CN111411751A - A composite decorative board and preparation method thereof - Google Patents
A composite decorative board and preparation method thereof Download PDFInfo
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- CN111411751A CN111411751A CN202010348032.6A CN202010348032A CN111411751A CN 111411751 A CN111411751 A CN 111411751A CN 202010348032 A CN202010348032 A CN 202010348032A CN 111411751 A CN111411751 A CN 111411751A
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- decorative panel
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- 239000002131 composite material Substances 0.000 title claims abstract description 115
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000009413 insulation Methods 0.000 claims abstract description 114
- 239000000463 material Substances 0.000 claims abstract description 81
- 239000010410 layer Substances 0.000 claims description 86
- 239000004568 cement Substances 0.000 claims description 60
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 42
- 239000002344 surface layer Substances 0.000 claims description 28
- 239000000377 silicon dioxide Substances 0.000 claims description 17
- 230000003014 reinforcing effect Effects 0.000 claims description 16
- 229920001187 thermosetting polymer Polymers 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 239000012783 reinforcing fiber Substances 0.000 claims description 12
- 150000004645 aluminates Chemical class 0.000 claims description 10
- 239000011230 binding agent Substances 0.000 claims description 10
- 239000004793 Polystyrene Substances 0.000 claims description 9
- 229920002223 polystyrene Polymers 0.000 claims description 9
- 239000000835 fiber Substances 0.000 claims description 8
- 239000011490 mineral wool Substances 0.000 claims description 7
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 6
- 239000004917 carbon fiber Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010451 perlite Substances 0.000 claims description 4
- 235000019362 perlite Nutrition 0.000 claims description 4
- -1 polypropylene Polymers 0.000 claims description 4
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- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000003000 extruded plastic Substances 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
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- 239000010959 steel Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims 2
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- 238000000034 method Methods 0.000 description 16
- 239000002002 slurry Substances 0.000 description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000002245 particle Substances 0.000 description 8
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000012774 insulation material Substances 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 230000002787 reinforcement Effects 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- 239000006004 Quartz sand Substances 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- 239000011398 Portland cement Substances 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- OSMSIOKMMFKNIL-UHFFFAOYSA-N calcium;silicon Chemical compound [Ca]=[Si] OSMSIOKMMFKNIL-UHFFFAOYSA-N 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
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- 239000013078 crystal Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
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- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 210000002257 embryonic structure Anatomy 0.000 description 1
- 229910001653 ettringite Inorganic materials 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 239000011494 foam glass Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
- C04B28/065—Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Structural Engineering (AREA)
- Ceramic Engineering (AREA)
- Architecture (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Building Environments (AREA)
- Finishing Walls (AREA)
Abstract
本发明提供了一种复合装饰板及其制备方法,涉及建材领域。该复合装饰板,包括:第一装饰面板和第二装饰面板,以及位于所述第一装饰面板和第二装饰面板之间的保温板;所述保温板分别与所述第一装饰面板和所述第二装饰面板一体连接。利用该复合装饰板能够解决目前的复合装饰板易发生形变,且由于使用粘结剂作为粘结材料而造成的防火性能较差的问题。
The invention provides a composite decorative board and a preparation method thereof, and relates to the field of building materials. The composite decorative panel includes: a first decorative panel and a second decorative panel, and a thermal insulation board located between the first decorative panel and the second decorative panel; the thermal insulation board is respectively connected with the first decorative panel and the The second decorative panel is integrally connected. The use of the composite decorative board can solve the problems that the current composite decorative board is prone to deformation and has poor fire resistance due to the use of an adhesive as a bonding material.
Description
技术领域technical field
本发明涉及建材领域,具体的涉及一种复合装饰板及其制备方法。The invention relates to the field of building materials, in particular to a composite decorative board and a preparation method thereof.
背景技术Background technique
传统的防火保温复合板为了兼顾防火保温与装饰的性能,通常采用压合设备将石材、瓷砖、铝板、水泥纤维板、硅钙板、玻镁板等面材与保温材料通过有机粘结剂进行粘贴,再在板材外侧喷涂真石漆、涂料、浮雕、装饰砂浆等装饰面层达到装饰效果,再通过锚固连接件与墙体进行连接。In order to take into account the performance of fire insulation and decoration, traditional fireproof and thermal insulation composite panels usually use pressing equipment to paste surface materials and thermal insulation materials such as stone, ceramic tile, aluminum board, cement fiber board, calcium silicon board, glass magnesium board, etc. through organic binders. , and then spray real stone paint, paint, embossing, decorative mortar and other decorative surfaces on the outside of the plate to achieve a decorative effect, and then connect to the wall through anchoring connectors.
其中,连接装饰面板与保温板的有机粘结剂在室外长期干湿循环、冻融循环、冷热交替、紫外线照射等作用条件下出现老化、脱落、渗漏、保温芯材与装饰面层脱落的严重问题,严重影响了建筑的安全性及耐久性。同时在复合板材过程中,有机材料VOC排放超标,存在着火灾的安全隐患,严重影响了人体的安全和健康。另外,目前的防火保温复合板是一层保温板+一层装饰面板的结构,该结构在使用中容易发生形变,易造成墙体表面的复合板脱落,影响建筑物的美观性。Among them, the organic binder connecting the decorative panel and the thermal insulation board will age, fall off, leak, and the thermal insulation core material and the decorative surface layer will fall off under the action conditions of long-term outdoor drying and humidity cycles, freeze-thaw cycles, alternating heat and cold, and ultraviolet radiation. serious problems, seriously affecting the safety and durability of the building. At the same time, in the process of composite board, the VOC emission of organic materials exceeds the standard, and there is a fire safety hazard, which seriously affects the safety and health of the human body. In addition, the current fireproof and thermal insulation composite board is a structure of one layer of thermal insulation board + one layer of decorative panels, which is prone to deformation during use, which easily causes the composite board on the wall surface to fall off, affecting the aesthetics of the building.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种复合装饰板,以解决目前的复合装饰板易发生形变,且由于使用粘结剂作为粘结材料而造成的防火性能较差的问题。The purpose of the present invention is to provide a composite decorative board to solve the problem that the current composite decorative board is prone to deformation and has poor fire resistance due to the use of an adhesive as a bonding material.
为达到上述发明目的,本发明采用的技术方案如下:In order to achieve the above-mentioned purpose of the invention, the technical scheme adopted in the present invention is as follows:
一种复合装饰板,包括:第一装饰面板和第二装饰面板,以及位于所述第一装饰面板和第二装饰面板之间的保温板;所述保温板分别与所述第一装饰面板和所述第二装饰面板一体连接。A composite decorative panel, comprising: a first decorative panel and a second decorative panel, and a thermal insulation board located between the first decorative panel and the second decorative panel; the thermal insulation board is respectively connected with the first decorative panel and the second decorative panel. The second decorative panels are integrally connected.
进一步地,所述第一装饰面板和所述第二装饰面板的制备原料按重量份数计包括:Further, the raw materials for the preparation of the first decorative panel and the second decorative panel, in parts by weight, include:
普硅白水泥10~30份,含铝水泥10~50份,缓凝剂0.1~0.2份,粘合剂3~7份;所述含铝水泥包括铝酸盐水泥和硫铝酸盐水泥的至少一种。10-30 parts of ordinary silica white cement, 10-50 parts of aluminum-containing cement, 0.1-0.2 parts of retarder, and 3-7 parts of binder; the aluminum-containing cement includes aluminate cement and sulfoaluminate cement. at least one.
进一步地,所述第一装饰面板和所述第二装饰面板的制备原料按重量份数计包括:Further, the raw materials for the preparation of the first decorative panel and the second decorative panel, in parts by weight, include:
普硅白水泥10~30份,含铝水泥10~50份,减缩组分5~10份,缓凝剂0.1~0.2份,促凝剂0.1~0.3,粘合剂2~5份,级配精选骨料10~30份。10-30 parts of ordinary silica white cement, 10-50 parts of aluminum-containing cement, 5-10 parts of shrinkage-reducing components, 0.1-0.2 parts of retarder, 0.1-0.3 parts of accelerator, 2-5 parts of binder, graded Selected aggregates of 10 to 30 servings.
进一步地,所述第一装饰面板和所述第二装饰面板内部均设有加强层,所述加强层为加强网层或加强纤维层。Further, both the first decorative panel and the second decorative panel are provided with a reinforcing layer, and the reinforcing layer is a reinforcing mesh layer or a reinforcing fiber layer.
进一步地,所述加强层为网状结构,所述加强层包括玻纤网、碳纤维网、玄武岩网或钢丝网中的至少一种。Further, the reinforcement layer is a mesh structure, and the reinforcement layer includes at least one of glass fiber mesh, carbon fiber mesh, basalt mesh or steel mesh.
进一步地,所述加强层为加强纤维层,所述加强纤维层中的加强纤维包括聚丙烯纤维、聚乙烯醇纤维、玻璃纤维、碳纤维或玄武岩纤维中的至少一种。Further, the reinforcing layer is a reinforcing fiber layer, and the reinforcing fibers in the reinforcing fiber layer include at least one of polypropylene fibers, polyvinyl alcohol fibers, glass fibers, carbon fibers or basalt fibers.
进一步地,所述保温板包括热固板、匀质板、硅质板、岩棉板、矿棉板、发泡水泥板、发泡玻璃板、发泡陶瓷板、珍珠岩板、挤塑板、聚苯板、石墨改性板、酚醛板或聚氨酯板中的至少一种。Further, the insulation board includes thermosetting board, homogeneous board, siliceous board, rock wool board, mineral wool board, foamed cement board, foamed glass board, foamed ceramic board, perlite board, extruded plastic board , at least one of polystyrene board, graphite modified board, phenolic board or polyurethane board.
进一步地,所述复合装饰板上设有用于与墙体连接的预设连接件。Further, the composite decorative board is provided with a preset connector for connecting with the wall.
一种上述复合装饰板的制备方法,包括以下步骤:A preparation method of the above-mentioned composite decorative board, comprising the following steps:
在所述保温板的两侧表面均涂覆面层料将,待所述面层料将固化后在所述保温板的两侧分别形成第一装饰面板和第二装饰面板,制备得到所述复合装饰板;The surface layer material is coated on both sides of the thermal insulation board, and after the surface layer material is cured, a first decorative panel and a second decorative panel are formed on both sides of the thermal insulation board respectively to prepare the composite Decorative plates;
或,or,
依次涂覆面层料将、保温层料将和面层料将,经固化后形成具有第一装饰面板、保温板和第二装饰面板结构的复合装饰板。The surface layer material, the heat insulation layer material and the surface layer material are sequentially coated, and after curing, a composite decorative panel having a structure of a first decorative panel, a heat insulating panel and a second decorative panel is formed.
进一步地,先将第一层面层料将置于模具中,然后在所述第一层面层料将的表面铺设所述保温板或所述保温层料将,之后再在所述保温板或所述保温层料将表面铺设第二层面层料将,经固化处理后形成所述复合装饰板。Further, the first layer layer material will be placed in the mold, and then the insulation board or the insulation layer material will be laid on the surface of the first layer layer material, and then the insulation board or the insulation layer material will be laid. The surface of the insulating layer material is laid with a second layer of layer material, and the composite decorative board is formed after curing treatment.
本发明提供的技术方案可以达到以下有益效果:The technical scheme provided by the present invention can achieve the following beneficial effects:
本发明提供的复合装饰板,采用双面板加保温板的结构,能够有效防止复合装饰板在使用过程中发生形变,进一步防止其从建筑物上发生脱落。另外,本发明的复合装饰板中保温板分别与第一装饰面板和第二装饰面板一体连接,提高了保温板与两面板的粘结强度,避免使用粘结剂,从而提高了复合装饰板的防火安全性以及连接的可靠性。The composite decorative board provided by the present invention adopts the structure of double-sided and thermal insulation board, which can effectively prevent the composite decorative board from being deformed during use, and further prevent it from falling off the building. In addition, in the composite decorative panel of the present invention, the thermal insulation board is integrally connected with the first decorative panel and the second decorative panel respectively, which improves the bonding strength between the thermal insulation board and the two panels, avoids the use of adhesives, and improves the durability of the composite decorative board. Fire safety and connection reliability.
应当理解的是,以上的一般描述和后文的细节描述仅是示例性的,并不能限制本发明。It is to be understood that the foregoing general description and the following detailed description are exemplary only and do not limit the invention.
附图说明Description of drawings
为了更清楚地说明本发明具体实施方式或现有技术中的技术方案,下面将对具体实施方式或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施方式,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to illustrate the specific embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings that need to be used in the description of the specific embodiments or the prior art. Obviously, the accompanying drawings in the following description The drawings are some embodiments of the present invention. For those of ordinary skill in the art, other drawings can also be obtained based on these drawings without creative efforts.
图1为本发明一种实施方式的复合装饰板的结构示意图。FIG. 1 is a schematic structural diagram of a composite decorative panel according to an embodiment of the present invention.
标号:10-第一装饰面板;20-保温板;30-第二装饰面板。Labels: 10-first decorative panel; 20-insulation panel; 30-second decorative panel.
具体实施方式Detailed ways
下面将结合实施例对本发明的实施方案进行详细描述,但是本领域技术人员将会理解,下列实施例仅用于说明本发明,而不应视为限制本发明的范围。实施例中未注明具体条件者,按照常规条件或制造商建议的条件进行。所用试剂或仪器未注明生产厂商者,均为可以通过市售购买获得的常规产品。The embodiments of the present invention will be described in detail below with reference to the examples, but those skilled in the art will understand that the following examples are only used to illustrate the present invention and should not be regarded as limiting the scope of the present invention. If the specific conditions are not indicated in the examples, it is carried out according to the conventional conditions or the conditions suggested by the manufacturer. The reagents or instruments used without the manufacturer's indication are conventional products that can be purchased from the market.
需要说明的是:本发明中,如果没有特别的说明,本文所提到的所有实施方式以及优选实施方法可以相互组合形成新的技术方案。本发明中,如果没有特别的说明,本文所提到的所有技术特征以及优选特征可以相互组合形成新的技术方案。本发明中,如果没有特别的说明,百分数(%)或者份指的是相对于组合物的重量百分数或重量份。本发明中,如果没有特别的说明,所涉及的各组分或其优选组分可以相互组合形成新的技术方案。本发明中,除非有其他说明,数值范围“a~b”表示a到b之间的任意实数组合的缩略表示,其中a和b都是实数。例如数值范围“6~22”表示本文中已经全部列出了“6~22”之间的全部实数,“6~22”只是这些数值组合的缩略表示。本发明所公开的“范围”以下限和上限的形式,可以分别为一个或多个下限,和一个或多个上限。本发明中,除非另有说明,各个反应或操作步骤可以顺序进行,也可以按照顺序进行。优选地,本文中的反应方法是顺序进行的。除非另有说明,本文中所用的专业与科学术语与本领域熟练人员所熟悉的意义相同。此外,任何与所记载内容相似或均等的方法或材料也可应用于本发明中。It should be noted that: in the present invention, if there is no special description, all the embodiments and preferred implementation methods mentioned herein can be combined with each other to form a new technical solution. In the present invention, unless otherwise specified, all the technical features and preferred features mentioned herein can be combined with each other to form a new technical solution. In the present invention, unless otherwise specified, percentage (%) or part refers to the weight percentage or weight part of the composition. In the present invention, unless otherwise specified, the involved components or their preferred components can be combined with each other to form a new technical solution. In the present invention, unless otherwise stated, the numerical range "a~b" represents an abbreviated representation of any combination of real numbers between a and b, wherein both a and b are real numbers. For example, the numerical range "6-22" indicates that all real numbers between "6-22" have been listed in this document, and "6-22" is just an abbreviated representation of the combination of these numerical values. A "range" disclosed herein may be in the form of a lower limit and an upper limit, which may be one or more lower limits, and one or more upper limits, respectively. In the present invention, unless otherwise specified, each reaction or operation step can be carried out sequentially or in sequence. Preferably, the reaction methods herein are performed sequentially. Unless otherwise defined, professional and scientific terms used herein have the same meanings as those familiar to those skilled in the art. In addition, any methods or materials similar or equivalent to those described can also be used in the present invention.
现有的复合装饰板,一般采用一层保温板和一层面板的结构,在安装时,面板朝外起到装饰建筑物的作用。但是由于面板长期裸露在外,受干湿循环、冻融循环、冷热交替、紫外线照射等作用条件下,面板易出现变形脱落等问题。The existing composite decorative board generally adopts the structure of one layer of thermal insulation board and one layer of panel, and during installation, the panel faces outwards to decorate the building. However, due to the long-term exposure of the panel, the panel is prone to problems such as deformation and falling off under the conditions of drying and humidity cycles, freeze-thaw cycles, alternating cold and heat, and ultraviolet radiation.
为了解决该问题,本发明提供了一种复合装饰板,如图1所示,包括第一装饰面板10和第二装饰面板30,以及位于所述第一装饰面板10和第二装饰面板30之间的保温板20;所述保温板20分别与所述第一装饰面板10和所述第二装饰面板30一体连接。In order to solve this problem, the present invention provides a composite decorative panel, as shown in FIG. 1 , comprising a first
本发明提供的上述复合装饰板,通过在保温板的两侧分别设置两面板,其中一侧的第一装饰面板用于装饰建筑物,另一侧的第二装饰面板则用于与建筑物的墙体接触。由于第二装饰面板处于墙体和保温板之间,处于相对封闭的空间,因此,第二装饰面板不易受到外界环境的干扰,不易发生变形,能够保持良好的结构稳定性,由此,采用双面板加保温板的结构,能够有效防止复合装饰板在使用过程中发生形变,进一步防止其从建筑物上发生脱落。同时,本发明的复合装饰板中保温板分别与第一装饰面板和第二装饰面板一体连接,提高了保温板与两面板的粘结强度,避免使用粘结剂,从而提高了复合装饰板的防火安全性以及连接的可靠性。In the above-mentioned composite decorative panel provided by the present invention, two panels are respectively arranged on both sides of the thermal insulation panel, wherein the first decorative panel on one side is used to decorate the building, and the second decorative panel on the other side is used to connect with the building. wall contact. Because the second decorative panel is located between the wall and the thermal insulation board, in a relatively closed space, the second decorative panel is not easily disturbed by the external environment, is not easily deformed, and can maintain good structural stability. The structure of the panel and the thermal insulation board can effectively prevent the composite decorative board from being deformed during use, and further prevent it from falling off the building. At the same time, in the composite decorative panel of the present invention, the thermal insulation board is integrally connected with the first decorative panel and the second decorative panel respectively, which improves the bonding strength between the thermal insulation board and the two panels, avoids the use of adhesives, and improves the durability of the composite decorative board. Fire safety and connection reliability.
为了实现保温板和装饰面板的一体化连接结构进而提高保温板与装饰面板的粘接性能,使得装饰面板不易发生脱落,在本发明的一种可能实施例中,采用将装饰面板的饰面材料料浆直接涂覆在保温板的表面进行固化,或将保温板的料将和饰面材料料将在塑化状态下实现粘接,再凝结固化,以形成一体化的复合装饰板,来获得更好的结合性能。In order to realize the integrated connection structure of the thermal insulation board and the decorative panel, thereby improving the bonding performance of the thermal insulation board and the decorative panel, so that the decorative panel is not easy to fall off, in a possible embodiment of the present invention, the veneer material of the decorative panel is used. The slurry is directly coated on the surface of the insulation board for curing, or the material of the insulation board and the decorative material will be bonded in a plasticized state, and then condensed and solidified to form an integrated composite decorative board. better binding properties.
而为了使得饰面材料料将能够具有很好的粘接性能和凝胶固化性能,同时还要兼具饰面材料的强度和表面性能要求。在本发明进一步的实施方式中,所述第一装饰面板和所述第二装饰面板的制备原料按重量份数计包括:In order to make the veneer material have good adhesion performance and gel curing performance, it also needs to meet the strength and surface performance requirements of the veneer material. In a further embodiment of the present invention, the raw materials for preparing the first decorative panel and the second decorative panel include, in parts by weight:
普硅白水泥10~30份,含铝水泥10~50份,缓凝剂0.1~0.2份,粘合剂3~7份;所述含铝水泥包括铝酸盐水泥和硫铝酸盐水泥的至少一种。10-30 parts of ordinary silica white cement, 10-50 parts of aluminum-containing cement, 0.1-0.2 parts of retarder, and 3-7 parts of binder; the aluminum-containing cement includes aluminate cement and sulfoaluminate cement. at least one.
本发明复合装饰板的装饰面板中,首先,选择普硅白水泥来作为主料,其具有较好的水化凝结性能,同时由于其具有很高的白度,色泽明亮,适合用于建筑装饰材料,但是由于其强度较低,因此,发明人采用了铝酸盐水泥和硫铝酸盐水泥中的至少一种和普硅白水泥混用,进而对饰面材料的强度进行增强,同时,铝酸盐水泥和硫铝酸盐水泥还具有很好的早强高强、抗冻、耐蚀、耐火度、抗渗等特性,并且还有利于提高饰面材料的凝结硬化速度,能够与普硅白水泥相互补强。但是,普硅白水泥跟铝酸盐水泥或硫铝酸盐水泥进行混用时,会急剧提高凝结速度,甚至发生“闪凝”现象,因此,发明人在饰面材料的组分中添加缓凝剂以控制料将的凝结速度。In the decorative panel of the composite decorative board of the present invention, firstly, ordinary silica white cement is selected as the main material, which has good hydration and coagulation performance, and at the same time, because of its high whiteness and bright color, it is suitable for architectural decoration. However, due to its low strength, the inventors used at least one of aluminate cement and sulfoaluminate cement to mix with ordinary silica white cement to enhance the strength of the facing material. At the same time, aluminum Salt cement and sulfoaluminate cement also have good early strength and high strength, frost resistance, corrosion resistance, refractoriness, impermeability and other characteristics, and are also conducive to improving the setting and hardening speed of the facing material, which can be combined with ordinary silica white. Cement reinforces each other. However, when ordinary silica white cement is mixed with aluminate cement or sulfoaluminate cement, the setting speed will increase sharply, and even a "flash setting" phenomenon will occur. agent to control the rate of coagulation.
进一步地,由于要使得饰面材料形成的装饰面层与保温板之间保持很好的结合强度,需要增强饰面材料本身的粘接性能,同时也需要使得水泥之间能够很好的粘接,进而固化后的装饰面层不容易脱落、变形以及粉化。因此,在饰面材料中加入粘合剂,以提高饰面材料料将整体的粘接性能以及成分之间的结合性能。Further, in order to maintain a good bonding strength between the decorative surface layer formed by the facing material and the thermal insulation board, it is necessary to enhance the bonding performance of the facing material itself, and at the same time, it is also necessary to enable good bonding between cements. , and the cured decorative surface layer is not easy to fall off, deform and powder. Therefore, an adhesive is added to the facing material to improve the overall bonding performance of the facing material and the bonding performance between the components.
因此,通过上述普硅白水泥10~30份、含铝水泥10~50份、缓凝剂0.1~0.2份和粘合剂3~7份的组分选择和科学配比,使得其组合形成的饰面材料预混料与水进行混合后能够形成饰面材料料将,该料将能够具有很好的凝结硬化性能,同时其还具有很强的粘接性能,能够凝结硬化后与保温板形成一体化复合板。进而使得形成的装饰面层不容易老化、脱落、安全系数高;同时,由上述水泥成分组合为主要原料形成的装饰面层保温防火性能较好,也不容易掉渣粉化。Therefore, through the above-mentioned component selection and scientific ratio of 10-30 parts of ordinary silica white cement, 10-50 parts of aluminum-containing cement, 0.1-0.2 parts of retarder and 3-7 parts of binder, the combination formed The decorative material premix can be mixed with water to form a decorative material. Integrated composite board. Further, the formed decorative surface layer is not easy to age, fall off, and has a high safety factor; at the same time, the decorative surface layer formed by the combination of the above-mentioned cement components as the main raw material has better thermal insulation and fire resistance, and is not easy to slag and powder.
作为进一步优选的实施方式,所述第一装饰面板和所述第二装饰面板的制备原料按重量份数计包括:As a further preferred embodiment, the raw materials for preparing the first decorative panel and the second decorative panel include, in parts by weight:
普硅白水泥10~30份,含铝水泥10~50份,减缩组分5~10份,缓凝剂0.1~0.2份,促凝剂0.1~0.3,粘合剂2~5份,级配精选骨料10~30份。10-30 parts of ordinary silica white cement, 10-50 parts of aluminum-containing cement, 5-10 parts of shrinkage-reducing components, 0.1-0.2 parts of retarder, 0.1-0.3 parts of accelerator, 2-5 parts of binder, graded Selected aggregates of 10 to 30 servings.
减缩组分包括但不限于硫铝酸钙膨胀剂、石膏粉、石灰、金属氧化物、明矾石类无机膨胀剂,与水泥反应生成钙矾石晶体或者氢氧化物,产生体积膨胀补偿后期收缩;聚醚或者聚醇类有机减缩剂降低水泥石毛细孔水的表面张力,减少水分蒸发过程的收缩力,从而起到减小收缩的目的。The shrinkage-reducing components include but are not limited to calcium sulfoaluminate expansion agent, gypsum powder, lime, metal oxides, and alumite inorganic expansion agents, which react with cement to generate ettringite crystals or hydroxides, resulting in volume expansion to compensate for later shrinkage; Polyether or polyalcohol organic shrinkage reducers reduce the surface tension of the water in the capillary pores of the cement stone and reduce the shrinkage force in the process of water evaporation, thereby reducing the shrinkage.
促凝剂包括但不限于氯化钙、氯化钠、亚硝酸钠、硫酸钠、硫代硫酸钠、偏铝酸钠、碳酸锂、氯化锂、氢氧化锂、硫酸铝或碳酸钠等,与水泥共同混合加水作用后,加速水泥的水化反应,起到提高早期强度的目的。Coagulants include but are not limited to calcium chloride, sodium chloride, sodium nitrite, sodium sulfate, sodium thiosulfate, sodium metaaluminate, lithium carbonate, lithium chloride, lithium hydroxide, aluminum sulfate or sodium carbonate, etc., After mixing with cement and adding water, it accelerates the hydration reaction of cement and improves the early strength.
级配精选骨料包括但不限于石英砂、河沙、尾矿砂、玻璃骨料、贝壳、玉石、彩砂、石材废料等按照一定级配进行搭配,起到减少收缩,降低用水量,提高强度的作用,同时骨料硬化后具有良好的装饰效果。Graded selected aggregates, including but not limited to quartz sand, river sand, tailings sand, glass aggregate, shells, jade, colored sand, stone waste, etc., are matched according to a certain gradation to reduce shrinkage, reduce water consumption, and improve The effect of strength, while the aggregate has a good decorative effect after hardening.
在本发明的一些实施方式中,所述第一装饰面板和所述第二装饰面板内部均设有加强层,所述加强层为加强网层或加强纤维层。In some embodiments of the present invention, both the first decorative panel and the second decorative panel are provided with a reinforcing layer, and the reinforcing layer is a reinforcing mesh layer or a reinforcing fiber layer.
通过设置加强层,可以提高第一装饰面板和第二装饰面板的抗拉强度,进一步提高复合装饰板的稳定性。By providing the reinforcement layer, the tensile strength of the first decorative panel and the second decorative panel can be improved, and the stability of the composite decorative panel can be further improved.
在本发明的一些实施方式中,所述加强层为网状结构,所述加强层包括玻纤网、碳纤维网、玄武岩网或钢丝网中的至少一种。In some embodiments of the present invention, the reinforcement layer is a mesh structure, and the reinforcement layer includes at least one of glass fiber mesh, carbon fiber mesh, basalt mesh or steel mesh.
在本发明的另一些实施方式中,所述加强层为加强纤维层,所述加强纤维层中的加强纤维包括聚丙烯纤维、聚乙烯醇纤维、玻璃纤维、碳纤维或玄武岩纤维中的至少一种。In other embodiments of the present invention, the reinforcing layer is a reinforcing fiber layer, and the reinforcing fibers in the reinforcing fiber layer include at least one of polypropylene fibers, polyvinyl alcohol fibers, glass fibers, carbon fibers or basalt fibers .
在本发明的一些实施方式中,所述保温板包括热固板、匀质板、硅质板、岩棉板、矿棉板、发泡水泥板、发泡玻璃板、发泡陶瓷板、珍珠岩板、挤塑板、聚苯板、石墨改性板、酚醛板或聚氨酯板中的至少一种。In some embodiments of the present invention, the thermal insulation board includes thermosetting board, homogeneous board, siliceous board, rock wool board, mineral wool board, foamed cement board, foamed glass board, foamed ceramic board, pearl At least one of rock board, extruded plastic board, polystyrene board, graphite modified board, phenolic board or polyurethane board.
进一步地,所述复合装饰板上设有用于与墙体连接的预设连接件。该预设连接件可以为预制方槽,方槽内为空腔结构,安装时,可以将“L”型的锚固件插入该方槽内,另一侧与墙体连接,从而实现复合装饰板与墙体的连接。Further, the composite decorative board is provided with a preset connector for connecting with the wall. The preset connector can be a prefabricated square groove, and the square groove is a cavity structure. During installation, an "L"-shaped anchor can be inserted into the square groove, and the other side is connected to the wall, so as to realize the composite decorative board Connection to the wall.
在安装时可以选用厚度可调的“L”型的锚固件,其一端可以插入保温板内并用粘结剂辅助加固,另一端则与墙体连接。或者用厚度可调的“L”型的锚固件的一端扣住复合装饰板边缘处的凹槽,另一端与墙体连接,该连接方式中,复合装饰板边缘处需设有凹槽,例如第一装饰面板和第二装饰面板的尺寸大于保温板的尺寸从而在边缘处形成凹槽。During installation, an "L"-shaped anchor with adjustable thickness can be selected, one end of which can be inserted into the insulation board and reinforced with adhesive, and the other end is connected with the wall. Or use one end of the "L"-shaped anchor with adjustable thickness to fasten the groove at the edge of the composite decorative panel, and connect the other end to the wall. In this connection method, a groove is required at the edge of the composite decorative panel, for example The size of the first decorative panel and the second decorative panel is larger than that of the thermal insulation board to form grooves at the edges.
第二方面,本发明提供了一种上述复合装饰板的制备方法,包括以下步骤:In a second aspect, the present invention provides a method for preparing the above-mentioned composite decorative panel, comprising the following steps:
在所述保温板的两侧表面均涂覆面层料将,待所述面层料将固化后在所述保温板的两侧分别形成第一装饰面板和第二装饰面板,制备得到所述复合装饰板;The surface layer material is coated on both sides of the thermal insulation board, and after the surface layer material is cured, a first decorative panel and a second decorative panel are formed on both sides of the thermal insulation board respectively to prepare the composite Decorative plates;
或,or,
依次涂覆面层料将、保温层料将和面层料将,经固化后形成具有第一装饰面板、保温板和第二装饰面板结构的复合装饰板。The surface layer material, the heat insulation layer material and the surface layer material are sequentially coated, and after curing, a composite decorative panel having a structure of a first decorative panel, a heat insulating panel and a second decorative panel is formed.
本发明提供的制备方法直接将面层料将涂覆于保温板的两侧,在塑性状态下经固化处理使保温板与面层材料融为一体,或者直接利用面层料将和保温层料将直接形成一体连接的复合装饰板,从而形成具有双层装饰面板结构的复合装饰板。该方法能够有效避免使用有机粘结剂,使装饰面板和保温板从自身结构内部形成稳定的连接,两者的连接强度远大于利用粘结剂所达到的粘结强度。The preparation method provided by the invention directly coats the surface layer material on both sides of the thermal insulation board, and then solidifies the thermal insulation board and the surface layer material in a plastic state to integrate the thermal insulation board and the surface layer material, or directly uses the surface layer material to combine with the thermal insulation layer material. An integrally connected composite decorative panel will be directly formed, thereby forming a composite decorative panel with a double-layer decorative panel structure. The method can effectively avoid the use of organic adhesives, so that the decorative panel and the thermal insulation board form a stable connection from the inside of their own structures, and the connection strength of the two is far greater than that achieved by using the adhesive.
其中,保温层料将例如包括采用水泥基材料、镁质材料、矿粉或粉煤灰等无机胶凝材料,与聚苯颗粒、聚氨酯颗粒、石墨改性颗粒、珍珠岩颗粒、膨胀蛭石、陶粒、陶砂等混合后形成的轻质保温材料或物理和化学形式的发泡混凝土材料。利用本发明的材料制备得到的复合装饰板的耐火等级均为A级。Among them, the thermal insulation layer material will include, for example, inorganic cementitious materials such as cement-based materials, magnesia materials, mineral powder or fly ash, etc., together with polystyrene particles, polyurethane particles, graphite modified particles, perlite particles, expanded vermiculite, Lightweight thermal insulation materials or foamed concrete materials in physical and chemical forms formed by mixing ceramsite, ceramic sand, etc. The fire resistance grades of the composite decorative panels prepared by using the materials of the present invention are all A grades.
在本发明的一些实施方式中,先将第一层面层料将置于模具中,然后在所述第一层面层料将的表面铺设所述保温板或所述保温层料将,之后再在所述保温板或所述保温层料将表面铺设第二层面层料将,经固化处理后形成所述复合装饰板。In some embodiments of the present invention, the first layer material will be placed in the mold, and then the insulation board or the insulation layer material will be laid on the surface of the first layer material, and then the insulation board will be placed on the surface of the first layer material. The surface of the thermal insulation board or the thermal insulation layer material will be laid with a second layer layer material, and the composite decorative board will be formed after curing treatment.
其中,模具底部可以设置不同的花纹造型。模具为硅胶模具、聚氨酯模具、塑料模具、玻璃钢模具、木质模具、石膏模具、聚苯板模具、铝质模具或橡胶模具中的一种或几种复合使用。Among them, the bottom of the mold can be set with different pattern shapes. The mold is one or a combination of silicone molds, polyurethane molds, plastic molds, glass fiber reinforced plastic molds, wooden molds, plaster molds, polystyrene molds, aluminum molds or rubber molds.
在本发明的一些实施方式中,可以利用自动计量的平模运行设备制备复合装饰板。其中,单个模具在平模运行设备上不断运行,在设备特定节点位置设有储料仓,当模具运行至该节点处,储料仓打开,储存于储料仓内的料将按预设计量值下落至模具内。在该设备的中间部位设有刮板、滚筒或振动装置将料将整平。另外,该设备还设有自动网格布铺设装置。该设备中模具的运行长度可以依据料将的硬化时间进行调整,这样,当料将硬化后就可以利用机械手翻转起模。当料将硬化后,后续可以选择性的进行喷涂、3D打印、雕刻、染色、打磨、抛光、酸洗和转印等处理工艺。In some embodiments of the present invention, composite trim panels may be prepared using automatic metering flat die running equipment. Among them, a single mold runs continuously on the flat mold operation equipment, and a storage bin is set at a specific node position of the equipment. When the mold runs to this node, the storage bin is opened, and the material stored in the storage bin will be measured according to the preset. The value falls into the mold. There is a scraper, a roller or a vibrating device in the middle of the equipment to level the material. In addition, the equipment is also equipped with an automatic grid cloth laying device. The running length of the mold in the equipment can be adjusted according to the hardening time of the material, so that when the material is hardened, the robot can be used to flip the mold. After the material will harden, it can be selectively sprayed, 3D printed, engraved, dyed, sanded, polished, pickled and transferred.
在底部面层料将保持塑性状态时,浇筑由水泥、母料、聚苯颗粒与水混合后形成的纳米微孔A级防火保温料浆或者铺设A级防火保温板(例如热固保温板),在保温层上方浇筑高流态面层料将,使保温层与上下两侧料将融为一体,硬化后形成双面复合的ABA的整体。When the bottom surface layer will remain in a plastic state, pour the nano-microporous Grade A fireproof and thermal insulation slurry formed by mixing cement, masterbatch, polystyrene particles with water, or lay a Grade A fireproof thermal insulation board (such as thermosetting thermal insulation board) , pour the high-fluid surface layer material above the insulation layer, so that the insulation layer and the upper and lower sides of the material will be integrated, and after hardening, a double-sided composite ABA is formed.
实施例1Example 1
本实施例是一种复合装饰板,如图1所示,包括第一装饰面板和第二装饰面板,以及位于第一装饰面板和第二装饰面板之间的保温板;所述保温板分别与所述第一装饰面板和所述第二装饰面板一体连接;其中,第一装饰面板和第二装饰面板的制备原料按重量份数计包括:普硅白水泥20份,铝酸盐水泥20份,柠檬酸0.15份,分散乳胶粉4份。This embodiment is a composite decorative panel, as shown in FIG. 1 , including a first decorative panel and a second decorative panel, and a thermal insulation board located between the first decorative panel and the second decorative panel; the thermal insulation board is respectively connected to the The first decorative panel and the second decorative panel are integrally connected; wherein, the raw materials for the preparation of the first decorative panel and the second decorative panel in parts by weight include: 20 parts of ordinary silica white cement and 20 parts of aluminate cement , 0.15 parts of citric acid, 4 parts of disperse polymer powder.
该该复合装饰板利用以下方法制备得到:The composite decorative board is prepared by the following method:
先将第一层面层料将置于模具中,然后在所述第一层面层料将的表面铺设保温层料将,之后再在保温层料将表面铺设第二层面层料将,经固化处理后形成所述复合装饰板。First, the first layer of layer material will be placed in the mold, and then the thermal insulation layer will be laid on the surface of the first layer of layer material, and then the second layer of layer will be laid on the surface of the thermal insulation layer. After curing Then the composite decorative board is formed.
其中,液态保温层料将为浇筑型A级防火保温料浆,采用水泥、母料、聚苯颗粒、水以及纤维共同融合形成的纳米微孔料浆包覆的A级材料。Among them, the liquid insulation layer material will be cast-type A-grade fire-proof insulation slurry, which is a grade-A material coated with nano-microporous slurry formed by the fusion of cement, masterbatch, polystyrene particles, water and fibers.
实施例2Example 2
本实施例是一种复合装饰板,其结构与实施例1中的复合装饰板的结构相同,且各原料也相同。This embodiment is a composite decorative board, the structure of which is the same as that of the composite decorative board in Embodiment 1, and the raw materials are also the same.
该复合装饰板利用以下方法制备得到:The composite decorative board is prepared by the following method:
先将第一层面层料将置于模具中,然后在所述第一层面层料将的表面铺设所述保温板,之后再在所述保温板表面铺设第二层面层料将,经固化处理后形成所述复合装饰板。First, the first layer of laminate will be placed in the mold, then the insulation board will be laid on the surface of the first layer of laminate, and then the second layer of laminate will be laid on the surface of the thermal insulation board. After curing Then the composite decorative board is formed.
其中,保温板采用热固复合保温板,是利用实施例1中的保温层料将制备得到的热固复合保温板。Wherein, the thermal insulation board adopts a thermoset composite thermal insulation board, which is a thermoset composite thermal insulation board prepared by using the thermal insulation layer material in Example 1.
实施例3-6Examples 3-6
实施例3-6分别为一种复合装饰板,其与实施例1的不同之处所使用的保温板不同,具体参见表1。Examples 3-6 are respectively a composite decorative board, which is different from the thermal insulation board used in Example 1 in the difference, see Table 1 for details.
实施例7Example 7
实施例7为一种复合装饰板,其与实施例1的不同之处在于第一装饰面板和第二装饰面板的制备原料不同,具体的为:Embodiment 7 is a composite decorative panel, which is different from Embodiment 1 in that the preparation raw materials of the first decorative panel and the second decorative panel are different, specifically:
普硅白水泥10~30份,含铝水泥10~50份,硫铝酸钙膨胀剂5~10份,缓凝剂0.1~0.2份,促凝剂0.1~0.3,粘合剂2~5份,10-30 parts of ordinary silica white cement, 10-50 parts of aluminum-containing cement, 5-10 parts of calcium sulfoaluminate expansion agent, 0.1-0.2 parts of retarder, 0.1-0.3 parts of accelerator, 2-5 parts of binder ,
普硅白水泥20份,铝酸盐水泥20份,硫铝酸钙膨胀剂7份,氯化钙0.2份,柠檬酸0.15份,分散乳胶粉4份,级配精选骨料石英砂15份。20 parts of ordinary silica white cement, 20 parts of aluminate cement, 7 parts of calcium sulfoaluminate expansion agent, 0.2 parts of calcium chloride, 0.15 parts of citric acid, 4 parts of disperse polymer powder, 15 parts of graded selected aggregate quartz sand .
实施例8Example 8
实施例8为一种复合装饰板,其与实施例7的不同之处在于第一装饰面板和第二装饰面板的制备原料不同,具体的为:Embodiment 8 is a composite decorative panel, which is different from Embodiment 7 in that the preparation raw materials of the first decorative panel and the second decorative panel are different, specifically:
普硅白水泥20份,铝酸盐水泥20份,硫铝酸钙膨胀剂10份,氯化钙0.1份,柠檬酸0.15份,分散乳胶粉4份,级配精选骨料石英砂25份。20 parts of ordinary silica white cement, 20 parts of aluminate cement, 10 parts of calcium sulfoaluminate expansion agent, 0.1 parts of calcium chloride, 0.15 parts of citric acid, 4 parts of disperse polymer powder, 25 parts of graded selected aggregate quartz sand .
实施例9Example 9
实施例9为一种复合装饰板,其与实施例7的不同之处在于第一装饰面板和第二装饰面板的制备原料不同,具体的为:Embodiment 9 is a composite decorative panel, which is different from Embodiment 7 in that the preparation raw materials of the first decorative panel and the second decorative panel are different, specifically:
普硅白水泥20份,铝酸盐水泥20份,硫铝酸钙膨胀剂5份,氯化钙0.3份,柠檬酸0.15份,分散乳胶粉4份,级配精选骨料石英砂10份。20 parts of ordinary silica white cement, 20 parts of aluminate cement, 5 parts of calcium sulfoaluminate expansion agent, 0.3 parts of calcium chloride, 0.15 parts of citric acid, 4 parts of disperse polymer powder, 10 parts of graded selected aggregate quartz sand .
实施例10Example 10
实施例10为一种复合装饰板,其与实施例2的不同之处在于第一装饰面板和第二装饰面板的制备原料不同,具体的为:42.5级白色硅酸盐水泥40%、级配骨料:60%,水料比0.25。
对比例1Comparative Example 1
本对比例是一种复合装饰板,包括保温板和位于保温板一侧表面的装饰面板。其中,装饰面板的制备原料按重量份数计包括:普硅白水泥20份,铝酸盐水泥20份,缓凝剂0.15份,粘合剂4份。This comparative example is a composite decorative board, including a thermal insulation board and a decorative panel on one side of the thermal insulation board. Among them, the raw materials for the preparation of the decorative panel include in parts by weight: 20 parts of ordinary silica white cement, 20 parts of aluminate cement, 0.15 parts of retarder, and 4 parts of adhesive.
该复合装饰板利用以下方法制备得到:The composite decorative board is prepared by the following method:
先将保温板置于模具中,然后在保温板表面铺设面层料将,经固化处理后形成所述复合装饰板。The thermal insulation board is first placed in the mold, and then a surface layer material is laid on the surface of the thermal insulation board, and the composite decorative board is formed after curing treatment.
其中,保温板采用的热固复合保温板与实施例2中的相同。Wherein, the thermosetting composite thermal insulation board used for the thermal insulation board is the same as that in Example 2.
对比例2Comparative Example 2
本对比例是一种复合装饰板,其与对比例1的不同之处在于使用的面层料将不同,该对比例中的面层料将具体为:42.5级白色硅酸盐水泥40%、级配骨料:60%,水料比0.25。其他制备工艺步骤与对比例1相同。This comparative example is a composite decorative board, which is different from the comparative example 1 in that the used surface layer material will be different, and the surface layer material in this comparative example will be: 42.5 grade white Portland cement 40%, Graded aggregate: 60%, water-material ratio 0.25. Other preparation process steps are the same as in Comparative Example 1.
表1Table 1
分别对实施例1-10提供的复合装饰板进行各项性能测试,测试结果列于表2。Various performance tests were performed on the composite decorative boards provided in Examples 1-10, and the test results are listed in Table 2.
表2Table 2
从表2中可以看出,浇筑型A级防火保温料浆为采用水泥、母料、聚苯颗粒、水和纤维共同融合形成的纳米微孔料浆包覆的A级材料,相比于传统压制型热固复合保温板由于大量纳米微孔料浆产生了较大体积包裹更好,所以防火效果更好,热值更低;同时大量微孔纳米料浆产生的气孔具有良好的保温作用对于聚苯颗粒的保温效果起到了有机与无机材料叠加、无机包裹有机的“包裹隔离”作用,同时在设备投入方面,不需要增加压制型设备进行预先压制成胚体在切割成板材的设备投入,只需要在成型过程中一次性进行粘接即可,流态保温料浆节省投入,避免粉尘,节能、经济、环保。面层高强度料浆与纳米微孔保温料浆均是在湿润状态下进行有效连接,融合性好,粘接强度更高。As can be seen from Table 2, the pouring type A-grade fireproof and thermal insulation slurry is a grade-A material coated with nano-microporous slurry formed by the joint fusion of cement, masterbatch, polystyrene particles, water and fibers. The pressed thermosetting composite insulation board has a larger volume and better packaging due to a large amount of nano-microporous slurry, so the fireproof effect is better and the calorific value is lower; at the same time, the pores generated by a large number of micro-porous nano-slurry have a good thermal insulation effect. The thermal insulation effect of polystyrene particles plays the role of "wrapping and isolating" organic and inorganic materials and inorganic wrapping organically. At the same time, in terms of equipment investment, there is no need to increase the equipment investment of pressing equipment to pre-press into embryos and cut into plates. It only needs to be bonded at one time during the molding process, and the fluid thermal insulation slurry saves investment, avoids dust, and is energy-saving, economical and environmentally friendly. The surface layer high-strength slurry and the nano-microporous thermal insulation slurry are effectively connected in a wet state, with good fusion and higher bonding strength.
相比于市场上其它A级防火的保温材料,流态保温料浆的密度更小、粘接强度高,抗承载力好,导热系数低。因而具有投入小,性能好、生产便利的特点具有广阔的市场前景和发展空间。Compared with other A-class fireproof insulation materials on the market, the fluid insulation slurry has lower density, higher bonding strength, better bearing resistance and lower thermal conductivity. Therefore, it has the characteristics of small investment, good performance and convenient production, and has broad market prospects and development space.
另外,对实施例2提供的双面复合结构的复合装饰板和对比例1提供的单面复合结构的复合装饰板进行了长期变形率测试、抗弯承载能力测试与内部粘结强度测试,并统计了实际运输施工过程中的破损率,结果列于表3。In addition, the long-term deformation rate test, the flexural bearing capacity test and the internal bond strength test were carried out on the composite decorative board with double-sided composite structure provided in Example 2 and the composite decorative board with single-sided composite structure provided in Comparative Example 1. The damage rate during the actual transportation and construction process was counted, and the results are listed in Table 3.
表3table 3
从表3中的测试数据可以看出以下几点:The following points can be seen from the test data in Table 3:
通过单面复合(AB)结构与双面复合(ABA)结构对比结果可以看到,单面复合(AB)结构的板材与双面复合结构的板材在30天内的变形量差异基本不大,但是随着龄期时间的延长,在365天后,单面复合板材达到-0.1%,相比于双面复合(ABA)结构,相差接近20倍,其原因的产生是由于,保温板材或者浆料自身密度较低(一般在180Kg/m3以内),强度较低(一般只有0.1~0.5MPa);而单面复合的无机料浆硬化后形成的板材抗压强度在50MPa以上,两者弹性模量差距过大,在湿粘接的作用下应力不同而产生的变形所导致。虽然面层材料从配比上采取了有效的方法进行控制,但是相比双面复合的结构形式仍然变形较大。而当采用双面复合(ABA)结构后,两侧形成了相同的变形量产生等量的约束作用,进而不会产生变形和翘曲。From the comparison results of the single-sided composite (AB) structure and the double-sided composite (ABA) structure, it can be seen that the difference in the deformation of the single-sided composite (AB) structure and the double-sided composite structure within 30 days is basically small, but With the prolongation of age, after 365 days, the single-sided composite sheet reaches -0.1%, which is nearly 20 times higher than that of the double-sided composite (ABA) structure. The reason is that the thermal insulation sheet or the slurry itself The density is low (generally within 180Kg/m3), and the strength is low (generally only 0.1 ~ 0.5MPa); while the compressive strength of the plate formed by the hardening of the single-sided composite inorganic slurry is above 50MPa, and the difference in elastic modulus between the two is If it is too large, it is caused by the deformation caused by different stress under the action of wet bonding. Although the surface layer material has taken an effective method to control the ratio, it is still deformed more than the double-sided composite structure. However, when the double-sided composite (ABA) structure is adopted, the same amount of deformation is formed on both sides, resulting in the same amount of restraint, so that deformation and warping will not occur.
从对比例2和实施例10的测试数据可以看出,采用白色硅酸盐水泥的普通水泥砂浆制作的面材,自身收缩变形量较大,采用双面复合的(ABA)结构后,变形量有了很大减小。From the test data of Comparative Example 2 and Example 10, it can be seen that the surface material made of ordinary cement mortar using white Portland cement has a large amount of shrinkage and deformation. After using the double-sided composite (ABA) structure, the amount of deformation has been greatly reduced.
2)抗弯承载能力代表了板材是否容易折断,当复合装饰层为单面复合(AB形式)结构时,保温层是薄弱层,很容易受到外力作用产生断裂;当复合装饰板采用双面复合(ABA)结构时,保温材料两侧具有保护层,受到外力作用下承受能力强,两侧力量叠加,因而抗弯承载能力更好,两者相比单面复合(AB)结构时只有0.8倍,双面复合(ABA)结构时为2.5倍。而且,当板材的尺寸规格越大,厚度越小,抗弯承载能力越重要。2) The flexural bearing capacity represents whether the board is easy to break. When the composite decorative layer is a single-sided composite (AB form) structure, the thermal insulation layer is a weak layer and is easily broken by external forces; when the composite decorative board adopts a double-sided composite structure. In the (ABA) structure, the insulation material has protective layers on both sides, which has a strong bearing capacity under the action of external force, and the forces on both sides are superimposed, so the flexural bearing capacity is better. Compared with the single-sided composite (AB) structure, the two are only 0.8 times. , 2.5 times for the double-sided composite (ABA) structure. Moreover, when the size of the sheet is larger and the thickness is smaller, the flexural bearing capacity is more important.
3)装饰保温一体化板采用粘接砂浆与墙体进行粘结时,单面复合(AB)结构是保温板与粘接剂连接,由于保温板强度较低,虽然在拉伸中破坏界面在保温层,但是却临近“界面边缘”,因而拉伸粘接强度较低;而当采用双面复合(ABA)结构时,面板与粘接砂浆进行粘接,面板强度高,拉应力高。拉伸破坏实验时,破坏界面在“保温层内部”,因而拉伸粘接强度高。由此,双面复合(ABA)结构高的拉伸粘接强度能够保证建筑结构整体的安全性,杜绝了保温材料与墙体之间空鼓、脱落的隐患。3) When the decorative and thermal insulation integrated board is bonded to the wall by bonding mortar, the single-sided composite (AB) structure is the connection between the thermal insulation board and the adhesive. Due to the low strength of the thermal insulation board, although the interface is damaged during stretching The thermal insulation layer is close to the "interface edge", so the tensile bond strength is low; when the double-sided composite (ABA) structure is used, the panel is bonded with the bonding mortar, the panel strength is high, and the tensile stress is high. In the tensile failure test, the failure interface is "inside the thermal insulation layer", so the tensile bonding strength is high. Therefore, the high tensile bonding strength of the double-sided composite (ABA) structure can ensure the overall safety of the building structure, and eliminate the hidden danger of hollowing and falling off between the thermal insulation material and the wall.
4)在板材运输过程中,单面复合(AB)结构中只有一层面板为加强层,而保温板为薄弱层,保温板容易受到破坏,同时面板边角处处于“悬空”,在运输过程中掉角、损边现象非常严重。采用当双面复合(ABA)结构时,上下面板同时为加强层,保温材不会受到破坏,同时双层平行的面板增加了复合装饰板整体的强度,不会产生破坏。在实际应用中,装饰板的掉角、损边产生会严重影响建筑外墙的整体美观效果,甚至物理力学性能。而采用当双面复合(ABA)结构时,从设计上完全避免了这一问题。4) In the process of board transportation, in the single-sided composite (AB) structure, only one panel is the reinforcing layer, and the insulation board is the weak layer, and the insulation board is easily damaged. The phenomenon of corner drop and edge damage is very serious. When the double-sided composite (ABA) structure is adopted, the upper and lower panels are simultaneously reinforcing layers, and the thermal insulation material will not be damaged. At the same time, the double-layer parallel panels increase the overall strength of the composite decorative panel without damage. In practical applications, the corner drop and edge damage of the decorative panel will seriously affect the overall aesthetic effect of the building exterior wall, and even the physical and mechanical properties. When the double-sided composite (ABA) structure is used, this problem is completely avoided by design.
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, but not to limit them; although the present invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: The technical solutions described in the foregoing embodiments can still be modified, or some or all of the technical features thereof can be equivalently replaced; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the technical solutions of the embodiments of the present invention. scope.
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