[go: up one dir, main page]

CN111426148A - A method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration - Google Patents

A method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration Download PDF

Info

Publication number
CN111426148A
CN111426148A CN201911304502.2A CN201911304502A CN111426148A CN 111426148 A CN111426148 A CN 111426148A CN 201911304502 A CN201911304502 A CN 201911304502A CN 111426148 A CN111426148 A CN 111426148A
Authority
CN
China
Prior art keywords
water
chilled water
refrigerant
air separation
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911304502.2A
Other languages
Chinese (zh)
Inventor
凡殿才
高明林
潘建田
张超
官进军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Haoyuan Chemical Industry Group Co ltd
Original Assignee
Anhui Haoyuan Chemical Industry Group Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Haoyuan Chemical Industry Group Co ltd filed Critical Anhui Haoyuan Chemical Industry Group Co ltd
Priority to CN201911304502.2A priority Critical patent/CN111426148A/en
Publication of CN111426148A publication Critical patent/CN111426148A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04157Afterstage cooling and so-called "pre-cooling" of the feed air upstream the air purification unit and main heat exchange line
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04612Heat exchange integration with process streams, e.g. from the air gas consuming unit
    • F25J3/04618Heat exchange integration with process streams, e.g. from the air gas consuming unit for cooling an air stream fed to the air fractionation unit
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04775Air purification and pre-cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04866Construction and layout of air fractionation equipments, e.g. valves, machines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/30Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
    • F25J2205/32Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes as direct contact cooling tower to produce a cooled gas stream, e.g. direct contact after cooler [DCAC]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/30Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
    • F25J2205/34Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes as evaporative cooling tower to produce chilled water, e.g. evaporative water chiller [EWC]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/70Steam turbine, e.g. used in a Rankine cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/90External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
    • F25J2270/906External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration by heat driven absorption chillers

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Sorption Type Refrigeration Machines (AREA)

Abstract

本发明提供一种利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法。所述利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法包括以下步骤:S1、通过将汽化炉底部灰水进入高压闪蒸罐被闪蒸后,进入低压闪蒸罐进行进一步闪蒸。本发明提供的利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法,通过利用气化炉闪蒸低压蒸汽和溴化锂溶剂组成溴化锂吸收式制冷机,制得溴化锂冷冻水,在空分冷冻水换热器中与水冷塔来的冷冻水进行换热,将冷冻水降温后,再进入氨蒸发器进一步降温,降低了氨蒸发器的液氨消耗,减小了氨蒸发器的负荷;溴化锂溶液循环使用,充分利用了汽化炉闪蒸低压蒸汽的余热,同时也降低了空分预冷系统液氨的消耗,能耗被降低。

Figure 201911304502

The invention provides a method for reducing the energy consumption of air separation by utilizing flashing low-pressure steam in a gasifier for refrigeration. The method for reducing the energy consumption of air separation by flashing low-pressure steam in a gasifier includes the following steps: S1. After the gray water at the bottom of the gasifier enters a high-pressure flash tank to be flashed, it enters a low-pressure flash tank for further flashing . The invention provides a method for reducing the energy consumption of air separation by utilizing the flashing low-pressure steam of a gasifier to cool down the energy consumption of air separation. By utilizing the flashing low-pressure steam of a gasifier and a lithium bromide solvent to form a lithium bromide absorption refrigerator, lithium bromide freezing water is prepared, and the freezing water is refrigerated in the air separation. The water heat exchanger exchanges heat with the chilled water from the water cooling tower. After cooling the chilled water, it enters the ammonia evaporator for further cooling, which reduces the liquid ammonia consumption of the ammonia evaporator and reduces the load of the ammonia evaporator; lithium bromide The solution is recycled, making full use of the waste heat of the low-pressure steam flashing in the vaporizer, and at the same time reducing the consumption of liquid ammonia in the air separation pre-cooling system, and the energy consumption is reduced.

Figure 201911304502

Description

一种利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法A method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration

技术领域technical field

本发明涉及空分装置降低能耗领域,尤其涉及一种利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法。The invention relates to the field of reducing energy consumption of air separation plants, in particular to a method for reducing energy consumption of air separation by utilizing flashing low-pressure steam in a gasifier for refrigeration.

背景技术Background technique

在空分装置中,因对氮气的需求量比较大,分子筛吸附器的再生也需要很大一部分污氮气,可供水冷塔使用的污氮气严重不足。所以要设置冷水机组,使空气出空气冷却塔的温度不高于17℃,保证分子筛吸附器的体积不至于过大和正常生产。In the air separation plant, due to the relatively large demand for nitrogen, the regeneration of the molecular sieve adsorber also requires a large part of the dirty nitrogen, and the dirty nitrogen available for the water cooling tower is seriously insufficient. Therefore, it is necessary to set up a chiller so that the temperature of the air out of the air cooling tower is not higher than 17 ℃, so as to ensure that the volume of the molecular sieve adsorber will not be too large and normal production.

出水冷塔冷冻水设计温度为16.3℃,空冷塔上部进水设计温度为10℃,这样才能保证出空冷塔的空气温度达到设计值12℃。这就需要氨蒸发器有足够的换热能力,其液氨消耗为6136Kg/h;液氨消耗很大,对冰机的负荷影响很大,加重了冰机的负荷。The design temperature of the chilled water in the outlet cooling tower is 16.3°C, and the design temperature of the inlet water at the upper part of the air cooling tower is 10°C, so as to ensure that the air temperature of the outlet air cooling tower reaches the design value of 12°C. This requires the ammonia evaporator to have sufficient heat exchange capacity, and its liquid ammonia consumption is 6136Kg/h; the liquid ammonia consumption is very large, which has a great impact on the load of the ice machine, which increases the load of the ice machine.

因此,有必要提供一种利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法解决上述技术问题。Therefore, it is necessary to provide a method for reducing the energy consumption of air separation by utilizing flashing low-pressure steam in a gasifier to solve the above-mentioned technical problems.

发明内容SUMMARY OF THE INVENTION

本发明提供一种利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法,解决了液氨消耗很大,对冰机的负荷影响很大,加重了冰机的负荷的问题。The invention provides a method for reducing the energy consumption of air separation by utilizing the flashing low-pressure steam of a gasifier for refrigeration, which solves the problem of large consumption of liquid ammonia, great influence on the load of the ice machine, and aggravation of the load of the ice machine.

为解决上述技术问题,本发明提供的利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法包括以下步骤:In order to solve the above-mentioned technical problems, the method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration provided by the present invention comprises the following steps:

S1、通过将汽化炉底部灰水进入高压闪蒸罐被闪蒸后,进入低压闪蒸罐进行进一步闪蒸;S1. After the gray water at the bottom of the vaporization furnace enters the high-pressure flash tank to be flashed, it enters the low-pressure flash tank for further flashing;

S2、低压闪蒸罐顶部的闪蒸低压蒸汽进入溴化锂吸收式制冷机组,在发生器中加热溴化锂稀溶液,使其浓缩成浓溶液,同时产生冷剂蒸汽;S2. The flashed low-pressure steam at the top of the low-pressure flash tank enters the lithium bromide absorption refrigeration unit, and the dilute solution of lithium bromide is heated in the generator to be concentrated into a concentrated solution, and refrigerant steam is generated simultaneously;

S3、再将S2中的冷剂蒸汽排进冷凝器内,这时就会被流经凝汽器传热管内的冷却水冷凝成冷剂水;S3, and then discharge the refrigerant vapor in S2 into the condenser, and then it will be condensed into refrigerant water by the cooling water flowing through the heat transfer tube of the condenser;

S4、再将冷剂水经U型管节流后排至蒸发器,在蒸发器内闪发降温后流入蒸发器冷剂水盘;S4, and then the refrigerant water is throttled through the U-shaped pipe and then discharged to the evaporator, and then flows into the evaporator refrigerant water tray after flashing and cooling in the evaporator;

S5、进入蒸发器冷剂水盘的冷剂水被冷剂水泵进行抽出,再通过冷剂水泵将抽出的冷剂水喷淋在蒸发器传热管表面,吸收传热管内冷水的热量,进行沸腾和蒸发,形成冷剂蒸汽;S5. The refrigerant water entering the refrigerant water pan of the evaporator is pumped out by the refrigerant water pump, and then the refrigerant water pumped out is sprayed on the surface of the evaporator heat transfer pipe by the refrigerant water pump to absorb the heat of the cold water in the heat transfer pipe. Boiling and evaporation to form refrigerant vapor;

S6、再通过将冷剂蒸汽排进吸收器内部,这时就会被回到吸收器的浓溶剂进行吸收,而浓溶剂吸收了冷剂蒸汽后变成稀溶剂,再进入发生器内被加热浓缩;S6. By discharging the refrigerant vapor into the absorber, it will be absorbed by the concentrated solvent returning to the absorber, and the concentrated solvent will absorb the refrigerant vapor and become a dilute solvent, and then enter the generator to be heated concentrate;

S7、冷水进入蒸发器内的热量被冷剂水换热后,使得温度降低,再经过水泵加压后送至空分预冷系统的冷冻水换热器的壳程,并且与管程中冷冻水泵的冷冻水换热,冷水经换热器换热后,温度升高返回发生器内降温,进行循环使用;S7. After the cold water enters the evaporator, the heat is exchanged by the refrigerant water, which reduces the temperature, and then is pressurized by the water pump and sent to the shell side of the chilled water heat exchanger of the air separation pre-cooling system, and is connected with the freezing water in the tube side. The chilled water of the pump exchanges heat, and after the cold water is exchanged by the heat exchanger, the temperature rises and returns to the generator to cool down for recycling;

S8、循环水经补水阀从水冷塔上部进入,与从水冷塔下部进入的污氮气传质传热,被降温后,由冷冻水泵加压后,进入冷冻水换热器的管程,与壳程的溴化锂冷水换热后,使其温度降低,并且排出的冷冻水换热器的冷冻水进入氨蒸发器的管程与壳程的液氨换热,温度被进一步降低后进入空冷塔的上部,为空冷塔提供冷却用水;S8. The circulating water enters from the upper part of the water-cooling tower through the replenishment valve, and transfers heat and mass with the sewage nitrogen entering from the lower part of the water-cooling tower. After the lithium bromide cold water heat exchange in the process, its temperature is lowered, and the chilled water of the discharged chilled water heat exchanger enters the tube side of the ammonia evaporator to exchange heat with the liquid ammonia in the shell side, and the temperature is further lowered into the upper part of the air cooling tower , to provide cooling water for the air cooling tower;

32℃的水冷塔C41102补水,经补水阀从水冷塔C41102上部进入,与从水冷塔C41102下部进入的污氮气传质传热,被降温至16.3℃后抽出,由冷冻水泵P41102加压后,进入冷冻水换热器的管程,与壳程的溴化锂冷水换热后温度降为11℃;出冷冻水换热器的冷冻水进入氨蒸发器的管程与壳程的液氨换热,温度被将至9℃后进入空冷塔的上部;为空冷塔提供冷却用水;The 32℃ water-cooling tower C41102 makes up water, enters from the upper part of the water-cooling tower C41102 through the replenishment valve, transfers mass and heat with the sewage nitrogen entering from the lower part of the water-cooling tower C41102, and is cooled to 16.3 ℃ and then pumped out. After being pressurized by the chilled water pump P41102, it enters the The tube side of the chilled water heat exchanger exchanges heat with the lithium bromide cold water on the shell side and the temperature drops to 11°C; the chilled water exiting the chilled water heat exchanger enters the ammonia evaporator and exchanges heat with the liquid ammonia on the shell side. After being cooled to 9℃, it enters the upper part of the air-cooling tower; provides cooling water for the air-cooling tower;

氨蒸发器的液氨消耗由6136Kg/h降低为1837Kg/h,使氨压机的3.8MPa蒸汽消耗,每小时减少0.8吨;同时出空冷塔空气温度由12℃降至10℃;最终使增压机的进气温度降低,使增压机的负荷降低,驱动机汽轮机的9.0MPa蒸汽消耗降低了0.1吨/h;进入冷箱的空气温度降低,装置的冷损减少,液体产量上升每天增加5吨液氧;如果3.8MPa蒸汽一顿按100元,如果9.0MPa蒸汽一顿按120元,液氧一顿700元,这样一天可以增加利润:0.8*100*24+0.1*120*24+5*700=5708元。The liquid ammonia consumption of the ammonia evaporator was reduced from 6136Kg/h to 1837Kg/h, which reduced the 3.8MPa steam consumption of the ammonia compressor by 0.8 tons per hour; at the same time, the air temperature of the outlet cooling tower was reduced from 12°C to 10°C; The inlet temperature of the compressor is reduced, the load of the supercharger is reduced, and the 9.0MPa steam consumption of the driving machine steam turbine is reduced by 0.1 ton/h; the temperature of the air entering the cold box is reduced, the cooling loss of the device is reduced, and the liquid output is increased every day. 5 tons of liquid oxygen; if 3.8MPa steam is charged at 100 yuan, if 9.0MPa steam is charged at 120 yuan, and liquid oxygen is 700 yuan, so one day can increase profit: 0.8*100*24+0.1*120*24+ 5*700=5708 yuan.

优选的,所述S2中的闪蒸低压蒸汽的温度为140-150℃。Preferably, the temperature of the flashed low-pressure steam in S2 is 140-150°C.

优选的,所述S8中降温至16.3℃-17.5℃。Preferably, the temperature is lowered to 16.3°C-17.5°C in the S8.

优选的,所述冷冻水泵出口和氨蒸发器之间增加一台冷冻水换热器。Preferably, a chilled water heat exchanger is added between the outlet of the chilled water pump and the ammonia evaporator.

优选的,所述冷冻水换热器的换热面积为700m3,壳程走溴化锂冷冻水,设计压力为0.6Mpa。Preferably, the heat exchange area of the chilled water heat exchanger is 700m 3 , the lithium bromide chilled water is carried on the shell side, and the design pressure is 0.6Mpa.

优选的,所述管程走冷冻水泵来的冷冻水设计压力为1.3Mpa。Preferably, the design pressure of the chilled water coming from the chilled water pump on the tube side is 1.3Mpa.

优选的,所述冷冻水换热器设有旁路阀,且所述冷冻水进换热器的管道高点出设有排气阀。Preferably, the chilled water heat exchanger is provided with a bypass valve, and an exhaust valve is provided at the high point of the pipeline of the chilled water into the heat exchanger.

本发明还提供一种冷冻水泵安装组件,包括冷冻水泵本体和安装板,所述安装板的顶部固定连接有活动箱,所述活动箱的内壁的顶部和底部之间转动连接有转动轴,所述转动轴的外表面从上至下依次固定连接有第一锥齿轮和旋转板,所述冻水泵本体的底部的两侧均设置有L型限位块。The present invention also provides a chilled water pump installation assembly, comprising a chilled water pump body and a mounting plate, a movable box is fixedly connected to the top of the mounting plate, and a rotating shaft is rotatably connected between the top and bottom of the inner wall of the movable box, so A first bevel gear and a rotating plate are fixedly connected to the outer surface of the rotating shaft in sequence from top to bottom, and L-shaped limit blocks are provided on both sides of the bottom of the chilled water pump body.

优选的,所述活动箱的内壁内壁的底部的两侧均滑动连接有滑动板,两个所述滑动板的顶部均固定连接有L型卡紧块,所述旋转板的顶部转动连接有两个驱动杆,两个所述驱动杆的另一端分别转动连接于两个所述滑动板的顶部。Preferably, sliding plates are slidably connected to both sides of the bottom of the inner wall of the inner wall of the movable box, L-shaped clamping blocks are fixedly connected to the tops of the two sliding plates, and two sliding plates are rotatably connected to the top of the rotating plate. There are two driving rods, and the other ends of the two driving rods are respectively rotatably connected to the tops of the two sliding plates.

优选的,所述活动箱的内壁的背面转动连接有旋转轴,所述旋转轴的外表面固定连接有与所述第一锥齿轮相啮合的第二锥齿轮,所述旋转轴的一端贯穿所述活动箱并延伸至所述活动箱的外部。Preferably, a rotating shaft is rotatably connected to the back of the inner wall of the movable box, a second bevel gear meshing with the first bevel gear is fixedly connected to the outer surface of the rotating shaft, and one end of the rotating shaft penetrates through the the movable box and extend to the outside of the movable box.

与相关技术相比较,本发明提供的利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法具有如下有益效果:Compared with the related art, the method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration provided by the present invention has the following beneficial effects:

本发明提供一种利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法,本空分装置的预冷系统冷冻水是由水冷塔和氨蒸发器进行降温,对氨蒸发器的液氨消耗比较大,特别是在开车阶段,精馏系统没有污氮气采出时水冷塔基本上没有降温效果,冷冻水温度与水冷塔的补水温度是一样的;冷冻水的降温所需要的冷量全部由氨蒸发器提供,氨蒸发器的液氨消耗更大,而且很难把水温降到要求的工艺范围内,增加了冷冻水换热器后,能够很大限度地降低了氨蒸发器的负荷,而且能够把出空冷塔的空气温度降到设计值12℃;The invention provides a method for reducing the energy consumption of air separation by flashing low-pressure steam in a gasifier. The consumption is relatively large, especially in the start-up stage, when the rectification system does not produce polluted nitrogen, the water-cooling tower basically has no cooling effect, and the temperature of the chilled water is the same as the make-up water temperature of the water-cooled tower; Provided by the ammonia evaporator, the liquid ammonia consumption of the ammonia evaporator is larger, and it is difficult to reduce the water temperature to the required process range. After adding the chilled water heat exchanger, the load of the ammonia evaporator can be greatly reduced. , and can reduce the air temperature of the air cooling tower to the design value of 12 °C;

通过利用气化炉闪蒸低压蒸汽和溴化锂溶剂组成溴化锂吸收式制冷机,制得溴化锂冷冻水,在空分冷冻水换热器中溴化锂冷冻水与水冷塔来的冷冻水进行换热,将冷冻水降温后,再进入氨蒸发器进一步降温,大大降低了氨蒸发器的液氨消耗,减小了氨蒸发器的负荷。溴化锂溶液循环使用,充分利用了汽化炉闪蒸低压蒸汽的余热,同时也降低了空分预冷系统液氨的消耗,能耗被降低。Lithium bromide chilled water is prepared by flashing low-pressure steam and lithium bromide solvent in a gasifier to form a lithium bromide absorption refrigerator. After the water is cooled, it enters the ammonia evaporator for further cooling, which greatly reduces the liquid ammonia consumption of the ammonia evaporator and reduces the load of the ammonia evaporator. The lithium bromide solution is recycled, which makes full use of the waste heat of the low-pressure steam flashing in the vaporizer, and also reduces the consumption of liquid ammonia in the air separation pre-cooling system, and the energy consumption is reduced.

附图说明Description of drawings

图1为本发明提供的利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法的一种较佳实施例的结构示意图;1 is a schematic structural diagram of a preferred embodiment of a method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration provided by the present invention;

图2为图1所示的预冷系统工艺流程图;Fig. 2 is the process flow diagram of the pre-cooling system shown in Fig. 1;

图3为本发明提供的冷冻水泵安装组件的一种较佳实施例的结构示意图;3 is a schematic structural diagram of a preferred embodiment of the chilled water pump installation assembly provided by the present invention;

图4为图3所示的活动箱的截面俯视图。FIG. 4 is a cross-sectional plan view of the movable box shown in FIG. 3 .

图中标号:1、冷水进口温度测点,2、冷水出口温度,3、冷却水进口温度,4、蒸汽凝水温度,5、浓溶液喷淋温度,6、浓溶液出口温度,7、冷凝温度,8、蒸发温度,9、融晶管温度,10、冷水流量,11、自抽装置压力,12、蒸汽压力,13、自动排气装置压力,14、冷冻水泵本体,15、安装板,16、活动箱,17、转动轴,18、第一锥齿轮,19、旋转板,20、L型限位块,21、滑动板,22、L型卡紧块,23、驱动杆,24、旋转轴,25、第二锥齿轮。Labels in the figure: 1. Measuring point of cold water inlet temperature, 2. Cold water outlet temperature, 3. Cooling water inlet temperature, 4. Steam condensate temperature, 5. Spray temperature of concentrated solution, 6. Outlet temperature of concentrated solution, 7. Condensation Temperature, 8. Evaporation temperature, 9. Melting tube temperature, 10. Cold water flow rate, 11. Self-pumping device pressure, 12. Steam pressure, 13. Automatic exhaust device pressure, 14. Chilled water pump body, 15. Mounting plate, 16, movable box, 17, rotating shaft, 18, first bevel gear, 19, rotating plate, 20, L-shaped limit block, 21, sliding plate, 22, L-shaped clamping block, 23, drive rod, 24, Rotating shaft, 25, second bevel gear.

具体实施方式Detailed ways

下面结合附图和实施方式对本发明作进一步说明。The present invention will be further described below with reference to the accompanying drawings and embodiments.

请结合参阅图1、图2、图3和图4,其中,图1为本发明提供的利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法的一种较佳实施例的结构示意图;图2为图1所示的预冷系统工艺流程图;图3为本发明提供的冷冻水泵安装组件的一种较佳实施例的结构示意图;图4为图3所示的活动箱的截面俯视图。利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法包括以下步骤:Please refer to FIG. 1, FIG. 2, FIG. 3 and FIG. 4, wherein, FIG. 1 is a schematic structural diagram of a preferred embodiment of the method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration provided by the present invention Fig. 2 is the pre-cooling system process flow chart shown in Fig. 1; Fig. 3 is the structural representation of a kind of preferred embodiment of chilled water pump installation assembly provided by the present invention; Fig. 4 is the section of the movable box shown in Fig. 3 Top view. The method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration includes the following steps:

S1、通过将汽化炉底部灰水进入高压闪蒸罐被闪蒸后,进入低压闪蒸罐进行进一步闪蒸;S1. After the gray water at the bottom of the vaporization furnace enters the high-pressure flash tank to be flashed, it enters the low-pressure flash tank for further flashing;

S2、低压闪蒸罐顶部的闪蒸低压蒸汽进入溴化锂吸收式制冷机组,在发生器中加热溴化锂稀溶液,使其浓缩成浓溶液,同时产生冷剂蒸汽;S2. The flashed low-pressure steam at the top of the low-pressure flash tank enters the lithium bromide absorption refrigeration unit, and the dilute solution of lithium bromide is heated in the generator to be concentrated into a concentrated solution, and refrigerant steam is generated simultaneously;

S3、再将S2中的冷剂蒸汽排进冷凝器内,这时就会被流经凝汽器传热管内的冷却水冷凝成冷剂水;S3, and then discharge the refrigerant vapor in S2 into the condenser, and then it will be condensed into refrigerant water by the cooling water flowing through the heat transfer tube of the condenser;

S4、再将冷剂水经U型管节流后排至蒸发器,在蒸发器内闪发降温后流入蒸发器冷剂水盘;S4, and then the refrigerant water is throttled through the U-shaped pipe and then discharged to the evaporator, and then flows into the evaporator refrigerant water tray after flashing and cooling in the evaporator;

S5、进入蒸发器冷剂水盘的冷剂水被冷剂水泵进行抽出,再通过冷剂水泵将抽出的冷剂水喷淋在蒸发器传热管表面,吸收传热管内冷水的热量,进行沸腾和蒸发,形成冷剂蒸汽;S5. The refrigerant water entering the refrigerant water pan of the evaporator is pumped out by the refrigerant water pump, and then the refrigerant water pumped out is sprayed on the surface of the evaporator heat transfer pipe by the refrigerant water pump to absorb the heat of the cold water in the heat transfer pipe. Boiling and evaporation to form refrigerant vapor;

S6、再通过将冷剂蒸汽排进吸收器内部,这时就会被回到吸收器的浓溶剂进行吸收,而浓溶剂吸收了冷剂蒸汽后变成稀溶剂,再进入发生器内被加热浓缩;S6. By discharging the refrigerant vapor into the absorber, it will be absorbed by the concentrated solvent returning to the absorber, and the concentrated solvent will absorb the refrigerant vapor and become a dilute solvent, and then enter the generator to be heated concentrate;

S7、冷水进入蒸发器内的热量被冷剂水换热后,使得温度降低,再经过水泵加压后送至空分预冷系统的冷冻水换热器的壳程,并且与管程中冷冻水泵的冷冻水换热,冷水经换热器换热后,温度升高返回发生器内降温,进行循环使用;S7. After the cold water enters the evaporator, the heat is exchanged by the refrigerant water, which reduces the temperature, and then is pressurized by the water pump and sent to the shell side of the chilled water heat exchanger of the air separation pre-cooling system, and is connected with the freezing water in the tube side. The chilled water of the pump exchanges heat, and after the cold water is exchanged by the heat exchanger, the temperature rises and returns to the generator to cool down for recycling;

S8、循环水经补水阀从水冷塔上部进入,与从水冷塔下部进入的污氮气传质传热,被降温后,由冷冻水泵加压后,进入冷冻水换热器的管程,与壳程的溴化锂冷水换热后,使其温度降低,并且排出的冷冻水换热器的冷冻水进入氨蒸发器的管程与壳程的液氨换热,温度被进一步降低后进入空冷塔的上部,为空冷塔提供冷却用水;S8. The circulating water enters from the upper part of the water-cooling tower through the replenishment valve, and transfers heat and mass with the sewage nitrogen entering from the lower part of the water-cooling tower. After the lithium bromide cold water heat exchange in the process, its temperature is lowered, and the chilled water of the discharged chilled water heat exchanger enters the tube side of the ammonia evaporator to exchange heat with the liquid ammonia in the shell side, and the temperature is further lowered into the upper part of the air cooling tower , to provide cooling water for the air cooling tower;

本空分装置的预冷系统冷冻水是由水冷塔和氨蒸发器进行降温,对氨蒸发器的液氨消耗比较大;特别是在开车阶段,精馏系统没有污氮气采出时水冷塔基本上没有降温效果,冷冻水温度与水冷塔的补水温度是一样的(通常30℃左右);冷冻水的降温所需要的冷量全部由氨蒸发器提供,氨蒸发器的液氨消耗更大,而且很难把水温降到要求的工艺范围内;增加了冷冻水换热器后,能够很大限度地降低了氨蒸发器的负荷,而且能够把出空冷塔的空气温度降到设计值12℃;The chilled water of the pre-cooling system of the air separation unit is cooled by the water-cooling tower and the ammonia evaporator, which consumes a large amount of liquid ammonia; especially in the start-up stage, when the rectification system does not produce dirty nitrogen, the water-cooling tower basically There is no cooling effect, the temperature of the chilled water is the same as the temperature of the make-up water of the water-cooling tower (usually about 30 ℃); all the cooling capacity required for the cooling of the chilled water is provided by the ammonia evaporator, and the ammonia evaporator consumes more liquid ammonia, And it is difficult to reduce the water temperature to the required process range; after adding the chilled water heat exchanger, the load of the ammonia evaporator can be greatly reduced, and the air temperature of the air cooling tower can be reduced to the design value of 12 ° C ;

本空分装置采用的时氨蒸发器作为给冷冻水进一步降温的换热器,使满足空冷塔上段的冷却用水。利用合成氨压缩机来的液氨作为制冷剂。中压液氨通过节流阀减压(并降温)进入氨蒸发器,使其吸热汽化,吸收冷冻水的热量,使冷冻水进一步降温。汽化后的气氨在回到氨压缩机的进口经压缩、冷凝后循环使用;The ammonia evaporator used in this air separation plant is used as a heat exchanger for further cooling the chilled water, so that it can meet the cooling water in the upper section of the air cooling tower. Liquid ammonia from a synthetic ammonia compressor is used as a refrigerant. The medium-pressure liquid ammonia is decompressed (and cooled) through the throttle valve and enters the ammonia evaporator, which absorbs heat and vaporizes, absorbs the heat of the chilled water, and further cools the chilled water. The vaporized gaseous ammonia is recycled after being compressed and condensed at the inlet of the ammonia compressor;

水冷塔为水冷塔C41102、冷冻水泵为冷冻水泵P41102、氨蒸发器为氨蒸发器E41101、进出水管口为进出水管口DN200The water cooling tower is the water cooling tower C41102, the chilled water pump is the chilled water pump P41102, the ammonia evaporator is the ammonia evaporator E41101, and the inlet and outlet pipes are DN200.

32℃的水冷塔补水,经补水阀从水冷塔上部进入,与从水冷塔下部进入的污氮气传质传热,被降温至16.3℃后抽出,由冷冻水泵P41102加压后,进入冷冻水换热器的管程,与壳程的溴化锂冷水换热后温度降为11℃;出冷冻水换热器的冷冻水进入氨蒸发器的管程与壳程的液氨换热,温度被将至9℃后进入空冷塔的上部;为空冷塔提供冷却用水;The 32°C water-cooling tower make-up water enters from the upper part of the water-cooling tower through the make-up valve, and transfers heat and mass with the sewage nitrogen entering from the lower part of the water-cooling tower. It is cooled to 16.3°C and then pumped out. The tube side of the heater exchanges heat with the lithium bromide cold water on the shell side and the temperature drops to 11°C; the chilled water from the chilled water heat exchanger enters the tube side of the ammonia evaporator and exchanges heat with the liquid ammonia on the shell side, and the temperature is reduced to Enter the upper part of the air-cooling tower after 9 ℃; provide cooling water for the air-cooling tower;

氨蒸发器的液氨消耗由6136Kg/h降低为1837Kg/h,使氨压机的3.8MPa蒸汽消耗,每小时减少0.8吨;同时出空冷塔空气温度由12℃降至10℃;最终使增压机的进气温度降低,使增压机的负荷降低,驱动机汽轮机的9.0MPa蒸汽消耗降低了0.1吨/h;进入冷箱的空气温度降低,装置的冷损减少,液体产量上升每天增加5吨液氧;如果3.8MPa蒸汽一顿按100元,如果9.0MPa蒸汽一顿按120元,液氧一顿700元,这样一天可以增加利润:0.8*100*24+0.1*120*24+5*700=5708元。The liquid ammonia consumption of the ammonia evaporator was reduced from 6136Kg/h to 1837Kg/h, which reduced the 3.8MPa steam consumption of the ammonia compressor by 0.8 tons per hour; at the same time, the air temperature of the outlet cooling tower was reduced from 12°C to 10°C; The inlet temperature of the compressor is reduced, the load of the supercharger is reduced, and the 9.0MPa steam consumption of the driving machine steam turbine is reduced by 0.1 ton/h; the temperature of the air entering the cold box is reduced, the cooling loss of the device is reduced, and the liquid output is increased every day. 5 tons of liquid oxygen; if 3.8MPa steam is charged at 100 yuan, if 9.0MPa steam is charged at 120 yuan, and liquid oxygen is 700 yuan, so one day can increase profit: 0.8*100*24+0.1*120*24+ 5*700=5708 yuan.

优选的,所述S2中的闪蒸低压蒸汽的温度为140-150℃。Preferably, the temperature of the flashed low-pressure steam in S2 is 140-150°C.

优选的,所述S8中降温至16.3℃-17.5℃。Preferably, the temperature is lowered to 16.3°C-17.5°C in the S8.

优选的,所述冷冻水泵出口和氨蒸发器之间增加一台冷冻水换热器;Preferably, a chilled water heat exchanger is added between the outlet of the chilled water pump and the ammonia evaporator;

冷冻水泵出口和氨蒸发器之间增加一台冷冻水换热器,用于冷冻水与溴化锂冷水换热。A chilled water heat exchanger is added between the outlet of the chilled water pump and the ammonia evaporator for heat exchange between chilled water and lithium bromide cold water.

优选的,所述冷冻水换热器的换热面积为700m3,壳程走溴化锂冷冻水,设计压力为0.6Mpa。Preferably, the heat exchange area of the chilled water heat exchanger is 700m 3 , the lithium bromide chilled water is carried on the shell side, and the design pressure is 0.6Mpa.

优选的,所述管程走冷冻水泵来的冷冻水设计压力为1.3Mpa。Preferably, the design pressure of the chilled water coming from the chilled water pump on the tube side is 1.3Mpa.

优选的,所述冷冻水换热器设有旁路阀,且所述冷冻水进换热器的管道高点出设有排气阀;Preferably, the chilled water heat exchanger is provided with a bypass valve, and an exhaust valve is provided at the high point of the pipeline where the chilled water enters the heat exchanger;

冷冻水换热器设有旁路阀,若没有供给溴化锂冷水或换热器检修时,可打开冷冻水换热器旁路阀,关闭冷冻水进出冷冻水换热器手阀,将冷冻水换热器切掉;同时在冷冻水换热器上设有壳程排气阀,在冷冻水进换热器的管道高点出设有排气阀,在冷冻水换热器投用时排尽管道和换热器内空气,保证冷冻水换热器的换热效果。在换热器和管道的低点设有导淋,用于冷冻水换热器停运后排尽换热器和管道内的积水。The chilled water heat exchanger is equipped with a bypass valve. If no lithium bromide cold water is supplied or the heat exchanger is overhauled, the bypass valve of the chilled water heat exchanger can be opened, and the hand valve of the chilled water in and out of the chilled water heat exchanger can be closed to exchange the chilled water. The heat exchanger is cut off; at the same time, there is a shell side exhaust valve on the chilled water heat exchanger, and an exhaust valve is provided at the high point of the pipeline where the chilled water enters the heat exchanger, so that the chilled water heat exchanger can be exhausted when the chilled water heat exchanger is put into use. And the air in the heat exchanger to ensure the heat exchange effect of the chilled water heat exchanger. There is a guide shower at the low point of the heat exchanger and the pipeline, which is used to drain the accumulated water in the heat exchanger and the pipeline after the chilled water heat exchanger is out of operation.

本发明提供的利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法的工作原理如下:The working principle of the method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration provided by the present invention is as follows:

通过将汽化炉底部灰水进入高压闪蒸罐被闪蒸后,进入低压闪蒸罐进行进一步闪蒸;After the grey water at the bottom of the vaporization furnace enters the high pressure flash tank to be flashed, it enters the low pressure flash tank for further flash evaporation;

低压闪蒸罐顶部的闪蒸低压蒸汽进入溴化锂吸收式制冷机组,在发生器中加热溴化锂稀溶液,使其浓缩成浓溶液,同时产生冷剂蒸汽;The flashed low-pressure steam at the top of the low-pressure flash tank enters the lithium bromide absorption refrigeration unit, and the dilute lithium bromide solution is heated in the generator to concentrate it into a concentrated solution, and refrigerant vapor is generated at the same time;

再将S2中的冷剂蒸汽排进冷凝器内,这时就会被流经凝汽器传热管内的冷却水冷凝成冷剂水;Then, the refrigerant vapor in S2 is discharged into the condenser, and then it will be condensed into refrigerant water by the cooling water flowing through the heat transfer tube of the condenser;

再将冷剂水经U型管节流后排至蒸发器,在蒸发器内闪发降温后流入蒸发器冷剂水盘;The refrigerant water is then throttled through the U-shaped pipe and then discharged to the evaporator, and then flows into the evaporator refrigerant water tray after flashing and cooling in the evaporator;

进入蒸发器冷剂水盘的冷剂水被冷剂水泵进行抽出,再通过冷剂水泵将抽出的冷剂水喷淋在蒸发器传热管表面,吸收传热管内冷水的热量,进行沸腾和蒸发,形成冷剂蒸汽;The refrigerant water entering the refrigerant water pan of the evaporator is pumped out by the refrigerant water pump, and then the refrigerant water pumped out is sprayed on the surface of the evaporator heat transfer pipe by the refrigerant water pump to absorb the heat of the cold water in the heat transfer pipe for boiling and heating. Evaporate to form refrigerant vapor;

再通过将冷剂蒸汽排进吸收器内部,这时就会被回到吸收器的浓溶剂进行吸收,而浓溶剂吸收了冷剂蒸汽后变成稀溶剂,再进入发生器内被加热浓缩;Then, by discharging the refrigerant vapor into the absorber, it will be absorbed by the concentrated solvent returning to the absorber, and the concentrated solvent will absorb the refrigerant vapor and become a dilute solvent, and then enter the generator to be heated and concentrated;

冷水进入蒸发器内的热量被冷剂水换热后,使得温度降低,再经过水泵加压后送至空分预冷系统的冷冻水换热器的壳程,并且与管程中冷冻水泵的冷冻水换热,冷水经换热器换热后,温度升高返回发生器内降温,进行循环使用;The heat of the cold water entering the evaporator is exchanged by the refrigerant water, which reduces the temperature, and then is pressurized by the water pump and sent to the shell side of the chilled water heat exchanger of the air separation pre-cooling system, and is connected with the chilled water pump in the tube side. Chilled water heat exchange, after the cold water is heated by the heat exchanger, the temperature rises and returns to the generator to cool down for recycling;

循环水经补水阀从水冷塔上部进入,与从水冷塔下部进入的污氮气传质传热,被降温后,由冷冻水泵加压后,进入冷冻水换热器的管程,与壳程的溴化锂冷水换热后,使其温度降低,并且排出的冷冻水换热器的冷冻水进入氨蒸发器的管程与壳程的液氨换热,温度被进一步降低后进入空冷塔的上部,为空冷塔提供冷却用水。The circulating water enters from the upper part of the water-cooling tower through the replenishment valve, and transfers heat and mass with the sewage nitrogen entering from the lower part of the water-cooling tower. After the lithium bromide cold water heat exchange, its temperature is lowered, and the chilled water of the discharged chilled water heat exchanger enters the tube side of the ammonia evaporator and exchanges heat with the liquid ammonia in the shell side, and the temperature is further lowered into the upper part of the air cooling tower, which is Air cooling towers provide cooling water.

与相关技术相比较,本发明提供的利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法具有如下有益效果:Compared with the related art, the method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration provided by the present invention has the following beneficial effects:

本空分装置的预冷系统冷冻水是由水冷塔和氨蒸发器进行降温,对氨蒸发器的液氨消耗比较大,特别是在开车阶段,精馏系统没有污氮气采出时水冷塔基本上没有降温效果,冷冻水温度与水冷塔的补水温度是一样的;冷冻水的降温所需要的冷量全部由氨蒸发器提供,氨蒸发器的液氨消耗更大,而且很难把水温降到要求的工艺范围内,增加了冷冻水换热器后,能够很大限度地降低了氨蒸发器的负荷,而且能够把出空冷塔的空气温度降到设计值12℃;The chilled water of the pre-cooling system of the air separation unit is cooled by the water-cooling tower and the ammonia evaporator, which consumes a large amount of liquid ammonia, especially in the start-up stage, when the rectification system does not produce dirty nitrogen, the water-cooling tower basically There is no cooling effect, and the temperature of the chilled water is the same as the temperature of the make-up water of the water-cooling tower; all the cooling capacity required for the cooling of the chilled water is provided by the ammonia evaporator, which consumes more liquid ammonia, and it is difficult to reduce the water temperature. Within the required process range, after adding the chilled water heat exchanger, the load of the ammonia evaporator can be greatly reduced, and the air temperature of the air cooling tower can be reduced to the design value of 12 °C;

通过利用气化炉闪蒸低压蒸汽和溴化锂溶剂组成溴化锂吸收式制冷机,制得溴化锂冷冻水,在空分冷冻水换热器中溴化锂冷冻水与水冷塔来的冷冻水进行换热,将冷冻水降温后,再进入氨蒸发器进一步降温,大大降低了氨蒸发器的液氨消耗,减小了氨蒸发器的负荷。溴化锂溶液循环使用,充分利用了汽化炉闪蒸低压蒸汽的余热,同时也降低了空分预冷系统液氨的消耗,能耗被降低。Lithium bromide chilled water is prepared by flashing low-pressure steam and lithium bromide solvent in a gasifier to form a lithium bromide absorption refrigerator. After the water is cooled, it enters the ammonia evaporator for further cooling, which greatly reduces the liquid ammonia consumption of the ammonia evaporator and reduces the load of the ammonia evaporator. The lithium bromide solution is recycled, which makes full use of the waste heat of the low-pressure steam flashing in the vaporizer, and also reduces the consumption of liquid ammonia in the air separation pre-cooling system, and the energy consumption is reduced.

请结合参阅图3-4,另外,本发明还提供一种冷冻水泵安装组件,用于用于安装利用气化炉闪蒸低压蒸汽制冷降低空分能耗的方法的冷冻水泵,包括冷冻水泵本体14和安装板15,所述安装板15的顶部固定连接有活动箱16,所述活动箱16的内壁的顶部和底部之间转动连接有转动轴17,所述转动轴17的外表面从上至下依次固定连接有第一锥齿轮18和旋转板19,所述冻水泵本体14的底部的两侧均设置有L型限位块20;Please refer to FIGS. 3-4 in conjunction. In addition, the present invention also provides a chilled water pump installation assembly for installing a chilled water pump for a method for reducing air separation energy consumption by flashing low-pressure steam in a gasifier, including a chilled water pump body 14 and a mounting plate 15, the top of the mounting plate 15 is fixedly connected with a movable box 16, and a rotating shaft 17 is rotatably connected between the top and bottom of the inner wall of the movable box 16, and the outer surface of the rotating shaft 17 is from above. The first bevel gear 18 and the rotating plate 19 are fixedly connected in sequence from the bottom, and L-shaped limit blocks 20 are provided on both sides of the bottom of the chilled water pump body 14;

L型限位块20的设置,主要是便于冷冻水泵本体14与活动箱16内部的两个L型卡紧块22进行卡紧,进而完成连接关系,而且活动箱16底部的安装板15与外界汽车进行固定安装。The setting of the L-shaped limit block 20 is mainly to facilitate the clamping between the chilled water pump body 14 and the two L-shaped clamping blocks 22 inside the movable box 16 to complete the connection relationship, and the mounting plate 15 at the bottom of the movable box 16 is connected to the outside world. Fixed installation of the car.

所述活动箱16的内壁内壁的底部的两侧均滑动连接有滑动板21,两个所述滑动板21的顶部均固定连接有L型卡紧块22,所述旋转板19的顶部转动连接有两个驱动杆23,两个所述驱动杆23的另一端分别转动连接于两个所述滑动板21的顶部;Both sides of the bottom of the inner wall of the inner wall of the movable box 16 are slidably connected with sliding plates 21 , the tops of the two sliding plates 21 are fixedly connected with L-shaped clamping blocks 22 , and the tops of the rotating plates 19 are rotatably connected. There are two driving rods 23, and the other ends of the two driving rods 23 are respectively connected to the tops of the two sliding plates 21 in rotation;

通过两个滑动板21相对或相离方向的运动,可以带动两个L型卡紧块22相对方向或相离方向运动,通过两个L型卡紧块22相对方向的运动,就可以对处于活动箱16内部的两个L型限位块20进行卡紧,进而完成对冷冻水泵本体14的安装,活动箱16顶部的两侧均设置有卡孔,便于两个L型限位块20的插入。Through the movement of the two sliding plates 21 relative to or away from each other, the two L-shaped clamping blocks 22 can be driven to move in the opposite direction or away from each other. The two L-shaped limit blocks 20 inside the movable box 16 are clamped, and then the installation of the chilled water pump body 14 is completed. insert.

所述活动箱16的内壁的背面转动连接有旋转轴24,所述旋转轴24的外表面固定连接有与所述第一锥齿轮18相啮合的第二锥齿轮25,所述旋转轴24的一端贯穿所述活动箱16并延伸至所述活动箱16的外部;A rotating shaft 24 is rotatably connected to the back of the inner wall of the movable box 16 , and a second bevel gear 25 meshing with the first bevel gear 18 is fixedly connected to the outer surface of the rotating shaft 24 . One end penetrates through the movable box 16 and extends to the outside of the movable box 16;

通过带动旋转轴24的旋转,可以带动第一锥齿轮18和第二锥齿轮25进行旋转,进而带动转动轴17进行旋转,而转动轴17的旋转,就会带动旋转板19进行旋转,而旋转板19的旋转,就会带动两个驱动杆23进行展开和收缩运动,通过两个驱动杆23展开和收缩的运动,就可以带动两个两个滑动板21和两个L型卡紧块22相对方向或相离方向运动,进而可以对处于活动箱16内部的两个L型限位块20进行卡紧,完成安装,而且可以失去对活动箱16内部的两个L型限位块20的卡紧,完成拆卸,操作简单,更加便于使用,便于工作人员对冷冻水泵的维护,而且只需操作一个步骤,就能连贯带动其他组件,完成安装和拆卸,省时省力。By driving the rotation of the rotating shaft 24, the first bevel gear 18 and the second bevel gear 25 can be driven to rotate, thereby driving the rotating shaft 17 to rotate, and the rotation of the rotating shaft 17 will drive the rotating plate 19 to rotate, and the rotation The rotation of the plate 19 will drive the two driving rods 23 to expand and contract. Through the expanding and contracting movements of the two driving rods 23, two sliding plates 21 and two L-shaped clamping blocks 22 can be driven. Move in the opposite direction or the opposite direction, and then the two L-shaped limit blocks 20 inside the movable box 16 can be clamped to complete the installation, and the two L-shaped limit blocks 20 inside the movable box 16 can be lost. Clamping, complete disassembly, simple operation, more convenient to use, convenient for staff to maintain the chilled water pump, and only need to operate one step, it can continuously drive other components to complete installation and disassembly, saving time and effort.

其中,该冷冻水泵安装组件的具体结构参照上述实施例,由于冷冻水泵安装组件采用了上述所有实施例的全部技术方案,因此至少具有上述实施例的技术方案所带来的所有有益效果,在此不再一一赘述。The specific structure of the chilled water pump installation assembly refers to the above-mentioned embodiments. Since the chilled water pump installation assembly adopts all the technical solutions of the above-mentioned embodiments, it has at least all the beneficial effects brought by the technical solutions of the above-mentioned embodiments. I won't repeat them one by one.

以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其它相关的技术领域,均同理包括在本发明的专利保护范围内。The above descriptions are only the embodiments of the present invention, and are not intended to limit the scope of the present invention. Any equivalent structure or equivalent process transformation made by using the contents of the description and drawings of the present invention, or directly or indirectly applied to other related technologies Fields are similarly included in the scope of patent protection of the present invention.

Claims (10)

1. A method for reducing air separation energy consumption by utilizing flash evaporation low-pressure steam refrigeration of a gasification furnace is characterized by comprising the following steps:
s1, allowing the grey water at the bottom of the vaporizing furnace to enter a high-pressure flash tank for flash evaporation, and allowing the grey water to enter a low-pressure flash tank for further flash evaporation;
s2, feeding the flash evaporation low-pressure steam at the top of the low-pressure flash evaporation tank into a lithium bromide absorption refrigerating unit, heating the lithium bromide dilute solution in a generator to concentrate the lithium bromide dilute solution into a concentrated solution, and generating refrigerant steam at the same time;
s3, discharging the refrigerant steam in S2 into a condenser, and condensing the refrigerant steam into refrigerant water by cooling water flowing through a heat transfer pipe of the condenser;
s4, throttling the refrigerant water through the U-shaped pipe, discharging the refrigerant water to the evaporator, and flashing and cooling the refrigerant water in the evaporator to flow into a refrigerant water tray of the evaporator;
s5, pumping out the refrigerant water entering the refrigerant water tray of the evaporator by a refrigerant water pump, spraying the pumped refrigerant water on the surface of a heat transfer pipe of the evaporator by the refrigerant water pump, absorbing the heat of cold water in the heat transfer pipe, and boiling and evaporating to form refrigerant steam;
s6, discharging the refrigerant steam into the absorber, absorbing the refrigerant steam by the rich solvent returned to the absorber, changing the rich solvent into the dilute solvent after absorbing the refrigerant steam, and then heating and concentrating the refrigerant steam in the generator;
s7, after heat of cold water entering the evaporator is exchanged by refrigerant water, the temperature is reduced, the cold water is pressurized by a water pump and then is sent to the shell side of a chilled water heat exchanger of the air separation pre-cooling system, the cold water exchanges heat with chilled water of a chilled water pump in a tube side, after heat exchange of the cold water by the heat exchanger, the temperature of the cold water is raised and returns to the generator for cooling, and the cold water is recycled;
and S8, circulating water enters from the upper part of the water cooling tower through a water replenishing valve, is subjected to mass and heat transfer with waste nitrogen gas entering from the lower part of the water cooling tower, is cooled, is pressurized by a refrigerating water pump, enters the tube pass of the chilled water heat exchanger, is subjected to heat exchange with lithium bromide cold water in the shell pass to lower the temperature of the chilled water, enters the tube pass of the ammonia evaporator to exchange heat with liquid ammonia in the shell pass, is further cooled, enters the upper part of the air cooling tower, and provides cooling water for the air cooling tower.
2. The method for reducing the energy consumption of air separation by utilizing the refrigeration of the flash low-pressure steam of the gasification furnace as claimed in claim 1, wherein the temperature of the flash low-pressure steam in S2 is 140-150 ℃.
3. The method for reducing the energy consumption of air separation by utilizing the flash evaporation low-pressure steam refrigeration of the gasification furnace as claimed in claim 1, wherein the temperature in the S8 is reduced to 16.3-17.5 ℃.
4. The method for reducing air separation energy consumption by utilizing gasification furnace flash evaporation low-pressure steam refrigeration as claimed in claim 1, wherein a chilled water heat exchanger is added between the outlet of the chilled water pump and the ammonia evaporator.
5. The method for reducing air separation energy consumption by utilizing gasification furnace flash evaporation low-pressure steam refrigeration as claimed in claim 1, wherein the heat exchange area of the chilled water heat exchanger is 700m3And the shell pass is filled with lithium bromide chilled water, and the design pressure is 0.6 MPa.
6. The method for reducing the energy consumption of air separation by utilizing the flash evaporation low-pressure steam refrigeration of the gasification furnace as claimed in claim 1, wherein the design pressure of the chilled water from the pipe pass chilled water pump is 1.3 Mpa.
7. The method for reducing the energy consumption of air separation by utilizing the flash evaporation low-pressure steam refrigeration of the gasification furnace as claimed in claim 1, wherein the chilled water heat exchanger is provided with a bypass valve, and an exhaust valve is arranged at the high point of a pipeline of the chilled water inlet heat exchanger.
8. The chilled water pump mounting assembly is used for mounting the chilled water pump of the method for reducing air separation energy consumption by utilizing gasification furnace flash evaporation low-pressure steam refrigeration according to any one of claims 1 to 7, and comprises a chilled water pump body and a mounting plate, wherein a movable box is fixedly connected to the top of the mounting plate, a rotating shaft is rotatably connected between the top and the bottom of the inner wall of the movable box, a first bevel gear and a rotating plate are fixedly connected to the outer surface of the rotating shaft from top to bottom in sequence, and L type limiting blocks are arranged on two sides of the bottom of the chilled water pump body.
9. The chilled water pump installation assembly according to claim 8, wherein sliding plates are slidably connected to both sides of the bottom of the inner wall of the movable box, L-type clamping blocks are fixedly connected to the tops of the two sliding plates, two driving rods are rotatably connected to the top of the rotating plate, and the other ends of the two driving rods are rotatably connected to the tops of the two sliding plates.
10. The chilled water pump mounting assembly according to claim 8, wherein a rotating shaft is rotatably connected to a rear surface of an inner wall of the movable box, a second bevel gear engaged with the first bevel gear is fixedly connected to an outer surface of the rotating shaft, and one end of the rotating shaft penetrates through the movable box and extends to the outside of the movable box.
CN201911304502.2A 2019-12-17 2019-12-17 A method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration Pending CN111426148A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911304502.2A CN111426148A (en) 2019-12-17 2019-12-17 A method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911304502.2A CN111426148A (en) 2019-12-17 2019-12-17 A method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration

Publications (1)

Publication Number Publication Date
CN111426148A true CN111426148A (en) 2020-07-17

Family

ID=71546895

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911304502.2A Pending CN111426148A (en) 2019-12-17 2019-12-17 A method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration

Country Status (1)

Country Link
CN (1) CN111426148A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112239682A (en) * 2020-09-08 2021-01-19 中石化宁波工程有限公司 Gasification device slag water flash evaporation gas comprehensive utilization system and method
KR20220043877A (en) * 2020-09-29 2022-04-05 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 Chiller, air separation system, and related methods

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004065869A1 (en) * 2003-01-22 2004-08-05 Lng International Pty Ltd A refrigeration process and the production of liquefied natural gas
CN203396202U (en) * 2013-06-12 2014-01-15 开封迪尔空分实业有限公司 Energy-saving nitrogen-cooled water pre-cooling system for air separation
CN104976863A (en) * 2015-07-15 2015-10-14 王林 Low-energy-consumption inner compression air separation device and process
CN105561616A (en) * 2016-02-04 2016-05-11 河南心连心化肥有限公司 Gasification ash water low-pressure flash heat energy utilizing device and heat energy utilizing method thereof
CN106642991A (en) * 2015-10-30 2017-05-10 河南晋开化工投资控股集团有限责任公司 Air separation pre-cooling system
CN107940801A (en) * 2017-10-23 2018-04-20 浙江大学 A kind of space division system for recycling compressed air waste-heat

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004065869A1 (en) * 2003-01-22 2004-08-05 Lng International Pty Ltd A refrigeration process and the production of liquefied natural gas
CN203396202U (en) * 2013-06-12 2014-01-15 开封迪尔空分实业有限公司 Energy-saving nitrogen-cooled water pre-cooling system for air separation
CN104976863A (en) * 2015-07-15 2015-10-14 王林 Low-energy-consumption inner compression air separation device and process
CN106642991A (en) * 2015-10-30 2017-05-10 河南晋开化工投资控股集团有限责任公司 Air separation pre-cooling system
CN105561616A (en) * 2016-02-04 2016-05-11 河南心连心化肥有限公司 Gasification ash water low-pressure flash heat energy utilizing device and heat energy utilizing method thereof
CN107940801A (en) * 2017-10-23 2018-04-20 浙江大学 A kind of space division system for recycling compressed air waste-heat

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112239682A (en) * 2020-09-08 2021-01-19 中石化宁波工程有限公司 Gasification device slag water flash evaporation gas comprehensive utilization system and method
KR20220043877A (en) * 2020-09-29 2022-04-05 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 Chiller, air separation system, and related methods
CN114322452A (en) * 2020-09-29 2022-04-12 气体产品与化学公司 Coolers, air separation systems and related methods
EP3974753A3 (en) * 2020-09-29 2022-09-21 Air Products And Chemicals, Inc. Chiller, air separation system, and related methods
KR102623304B1 (en) 2020-09-29 2024-01-09 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드 Chiller, air separation system, and related methods
US12038230B2 (en) 2020-09-29 2024-07-16 Air Products And Chemicals, Inc. Chiller, air separation system, and related methods

Similar Documents

Publication Publication Date Title
CN108211648B (en) Heat recovery type condensation and temperature and pressure swing adsorption combined process oil gas recovery device
CN103629854B (en) The ammonia that a kind of heat medium water drives and the integrated absorption type refrigerating unit of lithium bromide and method
CN108759303B (en) Cryogenic liquid gasification cold energy recycling device
CN105953459B (en) A kind of single-double effect compound type absorption refrigeration unit
CN102322705B (en) Diffusion absorption refrigeration and vapor compression refrigeration combined cycle device
CN101504219A (en) Air indirect cooling method and system for ammonia absorption type composite refrigeration cycle
CN111426148A (en) A method for reducing air separation energy consumption by utilizing gasifier flash low-pressure steam refrigeration
CN105910456A (en) Green comprehensive cold island equipment and cooling method
CN105650938B (en) A kind of absorption-type refrigerating method and device of full electric power reuse discharge heat
CN101280982B (en) Absorption cooling and heating machine
CN114485051A (en) Liquid ammonia dual-condition refrigerating system and liquid carbon dioxide production equipment
KR101218547B1 (en) Composion refrigerator
CN205690733U (en) A kind of single-double effect compound type absorption refrigeration unit
CN105066502B (en) A kind of direct-fired absorption refrigeration method and device for reclaiming the heat of transformation
CN203572091U (en) Heating-medium-water-driving ammonia and lithium bromide integrated absorption refrigeration device
CN211823478U (en) Device for reducing air separation energy consumption by utilizing gasification furnace flash evaporation low-pressure steam refrigeration
CN206739674U (en) A kind of device of rectifying tower top gaseous phase waste heat recovery fine frozen water
CN212511916U (en) Steam double-effect type lithium bromide absorption water chilling unit capable of supplying heat in single effect
CN204958415U (en) Energy -saving decarbonization system
CN1916531A (en) Absorption mode refrigerator of hot water type lithium bromide between single action and two stages
CN116164273A (en) Steam and cold combined lithium bromide absorption unit
CN210663439U (en) High-temperature wastewater lithium bromide absorption refrigeration all-in-one machine
CN101561198A (en) Cooling method by utilizing lithium bromide unit
CN203083196U (en) Device for producing low-temperature water by means of urea waste heat
CN113091349A (en) High-efficient absorption heat pump

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20200717

RJ01 Rejection of invention patent application after publication