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CN111470729A - Garbage leachate treatment system and method for garbage incineration power plant - Google Patents

Garbage leachate treatment system and method for garbage incineration power plant Download PDF

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CN111470729A
CN111470729A CN202010332288.8A CN202010332288A CN111470729A CN 111470729 A CN111470729 A CN 111470729A CN 202010332288 A CN202010332288 A CN 202010332288A CN 111470729 A CN111470729 A CN 111470729A
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landfill leachate
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anaerobic
reactor
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王然
郑忆枫
赵剑锋
兰建伟
徐文军
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Shenzhen Energy Resource Comprehensive Development Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/286Anaerobic digestion processes including two or more steps
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/02Softening water by precipitation of the hardness
    • C02F5/06Softening water by precipitation of the hardness using calcium compounds

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  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The invention discloses a waste leachate treatment system and a method of a waste incineration power plant, wherein the waste leachate treatment system comprises a primary sedimentation tank, a primary anaerobic reactor, a secondary anaerobic reactor, an anaerobic sedimentation tank, a softening reactor, a tubular microfiltration membrane, an ammonia still and a built-in MBR; the primary sedimentation tank, the primary anaerobic reactor, the secondary anaerobic reactor, the anaerobic sedimentation tank, the softening reactor, the tubular microfiltration membrane, the ammonia still and the built-in MBR are sequentially connected according to the circulation treatment direction of the garbage leachate. The invention realizes the standard discharge of the waste leachate by sequentially carrying out primary sedimentation pretreatment, primary anaerobic treatment, secondary anaerobic treatment, hardness-removing softening treatment, an ammonia still and low-load built-in MBR treatment on the waste leachate.

Description

垃圾焚烧发电厂的垃圾渗沥液处理系统及方法Landfill leachate treatment system and method for waste incineration power plant

技术领域technical field

本发明涉及废水处理技术领域,尤其涉及一种垃圾焚烧发电厂的垃圾渗沥液处理系统及方法。The invention relates to the technical field of wastewater treatment, in particular to a system and method for treating landfill leachate in a waste incineration power plant.

背景技术Background technique

现阶段全国垃圾电厂如雨后春笋般建设起来,垃圾焚烧发电必将是未来垃圾处理的主流技术,也将得到国家大力支持,而垃圾渗沥液又是垃圾焚烧发电技术里无法绕开的话题,一套投资成本更低、运行成本更低、能稳定运行的工艺系统是业界不断追求的目标。At this stage, garbage power plants have sprung up across the country. Waste incineration power generation will definitely be the mainstream technology of waste treatment in the future, and will also receive strong support from the state. Landfill leachate is an inescapable topic in waste incineration power generation technology. A process system with lower investment cost, lower operating cost and stable operation is the goal that the industry is constantly pursuing.

垃圾在存放、中转、运输、堆放过程中,由于厌氧发酵、有机物分解、雨水淋洗等原因产生多种代谢物质和水分,形成了成分极为复杂的高浓度有机废水——垃圾渗沥液。During the process of storage, transfer, transportation and stacking of garbage, various metabolites and water are generated due to anaerobic fermentation, organic matter decomposition, rainwater leaching, etc., forming a highly complex organic wastewater with high concentration - landfill leachate.

垃圾渗沥液成分复杂,COD浓度一般在40000-80000mg/l左右,氨氮浓度一般在1000-2500mg/l左右,盐分含量也较高,采用传统的生化处理工艺,很难将其处理到要求的排放标准。目前垃圾焚烧发电厂渗沥液处理的主流工艺流程主要为:预处理+厌氧+外置式MBR(硝化/反硝化+超滤系统)+NF+RO。此工艺路线是业界较为成熟的一套工艺,但也有一些缺点,如投资高、运行成本高、占地面积大、吨水处理费用一直居高不下,膜浓缩液需要电厂协同处理。根据运行经验,外置式MBR系统中的A/O系统中曝气风机、射流泵、回流泵、消泡泵等设备较多,整套工艺流程中此系统耗电量占比最高,硝化/反硝化运行用电量约占整体用电量的60%-80%,其成本占吨水处理成本的50%左右。同时,NF和RO系统投入运行后,即有30%左右的膜浓缩液产生。由于膜浓缩液高有机物浓度、高盐含量、结垢性强、污染物成分复杂等特点,使得对该浓缩液进行处理的难度相当大,国内外还没有一种经济合理的成熟处理工艺。The composition of landfill leachate is complex, the COD concentration is generally around 40000-80000mg/l, the ammonia nitrogen concentration is generally around 1000-2500mg/l, and the salt content is also high. It is difficult to treat it to the required level by using traditional biochemical treatment technology. Emission Standards. At present, the mainstream process of leachate treatment in waste incineration power plants is mainly: pretreatment + anaerobic + external MBR (nitrification / denitrification + ultrafiltration system) + NF + RO. This process route is a relatively mature set of processes in the industry, but it also has some disadvantages, such as high investment, high operating cost, large area, and high water treatment cost per ton. The membrane concentrate requires co-processing by power plants. According to the operating experience, the A/O system in the external MBR system has many equipments such as aeration fans, jet pumps, reflux pumps, defoaming pumps, etc. In the whole process flow, this system consumes the highest proportion of electricity, and nitrification/denitrification Operating electricity consumption accounts for about 60%-80% of the overall electricity consumption, and its cost accounts for about 50% of the cost of water treatment per ton. At the same time, after the NF and RO systems are put into operation, about 30% of the membrane concentrate is produced. Due to the characteristics of high organic concentration, high salt content, strong scaling, and complex pollutant components in the membrane concentrate, it is quite difficult to treat the concentrate. There is no mature economical and reasonable treatment process at home and abroad.

因此,为了减少膜浓缩液的产生,同时降低投资成本、减少吨水处理费用,有必要对处理工艺进行改进以取代外置式MBR系统和膜深度处理系统。Therefore, in order to reduce the production of membrane concentrate, and at the same time reduce the investment cost and ton water treatment cost, it is necessary to improve the treatment process to replace the external MBR system and the advanced membrane treatment system.

发明内容SUMMARY OF THE INVENTION

本发明要解决的技术问题在于,提供一种降低成本且处理效果好的垃圾焚烧发电厂的垃圾渗沥液处理系统及垃圾渗沥液处理方法。The technical problem to be solved by the present invention is to provide a landfill leachate treatment system and a landfill leachate treatment method for a waste incineration power plant with reduced cost and good treatment effect.

本发明解决其技术问题所采用的技术方案是:提供一种垃圾焚烧发电厂的垃圾渗沥液处理系统,包括接入垃圾渗滤液的初沉池、依序对垃圾渗沥液进行中温厌氧处理的一级厌氧反应器和二级厌氧反应器、厌氧沉淀池、对厌氧处理后的垃圾渗沥液进行软化处理的软化反应器、对软化后的垃圾渗沥液进行过滤处理的管式微滤膜、对过滤得到的清液进行蒸氨处理的蒸氨塔、对蒸氨后的清液进行生化处理和过滤处理的内置式MBR;The technical solution adopted by the present invention to solve the technical problem is: to provide a landfill leachate treatment system of a waste incineration power plant, which includes a primary sedimentation tank connected to the landfill leachate, and the landfill leachate is subjected to mesothermal anaerobic treatment in sequence. First-level anaerobic reactor and second-level anaerobic reactor for treatment, anaerobic sedimentation tank, softening reactor for softening anaerobic treatment of landfill leachate, and filtration treatment for softened landfill leachate The tubular microfiltration membrane, the ammonia distillation tower for the ammonia distillation treatment of the clear liquid obtained by filtration, the built-in MBR for the biochemical treatment and filtration treatment of the clear liquid after the ammonia distillation;

所述初沉池、一级厌氧反应器、二级厌氧反应器、厌氧沉淀池、软化反应器、管式微滤膜、蒸氨塔以及内置式MBR按垃圾渗沥液的流通处理方向依次连接。The primary sedimentation tank, the primary anaerobic reactor, the secondary anaerobic reactor, the anaerobic sedimentation tank, the softening reactor, the tubular microfiltration membrane, the ammonia distillation tower and the built-in MBR are processed according to the flow of the landfill leachate. Connect in sequence.

优选地,所述垃圾渗沥液处理系统还包括设置在所述初沉池前端、对垃圾渗沥液进行过滤处理的篮式过滤器和自清洗过滤器。Preferably, the landfill leachate treatment system further comprises a basket filter and a self-cleaning filter arranged at the front end of the primary settling tank for filtering the landfill leachate.

优选地,所述篮式过滤器的过滤精度为5mm或10mm;所述自清洗过滤器的过滤精度为1mm或2mm。Preferably, the filtration precision of the basket filter is 5mm or 10mm; the filtration precision of the self-cleaning filter is 1mm or 2mm.

优选地,所述垃圾渗沥液处理系统还包括对垃圾渗沥液进行均质均量处理的调节池;所述调节池连接在所述初沉池和一级厌氧反应器之间。Preferably, the landfill leachate treatment system further comprises a conditioning tank for homogeneous and uniform treatment of the landfill leachate; the conditioning tank is connected between the primary sedimentation tank and the primary anaerobic reactor.

优选地,所述一级厌氧反应器和二级厌氧反应器的厌氧反应温度均为35℃-38℃。Preferably, the anaerobic reaction temperatures of the primary anaerobic reactor and the secondary anaerobic reactor are both 35°C to 38°C.

优选地,所述管式微滤膜的微滤膜孔径为0.1-0.5μm。Preferably, the microfiltration membrane pore size of the tubular microfiltration membrane is 0.1-0.5 μm.

优选地,所述垃圾渗沥液处理系统还包括污泥池以及连接所述污泥池的污泥脱水处理装置;所述初沉池、一级厌氧反应器、二级厌氧反应器、厌氧沉淀池以及内置式MBR分别连接所述污泥池。Preferably, the landfill leachate treatment system further comprises a sludge tank and a sludge dewatering treatment device connected to the sludge tank; the primary sedimentation tank, the primary anaerobic reactor, the secondary anaerobic reactor, The anaerobic sedimentation tank and the built-in MBR are respectively connected to the sludge tank.

优选地,所述垃圾渗沥液处理系统还包括连接在所述内置式MBR的出水端的应急纳滤装置,对所述内置式MBR的出水进行过滤处理。Preferably, the landfill leachate treatment system further includes an emergency nanofiltration device connected to the water outlet end of the built-in MBR to filter the effluent of the built-in MBR.

本发明还提供一种垃圾焚烧发电厂的垃圾渗沥液处理方法,包括以下步骤:The present invention also provides a method for treating landfill leachate in a waste incineration power plant, comprising the following steps:

S1、垃圾渗沥液进入初沉池进行初步沉淀处理;S1. The landfill leachate enters the primary sedimentation tank for preliminary sedimentation treatment;

S2、将经过初步沉淀处理后的垃圾渗沥液输送至一级厌氧反应器进行中温厌氧处理,使垃圾渗沥液中的难溶有机物分解为小分子物质;S2. The landfill leachate after preliminary precipitation treatment is transported to the first-stage anaerobic reactor for mesophilic anaerobic treatment, so that the insoluble organic matter in the landfill leachate is decomposed into small molecular substances;

S3、将经过中温厌氧处理后的垃圾渗沥液输送至二级厌氧反应器进行二级厌氧处理,去除其中的有机物;S3. Transporting the landfill leachate after the mesothermal anaerobic treatment to the secondary anaerobic reactor for secondary anaerobic treatment to remove the organic matter therein;

S4、将经过二级厌氧处理后的垃圾渗沥液输送至厌氧沉淀池进行厌氧沉淀处理;S4. Transport the landfill leachate after the secondary anaerobic treatment to the anaerobic sedimentation tank for anaerobic sedimentation treatment;

S5、将厌氧沉淀池的出水送至软化反应器并投加氢氧化钙进行软化处理,根据在线测得的pH值调整氢氧化钙的加入量;S5, the effluent of the anaerobic sedimentation tank is sent to the softening reactor and calcium hydroxide is added for softening treatment, and the amount of calcium hydroxide added is adjusted according to the pH value measured online;

S6、将软化处理后的垃圾渗沥液输送至管式微滤膜,过滤去除垃圾渗沥液中的悬浮物和有机微生物;S6. Transport the softened landfill leachate to a tubular microfiltration membrane, and filter to remove suspended solids and organic microorganisms in the landfill leachate;

S7、将过滤后得到的清液输送至蒸氨塔进行蒸氨处理,去除清液中的氨氮;S7, the clear liquid obtained after the filtration is transported to the ammonia distillation tower to carry out the ammonia distillation process, and the ammonia nitrogen in the clear liquid is removed;

S8、将蒸氨塔的出水送至内置式MBR,经过反硝化、硝化作用,生化去除其中的可生化有机物并进行生物脱氮。S8. The effluent of the ammonia distillation tower is sent to the built-in MBR, and through denitrification and nitrification, the biochemical organic matter therein is biochemically removed and biological denitrification is carried out.

优选地,步骤S1中,垃圾渗沥液进入初沉池前,先依次经过篮式过滤器和自清洗过滤器进行过滤处理。Preferably, in step S1, before the landfill leachate enters the primary settling tank, it is filtered through the basket filter and the self-cleaning filter in sequence.

优选地,步骤S2中,经过初步沉淀处理后的垃圾渗沥液先输送至调节池内进行均质均量处理,再送至一级厌氧反应器。Preferably, in step S2, the landfill leachate after preliminary precipitation treatment is first transported to the conditioning tank for homogeneous and homogeneous treatment, and then sent to the primary anaerobic reactor.

优选地,所述垃圾渗沥液处理方法还包括以下步骤:Preferably, the landfill leachate treatment method further comprises the following steps:

S9、通过应急纳滤装置对所述内置式MBR的出水进行过滤处理,降低所述出水的有机物指标。S9, filtering the effluent of the built-in MBR through an emergency nanofiltration device to reduce the organic matter index of the effluent.

本发明的垃圾渗沥液处理系统及方法,通过将垃圾渗沥液依次经过初沉预处理、一级厌氧处理、二级厌氧处理、去硬度软化处理、蒸氨塔以及低负荷的内置式MBR处理,实现垃圾渗沥液达标排放。The landfill leachate treatment system and method of the present invention, by sequentially subjecting the landfill leachate to primary sedimentation pretreatment, first-stage anaerobic treatment, second-stage anaerobic treatment, de-hardening softening treatment, ammonia distillation tower and low-load built-in MBR treatment is adopted to realize the discharge of landfill leachate up to the standard.

本发明具有如下优点:The present invention has the following advantages:

(1)、降低整套工艺的吨水投资成本;(1), reduce the investment cost per ton of water for the entire process;

(2)、降低垃圾渗沥液处理行业吨水处理成本;(2), reduce the cost of water treatment per ton of landfill leachate treatment industry;

(3)、由于大部分有机物在厌氧处理中去除,且采用低负荷内置式MBR系统或膜深度处理系统,减少污泥量;(3) Since most of the organic matter is removed in anaerobic treatment, and the low-load built-in MBR system or membrane advanced treatment system is used to reduce the amount of sludge;

(4)、低负荷内置式MBR生化池停留时间减短,所需反应器容积减小,节省占地面积及土建等投资成本;(4) The residence time of the low-load built-in MBR biochemical tank is shortened, the required reactor volume is reduced, and the investment cost such as floor space and civil construction is saved;

(5)、采用内置式MBR时,减轻系统对膜深度处理系统的依赖,无膜浓缩液产生;(5) When the built-in MBR is used, the dependence of the system on the membrane advanced treatment system is reduced, and no membrane concentrate is generated;

(6)、充分利用蒸氨塔对氨氮的去除效果。(6) Make full use of the ammonia nitrogen removal effect of the ammonia distillation tower.

另外,通过应急纳滤装置设置,对内置式MBR出水进一步进行过滤,确保出水有机物指标达到排放标准,最大限度减少膜浓缩液产生。In addition, through the setting of the emergency nanofiltration device, the effluent of the built-in MBR is further filtered to ensure that the organic matter index of the effluent meets the discharge standard and minimize the generation of membrane concentrate.

附图说明Description of drawings

下面将结合附图及实施例对本发明作进一步说明,附图中:The present invention will be further described below in conjunction with the accompanying drawings and embodiments, in which:

图1是本发明一实施例的垃圾渗沥液处理系统的连接框图。FIG. 1 is a connection block diagram of a landfill leachate treatment system according to an embodiment of the present invention.

具体实施方式Detailed ways

为了对本发明的技术特征、目的和效果有更加清楚的理解,现对照附图详细说明本发明的具体实施方式。In order to have a clearer understanding of the technical features, objects and effects of the present invention, the specific embodiments of the present invention will now be described in detail with reference to the accompanying drawings.

本发明的垃圾焚烧发电厂的垃圾渗沥液处理系统及方法,用于对垃圾渗沥液进行处理,使其达到排放标准。The landfill leachate treatment system and method of the waste incineration power plant of the present invention are used for treating the landfill leachate to make it meet the discharge standard.

如图1所示,本发明一实施例的垃圾焚烧发电厂的垃圾渗沥液处理系统,可按垃圾渗沥液的流通处理方向依次连接的初沉池1、一级厌氧反应器3、二级厌氧反应器4、厌氧沉淀池5、软化反应器6、管式微滤膜7、蒸氨塔8以及内置式MBR(膜生物反应器)9。As shown in FIG. 1 , the landfill leachate treatment system of a waste incineration power plant according to an embodiment of the present invention includes a primary sedimentation tank 1, a first-stage anaerobic reactor 3, a primary sedimentation tank 1, a first-stage anaerobic reactor 3, Secondary anaerobic reactor 4, anaerobic sedimentation tank 5, softening reactor 6, tubular microfiltration membrane 7, ammonia distillation tower 8 and built-in MBR (membrane bioreactor) 9.

其中,初沉池1接入垃圾渗滤液,使垃圾渗沥液在其中进行初步沉淀的预处理。一级厌氧反应器3和二级厌氧反应器4依序对垃圾渗沥液进行中温厌氧处理,一级厌氧反应器3进行一级厌氧反应,二级厌氧反应器4进行二级厌氧处理,厌氧沉淀池5用于经过厌氧处理后的垃圾渗沥液在其中进行厌氧沉淀,降低其出水的污泥浓度。软化反应器6对厌氧处理后的垃圾渗沥液进行软化处理,去除大部分硬度。管式微滤膜7对软化后的垃圾渗沥液进行过滤处理,去除其中的悬浮物和有机微生物。蒸氨塔8对过滤得到的清液进行蒸氨处理,去除其中的氨氮。内置式MBR 9对蒸氨后的清液进行生化处理和过滤处理,使垃圾渗沥液达到排放标准。Among them, the primary sedimentation tank 1 is connected to landfill leachate, so that the landfill leachate is pretreated for preliminary precipitation therein. The first-level anaerobic reactor 3 and the second-level anaerobic reactor 4 sequentially perform mesophilic anaerobic treatment on the landfill leachate, the first-level anaerobic reactor 3 performs the first-level anaerobic reaction, and the second-level anaerobic reactor 4 performs the first-level anaerobic reaction. In the secondary anaerobic treatment, the anaerobic sedimentation tank 5 is used for anaerobic sedimentation of the landfill leachate after the anaerobic treatment, so as to reduce the sludge concentration in the effluent. The softening reactor 6 softens the anaerobic-treated landfill leachate to remove most of the hardness. The tubular microfiltration membrane 7 filters the softened landfill leachate to remove suspended solids and organic microorganisms therein. The ammonia distillation tower 8 performs ammonia distillation on the clear liquid obtained by filtration to remove ammonia nitrogen therein. The built-in MBR 9 performs biochemical treatment and filtration treatment on the clear liquid after ammonia distillation, so that the landfill leachate can meet the discharge standard.

本发明的垃圾渗沥液处理系统还包括篮式过滤器101和自清洗过滤器102,按照垃圾渗沥液的流通方向,篮式过滤器101和自清洗过滤器102设置在初沉池1的前端,对垃圾渗沥液进行过滤处理,过滤后的垃圾渗沥液再进入初沉池1进行初步沉淀,去除垃圾渗沥液中较大的颗粒物质以及部分悬浮物;初沉池1内底部沉淀积聚形成的污泥可通过动力泵排出。The landfill leachate treatment system of the present invention further includes a basket filter 101 and a self-cleaning filter 102. According to the flow direction of the landfill leachate, the basket filter 101 and the self-cleaning filter 102 are arranged in the primary sedimentation tank 1. At the front end, the landfill leachate is filtered, and the filtered landfill leachate enters the primary sedimentation tank 1 for preliminary precipitation to remove larger particulate matter and some suspended solids in the landfill leachate; the bottom of the primary sedimentation tank 1 The sludge formed by sedimentation can be discharged by the power pump.

作为选择,篮式过滤器101的过滤精度为5mm或10mm;自清洗过滤器102的过滤精度为1mm或2mm。Alternatively, the filtration precision of the basket filter 101 is 5mm or 10mm; the filtration precision of the self-cleaning filter 102 is 1mm or 2mm.

为了使垃圾渗沥液进入后续各处理单元的水质、水量稳定,本发明的垃圾渗沥液处理系统还包括对垃圾渗沥液进行均质均量处理的调节池2。调节池2连接在初沉池1和一级厌氧反应器3之间。In order to stabilize the water quality and quantity of the landfill leachate entering the subsequent treatment units, the landfill leachate treatment system of the present invention further includes a conditioning tank 2 for homogeneous and homogeneous treatment of the landfill leachate. The conditioning tank 2 is connected between the primary sedimentation tank 1 and the primary anaerobic reactor 3 .

一级厌氧反应器3和二级厌氧反应器4实现了对垃圾渗沥液的两级厌氧处理。其中,在一级厌氧反应器3中,以中温厌氧环境进行,作为中温的厌氧反应温度选择35℃-38℃。经过中温厌氧处理,垃圾渗沥液中的难溶有机污染物首先被分解为可溶性大分子物质,再被分解为小分子有机酸,最后被分解为二氧化碳、甲烷、水、氨氮、硫化氢、磷酸盐、无机盐等小分子物质,实现污染物的去除。经过一级厌氧处理后的垃圾渗沥液再进入二级厌氧反应器4继续厌氧反应,厌氧反应温度选择35℃-38℃,进一步去除其中的有机物。The primary anaerobic reactor 3 and the secondary anaerobic reactor 4 realize two-stage anaerobic treatment of landfill leachate. Among them, in the primary anaerobic reactor 3, it is carried out in a medium temperature anaerobic environment, and 35°C-38°C is selected as the medium temperature anaerobic reaction temperature. After mesophilic anaerobic treatment, insoluble organic pollutants in landfill leachate are first decomposed into soluble macromolecular substances, then decomposed into small molecular organic acids, and finally decomposed into carbon dioxide, methane, water, ammonia nitrogen, hydrogen sulfide, Phosphate, inorganic salts and other small molecular substances to achieve the removal of pollutants. The landfill leachate after the primary anaerobic treatment enters the secondary anaerobic reactor 4 to continue the anaerobic reaction, and the anaerobic reaction temperature is selected from 35°C to 38°C to further remove the organic matter therein.

在上述的两级厌氧处理中,垃圾渗沥液在厌氧环境下,通过厌氧微生物的作用,使其中的有机污染物绝大部分分解成小分子物质,降低COD和BOD。同时,厌氧反应器对硬度也有一定的去除率,去除率能达到70%左右,硬度的去除大大减少了后续处理单元的加药量。In the above-mentioned two-stage anaerobic treatment, the landfill leachate in the anaerobic environment, through the action of anaerobic microorganisms, decomposes most of the organic pollutants into small molecular substances, reducing COD and BOD. At the same time, the anaerobic reactor also has a certain removal rate for hardness, and the removal rate can reach about 70%. The removal of hardness greatly reduces the dosage of the subsequent treatment unit.

在上述的两级厌氧处理中,二级厌氧反应器4水力停留时间比一级厌氧反应器3短。一级厌氧反应器3和二级厌氧反应器4可采用UASB反应器或IC反应器。另外,上述厌氧处理中产生的沼气可收集至储气柜,由管道输送至电厂焚烧炉焚烧,同时设置应急火炬。In the above-mentioned two-stage anaerobic treatment, the hydraulic retention time of the second-stage anaerobic reactor 4 is shorter than that of the first-stage anaerobic reactor 3 . The primary anaerobic reactor 3 and the secondary anaerobic reactor 4 may adopt a UASB reactor or an IC reactor. In addition, the biogas generated in the above-mentioned anaerobic treatment can be collected in the gas storage tank, and transported by pipeline to the incinerator of the power plant for incineration, and an emergency flare is set at the same time.

二级厌氧反应器4的出水进入到厌氧沉淀池5(封闭),在其中进行厌氧沉淀,主要是避免厌氧出水污泥浓度过高,影响后续处理工艺。厌氧沉淀池5内底部沉淀积聚形成的污泥可通过动力泵排出。The effluent from the secondary anaerobic reactor 4 enters the anaerobic sedimentation tank 5 (closed), where anaerobic precipitation is carried out, mainly to avoid excessive sludge concentration in the anaerobic effluent, which affects the subsequent treatment process. The sludge formed by sedimentation and accumulation at the bottom of the anaerobic sedimentation tank 5 can be discharged by a power pump.

厌氧沉淀池5内置中心筒,形成中心进水周边出水的形式,厌氧沉淀池5底部设置为泥渣斗形式,便于排出污泥。The anaerobic sedimentation tank 5 has a built-in center cylinder, which forms the form of water inflow around the center, and the bottom of the anaerobic sedimentation tank 5 is set in the form of a sludge hopper, which is convenient for sludge discharge.

软化反应器6的进口端连接厌氧沉淀池5的出水端,接入厌氧沉淀池5的出水,对经过厌氧处理后的垃圾渗沥液进行软化处理,去除其中的大部分钙。软化处理时,可通过自动加药装置往软化反应器6内投入氢氧化钙(熟石灰),垃圾渗沥液与氢氧化钙反应进行混凝沉淀,去除垃圾渗沥液中的大部分硬度。氢氧化钙的投入量根据垃圾渗沥液的pH值调整,自动加药装置可根据垃圾渗沥液的pH值等情况调整氢氧化钙的投入量,调节软化反应器6内的pH值为11-12。软化反应器6的pH值由pH计61在线监测。The inlet end of the softening reactor 6 is connected to the outlet end of the anaerobic sedimentation tank 5 and connected to the effluent of the anaerobic sedimentation tank 5 to soften the anaerobic treated landfill leachate to remove most of the calcium. During the softening treatment, calcium hydroxide (slaked lime) can be put into the softening reactor 6 through the automatic dosing device, and the landfill leachate reacts with calcium hydroxide for coagulation and precipitation to remove most of the hardness in the landfill leachate. The input amount of calcium hydroxide is adjusted according to the pH value of the landfill leachate, and the automatic dosing device can adjust the input amount of calcium hydroxide according to the pH value of the landfill leachate, etc., and adjust the pH value in the softening reactor 6 to 11 -12. The pH of the softening reactor 6 is monitored online by a pH meter 61 .

管式微滤膜7进口端连接软化反应器6的出水端,接入软化反应器6的出水,对经过软化处理后的垃圾渗沥液进行过滤处理,去除其中的悬浮物和有机微生物,进一步分离、澄清垃圾渗沥液。The inlet end of the tubular microfiltration membrane 7 is connected to the effluent end of the softening reactor 6, and is connected to the effluent of the softening reactor 6, and the softened landfill leachate is filtered to remove the suspended solids and organic microorganisms, and further separated. , Clarify landfill leachate.

管式微滤膜7的微滤膜孔径可选0.1-0.5μm。The microfiltration membrane pore size of the tubular microfiltration membrane 7 can be selected from 0.1-0.5 μm.

管式微滤膜7的出水端连接蒸氨塔8,将过滤后得到的清液输送至蒸氨塔8进行蒸氨处理,以去除其中的氨氮,还去除部分易挥发的COD。The effluent end of the tubular microfiltration membrane 7 is connected to an ammonia distillation tower 8, and the clear liquid obtained after filtration is transported to the ammonia distillation tower 8 for ammonia distillation treatment to remove ammonia nitrogen and part of volatile COD.

清液中的氨氮,多以氨离子(NH4+)和游离氨(NH3)的状态存在并保持平衡,两者的平衡关系受pH值影响。当pH值为7时,氨氮多以NH4+的状态存在,而当pH值为11左右时,氨氮90%以NH3形态存在,游离氨(NH3)易于从水中逸出。本实施例中,蒸氨塔8采用鼓风氨气吹脱塔,促使氨从清液中逸出,蒸氨塔8对氨氮的去除率可以达到95%以上。为避免逸出的氨气造成二次污染,将逸出的氨气采取管路回收,经泵送至电厂脱硝系统。The ammonia nitrogen in the supernatant mostly exists in the state of ammonia ions (NH4+) and free ammonia ( NH3 ) and maintains a balance, and the equilibrium relationship between the two is affected by the pH value. When the pH value is 7, the ammonia nitrogen mostly exists in the state of NH4+, and when the pH value is about 11, 90% of the ammonia nitrogen exists in the form of NH3 , and free ammonia ( NH3 ) is easy to escape from the water. In this embodiment, the ammonia distillation tower 8 adopts a blast ammonia stripping tower to promote the escape of ammonia from the clear liquid, and the removal rate of ammonia nitrogen by the ammonia distillation tower 8 can reach more than 95%. In order to avoid secondary pollution caused by the escaping ammonia gas, the escaping ammonia gas is recovered by pipeline and pumped to the denitrification system of the power plant.

蒸氨塔8的出水送至内置式MBR 9,经过反硝化、硝化作用,生化去除其中的可生化有机物并进行生物脱氮,使最后出水达到《生活垃圾填埋场污染控制标准》(GB 16889-2008),实现达标排放。The effluent of the ammonia distillation tower 8 is sent to the built-in MBR 9. After denitrification and nitrification, the biochemical organic matter in it is biochemically removed and biological denitrification is carried out, so that the final effluent reaches the "Standards for Pollution Control of Domestic Waste Landfills" (GB 16889). -2008), to achieve emission standards.

本实施例中,内置式MBR 9包括依序连接的反硝化池91、硝化池92及内置式超滤膜装置93。在运行中,硝化池92的混合液回流到反硝化池91,使反硝化菌有足够的NO3-作为电子受体,从而提高反硝化速率。内置式MBR 9中微生物菌体通过内置式超滤膜装置93从水中分离,确保悬浮物、微生物和与CODCr相关的悬浮物安全地截留在内置式超滤膜装置93内,使水力停留时间和污泥停留时间得到真正意义上地分离。内置式超滤膜装置93产生的剩余污泥定期排入污泥池,出水达标排放。In this embodiment, the built-in MBR 9 includes a denitrification tank 91 , a nitrification tank 92 and a built-in ultrafiltration membrane device 93 which are connected in sequence. During operation, the mixed liquid in the nitrification tank 92 is returned to the denitrification tank 91, so that the denitrifying bacteria have enough NO 3- as an electron acceptor, thereby increasing the denitrification rate. The microbial cells in the built-in MBR 9 are separated from the water through the built-in ultrafiltration membrane device 93 to ensure that suspended matter, microorganisms and suspended matter related to CODCr are safely trapped in the built-in ultrafiltration membrane device 93, so that the hydraulic retention time and The sludge residence time is truly separated. The excess sludge produced by the built-in ultrafiltration membrane device 93 is regularly discharged into the sludge tank, and the effluent is discharged up to the standard.

内置式超滤膜装置93中的超滤膜可采用内置浸没式板式膜。The ultrafiltration membrane in the built-in ultrafiltration membrane device 93 can be a built-in submerged plate membrane.

进一步地,根据需要,本发明的垃圾渗沥液处理系统还包括污泥池10以及连接污泥池10的污泥脱水处理装置11。初沉池1、一级厌氧反应器3、二级厌氧反应器4、厌氧沉淀池5以及内置式MBR9分别连接污泥池10,各者内部积聚的污泥等沉淀物可通过泵等输送至污泥池10内。污泥池10内存储的污泥等沉淀物进一步可输送至污泥脱水处理装置11进行脱水处理,形成的干泥可送至发电厂焚烧,脱水液可返回至反硝化池处理。Further, as required, the landfill leachate treatment system of the present invention further includes a sludge tank 10 and a sludge dewatering treatment device 11 connected to the sludge tank 10 . The primary sedimentation tank 1, the primary anaerobic reactor 3, the secondary anaerobic reactor 4, the anaerobic sedimentation tank 5 and the built-in MBR9 are respectively connected to the sludge tank 10, and the sludge and other sediments accumulated in each of them can pass the pump And so on to the sludge tank 10. The sludge and other sediments stored in the sludge tank 10 can be further transported to the sludge dewatering treatment device 11 for dehydration treatment, the formed dry sludge can be sent to the power plant for incineration, and the dewatered liquid can be returned to the denitrification tank for treatment.

根据需要,本发明的垃圾渗沥液处理系统还包括应急纳滤装置12,连接在内置式MBR9的出水端,对内置式MBR9的出水进行过滤处理,降低出水的有机物指标,保证出水符合排放标准。According to needs, the landfill leachate treatment system of the present invention also includes an emergency nanofiltration device 12, which is connected to the water outlet of the built-in MBR9 to filter the effluent of the built-in MBR9, reduce the organic matter index of the effluent, and ensure that the effluent meets the discharge standard .

应急纳滤装置12具体连接在内置式超滤膜装置93的出水端。应急纳滤装置的纳滤膜孔径为1-10nm。The emergency nanofiltration device 12 is specifically connected to the water outlet of the built-in ultrafiltration membrane device 93 . The pore size of the nanofiltration membrane of the emergency nanofiltration device is 1-10 nm.

在少部分情况下,内置式MBR 9的出水有机物可能超标,这时候启动应急纳滤装置12,保证出水达标排放。该应急纳滤装置12作为选择,当内置式MBR9的出水的有机物指标符合相关标准时,可不启动该应急纳滤装置12。In a small number of cases, the effluent organic matter of the built-in MBR 9 may exceed the standard. At this time, the emergency nanofiltration device 12 is activated to ensure that the effluent is discharged up to the standard. As an option for the emergency nanofiltration device 12, when the organic matter index of the effluent of the built-in MBR9 meets the relevant standards, the emergency nanofiltration device 12 may not be activated.

本发明的垃圾焚烧发电厂的垃圾渗沥液处理方法,可采用上述的处理系统实现,参考图1,该处理方法可包括以下步骤:The landfill leachate treatment method of the waste incineration power plant of the present invention can be realized by the above-mentioned treatment system. Referring to FIG. 1 , the treatment method may include the following steps:

S1、垃圾渗沥液进入初沉池1进行初步沉淀处理。S1. The landfill leachate enters the primary sedimentation tank 1 for preliminary sedimentation treatment.

初步沉淀作为预处理步骤,去除其中的可沉淀物质。初沉池1内底部沉淀积聚形成的污泥可通过动力泵排至污泥池10。Preliminary precipitation is used as a pretreatment step to remove precipitable substances. The sludge formed by precipitation and accumulation at the bottom of the primary sedimentation tank 1 can be discharged to the sludge tank 10 through a power pump.

作为选择,本实施例中,垃圾渗沥液进入初沉池1前,先进行过滤处理,例如依次经过篮式过滤器101和自清洗过滤器102,滤去垃圾渗沥液中较大的颗粒物质以及部分悬浮物。Alternatively, in this embodiment, before the landfill leachate enters the primary settling tank 1, it is filtered first, for example, it passes through the basket filter 101 and the self-cleaning filter 102 in sequence to filter out larger particles in the landfill leachate. Substances and some suspended solids.

S2、将经过初步沉淀处理后的垃圾渗沥液输送至一级厌氧反应器3进行中温厌氧处理,使垃圾渗沥液中的难溶有机物分解为小分子物质,降低垃圾渗沥液的COD和BOD。S2. Transport the landfill leachate after the preliminary precipitation treatment to the first-stage anaerobic reactor 3 for medium-temperature anaerobic treatment, so that the insoluble organic matter in the landfill leachate is decomposed into small molecular substances, and the density of the landfill leachate is reduced. COD and BOD.

其中,中温厌氧处理的温度为35℃-38℃。Among them, the temperature of the mesophilic anaerobic treatment is 35°C-38°C.

经过中温厌氧处理,垃圾渗沥液中的难溶有机污染物首先被分解为可溶性大分子物质,再被分解为小分子有机酸,最后被分解为二氧化碳、甲烷、水、氨氮、硫化氢、磷酸盐、无机盐等小分子物质。After mesophilic anaerobic treatment, insoluble organic pollutants in landfill leachate are first decomposed into soluble macromolecular substances, then decomposed into small molecular organic acids, and finally decomposed into carbon dioxide, methane, water, ammonia nitrogen, hydrogen sulfide, Small molecular substances such as phosphates and inorganic salts.

在进入一级厌氧反应器3前,先对垃圾渗沥液进行均质均量处理,保证垃圾渗沥液进入后续各处理单元的水质、水量稳定。均质均量处理可在调节池2内实现,经过初步沉淀处理后的垃圾渗沥液先输送至调节池2内,再送至一级厌氧反应器3。Before entering the first-level anaerobic reactor 3, the landfill leachate is subjected to homogeneous and uniform treatment to ensure that the water quality and quantity of the landfill leachate entering the subsequent treatment units are stable. Homogeneous and homogeneous treatment can be realized in the conditioning tank 2 , and the landfill leachate after preliminary precipitation treatment is first transported to the conditioning tank 2 , and then sent to the primary anaerobic reactor 3 .

S3、将经过中温厌氧处理后的垃圾渗沥液输送至二级厌氧反应器4进行二级厌氧处理,去除其中的有机物。S3. The landfill leachate after the mesophilic anaerobic treatment is transported to the secondary anaerobic reactor 4 for secondary anaerobic treatment to remove the organic matter therein.

在上述的两级厌氧处理中,垃圾渗沥液在厌氧环境下,通过厌氧微生物的作用,使其中的有机污染物绝大部分分解成小分子物质,降低COD和BOD。同时,厌氧反应器对硬度也有一定的去除率,去除率能达到70%左右,硬度的去除大大减少了后续处理单元的加药量。In the above-mentioned two-stage anaerobic treatment, the landfill leachate in the anaerobic environment, through the action of anaerobic microorganisms, decomposes most of the organic pollutants into small molecular substances, reducing COD and BOD. At the same time, the anaerobic reactor also has a certain removal rate for hardness, and the removal rate can reach about 70%. The removal of hardness greatly reduces the dosage of the subsequent treatment unit.

在上述的两级厌氧处理中,二级厌氧反应器4水力停留时间比一级厌氧反应器3短。一级厌氧反应器3和二级厌氧反应器4可采用UASB反应器或IC反应器。另外,上述厌氧处理中产生的沼气可收集至储气柜,由管道输送至电厂焚烧炉焚烧,同时设置应急火炬。In the above-mentioned two-stage anaerobic treatment, the hydraulic retention time of the second-stage anaerobic reactor 4 is shorter than that of the first-stage anaerobic reactor 3 . The primary anaerobic reactor 3 and the secondary anaerobic reactor 4 may adopt a UASB reactor or an IC reactor. In addition, the biogas generated in the above-mentioned anaerobic treatment can be collected in the gas storage tank, and transported by pipeline to the incinerator of the power plant for incineration, and an emergency flare is set at the same time.

一级厌氧反应器3和二级厌氧反应器4底部沉淀积聚形成的污泥可通过动力泵排至污泥池10。The sludge formed by precipitation and accumulation at the bottom of the primary anaerobic reactor 3 and the secondary anaerobic reactor 4 can be discharged to the sludge tank 10 through a power pump.

S4、将经过二级厌氧处理后的垃圾渗沥液输送至厌氧沉淀池5进行厌氧沉淀处理。S4. The landfill leachate after the secondary anaerobic treatment is transported to the anaerobic sedimentation tank 5 for anaerobic sedimentation treatment.

厌氧沉淀池5主要是供二级厌氧处理后的垃圾渗沥液在其中进行停留沉淀,避免厌氧出水污泥浓度过高,影响后续处理工艺。厌氧沉淀池5内底部沉淀积聚形成的污泥可通过动力泵排至污泥池10。The anaerobic sedimentation tank 5 is mainly for the landfill leachate after the secondary anaerobic treatment to stay and settle in it, so as to avoid the high concentration of the anaerobic effluent sludge and affect the subsequent treatment process. The sludge formed by sedimentation and accumulation at the bottom of the anaerobic sedimentation tank 5 can be discharged to the sludge tank 10 through a power pump.

本实施例中,厌氧沉淀池5内置中心筒,形成中心进水周边出水的形式,厌氧沉淀池5底部设置为泥渣斗形式,便于排出污泥,污泥可排至污泥池10。In this embodiment, the anaerobic sedimentation tank 5 has a built-in center cylinder to form a form of water inflow around the center, and the bottom of the anaerobic sedimentation tank 5 is set in the form of a sludge hopper, which is convenient for discharging sludge, and the sludge can be discharged to the sludge tank 10 .

S5、将厌氧沉淀池5的出水送至软化反应器6并投加氢氧化钙进行软化处理,根据在线测得的pH值调整氢氧化钙的加入量。S5, the effluent of the anaerobic sedimentation tank 5 is sent to the softening reactor 6 and calcium hydroxide is added for softening treatment, and the amount of calcium hydroxide added is adjusted according to the pH value measured online.

软化处理时,可通过自动加药装置往软化反应器6内投入氢氧化钙(熟石灰),垃圾渗沥液与氢氧化钙反应进行混凝沉淀,去除垃圾渗沥液中的大部分硬度。氢氧化钙的投入量根据垃圾渗沥液的pH值调整,自动加药装置可根据垃圾渗沥液的pH值等情况调整氢氧化钙的投入量,调节软化反应器6内的pH值为11-12。软化反应器6的pH值由pH计61在线监测。During the softening treatment, calcium hydroxide (slaked lime) can be put into the softening reactor 6 through the automatic dosing device, and the landfill leachate reacts with calcium hydroxide for coagulation and precipitation to remove most of the hardness in the landfill leachate. The input amount of calcium hydroxide is adjusted according to the pH value of the landfill leachate, and the automatic dosing device can adjust the input amount of calcium hydroxide according to the pH value of the landfill leachate, etc., and adjust the pH value in the softening reactor 6 to 11 -12. The pH of the softening reactor 6 is monitored online by a pH meter 61 .

S6、将软化处理后的垃圾渗沥液输送至管式微滤膜7,过滤去除垃圾渗沥液中的悬浮物和有机微生物,得到澄清的清液。S6. The softened landfill leachate is transported to the tubular microfiltration membrane 7, and the suspended solids and organic microorganisms in the landfill leachate are filtered and removed to obtain a clear clear liquid.

其中,管式微滤膜7的微滤膜孔径可选0.5μm。Wherein, the microfiltration membrane pore size of the tubular microfiltration membrane 7 can be selected as 0.5 μm.

S7、将过滤后得到的清液输送至蒸氨塔8进行蒸氨处理,去除清液中的氨氮,还去除部分易挥发的COD。S7, the clear liquid obtained after filtration is transported to the ammonia distillation tower 8 for ammonia distillation treatment to remove ammonia nitrogen in the clear liquid, and also remove part of volatile COD.

由于清液中的氨氮,多以氨离子(NH4+)和游离氨(NH3)的状态存在并保持平衡,两者的平衡关系受pH值影响。当pH值为7时,氨氮多以NH4+的状态存在,而当pH值为11左右时,氨氮90%以NH3形态存在,游离氨(NH3)易于从水中逸出。因此,本实施例中,蒸氨塔8采用鼓风氨气吹脱塔,促使氨从清液中逸出,蒸氨塔8对氨氮的去除率可以达到95%以上。为避免逸出的氨气造成二次污染,将逸出的氨气采取管路回收,经泵送至电厂脱硝系统。Due to the ammonia nitrogen in the supernatant, it mostly exists in the state of ammonia ion (NH4+) and free ammonia ( NH3 ) and maintains a balance, and the equilibrium relationship between the two is affected by pH value. When the pH value is 7, the ammonia nitrogen mostly exists in the state of NH4+, and when the pH value is about 11, 90% of the ammonia nitrogen exists in the form of NH3 , and free ammonia ( NH3 ) is easy to escape from the water. Therefore, in this embodiment, the ammonia distillation tower 8 adopts a blast ammonia gas stripping tower to promote the escape of ammonia from the clear liquid, and the removal rate of ammonia nitrogen by the ammonia distillation tower 8 can reach more than 95%. In order to avoid secondary pollution caused by the escaping ammonia gas, the escaping ammonia gas is recovered by pipeline and pumped to the denitrification system of the power plant.

S8、将蒸氨塔8的出水送至内置式MBR 9,经过反硝化、硝化作用,生化去除其中的可生化有机物并进行生物脱氮,使最后出水达到排放标准。S8. The effluent of the ammonia distillation tower 8 is sent to the built-in MBR 9, and through denitrification and nitrification, the biochemical organic matter therein is biochemically removed and biological denitrification is carried out, so that the final effluent reaches the discharge standard.

内置式MBR 9中,反硝化池91和硝化池92内沉淀积聚形成的污泥可通过动力泵等排至污泥池10。In the built-in MBR 9, the sludge formed by precipitation and accumulation in the denitrification tank 91 and the nitrification tank 92 can be discharged to the sludge tank 10 through a power pump or the like.

进一步地,根据需要,本发明的处理方法还包括以下步骤:Further, as required, the processing method of the present invention also comprises the following steps:

S9、通过应急纳滤装置12对内置式MBR的出水进行过滤处理,降低出水的有机物指标,保证出水符合排放标准。S9. The effluent of the built-in MBR is filtered through the emergency nanofiltration device 12 to reduce the organic matter index of the effluent and ensure that the effluent meets the discharge standard.

综上,本发明的处理系统及方法,能够减少膜浓缩液产生,降低垃圾焚烧发电厂关于垃圾渗沥液处理的吨水投资成本、处理成本以及占地面积,实现降低成本且处理效果好的目的。In summary, the treatment system and method of the present invention can reduce the production of membrane concentrate, reduce the investment cost per ton of water, treatment cost and floor space for landfill leachate treatment in waste incineration power plants, and achieve cost reduction and good treatment effect. Purpose.

以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。The above descriptions are only the embodiments of the present invention, and are not intended to limit the scope of the present invention. Any equivalent structure or equivalent process transformation made by using the contents of the description and drawings of the present invention, or directly or indirectly applied to other related technologies Fields are similarly included in the scope of patent protection of the present invention.

Claims (10)

1.一种垃圾焚烧发电厂的垃圾渗沥液处理系统,其特征在于,包括接入垃圾渗滤液的初沉池、依序对垃圾渗沥液进行中温厌氧处理的一级厌氧反应器和二级厌氧反应器、厌氧沉淀池、对厌氧处理后的垃圾渗沥液进行软化处理的软化反应器、对软化后的垃圾渗沥液进行过滤处理的管式微滤膜、对过滤得到的清液进行蒸氨处理的蒸氨塔、对蒸氨后的清液进行生化处理和过滤处理的内置式MBR;1. a landfill leachate treatment system of a waste incineration power plant, is characterized in that, comprises the primary settling tank of access landfill leachate, the one-stage anaerobic reactor that the landfill leachate is carried out to the middle temperature anaerobic treatment in sequence and secondary anaerobic reactor, anaerobic sedimentation tank, softening reactor for softening anaerobic treatment of landfill leachate, tubular microfiltration membrane for filtration treatment of softened landfill leachate, The obtained clear liquid is subjected to ammonia distillation tower for ammonia distillation, and the built-in MBR for biochemical treatment and filtration treatment of the clear liquid after ammonia distillation; 所述初沉池、一级厌氧反应器、二级厌氧反应器、厌氧沉淀池、软化反应器、管式微滤膜、蒸氨塔以及内置式MBR按垃圾渗沥液的流通处理方向依次连接。The primary sedimentation tank, the primary anaerobic reactor, the secondary anaerobic reactor, the anaerobic sedimentation tank, the softening reactor, the tubular microfiltration membrane, the ammonia distillation tower and the built-in MBR are processed according to the flow of the landfill leachate. Connect in sequence. 2.根据权利要求1所述的垃圾渗沥液处理系统,其特征在于,所述垃圾渗沥液处理系统还包括设置在所述初沉池前端、对垃圾渗沥液进行过滤处理的篮式过滤器和自清洗过滤器。2 . The landfill leachate treatment system according to claim 1 , wherein the landfill leachate treatment system further comprises a basket type disposed at the front end of the primary sedimentation tank for filtering and treating the landfill leachate. 3 . filters and self-cleaning filters. 3.根据权利要求2所述的垃圾渗沥液处理系统,其特征在于,所述篮式过滤器的过滤精度为5mm或10mm;所述自清洗过滤器的过滤精度为1mm或2mm。3 . The landfill leachate treatment system according to claim 2 , wherein the filtration precision of the basket filter is 5 mm or 10 mm; the filtration precision of the self-cleaning filter is 1 mm or 2 mm. 4 . 4.根据权利要求1所述的垃圾渗沥液处理系统,其特征在于,所述垃圾渗沥液处理系统还包括对垃圾渗沥液进行均质均量处理的调节池;所述调节池连接在所述初沉池和一级厌氧反应器之间。4 . The landfill leachate treatment system according to claim 1 , wherein the landfill leachate treatment system further comprises a regulating tank for performing homogeneous and homogeneous treatment on the landfill leachate; the regulating pool is connected to between the primary settling tank and the primary anaerobic reactor. 5.根据权利要求1所述的垃圾渗沥液处理系统,其特征在于,所述一级厌氧反应器和二级厌氧反应器的厌氧反应温度均为35℃-38℃。5 . The landfill leachate treatment system according to claim 1 , wherein the anaerobic reaction temperature of the primary anaerobic reactor and the secondary anaerobic reactor is both 35°C to 38°C. 6 . 6.根据权利要求1所述的垃圾渗沥液处理系统,其特征在于,所述管式微滤膜的微滤膜孔径为0.1-0.5μm。6 . The landfill leachate treatment system according to claim 1 , wherein the microfiltration membrane pore size of the tubular microfiltration membrane is 0.1-0.5 μm. 7 . 7.根据权利要求1-6任一项所述的垃圾渗沥液处理系统,其特征在于,所述垃圾渗沥液处理系统还包括污泥池以及连接所述污泥池的污泥脱水处理装置;所述初沉池、一级厌氧反应器、二级厌氧反应器、厌氧沉淀池以及内置式MBR分别连接所述污泥池;和/或,7 . The landfill leachate treatment system according to claim 1 , wherein the landfill leachate treatment system further comprises a sludge tank and a sludge dewatering treatment connected to the sludge tank. 8 . device; the primary sedimentation tank, the primary anaerobic reactor, the secondary anaerobic reactor, the anaerobic sedimentation tank and the built-in MBR are respectively connected to the sludge tank; and/or, 所述垃圾渗沥液处理系统还包括连接在所述内置式MBR的出水端的应急纳滤装置,对所述内置式MBR的出水进行过滤处理。The landfill leachate treatment system further includes an emergency nanofiltration device connected to the water outlet end of the built-in MBR to filter the effluent of the built-in MBR. 8.一种垃圾焚烧发电厂的垃圾渗沥液处理方法,其特征在于,包括以下步骤:8. A method for treating landfill leachate in a waste incineration power plant, comprising the following steps: S1、垃圾渗沥液进入初沉池进行初步沉淀处理;S1. The landfill leachate enters the primary sedimentation tank for preliminary sedimentation treatment; S2、将经过初步沉淀处理后的垃圾渗沥液输送至一级厌氧反应器进行中温厌氧处理,使垃圾渗沥液中的难溶有机物分解为小分子物质;S2. The landfill leachate after preliminary precipitation treatment is transported to the first-stage anaerobic reactor for mesophilic anaerobic treatment, so that the insoluble organic matter in the landfill leachate is decomposed into small molecular substances; S3、将经过中温厌氧处理后的垃圾渗沥液输送至二级厌氧反应器进行二级厌氧处理,去除其中的有机物;S3. Transporting the landfill leachate after the mesothermal anaerobic treatment to the secondary anaerobic reactor for secondary anaerobic treatment to remove the organic matter therein; S4、将经过二级厌氧处理后的垃圾渗沥液输送至厌氧沉淀池进行厌氧沉淀处理;S4. Transport the landfill leachate after the secondary anaerobic treatment to the anaerobic sedimentation tank for anaerobic sedimentation treatment; S5、将厌氧沉淀池的出水送至软化反应器并投加氢氧化钙进行软化处理, 根据在线测得的pH值调整氢氧化钙的加入量;S5, the effluent of the anaerobic sedimentation tank is sent to the softening reactor and calcium hydroxide is added for softening treatment, and the amount of calcium hydroxide added is adjusted according to the pH value measured online; S6、将软化处理后的垃圾渗沥液输送至管式微滤膜,过滤去除垃圾渗沥液中的悬浮物和有机微生物;S6. Transport the softened landfill leachate to a tubular microfiltration membrane, and filter to remove suspended solids and organic microorganisms in the landfill leachate; S7、将过滤后得到的清液输送至蒸氨塔进行蒸氨处理,去除清液中的氨氮;S7, the clear liquid obtained after the filtration is transported to the ammonia distillation tower to carry out the ammonia distillation process, and the ammonia nitrogen in the clear liquid is removed; S8、将蒸氨塔的出水送至内置式MBR,经过反硝化、硝化作用,生化去除其中的可生化有机物并进行生物脱氮。S8. The effluent of the ammonia distillation tower is sent to the built-in MBR, and through denitrification and nitrification, the biochemical organic matter therein is biochemically removed and biological denitrification is carried out. 9.根据权利要求8所述的垃圾渗沥液处理方法,其特征在于,步骤S1中,垃圾渗沥液进入初沉池前,先依次经过篮式过滤器和自清洗过滤器进行过滤处理;9. The method for treating landfill leachate according to claim 8, wherein in step S1, before the landfill leachate enters the primary settling tank, it is filtered through a basket filter and a self-cleaning filter in sequence; 步骤S2中,经过初步沉淀处理后的垃圾渗沥液先输送至调节池内进行均质均量处理,再送至一级厌氧反应器。In step S2, the landfill leachate after preliminary precipitation treatment is firstly transported to the conditioning tank for homogeneous and homogeneous treatment, and then sent to the primary anaerobic reactor. 10.根据权利要求8或9所述的垃圾渗沥液处理方法,其特征在于,所述垃圾渗沥液处理方法还包括以下步骤:10. The landfill leachate treatment method according to claim 8 or 9, wherein the landfill leachate treatment method further comprises the following steps: S9、通过应急纳滤装置对所述内置式MBR的出水进行过滤处理,降低所述出水的有机物指标。S9, filtering the effluent of the built-in MBR through an emergency nanofiltration device to reduce the organic matter index of the effluent.
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