CN111440670A - Formula of cleaning agent, preparation method of cleaning agent and use method of cleaning agent - Google Patents
Formula of cleaning agent, preparation method of cleaning agent and use method of cleaning agent Download PDFInfo
- Publication number
- CN111440670A CN111440670A CN201910040712.9A CN201910040712A CN111440670A CN 111440670 A CN111440670 A CN 111440670A CN 201910040712 A CN201910040712 A CN 201910040712A CN 111440670 A CN111440670 A CN 111440670A
- Authority
- CN
- China
- Prior art keywords
- sodium
- parts
- cleaning agent
- detergent
- imidazoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000003599 detergent Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 14
- 239000002738 chelating agent Substances 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 150000001447 alkali salts Chemical class 0.000 claims description 12
- 239000004115 Sodium Silicate Substances 0.000 claims description 9
- 238000009472 formulation Methods 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 102000004190 Enzymes Human genes 0.000 claims description 8
- 108090000790 Enzymes Proteins 0.000 claims description 8
- 239000007844 bleaching agent Substances 0.000 claims description 8
- -1 fatty acid salt Chemical class 0.000 claims description 8
- 239000002455 scale inhibitor Substances 0.000 claims description 8
- 239000012190 activator Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000004061 bleaching Methods 0.000 claims description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000004382 Amylase Substances 0.000 claims description 4
- 102000013142 Amylases Human genes 0.000 claims description 4
- 108010065511 Amylases Proteins 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- BQTOJCOSKKLTAB-UHFFFAOYSA-L [Na+].O1P(OC1CO)(=O)OP(=O)([O-])[O-].[Na+] Chemical compound [Na+].O1P(OC1CO)(=O)OP(=O)([O-])[O-].[Na+] BQTOJCOSKKLTAB-UHFFFAOYSA-L 0.000 claims description 4
- FENRSEGZMITUEF-ATTCVCFYSA-E [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] FENRSEGZMITUEF-ATTCVCFYSA-E 0.000 claims description 4
- 235000019418 amylase Nutrition 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 229940083982 sodium phytate Drugs 0.000 claims description 4
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 claims description 4
- 108091005804 Peptidases Proteins 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 3
- PDIZYYQQWUOPPK-UHFFFAOYSA-N acetic acid;2-(methylamino)acetic acid Chemical compound CC(O)=O.CC(O)=O.CNCC(O)=O PDIZYYQQWUOPPK-UHFFFAOYSA-N 0.000 claims description 3
- 239000013522 chelant Substances 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical group CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 2
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 claims description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 2
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 2
- QUPKCFBHJFNUEW-UHFFFAOYSA-N 2-ethyl-4,5-dihydro-1h-imidazole Chemical compound CCC1=NCCN1 QUPKCFBHJFNUEW-UHFFFAOYSA-N 0.000 claims description 2
- FDGBQHCDMSYZRC-UHFFFAOYSA-N 2-hydroxy-2-oxo-1,3,2$l^{5}-dioxaphosphinan-4-amine Chemical compound NC1CCOP(O)(=O)O1 FDGBQHCDMSYZRC-UHFFFAOYSA-N 0.000 claims description 2
- VWSLLSXLURJCDF-UHFFFAOYSA-N 2-methyl-4,5-dihydro-1h-imidazole Chemical compound CC1=NCCN1 VWSLLSXLURJCDF-UHFFFAOYSA-N 0.000 claims description 2
- 239000004155 Chlorine dioxide Substances 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 2
- 102000004882 Lipase Human genes 0.000 claims description 2
- 239000004367 Lipase Substances 0.000 claims description 2
- 108090001060 Lipase Proteins 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 2
- DDAQLPYLBPPPRV-UHFFFAOYSA-N [4-(hydroxymethyl)-2-oxo-1,3,2lambda5-dioxaphosphetan-2-yl] dihydrogen phosphate Chemical compound OCC1OP(=O)(OP(O)(O)=O)O1 DDAQLPYLBPPPRV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical group [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- GXUACSARIHYYTF-UHFFFAOYSA-G heptasodium;[oxido-[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O GXUACSARIHYYTF-UHFFFAOYSA-G 0.000 claims description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 2
- 235000019421 lipase Nutrition 0.000 claims description 2
- 235000002949 phytic acid Nutrition 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 108010064470 polyaspartate Proteins 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229940080818 propionamide Drugs 0.000 claims description 2
- 235000019419 proteases Nutrition 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 2
- 229960001922 sodium perborate Drugs 0.000 claims description 2
- 229940045872 sodium percarbonate Drugs 0.000 claims description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 2
- NWPMTMCXJZTLSO-UHFFFAOYSA-M sodium;4-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 NWPMTMCXJZTLSO-UHFFFAOYSA-M 0.000 claims description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 2
- OHOTVSOGTVKXEL-WJXVXWFNSA-K trisodium;(2s)-2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)[C@H](C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-WJXVXWFNSA-K 0.000 claims description 2
- GOHZKUSWWGUUNR-UHFFFAOYSA-N 2-(4,5-dihydroimidazol-1-yl)ethanol Chemical compound OCCN1CCN=C1 GOHZKUSWWGUUNR-UHFFFAOYSA-N 0.000 claims 1
- 101710180316 Protease 2 Proteins 0.000 claims 1
- JBFYUZGYRGXSFL-UHFFFAOYSA-N imidazolide Chemical compound C1=C[N-]C=N1 JBFYUZGYRGXSFL-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 description 13
- 235000013305 food Nutrition 0.000 description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 2
- 244000017020 Ipomoea batatas Species 0.000 description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- WGTDLPBPQKAPMN-KTKRTIGZSA-N 2-[2-[(z)-heptadec-8-enyl]-4,5-dihydroimidazol-1-yl]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCC1=NCCN1CCO WGTDLPBPQKAPMN-KTKRTIGZSA-N 0.000 description 1
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 1
- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical compound O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100000171 higher toxicity Toxicity 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a formula of a cleaning agent, a preparation method and a using method of the cleaning agent, wherein the formula of the cleaning agent comprises the following components in parts by weight:
Description
Technical Field
The invention relates to the field of daily chemicals, in particular to a formula of a cleaning agent and a preparation method of the cleaning agent.
Background
Food can drip or splash on the surface of the inner container when the steam box and the oven are used, and the food is oxidized and solidified after being heated at high temperature and firmly adhered to the surface of the inner container, so that the steam box and the oven bring great troubles to users for cleaning. The prior art proposal is a cleaning agent containing alkali salt, surfactant, boiling agent, scale inhibitor and other components, or cleaning with glycol ether, isopropanol and other organic solvents, which have higher toxicity. The cleaning agent containing the surfactant has poor cleaning effect on stubborn dirt and cannot clean the stubborn dirt. The organic solvent has relatively good cleaning effect, but cannot be completely cleaned, and the organic solvent is easy to volatilize and absorb into human bodies, thus being harmful to human health.
CN200510027112.7 discloses a high-solid-content scale-inhibition type tableware detergent, which comprises: 30-50% of caustic alkali; 1-5% of an alkali-resistant low-foaming surfactant; 0.5-5% of an organic multi-phosphonate scale inhibitor; 10-40% of a chelating agent; 5-25% of a builder; 0.5-3% of an organic silicon defoaming agent; 0.1-1% of chlorine-containing bactericide; the balance of water. According to the application, high-concentration alkali, low-foaming surfactant, chelating agent and organic polyphosphonate are compounded, so that the detergency is improved, and the water-insoluble salt generated by the surfactant, calcium, magnesium and other ions in water and the protein and fatty acid in dirt is reduced, so that the scale formation on the surface of a conductive electrode and the residue on the surface to be cleaned are realized. The chelating agent contains chlorine bactericide, and has bactericidal effect. However, the detergent is not effective in removing stubborn dirt.
Disclosure of Invention
The invention aims to solve the technical problem of providing an environment-friendly detergent formula capable of effectively removing stubborn dirt aiming at the current situation of the prior art.
The technical scheme adopted by the invention for solving the technical problems is as follows: the formula of the cleaning agent is characterized by comprising the following components in parts by weight:
the alkali salt is selected from sodium carbonate and/or sodium metasilicate;
the surfactant is selected from at least one of fatty acid salt anionic surfactant, fatty alcohol polyoxyalkyl ether nonionic surfactant and EO-PO type block polyether nonionic surfactant;
the chelating agent is at least one selected from citrate, ethylene diamine tetraacetic acid tetrasodium salt, methylglycine diacetic acid trisodium salt, hydroxyethylidene diphosphate, diethyl diamido pentaphosphate sodium, aminotrimethylene phosphate, polyaspartate and phytate;
the bleaching agent is selected from sodium percarbonate, sodium perborate, sodium persulfate, sodium hypochlorite or chlorine dioxide;
the bleaching activator is selected from tetraacetylethylenediamine, sodium p-acetoxy-benzenesulfonate or triacetyl ethyl cyanurate;
the scale inhibitor is selected from at least one of polyacrylic acid, acrylic acid and maleic anhydride copolymer, sodium epoxy succinate and acrylic acid and propionamide copolymer;
the water-soluble organic solvent is at least one selected from propylene glycol methyl ether, propylene glycol n-butyl ether, propylene glycol n-propyl ether, dipropylene glycol n-propyl ether and triisopropanolamine;
the corrosion inhibitor is selected from at least one of benzotriazole and imidazole line compound;
the enzyme is selected from at least one of lipase, amylase and protease.
Preferably, the alkali salt comprises 15-30 parts of sodium carbonate and 5-10 parts of sodium metasilicate.
More preferably, the alkali salt comprises 25 parts of sodium carbonate and 10 parts of sodium metasilicate; the using amount of the sodium hydroxide is 0 part.
Preferably, the enzyme is 1 part of amylase and 2 parts of protease.
Preferably, the chelating agent may include 1-5 parts of sodium hydroxyethylidene diphosphate, 5-15 parts of trisodium methylglycinediacetate and 1-5 parts of sodium phytate.
Preferably, the chelating agent comprises 3 parts of hydroxyethylidene diphosphate sodium, 5 parts of methylglycine diacetic acid trisodium and 2 parts of sodium phytate.
In each of the above embodiments, the imidazolone complex is preferably at least one selected from the group consisting of 2-methylimidazoline, 2-ethylimidazoline, oleylhydroxyethylimidazoline, betaine imidazoline, imidazoline amide, and cycloalkyl imidazoline.
Preferably, the layered crystalline sodium disilicate is used in an amount of 10 to 20 parts.
More preferably, the layered crystalline sodium disilicate is used in an amount of 10 parts by weight.
The method for preparing the cleaning agent by using the cleaning agent formula in each scheme is characterized by comprising the following steps:
1) weighing the components according to the formula
2) Sequentially adding the alkali salt, the chelating agent, the bleaching agent and the scale inhibitor into a container, and uniformly stirring;
3) adding the bleaching activator and the enzyme into a container, and uniformly stirring;
4) adding the organic solvent and the pre-mixed mixture of the surfactant and the modified layered sodium silicate into a container, and uniformly stirring to obtain a detergent mixture;
5) and grinding the cleaning agent mixture into powder with uniform granularity to obtain the cleaning agent powder.
The method for using the prepared detergent is characterized in that the prepared detergent powder is diluted by adding 5-10 times of water for use.
The alkali salt in the formula can provide an alkaline environment for the formula, so that saponification of grease is facilitated, and emulsification is promoted by the alkali salt in cooperation with a surfactant; the surfactant promotes dirt to be separated from the surface of the base material through penetration, wetting and emulsification; the chelating agent can chelate calcium, magnesium, iron, zinc and other ions in hard water and dirt, prevent the surfactant from losing efficacy due to the hard water, and chelate the calcium, magnesium and chelating agent in the dirt to separate from the substrate; bleaching agents help the soil break down by oxidation, leaving the substrate surface; the bleaching activator assists the bleaching agent to decompose active oxygen; the scale inhibitor prevents secondary precipitation of dirt; the water-soluble organic solvent can permeate the bottom layer of the dirt to promote the dirt to swell and dissolve; the corrosion inhibitor can protect the base material from being corroded; the enzyme can decompose the corresponding dirt; the modified phyllosilicate can adsorb a surfactant during dosing, can adsorb calcium and magnesium ions and dirt during cleaning, and can be used as an abrasive during wiping.
Compared with the prior art, the formula of the cleaning agent, the preparation method of the cleaning agent and the using method provided by the invention can easily and effectively remove stubborn stains, are environment-friendly, meet the GB14930.1 national standard for food safety detergent, and are particularly suitable for being used as the cleaning agent for food containers.
Detailed Description
The present invention will be described in further detail with reference to examples.
The formulations of examples 1 to 5 are shown in table 1.
The preparation method of the cleaning agent comprises the following steps:
1) weighing the components according to the formula
2) Sequentially adding the alkali salt, the chelating agent, the bleaching agent and the scale inhibitor into a container, and uniformly stirring;
3) adding the bleaching activator and the enzyme into a container, and uniformly stirring;
4) adding the organic solvent and the pre-mixed mixture of the surfactant and the modified layered sodium silicate into a container, and uniformly stirring to obtain a detergent mixture;
5) and grinding the cleaning agent mixture into powder with uniform granularity to obtain the cleaning agent powder.
TABLE 1
Note: tetraacetylethylenediamine in table 1 is a bleach activator.
The detergent powder prepared in each example is detected, and the product of each example conforms to GB14930.1 national standard for food safety detergent.
And (3) washing performance test:
1. preparation of Standard contaminants
The food cooked by a steam box or an oven is various, three categories of protein, fat and starch are summarized, the representative food which is the most difficult to treat in the three categories of pollutants is taken as standard pollutants, namely chicken wings, fish and sweet potatoes, the cooking process of steaming and baking combination is adopted, the specified amount of chicken wings, fish and sweet potatoes are cooked according to the program, the cooking process is taken as a cycle, two cycles are taken every day, and the mixed residues are taken as the final standard pollutants after five days.
2. Cleaning of
A Fangtai ZK55-Z3 steaming oven is used, a cleaning program is selected, the cleaning temperature is 60-70 ℃, the cleaning time is 20 minutes, and 300 g of water vapor is sprayed to the inner container at intervals in the cleaning process. Uniformly coating 30 g of cleaning agent powder on the bottom of the inner container to be cleaned, starting a cleaning procedure to clean, cooling after the cleaning procedure is finished, wiping the surface of the inner container with rag, and observing the cleaning degree.
The cleaning results are shown in table 2:
TABLE 2
Note: comparative 1 in Table 2 uses a Miller liner cleaner in place of the example powder; comparative example 2 a commercially available dishwashing powder was used in place of the example powder.
Claims (10)
1. The formula of the cleaning agent is characterized by comprising the following components in parts by weight:
the alkali salt is selected from sodium carbonate and/or sodium metasilicate;
the surfactant is selected from at least one of fatty acid salt anionic surfactant, fatty alcohol polyoxyalkyl ether nonionic surfactant and EO-PO type block polyether nonionic surfactant;
the chelating agent is at least one selected from citrate, ethylene diamine tetraacetic acid tetrasodium salt, methylglycine diacetic acid trisodium salt, hydroxyethylidene diphosphate, diethyl diamido pentaphosphate sodium, aminotrimethylene phosphate, polyaspartate and phytate;
the bleaching agent is selected from sodium percarbonate, sodium perborate, sodium persulfate, sodium hypochlorite or chlorine dioxide;
the bleaching activator is selected from tetraacetylethylenediamine, sodium p-acetoxy-benzenesulfonate or triacetyl ethyl cyanurate;
the scale inhibitor is selected from at least one of polyacrylic acid, acrylic acid and maleic anhydride copolymer, sodium epoxy succinate and acrylic acid and propionamide copolymer;
the water-soluble organic solvent is at least one selected from propylene glycol methyl ether, propylene glycol n-butyl ether, propylene glycol n-propyl ether, dipropylene glycol n-propyl ether and triisopropanolamine;
the corrosion inhibitor is selected from at least one of benzotriazole and imidazole line compound;
the enzyme is selected from at least one of lipase, amylase and protease.
2. The detergent formulation of claim 1, wherein said alkali salt comprises 15-30 parts sodium carbonate and 5-10 parts sodium metasilicate.
3. The detergent formulation of claim 2, wherein said alkali salt comprises 25 parts sodium carbonate and 10 parts sodium metasilicate; the using amount of the sodium hydroxide is 0 part.
4. The detergent formulation of claim 1, wherein said enzyme is amylase 1 part and protease 2 parts.
5. The cleaner formulation of claim 1 wherein the chelant comprises 1-5 parts sodium hydroxyethylidene diphosphate, 5-15 parts trisodium methylglycinediacetate, and 1-5 parts sodium phytate.
6. The detergent formulation of claim 5, wherein the chelating agent comprises 3 parts sodium hydroxyethylidene diphosphate, 5 parts trisodium methylglycinediacetate, and 2 parts sodium phytate.
7. The detergent formulation of claim 1, wherein said imidazolate bath complex is selected from at least one of 2-methyl imidazoline, 2-ethyl imidazoline, oleic hydroxyethyl imidazoline, betaine imidazoline, imidazoline amide, and cycloalkyl imidazoline.
8. The detergent formulation according to any one of claims 1 to 6, characterized in that the layered crystalline sodium disilicate is used in an amount of 10-20 parts.
9. A process for preparing a detergent formulation as claimed in any one of claims 1 to 8, characterized by the steps of:
1) weighing the components according to the formula
2) Sequentially adding the alkali salt, the chelating agent, the bleaching agent and the scale inhibitor into a container, and uniformly stirring;
3) adding the bleaching activator and the enzyme into a container, and uniformly stirring;
4) adding the organic solvent and the pre-mixed mixture of the surfactant and the modified layered sodium silicate into a container, and uniformly stirring to obtain a detergent mixture;
5) and grinding the cleaning agent mixture into powder with uniform granularity to obtain the cleaning agent powder.
10. The method of using the detergent prepared according to claim 9, wherein the detergent powder is diluted with 5 to 10 times of water and used.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114540825A (en) * | 2021-03-15 | 2022-05-27 | 广东多创新材料科技有限公司 | Oil-removing wax-removing powder and preparation method thereof |
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