CN111482060A - Oil gas recovery device and method by organic membrane separation method - Google Patents
Oil gas recovery device and method by organic membrane separation method Download PDFInfo
- Publication number
- CN111482060A CN111482060A CN202010487381.6A CN202010487381A CN111482060A CN 111482060 A CN111482060 A CN 111482060A CN 202010487381 A CN202010487381 A CN 202010487381A CN 111482060 A CN111482060 A CN 111482060A
- Authority
- CN
- China
- Prior art keywords
- gas
- oil
- communicated
- inlet
- sent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 67
- 238000000926 separation method Methods 0.000 title claims abstract description 35
- 238000011084 recovery Methods 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000001179 sorption measurement Methods 0.000 claims abstract description 43
- 239000007788 liquid Substances 0.000 claims abstract description 33
- 238000001816 cooling Methods 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000012071 phase Substances 0.000 claims abstract description 13
- 239000007791 liquid phase Substances 0.000 claims abstract description 12
- 239000007789 gas Substances 0.000 claims description 144
- 239000002912 waste gas Substances 0.000 claims description 38
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 230000006641 stabilisation Effects 0.000 claims description 6
- 238000011105 stabilization Methods 0.000 claims description 6
- 230000009467 reduction Effects 0.000 claims description 5
- 238000005057 refrigeration Methods 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000003795 desorption Methods 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 239000010865 sewage Substances 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 7
- 238000011068 loading method Methods 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 74
- 238000012423 maintenance Methods 0.000 description 4
- 230000007306 turnover Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000011268 retreatment Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
- C10G5/02—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas with solid adsorbents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
- C10G5/06—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
An oil-gas recovery device adopting an organic membrane separation method comprises a buffer tank, a gas-liquid separator, a heat exchanger and an oil storage tank, wherein an inlet of the buffer tank is communicated with an external oil-gas main pipeline, an inlet of the gas-liquid separator is communicated with an outlet of the buffer tank through an oil-gas compressor unit, a liquid phase outlet of the gas-liquid separator is communicated with an inlet of the oil storage tank, a gas phase outlet of the gas-liquid separator is communicated with a hot inlet of the heat exchanger, a hot outlet of the heat exchanger is communicated with an inlet of the oil storage tank, and a cooling device is communicated between a cold inlet and a; an exhaust port is also arranged on the heat chamber of the heat exchanger, and a membrane component for further recovering oil gas is communicated with the exhaust port; the outlet at the permeation side of the membrane module is communicated with an external oil-gas main pipeline through a first vacuum pump, and the exhaust port of the membrane module is communicated with an adsorption device. The device is safe and environment-friendly, and economic benefits of reducing volatilization loss of oil products, environmental benefits of blue sky green water and safety benefits of loading and unloading processes can be obtained through the arrangement of the membrane component.
Description
Technical Field
The invention relates to the technical field of oil gas recovery, in particular to an oil gas recovery device adopting an organic membrane separation method and a recovery method of the oil gas recovery device adopting the organic membrane separation method.
Background
A large amount of volatile components (called oil gas) exist in finished oil (gasoline, diesel oil, kerosene and the like) or chemical products, and the generated volatile components can volatilize and leak in multiple links of storage, transportation, loading and unloading and the like. Under some occasions, the oil gas leakage amount is large, for example, when a loading platform of a wharf refinery or a turnover oil depot is loaded, the oil gas volatilized from an oil filling port of a tank car has the concentration of about 10% -45% according to the difference of the air temperature and the flow rate during oil filling.
The volatile oil gas mainly contains poisonous and harmful organic components such as ethane, propane, butane, pentane, heptane, octane, benzene and the like, the flammable organic gases are dispersed in the air to cause air pollution and harm human health, fire and explosion accidents are easy to happen, potential safety hazards exist, the loss of the volatile oil gas accounts for about 1% of the total amount of the finished oil according to statistics of relevant scientific research institutions, and the economic loss caused by the volatile oil gas is considerable.
Disclosure of Invention
The invention aims to solve the technical problem of the prior art and provides an oil-gas recovery device by an organic membrane separation method, which has reasonable design, safety and reliability and can recover and treat volatile gas organic components in the loading and unloading links of a wharf or a turnover warehouse.
The invention also provides a recovery method of the oil-gas recovery device by the organic membrane separation method.
The technical problem to be solved by the present invention is achieved by the following technical means. The invention relates to an oil-gas recovery device by an organic membrane separation method, which comprises a buffer tank, a gas-liquid separator, a heat exchanger and an oil storage tank, wherein the inlet of the buffer tank is communicated with an external oil-gas main pipeline, the inlet of the gas-liquid separator is communicated with the outlet of the buffer tank through an oil-gas compressor unit, the liquid-phase outlet of the gas-liquid separator is communicated with the inlet of the oil storage tank, the gas-phase outlet of the gas-liquid separator is communicated with the heat inlet of the heat exchanger, the heat outlet of the heat exchanger is communicated with the inlet of the oil storage tank, and a cooling device is communicated between; an exhaust port is also arranged on the heat chamber of the heat exchanger, and a membrane component used for further recovering oil gas is communicated with the exhaust port.
The technical problem to be solved by the invention can be further solved by adopting the following technical scheme that for the oil-gas recovery device adopting the organic membrane separation method, the permeation side outlet of the membrane component is communicated with the inlet of an external oil-gas main pipeline through a first vacuum pump, the discharge port of the membrane component is communicated with an adsorption device, the desorption discharge port of the adsorption device is communicated with the external oil-gas pipeline through a second vacuum pump, the output port of the adsorption device is communicated with an exhaust pipeline, and the exhaust pipeline is communicated with an external exhaust funnel.
The technical problem to be solved by the invention can be further realized by the following technical scheme that 2 adsorption devices are arranged for the oil gas recovery device by the organic membrane separation method, and the 2 adsorption devices are arranged in parallel.
The technical problem to be solved by the invention can be further realized by the following technical scheme that for the oil gas recovery device adopting the organic membrane separation method, the adsorption device is an activated carbon adsorption tank.
The technical problem to be solved by the invention can be further realized by the following technical scheme that for the oil-gas recovery device adopting the organic membrane separation method, an emergency discharge pipeline is also communicated with the external oil-gas pipeline at the communication position of the buffer tank and the external oil-gas main pipeline, and an emergency control valve is arranged on the emergency discharge pipeline.
The technical problem to be solved by the invention can be further realized by the following technical scheme that for the oil-gas recovery device adopting the organic membrane separation method, the oil-gas compressor unit comprises two oil-gas compressors which are arranged in parallel.
The technical problem to be solved by the invention can be further realized by the following technical scheme that for the oil-gas recovery device adopting the organic membrane separation method, the oil storage tank is also provided with an oil outlet, the bottom of the oil storage tank is provided with a drain outlet, the bottom of the buffer tank is also provided with a liquefied water-gas outlet, the oil outlet is communicated with an oil discharge pipeline, and the drain outlet and the liquefied water-gas outlet are communicated with a drain pipeline.
The technical problem to be solved by the invention can be further solved by adopting the following technical scheme that for the oil-gas recovery device adopting the organic membrane separation method, the cooling device is a refrigeration compressor.
The technical problem to be solved by the invention can be further realized by the following technical scheme, and for the oil-gas recovery device adopting the organic membrane separation method, the oil-gas recovery method adopting the organic membrane separation method comprises the following steps:
(1) waste gas containing high-concentration oil gas enters a buffer tank from an oil gas main pipeline for pressure stabilization, liquefied water gas is discharged from a liquefied water gas outlet, and the rest waste gas is subjected to pressure stabilization, then is sent to an oil gas compressor unit for compression and cooling, and then is sent to a gas-liquid separator;
(2) the gas-liquid separator performs gas-liquid separation on the entering waste gas, the separated liquid is sent to the oil storage tank, and the separated gas is sent to the heat exchanger;
(3) the gas entering the heat exchanger is subjected to heat exchange and temperature reduction with a cooling device and then is divided into liquid-phase waste gas and gas-phase waste gas, the liquid-phase waste gas is sent into an oil storage tank, and the gas-phase waste gas is sent into a membrane component;
(4) after the gas-phase waste gas entering the membrane module is subjected to permeation treatment by the membrane module, the permeation gas is sent back to the oil-gas main pipeline for secondary treatment, and the residual gas is sent to an adsorption device for adsorption treatment; the gas absorbed by the absorption device is sent back to the oil-gas main pipeline for secondary treatment, and the residual gas is sent to the exhaust pipeline for high-altitude discharge.
Compared with the prior art, the invention is used for recovering and treating the volatile gas organic components in the loading and unloading links of wharfs or turnover warehouses, the input waste gas containing high-concentration oil gas is firstly stabilized by the buffer tank and then compressed by the oil gas compressor unit, then the gas-liquid separator is input for gas-liquid separation, the separated liquid is sent into an oil storage tank, the separated gas is sent into a heat exchanger for heat exchange and temperature reduction, the liquid generated by temperature reduction and liquefaction is sent into the oil storage tank, the residual gas is sent into a membrane component for filtration, the filtered gas is sent back to an oil-gas main pipeline for recycling treatment again, the residual gas is sent into an adsorption device for adsorption treatment, the adsorbed gas is sent back to the oil-gas main pipeline for recycling treatment again, and the residual gas is discharged at high altitude, thereby effectively and reasonably achieving the processing efficiency and non-methane emission index of the oil gas recovery device required by the latest national standard. The device is energy-saving, environment-friendly, safe and reliable, and can obtain economic benefits of reducing the volatilization loss of oil products, environmental benefits of blue sky and green water and safety benefits of loading and unloading processes through the arrangement of the membrane component.
Drawings
FIG. 1 is a schematic diagram of a structure of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings of the present invention, and it is obvious that the described embodiments are some embodiments of the present invention, but not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, the oil-gas recovery device by organic membrane separation comprises a buffer tank 1, a gas-liquid separator 4, a heat exchanger 5 and an oil storage tank 6, wherein an inlet of the buffer tank 1 is communicated with an external oil-gas main pipeline 2, an inlet of the gas-liquid separator 4 is communicated with an outlet of the buffer tank 1 through an oil-gas compressor unit 3, a liquid phase outlet of the gas-liquid separator 4 is communicated with an inlet of the oil storage tank 6, a gas phase outlet of the gas-liquid separator 4 is communicated with a heat inlet of the heat exchanger 5, a heat outlet of the heat exchanger 5 is communicated with an inlet of the oil storage tank 6, and a cooling device 7 is communicated between a cold inlet and a cold outlet; an exhaust port is also arranged on the heat chamber of the heat exchanger 5, and a membrane module 8 for further recovering oil gas is communicated with the exhaust port. The buffer tank 1 is used for stabilizing the pressure of the output waste gas; the gas-liquid separator 4 is used for separating oil gas and moisture in the waste gas, so that liquid phase substances are prevented from entering downstream and damaging downstream equipment, and is mainly used as equipment for improving the safe operation of the membrane component 8; the heat exchanger 5 adopts a shell-and-tube heat exchanger 5, so that ice blockage can be effectively avoided, the heat exchange efficiency is improved, and the maintenance is convenient; the membrane module 8 adopts the membrane module 8 in the prior art, which is a practical device containing membranes and supporting structures thereof in various specifications, and a single module or a plurality of modules can be assembled into a membrane separation device, the membrane module 8 adopted in the application is a roll-type membrane module 8, so that the maintenance is convenient, the safety performance is improved, and the equipment arrangement simultaneously reduces the occupied area; fire arresters are further installed on the external oil and gas main pipeline 2, particularly the inlet and the outlet of the external oil and gas main pipeline 2, and the safety performance of the whole device is improved.
The outlet of the permeation side of the membrane module 8 is communicated with the external oil gas main pipeline 2 through a first vacuum pump 9, the discharge port of the membrane module 8 is communicated with an adsorption device 10, the desorption discharge port of the adsorption device 10 is communicated with the external oil gas pipeline through a second vacuum pump 11, the output port of the adsorption device 10 is communicated with an exhaust pipeline 14, and the exhaust pipeline 14 is communicated with an external exhaust funnel. The membrane module 8 and the adsorption device 10 are used in cooperation, and are used for gradually extracting high-concentration oil gas in the waste gas, so that the remaining waste gas meets the emission index, the high-altitude standard emission is carried out through the exhaust funnel, and the height of the exhaust funnel is about 15 m; the membrane module 8 is used for filtering the waste gas cooled by the heat exchanger 5, and high-concentration oil gas in the waste gas passes through the membrane module 8, returns to the external oil gas main pipeline 2 through the first vacuum pump 9, and enters the buffer tank 1 again for recycling treatment; the remaining waste gas is sent into an adsorption device 10 for adsorption treatment, the adsorption device 10 further adsorbs and recovers oil gas with relatively high concentration in the waste gas, the oil gas returns to an external oil gas main pipeline 2 through a second vacuum pump 11, and the oil gas enters a buffer tank 1 again for recovery treatment; the concentration of the waste gas after adsorption treatment is reduced, the waste gas meets the emission standard, and the waste gas is sent into an external exhaust funnel through an exhaust pipeline 14 to be discharged; the first vacuum pump 9 is used for improving the permeation and separation efficiency of the membrane module 8; the adsorption device 10 and the second vacuum pump 11 are used for retreatment of the exhaust gas treated by the membrane module 8, so that the exhaust gas treated by the membrane module 8 can reach the emission standard.
The adsorption device 10 is an activated carbon adsorption tank. The active carbon adsorption tank adopts the active carbon adsorption tank in the prior art, and granular active carbon is adopted in a fixed bed mode to adsorb organic solutes (including chromaticity, smell and the like) in the treated object, so that the treated object is purified; the application adopts the activated carbon adsorption tank to adsorb the waste gas through the membrane module 8 processing, adsorbs again, retrieves the oil gas that includes wherein.
An emergency discharge pipeline 15 is further communicated with the external oil gas pipeline at the communication position of the buffer tank 1 and the external oil gas main pipeline 2, and an emergency control valve 16 is installed on the emergency discharge pipeline 15. The emergency discharge pipeline 15 is used in the case of shutdown of the device, the emergency control valve 16 is opened, and oil and gas in the external oil and gas main pipeline 2 are directly discharged through the emergency discharge pipeline 15; secondly, the emergency discharge pipeline 15 is communicated with the exhaust pipeline 14, and oil and gas can be discharged from high altitude.
The oil-gas compressor unit 3 comprises two oil-gas compressors which are arranged in parallel. The oil gas compressor adopts a gas compressor in the prior art, is a power device for converting mechanical energy into gas pressure energy, is used for compressing oil gas, and generally compresses the oil gas to 0.8MPa, and simultaneously adopts a water-cooling self-circulation cooling system, so that on one hand, a natural water cooling device 7 is used as a cold source to cool the compressed oil gas to about 40 ℃, and on the other hand, the oil gas compressor is favorable for being used under the condition that a wharf or a turnover warehouse has no circulating water public engineering; the two oil-gas compressors are arranged in parallel, so that the running cost can be reduced, and the operation elasticity range is greatly improved.
The oil storage tank 6 is also provided with an oil outlet for outputting the recovered liquid-phase oil outwards, and the bottom of the oil storage tank 6 is provided with a drain outlet for discharging the wastewater at the bottom of the tank; the bottom of the buffer tank 1 is also provided with a liquefied water vapor outlet for discharging liquefied water vapor in the buffer tank 1, an oil outlet is communicated with an oil discharge pipeline 12, and a drain outlet and the liquefied water vapor outlet are communicated with a drain pipeline 13.
The cooling device 7 is a refrigeration compressor. The refrigeration compressor in the prior art is adopted, so that the refrigerant can be increased from low pressure to high pressure, and the refrigerant continuously and circularly flows, so that the system continuously discharges internal heat to the environment with the temperature higher than the temperature of the system; the utility model provides a supercooled water that uses compressor output is as 5 cold source media of heat exchanger, cools down the waste gas in the heat exchanger 5, and this mode can improve security performance and heat exchange efficiency.
An oil gas recovery method by an organic membrane separation method comprises the following steps:
(1) waste gas containing high-concentration oil gas enters a buffer tank from an oil gas main pipeline for pressure stabilization, liquefied water gas is discharged from a liquefied water gas outlet, and the rest waste gas is subjected to pressure stabilization, then is sent to an oil gas compressor unit for compression and cooling, and then is sent to a gas-liquid separator;
(2) the gas-liquid separator performs gas-liquid separation on the entering waste gas, the separated liquid is sent to the oil storage tank, and the separated gas is sent to the heat exchanger;
(3) the gas entering the heat exchanger is subjected to heat exchange and temperature reduction with a cooling device and then is divided into liquid-phase waste gas and gas-phase waste gas, the liquid-phase waste gas is sent into an oil storage tank, and the gas-phase waste gas is sent into a membrane component;
(4) after the gas-phase waste gas entering the membrane module is subjected to permeation treatment by the membrane module, the permeation gas is sent back to the oil-gas main pipeline for secondary treatment, and the residual gas is sent to an adsorption device for adsorption treatment; and after the gas adsorbed by the adsorption device is desorbed, the gas is sent back to the oil gas main pipeline for secondary treatment, and the residual gas is sent to the exhaust pipeline for high-altitude discharge.
Claims (9)
1. The oil gas recovery device by the organic membrane separation method is characterized in that: the device comprises a buffer tank, a gas-liquid separator, a heat exchanger and an oil storage tank, wherein an inlet of the buffer tank is communicated with an external oil-gas main pipeline, an inlet of the gas-liquid separator is communicated with an outlet of the buffer tank through an oil-gas compressor unit, a liquid-phase outlet of the gas-liquid separator is communicated with an inlet of the oil storage tank, a gas-phase outlet of the gas-liquid separator is communicated with a hot inlet of the heat exchanger, a hot outlet of the heat exchanger is communicated with an inlet of the oil storage tank, and a cooling device is communicated between a cold inlet and a; an exhaust port is also arranged on the heat chamber of the heat exchanger, and a membrane component used for further recovering oil gas is communicated with the exhaust port.
2. The organic membrane separation oil-gas recovery device according to claim 1, wherein: the permeation side outlet of the membrane assembly is communicated with the inlet of an external oil-gas main pipeline through a first vacuum pump, the discharge port of the membrane assembly is communicated with an adsorption device, the desorption discharge port of the adsorption device is communicated with the external oil-gas pipeline through a second vacuum pump, the output port of the adsorption device is communicated with an exhaust pipeline, and the exhaust pipeline is communicated with an external exhaust funnel.
3. The organic membrane separation oil-gas recovery device according to claim 2, wherein: the adsorption device is provided with 2, and 2 adsorption device parallelly connected settings.
4. The organic membrane separation oil-gas recovery device according to claim 3, wherein: the adsorption device is an activated carbon adsorption tank.
5. The organic membrane separation oil-gas recovery device according to claim 1, wherein: an emergency discharge pipeline is also communicated with the external oil-gas pipeline at the communication position of the buffer tank and the external oil-gas main pipeline, and an emergency control valve is installed on the emergency discharge pipeline.
6. The organic membrane separation oil-gas recovery device according to claim 1, wherein: the oil-gas compressor unit comprises two oil-gas compressors which are connected in parallel.
7. The organic membrane separation oil-gas recovery device according to claim 1, wherein: still be provided with the oil-out on the oil storage tank, the bottom of oil storage tank is provided with the drain, and the bottom of buffer tank still is provided with the export of liquefied gas water, and oil-out department intercommunication has oil drain pipe, and drain and liquefied gas water exit department intercommunication have sewage pipes.
8. The organic membrane separation oil-gas recovery device according to claim 1, wherein: the cooling device is a refrigeration compressor.
9. An oil gas recovery method by an organic membrane separation method is characterized in that: the method uses the oil gas recovery device of the organic membrane separation method according to any one of claims 1 to 8, and comprises the following steps:
(1) waste gas containing high-concentration oil gas enters a buffer tank from an oil gas main pipeline for pressure stabilization, liquefied water gas is discharged from a liquefied water gas outlet, and the rest waste gas is subjected to pressure stabilization, then is sent to an oil gas compressor unit for compression and cooling, and then is sent to a gas-liquid separator;
(2) the gas-liquid separator performs gas-liquid separation on the entering waste gas, the separated liquid is sent to the oil storage tank, and the separated gas is sent to the heat exchanger;
(3) the gas entering the heat exchanger is subjected to heat exchange and temperature reduction with a cooling device and then is divided into liquid-phase waste gas and gas-phase waste gas, the liquid-phase waste gas is sent into an oil storage tank, and the gas-phase waste gas is sent into a membrane component;
(4) after the gas-phase waste gas entering the membrane module is subjected to permeation treatment by the membrane module, the permeation gas is sent back to the oil-gas main pipeline for secondary treatment, and the residual gas is sent to an adsorption device for adsorption treatment; the gas absorbed by the absorption device is sent back to the oil-gas main pipeline for secondary treatment, and the residual gas is sent to the exhaust pipeline for high-altitude discharge.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010487381.6A CN111482060A (en) | 2020-06-02 | 2020-06-02 | Oil gas recovery device and method by organic membrane separation method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010487381.6A CN111482060A (en) | 2020-06-02 | 2020-06-02 | Oil gas recovery device and method by organic membrane separation method |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111482060A true CN111482060A (en) | 2020-08-04 |
Family
ID=71810542
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010487381.6A Pending CN111482060A (en) | 2020-06-02 | 2020-06-02 | Oil gas recovery device and method by organic membrane separation method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111482060A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112870908A (en) * | 2021-03-12 | 2021-06-01 | 连云港市拓普科技发展有限公司 | Sequencing batch type VOCs gas advanced treatment device and method |
CN112870907A (en) * | 2021-03-12 | 2021-06-01 | 连云港市拓普科技发展有限公司 | High-pressure shallow-cooling combined VOCs gas recovery device and method |
CN114195082A (en) * | 2020-09-17 | 2022-03-18 | 海湾环境科技(北京)股份有限公司 | Oil gas recovery system and oil gas recovery method |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201495195U (en) * | 2009-09-15 | 2010-06-02 | 大连欧科膜技术工程有限公司 | Propylene recycling device in process of producing polypropylene |
CN201692748U (en) * | 2010-06-04 | 2011-01-05 | 大连欧科膜技术工程有限公司 | Emission control and recovery device of organic gases |
CN104923029A (en) * | 2015-06-01 | 2015-09-23 | 中国寰球工程公司 | Method for recovering exhaust gas according to polyolefin gas phase method |
CN107297141A (en) * | 2016-04-15 | 2017-10-27 | 中国石油化工股份有限公司 | A kind of petroleum vapor recovery handling process and complexes |
CN107413173A (en) * | 2016-05-24 | 2017-12-01 | 中国石油化工股份有限公司 | A kind of efficiently organic exhaust gas recovery and treatment method and complexes |
-
2020
- 2020-06-02 CN CN202010487381.6A patent/CN111482060A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201495195U (en) * | 2009-09-15 | 2010-06-02 | 大连欧科膜技术工程有限公司 | Propylene recycling device in process of producing polypropylene |
CN201692748U (en) * | 2010-06-04 | 2011-01-05 | 大连欧科膜技术工程有限公司 | Emission control and recovery device of organic gases |
CN104923029A (en) * | 2015-06-01 | 2015-09-23 | 中国寰球工程公司 | Method for recovering exhaust gas according to polyolefin gas phase method |
CN107297141A (en) * | 2016-04-15 | 2017-10-27 | 中国石油化工股份有限公司 | A kind of petroleum vapor recovery handling process and complexes |
CN107413173A (en) * | 2016-05-24 | 2017-12-01 | 中国石油化工股份有限公司 | A kind of efficiently organic exhaust gas recovery and treatment method and complexes |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114195082A (en) * | 2020-09-17 | 2022-03-18 | 海湾环境科技(北京)股份有限公司 | Oil gas recovery system and oil gas recovery method |
CN112870908A (en) * | 2021-03-12 | 2021-06-01 | 连云港市拓普科技发展有限公司 | Sequencing batch type VOCs gas advanced treatment device and method |
CN112870907A (en) * | 2021-03-12 | 2021-06-01 | 连云港市拓普科技发展有限公司 | High-pressure shallow-cooling combined VOCs gas recovery device and method |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108043064B (en) | VOCs recovery process and system | |
CN204294073U (en) | A VOCs volatile gas recovery and utilization device | |
CN111482060A (en) | Oil gas recovery device and method by organic membrane separation method | |
CN101342427B (en) | Oil gas recovery method | |
CN105413390B (en) | The absorption supercharging recovery system of volatile organic steam in a kind of oil gas | |
CN212383452U (en) | Oil gas recovery device by organic membrane separation method | |
CN107789956A (en) | It is a kind of to realize internal floating roof tank interbedded gas VOCs zero-emissions, remove oxygen and recycle the device of nitrogen | |
CN107413164B (en) | Process and device for recycling and treating organic waste gas by secondary membrane | |
CN100369653C (en) | Oil gas absorptive reclaiming method and apparatus | |
CN107854955B (en) | Hydrocarbon-containing waste gas recovery process and operation control method | |
CN202226647U (en) | Oil gas recovery system of filling station | |
CN212141530U (en) | Small vehicle-mounted VOCs recovery processing equipment | |
CN112870907A (en) | High-pressure shallow-cooling combined VOCs gas recovery device and method | |
CN107413165B (en) | Organic waste gas treatment process and device combining oil absorption and double-membrane circulation | |
CN111171867A (en) | Oil gas recovery method | |
CN201235269Y (en) | System for separating and recycling oil gas with film and pressure swing adsorption overlapping method | |
CN111171868A (en) | Oil gas recovery device | |
CN101601969B (en) | Method for reclaiming oil-containing gases | |
CN212818960U (en) | Three-stage cascade condensation cold energy recycling and adsorption combined type oil gas recovery device | |
CN211328784U (en) | Oil gas recovery system | |
CN106310697A (en) | Novel integrated oil and gas deep recovery and emission control device | |
CN207493453U (en) | It is a kind of to realize internal floating roof tank interbedded gas VOCs zero-emissions, removal oxygen and the device for recycling nitrogen | |
CN108043062B (en) | Storage tank breathes processing system who discharges volatile gas | |
CN217479385U (en) | Oil gas recovery system | |
CN215841700U (en) | High-pressure cryogenic combined VOCs gas recovery device |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |