CN111511572B - Method for surface application of a safety device over a hole made in a paper machine - Google Patents
Method for surface application of a safety device over a hole made in a paper machine Download PDFInfo
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- CN111511572B CN111511572B CN201880080558.1A CN201880080558A CN111511572B CN 111511572 B CN111511572 B CN 111511572B CN 201880080558 A CN201880080558 A CN 201880080558A CN 111511572 B CN111511572 B CN 111511572B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/324—Reliefs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/333—Watermarks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/346—Perforations
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/351—Translucent or partly translucent parts, e.g. windows
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
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Abstract
Description
技术领域technical field
在一个方面,本发明涉及具有通孔的片材,其中一个或多个安全装置联接到这些通孔。片材示例性地用于形成安全文件,该安全文件包括上述通孔和联接的安全装置。在另一方面,本发明通常还涉及一种制备此类片材的方法;形成安全文件的方法;以及通过通孔与一个或多个安全装置的联接来保护这些文件的装置。本文所述的通孔包括“软边”通孔。因此,本发明的另一方面还包括在片材或更具体地在安全文件中形成软边通孔的方法。In one aspect, the present invention relates to a sheet material having through holes, wherein one or more safety devices are coupled to the through holes. The sheet material is exemplarily used to form a security document comprising the above-described through-holes and attached security means. In another aspect, the invention generally also relates to a method of making such a sheet; a method of forming security documents; and a device for securing these documents through the coupling of through holes to one or more security devices. Vias as described herein include "soft edge" vias. Accordingly, another aspect of the present invention also includes a method of forming soft edged through holes in a sheet material or, more specifically, a security document.
背景技术Background technique
非排他性地包括各种形式的条、带、线或丝带的安全装置被广泛地用于保护或美观高安全和高价值文件,从而提供用于验证这些文件的真实性的视觉和/或机器可检测手段。这些安全装置可完全嵌入或部分地嵌入文件中,或安装在其表面上。Security devices including, non-exclusively, various forms of strips, tapes, threads or ribbons are widely used to protect or aesthetically high security and high value documents, thereby providing visual and/or machine accessibility for verifying the authenticity of these documents. testing method. These security devices can be fully or partially embedded in the document, or mounted on its surface.
至少部分地嵌入的安全装置可通过在造纸过程的湿阶段期间将安全装置引入到纤维幅材中而被施加到成形纤维幅材。然而,在此阶段将安全装置引入纤维幅材中虽然适用于嵌入和部分地嵌入的安全装置,但迄今为止对于表面施加的安全装置是不切实际的,因为所得的片材或文件将易于降低耐久性(例如,流通耐久性)。The at least partially embedded safety device may be applied to the forming fibrous web by introducing the safety device into the fibrous web during the wet stage of the papermaking process. However, the introduction of security devices into the fibrous web at this stage, while suitable for embedded and partially embedded security devices, has hitherto been impractical for surface-applied security devices as the resulting sheet or document would be prone to lowering Durability (eg, circulation durability).
已经发现,在将安全装置引入成形纤维幅材的湿阶段期间,当安全装置被压入到纤维幅材中时,一些纤维在安全装置周围流动时发生移位。这导致一定量的纤维从子区域(即,纤维幅材的位于安全装置下面或下方的区域)和铰链区域(即,纤维幅材的位于邻近安全装置的边缘或侧面的区域)移位,所述移位足以影响安全装置与纤维幅材或与所得片材或文件的基底的相互作用。子区域和铰链区域中的所得的纤维浓度小于至少相邻的一个或多个主体区域中的纤维浓度。这导致在安全装置与片材或文件的基底的界面处的弱连接相互作用,并且特别地导致在安全装置的界面表面和/或边缘处的弱连接相互作用。在所得文件的使用或流通期间,这些弱区域非常易于在片材或文件中沿安全装置与基底之间的界面边缘撕裂,或产生铰链效应(即,界面边缘之间的分离区域)。此外,该文件倾向于表现出背面透印;即,当施加在纤维幅材的一侧上时,所施加的安全装置将产生可从纤维幅材、任何所得的纤维片材或任何所得的文件的相对侧观察到的阴影效果。这通常需要使用背面伪装涂层来解决该问题。还已经观察到,所述所得片材或文件表现出横向(CD)拉伸强度的降低。It has been found that some fibers are displaced as they flow around the safety device as the safety device is pressed into the fibrous web during the wet stage of its introduction into the forming fibrous web. This results in a certain amount of fibre being displaced from the sub-areas (ie the area of the fibrous web that is located under or below the safety device) and the hinge area (ie the area of the fibrous web that is located adjacent to the edge or side of the safety device), so The displacement is sufficient to affect the interaction of the security device with the fibrous web or with the substrate of the resulting sheet or document. The resulting fiber concentration in the sub-regions and hinge region is less than the fiber concentration in at least the adjacent one or more bulk regions. This results in weak tie interactions at the interface of the security device and the substrate of the sheet or document, and in particular at the interface surfaces and/or edges of the security device. During use or circulation of the resulting document, these weak areas are very susceptible to tearing in the sheet or document along the interface edges between the security device and the substrate, or to create a hinge effect (ie, areas of separation between the interface edges). Furthermore, the document tends to exhibit backside print-through; that is, when applied on one side of a fibrous web, the applied security device will produce a document that can be obtained from the fibrous web, any resulting fibrous sheet, or any resulting document The shadow effect observed on the opposite side of the . This usually requires the use of a backside camouflage coating to solve the problem. It has also been observed that the resulting sheet or document exhibits a reduction in cross direction (CD) tensile strength.
一种用于获得表面施加的安全装置的替代方案是将安全装置施加到完全成形的纤维基底的表面。然而,施加到完全成形的纤维基底伴随其他实质性限制。例如,这实质上限制了可使用的安全装置的厚度范围。通常,表面施加限于最薄(诸如小于15微米(μm))的安全装置。较厚的安全装置通常被排除在此类施加之外,至少部分地因为在所得片材上所得的厚度差影响下游处理。如本文所用,术语“厚度差”是指从片材的主体区域的上表面到安全装置的上表面测量的高度差。因此,厚度差可以为负或正。例如,在安全装置的上表面位于片材的主体区域的上表面的高度下方的情况下,厚度差为负。相反,在安全装置的上表面位于片材的主体区域的上表面的高度上方的情况下,厚度差为正。另选地,厚度差为零指示安全装置的上表面与主体区域的上表面齐平。由于在造纸过程的干燥阶段中或在后施加过程中引入的较厚的安全装置产生的厚度差,下游过程诸如卷绕、成片、堆叠、切割和通过ATM处理在时间和成本方面受到影响。重要的是,以这种方式产生的堆叠尚未做好压榨准备或印刷准备。An alternative for obtaining a surface-applied safety device is to apply the safety device to the surface of a fully formed fiber substrate. However, application to fully formed fibrous substrates comes with other substantial limitations. For example, this substantially limits the range of thicknesses of safety devices that can be used. Typically, surface application is limited to the thinnest (such as less than 15 micrometers (μm)) security devices. Thicker safety devices are generally excluded from such applications, at least in part, because the resulting difference in thickness on the resulting sheet affects downstream processing. As used herein, the term "thickness difference" refers to the difference in height measured from the upper surface of the body region of the sheet to the upper surface of the safety device. Therefore, the thickness difference can be negative or positive. For example, where the upper surface of the safety device is located below the height of the upper surface of the main body region of the sheet, the thickness difference is negative. Conversely, where the upper surface of the safety device is located above the height of the upper surface of the body region of the sheet, the difference in thickness is positive. Alternatively, a thickness difference of zero indicates that the upper surface of the safety device is flush with the upper surface of the body region. Downstream processes such as winding, sheeting, stacking, cutting and processing by ATM suffer in terms of time and cost due to thickness differences created by thicker safety devices introduced during the drying stage of the papermaking process or during post-application. Importantly, the stacks produced in this way are not ready for pressing or printing.
鉴于上述情况,仍然需要具有表面施加的安全装置的改进片材,而不管厚度如何,并且需要能够产生这些片材的改进的方法。还存在对提供具有附加真实性特征的安全文件的持续需求,该附加真实性特征允许验证文件的真实性,同时防止未经授权的复制。In view of the foregoing, there remains a need for improved sheets with surface-applied safety devices, regardless of thickness, and for improved methods of producing these sheets. There is also a continuing need to provide secure documents with additional authenticity features that allow verification of document authenticity while preventing unauthorized copying.
发明内容SUMMARY OF THE INVENTION
本发明通过提供片材、安全文件和用于通过在造纸的湿阶段期间将安全装置引入成形纤维幅材而将安全装置表面施加到纤维片材或文件的方法来解决上述需求中的至少一者。在一个实施方案中,安全装置被施加在形成于纤维幅材中的一个或多个“软边”通孔上方。该实施方案中的安全装置由结构膜制备,并且具有至少约10微米的厚度,从而为该装置提供跨越一个或多个通孔的充分耐久性。如本文所用,术语“软边通孔”意指在造纸期间片材中的纤维延伸到由通孔环绕的开口中而产生的通孔。通孔的开口从幅材的一侧或表面延伸到相对侧或表面,并且在边缘区域表现出独特的不规则性。该独特的不规则性是由于缺少尖锐的切割边缘而引起的,并且包括边缘区域中的纤维和 /或延伸到开口中的纤维的不规则积聚。在此类贯通开口具有经常变化且不易于复制的独特不规则性的情况下,这些开口用作具有高安全值的真实性特征。本发明的方法包括在纤维幅材充分固结的造纸过程的湿阶段期间,将安全装置引入到成形的纤维幅材之上或之中,任选地在形成于纤维幅材中的一个或多个“软边”通孔上方。在一个实施方案中,当纤维幅材具有基于纤维幅材的总重量小于98重量%的水或水分含量时,纤维幅材充分固结。优选地,当纤维幅材在造纸机的伏辊或类似工具处或附近时纤维幅材充分固结。The present invention addresses at least one of the above needs by providing a sheet, a security document, and a method for surface application of a security device to a fibrous sheet or document by introducing the security device into a forming fibrous web during the wet stage of papermaking . In one embodiment, the safety device is applied over one or more "soft edge" through-holes formed in the fibrous web. The safety device in this embodiment is fabricated from a structural film and has a thickness of at least about 10 microns to provide sufficient durability for the device across one or more through holes. As used herein, the term "soft edged through-holes" means through-holes created during papermaking by fibers in a sheet extending into openings surrounded by through-holes. The openings of the through holes extend from one side or surface of the web to the opposite side or surface and exhibit unique irregularities in the edge regions. This unique irregularity is caused by the lack of sharp cutting edges and includes irregular accumulation of fibers in the edge region and/or fibers extending into the openings. Where such through openings have unique irregularities that vary frequently and are not easily replicated, these openings serve as authenticity features with a high security value. The method of the present invention comprises introducing a safety device onto or into the formed fibrous web, optionally during the wet stage of the papermaking process in which the fibrous web is sufficiently consolidated, optionally in one or more of the formed fibrous webs. above a "soft edge" via. In one embodiment, a fibrous web is sufficiently consolidated when the fibrous web has a water or moisture content of less than 98% by weight based on the total weight of the fibrous web. Preferably, the fibrous web is sufficiently consolidated when it is at or near the couch roll or similar tool of the paper machine.
本发明还提供了通过上述方法产生的纤维片材以及包括该纤维片材的所得文件。在第一实施方案中,纤维片材具有:相对的表面;在其一个表面上的至少一个凹部;纤维子区域,该纤维子区域是设置在凹部下面或下方的三维体积;以及纤维主体区域,该纤维主体区域也是邻近凹部和子区域设置的三维体积;设置在凹部中的表面施加的安全装置;以及表面施加的安全装置与片材的主体区域和子区域之间的界面;其中在该纤维子区域和纤维主体区域中存在以基本上相等的量存在的纤维。纤维子区域在横向或侧向上与表面施加的安全装置共同延伸。换句话讲,三维子区域占据纤维片材的位于安全装置下方的体积。纤维主体区域邻近凹部和子区域设置,并占据纤维片材的剩余体积。The present invention also provides the fibrous sheet produced by the above method and the resulting document comprising the fibrous sheet. In a first embodiment, a fibrous sheet has: opposing surfaces; at least one recess on one surface thereof; a fiber sub-region, which is a three-dimensional volume disposed under or below the recess; and a fiber body region, The fiber body region is also a three-dimensional volume disposed adjacent to the recesses and sub-regions; a surface-applied safety device disposed in the recesses; and the interface between the surface-applied safety device and the body region and sub-regions of the sheet; wherein in the fiber sub-region The fibers are present in substantially equal amounts in the fiber body region. The fiber sub-regions are coextensive with the surface-applied safety device in the transverse or lateral direction. In other words, the three-dimensional sub-regions occupy the volume of the fiber sheet below the safety device. The fiber body regions are positioned adjacent the recesses and subregions and occupy the remaining volume of the fiber sheet.
通过比较片材在安全装置下面的三维区域(在安全装置已被移除之后(参见例如由图11中的宽度A、高度a和深度维度(未示出)限定的区域)的质量(重量)与片材的与安全装置相邻的具有相等宽度(即,宽度等于安全装置的宽度)的三维区域(参见例如由图11中的宽度B、高度b和深度维度(未示出)限定的区域)的质量(重量),来实现片材的子区域和主体区域两者中存在基本上等量的纤维的确认。在以下描述的其中通孔存在于片材的在安全装置下方的区域中的实施方案中,首先通过加回现在由通孔占据的区域的质量(重量)来调整该区域中的质量(重量),然后将该区域(子区域)的质量(重量)与主体区域的质量(重量)进行比较。By comparing the mass (weight) of the three-dimensional area of the sheet under the safety device (after the safety device has been removed (see eg the area defined by the width A, height a and depth dimensions (not shown) in Figure 11) A three-dimensional area of equal width (ie, width equal to the width of the safety device) of the sheet adjacent to the safety device (see, eg, the area defined by the width B, height b, and depth dimensions (not shown) in FIG. 11 ) ) to achieve confirmation of the presence of substantially equal amounts of fibers in both the sub-regions and the bulk region of the sheet. In the following descriptions where through-holes are present in the region of the sheet below the safety device In an embodiment, the mass (weight) in the region now occupied by the via is first adjusted by adding back the mass (weight) of the region, and then the mass (weight) of the region (sub-region) is compared to the mass (weight) of the main region ( weight) for comparison.
在本发明的第二实施方案或方面中,纤维片材具有相对的表面和一个或多个造纸机制成或“软边”的通孔。表面施加的安全装置被施加在一个或多个通孔上方,该表面施加的安全装置的形状和尺寸可与一个或多个通孔的形状和尺寸基本上相同或不同。例如,表面施加的安全装置可被成形为与通孔不同并且大于通孔,或者其尺寸可被设定成与通孔相似并且仅略大于通孔。在这两种情况下,纤维片材和由此形成的文件将与上述相似,不同之处在于一个或多个通孔将从凹部延伸穿过纤维片材的相对表面。具有三维体积的纤维子区域因此将被设置在界定通孔的那些凹部区域的下面或下方,并从其横向延伸到表面施加的安全装置的外周边。换句话讲,如上所述,纤维子区域将占据由表面施加的安全装置占据的空间下方的空间。In a second embodiment or aspect of the present invention, the fibrous sheet has opposing surfaces and one or more paper machine made or "soft edged" through holes. A surface-applied safety device is applied over the one or more through-holes, the surface-applied safety device may be substantially the same or different in shape and size than the one or more through-holes. For example, a surface-applied safety device may be shaped differently and larger than the through-hole, or it may be sized to be similar to and only slightly larger than the through-hole. In both cases, the fibrous sheet and the document formed therefrom will be similar to that described above, except that one or more through holes will extend from the recesses through opposing surfaces of the fibrous sheet. Fiber sub-regions with a three-dimensional volume will therefore be positioned below or below those recessed regions that define the through-holes, and extend laterally therefrom to the outer perimeter of the surface-applied safety device. In other words, as described above, the fiber sub-regions will occupy space below the space occupied by the surface-applied safety device.
令人惊讶地,已经发现,表面施加的安全装置可在纤维幅材充分固结为例如完全成形的湿幅材的湿阶段期间被引入。通过在造纸过程的该湿阶段引入安全装置,安全装置可被充分地推入纤维幅材中以使子区域中的纤维进一步固结而不是使它们移位。这继而有助于在纤维和表面施加的安全装置之间提供增加的连接相互作用。结果,耐久性、油墨粘附性、横向(CD)拉伸强度和背面透印中的至少一者得到改善。这些令人惊讶的优点避免了对改善油墨粘附性、改善拉伸强度或伪装背面透印的进一步处理步骤的需要。此外,因为在纤维幅材充分固结的湿阶段期间引入安全装置,所以使得可能迫使安全装置进入纤维幅材中,从而使得能够使用更厚的安全装置,因为它们的厚度差可显著减小。由此所得的厚度差对下游过程的影响较小。Surprisingly, it has been found that a surface-applied safety device can be introduced during the wet stage when the fibrous web is sufficiently consolidated into eg a fully formed wet web. By introducing the safety device during this wet stage of the papermaking process, the safety device can be pushed sufficiently into the fibrous web to further consolidate the fibers in the sub-regions rather than dislodging them. This in turn helps to provide increased connection interaction between the fibers and the surface applied safety device. As a result, at least one of durability, ink adhesion, cross direction (CD) tensile strength, and backside print-through is improved. These surprising advantages obviate the need for further processing steps to improve ink adhesion, improve tensile strength, or camouflage backside print-through. Furthermore, since the safety devices are introduced during the wet phase when the fibrous web is sufficiently consolidated, it is made possible to force the safety devices into the fibrous web, enabling the use of thicker safety devices as their thickness difference can be significantly reduced. The resulting thickness difference has less impact on downstream processes.
通过本文提供的方法,申请人还出人意料地发现,表面施加的安全装置可与纤维幅材、纤维片材或所得文件中的至少一个其他特征配准地施加。在本发明的第二方面中,表面施加的安全装置与一个或多个通孔配准地施加。如本领域技术人员将容易理解的,将安全装置与纤维幅材中的又一特征配准地施加极大地增加了所得片材或文件的防伪性。此外,因为在纤维幅材制造过程的湿阶段期间引入安全装置,所以可能在造纸过程期间调整配准。因此,避免了否则将需要校正安全装置与其他特征的未对准的进一步处理步骤。以连续方式引入安全装置还避免了对载体基底的需求,因为可用单个引入装置将安全装置切割/冲压并引入纤维幅材。如本文所用,术语“引入装置”是指用于在湿阶段期间将安全装置切割/冲压和/或引入纤维幅材的装置。合适的引入装置在本文中进一步描述。Through the methods provided herein, Applicants have also surprisingly discovered that a surface-applied security device can be applied in registration with at least one other feature in the fibrous web, fibrous sheet, or resultant document. In a second aspect of the invention, the surface-applied safety device is applied in registration with the one or more through holes. As those skilled in the art will readily appreciate, the application of the security device in registration with a further feature in the fibrous web greatly increases the security of the resulting sheet or document. Furthermore, since safety devices are introduced during the wet stage of the fiber web manufacturing process, it is possible to adjust the registration during the papermaking process. Thus, further processing steps that would otherwise be required to correct misalignment of the safety device with other features are avoided. Introducing the safety device in a continuous manner also avoids the need for a carrier substrate since the safety device can be cut/punched and introduced into the fibrous web with a single introduction device. As used herein, the term "introduction device" refers to a device for cutting/punching and/or introducing a safety device into the fibrous web during the wet stage. Suitable introduction devices are described further herein.
本领域的普通技术人员通过以下详细描述和附图将能够辨别本发明的其他特征和优点。除非另有定义,否则本文使用的所有技术和科学术语具有与本发明所属领域的普通技术人员通常所理解的相同含义。本文提及的所有出版物、专利申请、专利和其他参考文献均全文以引用方式并入本文。在冲突的情况下,以本说明书(包括定义)为准。此外,材料、方法和示例仅是例示性的,并且不旨在进行限制。此外,本文明确列举的所有范围也隐含地涵盖所有子范围。Other features and advantages of the present invention will be apparent to those of ordinary skill in the art from the following detailed description and accompanying drawings. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. All publications, patent applications, patents, and other references mentioned herein are incorporated by reference in their entirety. In case of conflict, the present specification, including definitions, will control. Furthermore, the materials, methods, and examples are illustrative only and not intended to be limiting. Furthermore, all ranges expressly recited herein also implicitly encompass all subranges.
附图说明Description of drawings
参考以下附图可更好地理解本公开。附图中的部件不一定按比例绘制,而是将重点放在清楚地示出本公开的原理上。尽管结合附图公开了示例性实施方案,但并不旨在将本公开限制于本文所公开的一个或多个实施方案。相反,旨在覆盖所有的替代方案、修改和等同物。The present disclosure may be better understood with reference to the following drawings. The components in the drawings are not necessarily to scale, emphasis instead being placed upon clearly illustrating the principles of the present disclosure. Although exemplary embodiments are disclosed in connection with the accompanying drawings, it is not intended to limit the disclosure to the embodiment or embodiments disclosed herein. On the contrary, the intention is to cover all alternatives, modifications and equivalents.
通过参考所附的附图来说明所公开的发明的特定特征,在附图中:Certain features of the disclosed invention are illustrated with reference to the accompanying drawings, in which:
图1是通过在造纸的湿阶段期间在纤维幅材未充分固结的情况下将安全装置引入到纤维幅材中而产生的纤维片材的横截面侧视图;Figure 1 is a cross-sectional side view of a fibrous sheet produced by introducing a safety device into a fibrous web during the wet stage of papermaking without adequate consolidation of the fibrous web;
图2是通过在造纸的干燥阶段期间或之后水分含量太低以至不允许将安全装置压入到基底中以使纤维进一步固结时将安全装置引入到纤维幅材上而产生的纤维片材的横截面侧视图;Figure 2 is a fibrous sheet produced by introducing a safety device onto a fibrous web during or after the drying stage of papermaking when the moisture content is too low to allow the safety device to be pressed into the substrate to further consolidate the fibers cross-sectional side view;
图3是本发明的纤维片材的示例性实施方案的横截面侧视图,该纤维片材具有表面施加的安全装置,其中在纤维幅材充分固结时将安全装置引入到纤维幅材之中或之上;3 is a cross-sectional side view of an exemplary embodiment of a fibrous sheet of the present invention having a surface-applied safety device, wherein the safety device is introduced into the fibrous web when the fibrous web is sufficiently consolidated or above;
图4是长网造纸机的示意图,其中在湿作业线之后且在伏辊之前将连续幅材形式的安全装置引入网上的成形纤维幅材;Figure 4 is a schematic diagram of a Fourdrinier wire machine in which a safety device in the form of a continuous web is introduced into the forming fibrous web on the wire after the wet line and before the couch roll;
图5是根据本发明的具有施加于其上的多个不连续的表面施加的安全装置(贴片和条)的文件的示例性实施方案的俯视图;5 is a top view of an exemplary embodiment of a document having a plurality of discrete surface-applied security devices (patches and strips) applied thereon in accordance with the present invention;
图6是根据本发明的具有与文件中的另一特征(诸如水印)配准地施加的多个不连续的表面施加的安全装置(贴片)的文件的另一示例性实施方案的俯视图;6 is a top view of another exemplary embodiment of a document having a plurality of discrete surface-applied security devices (patches) applied in registration with another feature in the document, such as a watermark, in accordance with the present invention;
图7A是通过在造纸的湿阶段期间纤维幅材未充分固结时将安全装置引入成形纤维幅材而产生的在已经通过流通模拟测试经受一(1) 个循环之后的纤维片材或文件的正面的平面图;Figure 7A is of a fibrous sheet or document after it has been subjected to one (1) cycle through a flow-through simulation test, produced by introducing a safety device into a forming fibrous web when the fibrous web is not sufficiently consolidated during the wet stage of papermaking front plan;
图7B是通过在造纸的湿阶段期间纤维幅材未充分固结时将安全装置引入纤维幅材而产生的在已经通过流通模拟测试经受一(1)个循环之后的纤维片材或文件的背面的平面图;Figure 7B is the back side of a fibrous sheet or document after it has been subjected to one (1) cycle through the flow-through simulation test, produced by introducing a safety device into the fibrous web when the fibrous web is not sufficiently consolidated during the wet stage of papermaking the floor plan;
图8A是根据本发明的通过在造纸的湿阶段期间纤维幅材充分固结时将安全装置引入成形纤维幅材而产生的在已经通过流通模拟测试经受一(1)个循环之后的纤维片材或文件的示例性实施方案的正面的平面图;Figure 8A is a fibrous sheet produced by introducing a safety device into a forming fibrous web when the fibrous web is sufficiently consolidated during the wet stage of papermaking in accordance with the present invention after it has been subjected to one (1) cycle through a flow-through simulation test or a plan view of the front of an exemplary embodiment of the document;
图8B是根据本发明的通过在造纸的湿阶段期间纤维幅材充分固结时将安全装置引入纤维幅材而产生的在已经通过流通模拟测试经受一(1)个循环之后的纤维片材或文件的示例性实施方案的背面的平面图;Figure 8B is a fibrous sheet after having been subjected to one (1) cycle through a flow-through simulation test produced by introducing a safety device into a fibrous web when the fibrous web is sufficiently consolidated during the wet stage of papermaking, or A plan view of the back of the exemplary embodiment of the document;
图9A是通过在造纸的湿阶段期间纤维幅材未充分固结时将安全装置引入成形纤维幅而产生的在已经通过流通模拟测试经受三(3)个循环之后的纤维片材或文件的正面的平面图;Figure 9A is the front side of a fibrous sheet or document after it has been subjected to three (3) cycles through the flow-through simulation test, produced by introducing a safety device into the forming fibrous web when the fibrous web is not sufficiently consolidated during the wet stage of papermaking the floor plan;
图9B是通过在造纸的湿阶段期间纤维幅材未充分固结时将安全装置引入成形纤维幅材而产生的在已经通过流通模拟测试经受三(3) 个循环之后的纤维片材或文件的背面的平面图;Figure 9B is a fibrous sheet or document after it has been subjected to three (3) cycles through the flow-through simulation test, produced by introducing a safety device into the forming fibrous web when the fibrous web is not sufficiently consolidated during the wet stage of papermaking plan view of the back;
图10A是根据本发明的通过在造纸的湿阶段期间纤维幅材充分固结时将安全装置引入纤维幅材而产生的在已经通过流通模拟测试经受三(3)个循环之后的纤维片材或文件的示例性实施方案的正面的平面图;Figure 10A is a fibrous sheet after having been subjected to three (3) cycles through a flow-through simulation test or a a plan view of the front of the exemplary embodiment of the document;
图10B是根据本发明的通过在造纸的湿阶段期间纤维幅材充分固结时将安全装置引入纤维幅材而产生的在已经通过流通模拟测试经受三(3)个循环之后的纤维片材或文件的示例性实施方案的背面的平面图;Figure 10B is a fibrous sheet after having been subjected to three (3) cycles through a flow-through simulation test or a A plan view of the back of the exemplary embodiment of the document;
图11是通过将安全装置引入具有相对的表面和造纸机制成的或“软边”通孔的纤维幅材中而产生的本发明(第二方面)的纤维片材的另一示例性实施方案的横截面侧视图。一旦纤维幅材充分固结,就将安全装置引入到纤维幅材之中或之上;以及Figure 11 is another exemplary embodiment of a fibrous sheet of the present invention (second aspect) produced by incorporating a safety device into a fibrous web having opposing surfaces and paper machine made or "soft edge" through holes cross-sectional side view. introducing a safety device into or on the fibrous web once the fibrous web is sufficiently consolidated; and
图12是长网造纸机的示意图,其中使用图案化成形网在成形纤维幅材中引入通孔,然后在湿作业线之后且在伏辊之前将连续幅材形式的安全装置引入纤维幅材。图12A中描绘了在将造纸原料从流浆箱排出到成形网上之前的图案化成形网,而图12B中描绘了在将造纸原料排出到网上之后相同的成形网。Figure 12 is a schematic diagram of a Fourdrinier wire machine in which a patterned forming wire is used to introduce through holes in a forming fibrous web and then a safety device in the form of a continuous web is introduced into the fibrous web after the wet line and before the couch roll. The patterned forming wire is depicted in Figure 12A prior to discharging the papermaking stock from the headbox onto the forming wire, while the same forming wire after discharging the papermaking stock onto the wire is depicted in Figure 12B.
具体实施方式Detailed ways
通过以下细节将进一步理解本发明,这些细节被提供作为对所要求保护的发明的某些示例性实施方案的描述。The invention will be further understood through the following details, which are provided as a description of certain exemplary embodiments of the claimed invention.
通过本发明的方法,提供了包括表面施加的安全装置的纤维片材。在本发明的第一方面,提供了用于将安全装置表面施加到纤维片材的方法。该方法包括在造纸期间将安全装置引入到纤维幅材之中或之上。在第二方面,该方法包括在造纸期间在纤维幅材变得充分固结之前在纤维幅材中形成一个或多个“软边”通孔,然后一旦纤维幅材已变得充分固结,就将安全装置引入到纤维幅材之中或之上在一个或多个“软边”通孔上方。通过在造纸期间形成通孔,通孔从而设置有独特边缘不规则性,该独特边缘不规则性用作具有高安全值的真实性特征。此外,通过在造纸过程期间引入安全装置,已知的处理步骤是不间断的并且消除了附加的处理步骤。此外,通过在造纸过程的湿阶段期间引入安全装置,可由此施加比可在造纸的干燥阶段中施加的那些安全装置更厚的安全装置。By the method of the present invention, a fibrous sheet including a surface-applied safety device is provided. In a first aspect of the present invention, a method for surface application of a safety device to a fibrous sheet is provided. The method includes introducing a safety device into or onto the fibrous web during papermaking. In a second aspect, the method comprises forming one or more "soft edge" through-holes in the fibrous web during papermaking before the fibrous web becomes sufficiently consolidated, and then once the fibrous web has become sufficiently consolidated, The safety device is then introduced into or on the fibrous web over one or more "soft edge" through holes. By forming the through-holes during papermaking, the through-holes are thus provided with unique edge irregularities that serve as authenticity features with a high security value. Furthermore, by introducing safety devices during the papermaking process, the known processing steps are uninterrupted and additional processing steps are eliminated. Furthermore, by introducing the safety features during the wet stage of the papermaking process, thicker safety features can thereby be applied than those that can be applied during the dry stage of the papermaking process.
在一个实施方案中,该方法还包括使子区域中的纤维进一步固结。为了使子区域中的纤维进一步固结,将表面施加的安全装置压入到充分固结(均匀或非均匀)的纤维幅材中。纤维在该区域中压实,使得尽管该子区域的体积减小,但该区域中的纤维量不发生移位;至少不以任何显著的量移位。该区域中的纤维不发生移位的事实极大地降低了(如果不是消除)当纤维在该区域中进一步固结时一个或多个通孔变得堵塞或阻塞的可能性。In one embodiment, the method further comprises further consolidating the fibers in the sub-regions. To further consolidate the fibers in the sub-regions, a surface-applied safety device is pressed into the fully consolidated (uniform or non-uniform) fibrous web. The fibers are compacted in this region such that despite the reduced volume of the subregion, the amount of fibers in this region is not displaced; at least not by any significant amount. The fact that the fibers in this region are not displaced greatly reduces, if not eliminates, the likelihood that one or more of the through holes will become blocked or blocked as the fibers consolidate further in this region.
如本文所用,相对于本公开,本领域普通技术人员将理解术语“充分固结”意指纤维幅材处于完全成形的湿幅材状态。在该湿幅材阶段,纤维幅材包含少于98%的水和/或水分。因此,纤维幅材包含大于2%的纤维和/或纸浆。在另一个实施方案中,纤维幅材包含少于95%的水和/或水分,其余5%的成分是纤维和/或纸浆。在更优选的实施方案中,纤维幅材中的水和/或水分在约60%至小于98%、或约60%至约 95%的范围内。申请人已经发现,在引入安全装置时水和/或水分含量超过98%导致纤维移位。纤维的显著移位,尤其是在基底的子区域中,导致安全装置与基底中的纤维之间的弱相互作用。特别地,纤维的移位降低了基底的耐久性和强度,并且降低了在子区域和铰链区域中提供的伪装效果。如本文所述,这些弱相互作用,尤其是在安全装置的界面边缘处,导致上面所识别的问题。相应地,还已发现,在纤维幅材具有小于60%的水和/或水分的情况下,在造纸过程期间引入安全装置不足以允许安全装置凹入以容纳较厚的安全装置,同时仍保持低的厚度差。此外,在低于60%的水和/或水分下,子区域中的纤维不能进一步固结到足以将纤维固定在安全装置的界面边缘附近。如本文所用,术语“凹入”是指将安全装置压入到纤维幅材中以在纤维片材的基底表面中形成浮雕/凹部,使得安全装置的高度的至少一部分凹入到主体区域的表面高度以下,同时安全装置的顶部或上表面区域保持暴露。As used herein, with respect to this disclosure, one of ordinary skill in the art will understand that the term "substantially consolidated" means that the fibrous web is in a fully formed wet web state. In this wet web stage, the fibrous web contains less than 98% water and/or moisture. Thus, the fibrous web contains more than 2% fibers and/or pulp. In another embodiment, the fibrous web comprises less than 95% water and/or moisture, with the remaining 5% of the constituents being fibers and/or pulp. In more preferred embodiments, the water and/or moisture in the fibrous web is in the range of about 60% to less than 98%, or about 60% to about 95%. Applicants have found that water and/or moisture levels above 98% cause fibre displacement when the safety device is introduced. Significant displacement of fibers, especially in sub-regions of the substrate, results in weak interactions between the safety device and fibers in the substrate. In particular, the displacement of the fibers reduces the durability and strength of the substrate and reduces the camouflage effect provided in the sub-regions and hinge regions. As described herein, these weak interactions, especially at the interface edges of the safety device, lead to the problems identified above. Accordingly, it has also been found that where the fibrous web has less than 60% water and/or moisture, the introduction of the safety device during the papermaking process is not sufficient to allow the safety device to be recessed to accommodate thicker safety devices while still maintaining Low thickness difference. Furthermore, at less than 60% water and/or moisture, the fibers in the sub-regions cannot consolidate further enough to secure the fibers near the interface edge of the safety device. As used herein, the term "recessed" refers to pressing the safety device into the fibrous web to form a relief/recess in the base surface of the fibrous sheet such that at least a portion of the height of the safety device is recessed into the surface of the body area height, while the top or upper surface area of the safety device remains exposed.
如上所定义的湿阶段可被调整到在沿着造纸机的各种位置处,并且本发明设想了所有这些可能性。然而,在优选的实施方案中,在造纸过程的湿阶段期间,例如在造纸机的伏辊或类似工具处或附近,当纤维幅材构成充分固结或完全成形湿幅材(即,具有基于纤维幅材的总重量小于纤维幅材重量的98%、优选地纤维幅材重量的约60%至小于98%、或更优选地纤维幅材重量的约60%至约95%、或纤维幅材重量的约60%至约90%的水分或水含量)时,将安全装置施加到成形纤维幅材之中或之上。在此类位置处,不需要进一步的过程调整以适应安全装置到凹部中的整合。例如,吸水箱通常位于伏辊正前方,以在幅材离开机器的湿端之前去除尽可能多的水分,以便使机器的干燥器段上的负担最小化。类似地,在离开圆网造纸机的圆网部(并且在伏辊之后)时,纤维幅材将优选地由约75%至约95%的水和/或水分以及约5%至约25%的纸浆或纤维构成。The wet stage as defined above can be adjusted to various positions along the paper machine, and the present invention contemplates all these possibilities. However, in preferred embodiments, during the wet stage of the papermaking process, such as at or near a couch roll or similar tool in a paper machine, when the fibrous web constitutes a fully consolidated or fully formed wet web (ie, has a The total weight of the fibrous web is less than 98% by weight of the fibrous web, preferably from about 60% to less than 98% by weight of the fibrous web, or more preferably from about 60% to about 95% by weight of the fibrous web, or from about 60% to about 90% moisture or water content by weight of the material), the safety device is applied in or on the forming fibrous web. In such locations, no further process adjustments are required to accommodate the integration of the safety device into the recess. For example, a suction box is usually located directly in front of the couch rolls to remove as much moisture as possible before the web leaves the wet end of the machine in order to minimize the burden on the dryer section of the machine. Similarly, the fibrous web will preferably be comprised of from about 75% to about 95% water and/or moisture and from about 5% to about 25% on exiting the cylinder section of the rotary wire machine (and after the couch roll) of pulp or fibers.
虽然设想在长网造纸机上的几个造纸阶段提供纤维幅材的充分固结(如本文所定义的),但在优选的实施方案中,将安全装置引入纤维幅材的造纸阶段紧接在湿作业线之后和伏辊之前。这是在纤维幅材的上侧上不再有明显的表面水的点。在另选的实施方案中,在湿端中的真空箱上或之前将安全装置引入纤维幅材,这有利地帮助将装置设置到幅材中。优选地,安全装置经由传送轮、辊或接触靴直接放置到纤维幅材的面。While it is envisaged to provide adequate consolidation of the fibrous web (as defined herein) at several papermaking stages on a Fourdrinier wire machine, in a preferred embodiment the safety device is introduced into the fibrous web during the papermaking stage immediately following the wet After the line and before the couch. This is the point at which there is no longer significant surface water on the upper side of the fibrous web. In an alternative embodiment, the safety device is introduced into the fibrous web on or before the vacuum box in the wet end, which advantageously aids in the placement of the device into the web. Preferably, the safety device is placed directly to the face of the fibrous web via transfer wheels, rollers or contact shoes.
在一个实施方案中,在移动经过或进一步越过伏辊时,纤维纸幅在行进到造纸机的干燥端时处于具有表面施加的安全装置的完全成形幅材的状态,该干燥端由压榨机段和干燥器段组成。In one embodiment, while moving past or further past the couch roll, the fibrous web is in a state of a fully formed web with surface-applied safety devices as it travels to the dry end of the paper machine, which is formed by the press section and dryer section.
在这两种类型的造纸机的压榨机段中,通过在辊与毛毡之间压缩湿纸来去除水和/或水分,以将水和/或水分含量降低至期望的水平。申请人惊奇地发现,压缩具有表面施加的安全装置的完全成形的湿幅材,使得子区域(即,纤维幅材的在所引入的安全装置下面或下方的区域)中的纤维进一步固结,因为它们被压实而不是移位。结果,所得纤维片材或所得文件的强度特性以及背面不透明性得到改善,所述背面不透明性提供安全装置的伪装以减少背面透印。In the press section of both types of paper machines, water and/or moisture is removed by compressing the wet paper between rolls and felt to reduce the water and/or moisture content to a desired level. Applicants have surprisingly found that compressing a fully formed wet web with surface-applied safety devices results in further consolidation of the fibers in sub-regions (ie the regions of the fibrous web below or below the introduced safety devices), Because they are compacted and not displaced. As a result, the strength properties of the resulting fibrous sheet or resulting document are improved as well as the backside opacity which provides camouflage of the security device to reduce backside print-through.
本发明的安全装置可具有各种厚度。然而,已经发现,本发明的方法有利地允许在厚度谱的较厚端上的安全装置的表面施加。在一个实施方案中,安全装置具有至多100微米(μm)的厚度。在另一个实施方案中,安全装置具有在5μm至75μm或更优选地10μm至50μm 范围内的厚度。安全装置的宽度仅由纤维片材的宽度限制。在优选的实施方案中,宽度在0.25毫米至20毫米(mm)、更优选地0.5mm至 15mm的范围内。The safety device of the present invention can have various thicknesses. However, it has been found that the method of the present invention advantageously allows for the surface application of safety devices on the thicker end of the thickness spectrum. In one embodiment, the security device has a thickness of up to 100 micrometers (μm). In another embodiment, the safety device has a thickness in the range of 5 μm to 75 μm or more preferably 10 μm to 50 μm. The width of the safety device is limited only by the width of the fiber sheet. In a preferred embodiment, the width is in the range of 0.25 millimeters to 20 millimeters (mm), more preferably 0.5 mm to 15 mm.
通过在造纸的湿阶段期间引入安全装置,这些安全装置可被压入到纤维幅材中以在所得的纤维片材的表面中产生凹部。所得的纤维片材包括表面施加的安全装置,该表面施加的安全装置具有不会导致上述缺点的厚度差。在一个实施方案中,厚度差相对于安全装置的厚度来表达。在该实施方案中,厚度差的绝对值在安全装置厚度的0%至约80%的范围内;优选地小于安全装置厚度的10%。By introducing safety devices during the wet stage of papermaking, these safety devices can be pressed into the fibrous web to create recesses in the surface of the resulting fibrous sheet. The resulting fibrous sheet comprises a surface-applied safety device with a thickness difference that does not lead to the above-mentioned disadvantages. In one embodiment, the difference in thickness is expressed relative to the thickness of the safety device. In this embodiment, the absolute value of the difference in thickness is in the range of 0% to about 80% of the thickness of the safety device; preferably less than 10% of the thickness of the safety device.
在一个实施方案中,厚度差在-10μm至约50μm的范围内。更优选地,厚度差在-5μm至30μm、或0μm至25μm的范围内。In one embodiment, the difference in thickness is in the range of -10 μm to about 50 μm. More preferably, the thickness difference is in the range of -5 μm to 30 μm, or 0 μm to 25 μm.
在某些实施方案中,该装置足够薄,使得安全装置到纤维湿幅材中的压入导致负的厚度差(即,安全装置的厚度或高度小于主体区域的厚度或高度)。在此类实施方案中,通过参考厚度差相对于安全装置厚度的绝对值来最佳地表征厚度差。例如,在一个实施方案中,安全装置的厚度小于25μm,使得当安全装置被压入到纤维幅材中时,表面施加的安全装置的厚度差的绝对值在安全装置厚度的0%至约 50%、更优选地0%至约30%、甚至更优选地约0%至约10%的范围内。在一个其他实施方案中,安全装置的厚度同样小于25μm,使得通过将安全装置压入到纤维幅材中使子区域进一步固结产生在-10μm至 15μm、优选地-5μm至10μm范围内的厚度差。In certain embodiments, the device is thin enough that the indentation of the safety device into the fibrous wet web results in a negative caliper difference (ie, the thickness or height of the safety device is less than the thickness or height of the body region). In such embodiments, the difference in thickness is best characterized by reference to the absolute value of the difference in thickness relative to the thickness of the safety device. For example, in one embodiment, the thickness of the safety device is less than 25 μm such that when the safety device is pressed into the fibrous web, the absolute value of the difference in thickness of the surface-applied safety device is between 0% and about 50% of the safety device thickness. %, more preferably from 0% to about 30%, even more preferably from about 0% to about 10%. In a further embodiment, the thickness of the safety device is likewise less than 25 μm, such that further consolidation of the sub-regions by pressing the safety device into the fibrous web results in a thickness in the range of -10 μm to 15 μm, preferably -5 μm to 10 μm Difference.
另选地,在一个实施方案中,安全装置的厚度大于25μm,使得通过将安全装置压入到纤维幅材中使子区域进一步固结产生在-10 μm至50μm、优选地-5μm至25μm、或0μm至15μm范围内的厚度差。在其中安全装置也具有大于25μm的厚度的一个其他实施方案中,厚度差相对于安全装置厚度的绝对值在0%至约50%的范围内。优选地,厚度差的绝对值在安全装置厚度的0%至约20%的范围内。Alternatively, in one embodiment, the thickness of the safety device is greater than 25 μm, such that further consolidation of the sub-regions by pressing the safety device into the fibrous web results in a range between -10 μm and 50 μm, preferably between -5 μm and 25 μm, or thickness difference in the range of 0 μm to 15 μm. In one other embodiment in which the safety device also has a thickness greater than 25 μm, the difference in thickness is in the range of 0% to about 50% relative to the absolute value of the safety device thickness. Preferably, the absolute value of the thickness difference is in the range of 0% to about 20% of the thickness of the safety device.
“伏辊”将被本领域普通技术人员理解为在长网造纸机上用于长网的定位在纸幅离开网(即,湿端或纸成形段)并且网返回胸辊的位置处的导向辊或转向辊。伏辊在圆网造纸机上用于相同的目的,其中长网部已被圆网部代替。具体地,当幅材离开圆网部并朝伏辊行进时,伏辊引导并转动幅材。A "couch roll" will be understood by those of ordinary skill in the art as a guide roll for a Fourdrinier wire on a Fourdrinier wire machine positioned at the point where the web leaves the wire (ie, the wet end or paper forming section) and the wire returns to the breast roll or steering rollers. Couch rolls are used for the same purpose on rotary wire machines, where the Fourdrinier wire section has been replaced by the rotary wire section. Specifically, the couch rolls guide and turn the web as it leaves the cylinder section and travels towards the couch rolls.
尽管还设想整个纤维幅材在水和/或水分含量和纤维含量方面具有均匀的一致性,但纤维幅材不均匀地充分固结也在本发明的范围内。例如,在一个实施方案中,纤维幅材仅在引入点处或沿着引入点充分固结。如本文所用,“引入点”是指在纤维幅材处或沿着纤维幅材的至少部分地被安全装置覆盖的区域。在另一个实施方案中,纤维幅材仅部分地充分固结或以梯度或矩阵图案充分固结,使得在引入点处,纤维未显著分散而导致所识别的缺点。例如,通过在沿着成形纤维幅材的位置处进行选择性真空处理,可提供充分固结的梯度或矩阵图案。另选地,在一个实施方案中,通过施加辐射源(即,热)以在沿着成形纤维幅材的选定位置处去除顶部表面水来以梯度或矩阵图案去除水分含量。While it is also contemplated that the entire fibrous web has a uniform consistency in water and/or moisture content and fiber content, it is also within the scope of the present invention that the fibrous web is not uniformly sufficiently consolidated. For example, in one embodiment, the fibrous web is sufficiently consolidated only at or along the point of introduction. As used herein, "entry point" refers to an area at or along a fibrous web that is at least partially covered by a safety device. In another embodiment, the fibrous web is only partially sufficiently consolidated or sufficiently consolidated in a gradient or matrix pattern such that at the point of introduction, the fibers are not significantly dispersed to cause the identified disadvantage. For example, by selective vacuum treatment at locations along the forming fibrous web, a well consolidated gradient or matrix pattern can be provided. Alternatively, in one embodiment, the moisture content is removed in a gradient or matrix pattern by applying a radiation source (ie, heat) to remove top surface water at selected locations along the forming fibrous web.
将安全装置引入纤维幅材在安全装置与基底纤维幅材、所得纤维片材或所得文件之间形成界面。本文所使用,术语“界面”可通过安全装置与基底之间的直接或间接接触来形成。在界面是直接的情况下,安全装置与基底中的纤维直接接触。然而,设想安全装置沿着一些或所有底表面和侧表面与基底形成间接界面。例如,界面可包括安全装置与基底之间的其他材料。尽管设想了各种材料,但另外的纤维或聚合材料(例如从天然来源诸如植物来源获得或从聚合物熔体组合物纺制等的单独或组合的单组分和/或多组分纤维)是特别合适的。此外,优选粘合剂材料用于形成间接界面。可激活粘合剂可用于将安全装置锚固或粘合到纤维幅材的凹入表面之上或之内。合适的粘合剂不受限制,并且包括但不限于在造纸机的其中温度达到100℃至160℃的干燥器段中激活的水激活、热激活和/或压力激活粘合剂。这些涂层可以溶剂基聚合物溶液或水溶液或分散体的形式施加。合适的分散体选自丙烯酸类树脂分散体、环氧树脂分散体、天然胶乳分散体、聚氨酯树脂分散体、聚乙酸乙烯酯树脂分散体、聚乙烯醇树脂分散体、脲醛树脂分散体、乙酸乙烯酯树脂分散体、乙烯乙酸乙烯酯树脂分散体、乙烯乙烯醇树脂分散体、聚酯树脂分散体以及它们的混合物。在移动经过伏辊时,具有表面施加的安全装置的完全成形湿幅材行进到造纸机的干燥端,该干燥端由压榨机段和干燥器段组成。粘合剂可另选地形成安全装置的一部分,并且在此类实施方案中具有在5μm至约50 μm、优选地5μm至约20μm范围内的厚度。The introduction of the security device into the fibrous web forms an interface between the security device and the base fibrous web, the resulting fibrous sheet, or the resulting document. As used herein, the term "interface" may be formed by direct or indirect contact between the security device and the substrate. Where the interface is direct, the safety device is in direct contact with the fibers in the substrate. However, it is contemplated that the safety device forms an indirect interface with the substrate along some or all of the bottom and side surfaces. For example, the interface may include other materials between the security device and the substrate. Although various materials are contemplated, additional fibers or polymeric materials (eg, monocomponent and/or multicomponent fibers, either alone or in combination, obtained from natural sources such as plant sources or spun from polymer melt compositions, etc.) is particularly suitable. Furthermore, a binder material is preferred for forming the indirect interface. The activatable adhesive can be used to anchor or bond the safety device onto or into the concave surface of the fibrous web. Suitable adhesives are not limited and include, but are not limited to, water activated, heat activated and/or pressure activated adhesives activated in the dryer section of the paper machine where the temperature reaches 100°C to 160°C. These coatings can be applied in the form of solvent-based polymer solutions or aqueous solutions or dispersions. Suitable dispersions are selected from the group consisting of acrylic resin dispersions, epoxy resin dispersions, natural latex dispersions, polyurethane resin dispersions, polyvinyl acetate resin dispersions, polyvinyl alcohol resin dispersions, urea-formaldehyde resin dispersions, vinyl acetate Ester resin dispersions, ethylene vinyl acetate resin dispersions, ethylene vinyl alcohol resin dispersions, polyester resin dispersions, and mixtures thereof. While moving past the couch roll, the fully formed wet web with surface-applied safety devices travels to the dry end of the paper machine, which consists of a press section and a dryer section. The adhesive may alternatively form part of the safety device, and in such embodiments has a thickness in the range of 5 μm to about 50 μm, preferably 5 μm to about 20 μm.
适用于本发明的安全装置包括本领域普通技术人员通常使用以提供防假冒或伪造的安全性的那些装置。在本发明的第二方面,安全装置优选地由结构膜(例如,聚对苯二甲酸乙二醇酯(PET)膜)形成,并且具有至少约10微米至15微米的厚度,这为装置提供了充分的耐久性以允许其跨越一个或多个通孔。如本文所用,术语“结构膜”旨在意指具有结构完整性的膜,其是安全装置的结构的整体部分,而不是例如通常与转移箔一起使用的可移除载体膜,或转移箔本身。安全装置可以是适于另选地或附加地将美学特征施加到基底的那些装置。合适的安全装置可显示无论是直接还是借助于装置而可被人类感知的信息,或者可显示附加地或另选地可被机器感知的信息。该安全装置可采用以下特征中的一者或多者:去金属化或选择性地金属化、磁性、组合的磁性和金属性,或压花区域或层、由色移、虹彩、液晶、光致变色和/或热致变色材料构成的变色涂层、发光和/或磁性材料的涂层、全息和/或衍射安全特征,以及微光学安全特征。在优选实施方案中,安全装置提供安全性,使得安全或有价文件可容易地被认证。在一个实施方案中,安全装置包括聚焦元件的阵列和图像图标的阵列,其中聚焦元件和图像图标的阵列被布置成使得由安全装置投射一个或多个合成图像。本发明中使用的聚焦元件用于高亮、放大、照明或强调图像图标阵列中的小点,并且包括但不限于双凸透镜和非柱面透镜(即微透镜)。上面提到的合成成像是整体成像的一种形式,因为由观察者感知的图像是由数百或数千个单独的图像片段合成的,这些图像片段被透镜(例如,微透镜)放大并向观察者的眼睛投射。Security devices suitable for use in the present invention include those commonly used by those of ordinary skill in the art to provide security against counterfeiting or counterfeiting. In a second aspect of the invention, the safety device is preferably formed from a structural film (eg, polyethylene terephthalate (PET) film) and has a thickness of at least about 10 to 15 microns, which provides the device with Sufficient durability to allow it to span one or more vias. As used herein, the term "structural film" is intended to mean a film with structural integrity that is an integral part of the structure of the security device, rather than, for example, a removable carrier film commonly used with transfer foils, or the transfer foil itself. The security devices may be those adapted to alternatively or additionally apply aesthetic features to the substrate. A suitable security device may display information that is perceptible to humans, either directly or with the aid of the device, or may additionally or alternatively display information that is perceptible to machines. The security device may employ one or more of the following features: de- or selectively metallized, magnetic, combined magnetic and metallic, or embossed areas or layers, by color shifting, iridescence, liquid crystal, light Color-changing coatings of photochromic and/or thermochromic materials, coatings of luminescent and/or magnetic materials, holographic and/or diffractive security features, and micro-optical security features. In a preferred embodiment, the security device provides security so that the security or document of value can be easily authenticated. In one embodiment, the security device includes an array of focusing elements and an array of image icons, wherein the array of focusing elements and image icons are arranged such that one or more composite images are projected by the security device. Focusing elements used in the present invention are used to highlight, magnify, illuminate, or accentuate small points in an array of image icons, and include, but are not limited to, lenticular lenses and acylindrical lenses (ie, microlenses). Composite imaging, mentioned above, is a form of ensemble imaging in that the image perceived by the observer is composited from hundreds or thousands of individual image segments that are magnified by a lens (eg, a microlens) and directed toward The observer's eye projection.
在示例性实施方案中,安全装置是基于微透镜的安全装置。此类装置通常包括(a)透光聚合物基底,(b)位于聚合物基底之上或之内的微尺寸图像图标的布置,以及(c)聚焦元件(例如,微透镜)的布置。图像图标和聚焦元件布置被配置为使得当通过聚焦元件布置来查看图像图标的布置时投射一个或多个合成图像。这些投影图像可显示许多不同的光学效果。能够呈现此类效果的材料构造在以下专利中有所描述:授予Steenblik等人的美国专利号7,333,268,授予Steenblik等人的美国专利号7,468,842,授予Steenblik等人的美国专利号7,738,175,授予Commander的美国专利号7,830,627,授予Kaule等人的美国专利号8,149,511;授予Kaule等人的美国专利号8,878,844;授予Kaule 等人的美国专利号8,786,521;授予Kaule等人的欧洲专利号2162294;以及授予Kaule的欧洲专利申请号08759342.2(或欧洲公布号 2164713)。这些参考文献在此全文并入本文。In an exemplary embodiment, the security device is a microlens based security device. Such devices typically include (a) a light transmissive polymer substrate, (b) an arrangement of micro-sized image icons on or within the polymer substrate, and (c) an arrangement of focusing elements (eg, microlenses). The image icons and focusing element arrangement are configured such that one or more composite images are projected when the arrangement of image icons is viewed through the focusing element arrangement. These projected images can display many different optical effects. Material constructions capable of exhibiting such effects are described in US Patent No. 7,333,268 to Steenblik et al., US Patent No. 7,468,842 to Steenblik et al., US Patent No. 7,738,175 to Steenblik et al., US Patent No. 7,738,175 to Commander Patent No. 7,830,627, US Patent No. 8,149,511 to Kaule et al; US Patent No. 8,878,844 to Kaule et al; US Patent No. 8,786,521 to Kaule et al; European Patent No. 2162294 to Kaule et al; Application No. 08759342.2 (or European Publication No. 2164713). These references are incorporated herein in their entirety.
在优选的实施方案中,通过本发明的方法表面施加的安全装置包括但不限于微光学安全装置(诸如在例如美国专利号7,333,268中描述的MOTIONTM微光学安全装置)、RAPIDTM微光学安全装置、全息安全装置(例如金属化全息装置)。这些装置可从美国马萨诸塞州的Crane Currency US,LLC购得。其他合适的装置包括但不限于光学可变装置 (OVD)诸如KINEGRAMTM光学数据载体以及色移安全装置。In preferred embodiments, surface-applied security devices by the methods of the present invention include, but are not limited to, micro-optical security devices (such as the MOTION ™ micro-optical security device described, for example, in US Pat. No. 7,333,268), RAPID ™ , Holographic security devices (eg metallized holographic devices). These devices are available from Crane Currency US, LLC of Massachusetts, USA. Other suitable devices include, but are not limited to, optically variable devices (OVDs) such as KINEGRAM ™ optical data carriers and color shift security devices.
虽然安全装置可以待引入纤维幅材的各种形式呈现,但已经发现提供连续幅材形式的安全装置是最有利的。通过提供连续幅材形式的安全装置,已经发现可以连续的方式将安全装置引入纤维幅材。然后将连续幅材分段或分割成多个不连续的安全装置。将连续幅材分段成不连续的安全装置可通过各种切割和/或冲压方法来实现。在优选的实施方案中,该方法是在造纸机上的制造期间将多个不连续的安全装置在不使用载体膜的情况下串联施加到纤维幅材的过程。该方法包括提供连续幅材形式的安全装置;以连续的方式切割或冲压连续幅材以形成不连续的安全装置,每个安全装置具有期望的形状和尺寸;然后在造纸期间以连续的方式将不连续的安全装置施加到纤维幅材上。Although the safety device can be present in various forms to be introduced into the fibrous web, it has been found to be most advantageous to provide the safety device in the form of a continuous web. By providing the safety device in the form of a continuous web, it has been found that the safety device can be introduced into the fibrous web in a continuous manner. The continuous web is then segmented or divided into multiple discrete safety devices. Segmenting the continuous web into discrete safety devices can be accomplished by various cutting and/or punching methods. In a preferred embodiment, the method is a process of applying a plurality of discrete safety devices in series to the fibrous web without the use of a carrier film during manufacture on a paper machine. The method includes providing a safety device in the form of a continuous web; cutting or punching the continuous web in a continuous manner to form discrete safety devices, each safety device having a desired shape and size; and then in a continuous fashion during papermaking Discontinuous safety devices are applied to the fibrous web.
本文设想可通过表面施加、部分地嵌入或全部嵌入将附加的安全装置施加到纤维片材。例如,在一个实施方案中,附加的安全装置被施加到纤维片材的表面。所述附加装置可在引入表面施加的安全装置之前被引入纤维幅材,或在引入表面施加的安全装置之后施加。该附加的安全装置可与表面施加的安全装置不同或类似。例如,在一个实施方案中,当不连续的安全装置中的一个具有25μm或更小的厚度时,设想在水分含量按重量计小于60%、优选地在约90%至0%的范围内时将其引入纤维幅材。例如,安全装置在纤维幅材在第一干燥器段和施胶压榨机之间行进通过造纸机时被引入纤维幅材,并且任选地被再润湿以将水和/或水分含量增加至约4%至约7%之间。It is contemplated herein that additional safety devices may be applied to the fibrous sheet by surface application, partial embedding or full embedding. For example, in one embodiment, additional safety features are applied to the surface of the fiber sheet. The additional means may be introduced into the fibrous web prior to introduction of the surface-applied safety means, or applied after the introduction of the surface-applied safety means. This additional safety device may be different or similar to the surface-applied safety device. For example, in one embodiment, when one of the discrete safety devices has a thickness of 25 μm or less, it is envisaged when the moisture content is less than 60% by weight, preferably in the range of about 90% to 0% It is introduced into the fibrous web. For example, a safety device is introduced into the fibrous web as it travels through the paper machine between the first dryer section and the size press, and is optionally rewetted to increase the water and/or moisture content to Between about 4% and about 7%.
安全装置可采用各种尺寸、形状或颜色。例如,设想不连续安全装置形式的安全装置采取条、带、线、丝带或贴片的非限制性形式。这些装置的总宽度可为约2mm至约25mm(优选地,约6mm至约 12mm),并且总厚度为约10微米至约50微米(优选地,约20微米至约40微米)。在优选的实施方案中,安全装置是条或贴片。如本文所用,“条”是指纵向长度维度基本上大于横向宽度维度的安全装置。相比之下,“贴片”可具有基本上相等的纵向长度和横向长度,并且可具有均匀或各种不均匀的形状。本文设想了各种形状和尺寸的条和贴片。然而,虽然条或贴片可延伸到纤维片材或所得文件的边缘,但在优选的实施方案中,条或贴片位于纤维片材或文件的周边内,并且不延伸到片材或文件的边缘。Safety devices come in a variety of sizes, shapes or colors. For example, it is envisaged that a safety device in the form of a discontinuous safety device takes the non-limiting form of a strip, tape, thread, ribbon or patch. These devices may have an overall width of about 2 mm to about 25 mm (preferably, about 6 mm to about 12 mm), and an overall thickness of about 10 microns to about 50 microns (preferably, about 20 microns to about 40 microns). In a preferred embodiment, the safety device is a strip or patch. As used herein, "strip" refers to a security device having a longitudinal length dimension that is substantially greater than a transverse width dimension. In contrast, a "patch" may have substantially equal longitudinal and transverse lengths, and may have uniform or various non-uniform shapes. This article contemplates strips and patches of various shapes and sizes. However, while the strips or patches may extend to the edges of the fibrous sheet or the resulting document, in preferred embodiments the strips or patches are located within the perimeter of the fibrous sheet or document and do not extend to the edge of the sheet or document. edge.
如所述,各种尺寸的安全装置被认为适合于本发明的方法和纤维片材。在一个实施方案中,尺寸的总长度在约5mm至约75mm、优选地约15mm至约40mm的范围内;并且总宽度为约2mm至约50 mm、优选地约6mm至约25mm;并且总厚度为约10微米至约50 微米、优选地约15微米至约40微米。本文提到的所有范围包括所有子范围,包括整数和分数。如上所述,在本发明的第二方面中,安全装置优选地由结构膜(例如,聚对苯二甲酸乙二醇酯(PET)膜)形成,并且具有至少约10微米至15微米的厚度,这为装置提供了充分的耐久性以允许其跨越一个或多个通孔。As mentioned, various sizes of safety devices are considered suitable for the method and fiber sheet of the present invention. In one embodiment, the dimensions have an overall length in the range of about 5 mm to about 75 mm, preferably about 15 mm to about 40 mm; and an overall width of about 2 mm to about 50 mm, preferably about 6 mm to about 25 mm; and an overall thickness From about 10 microns to about 50 microns, preferably from about 15 microns to about 40 microns. All ranges mentioned herein include all subranges, including integers and fractions. As noted above, in the second aspect of the invention, the security device is preferably formed from a structural film (eg, polyethylene terephthalate (PET) film) and has a thickness of at least about 10 to 15 microns , which provides the device with sufficient durability to allow it to span one or more vias.
如所述,还设想了安全装置的各种形状;例如贴片、条或线、几何形状(诸如星形、平行四边形、多边形(例如六边形、八边形等)形状)、数字、字母和各种符号。简单和复杂的非几何设计也被认为是合适的。这些形状和设计可通过旋转模具工艺进行切割。As mentioned, various shapes of security devices are also contemplated; eg patches, strips or lines, geometric shapes (such as star, parallelogram, polygonal (eg hexagon, octagon, etc.) shapes), numbers, letters and various symbols. Simple and complex non-geometric designs are also considered suitable. These shapes and designs can be cut through a rotary die process.
在本发明方法的一个实施方案中,安全装置被引入到成形纤维幅材中,使得其与纤维幅材、纤维片材或所得文件的基底之上或之中的至少一个其他特征配准。在某些实施方案中,安全装置被引入使得安全装置内的特定特征与纤维幅材、所得纤维片材或文件中的另一特征配准。该至少一个其他特征可相对于应用根据需要而变化。例如,该至少一个其他特征是水印、印刷图像、浮雕结构、另一安全装置或纸质特征。在本发明的第二方面,安全装置被引入使得其优选地与一个或多个“软边”通孔配准。在将安全装置引入纤维幅材使得其配准时,设想首先将以连续幅材形式呈现的安全装置递送到一件设备或系统 (本文中称为引入装置),该设备或系统可用于将连续幅材切割/冲压成不连续的安全装置。虽然可能使用单独的装置来切割然后将安全装置施加到纤维幅材,但优选的是,用于形成不连续安全装置的系统也用于将安全装置施加到纤维幅材之中或之上。利用单个装置,可能更精确地配准地施加安全装置,因为它需要较少的移动部件。In one embodiment of the method of the present invention, the security device is incorporated into the forming fibrous web such that it registers with at least one other feature on or in the substrate of the fibrous web, fibrous sheet or resultant document. In certain embodiments, a security device is introduced such that a particular feature within the security device registers with another feature in the fibrous web, resulting fibrous sheet, or document. The at least one other characteristic may vary as desired with respect to the application. For example, the at least one other feature is a watermark, a printed image, an embossed structure, another security device or a paper feature. In a second aspect of the invention, the safety device is introduced such that it preferably registers with one or more "soft edge" through holes. When introducing a safety device into a fibrous web so that it is in registration, it is envisaged to first deliver the safety device in the form of a continuous web to a piece of equipment or system (referred to herein as an introduction device) that can be used to introduce the continuous web Wood cutting/punching into discrete safety devices. Although it is possible to use a separate device to cut and then apply the safety device to the fibrous web, it is preferred that the system for forming the discontinuous safety device is also used to apply the safety device into or onto the fibrous web. With a single device, it is possible to apply the safety device in more precise registration as it requires fewer moving parts.
在优选的实施方案中,其中连续幅材被切成不连续的安全装置,然后通过相同的引入装置将其引入到纤维幅材之中或之上,还设想安全装置的放置可通过引入装置进行调整,使得可以连续的方式将未配准(与至少一个其他特征未配准)的安全装置调整成配准。通过在造纸过程中使用单个引入装置原位切割、施加和调整配准,使得无需附加的处理来调整放置。例如,在造纸过程期间配准地施加和调整消除了在印刷之前对所得片材或文件进行二次处理的需要。In a preferred embodiment where the continuous web is cut into discrete safety devices which are then introduced into or onto the fibrous web by the same introduction device, it is also envisaged that the placement of the safety devices can be performed by the introduction device The adjustment is such that the unregistered (unregistered with at least one other feature) security device can be adjusted into registration in a continuous manner. By using a single introduction device to cut, apply and adjust the registration in situ during the papermaking process, no additional processing is required to adjust the placement. For example, application and adjustment in registration during the papermaking process eliminates the need for secondary processing of the resulting sheet or document prior to printing.
在了解了本公开内容之后,适当的引入装置对于本领域普通技术人员而言将是显而易见的。然而,在优选的实施方案中,引入装置是采用检查安全装置与纤维幅材、纤维材料或所得文件中的至少一个其他特征之间的配准的光学或纤维密度传感器的系统。鉴于安全装置的所识别或计算的位置或安全装置与该至少一个其他特征的相对位置,引入装置用于在安全装置的放置方面进行调整。为了进行此类调整,引入装置使用变速推进装置(例如,具有伺服驱动的电动伺服机构),该变速推进装置控制连续幅材上的张力,使得可根据需要配准地施加不连续安全装置。因此,通过调节连续幅材上的张力来连续地调整安全装置的引入点。另选地,引入装置可以是旋转模切和转移装置,诸如在标签行业中用于配准地施加标签的装置。Appropriate introduction means will be apparent to those of ordinary skill in the art after an understanding of the present disclosure. However, in a preferred embodiment, the introduction device is a system employing an optical or fiber density sensor that checks the registration between the security device and at least one other feature in the fibrous web, fibrous material, or resultant document. In view of the identified or calculated position of the safety device or the relative position of the safety device to the at least one other feature, the lead-in device is used to make adjustments in the placement of the safety device. To make such adjustments, the introduction device uses a variable speed advance (eg, an electric servo with a servo drive) that controls the tension on the continuous web so that the discontinuous safety device can be applied in registration as needed. Thus, the point of introduction of the safety device is continuously adjusted by adjusting the tension on the continuous web. Alternatively, the introduction device may be a rotary die cutting and transfer device, such as is used in the label industry to apply labels in registration.
在本发明的第二方面,提供了一种方法,该方法用于在成形纤维幅材中形成一个或多个“软边”通孔,然后在该一个或多个通孔上方表面施加安全装置。在该第二方面,该方法包括:在造纸期间在成形纤维幅材中形成一个或多个“软边”通孔,并且一旦纤维幅材充分地固结 (均匀或非均匀地),就将安全装置引入到成形纤维幅材之中或之上在一个或多个“软边”通孔上方。In a second aspect of the present invention there is provided a method for forming one or more "soft edge" through holes in a forming fibrous web and then surface applying a safety device over the one or more through holes . In this second aspect, the method includes forming one or more "soft edge" through-holes in the forming fibrous web during papermaking, and once the fibrous web is sufficiently consolidated (uniformly or non-uniformly), Safety devices are introduced into or on the forming fibrous web over one or more "soft edge" through holes.
虽然本发明的第二方面被描述为具有位于一个或多个通孔上方的安全装置,但安全装置和一个或多个通孔可以其他方式配准或根本不配准。例如,安全装置和一个或多个通孔可以并排配置配准,其中安全装置邻近一个或多个通孔定位在纤维幅材之上/之中。Although the second aspect of the invention is described as having the safety device over the one or more through holes, the safety device and the one or more through holes may be otherwise registered or not registered at all. For example, the safety device and the one or more through-holes may be registered in a side-by-side configuration, wherein the safety device is positioned on/in the fibrous web adjacent the one or more through-holes.
在本发明方法的一个实施方案中,该方法还包括使纤维片材的子区域中的纤维进一步固结。为了使子区域中的纤维进一步固结,表面施加的安全装置被压入到充分固结的纤维幅材中。纤维在该区域中压实,使得尽管子区域的体积减小,但该区域(围绕一个或多个通孔)中的纤维量不发生移位,至少不以任何显著的量移位。如上所述,该区域中的纤维不发生移位的事实极大地降低了(如果不是消除)随着该区域中纤维的进一步固结,一个或多个通孔变得堵塞或阻塞的可能性。In one embodiment of the method of the present invention, the method further comprises further consolidating the fibers in the sub-regions of the fibrous sheet. To further consolidate the fibers in the sub-regions, surface-applied safety devices are pressed into the fully consolidated fiber web. The fibers are compacted in this area so that despite the reduced volume of the sub-areas, the amount of fibers in this area (around the one or more through holes) is not displaced, at least not by any significant amount. As noted above, the fact that the fibers in this region are not displaced greatly reduces, if not eliminates, the likelihood that one or more of the through holes will become blocked or blocked as the fibers in the region further consolidate.
在造纸的湿幅材阶段期间在成形纤维幅材变得“充分固结”之前产生一个或多个通孔。换句话讲,纤维幅材未处于完全成形的湿幅材状态。因此,纤维幅材包含按纤维幅材的重量计高于98%的水和/或水分含量。为了能够产生该贯通开口,造纸机的筛网必须设置有至少一个不透水元件,该不透水元件防止在该区域中形成片材。造纸筛网可以是长网造纸机的连续移动成形网或圆网造纸机的圆网。One or more through holes are created before the forming fibrous web becomes "well consolidated" during the wet web stage of papermaking. In other words, the fibrous web is not in a fully formed wet web state. Thus, the fibrous web comprises water and/or moisture content above 98% by weight of the fibrous web. In order to be able to create this through-opening, the screen of the paper machine must be provided with at least one water-tight element, which prevents sheet formation in this area. The papermaking screen can be a continuously moving forming wire of a Fourdrinier wire machine or a cylinder wire of a rotary wire machine.
通孔可采用任何合适的尺寸和形状或轮廓外形。例如,通孔可以是圆形、椭圆形、星形、形成为类似平行四边形(例如,正方形、矩形)或梯形等。在示例性实施方案中,该孔具有比放置在其上方的安全装置窄/小约1毫米(mm)的至少一个交叉维度。交叉维度是指在安全装置的至少一部分处交叉的孔上的两点之间的线。因此,如果孔的直径为5mm,则该装置将必须具有至少约6mm的最小维度。如果孔是不规则的(例如星形),则装置的最窄边缘必须与孔的最宽边缘相距约1mm。一个或多个通孔的形状或轮廓外形可与安全装置的形状或轮廓外形和/或由安全装置显示或投影的图像匹配或协调。The through holes may take any suitable size and shape or profile. For example, the vias may be circular, oval, star-shaped, formed to resemble a parallelogram (eg, square, rectangle) or trapezoid, and the like. In an exemplary embodiment, the aperture has at least one intersecting dimension that is about 1 millimeter (mm) narrower/smaller than the safety device placed over it. The intersection dimension refers to the line between two points on the aperture that intersect at at least a portion of the safety device. Therefore, if the diameter of the hole is 5mm, the device will have to have a minimum dimension of at least about 6mm. If the hole is irregular (eg star shaped), the narrowest edge of the device must be about 1 mm from the widest edge of the hole. The shape or profile of the one or more through holes may match or coordinate with the shape or profile of the security device and/or the image displayed or projected by the security device.
在形成一个或多个通孔并且纤维幅材充分固结之后,安全装置被施加到一个或多个通孔上方。如上所述,在优选的实施方案中,在造纸过程的湿阶段期间,例如在造纸机的伏辊或类似工具处或附近,当纤维幅材构成充分固结或完全成形湿幅材(即,具有基于纤维幅材的总重量小于纤维幅材重量的98%、优选地纤维幅材重量的约60%至小于98%、或更优选地纤维幅材重量的约60%至约95%、或纤维幅材重量的约60%至约90%的水分或水含量)时,将安全装置施加到成形纤维幅材之中或之上。After the one or more through holes are formed and the fiber web is sufficiently consolidated, a safety device is applied over the one or more through holes. As noted above, in preferred embodiments, during the wet stage of the papermaking process, such as at or near a couch roll or similar tool in a paper machine, when the fibrous web constitutes a fully consolidated or fully formed wet web (ie, having less than 98% by weight of the fibrous web, preferably from about 60% to less than 98% by weight of the fibrous web, or more preferably from about 60% to about 95% by weight of the fibrous web, based on the total weight of the fibrous web, or 60% to about 90% moisture or water content by weight of the fibrous web), the safety device is applied in or on the forming fibrous web.
表面施加的安全装置可被成形为与一个或多个通孔相同或不同,并且其尺寸可被设定成比一个或多个通孔大得多或仅略大于一个或多个通孔。如上所述,安全装置可采用条、带、线、丝带或贴片的非限制性形式,而通孔可以是圆形、椭圆形、星形、形成为类似平行四边形(例如,正方形/矩形)或梯形等。在一个示例性实施方案中,表面施加的安全装置是沿着由纤维幅材制成的纤维片材的整个长度或宽度的全部或部分延伸的具有在约5mm至约20mm(优选地约8mm 至约12mm)范围内的宽度的细长安全线。在另一个示例性实施方案中,通孔具有最大直径在5mm至15mm(优选地约7mm至约10mm) 之间的范围内的圆形形状,并且表面施加的安全装置是具有互补或对比形状并且宽度和长度比孔大至少2mm的贴片。The surface-applied safety device can be shaped the same as or different from the one or more through holes, and can be sized much larger than the one or more through holes or only slightly larger than the one or more through holes. As noted above, the safety device may take the non-limiting form of strips, strips, wires, ribbons or patches, while the through holes may be circular, oval, star-shaped, formed to resemble a parallelogram (eg, square/rectangular) or trapezoid etc. In an exemplary embodiment, the surface-applied safety device is extending along all or part of the entire length or width of the fibrous sheet made from the fibrous web having a range of between about 5 mm and about 20 mm (preferably between about 8 mm and 20 mm). Slender safety wire with a width in the range of about 12mm). In another exemplary embodiment, the through hole has a circular shape with a maximum diameter ranging between 5mm to 15mm (preferably about 7mm to about 10mm) and the surface applied safety device is of complementary or contrasting shape and A patch with a width and length that is at least 2mm larger than the hole.
在本发明的另一方面,提供了一种纤维片材。如本文所述的纤维片材是在安全装置被引入纤维幅材之后对纤维幅材进一步处理的结果。所述进一步处理任选地包括在将安全装置压入到纤维幅材中之前或之后施加的干燥步骤。将安全装置压入到纤维幅材中产生具有纤维主体区域和纤维子区域的纤维片材。In another aspect of the present invention, a fibrous sheet is provided. The fibrous sheet as described herein is the result of further processing of the fibrous web after the safety device has been introduced into the fibrous web. The further treatment optionally includes a drying step applied before or after pressing the safety device into the fibrous web. Pressing the safety device into the fibrous web results in a fibrous sheet having a bulk region of fibers and sub-regions of fibers.
在第一方面,具有相对的表面和在一个相对表面中的凹部的所得的纤维片材包括:设置在凹部中的表面施加的安全装置;设置在凹部下方的纤维子区域;邻近安全装置(设置在凹部中)和子区域设置的纤维主体区域;以及安全装置与纤维片材的至少一个表面之间的界面。在第二方面,所得的纤维片材具有一个或多个“软边”通孔,这些通孔从凹部延伸到纤维片材的相对表面。如本文所用,提及主体区域邻近安全装置指示在横截面视图中主体区域是沿着x轴线与安全装置相邻的三维区域。如本文所用,提及子区域在安全装置下方指示在横截面视图中该子区域是安全装置的至少部分覆盖的沿着y轴线的三维区域。该子区域的厚度小于主体区域的厚度,使得表面施加的安全装置具有小于安全装置厚度的80%或如上所述在指定范围和隐含的子范围内的厚度差。In a first aspect, a resulting fibrous sheet having opposing surfaces and a recess in one opposing surface comprises: a surface-applied safety device disposed in the recess; a fiber sub-region disposed below the recess; adjacent the safety device (disposed in the recess) and the sub-regions of the fiber body region; and the interface between the safety device and at least one surface of the fiber sheet. In a second aspect, the resulting fibrous sheet has one or more "soft edge" through holes extending from the recesses to opposing surfaces of the fibrous sheet. As used herein, reference to a body region adjacent to a safety device indicates that the body region is a three-dimensional region adjacent to the safety device along the x-axis in a cross-sectional view. As used herein, reference to a sub-region below the safety device indicates that the sub-region is a three-dimensional region along the y-axis that is at least partially covered by the safety device in cross-sectional view. The thickness of this sub-region is less than the thickness of the main body region such that the surface-applied safety device has a thickness difference of less than 80% of the thickness of the safety device or within the specified range and the implied sub-range as described above.
在一个实施方案中,该子区域中的纤维被进一步固结,使得子区域中的纤维量基本上等于至少紧邻的主体区域中的纤维。在另一实施方案中,该子区域中的纤维量基本上等于该主体区域中的纤维量。如本文所用,术语“基本上等于”,如提及主体区域和子区域中的纤维量时,是指每个区域中的纤维量在另一区域中的量的80%至100%以内,优选地90%至100%,如以纤维的每平方米克数(gsm)表征的。在优选的实施方案中,该子区域中的纤维量等于主体区域(特别是紧邻的主体区域)的80%至约100%范围内的量。In one embodiment, the fibers in the subregion are further consolidated such that the amount of fibers in the subregion is substantially equal to the fibers in at least the immediately adjacent bulk region. In another embodiment, the amount of fibers in the subregion is substantially equal to the amount of fibers in the bulk region. As used herein, the term "substantially equal", as in reference to the amount of fibers in the main region and subregions, means that the amount of fibers in each region is within 80% to 100% of the amount in the other region, preferably 90% to 100%, as characterized in grams per square meter (gsm) of fiber. In a preferred embodiment, the amount of fibers in this subregion is equal to an amount in the range of 80% to about 100% of the bulk region, particularly the immediately adjacent bulk region.
如本文所述,各种厚度可归因于合适的安全装置。因此,还设想了各种厚度差。在纤维片材的一个实施方案中,安全装置具有在约 10微米至约75微米范围内的厚度。厚度差的范围为约-10微米至约 30微米;优选地0微米至约25微米;优选地约0um至约15um。As described herein, various thicknesses can be attributed to suitable safety devices. Therefore, various thickness differences are also envisaged. In one embodiment of the fibrous sheet, the security device has a thickness in the range of about 10 microns to about 75 microns. The thickness difference ranges from about -10 microns to about 30 microns; preferably 0 microns to about 25 microns; preferably about 0 um to about 15 um.
在本发明的第一方面和第二方面两者的一个实施方案中,纤维片材表现出以下中的至少一者:(1)改善的耐久性,(2)可接受的油墨粘附性,(3)高的横向(CD)拉伸强度,或(4)降低的背面透印。如本文所用,改善的耐久性可通过以下中的至少一者来表征:(a)与当纤维幅材未充分固结时产生的此类片材相比,在界面处的损坏最小或减小,或 (b)几乎没有铰链效应。这些效果可通过模拟文件流通效果的已知行业技术来量化或评定。例如,纸币的流通可用耐久性测试来模拟。一种此类合适的耐久性测试是“流通模拟”测试(CST)。这是一种磨损测试,其被设计为模拟纸币在其流通生命周期中所经历的机械和光学退化。该测试通过将每个重7.5克的橡胶垫圈附接到纸币的四个角,然后将被加重的纸币放置在校准到60转/分钟(RPM)速度的磨石机中保持30 分钟的固定持续时间(一(1)个循环)来执行。被加重的纸币所经历的翻滚动作引起机械和光学退化。然后将受控量的液体和固体污物剂(例如,大豆油和粘土)添加到磨石机以模拟纸币在其生命周期期间通常会接触到的油和污垢的影响。在每轮模拟的退化之前和之后测试纸币的机械劣化(例如,孔、撕裂、切口、铰链、分离部分和粗糙不平的边缘形式的表面和边缘损坏,拉伸强度损失,耐折性,撕裂强度和穿孔强度)、光学劣化(例如,印刷油墨颜色特性的劣化)和污染。界面处的铰链效应和撕裂是特别适于该耐久性测试的机械退化的示例。In one embodiment of both the first and second aspects of the invention, the fibrous sheet exhibits at least one of: (1) improved durability, (2) acceptable ink adhesion, (3) High cross-direction (CD) tensile strength, or (4) reduced backside print-through. As used herein, improved durability can be characterized by at least one of: (a) minimal or reduced damage at the interface compared to such sheets produced when the fibrous web is not sufficiently consolidated , or (b) almost no hinge effect. These effects can be quantified or assessed by known industry techniques for simulating the effects of document circulation. For example, the circulation of banknotes can be simulated with durability tests. One such suitable durability test is the "flow through simulation" test (CST). This is a wear test designed to simulate the mechanical and optical degradation a banknote experiences during its life cycle in circulation. The test is performed by attaching rubber washers each weighing 7.5 grams to the four corners of the banknote, then placing the weighted banknote in a grindstone calibrated to a speed of 60 revolutions per minute (RPM) for a 30-minute immobilization duration time (one (1) cycle) to execute. The tumbling action experienced by weighted banknotes causes mechanical and optical degradation. Controlled amounts of liquid and solid soiling agents (eg, soybean oil and clay) were then added to the stone grinder to simulate the effects of oil and soiling to which a banknote would normally be exposed during its life cycle. The banknotes were tested for mechanical degradation before and after each round of simulated degradation (e.g. surface and edge damage in the form of holes, tears, cuts, hinges, breakaways and rough edges, loss of tensile strength, folding endurance, tearing crack strength and perforation strength), optical deterioration (eg, deterioration of the color properties of printing inks), and contamination. Hinge effects and tearing at the interface are examples of mechanical degradation that are particularly suitable for this durability test.
可接受的油墨粘附性的测试是本领域普通技术人员已知的。例如,油墨蹭脏,其为在多个纤维片材或文件的堆叠形式中从一个片材转移到另一个片材的油墨量,可通过本领域普通技术人员已知的方法来量化测量。类似地,拉伸强度和背面透印可通过本领域普通技术人员已知的方法来量化。例如,透印可通过已知的光反射率或透射率测试来量化。在使用例如张力测试仪或拉力测试仪的CD拉伸强度测试中,并且如本文下表2所示,根据本发明制造的纸表现出 CD拉伸强度增加,在与通过常规圆网将安全装置施加到完全成形的纤维幅材相比时,所测试的特性具有在约90%至约100%范围内的增加值。Tests for acceptable ink adhesion are known to those of ordinary skill in the art. For example, ink smear, which is the amount of ink transferred from one sheet to another in a stack of multiple fibrous sheets or documents, can be quantitatively measured by methods known to those of ordinary skill in the art. Similarly, tensile strength and backside print through can be quantified by methods known to those of ordinary skill in the art. For example, print-through can be quantified by known light reflectance or transmittance tests. using e.g. In the Tensile Tester or Tensile Tester CD Tensile Strength Test, and as shown in Table 2 herein below, the paper made in accordance with the present invention exhibited an increase in CD Tensile Strength compared to the safety device applied through a conventional rotary wire to fully The properties tested have increases in the range of about 90% to about 100% when compared to formed fibrous webs.
如所述,纤维片材具有在安全装置下方的纤维子区域以及邻近安全装置和子区域的纤维主体区域。因为在纤维幅材充分固结时引入安全装置,所以在对应于片材中的子区域的纤维幅材的区域中的纤维不会发生导致所识别的缺点的量的移位。这样,纤维子区域中的纤维量基本上等于至少紧邻的主体区域中的纤维量。如本文所用,术语“紧邻的主体区域”是指主体区域中邻接子区域和安全装置的凹入部分的三维区域。该紧邻的主体区域从凹入部分和子区域径向延伸到在横截面x轴线上等于子区域的x轴线长度的距离。鉴于紧邻的主体区域和子区域之间的体积差异,子区域中的纤维密度大于紧邻的主体区域中的纤维密度。紧邻的主体区域和子区域中的纤维量基本上相等,使得在给定两个区域的体积差异的情况下,子区域中的密度大于紧邻的主体区域中的密度。在一个示例性实施方案中,主体区域中的纤维量在 88.55gsm至90.15gsm的范围内,而子区域中的纤维量在87.26gsm 至90.69gsm的范围内。如本文所用,“密度”是指一定体积中纤维的平均量。As described, the fiber sheet has a fiber sub-region below the safety device and a fiber body region adjacent the safety device and the sub-region. Because the safety device is introduced when the fibrous web is sufficiently consolidated, the fibers in the regions of the fibrous web corresponding to the sub-regions in the sheet are not displaced by an amount that leads to the identified defects. In this way, the amount of fiber in the fiber sub-region is substantially equal to the amount of fiber in at least the immediately adjacent body region. As used herein, the term "proximate body region" refers to the three-dimensional region of the body region that adjoins the sub-region and the recessed portion of the safety device. The immediately adjacent body region extends radially from the recessed portion and the sub-region to a distance in the cross-sectional x-axis equal to the x-axis length of the sub-region. Given the volume difference between the immediately adjacent bulk region and the subregion, the fiber density in the subregion is greater than the fiber density in the immediately adjacent bulk region. The amount of fibers in the immediately adjacent bulk region and subregion is substantially equal such that, given the difference in volume between the two regions, the density in the subregion is greater than the density in the immediately adjacent bulk region. In an exemplary embodiment, the amount of fibers in the bulk region is in the range of 88.55gsm to 90.15gsm and the amount of fibers in the subregions is in the range of 87.26gsm to 90.69gsm. As used herein, "density" refers to the average amount of fibers in a volume.
在本发明的第二方面中,具有相对的表面、一个或多个“软边”通孔以及在一个或多个通孔上方的凹部的纤维片材包括:设置在凹部中的表面施加安全装置;设置在凹部下方的纤维子区域,该纤维子区域界定一个或多个通孔;邻近安全装置(设置在凹部中)和子区域设置的纤维主体区域;以及安全装置与纤维片材的纤维子区域和主体区域之间的界面。该纤维子区域沿着由一个或多个通孔的外周边和安全装置的一个或多个外边界限定的区域延伸。In a second aspect of the invention, a fibrous sheet having opposing surfaces, one or more "soft edge" through-holes and a recess above the one or more through-holes comprises: a surface-applied safety device disposed in the recess fiber sub-regions disposed below the recesses, the fiber sub-regions defining one or more through holes; fiber body regions disposed adjacent to the safety device (disposed in the recesses) and sub-regions; and fiber sub-regions of safety devices and fiber sheets and the interface between the main area. The fiber sub-region extends along an area defined by the outer perimeter of the one or more through-holes and the one or more outer boundaries of the safety device.
如本文所述,适用于本发明的安全装置很多。然而,在一个实施方案中,纤维片材包括一种安全装置,该安全装置具有圆柱形和/或非圆柱形聚焦元件阵列以及与聚焦元件光学相互作用以产生至少一个合成图像的图像图标阵列。在优选的实施方案中,聚焦元件仅是柱面透镜或非柱面透镜(例如微透镜)。然而,本文设想透镜阵列包括各种比率的两者的混合。As described herein, there are many safety devices suitable for use with the present invention. However, in one embodiment, the fiber sheet includes a security device having an array of cylindrical and/or non-cylindrical focusing elements and an array of image icons that optically interact with the focusing elements to produce at least one composite image. In preferred embodiments, the focusing elements are only cylindrical lenses or non-cylindrical lenses (eg microlenses). However, it is contemplated herein that the lens array includes a mixture of the two in various ratios.
如本文所述,安全装置可以是条或贴片或其他形状或几何形状的形式。在一个实施方案中,安全装置以与片材中的至少一个其他特征配准的方式存在于片材中。本文描述了合适的其他特征。As described herein, the safety device may be in the form of a strip or patch or other shape or geometry. In one embodiment, the safety device is present in the sheet in registration with at least one other feature in the sheet. Suitable additional features are described herein.
另一方面,本发明是包括纤维片材的文件。本发明设想了各种文件。例如,合适的文件包括但不限于纸币、债券、支票、旅行支票、身份证、彩票、护照、邮票、股票凭证以及非安全文件(诸如文具物品和标签以及用于美观的物品)。可将多个安全装置引入到纤维幅材中,并且因此可发现多个安全装置被施加到纤维片材和任何所得的文件。另选地,在一个实施方案中,该文件包括至少一个表面施加的安全装置和至少一个其他安全装置,诸如嵌入或部分地嵌入的安全装置或安全特征。表面施加的安全装置可与文件的其他特征(诸如其他安全装置或安全或装饰特征)配准。In another aspect, the present invention is a document comprising a fibrous sheet. Various documents are contemplated by the present invention. For example, suitable documents include, but are not limited to, banknotes, bonds, checks, traveler's checks, ID cards, lottery tickets, passports, stamps, stock certificates, and non-secure documents such as stationery items and labels and items for aesthetics. Multiple security devices can be incorporated into the fibrous web and thus can be found applied to the fibrous sheet and any resulting documents. Alternatively, in one embodiment, the document includes at least one surface-applied security device and at least one other security device, such as an embedded or partially embedded security device or security feature. Surface-applied security features may be registered with other features of the document, such as other security features or security or decorative features.
适用于本发明的纤维片材是纸或纸状片材。为单层或多层片材的这些片材可由包括合成或天然纤维或两者的混合物的一系列纤维类型制成。例如,这些片材可由纤维诸如蕉麻、棉、亚麻、木浆以及它们的共混物制成。如本领域技术人员所公知的,棉和棉/亚麻或棉/合成纤维共混物优选地用于纸币,而木浆通常用于非纸币安全文件。Fibrous sheets suitable for use in the present invention are paper or paper-like sheets. These sheets, which are single-layer or multi-layer sheets, can be made from a range of fiber types including synthetic or natural fibers or mixtures of both. For example, these sheets can be made from fibers such as abaca, cotton, flax, wood pulp, and blends thereof. As known to those skilled in the art, cotton and cotton/linen or cotton/synthetic fiber blends are preferably used for banknotes, while wood pulp is typically used for non-banknote security documents.
如上所述,设想与本发明一起使用的安全装置可采取多种不同形式,包括但不限于条、带、线、丝带或贴片(例如,基于微透镜的、全息的和/或色移安全线)。As noted above, it is contemplated that security devices for use with the present invention may take many different forms, including but not limited to strips, tapes, threads, ribbons, or patches (eg, microlens-based, holographic, and/or color-shifting security Wire).
通过以下对代表示例性实施方案的附图的描述,将有助于进一步理解所要求保护的发明。A further understanding of the claimed invention will be facilitated by the following description of the accompanying drawings, which represent exemplary embodiments.
图1和图2中描绘了常规技术。通常,如图1所示,安全装置(11) 在造纸的湿阶段被引入,以将装置(11)嵌入纤维片材或文件(10)中。当使用该方法表面施加安全装置时,所得的纤维片材遭受低的流通耐久性、差的CD拉伸强度和高的背面透印。如本文其他地方所提到的,已经发现这是部分由于当将安全装置(11)引入成形纤维幅材时纤维 (15)从子区域(12)移位引起的。可以看出,铰链区域(14)中的纤维量显著减少。这导致在安全装置与纤维片材或文件(10)的基底(18)之间的界面(17)处的弱相互作用。这在界面边缘(17a)处尤为明显。Conventional techniques are depicted in FIGS. 1 and 2 . Typically, as shown in Figure 1, a security device (11) is introduced during the wet stage of papermaking to embed the device (11) in a fibrous sheet or document (10). When the security device is surface applied using this method, the resulting fibrous sheet suffers from low flow-through durability, poor CD tensile strength, and high backside print-through. As mentioned elsewhere herein, it has been found that this is partly due to the displacement of the fibers (15) from the sub-regions (12) when the safety device (11) is introduced into the forming fiber web. As can be seen, the amount of fibers in the hinge region (14) is significantly reduced. This results in a weak interaction at the interface (17) between the security device and the substrate (18) of the fibrous sheet or document (10). This is especially noticeable at the interface edge (17a).
在图2所示的常规实施方案中也发现了缺点,其中安全装置(21) 在造纸的干燥阶段或在纸完全固结的造纸阶段之后被引入。此处,子区域(22)中的纤维(25)如此充分地固结,使得安全装置(21)不能被压入到基底(28)中。结果,厚度差很高。高厚度差已经与在片材或文件(20) 上油墨的不良施加有关。结果,对于其中在干燥阶段添加安全装置的实施方案,安全装置必须非常薄以便具有合适的厚度差。Disadvantages are also found in the conventional embodiment shown in Figure 2, where the safety device (21) is introduced during the drying stage of the papermaking or after the papermaking stage where the paper is fully consolidated. Here, the fibers ( 25 ) in the sub-regions ( 22 ) are so sufficiently consolidated that the safety device ( 21 ) cannot be pressed into the substrate ( 28 ). As a result, the thickness difference is high. High thickness differences have been associated with poor application of ink on the sheet or document (20). As a result, for embodiments in which the safety device is added during the drying stage, the safety device must be very thin in order to have a suitable thickness difference.
本发明解决了这些缺点中的至少一个。图3描绘了本发明的一个实施方案。此处,与图1和图2不同,安全装置(31)在湿阶段纤维在幅材充分固结时被引入,使得当安全装置被压入到纤维片材(30)的基底(38)中时,显著量的纤维(35)不从子区域(32)移位。相反,纤维(35) 在安全装置(31)下方和在铰链区域(34)中进一步固结或压实。这导致在界面(37)处并且特别是在界面边缘(37a)处的强纤维相互作用。此外,由于安全装置(31)在湿阶段期间被引入,因此它可被压入到基底 (38)中以提供低的厚度差。The present invention addresses at least one of these disadvantages. Figure 3 depicts one embodiment of the present invention. Here, unlike Figures 1 and 2, the safety device (31) is introduced during the wet phase when the fibers are sufficiently consolidated in the web, so that when the safety device is pressed into the base (38) of the fiber sheet (30) , a significant amount of fibers (35) are not displaced from the sub-regions (32). Instead, the fibers (35) are further consolidated or compacted below the safety device (31) and in the hinge area (34). This results in strong fiber interactions at the interface (37) and especially at the interface edge (37a). Furthermore, since the safety device (31) is introduced during the wet phase, it can be pressed into the substrate (38) to provide a low thickness difference.
可使用各种方法和技术来将安全装置(41)引入纤维幅材(49)。在图4所示的优选实施方案中,安全装置(41)以连续幅材的形式呈现,并且在长网造纸机(40)上紧接湿作业线(42)之后且在伏辊(44)之前并且在真空箱(45a、45b)之间被连续地施加到成形纤维幅材(49),这些真空箱有助于将安全装置设置到纤维幅材(49)中。Various methods and techniques can be used to introduce the safety device (41) into the fibrous web (49). In the preferred embodiment shown in Figure 4, the safety device (41) is presented in the form of a continuous web and is located on the Fourdrinier machine (40) immediately after the wet line (42) and after the couch roll (44) It is applied to the forming fibrous web (49) before and continuously between vacuum boxes (45a, 45b) which assist in the placement of safety devices into the fibrous web (49).
图5和图6描绘了具有多个表面施加的安全装置(52a、52b、53、 63a、63b)的本发明的纤维片材或所得文件(50、60)。装置(52a、52b、 53、63a、63b)在此处以不同尺寸和形状的贴片(53、63a、63b)和条(52a、 52b)的形式呈现。虽然在安全装置(52a、52b、53、63a、63b)的放置位置方面不限于此,但在本发明的一个实施方案中,安全装置(例如 53、63a、63b)在造纸期间通过引入装置(未示出)被切割或冲压并且施加到纤维幅材(55),使得其与纤维幅材、纤维片材或所得文件(60)中的至少一个其他特征(例如水印(61))配准。图6描绘了其中作为贴片 (63a、63b)施加的多个安全装置与水印(61)配准地施加的实施方案。第一贴片(63a)以与水印(61)横向配准的方式施加,而第二贴片(63b) 以与水印(61)纵向配准的方式施加。还设想安全装置(63a、63b)与水印(61)对准,使得贴片(63a、63b)中的至少一个特征(未示出)与水印(61) 或者纤维幅材、纤维片材或所得文件(60)中的其他特征配准。文件(50、 60)具有边缘(59、69),尽管此处将其描绘为平行四边形的边,但也可以具有其他角度的其他形状来描绘。安全装置(52a、52b、53、63a、 63b)被施加到纤维幅材、纤维片材或文件使得其不延伸超过文件(50、 60)的边缘(59、69)。在优选的实施方案中,安全装置设置在表面上,使得其远离边缘定位而不接触。Figures 5 and 6 depict fibrous sheets or resulting documents (50, 60) of the present invention with multiple surface-applied security devices (52a, 52b, 53, 63a, 63b). The devices (52a, 52b, 53, 63a, 63b) are here presented in the form of patches (53, 63a, 63b) and strips (52a, 52b) of different sizes and shapes. Although not limited in terms of the placement position of the safety devices (52a, 52b, 53, 63a, 63b), in one embodiment of the present invention, the safety devices (
实施例Example
比较例1:在纤维幅材未充分固结时表面施加的安全装置的单个循环耐久性测试Comparative Example 1 : Single Cycle Durability Testing of Surface Applied Safety Devices When the Fiber Web is Inadequately Consolidated
在第一比较例中,根据常规湿阶段过程制造纤维片材,其中在造纸过程期间在纤维幅材中的水和/或水分含量大于98%时将安全装置引入纤维幅材。作为纤维移位的结果,铰链区域(74)和子区域中的纤维发生移位,从而导致安全装置(71)与纤维片材(70)的纤维基底(78) 在这些区域中的相互作用减小。根据该过程形成的纤维片材(70)在通过流通模拟测试的单个循环(30min)之后示于图7A中。作为该单个循环的结果,纤维片材(70)表现出差的耐久性,至少如由铰链区域(74) 中所示的铰链效应的发展所定义的。安全装置(71)在沿着界面边缘 (77a)的点处从纤维片材(70)的基底(78)分离。In a first comparative example, the fibrous sheet was produced according to a conventional wet stage process in which a safety device was introduced into the fibrous web when the water and/or moisture content in the fibrous web was greater than 98% during the papermaking process. As a result of the fiber displacement, the fibers in the hinge region (74) and sub-regions are displaced, resulting in a reduced interaction of the safety device (71) with the fiber base (78) of the fiber sheet (70) in these regions . A fibrous sheet (70) formed according to this process is shown in Figure 7A after passing a single cycle (30 min) of the flow-through simulation test. As a result of this single cycle, the fiber sheet (70) exhibits poor durability, at least as defined by the development of the hinge effect shown in the hinge region (74). The safety device (71) separates from the base (78) of the fibrous sheet (70) at points along the interface edge (77a).
此外,表面施加的安全装置表现出背面透印。要求一组五(5)人 (P1、P2、P3、P4、P5)从1到5评定背面透印的程度,其中5具有最高透印,并且1具有最低透印。小组成员P1和P4将背面透印评定为 4;小组成员P2、P3和P5将背面透印评定为5。图7B描绘了显示背面透印的纤维片材(70)。这将需要某种背面伪装涂层来解决这个问题。Additionally, surface-applied security devices exhibit backside print-through. A group of five (5) people (P1, P2, P3, P4, P5) were asked to rate the degree of backside blow-through on a scale from 1 to 5, with 5 having the highest blow-through and 1 having the lowest blow-through. Panelists P1 and P4 rated backside blow-through as 4; panelists P2, P3, and P5 rated backside blow-through as 5. Figure 7B depicts a fibrous sheet (70) showing back print through. This will require some kind of backside camouflage coating to fix that.
还使用5965型张力测试仪测量纤维片材的横向(CD) 拉伸强度。将纸样品切割成125mm宽×15mm高的维度,使线垂直穿过样品的中心。然后将样品放入Instron(5965型)张力测试仪的钳口中,钳口之间的设定间距为40mm,并且使线在间隙中居中。然后将样品以38毫米/分钟的速率拉伸,直到样品断裂。重复此过程5次,这5个值的平均值是测试的报告结果。结果表明,CD拉伸强度在5.4 kg至6.3kg的范围内。Also use Type 5965 The Tensile Tester measures the cross-direction (CD) tensile strength of fibrous sheets. The paper sample was cut to a dimension of 125mm wide x 15mm high with the line running vertically through the center of the sample. The sample was then placed into the jaws of an Instron (Model 5965) tensile tester with a set spacing of 40mm between the jaws and the wire centered in the gap. The sample was then stretched at a rate of 38 mm/min until the sample broke. Repeat this process 5 times and the average of these 5 values is the reported result of the test. The results showed that the CD tensile strength was in the range of 5.4 kg to 6.3 kg.
发明例1:在纤维幅材充分固结时表面施加的安全装置的单个循环耐久性测试Invention Example 1: Single Cycle Durability Testing of Surface-Applied Safety Devices When Fiber Webs Are Fully Consolidated
在第一发明例中,根据本文所公开的本发明制造纤维片材(80),其中在造纸过程期间在纤维幅材的水分含量小于98%时将安全装置 (81)引入纤维幅材。作为从铰链区域减少的纤维移位和子区域中增加的纤维固结的结果,安全装置(81)与纤维片材(80)的基底(88)存在充分的相互作用。根据该过程形成的纤维片材(80)在通过流通模拟测试的单个循环之后示于图8A中。显然,相对于比较例1中产生的材料,纤维片材(80)具有改善的耐久性。此处,纤维片材(80)沿着安全装置(81) 的界面边缘(87a)与纤维片材(80)的基底(88)没有显示出铰链效应并且没有损坏或分离。纤维片材(80)保持完整,表现出耐久性得到改善。In a first inventive example, a fibrous sheet (80) is made according to the invention disclosed herein, wherein a safety device (81) is introduced into the fibrous web during the papermaking process when the moisture content of the fibrous web is less than 98%. There is sufficient interaction of the safety device (81) with the base (88) of the fiber sheet (80) as a result of reduced fiber displacement from the hinge region and increased fiber consolidation in the sub-regions. A fibrous sheet (80) formed according to this process is shown in Figure 8A after passing a single cycle of the flow-through simulation test. Clearly, the fibrous sheet (80) has improved durability relative to the material produced in Comparative Example 1 . Here, the fiber sheet (80) exhibits no hinge effect and is not damaged or separated from the base (88) of the fiber sheet (80) along the interface edge (87a) of the safety device (81). The fibrous sheet (80) remains intact, showing improved durability.
此外,与比较例1相比,表面施加的安全装置(81)表现出较少的背面透印。要求一组五(5)人(P1、P2、P3、P4、P5)从1到5评定背面透印的程度,其中5具有最高透印,并且1具有最低透印。小组成员 P2将背面透印评定为1;小组成员P1、P3、P4和P5将背面透印评定为2。图8B描绘了显示背面透印的纤维片材。另选地,背面透印通过测量跨线灰度密度来表征。在已经使用IT8参考靶标校准的 Epson V750 Perfection平板扫描仪上扫描纸样品。以600dpi扫描纸,作为反射光中的灰度图像,在样品后面具有黑色背景。一旦扫描被捕获,就生成选定区域的密度分布。利用该功能,我们选择跨线的区域,其中软件捕获选定区域中的每个像素的灰度值,对于该特定测试,其中线垂直地穿过选定区域的中心,软件对区域内的垂直像素求平均,并且报告每个水平像素的垂直平均数据点(例如,如果区域为20像素高乘200像素宽,则对于每个水平位置,对应的垂直像素值将被求平均并且将导致200个数据点的输出)。然后将所得数据绘制成图以显示在采样区域内的灰度值中是否存在任何明显的移位。密度测量结果提供在表1中。本发明例的结果由顶部线提供,而比较例的结果提供在底部线中,指示当测量装置横穿安全装置的相对侧时纤维密度测量中的显著下降。较低的值指示高的背面透印。可以看出,利用本发明的方法(<90%水和/或水分),纤维片材上的密度值保持相对恒定,而对于比较例(>98%水和/或水分),密度值在数值上具有公认且显著的降低。对于比较例(>98%水),平均跨线灰度密度为214;而对于本发明例(<90%水),平均跨线灰度密度为226。Furthermore, compared to Comparative Example 1, the surface-applied security device (81) exhibited less backside print-through. A group of five (5) people (P1, P2, P3, P4, P5) were asked to rate the degree of backside blow-through on a scale from 1 to 5, with 5 having the highest blow-through and 1 having the lowest blow-through. Panelist P2 rated backside blow-through as 1; panelists P1, P3, P4, and P5 rated backside blow-through as 2. Figure 8B depicts a fibrous sheet showing back print through. Alternatively, backside print-through is characterized by measuring across-line grayscale density. The paper samples were scanned on an Epson V750 Perfection flatbed scanner that had been calibrated using the IT8 reference target. The paper was scanned at 600 dpi as a grayscale image in reflected light with a black background behind the sample. Once the scan is captured, a density distribution of the selected area is generated. Using this function, we select regions across the line, where the software captures the gray value of each pixel in the selected region, and for this particular test, where the line runs vertically through the center of the selected region, the software The pixels are averaged, and the vertically averaged data points are reported for each horizontal pixel (for example, if the area is 20 pixels high by 200 pixels wide, for each horizontal position, the corresponding vertical pixel values will be averaged and will result in 200 output of data points). The resulting data is then plotted to show whether there are any significant shifts in the grayscale values within the sampled area. Density measurements are provided in Table 1. The Inventive Example results are provided in the top line, while the Comparative Example results are provided in the bottom line, indicating a significant drop in fiber density measurement as the measurement device traverses the opposite side of the safety device. Lower values indicate high backside blow-through. It can be seen that with the method of the invention (<90% water and/or moisture) the density values on the fibrous sheet remain relatively constant, whereas for the comparative example (>98% water and/or moisture) the density values are in the numerical value There is a well-recognized and significant reduction in . For the comparative example (>98% water), the average grayscale density across the line was 214; while for the inventive example (<90% water), the average grayscale density across the line was 226.
使用5965型张力测试仪还测量了纤维片材(80)的横向(CD)拉伸强度。此处重复与上述相同的过程。结果表明,CD拉伸强度优于对比例1中所显示的。比较例的结果被描绘为表2中的第一条(>98%水),而本发明例的结果(<90%水)被描绘为表2中的第二条。Use Type 5965 The tensile tester also measured the cross direction (CD) tensile strength of the fibrous sheet (80). The same process as above is repeated here. The results show that the CD tensile strength is better than that shown in Comparative Example 1. The results for the Comparative Examples are depicted as the first bar in Table 2 (>98% water), while the results for the Inventive Examples (<90% water) are depicted as the second bar in Table 2.
跨线灰度密度测量Gray Density Measurements Across Lines
表1Table 1
CD拉伸强度的平均增加为25%Average increase in CD tensile strength of 25%
表2Table 2
比较例2:在纤维幅材未充分固结时表面施加的安全装置的三个循环耐久性测试Comparative Example 2: Three-Cycle Durability Testing of Surface-Applied Safety Devices When the Fiber Web is Inadequately Consolidated
在第二比较例中,根据常规湿阶段过程制造纤维片材(90),其中在造纸过程期间在纤维幅材中的水和/或水分含量大于98%时将安全装置引入纤维幅材。作为纤维移位的结果,铰链区域和子区域中的纤维在安全装置(91)的引入期间发生移位,从而导致安全装置(91)与纤维片材(90)的基底(98)在这些区域中的相互作用减小。根据该过程形成的纤维片材(90)在通过流通模拟测试的三个循环之后示于图9A中。作为这些三个循环的结果,纤维片材(90)表现出差的耐久性,至少由片材中沿着界面边缘(97a)的撕裂的发展所定义的。纤维片材(90)沿着界面边缘(97a)被撕成两片。In a second comparative example, the fibrous sheet (90) was manufactured according to a conventional wet stage process in which a safety device was introduced into the fibrous web when the water and/or moisture content in the fibrous web was greater than 98% during the papermaking process. As a result of the fiber displacement, the fibers in the hinge region and sub-regions are displaced during the introduction of the safety device (91), resulting in the safety device (91) and the base (98) of the fiber sheet (90) in these regions interaction is reduced. A fibrous sheet (90) formed according to this process is shown in Figure 9A after passing three cycles of the flow-through simulation test. As a result of these three cycles, the fibrous sheet (90) exhibited poor durability, at least as defined by the development of tears in the sheet along the interface edge (97a). The fiber sheet (90) is torn into two pieces along the interface edge (97a).
此外,表面施加的安全装置(91)表现出背面透印。要求一组五(5) 人(P1、P2、P3、P4、P5)从1到5评定背面透印的程度,其中5具有最高透印,并且1具有最低透印。小组成员P1和P5将背面透印评定为5;小组成员P2、P3和P4将背面透印评定为4。图9B描绘了显示撕裂和背面透印的纤维片材(90)。这将需要某种背面伪装涂层来解决这个问题。In addition, the surface applied security device (91) exhibits backside print-through. A group of five (5) people (P1, P2, P3, P4, P5) were asked to rate the degree of backside blow-through from 1 to 5, with 5 having the highest blow-through and 1 having the lowest blow-through. Panelists P1 and P5 rated backside blow-through as 5; panelists P2, P3 and P4 rated backside blow-through as 4. Figure 9B depicts a fibrous sheet (90) showing tearing and back print through. This will require some kind of backside camouflage coating to fix that.
发明例2:在纤维幅材充分固结时表面施加的安全装置的三个循环耐久性测试Invention Example 2: Three Cycle Durability Testing of Surface-Applied Safety Devices When the Fiber Web is Fully Consolidated
在第二发明例中,根据本文所公开的本发明制造纤维片材(100),其中在造纸过程期间在纤维幅材的水分含量小于98%时将安全装置 (101)引入纤维幅材。相对于比较例1中的情况,作为从铰链区域减少的纤维移位和子区域中增加的纤维固结的结果,安全装置与纤维片材 (100)的基底(108)存在充分的相互作用。根据该过程形成的纤维片材 (100)在通过流通模拟测试的三个循环之后示于图10A中。显然,相对于比较例2中产生的材料,纤维片材(100)具有改善的耐久性。此处,纤维片材(100)沿着安全装置(101)的界面边缘(107a)与纤维片材(100) 的基底(108)显示很少至没有铰链效应或损坏。纤维片材(100)保持完整,表现出耐久性得到改善。In a second inventive example, a fibrous sheet (100) is made according to the invention disclosed herein, wherein a safety device (101) is introduced into the fibrous web during the papermaking process when the moisture content of the fibrous web is less than 98%. Relative to the situation in Comparative Example 1, there is sufficient interaction of the safety device with the base (108) of the fiber sheet (100) as a result of reduced fiber displacement from the hinge region and increased fiber consolidation in the sub-region. The fibrous sheet (100) formed according to this process is shown in Figure 10A after passing three cycles of the flow-through simulation test. Clearly, the fibrous sheet (100) has improved durability relative to the material produced in Comparative Example 2. Here, the fiber sheet (100) exhibits little to no hinge effect or damage along the interface edge (107a) of the safety device (101) with the base (108) of the fiber sheet (100). The fibrous sheet (100) remains intact, showing improved durability.
此外,与比较例2相比,表面施加的安全装置(101)表现出较少的背面透印。要求一组五(5)人(P1、P2、P3、P4、P5)从1到5评定背面透印的程度,其中5具有最高透印,并且1具有最低透印。小组成员 P1将背面透印评定为2;P2、P4和P5将背面透印评定为1;并且小组成员P3将背面透印评定为3。图10B描绘了显示改善的背面透印的纤维片材。Furthermore, compared to Comparative Example 2, the surface-applied security device (101) exhibited less backside print-through. A group of five (5) people (P1, P2, P3, P4, P5) were asked to rate the degree of backside blow-through on a scale from 1 to 5, with 5 having the highest blow-through and 1 having the lowest blow-through. Panelist P1 rated backside blow-through as 2; P2, P4, and P5 rated backside blow-through as 1; and panelist P3 rated backside blow-through as 3. Figure 10B depicts a fibrous sheet showing improved backside print-through.
图11描绘了本发明第二方面的一个实施方案。此处,纤维片材用附图标记110标记。在造纸的湿阶段在纤维片材(110)变得充分固结之前,在纤维片材(110)中形成“软边”通孔(111)。然后,在纤维片材充分固结时将安全装置(112)引入到通孔(111)上方,使得当安全装置被压入到纤维片材(110)的基底(115)中时,显著量的纤维(113)不从子区域(114)移位。相反,纤维(113)在安全装置(112)下方在界定通孔(111) 的子区域(114)中并且在铰链区域(116)中被进一步固结或压实。这导致在界面(117)处并且特别是在界面边缘(117a)处的强纤维相互作用。此外,由于安全装置(112)在湿阶段期间被引入,因此它可被压入到基底(115)中以提供低的厚度差。此外,由于在该状态下纤维未发生移位,因此在子区域(114)中的进一步固结极大地降低(如果不是消除)通孔 (111)被堵塞或阻塞的可能性。Figure 11 depicts an embodiment of the second aspect of the invention. Here, the fiber sheet is designated with
如上所述,可使用各种方法和技术将通孔(111)和安全装置(112) 引入纤维片材(110)。特别地,造纸机的筛网可以是长网造纸机的连续移动成形网或圆网造纸机的圆网。在图12、图12A、图12B所示的优选实施方案中,在设置有至少一个不透水元件120的长网造纸机 119上使用图案化成形网118形成通孔111,该不透水元件防止在该区域中形成片材。描绘了在将造纸原料从流浆箱排出到成形网上之前 (图12A)和之后(图12B)的图案化成形网(118)。如图12B所示,在不透水元件(120)的区域中防止片材形成。在形成通孔(111)并且纤维片材(110)变得充分固结之后,安全装置(112)以连续幅材的形式呈现并且紧接在湿作业线(122)之后且伏辊(123)之前并且在真空箱(124a、 124b)之间被连续地施加到形成纤维片材(110),这些真空箱有助于将安全装置设置到纤维片材(110)中。As mentioned above, various methods and techniques can be used to introduce through holes (111) and safety devices (112) into the fiber sheet (110). In particular, the screen of a paper machine may be a continuously moving forming wire of a Fourdrinier wire machine or a cylinder wire of a rotary wire machine. In the preferred embodiment shown in Figures 12, 12A, 12B, the through
尽管上面已经描述了本发明的各种实施方案,但应当理解,它们仅以举例的方式给出而非进行限制。因此,本发明的广度和范围不应受到任何示例性实施方案的限制。While various embodiments of the present invention have been described above, it should be understood that they have been presented by way of example only, and not limitation. Therefore, the breadth and scope of the present invention should not be limited by any of the exemplary embodiments.
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2018
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- 2018-12-14 EP EP18888658.4A patent/EP3723996A4/en active Pending
- 2018-12-14 CN CN201880080558.1A patent/CN111511572B/en active Active
- 2018-12-14 JP JP2020532047A patent/JP2021506622A/en active Pending
- 2018-12-14 WO PCT/US2018/065807 patent/WO2019118904A1/en not_active Ceased
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2023
- 2023-05-15 JP JP2023080271A patent/JP2023106485A/en active Pending
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2023106485A (en) | 2023-08-01 |
| WO2019118904A1 (en) | 2019-06-20 |
| RU2020123078A (en) | 2022-01-14 |
| KR20200096544A (en) | 2020-08-12 |
| JP2021506622A (en) | 2021-02-22 |
| KR102665889B1 (en) | 2024-05-13 |
| EP3723996A1 (en) | 2020-10-21 |
| RU2020123078A3 (en) | 2022-01-14 |
| EP3723996A4 (en) | 2021-07-21 |
| CN111511572A (en) | 2020-08-07 |
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