CN1113882A - Preparing method for industrial ammonium phosphate and series compound fertilizer - Google Patents
Preparing method for industrial ammonium phosphate and series compound fertilizer Download PDFInfo
- Publication number
- CN1113882A CN1113882A CN 94111803 CN94111803A CN1113882A CN 1113882 A CN1113882 A CN 1113882A CN 94111803 CN94111803 CN 94111803 CN 94111803 A CN94111803 A CN 94111803A CN 1113882 A CN1113882 A CN 1113882A
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- Prior art keywords
- phosphorus
- ammonium
- mother liquor
- compound fertilizer
- fertilizer
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 39
- 239000004254 Ammonium phosphate Substances 0.000 title claims abstract description 15
- 229910000148 ammonium phosphate Inorganic materials 0.000 title claims abstract description 15
- 235000019289 ammonium phosphates Nutrition 0.000 title claims abstract description 15
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 150000001875 compounds Chemical class 0.000 title claims abstract description 11
- 239000012452 mother liquor Substances 0.000 claims abstract description 22
- 238000002425 crystallisation Methods 0.000 claims abstract description 18
- 238000001816 cooling Methods 0.000 claims abstract description 15
- 239000002002 slurry Substances 0.000 claims abstract description 12
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000000926 separation method Methods 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002367 phosphate rock Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 8
- 230000008025 crystallization Effects 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims description 9
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 8
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 8
- 230000002000 scavenging effect Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 6
- RSJLUKOWBCNLRU-UHFFFAOYSA-M N.P.[Cl-].Cl.Cl.Cl.Cl.Cl.Cl.[K+] Chemical compound N.P.[Cl-].Cl.Cl.Cl.Cl.Cl.Cl.[K+] RSJLUKOWBCNLRU-UHFFFAOYSA-M 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- 239000007790 solid phase Substances 0.000 claims description 4
- WBQUJKGRZFXXHA-UHFFFAOYSA-N [N].[K].[P].[Cl] Chemical compound [N].[K].[P].[Cl] WBQUJKGRZFXXHA-UHFFFAOYSA-N 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 2
- 238000001640 fractional crystallisation Methods 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 238000009955 starching Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 2
- 239000000460 chlorine Substances 0.000 abstract description 10
- 229910052801 chlorine Inorganic materials 0.000 abstract description 9
- 229910052700 potassium Inorganic materials 0.000 abstract description 8
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011574 phosphorus Substances 0.000 abstract description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011591 potassium Substances 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 150000003112 potassium compounds Chemical class 0.000 abstract 1
- 238000007613 slurry method Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000002386 leaching Methods 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 235000015097 nutrients Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
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Abstract
本发明公开了一种工业磷铵及系列复肥的制备 方法，其技术要点是：以“料浆法”生产的浓缩料浆作 原料，经水浸、分离、浓缩，冷却结晶得工业级磷铵产 品；分离后的母液加KCl，进行转化反应，冷却结晶 分离得一级无氯氮磷钾复肥；再将分离余下的母液加 入磷矿粉在一定工艺条件下分解反应，返料造粒获含 氯氮磷钾固体复肥。本发明以现有磷铵厂为基础，无 需增加过多投资，就可使其磷素大大增值，且整个工 艺过程无废物产生。
The invention discloses a method for preparing industrial ammonium phosphate and a series of compound fertilizers. The main technical points are: use the concentrated slurry produced by the "slurry method" as raw material, and undergo water immersion, separation, concentration, cooling and crystallization to obtain industrial-grade phosphorus Ammonium product; the separated mother liquor is added with KCl for conversion reaction, cooled and crystallized to obtain a first-grade chlorine-free nitrogen, phosphorus and potassium compound fertilizer; then the remaining mother liquor after separation is added to phosphate rock powder to decompose and react under certain process conditions, and then returned to granulate Obtain solid compound fertilizer containing chlorine, nitrogen, phosphorus and potassium. Based on the existing ammonium phosphate plant, the invention can greatly increase the value of phosphorus without increasing too much investment, and no waste is generated in the whole process.
Description
The invention belongs to phosphorus ammonium production technical field, is a kind of in the system with Wet-process Phosphoric Acid Production fertilizer grade ammonium phosphate, the method for coproduction industrial grade acid-ammonium and series compound fertilizer.
At present, adopt conventional " slurry process " technology, with phosphoric acid by wet process and the resulting ammonium phosphate of ammonia neutralization reaction, because it contains a large amount of impurity, can only be used as fertilizer usually, thereby make a low multiple use, economic benefit is also poor.In order to change this situation, the method (seeing CN 92108090.5) that prior art discloses a kind of " with phosphoric acid by wet process coproduction fertilizer grade and pure phosphoric acid-ammonium ".During this method is produced with " slurry process " and slip be raw material, adopt means such as separation, clear liquid concentrate, crystallisation by cooling to extract pure phosphoric acid-ammoniums, isolated slip and mother liquor return the raw material usefulness that original system is made the fertilizer grade ammonium phosphate after mixing in the process, and realize its goal of the invention with this.But, because the purification of raw materials that this method adopts is not enough, there is not additional control techniques again, so that the quality of product pure phosphoric acid-ammonium, promptly purity can not get guaranteeing completely; Secondly, make the raw material of fire-fighting with ABC powder extinguishing agent if use it for, its rate of moisture absorption index also is difficult for reaching requirement (promptly 20 ± 1 ℃, 78%, 24 hour rate of moisture absorption≤2% of relative humidity); Moreover, return separated the mother liquor behind the ammonium phosphate to original system, produce influence of fluctuations to system, suitably the adjusting process controlled variable could be eliminated, and this has brought operational trouble again.
Therefore, task of the present invention is to adopt " slurry process " to produce on the basis of fertilizer grade phosphorus ammonium system, do not changing its original Production Flow Chart, do not influencing under the prerequisite of its fertilizer grade phosphorus ammonium production, a kind of method for preparing industrial ammonium phosphate (being pure phosphoric acid-ammonium) and series compound fertilizer thereof is being provided.
Task of the present invention is finished by following technical proposals:
1. the enriching slurry of producing with " slurry process " is made raw material, starching: water=1: 0.3～1.5(weight ratio), 60～110 ℃ of temperature, agitation condition leached 10～40 minutes down, separate then, obtain the scavenging solution of phosphoric acid-ammonium and ammonium sulfate and contain the mud that does not dissolve body refuse.Contain the mud that does not dissolve body refuse and send the concentration section that returns fertilizer grade phosphorus ammonium production system.
2. the scavenging solution with phosphoric acid-ammonium and sulphur ammonium is concentrated into proportion 1.15～1.45(80 ℃ with conventional evaporating and concentrating process) after, crystallisation by cooling again.Technical grade phosphorus ammonium is washed and be drying to obtain to Crystallization Separation;
3. the mother liquor behind the fractional crystallization is with NH
3The proportioning of/K=0.8～4.0 (mol ratio) adds concentration and is 5～40% potassium chloride solution, and carries out conversion reaction 1～10 hour under 60～110 ℃ of temperature, and crystallisation by cooling separates then.The solid phase that obtains after the separation is that one-level does not have chlorine nitrogen phosphorus potassium and sprays multiple fertilizer, and remaining mother liquor is answered fertilizer owing to contain multiple nutrient based on ammonium chloride so can make liquid.
Become solid fertilizer in order to make to contain based on the multiple fertilizer of the liquid of ammonium chloride, so that transportation and fertilising operation, the present invention is off the beaten track, on technique scheme, increased a kind of special technology again, that is: with the remaining mother liquor in conversion reaction separation back, press mother liquor: the proportioning of ground phosphate rock=1: 0.05～1.0 (weight ratio), add ground phosphate rock and under 60～110 ℃ of temperature, carried out decomposition reaction 1～8 hour, use common process method returning charge granulating and drying then, can make the chloride Nitrogen-Phosphorus-Potassium compound fertilizer of solid.The advantage of this technology is fairly obvious, and it not only makes liquid fertilizer become solid with a kind of short-cut method, and has simplified the solid concentrating unit of conventional change, has avoided the etching problem of thickening equipment material, has also increased effective nutrient of phosphorus in the multiple fertilizer of former system.
In addition, with regard to the whole technical proposal that the present invention proposes, it also has the following advantages and positively effect:
1, because the raw material that the present invention uses is the slips after neutralization, concentrated two steps purify, add the further purification of water logging, the removal of impurity height, thereby can make high purity (〉=98%), pure phosphoric acid-the ammonium of low rate of moisture absorption (≤2%), and constant product quality, can do industry, the raw material that especially fire-fighting ABC powder extinguishing agent is used.
2, because the technology of the present invention route is reasonable, design ingeniously, not only noiseless, also increased the fertilizer new variety fertilizer grade phosphorus ammonium production system, and the generation of whole technological process no waste.
3, under the situation that does not increase too much investment, can obtain the high polynary multiple fertilizer of serial added value, wherein not only contain nitrogen, phosphorus, potassium, also contain nutrients such as sulphur, and the ratio of each component more is tending towards reasonable for plant-growth.
4, owing to less investment of the present invention, the technological process no waste generates, product (industrial ammonium phosphate and series compound fertilizer) added value height, and production does not have influence again to fertilizer grade phosphorus ammonium, thereby has remarkable economic efficiency and social benefit.
Accompanying drawing is the main device synoptic diagram of the used flow process of the present invention.
Provide embodiment below in conjunction with accompanying drawing
Embodiment one:
Present embodiment adopts flow path device shown in the drawings.
At first 2200g is contained P
2O
5About 24% enriching slurry is put into leaching groove 1, and again by slurry: water=1: the proportioning 0.7(weight ratio) adds water, and 95 ℃ are stirred leaching 20 minutes down.Then it is sent in the separating machine 2 and separate, obtain the scavenging solution of phosphoric acid-ammonium and ammonium sulfate and contain the mud that does not dissolve body refuse.Mud is sent the concentration section of fertilizer grade phosphorus ammonium production system back to.Scavenging solution is then sent into thickener 3, and with conventional evaporating and concentrating process it being concentrated into proportion is 1.34(80 ℃) after, send into again and carry out crystallisation by cooling in the crystallisation by cooling groove 4, at this moment ammonium phosphate is separated out crystallization gradually under cooling conditions.Material after the crystallization sent into again in the separating machine 5 separate, it is dry 6 that the suitable washing of isolated crystal is sent to again, promptly obtains the 200g industrial grade acid-ammonium.The main quality index of its product is: P
2O
560.20%, N11.87%(water content～1%), rate of moisture absorption 0.73%.
Mother liquor 840g behind the separation ammonium phosphate crystal sends into reactive tank 7, presses NH
3/ K=1.3(mol ratio) adding concentration is 16% the KCl aqueous solution, under 90 ℃, carry out conversion reaction 3 hours, send into then in crystallisation by cooling in the crystallisation by cooling groove 8, the separating machine 9 and separate, the solid phase drying 10 after the separation promptly makes finished product-one-level does not have chlorine Nitrogen-Phosphorus-Potassium compound fertilizer 250g.Group of products becomes: N4.38%, P
2O
522.80%, K
2O 32.55%, SO
321.95%, Cl
-1.61%(Cl
-Content≤2.5% is called no chlorine fertilizer).This product is owing to belong to no chlorine fertilizer, thereby can extensively be applied to fear-chlorion crop, as the tobacco in the cash crop, citrus etc.
Isolating mother liquor 1040g remaining behind the chlorine-free compound fertilizer enters mother liquor and awards groove 11(and form: P
2O
58.28%, K
2O 8.18%, N4.95%, SO
31.69%, Cl
-12.93%), can be directly multiple fertile as liquid, also can use with other solid fertilizer blending, can also further process according to method provided by the invention: be about to mother liquor and send into reactive tank 12, and press mother liquor: ground phosphate rock=1: the 0.12(weight ratio) add ground phosphate rock, under 80 ℃, carry out decomposition reaction 2 hours, use common process method returning charge granulating and drying 13 then, promptly make chloride Nitrogen-Phosphorus-Potassium compound fertilizer 640g.Its group of products becomes: effective P
2O
517.58%, N7.99%, K
2O 13.28%, SO
32.75%, Cl
-21.01%.
Embodiment two:
Present embodiment still adopts flow path device shown in the drawings.
1840g is contained P
2O
5About 26% enriching slurry is put into leaching groove 1, adds slurry again: water=1: the water 0.5(weight ratio), stir leaching 40 minutes down in 80 ℃, and send in the separating machine 2 and separate, obtain the scavenging solution of phosphoric acid-ammonium and ammonium sulfate and contain the mud that does not dissolve body refuse.The concentration section of mud foldback fertilizer grade phosphorus ammonium production system.Scavenging solution is then sent into thickener 3, is concentrated into proportion 1.27(80 ℃) after, send into again and carry out crystallisation by cooling in the crystallisation by cooling groove 4, separate in the separating machine 5.Drying 6 is delivered in the suitable washing of isolated crystal again, can obtain the 200g industrial grade acid-ammonium.The main quality index of product is: P
2O
559.93%, N 11.68%(water content～1%), rate of moisture absorption 1.24%.
Separate the mother liquor 1000g behind the ammonium phosphate crystal, sent into reactive tank 7, met NH
3/ K=3.0(mol ratio) adding concentration is 30% the KCl aqueous solution, under 75 ℃, carry out conversion reaction 4 hours, send into crystallisation by cooling in the crystallisation by cooling groove 8 then, separate in the separating machine 9, the solid phase drying after the separation promptly makes the free from chloride Nitrogen-Phosphorus-Potassium compound fertilizer 264g of one-level.Group of products becomes: N 7.87%, P
2O
534.63%, K
2O 21.69%, SO
320.17%, Cl
-2.24%.
Remaining mother liquor 624g enters mother liquor tank 11(composition: P after isolating chlorine-free compound fertilizer
2O
513.17%, K
2O 4.30%, and N 6.94%, SO
35.09%, Cl
-8.80%), can be directly multiple fertile as liquid, also can use and further to process according to method provided by the invention: be about to mother liquor and send into reactive tank 12 with other solid fertilizer blending, and press mother liquor: ground phosphate rock=1: the 0.3(weight ratio) add ground phosphate rock, under 100 ℃, carry out decomposition reaction 1.5 hours, send returning charge granulating and drying 13 then, promptly make chloride Nitrogen-Phosphorus-Potassium compound fertilizer 445g.Its group of products becomes: effective P
2O
525.26%, N 9.69%, K
2O 6.05%, SO
37.14%, Cl
-12.28%.
Claims (2)
1, the preparation method of a kind of industrial ammonium phosphate and series compound fertilizer is characterized in that:
1. the enriching slurry of producing with " slurry process " is made raw material, starching: water=1: 0.3～1.5 (weight ratio), 60～110 ℃ of temperature, agitation condition leached 10～40 minutes down, separate the scavenging solution that obtains phosphoric acid-ammonium and ammonium sulfate, with contain the mud that does not dissolve body refuse, the mud system's concentration section that reverts;
2. after scavenging solution being concentrated into proportion 1.15～1.45 with conventional evaporating and concentrating process, promptly crystallisation by cooling with the Crystallization Separation washing, and is drying to obtain technical grade phosphorus ammonium;
3. the mother liquor behind the fractional crystallization is with NH
3The proportioning of/K=0.8～4.0 (mol ratio), add concentration and be 5～40% potassium chloride solution, and carried out conversion reaction 1～7 hour under 60～110 ℃ of temperature, crystallisation by cooling separates, solid phase after the separation is that one-level does not have chlorine nitrogen phosphorus potassium and sprays multiple fertilizer, and it is multiple fertile that remaining mother liquor is made liquid.
2, the preparation method of industrial ammonium phosphate according to claim 1 and series compound fertilizer, it is characterized in that conversion reaction is separated the remaining mother liquor in back, press mother liquor: the proportioning of ground phosphate rock=1: 0.05～1.0 (weight ratio), add ground phosphate rock and under 60～110 ℃ of temperature, carried out decomposition reaction 1～8 hour, with common process method returning charge granulating and drying, make the chloride Nitrogen-Phosphorus-Potassium compound fertilizer of solid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94111803A CN1045576C (en) | 1994-06-18 | 1994-06-18 | Preparing method for industrial ammonium phosphate and series compound fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94111803A CN1045576C (en) | 1994-06-18 | 1994-06-18 | Preparing method for industrial ammonium phosphate and series compound fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1113882A true CN1113882A (en) | 1995-12-27 |
| CN1045576C CN1045576C (en) | 1999-10-13 |
Family
ID=5035635
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94111803A Expired - Fee Related CN1045576C (en) | 1994-06-18 | 1994-06-18 | Preparing method for industrial ammonium phosphate and series compound fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1045576C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103130205A (en) * | 2013-03-11 | 2013-06-05 | 马光明 | Method for producing industrial monoammonium phosphate and coproducing water-soluble ammonium sulfate phosphate |
| CN106518263A (en) * | 2016-11-08 | 2017-03-22 | 威海恒邦化工有限公司 | Method for producing high-concentration compound fertilizer by utilizing ammonium phosphate plant |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4610853A (en) * | 1985-03-08 | 1986-09-09 | Chisso Corporation | Process for producing purified monoammonium phosphate from wet process phosphoric acid |
| SU1542896A1 (en) * | 1987-12-15 | 1990-02-15 | Le T I Im Lensoveta | Method of producing monoammonium phosphate |
| CN1025021C (en) * | 1992-04-11 | 1994-06-15 | 四川省德阳市什邡化肥总厂 | Production method of industrial grade ammonium phosphate |
| CN1070901A (en) * | 1992-09-26 | 1993-04-14 | 简阳县农业生产资料公司 | A kind of production technique of potassium-ammonium phosphate |
-
1994
- 1994-06-18 CN CN94111803A patent/CN1045576C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103130205A (en) * | 2013-03-11 | 2013-06-05 | 马光明 | Method for producing industrial monoammonium phosphate and coproducing water-soluble ammonium sulfate phosphate |
| CN103130205B (en) * | 2013-03-11 | 2015-09-30 | 马光明 | The method of the water-soluble ammonium phosphate sulfate of a kind of manufacture level monoammonium phosphate co-production |
| CN106518263A (en) * | 2016-11-08 | 2017-03-22 | 威海恒邦化工有限公司 | Method for producing high-concentration compound fertilizer by utilizing ammonium phosphate plant |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1045576C (en) | 1999-10-13 |
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