CN111393882B - Ultraviolet radiation resistant low-absorptivity inorganic white thermal control coating and preparation method thereof - Google Patents
Ultraviolet radiation resistant low-absorptivity inorganic white thermal control coating and preparation method thereof Download PDFInfo
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- CN111393882B CN111393882B CN202010212002.2A CN202010212002A CN111393882B CN 111393882 B CN111393882 B CN 111393882B CN 202010212002 A CN202010212002 A CN 202010212002A CN 111393882 B CN111393882 B CN 111393882B
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- thermal control
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- water glass
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- 238000000576 coating method Methods 0.000 title claims description 55
- 239000011248 coating agent Substances 0.000 title claims description 51
- 230000005855 radiation Effects 0.000 title claims description 10
- 238000002360 preparation method Methods 0.000 title claims description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 17
- -1 polyoxypropylene glycerol Polymers 0.000 claims description 15
- 235000019353 potassium silicate Nutrition 0.000 claims description 15
- 239000002562 thickening agent Substances 0.000 claims description 15
- 239000002518 antifoaming agent Substances 0.000 claims description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910001868 water Inorganic materials 0.000 claims description 10
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 229920000570 polyether Polymers 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004111 Potassium silicate Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 4
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 4
- RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical compound [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 244000137852 Petrea volubilis Species 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 239000012463 white pigment Substances 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 229910000733 Li alloy Inorganic materials 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 239000001989 lithium alloy Substances 0.000 claims description 2
- GCICAPWZNUIIDV-UHFFFAOYSA-N lithium magnesium Chemical compound [Li].[Mg] GCICAPWZNUIIDV-UHFFFAOYSA-N 0.000 claims description 2
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052912 lithium silicate Inorganic materials 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
本发明公开了一种耐紫外辐照低吸收率无机白色热控涂层及其制备方法。本发明要解决现有的无机白漆热控涂层的在空间紫外辐照作用下对其光热性能退化较大的问题。本发明热控涂层的组成为:水玻璃、白颜料、分散剂、基材润湿剂、消泡剂、增稠剂,余量的去离子水。采用砂磨工艺分散2~6小时即可制备涂料,随后可采用空气喷涂、刷涂或刮涂等涂装工艺制备涂层。本发明涂层的太阳吸收比为0.11~0.20,附着力为0~1级,耐紫外辐照5000ESH后,太阳吸收比变化值不大于0.05,满足高性能、高可靠性航天器对热控涂层的性能需求。
The invention discloses an inorganic white thermal control coating with ultraviolet radiation resistance and low absorption rate and a preparation method thereof. The invention aims to solve the problem that the photothermal performance of the existing inorganic white paint thermal control coating is greatly degraded under the action of space ultraviolet irradiation. The thermal control coating of the present invention is composed of water glass, white pigment, dispersant, substrate wetting agent, defoaming agent, thickening agent, and the balance of deionized water. The coating can be prepared by sanding and dispersing for 2 to 6 hours, and then the coating can be prepared by air spraying, brushing or blade coating. The solar absorption ratio of the coating of the invention is 0.11-0.20, the adhesion is 0-1 grade, and the change value of the solar absorption ratio is not more than 0.05 after ultraviolet radiation resistance of 5000ESH, which meets the requirements of high-performance and high-reliability spacecraft for thermal control coatings. layer performance requirements.
Description
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CN202010212002.2A CN111393882B (en) | 2020-03-24 | 2020-03-24 | Ultraviolet radiation resistant low-absorptivity inorganic white thermal control coating and preparation method thereof |
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CN202010212002.2A CN111393882B (en) | 2020-03-24 | 2020-03-24 | Ultraviolet radiation resistant low-absorptivity inorganic white thermal control coating and preparation method thereof |
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CN111393882B true CN111393882B (en) | 2021-09-28 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111893451B (en) * | 2020-08-13 | 2022-10-21 | 上海卫星工程研究所 | High-performance wave-transparent nano thermal control film for satellite, preparation method and application thereof |
CN112480727B (en) * | 2020-11-26 | 2021-07-20 | 哈尔滨工业大学 | Preparation method of white molecular adsorption coating with thermal control function |
CN112961520A (en) * | 2021-04-06 | 2021-06-15 | 广州大学 | Water-resistant long-acting inorganic zinc oxide super-hydrophilic coating and preparation method and application thereof |
CN114192363A (en) * | 2021-12-23 | 2022-03-18 | 上海卫星装备研究所 | Preparation method and system of solar absorption ratio adjustable thermal control coating and heat insulation assembly |
CN116082877B (en) * | 2022-12-29 | 2024-04-09 | 上海卫星装备研究所 | High-reflectivity filler and inorganic thermal control coating thereof and preparation method thereof |
CN118460049B (en) * | 2024-05-30 | 2025-02-28 | 哈尔滨工业大学 | ALD modified ultraviolet radiation resistant organic white thermal control coating and preparation method thereof |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5310422A (en) * | 1992-12-01 | 1994-05-10 | General Electric Co. | High temperature inorganic paint |
US5885658A (en) * | 1992-08-10 | 1999-03-23 | Mcdonnell Douglas Technologies, Inc. | Process for protecting optical properties of a thermal control |
US6176453B1 (en) * | 1997-03-18 | 2001-01-23 | Hughes Electronics Corporation | Radiator using thermal control coating |
CN1474790A (en) * | 2000-09-20 | 2004-02-11 | Inorganic matrix compositions and composite material incorporating matrix composite material | |
US6921431B2 (en) * | 2003-09-09 | 2005-07-26 | Wessex Incorporated | Thermal protective coating for ceramic surfaces |
CN106661345A (en) * | 2014-07-07 | 2017-05-10 | 爱尔兰国立大学都柏林大学学院 | Thermal control coatings |
CN106675391A (en) * | 2015-11-11 | 2017-05-17 | 北京卫星环境工程研究所 | Anti-radiation thermal control coating and manufacturing method thereof |
CN108950549A (en) * | 2018-07-05 | 2018-12-07 | 哈尔滨工业大学 | A kind of preparation method of aluminum alloy surface low sunlight absorptivity high emissivity conduction thermal control coating |
CN110330822A (en) * | 2019-07-29 | 2019-10-15 | 四川瑞珂新材料科技有限公司 | A kind of inorganic coating and its preparation method and application |
-
2020
- 2020-03-24 CN CN202010212002.2A patent/CN111393882B/en active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5885658A (en) * | 1992-08-10 | 1999-03-23 | Mcdonnell Douglas Technologies, Inc. | Process for protecting optical properties of a thermal control |
US5310422A (en) * | 1992-12-01 | 1994-05-10 | General Electric Co. | High temperature inorganic paint |
US6176453B1 (en) * | 1997-03-18 | 2001-01-23 | Hughes Electronics Corporation | Radiator using thermal control coating |
CN1474790A (en) * | 2000-09-20 | 2004-02-11 | Inorganic matrix compositions and composite material incorporating matrix composite material | |
US6921431B2 (en) * | 2003-09-09 | 2005-07-26 | Wessex Incorporated | Thermal protective coating for ceramic surfaces |
CN106661345A (en) * | 2014-07-07 | 2017-05-10 | 爱尔兰国立大学都柏林大学学院 | Thermal control coatings |
CN106675391A (en) * | 2015-11-11 | 2017-05-17 | 北京卫星环境工程研究所 | Anti-radiation thermal control coating and manufacturing method thereof |
CN108950549A (en) * | 2018-07-05 | 2018-12-07 | 哈尔滨工业大学 | A kind of preparation method of aluminum alloy surface low sunlight absorptivity high emissivity conduction thermal control coating |
CN110330822A (en) * | 2019-07-29 | 2019-10-15 | 四川瑞珂新材料科技有限公司 | A kind of inorganic coating and its preparation method and application |
Non-Patent Citations (1)
Title |
---|
"航天器热控涂料";俞善庆;《涂料工业》;19870430(第2期);第51-54页 * |
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