CN111498937A - Multi-channel shallow air flotation process and equipment - Google Patents
Multi-channel shallow air flotation process and equipment Download PDFInfo
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- 238000005188 flotation Methods 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 18
- 230000008569 process Effects 0.000 title claims abstract description 11
- 239000012528 membrane Substances 0.000 claims abstract description 57
- 239000000919 ceramic Substances 0.000 claims abstract description 54
- 239000002101 nanobubble Substances 0.000 claims abstract description 11
- 239000010865 sewage Substances 0.000 claims abstract description 11
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 239000002893 slag Substances 0.000 claims description 14
- 238000007790 scraping Methods 0.000 claims description 11
- 238000007789 sealing Methods 0.000 claims description 6
- 238000002627 tracheal intubation Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 abstract description 12
- 238000007667 floating Methods 0.000 abstract description 9
- 238000000926 separation method Methods 0.000 abstract description 8
- 238000012423 maintenance Methods 0.000 abstract description 5
- 238000005265 energy consumption Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 8
- 239000002245 particle Substances 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000005273 aeration Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/023—Reactive oxygen species, singlet oxygen, OH radical
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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Abstract
本发明公开了多通道浅层气浮工艺及设备,涉及污水处理领域,为达到上述目的,本发明的技术方案:向待处理污水内加入空气,该空气通过倾斜的微纳米功能陶瓷膜生成大量微纳米气泡,这些微纳米气泡上浮过程中将杂质带到液面。具有能耗低、分离效率高、可去除有机物、运行成本低、投资低、维护简单的特点。
The invention discloses a multi-channel shallow-layer air flotation process and equipment, and relates to the field of sewage treatment. In order to achieve the above purpose, the technical scheme of the invention: add air into the sewage to be treated, and the air generates a large amount of air through the inclined micro-nano functional ceramic membrane Micro-nano bubbles, these micro-nano bubbles bring impurities to the liquid surface during the floating process. It has the characteristics of low energy consumption, high separation efficiency, organic removal, low operating cost, low investment and simple maintenance.
Description
技术领域technical field
本发明涉及一种多通道浅层气浮工艺及设备,主要涉及污水处理领域。The invention relates to a multi-channel shallow air flotation process and equipment, and mainly relates to the field of sewage treatment.
背景技术Background technique
气浮是一种重要的水处理技术,通过专用设备在水中形成高度分散的微小气泡,这些气泡粘附于废水中疏水性的固体或液体颗粒,形成表观密度小于水的絮体而上浮到水面,所形成的浮渣层被刮除,从而实现固液或者液液分离的目的。Air flotation is an important water treatment technology, which forms highly dispersed tiny air bubbles in the water through special equipment. These air bubbles adhere to the hydrophobic solid or liquid particles in the wastewater to form flocs with an apparent density less than water and float to the surface. On the water surface, the formed scum layer is scraped off, so as to achieve the purpose of solid-liquid or liquid-liquid separation.
气浮目前在给水、工业废水和城市污水处理等方面都有应用,其优点在于它固-液分离设备具有投资少、占地面积小、自动化程度高、操作管理方便等特点。Air flotation is currently used in water supply, industrial wastewater and urban sewage treatment.
气泡粘附于固液表面的絮体一般采用自然上浮和刮渣相结合的方式去除,由于气浮池较深,自然上浮速度较慢,造成气浮分离的效率受限,如采用较小的气泡会造成停留时间延长,效率下降等问题。The flocs with bubbles adhering to the solid-liquid surface are generally removed by a combination of natural floating and slag scraping. Because the air flotation tank is deep and the natural floating speed is slow, the efficiency of air flotation separation is limited. For example, the use of smaller bubbles It will cause problems such as prolonged residence time and reduced efficiency.
气浮产生微气泡的方法,常用的有曝气法和溶气法两种。曝气法又称分散空气法,通常是在气浮池的底部设置微孔扩散板或扩散管,压缩空气从板面或管面以微小气泡形式逸出于水中,这种方法产生的气泡通常较大,气浮效果不好。溶气法通常是指溶解在水中的气体,在水面气压降低时就可以从水中逸出,常用的设备有加压泵、溶气罐、空气压缩机、减压阀等,设备维护管理较复杂。There are two commonly used methods for air flotation to generate microbubbles: aeration method and dissolved air method. The aeration method, also known as the dispersed air method, usually sets a microporous diffuser plate or a diffuser tube at the bottom of the air flotation tank, and the compressed air escapes from the surface of the plate or the tube surface in the form of tiny bubbles. Large, the air flotation effect is not good. Dissolved gas method usually refers to the gas dissolved in water, which can escape from the water when the pressure on the water surface decreases. Commonly used equipment includes pressurized pump, dissolved gas tank, air compressor, pressure reducing valve, etc., equipment maintenance and management are more complicated .
发明内容SUMMARY OF THE INVENTION
针对以上现有技术的不足,根据浅层沉淀原理,本发明提出一种多通道浅层气浮设备,具有能耗低、分离效率高、可去除有机物、运行成本低、投资低、维护简单的特点。In view of the above shortcomings of the prior art, according to the principle of shallow sedimentation, the present invention proposes a multi-channel shallow air flotation device, which has the advantages of low energy consumption, high separation efficiency, organic removal, low operating cost, low investment and simple maintenance. Features.
为达到上述目的,本发明的技术方案是:向待处理污水内加入空气,该空气通过倾斜的微纳米功能陶瓷膜生成大量微纳米气泡,这些微纳米气泡上浮过程中将杂质带到液面。In order to achieve the above object, the technical scheme of the present invention is: adding air into the sewage to be treated, the air generates a large number of micro-nano bubbles through the inclined micro-nano functional ceramic membrane, and the impurities are brought to the liquid surface during the floating process of these micro-nano bubbles.
本发明的技术原理及有益效果如下:The technical principle and beneficial effects of the present invention are as follows:
通过微纳米功能陶瓷膜将空气微纳米化,所产生的微气泡直径可达到微纳米级,在同样条件下,接触面积、传质面积和传质效率可大幅提高;同时纳米功能膜能产生一定浓度的羟基自由基,强化微气泡氧化效果。The air is micro-nano through the micro-nano functional ceramic membrane, and the diameter of the generated micro-bubble can reach the micro-nano level. Under the same conditions, the contact area, mass transfer area and mass transfer efficiency can be greatly improved; at the same time, the nano-functional membrane can produce a certain amount of The concentration of hydroxyl radicals strengthens the oxidation effect of micro-bubble.
多通道浅层气浮设备,包括气浮池、支架和若干微纳米功能陶瓷膜;所述支架设置于所述气浮池内,若干所述微纳米功能陶瓷膜自上向下依次分布于所述支架,所述微纳米功能陶瓷膜的一端固定于所述支架上,所述微纳米功能陶瓷膜的另一端向上倾斜设置;所述支架内置有气流通道,所述气流通道外接供气装置,所述气流通道的侧壁设有若干排气孔,在所述微纳米功能陶瓷膜(3)的内孔与所述气流通道的内端连通。A multi-channel shallow air flotation device, including an air flotation tank, a bracket and a number of micro-nano functional ceramic membranes; the bracket is arranged in the air flotation tank, and a number of the micro-nano functional ceramic membranes are sequentially distributed on the bracket from top to bottom , one end of the micro-nano functional ceramic membrane is fixed on the bracket, and the other end of the micro-nano functional ceramic membrane is inclined upward; the bracket has a built-in airflow channel, the airflow channel is connected to an external air supply device, and the The side wall of the airflow channel is provided with a plurality of exhaust holes, and the inner hole of the micro-nano functional ceramic membrane (3) communicates with the inner end of the airflow channel.
通过支架向内部充入空气,空气气泡在浮力的作用下向上浮动,气泡浮动的过程中与微纳米功能陶瓷膜接触,微纳米功能陶瓷膜将注入的空气形成微纳米的气泡,被微纳米化的气泡将具有更大的接触面积和传质面积,更高的传质效率,并且纳米功能膜能产生一定浓度的羟基自由基,强化微气泡氧化效果。产生的微纳米化的空气气泡与水中颗粒物粘附,并与水分离,将颗粒物杂质更高效率的与水分离。具有能耗低、分离效率高、可去除有机物、运行成本低、投资低、维护简单的特点。Air is filled into the interior through the bracket, and the air bubbles float upward under the action of buoyancy. During the floating process of the bubbles, they contact the micro-nano functional ceramic membrane. The micro-nano functional ceramic membrane will form the injected air into micro-nano bubbles, which are micronized. The micro-bubble will have a larger contact area and mass transfer area, higher mass transfer efficiency, and the nano-functional film can generate a certain concentration of hydroxyl radicals to strengthen the oxidation effect of micro-bubble. The generated micro-nano air bubbles adhere to the particles in the water and separate from the water, separating the particles and impurities from the water more efficiently. It has the characteristics of low energy consumption, high separation efficiency, organic removal, low operating cost, low investment and simple maintenance.
优选的,所述微纳米功能陶瓷膜一端封堵,另一端设有气腔,所述气腔与所述微纳米陶瓷膜分别连通,所述气腔设有插管,所述插管插接至所述排气孔。空气通过插管进入到气腔,然后通过气腔分流进入到微纳米功能陶瓷膜各个内孔,然后通过微纳米陶瓷膜的微孔进入到液体中,此时空气已被微纳米化。Preferably, one end of the micro-nano functional ceramic membrane is blocked, and the other end is provided with an air cavity, the air cavity is respectively connected with the micro-nano ceramic membrane, the air cavity is provided with an intubation tube, and the intubation tube is inserted and connected to the vent hole. The air enters the air cavity through the cannula, and then flows into each inner hole of the micro-nano functional ceramic membrane through the air cavity, and then enters the liquid through the micro-pores of the micro-nano ceramic membrane. At this time, the air has been micro-nanoified.
优选的,所述支架为竖直设置的墙体,所述微纳米功能陶瓷膜固定于所述墙体的两侧,采用墙体结构的支架,整体强度更高。Preferably, the bracket is a vertically arranged wall, the micro-nano functional ceramic membrane is fixed on both sides of the wall, and a bracket with a wall structure is adopted, and the overall strength is higher.
优选地,所述微纳米功能陶瓷膜的另一端端部向上竖直延伸有封口段,所述封口段的上端与上一层的所述微纳米功能陶瓷膜之间留设有排渣口,通过以上行程一个仓室的结构,污水在内部可以更好的与微纳米化的气泡接触。Preferably, a sealing section extends vertically upward at the other end of the micro-nano functional ceramic membrane, and a slag discharge port is left between the upper end of the sealing section and the upper layer of the micro-nano functional ceramic membrane, Through the structure of one chamber in the above stroke, the sewage can better contact the micro-nano bubbles inside.
优选地,所述支架上方的所述气浮池内设有刮渣装置,便于对漂浮在液面的浮渣进行清理。Preferably, the air flotation tank above the support is provided with a slag scraping device, which is convenient for cleaning the scum floating on the liquid surface.
优选地,所述刮渣装置包括螺杆、导向杆和刮板;所述螺杆和导向杆水平并列设置,所述螺杆两端与所述气浮池转动配合,所述导向杆的两端与所述起伏池固定设置,所述刮板对应所述螺杆设有螺孔,所述螺孔与所述螺杆螺纹配合,所述刮板对应所述导向杆设有通孔,所述通孔与所述导向杆滑动配合,通过转动螺杆即可驱动刮板在导向杆上滑动,来回驱动刮板,即可实现对浮渣的清理。Preferably, the slag scraping device includes a screw rod, a guide rod and a scraper; the screw rod and the guide rod are arranged horizontally side by side, the two ends of the screw rod rotate and cooperate with the air flotation tank, and the two ends of the guide rod are connected with the air flotation tank. The undulating pool is fixedly arranged, the scraper is provided with a screw hole corresponding to the screw, the screw hole is threaded with the screw, the scraper is provided with a through hole corresponding to the guide rod, and the through hole is connected with the screw. The guide rod is slidingly matched, and the scraper can be driven to slide on the guide rod by rotating the screw, and the scum can be cleaned by driving the scraper back and forth.
优选地,所述螺杆的两侧分别设有一导向杆,通过两侧分别设置,可以使螺杆对刮板驱动的力更加均衡。Preferably, the two sides of the screw rod are respectively provided with a guide rod, and by setting the two sides respectively, the driving force of the screw rod on the scraper can be more balanced.
优选地,所述刮板的下沿设有若干刮齿,便于在带动浮渣移动的时候,污水在下方流走,可以更好的将液体与浮渣分离。Preferably, the lower edge of the scraper is provided with a number of scraping teeth, so that when the scum is driven to move, the sewage flows away from the bottom, and the liquid and the scum can be better separated.
附图说明Description of drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的其中三幅,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to illustrate the embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings used in the description of the embodiments. Obviously, the drawings in the following description are only for the present invention. For three of the drawings, for those of ordinary skill in the art, other drawings can also be obtained from these drawings without any creative effort.
图1为本发明实施例的结构示意图;1 is a schematic structural diagram of an embodiment of the present invention;
图2为图1的A局部放大图;Fig. 2 is a partial enlarged view of A of Fig. 1;
图3为微纳米陶瓷膜的结构示意图;Figure 3 is a schematic structural diagram of a micro-nano ceramic membrane;
图4为本发明实施例刮板的示意图;4 is a schematic diagram of a scraper according to an embodiment of the present invention;
图5为本发明实施例刮渣装置的示意图。FIG. 5 is a schematic diagram of a slag scraping device according to an embodiment of the present invention.
其中,气浮池1、支架2、微纳米功能陶瓷膜3、封口段4、螺杆5、刮板6、刮齿7、螺孔8、通孔9、导向杆10、排气孔11、插管12、气流通道13。Among them, the air flotation tank 1, the
具体实施方式Detailed ways
下面将结合附图,对本发明中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明的较佳实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions of the present invention will be clearly and completely described below with reference to the accompanying drawings. Obviously, the described embodiments are only preferred embodiments of the present invention, rather than all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
实施例Example
如图1所示,本发明实施例多通道浅层气浮工艺,向待处理污水内加入空气气泡,该空气气泡通过倾斜的微纳米功能陶瓷膜3生成。As shown in FIG. 1 , in the multi-channel shallow air flotation process according to the embodiment of the present invention, air bubbles are added to the sewage to be treated, and the air bubbles are generated by the inclined micro-nano functional
微纳米功能陶瓷膜3为现有常见的材料,即微纳米陶瓷膜,由于其孔径小,经过其的空气能够被处理成颗粒非常小的体积。The micro-nano functional
通过微纳米功能陶瓷膜3将空气微纳米化,所产生的微气泡直径可达到微纳米级,在同样条件下,接触面积、传质面积和传质效率可大幅提高;同时纳米功能膜能产生一定浓度的羟基自由基,强化微气泡氧化效果。The air is micronanoified by the micronano functional
多通道浅层气浮设备,包括气浮池1、支架2和若干微纳米功能陶瓷膜3。The multi-channel shallow air flotation equipment includes an air flotation tank 1, a
所述支架2设置于所述气浮池1内,若干所述微纳米功能陶瓷膜3自上向下依次分布于所述支架2,所述微纳米功能陶瓷膜3的一端固定于所述支架2上,所述微纳米功能陶瓷膜3的另一端向上倾斜设置。所述支架2为竖直设置的墙体,所述微纳米功能陶瓷膜3固定于所述墙体的两侧,采用墙体结构的支架2,整体强度更高。The
所述支架2内置有气流通道13,所述气流通道13外接供气装置,所述气流通道13的侧壁设有若干排气孔11,在所述微纳米功能陶瓷膜3的内孔与所述气流通道13的内端连通。The
通过支架2向内部充入空气,空气在微纳米陶瓷膜的作用下形成微纳米的气泡,微纳米的气泡在浮力的作用下向上浮动,气泡浮动的过程中与微纳米功能陶瓷膜3接触,微纳米功能陶瓷膜3将空气气泡微纳米化,被微纳米化的气泡将具有更大的接触面积和传质面积,更高的传质效率,并且纳米功能膜能产生一定浓度的羟基自由基,强化微气泡氧化效果。产生的微纳米化的空气气泡与水中颗粒物粘附,并与水分离,将颗粒物杂质更高效率的与水分离。Air is filled into the interior through the
所述微纳米功能陶瓷膜3一端封堵,另一端设有气腔,所述气腔与所述微纳米陶瓷膜分别连通,所述气腔设有插管12,所述插管12插接至所述排气孔11。空气通过插管12进入到气腔,然后通过气腔分流进入到微纳米功能陶瓷膜3各个内孔,然后通过为纳米陶瓷膜的微孔进入到液体中,此时空气已被微纳米化。One end of the micro-nano functional
本实施例设有若干支架2,相邻支架2的微纳米功能陶瓷膜3间留设有排渣通道。In this embodiment, a plurality of
所述微纳米功能陶瓷膜3的另一端端部向上竖直延伸有封口段4,所述封口段4的上端与上一层的所述微纳米功能陶瓷膜3之间留设有排渣口,通过以上行程一个仓室的结构,污水在内部可以更好的与微纳米化的气泡接触。所述支架2上方的所述气浮池1内设有刮渣装置,便于对漂浮在液面的浮渣进行清理。The other end of the micro-nano functional
所述刮渣装置包括螺杆5、导向杆10和刮板6;所述螺杆5和导向杆10水平并列设置,所述螺杆5两端与所述气浮池1转动配合,所述导向杆10的两端与所述气浮池固定设置,所述刮板6对应所述螺杆5设有螺孔8,所述螺孔8与所述螺杆5螺纹配合,所述刮板6对应所述导向杆10设有通孔9,所述通孔9与所述导向杆10滑动配合,通过转动螺杆5即可驱动刮板6在导向杆10上滑动,来回驱动刮板6,即可实现对浮渣的清理。所述螺杆5的两侧分别设有一导向杆10,通过两侧分别设置,可以使螺杆5对刮板6驱动的力更加均衡。所述刮板6的下沿设有若干刮齿7,便于在带动浮渣移动的时候,污水在下方流走,可以更好的将液体与浮渣分离。The slag scraping device includes a
由微纳米功能陶瓷膜3产生的气体排斥絮体、在气泡沿着陶瓷膜下部上升作用力的推动下,排到中间排渣通道,在中间通道气体向上提升作用下排出到顶部,经刮渣设备最终排出。The gas generated by the micro-nano functional
本技术方案具有气浮能耗低、分离效率高、可去除有机物、运行成本低、投资低、维护简单等特点。The technical solution has the characteristics of low air flotation energy consumption, high separation efficiency, organic matter removal, low operating cost, low investment, and simple maintenance.
1、本发明通过微纳米功能陶瓷膜3将空气(或其他气体)微纳米化,所产生的微气泡直径可达到微纳米级,在同样条件下,接触面积、传质面积和传质效率可大幅提高;微纳米化过程中能产生一定浓度的羟基自由基,强化微气泡氧化效果。1. In the present invention, the air (or other gas) is micronanoized through the micronano functional
2、本发明包括若干微纳米功能陶瓷膜3排列而成的多通道构成,为高效气浮分离提供了可能,强化了分离效果。2. The present invention includes a multi-channel structure in which several micro-nano functional
3、本发明排渣系统充分利用了气泡上浮的特点提升作用,使浮渣在气体动力下不断排出,节省了动力。3. The slag discharge system of the present invention makes full use of the lifting effect of the bubbles floating, so that the scum is continuously discharged under the gas power, saving power.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included in the scope of the present invention. within the scope of protection.
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