000003093 cationic surfactant Substances 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical group OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 206010021703 Indifference Diseases 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a liquid detergent composition with washing and softening functions, which comprises the following components in percentage by mass: 0.1 to 20% of an imidazolinium salt; 0.5-40% of potassium salt of fatty acid; 1-50% of an alcohol solvent. The balance being other components. The other component may be water, and may also include other functional components. The composition has both washing and softening functions, and can still provide softening effect for fabrics after the whole washing and rinsing process, so that the washing and softening can be finished only by one step, and the use is convenient.
Description
Technical Field
The invention belongs to the technical field of detergents, and particularly relates to a liquid washing composition with washing and softening functions.
Background
The main functional component of the washing preparation is surfactant, wherein anionic surfactant and nonionic surfactant are taken as main components, and the two surfactants have good dirt-removing capability on common stains (such as oil stains, dust, blood stains, milk stains and the like) in daily life; in contrast, cationic surfactants generally do not serve as the primary surfactant in a detergent formulation because such surfactants have relatively poor detergency on common stains.
However, cationic surfactants can improve the hand of the fabric and provide a softening experience to the consumer and are therefore often the primary component of softeners. When the common anionic surfactant and the common cationic surfactant are compounded into a liquid formula, precipitates can be generated, and the original effects of the anionic surfactant and the common cationic surfactant are influenced.
Therefore, in the prior art, the washing preparation and the softener are generally used separately, and particularly, the softener can be added after the washing preparation is used for washing and is rinsed sufficiently, so that the washing preparation and the softener can respectively play the roles of decontamination and softening. Furthermore, the addition of the softener cannot be followed by a further rinse, since the rinse washes away the cationic surfactant remaining in the softener on the fabric surface, which makes the effect of the softener non-obvious.
Therefore, in the process of washing clothes, two procedures of washing and softening are needed, and a detergent and a softener are used in the two procedures respectively, so that great inconvenience is brought to a user.
Disclosure of Invention
The invention aims to provide a liquid washing composition with washing and softening functions, which has the washing and softening functions at the same time and can still provide softening effect for fabrics after the whole washing and rinsing process.
The purpose of the invention is realized by the following technical scheme:
a liquid detergent composition with washing and softening functions comprises the following components in percentage by mass: 0.1 to 20% of an imidazolinium salt; 0.5-40% of potassium salt of fatty acid; 1-50% of an alcohol solvent. The balance being other components. The other component may be water, and may also include other functional components.
The imidazolinium salt has the following molecular structure (I)
Or molecular structure (II)
In the liquid detergent composition, the imidazolinium salt functions as a cationic surfactant and functions as a softening agent; the potassium salt of fatty acid serves as an anionic surfactant and plays a washing role. The formula combines the imidazolinium salt and the fatty acid potassium salt in one formula, can bring washing and softening effects simultaneously, and the imidazolinium salt and the fatty acid potassium salt form a stable complex after being mixed, so that precipitates which enable the imidazolinium salt and the fatty acid potassium salt to lose the original activity are not generated, and the original effect cannot be achieved.
In the molecular structure (I) or the molecular structure (II) of the imidazolinium salt:
R1each independently selected from hydrogen or alkyl, preferably C1～C4Straight chain alkyl, i.e. methyl, ethyl, propyl or butyl. "independently of one another" is to be understood as meaning a plurality of R's which are contained in the same molecule1And may be different from each other.
R2Selected from straight chain or branched chain alkyl with 1-24 carbon atoms in total, including saturated alkyl or unsaturated hydrocarbonThe unsaturated hydrocarbon group may include a carbon-carbon double bond, a carbon-carbon triple bond, and a cyclic structure including various structures of an aliphatic ring and/or an aromatic ring. More preferably, R2Selected from straight chain or branched chain alkyl with 8-24 carbon atoms in total.
R3Selected from hydrogen or linear and/or branched, saturated and/or unsaturated substituents with a total number of carbon atoms of 1 to 12 and containing and/or not oxygen and/or nitrogen atoms, more preferably R3The total number of carbon atoms is 1 to 4. Further preferably, methyl or ethyl.
R4Selected from linear or branched substituents containing and/or not containing oxygen and/or nitrogen atoms, including saturated substituents or unsaturated substituents, which may include carbon-carbon double bonds, carbon-carbon triple bonds, and cyclic structures including aliphatic and/or aromatic rings of various structures. Preferably, R4Is an ethylene group.
R5Selected from the chain length C2～C24The straight-chain or branched-chain hydrocarbon group of (1) includes a saturated hydrocarbon group or an unsaturated hydrocarbon group, and the unsaturated hydrocarbon group may include a carbon-carbon double bond, a carbon-carbon triple bond, and a cyclic structure including an aliphatic ring and/or an aromatic ring of various structures. Preferably, R5Is chain length C12～C24And a linear hydrocarbon group having at most one double bond.
R6Selected from the chain length C2～C24The straight-chain or branched-chain hydrocarbon group of (1) includes a saturated hydrocarbon group or an unsaturated hydrocarbon group, and the unsaturated hydrocarbon group may include a carbon-carbon double bond, a carbon-carbon triple bond, and a cyclic structure including an aliphatic ring and/or an aromatic ring of various structures. Preferably, R6Is chain length C12～C24And a linear hydrocarbon group having at most one double bond.
Preferably, X-Is methyl sulfate ion.
When the detergent composition contains 0.1-20% of imidazolinium salt, a good softening effect can be obtained. Preferably, a particularly good softening effect is obtained when the detergent composition contains 2 to 20% of imidazolinium salts.
The other functional components include:
according to the actual application requirement, the liquid detergent composition with the washing and softening functions can also contain 5-70% of other surfactants. The other surfactants are understood to be other surfactants than imidazolinium salts and fatty acid potassium salts, including one or more of various anionic, nonionic and amphoteric surfactants.
The anionic surfactant may preferably be selected from C8～C18Alkyl benzene sulfonate, C8～C18Neutralized product of alkylbenzene sulfonic acid and monoethanolamine/diethanolamine/triethanolamine, fatty alcohol polyoxyethylene sulfate, C8～C18Alkyl sulfate, fatty alcohol polyoxyethylene carboxylate, α -olefin sulfonate, C8～C18Fatty acid methyl ester sulfonate, fatty acid methyl ester polyoxyethylene sulfonate and C8～C18One or more of a fatty acid salt.
The nonionic surfactant may preferably be one or more selected from fatty alcohol polyoxyalkyl ethers, fatty acid methyl ester polyoxyalkyl ethers or alkyl polysaccharides.
The fatty alcohol polyoxy alkyl ether is a homo-polymer or copolymer of fatty alcohol and an alkyl epoxy compound, and the fatty alcohol is a straight-chain or branched-chain fatty alcohol with the total carbon atoms of 8-24; the alkyl epoxy compound is a compound which contains an epoxy group and an alkyl chain and has the total number of carbon atoms of 2-12. Preferably, the alkyl epoxide is ethylene oxide and/or propylene oxide.
The amphoteric surfactant may preferably be selected from one or more of cocamide acetate, cocamide diacetate, lauramide acetate, lauramide diacetate, lauryl sarcosinate, cocoyl glycinate and lauroyl glutamate.
The alcohol solvent comprises one or more of monohydric alcohol, dihydric alcohol and polyhydric alcohol. Preferably, the alcohol solvent is one or more of ethanol, propanol, 1, 2-propanediol, 1, 3-propanediol, isopropanol and glycerol.
The liquid detergent composition having washing and softening functions may further comprise other additive ingredients in conventional detergents, including one or more of enzymes, enzyme stabilizers, bleaching agents, soil suspending agents, optical brighteners, dyes, perfumes, rheology modifiers, pH adjusters, dye traps and preservatives. The addition amount of the detergent is the addition amount of the conventional detergent.
The enzyme may be selected from one or more of protease, lipase, amylase, cellulase, mannanase, pectin lyase and xyloglucanase.
The enzyme stabilizer may be one or more selected from the group consisting of calcium and/or magnesium containing compounds, inorganic salts of boric acid, organic substances containing boric acid groups, short chain carboxylic acid salts and glycine.
The bleaching agent may be selected from one or more of percarbonate, perborate, percarbamide and hypochlorite.
The soil suspending agent can be selected from one or more of polyethyleneimine and derivatives thereof, polyacrylic acid, polyacrylate and derivatives thereof, carboxymethyl cellulose, sodium carboxymethyl cellulose, carboxyethyl cellulose and sodium carboxyethyl cellulose.
The optical brightening agent can be selected from one or more of derivatives of distyrylbiphenyl.
The dye may be selected from any pigment, pigment or dye suitable for use in detergents, including natural dyes and synthetic dyes.
The perfume may be selected from any perfume suitable for use in detergents or odour modifiers including naturally extracted perfumes and artificially synthesised perfumes.
The rheology modifier can be selected from alcohol or water-soluble polymers, wherein the alcohol is preferably ethanol, and the water-soluble polymers comprise xanthan gum, carbomer and carrageenan.
The pH regulator is usually a pair combination mode of polybasic weak acid and metal salt thereof, and comprises citric acid-sodium citrate, phosphoric acid-disodium hydrogen phosphate or boric acid-sodium borate.
The dye trapping agent may be selected from polyvinylpyrrolidone and derivatives thereof.
The preservative is selected from phenoxyethanol, Bronopol (Bronopol), sodium benzoate, isothiazolinone and its derivatives, C8～C18Alkyl dimethyl benzyl ammonium salt and C8～C18One or more of alkylpyridine halide salts.
For convenience of use, the liquid detergent composition with washing and softening functions can be filled in a water-soluble small bag to be made into a washing preparation for quantitative dosing.
Compared with the prior art, the invention has the following beneficial effects:
1. according to the liquid detergent composition, the imidazolinium salt and the fatty acid potassium salt with specific structures are selected for compounding, so that the problem that an anionic surfactant and a cationic surfactant which are commonly used in the prior art cannot stably coexist is solved;
2. the liquid detergent composition disclosed by the invention does not reduce the detergency of an anionic surfactant after being compounded;
3. the liquid detergent composition provided by the invention can still retain a sufficient amount of cationic surfactant (imidazolinium salt) on the surface of the fabric after rinsing, provides a good softening effect, enables rinsing and softening to be completed in one step, simplifies the operation and brings convenience to users.
Detailed Description
The present invention will be further described with reference to the following specific examples.
The test methods used in the following examples are as follows:
low temperature stability test
The sample was placed in a 0 ℃ incubator for 4 weeks, taken out, and after returning to normal temperature, the appearance was observed.
High temperature stability test
The sample was placed in a thermostat at 45 ℃ for 4 weeks, taken out, and after returning to normal temperature, the appearance was observed.
Detergency test
When tested according to the relevant regulations of GB13174, to ensure that the examples have the same surfactant loading as the standard laundry detergent, which is specified to have a surfactant content of about 15% and an loading of 2 g/sample, the examples were tested for detergency in the amount of (2 × 15% ÷ surfactant content in examples%) g/sample.
Method for evaluating the benefit of liquid detergents on fabric softness
A commercially available cotton towel of the same brand and batch and the same quality was selected as the test object in the experiment. The commercially available pure cotton towel needs to be pre-treated: a commercially available towel is mixed with 1kg of polyester fabric filler, washed 10 times with a common fabric detergent without softening effect in a drum washing machine at the water temperature of 30 ℃, and dried for standby.
In each test, a blank control group is arranged, namely blank washing (washing by using a detergent without a softening component), the blank control group and the test group are washed at the same time and dried for 24 hours in the same environment, then the flexibility of the two groups of experimental towels is evaluated by professional technicians, and the two groups of experimental towels are graded according to 0-3 grades, wherein the grading meaning is as follows:
| grade | Means of |
| 0 | Indifference or worse |
| 1 | Feel slightly supple |
| 2 | Felt obvious compliance |
| 3 | Feel very soft and pliable |
The formulations of examples 1 to 4 and comparative examples 1 to 2 were as follows, and the data in the table are in mass percent:
saponification of fatty acid and potassium hydroxide to form potassium salt of fatty acid
Low temperature stability test and high temperature stability test of examples 1 to 4 and comparative examples 1 to 2:
| example 1 | Example 2 | Example 3 | Example 4 | Comparative example 1 | Comparative example 2 | |
| Low temperature stability test | Clear and transparent | Clear and transparent | Clear and transparent | Clear and transparent | Precipitation out of the precipitate | Precipitation out of the precipitate |
| High temperature stability test | Clear and transparent | Clear and transparent | Clear and transparent | Clear and transparent | Precipitation out of the precipitate | Precipitation out of the precipitate |
As can be seen from the above table, comparative example 1 does not contain an alcohol solvent, comparative example 2 does not contain a fatty acid potassium salt, both of which show a phenomenon of precipitation in the low temperature stability test and the high temperature stability test, while examples 1 to 4 show stability in the low temperature stability test and the high temperature stability test, and have no phenomenon of precipitation, which indicates that the simultaneous existence of the alcohol solvent and the fatty acid potassium salt plays an important role in forming a stable and uniform system in the formulation of the composition of the present invention.
Detergency test
Using example 2 as a test example containing 15% of an imidazolinium salt, a comparative sample was prepared which did not contain an imidazolinium salt and had the same other components as in example 2 (the imidazolinium salt portion was replenished with water), and the results of the detergency test were as follows:
| serial number | Whiteness retention value | JB01 | JB02 | JB03 |
| 1 | Standard laundry detergent | 1 | 1 | 1 |
| 2 | Example 2 | 1.2 | 2.33 | 1.48 |
| 3 | Comparative sample | 1.17 | 2.4 | 1.50 |
As can be seen from the above table, there is little difference in detergency between example 2 containing an imidazolinium salt and the comparative sample containing no imidazolinium salt, and it can be seen that the imidazolinium salt in the formulation does not significantly affect the detergency of the cleaning composition.
The formulations of examples 5 to 12 and comparative example 3 are as follows, and the data in the table are in mass percent:
saponification of fatty acid and potassium hydroxide to form potassium salt of fatty acid
Test of Fabric flexibility for examples 5 to 8 and comparative example 3
Commercially available softeners in the following table are put into a special softener tank according to a common use method, and are sent into a drum by a washing machine at the final stage of washing, and are characterized in that the softener is not subjected to a rinsing procedure and is not mixed with a detergent. The compliance test results are shown below:
| sample (I) | Example 5 | Example 6 | Example 7 | Example 8 | Comparative example 3 | Commercially available softener |
| Scoring | 2 | 2 | 1 | 1 | 0 | 3 |
As can be seen from the above table, the content of imidazolinium salt is directly proportional to the softening effect, and the higher the content of imidazolinium salt is, the better the softening effect is. In addition, the method of use of the present invention requires a rinse cycle, i.e., the compositions of examples 5-8 are added at the beginning of the wash, and the rinse cycle has a non-negligible effect on the residual amount of softening composition on the fabric. The compositions of examples 5-8 can still enable the tested pure cotton towel to show good flexibility after rinsing, and the invention can still keep enough imidazolinium salts on the surface of the fabric after rinsing, thereby providing good flexibility effect, completing rinsing and flexibility in one step, simplifying operation and bringing convenience to users.
Examples 1 to 12 are merely illustrative of the embodiment of the present invention, and the imidazolinium salt is not limited to the 1-ethyl-1-oleamidoethyl-2-methyl-imidazolinium methosulfate and 1-methyl-1-oleamidocarbonylethyl-2-methyl-imidazolinium methosulfate, and may be an imidazolinium salt having the molecular structure (I) or the molecular structure (II).
In the molecular structure (I) or the molecular structure (II) of the imidazolinium salt:
R1each independently selected from hydrogen or alkyl, preferably C1～C4Straight chain alkyl, i.e. methyl, ethyl, propyl or butyl. "independently of one another" is to be understood as meaning a plurality of R's which are contained in the same molecule1And may be different from each other.
R2The aliphatic hydrocarbon is selected from straight chain or branched chain alkyl with the total number of carbon atoms of 1-24, and comprises saturated alkyl and unsaturated alkyl, wherein the unsaturated alkyl can comprise a carbon-carbon double bond, a carbon-carbon triple bond and a cyclic structure, and the cyclic structure comprises an aliphatic ring and an aromatic ring with various structures. More preferably, R2Selected from straight chain or branched chain alkyl with 8-24 carbon atoms in total.
R3Selected from hydrogen or linear and/or branched, saturated and/or unsaturated substituents with a total number of carbon atoms of 1 to 12 and containing and/or not oxygen and/or nitrogen atoms, more preferably R3Total number of carbon atoms of (C)1～C4. Further preferably, methyl or ethyl.
R4Selected from linear or branched substituents containing and/or not containing oxygen and/or nitrogen atoms, including saturated substituents and unsaturated substituents, which may include carbon-carbon double bonds, carbon-carbon triple bonds and cyclic structures including aliphatic and aromatic rings of various structures. Preferably, R4Is an ethylene group.
R5Selected from chain length C2～C24The straight-chain or branched-chain hydrocarbon group of (1) includes a saturated hydrocarbon group and an unsaturated hydrocarbon group, and the unsaturated hydrocarbon group may include a carbon-carbon double bond, a carbon-carbon triple bond and a cyclic structure including aliphatic rings and aromatic rings of various structures. Preferably, R5Is chain length C12～C24And a linear hydrocarbon group having at most one double bond.
R6Selected from chain length C2～C24The straight-chain or branched-chain hydrocarbon group of (1) includes a saturated hydrocarbon group and an unsaturated hydrocarbon group, and the unsaturated hydrocarbon group may include a carbon-carbon double bond, a carbon-carbon triple bond and a cyclic structure including aliphatic rings and aromatic rings of various structures. Preferably, R6Is chain length C12～C24And a linear hydrocarbon group having at most one double bond.
X-Preferably methyl sulfate ion.
The object of the present invention can be achieved by any imidazolinium salt having the molecular structure (I) or the molecular structure (II).
In the other components than the imidazolinium salt and the fatty acid potassium salt, the anionic surfactant may preferably be selected from C8～C18Alkyl benzene sulfonate, C8～C18Neutralized product of alkyl benzene sulfonic acid and monoethanolamine/diethanolamine/triethanolamineFatty alcohol polyoxyethylene sulfates, C8～C18Alkyl sulfate, fatty alcohol polyoxyethylene carboxylate, α -olefin sulfonate, C8～C18Fatty acid methyl ester sulfonate, fatty acid methyl ester polyoxyethylene sulfonate and C8～C18One or more of a fatty acid salt;
the nonionic surfactant may preferably be selected from one or more of fatty alcohol polyoxyalkyl ether, fatty acid methyl ester polyoxyalkyl ether or alkyl polysaccharide;
the fatty alcohol polyoxy alkyl ether is a homo-polymer or copolymer of fatty alcohol and an alkyl epoxy compound, and the fatty alcohol is a straight-chain or branched-chain fatty alcohol with the total carbon atoms of 8-24; the alkyl epoxy compound is a compound which contains an epoxy group and an alkyl chain and has the total number of carbon atoms of 2-12.
The amphoteric surfactant may preferably be selected from one or more of cocamide acetate, cocamide diacetate, lauramide acetate, lauramide diacetate, lauryl sarcosinate, cocoyl glycinate and lauroyl glutamate.
The alcohol solvent comprises one or more of monohydric alcohol, dihydric alcohol and polyhydric alcohol. The above components are all components for further improving or improving the performance of the composition, can stably coexist with the imidazolinium salt and the fatty acid potassium salt, do not influence the achievement of the object of the invention, and can be freely selected and added by a person skilled in the art according to the actual product requirement, so that the technical effect of the invention can be achieved.
The detergent compositions comprising enzymes, enzyme stabilizers, bleaching agents, soil suspending agents, optical brighteners, dyes, perfumes, rheology modifiers, pH adjusters, dye traps and preservatives are all common functional components of conventional detergent compositions and can be optionally added by one skilled in the art without affecting the achievement of the object of the invention.
The enzyme may be selected from one or more of protease, lipase, amylase, cellulase, mannanase, pectin lyase and xyloglucanase.
The enzyme stabilizer may be one or more selected from the group consisting of calcium and/or magnesium containing compounds, inorganic salts of boric acid, organic substances containing boric acid groups, short chain carboxylic acid salts and glycine.
The bleaching agent may be selected from one or more of percarbonate, perborate, percarbamide and hypochlorite.
The soil suspending agent can be selected from one or more of polyethyleneimine and derivatives thereof, polyacrylic acid, polyacrylate and derivatives thereof, carboxymethyl cellulose, sodium carboxymethyl cellulose, carboxyethyl cellulose and sodium carboxyethyl cellulose.
The optical brightening agent can be selected from one or more of derivatives of distyrylbiphenyl.
The dye may be selected from any pigment, pigment or dye suitable for use in detergents, including natural dyes and synthetic dyes.
The perfume may be selected from any perfume suitable for use in detergents or odour modifiers including naturally extracted perfumes and artificially synthesised perfumes.
The rheology modifier can be selected from alcohol or water-soluble polymers, wherein the alcohol is preferably ethanol, and the water-soluble polymers comprise xanthan gum, carbomer and carrageenan.
The pH adjusting agent is typically a pair-wise combination of a weak polybasic acid and its metal salt, including citric acid-sodium citrate, phosphoric acid-disodium hydrogen phosphate, and boric acid-sodium borate.
The dye trapping agent may be selected from polyvinylpyrrolidone and derivatives thereof.
The preservative is selected from phenoxyethanol, Bronopol (Bronopol), sodium benzoate, isothiazolinone and its derivatives, C8～C18Alkyl dimethyl benzyl ammonium salt and C8～C18One or more of alkylpyridine halide salts.
The combination and collocation of the components do not influence the realization of the purpose of the invention.
It should be noted that the above-mentioned embodiments are only illustrative and not restrictive, and any modifications or changes within the meaning and range of equivalents to the technical solutions of the present invention by those skilled in the art should be considered to be included in the protection scope of the present invention.
Claims (22)
1. A liquid detergent composition with washing and softening functions is characterized by comprising the following components in percentage by mass: 0.1 to 20% of an imidazolinium salt; 0.5-40% of potassium salt of fatty acid; 1-50% of alcohol solvent and water.
2. A liquid detergent composition having washing and softening functions according to claim 1, wherein said imidazolinium salt has the following molecular structure (I) or molecular structure (II):
molecular Structure (I)
Molecular Structure (II)
3. A liquid detergent composition having washing and softening functions according to claim 2, wherein in said molecular structure (I) or said molecular structure (II):
R1each independently selected from hydrogen or alkyl, alkyl is C1～C4A linear alkyl group;
R2the aliphatic hydrocarbon is selected from straight chain or branched chain alkyl with 1-24 carbon atoms in total number, and the alkyl comprises saturated alkyl or unsaturated alkyl, wherein the unsaturated alkyl comprises one or more of carbon-carbon double bond, carbon-carbon triple bond and cyclic structure, and the cyclic structure comprises aliphatic rings and/or aromatic rings with various structures;
R3selected from hydrogen or linear and/or branched, saturated and/or unsaturated substituents with the total number of carbon atoms of 1-12 and containing and/or not containing oxygen and/or nitrogen atoms;
R4selected from linear or branched substituents containing and/or not containing oxygen and/or nitrogen atoms, including saturated substituents or unsaturated substituents, unsaturated substituents comprising one or more of carbon-carbon double bonds, carbon-carbon triple bonds and cyclic structures, including aliphatic and/or aromatic rings of various structures;
R5selected from the chain length C2～C24The straight-chain or branched-chain hydrocarbon group of (1) includes a saturated hydrocarbon group or an unsaturated hydrocarbon group, the unsaturated hydrocarbon group includes one or more of a carbon-carbon double bond, a carbon-carbon triple bond and a cyclic structure, and the cyclic structure includes various structures of aliphatic rings and/or aromatic rings;
R6selected from the chain length C2～C24The straight-chain or branched-chain hydrocarbon group of (1) includes a saturated hydrocarbon group or an unsaturated hydrocarbon group, the unsaturated hydrocarbon group includes one or more of a carbon-carbon double bond, a carbon-carbon triple bond and a cyclic structure, and the cyclic structure includes various structures of aliphatic rings and/or aromatic rings;
X-is methyl sulfate ion.
4. A liquid detergent composition with washing and softening functions according to claim 3, wherein R is2Selected from straight chain or branched chain alkyl with 8-24 carbon atoms in total; r3The total number of carbon atoms is 1 to 4; r4Is an ethylene group; r5Is chain length C12～C24And a straight chain hydrocarbon group containing at most one double bond; r6Is chain length C12～C24And a linear hydrocarbon group having at most one double bond.
5. The liquid detergent composition with washing and softening functions as claimed in claim 3, wherein the composition further comprises 5-70% by mass of other surfactants, including one or more of various anionic surfactants, nonionic surfactants and amphoteric surfactants.
6. A liquid detergent composition having washing and softening functions according to claim 5, wherein the anionic surfactant is selected from C8～C18Alkyl benzene sulfonate, C8～C18Neutralized product of alkylbenzene sulfonic acid and monoethanolamine/diethanolamine/triethanolamine, fatty alcohol polyoxyethylene sulfate, C8～C18Alkyl sulfate, fatty alcohol polyoxyethylene carboxylate, α -olefin sulfonate, C8～C18Fatty acid methyl ester sulfonate, fatty acid methyl ester polyoxyethylene sulfonate and C8～C18One or more of a fatty acid salt.
7. The liquid detergent composition having washing and softening functions according to claim 5, wherein the nonionic surfactant is selected from one or more of fatty alcohol polyoxyalkylether, fatty acid methyl ester polyoxyalkylether or alkylpolysaccharide;
the fatty alcohol polyoxy alkyl ether is a homo-polymer or copolymer of fatty alcohol and an alkyl epoxy compound, and the fatty alcohol is a straight-chain or branched-chain fatty alcohol with the total carbon atoms of 8-24; the alkyl epoxy compound is a compound which contains an epoxy group and an alkyl chain and has the total number of carbon atoms of 2-12.
8. A liquid detergent composition having washing and softening functions according to claim 5, wherein the amphoteric surfactant is selected from one or more of cocamide acetate, cocamide diacetate, lauramide acetate, lauramide diacetate, lauryl sarcosinate, cocoyl glycinate and lauroyl glutamate.
9. A liquid detergent composition having a washing and softening function according to claim 1, wherein the alcohol solvent comprises one or more of monohydric alcohol, dihydric alcohol and polyhydric alcohol.
10. A liquid detergent composition with washing and softening functions according to claim 9, wherein the alcohol solvent is one or more of ethanol, propanol, 1, 2-propanediol, 1, 3-propanediol, isopropanol and glycerol.
11. A liquid detergent composition with washing and softening functions according to any one of claims 1-10, wherein the composition further comprises other additive ingredients in conventional detergents, including one or more of enzymes, enzyme stabilizers, bleaches, soil suspending agents, optical brighteners, dyes, perfumes, rheology modifiers, pH adjusters, dye traps and preservatives.
12. A liquid detergent composition with washing and softening functions according to claim 11, wherein the enzyme is selected from one or more of protease, lipase, amylase, cellulase, mannanase, pectin lyase and xyloglucanase.
13. A liquid detergent composition having washing and softening functions according to claim 11, wherein the enzyme stabilizer is one or more selected from the group consisting of calcium and/or magnesium-containing compounds, inorganic salts of boric acid, organic substances containing boric acid groups, short-chain carboxylic acid salts and glycine.
14. A liquid detergent composition having both detergent and softening functions according to claim 11, wherein said bleaching agent is selected from one or more of percarbonate, perborate, percarbamide and hypochlorite.
15. A liquid detergent composition with washing and softening functions according to claim 11, wherein the soil suspending agent is selected from one or more of polyethyleneimine and derivatives thereof, polyacrylic acid, polyacrylate and derivatives thereof, carboxymethyl cellulose, sodium carboxymethyl cellulose, carboxyethyl cellulose and sodium carboxyethyl cellulose.
16. A liquid detergent composition with washing and softening functions according to claim 11, wherein the optical brightener is selected from one or more of derivatives of distyrylbiphenyl.
17. A liquid detergent composition having both detergent and softening functions according to claim 11, wherein said dye is selected from any detergent-suitable pigment, pigment or dye including natural dyes and synthetic dyes.
18. A liquid detergent composition with washing and softening functions according to claim 11, wherein said perfume is selected from any perfume suitable for detergents or odor control agents including naturally extracted perfumes and artificially synthesized perfumes.
19. A liquid detergent composition with washing and softening functions according to claim 11, wherein the rheology modifier is selected from alcohol, preferably ethanol, or water-soluble polymers including xanthan gum, carbomer and carrageenan.
20. A liquid detergent composition having washing and softening functions according to claim 11, wherein the pH adjuster comprises citric acid-sodium citrate, phosphoric acid-disodium hydrogen phosphate or boric acid-sodium borate.
21. A liquid detergent composition having washing and softening functions according to claim 11, wherein the dye-capturing agent is selected from polyvinylpyrrolidone and derivatives thereof.
22. A liquid detergent composition having both detergent and softening functions according to claim 11, wherein said preservative is selected from benzeneOxyethanol, Bronopol (Bronopol), sodium benzoate, isothiazolinone and its derivatives, C8～C18Alkyl dimethyl benzyl ammonium salt and C8～C18One or more of alkylpyridine halide salts.
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| CN102965222A (en) * | 2012-12-04 | 2013-03-13 | 新时代健康产业（集团）有限公司 | Low-foaming anti-crease soft laundry detergent and preparation method thereof |
| CN104629922A (en) * | 2013-11-08 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Fabric mild detergent |
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