CN111370605A - A kind of electrochemical device and preparation method thereof - Google Patents
A kind of electrochemical device and preparation method thereof Download PDFInfo
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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Abstract
本发明公开一种电化学器件及其制备方法,包括方形壳体,壳体内设有电芯,电芯两端分别连接电极组件,电极组件包括电极极柱,壳体的一端设有用于供电芯极柱从外到内进入的开口,另一端的端面中部设有开孔,端面的开孔端上注塑有透明绝缘密封垫,靠近壳体开口端的电极组件连接有端盖,端盖边缘与壳体开口端焊接封堵,靠近壳体开孔端的电极极柱从开孔处穿出,靠近壳体开孔端的电极极柱上注塑有绝缘密封圈,绝缘密封圈与透明绝缘密封垫相接触,且接触面相互粘结密封后通过激光穿透焊焊接。本发明入壳难度低,工艺简单,操作性强,有效提高生产效率、能量密度;将粘结与激光穿透焊两种工艺结合在一起,保证连接处的密封性,有效防止壳体内电解液溢出。
The invention discloses an electrochemical device and a preparation method thereof, comprising a square shell, an electric core is arranged in the shell, two ends of the electric core are respectively connected with an electrode assembly, the electrode assembly includes an electrode pole, and one end of the shell is provided with a power supply core The opening of the pole entering from the outside to the inside, the middle of the end face of the other end is provided with an opening, the opening end of the end face is injected with a transparent insulating gasket, the electrode assembly close to the open end of the shell is connected with an end cap, and the edge of the end cap is connected to the shell. The open end of the body is welded and sealed, the electrode pole close to the opening end of the shell is pierced from the opening, and the electrode pole close to the opening end of the shell is injected with an insulating sealing ring, and the insulating sealing ring is in contact with the transparent insulating gasket. And the contact surfaces are bonded and sealed with each other and welded by laser penetration welding. The invention has the advantages of low difficulty in entering the shell, simple process and strong operability, and can effectively improve the production efficiency and energy density; the two processes of bonding and laser penetration welding are combined together to ensure the sealing of the joint and effectively prevent the electrolyte in the shell. overflow.
Description
技术领域technical field
本发明属于电化学技术领域,具体涉及一种电化学器件及其制备方法。The invention belongs to the technical field of electrochemistry, and in particular relates to an electrochemical device and a preparation method thereof.
背景技术Background technique
方形铝壳锂电池早期主要用在小型数码电子用品上,随着技术的发展和领域的拓展,方形铝壳锂电池开始向摩托车、汽车、电动工具、电动车领域发展,特别是近期用作车用大功率充放电电源发展迅速,但传统的锂电池设计采用钢壳、铝塑膜或塑壳等设计,电芯极柱与壳盖先连接之后整体入壳,再将其与壳体焊接、封堵,这种入壳方式使得连接件易折断或可能与壳体接触短路,造成入壳难度大,且存在密封不严的问题。The square aluminum shell lithium battery was mainly used in small digital electronic products in the early days. With the development of technology and the expansion of the field, the square aluminum shell lithium battery began to develop into the fields of motorcycles, automobiles, power tools and electric vehicles, especially in the recent past. The high-power charging and discharging power supply for vehicles has developed rapidly, but the traditional lithium battery design adopts the design of steel shell, aluminum-plastic film or plastic shell. , Blocking, this way of entering the shell makes the connector easy to break or may be short-circuited with the shell, making it difficult to enter the shell, and there is a problem of poor sealing.
发明内容SUMMARY OF THE INVENTION
为解决上述问题,本发明提供一种电化学器件及其制备方法,使电芯入壳难度降低,连接件不易受损,密封严且强度大,增加电池的能量密度。In order to solve the above problems, the present invention provides an electrochemical device and a preparation method thereof, which can reduce the difficulty of inserting the battery into the shell, the connecting piece is not easily damaged, the sealing is tight and the strength is high, and the energy density of the battery is increased.
本发明的目的是以下述方式实现的:The purpose of this invention is to realize in the following way:
一种电化学器件,包括方形的壳体,壳体内设有电芯,电芯的两端分别连接电极组件,电极组件包括电极极柱,所述壳体的一端设有用于供电芯极柱从外到内进入的开口,另一端的端面中部设有开孔,端面的开孔端上注塑有透明绝缘密封垫,靠近壳体开口端的电极组件连接有端盖,端盖边缘与壳体开口端焊接封堵,靠近壳体开孔端的电极极柱从开孔处穿出,靠近壳体开孔端的电极极柱上注塑有绝缘密封圈,绝缘密封圈与透明绝缘密封垫相接触,且接触面相互粘结密封后通过激光穿透焊焊接。An electrochemical device includes a square shell, a battery core is arranged in the shell, two ends of the battery core are respectively connected to an electrode assembly, the electrode assembly includes an electrode pole, and one end of the shell is provided with a power supply core pole from The opening that enters from outside to inside has an opening in the middle of the end face of the other end. The open end of the end face is injected with a transparent insulating gasket. The electrode assembly near the open end of the casing is connected with an end cap, and the edge of the end cap is connected to the open end of the casing. Welding and sealing, the electrode pole near the opening end of the casing is pierced from the opening, and an insulating sealing ring is injected on the electrode pole near the opening end of the casing. The insulating sealing ring is in contact with the transparent insulating gasket, and the contact surface After being bonded and sealed to each other, they are welded by laser penetration welding.
所述透明绝缘密封垫为U型体,U型体的内侧面紧贴且包裹壳体开孔端端部,所述绝缘密封圈为平面状,透明绝缘密封垫的下表面与绝缘密封圈的上表面相接触。The transparent insulating gasket is a U-shaped body, the inner side of the U-shaped body is close to and wraps the end of the opening of the casing, the insulating sealing ring is flat, and the lower surface of the transparent insulating sealing gasket contact with the top surface.
所述靠近壳体开口端的电极组件包括极柱Ⅱ和绝缘密封圈Ⅱ,极柱Ⅱ从端盖Ⅰ中部穿出,极柱Ⅱ与端盖Ⅰ、绝缘密封圈Ⅱ连接在一起,绝缘密封圈Ⅱ也为U型。The electrode assembly close to the open end of the casing includes a pole II and an insulating sealing ring II, the pole II protrudes from the middle of the end cover I, the pole II is connected with the end cover I and the insulating sealing ring II, and the insulating sealing ring II is connected together. Also U-shaped.
所述透明绝缘密封垫为平面状且位于壳体外,所述绝缘密封圈为L型,L型的一边沿电极极柱向壳体开孔处延伸且位于壳体开孔端面与电极极柱之间,透明绝缘密封垫与绝缘密封圈相接触。The transparent insulating gasket is flat and is located outside the casing, the insulating sealing ring is L-shaped, and one side of the L-shaped extends along the electrode pole to the opening of the casing and is located between the end face of the opening of the casing and the electrode pole. In between, the transparent insulating gasket is in contact with the insulating sealing ring.
所述靠近壳体开口端的电极组件与靠近壳体开孔端的电极组件的结构相同,靠近壳体开口端的电极组件和端盖之间的连接方式与靠近壳体开孔端的电极组件和壳体开孔端面的连接方式相同。The structure of the electrode assembly close to the open end of the casing is the same as that of the electrode assembly close to the open end of the casing, and the connection between the electrode assembly close to the open end of the casing and the end cap is the same as that of the electrode assembly close to the open end of the casing The end faces of the holes are connected in the same way.
所述透明绝缘密封垫为透明塑料的绝缘密封垫。The transparent insulating gasket is a transparent plastic insulating gasket.
所述电芯的两端形成有正极全极耳和负极全极耳,正极全极耳和负极全极耳分别与电极组件焊接。Both ends of the battery core are formed with positive all-pole tabs and negative all-pole tabs, which are respectively welded to the electrode assembly.
所述的电化学器件的制备方法,包括以下步骤:The preparation method of the electrochemical device comprises the following steps:
(1)壳体的制备:采用冷拔精抽方法成型出壳体,壳体的开孔处注塑透明绝缘密封垫;(1) Preparation of the shell: the shell is formed by cold drawing and precise extraction, and a transparent insulating gasket is injected into the opening of the shell;
(2)端盖的制备:运用冲压方法成型出中部开孔的端盖Ⅰ;(2) Preparation of the end cap: use the stamping method to form the end cap I with the opening in the middle;
(3)电芯的制备:采用全极耳卷绕方式制取电芯,电芯上形成有正极全极耳和负极全极耳;(3) Preparation of battery core: The battery core is prepared by winding all-pole tabs, and positive all-pole tabs and negative all-pole tabs are formed on the battery core;
(4)电极组件的制备:将电极极柱Ⅰ、汇流片Ⅰ连接在一起,电极极柱Ⅰ上注塑有绝缘密封圈Ⅰ,绝缘密封圈Ⅰ外侧面涂覆有绝缘胶水,形成靠近壳体开孔端的电极组件Ⅰ;将极柱Ⅱ、汇流片Ⅱ连接在一起,端盖Ⅰ中部开孔处注塑有绝缘密封圈Ⅱ,极柱Ⅱ从端盖Ⅰ中部穿出,绝缘密封圈Ⅱ与极柱Ⅱ连接在一起,形成靠近壳体开口端的电极组件Ⅱ;(4) Preparation of electrode assembly: connect the electrode pole I and the busbar I together, the insulating sealing ring I is injection-molded on the electrode pole I, and the outer surface of the insulating sealing ring I is coated with insulating glue to form an opening close to the shell. The electrode assembly I at the end of the hole; the pole II and the busbar II are connected together, and an insulating sealing ring II is injected into the opening in the middle of the end cover I. The pole II passes through the middle of the end cover I, and the insulating sealing ring II and the pole II are connected together to form electrode assembly II near the open end of the shell;
(5)将电极组件与电芯连接:采用超声波焊接或超声波焊接后激光焊加强或电磁脉冲焊工艺将电极组件Ⅰ和电极组件Ⅱ分别固定连接到电芯上的全极耳,形成电芯极柱;(5) Connect the electrode assembly to the cell: Use ultrasonic welding or ultrasonic welding followed by laser welding enhancement or electromagnetic pulse welding to fix the electrode assembly I and the electrode assembly II to the all-pole lugs on the cell, respectively, to form a cell electrode column;
(6)组装入壳:电芯极柱从壳体开口端进入,电极组件Ⅰ朝上,电极组件Ⅱ朝下,使极柱Ⅰ从壳体的开孔处穿出,先采用激光焊或摩擦焊焊接工艺将电极组件Ⅱ上的端盖Ⅰ焊接、封堵固定于壳体的开口边缘,然后使绝缘密封圈Ⅰ与透明绝缘密封垫压紧粘结,接着采用激光穿透焊通过壳体开孔端与电极极柱之间的空隙部分,将透明绝缘密封垫与绝缘密封圈Ⅰ焊接、密封,组装入壳完成;从壳体端部注入电解液,将注入口焊接密封,从而制成锂电池。(6) Assembling into the shell: the pole of the battery core enters from the open end of the shell, the electrode assembly I faces up, and the electrode assembly II faces downward, so that the pole I penetrates through the opening of the shell, first use laser welding or friction The welding process welds, seals and fixes the end cap I on the electrode assembly II to the opening edge of the shell, then presses and bonds the insulating sealing ring I and the transparent insulating gasket, and then uses laser penetration welding to open the shell through the shell. In the gap part between the hole end and the electrode pole, the transparent insulating gasket and the insulating sealing ring I are welded and sealed, and the assembly is completed into the shell; the electrolyte is injected from the end of the shell, and the injection port is welded and sealed to make lithium Battery.
所述的电化学器件的制备方法,包括以下步骤:The preparation method of the electrochemical device comprises the following steps:
(1)壳体的制备:采用冷拔精抽方法成型出壳体,壳体开孔处注塑透明绝缘密封垫;(1) Preparation of the shell: The shell is formed by cold drawing and precise extraction, and a transparent insulating gasket is injected at the opening of the shell;
(2)端盖的制备:运用冲压方法成型出中部开孔的端盖Ⅱ,端盖Ⅱ中部开孔处的外侧注塑有透明绝缘密封垫;(2) Preparation of end cap: use stamping method to form end cap II with an opening in the middle, and a transparent insulating gasket is injected on the outside of the opening in the middle of end cap II;
(3)电芯的制备:采用全极耳卷绕方式制取电芯,电芯上形成有正极全极耳和负极全极耳;(3) Preparation of battery core: The battery core is prepared by winding all-pole tabs, and positive all-pole tabs and negative all-pole tabs are formed on the battery core;
(4)电极组件的制备:将极柱Ⅲ、汇流片Ⅲ连接在一起,极柱Ⅲ上注塑有绝缘密封圈Ⅲ,绝缘密封圈Ⅲ外侧面涂覆有绝缘胶水,形成靠近壳体开孔端的电极组件Ⅲ;将极柱Ⅳ、汇流片Ⅳ连接在一起,极柱Ⅳ上注塑绝缘密封圈Ⅳ,绝缘密封圈Ⅳ的外侧面涂覆有绝缘胶水,极柱Ⅳ从端盖Ⅱ中部穿出,绝缘密封圈Ⅳ与透明绝缘密封垫压紧粘结在一起,形成靠近壳体开口端的电极组件Ⅳ;(4) Preparation of the electrode assembly: connect the pole III and the busbar III together, the pole III is injected with an insulating sealing ring III, and the outer surface of the insulating sealing ring III is coated with insulating glue to form a surface close to the opening end of the shell. Electrode assembly III; connect the pole IV and the busbar IV together, the insulating sealing ring IV is injected on the pole IV, the outer side of the insulating sealing ring IV is coated with insulating glue, and the pole IV passes through the middle of the end cover II, The insulating sealing ring IV and the transparent insulating sealing gasket are pressed and bonded together to form the electrode assembly IV close to the open end of the shell;
(5)将电极组件与电芯连接:采用超声波焊接或超声波焊接后激光焊加强或电磁脉冲焊工艺将电极组件Ⅲ和电极组件Ⅳ分别固定连接到电芯上的全极耳,形成电芯极柱;(5) Connect the electrode assembly to the cell: Use ultrasonic welding or ultrasonic welding followed by laser welding enhancement or electromagnetic pulse welding to fix and connect the electrode assembly III and electrode assembly IV to the all-pole lugs on the cell to form a cell electrode. column;
(6)组装入壳:电芯极柱从壳体开口端进入,电极组件Ⅲ朝上,电极组件Ⅳ朝下,使极柱Ⅲ从壳体的开孔处穿出,先采用激光焊或摩擦焊焊接工艺将电极组件Ⅳ上连接的端盖Ⅱ焊接、封堵固定于壳体的开口边缘,然后使绝缘密封圈Ⅲ与透明绝缘密封垫压紧粘结,接着采用激光穿透焊将透明绝缘密封垫与绝缘密封圈Ⅲ焊接、密封,再采用激光穿透焊将绝缘密封圈Ⅳ与透明绝缘密封垫焊接、密封,组装入壳完成;从壳体端部注入电解液,将注入口焊接密封,从而制成锂电池。(6) Assembling into the shell: the pole of the battery core enters from the open end of the shell, the electrode assembly III faces up, and the electrode assembly IV faces downward, so that the pole III passes through the opening of the shell, first use laser welding or friction The welding process welds, seals and fixes the end cap II connected to the electrode assembly IV on the opening edge of the shell, then presses and bonds the insulating sealing ring III and the transparent insulating gasket, and then uses laser penetration welding to seal the transparent insulating The sealing gasket is welded and sealed with the insulating sealing ring III, and then the insulating sealing ring IV and the transparent insulating sealing gasket are welded and sealed by laser penetration welding, and the assembly is completed into the shell; the electrolyte is injected from the end of the shell, and the injection port is welded and sealed , thus making a lithium battery.
所述壳体和端盖均为铝材或铝镁合金。The shell and the end cover are made of aluminum material or aluminum-magnesium alloy.
相对于现有技术,本发明的优点如下:Compared with the prior art, the advantages of the present invention are as follows:
1.将焊接好的电极极柱穿过留有开孔的壳体,使极柱上的绝缘密封圈与壳体开孔处的透明绝缘密封垫压紧密封,入壳难度低,工艺简单,操作性强,有效提高生产效率,适合规模化生产,减小了预留的装配空间,提高了电池的空间利用率,进而提高了能量密度。1. Pass the welded electrode pole through the shell with openings, so that the insulating sealing ring on the pole and the transparent insulating gasket at the opening of the shell are pressed and sealed, the difficulty of entering the shell is low, and the process is simple. It has strong operability, effectively improves production efficiency, is suitable for large-scale production, reduces the reserved assembly space, improves the space utilization rate of the battery, and thus improves the energy density.
2.用绝缘胶水将绝缘密封圈和透明绝缘密封垫粘接之后,再用激光穿透焊将绝缘密封圈和透明绝缘密封垫焊接,两种工艺结合在一起,保证连接处的密封性,有效防止壳体内电解液溢出;2. After the insulating sealing ring and the transparent insulating sealing gasket are bonded with insulating glue, the insulating sealing ring and the transparent insulating sealing gasket are welded by laser penetration welding. The two processes are combined to ensure the sealing of the joint, which is effective Prevent the electrolyte from overflowing in the shell;
3.用激光穿透焊将绝缘密封圈和透明绝缘密封垫焊接密封,可实现精准密封,保证在壳体开孔端与电极极柱之间极细的间隔内将其密封,对连接件不产生影响。3. The insulating sealing ring and the transparent insulating sealing gasket are welded and sealed by laser penetration welding, which can achieve precise sealing and ensure that it is sealed within a very fine interval between the opening end of the shell and the electrode pole, and does not affect the connection parts. make an impact.
附图说明Description of drawings
图1是本发明的结构示意图。Figure 1 is a schematic structural diagram of the present invention.
图2是实施例1的图1的A-A剖视图。FIG. 2 is a cross-sectional view taken along line A-A of FIG. 1 in Example 1. FIG.
图3是图2的部分放大图。FIG. 3 is a partially enlarged view of FIG. 2 .
图4是实施例2的图1的A-A剖视图。4 is a cross-sectional view taken along line A-A of FIG. 1 of Example 2. FIG.
图5是图4的部分放大图。FIG. 5 is a partially enlarged view of FIG. 4 .
其中,1是壳体;2是电极组件Ⅰ,21是极柱Ⅰ,22是汇流片Ⅰ,23是绝缘密封圈Ⅰ;3是电芯;4是电极组件Ⅱ,41是极柱Ⅱ,42是汇流片Ⅱ,43是端盖Ⅰ,44是绝缘密封圈Ⅱ;5是透明绝缘密封垫Ⅰ;6是端盖Ⅱ;7是电极组件Ⅲ,71是绝缘密封圈Ⅲ,72是透明绝缘密封垫Ⅱ;8是电极组件Ⅳ,81是绝缘密封圈Ⅳ,82是透明绝缘密封垫Ⅲ。Among them, 1 is the shell; 2 is the electrode assembly I, 21 is the pole I, 22 is the busbar I, 23 is the insulating sealing ring I; 3 is the battery core; 4 is the electrode assembly II, 41 is the pole II, 42 is the busbar II, 43 is the end cap I, 44 is the insulating sealing ring II; 5 is the transparent insulating gasket I; 6 is the end cap II; 7 is the electrode assembly III, 71 is the insulating sealing ring III, 72 is the transparent insulating seal Gasket II; 8 is electrode assembly IV, 81 is insulating sealing ring IV, 82 is transparent insulating sealing gasket III.
具体实施方式Detailed ways
实施例1Example 1
如图1、图2、图3所示,一种电化学器件,包括方形的壳体1,壳体1内设有电芯3,电芯3的两端分别连接电极组件,电极组件包括电极极柱,所述壳体1的一端设有用于供电芯极柱从外到内进入的开口,即图2中壳体1的下端,另一端的端面中部设有开孔,即图2中壳体1的上端,端面的开孔端上注塑有透明绝缘密封垫Ⅰ5,靠近壳体1开口端的电极组件连接有端盖Ⅰ43,端盖Ⅰ43边缘与壳体1开口端焊接封堵,靠近壳体开孔端的电极极柱从开孔处穿出,靠近壳体开孔端的电极极柱上注塑有绝缘密封圈Ⅰ23,绝缘密封圈Ⅰ23与透明绝缘密封垫Ⅰ5相接触,且接触面粘结密封,透明绝缘密封垫Ⅰ5的位于壳体1开孔端与电极极柱之间的部分与绝缘密封圈Ⅰ23通过激光穿透焊焊接。As shown in Fig. 1, Fig. 2, Fig. 3, an electrochemical device includes a
上述电极组件分为电极组件Ⅰ2和电极组件Ⅱ4,其中一个为正极,一个为负极,电极组件Ⅰ2由极柱Ⅰ21、汇流片Ⅰ22和绝缘密封圈Ⅰ23组成,极柱Ⅰ21、汇流片Ⅰ22和绝缘密封圈Ⅰ23事先连接或注塑好,电极组件Ⅱ4由极柱Ⅱ41、汇流片Ⅱ42和绝缘密封圈Ⅱ44组成,极柱Ⅱ41、汇流片Ⅱ42、端盖Ⅰ43和绝缘密封圈Ⅱ44事先连接或注塑好,为现有技术。本发明的铝壳可以为纯铝的,也可以是铝镁合金的。The above electrode assembly is divided into electrode assembly I2 and electrode assembly II4, one of which is a positive electrode and the other is a negative electrode. The electrode assembly I2 is composed of a pole I21, a busbar I22 and an insulating seal ring I23. The pole I21, the busbar I22 and the insulating seal Ring I23 is pre-connected or injection-molded. Electrode assembly II4 is composed of pole II41, busbar II42 and insulating seal ring II44. Pole II41, busbar II42, end cap I43 and insulating seal ring II44 are pre-connected or injection-molded. There is technology. The aluminum shell of the present invention can be pure aluminum or aluminum-magnesium alloy.
优选地,所述透明绝缘密封垫Ⅰ5为U型体,U型体的内侧面紧贴且包裹壳体1开孔端端部,如图3所示,所述绝缘密封圈Ⅰ23为平面状,透明绝缘密封垫Ⅰ5的下表面与绝缘密封圈Ⅰ23的上表面相接触。Preferably, the transparent insulating sealing gasket I5 is a U-shaped body, and the inner side of the U-shaped body is in close contact with and wraps the end of the opening of the
所述靠近壳体1开口端的电极组件Ⅱ4包括极柱Ⅱ41和绝缘密封圈Ⅱ44,极柱Ⅱ41从端盖Ⅰ43中部穿出,极柱Ⅱ41与端盖Ⅰ43、绝缘密封圈Ⅱ44连接在一起,绝缘密封圈Ⅱ44也为U型。The electrode assembly II4 near the open end of the
优选地,所述透明绝缘密封垫Ⅰ5为透明塑料的绝缘密封垫,当然也可以是其他透明的能与橡胶粘合的材料。Preferably, the transparent insulating gasket I5 is a transparent plastic insulating gasket, of course, it can also be other transparent materials that can be bonded to rubber.
进一步地,所述电芯3的两端形成有正极全极耳和负极全极耳,正极全极耳和负极全极耳分别与电极组件Ⅰ2、电极组件Ⅱ4焊接。Further, both ends of the
本发明电化学器件的制备方法如下:The preparation method of the electrochemical device of the present invention is as follows:
(1)壳体1的制备:以铝材或铝镁合金为原材料,采用冷拔精抽方法成型出壳体1,壳体1开孔处注塑透明绝缘密封垫,即透明绝缘密封垫Ⅰ5;(1) Preparation of shell 1: Using aluminum material or aluminum-magnesium alloy as raw material, the
(2)端盖的制备:以铝材或铝镁合金为原材料,运用冲压方法成型出中部开孔的端盖Ⅰ43;(2) Preparation of end caps: Use aluminum or aluminum-magnesium alloy as raw materials, and use stamping method to form end caps I43 with holes in the middle;
(3)电芯3的制备:采用全极耳卷绕方式制取电芯3,电芯3上形成有正极全极耳和负极全极耳;(3) Preparation of battery core 3: The
(4)电极组件的制备:将极柱Ⅰ21、汇流片Ⅰ22连接在一起,极柱Ⅰ21上注塑有绝缘密封圈Ⅰ23,绝缘密封圈Ⅰ23外侧面涂覆有绝缘胶水,形成靠近壳体1开孔端的电极组件Ⅰ2;将极柱Ⅱ41、汇流片Ⅱ42连接在一起,端盖Ⅰ43中部开孔处注塑有绝缘密封圈Ⅱ44,极柱Ⅱ41从端盖Ⅰ43中部穿出,绝缘密封圈Ⅱ44与极柱Ⅱ41连接在一起,形成靠近壳体1开口端的电极组件Ⅱ4;(4) Preparation of electrode assembly: connect the pole I21 and the busbar I22 together, the pole I21 is injected with an insulating sealing ring I23, and the outer side of the insulating sealing ring I23 is coated with insulating glue to form an opening close to the
(5)将电极组件与电芯3连接:采用超声波焊接或超声波焊接后激光焊加强或电磁脉冲焊工艺将电极组件Ⅰ2和电极组件Ⅱ4分别固定连接到电芯3上的全极耳,形成电芯极柱;(5) Connect the electrode assembly to the cell 3: Use ultrasonic welding or ultrasonic welding followed by laser welding enhancement or electromagnetic pulse welding to fix the electrode assembly I2 and the electrode assembly II4 to the all-pole lugs on the
(6)组装入壳:电芯极柱从壳体1开口端进入,电极组件Ⅰ2朝上,电极组件Ⅱ4朝下,使极柱Ⅰ21从壳体1的开孔处穿出,先采用激光焊或摩擦焊焊接工艺将电极组件Ⅱ4上的端盖Ⅰ43焊接、封堵固定于壳体1的开口边缘,然后使绝缘密封圈Ⅰ23与透明绝缘密封垫Ⅰ5压紧粘结,接着采用激光穿透焊通过壳体1开孔端与电极极柱之间的空隙部分,将透明绝缘密封垫Ⅰ5与绝缘密封圈Ⅰ23焊接、密封,组装入壳完成;从壳体1端部注入电解液,将注入口焊接密封,从而制成锂电池。此处注入口设置在端盖Ⅰ43上,为现有技术,在此不再赘述。(6) Assemble into the shell: the pole of the battery core enters from the open end of the
实施例2Example 2
如图1、图4、图5所示,一种电化学器件,包括方形的壳体1,壳体1内设有电芯3,电芯3的两端分别连接电极组件,电极组件包括电极极柱,所述壳体1的一端设有用于供电芯极柱从外到内进入的开口,即图4中壳体1的下端,另一端的端面中部设有开孔,即图4中壳体1的上端,端面的开孔端上注塑有透明绝缘密封垫Ⅱ72,靠近壳体1开口端的电极组件连接有端盖Ⅱ6,端盖Ⅱ6边缘与壳体1开口端焊接封堵,靠近壳体1开孔端的电极极柱从开孔处穿出,靠近壳体1开孔端的电极极柱上注塑有绝缘密封圈Ⅲ71,绝缘密封圈Ⅲ71与透明绝缘密封垫Ⅱ72相接触,且接触面粘结密封,透明绝缘密封垫Ⅱ72的位于壳体1开孔端与电极极柱之间的正上方部分与绝缘密封圈Ⅲ71通过激光穿透焊焊接。As shown in Fig. 1, Fig. 4, Fig. 5, an electrochemical device includes a
上述电极组件分为电极组件Ⅲ7和电极组件Ⅳ8,其中一个为正极,一个为负极,电极组件Ⅲ7由极柱Ⅲ(图中未标出)、汇流片Ⅲ(图中未标出)和绝缘密封圈Ⅲ71组成,极柱Ⅲ、汇流片Ⅲ和绝缘密封圈Ⅲ71事先连接或注塑好;电极组件Ⅳ8由极柱Ⅳ(图中未标出)、汇流片Ⅳ(图中未标出)和绝缘密封圈Ⅳ81组成,极柱Ⅳ、汇流片Ⅳ和绝缘密封圈Ⅳ81事先连接或注塑好,为现有技术。本发明的铝壳可以为纯铝的,也可以是铝镁合金的。The above-mentioned electrode assembly is divided into electrode assembly III7 and electrode assembly IV8, one of which is a positive electrode and the other is a negative electrode. The electrode assembly IV8 is composed of the pole IV (not marked in the figure), the busbar IV (not marked in the figure) and the insulating seal It is composed of a ring IV81, and the pole IV, the busbar IV and the insulating sealing ring IV81 are connected or injection molded in advance, which is the prior art. The aluminum shell of the present invention can be pure aluminum or aluminum-magnesium alloy.
优选地,所述透明绝缘密封垫Ⅱ72和透明绝缘密封垫Ⅲ82均为透明塑料的绝缘密封垫,当然也可以是其他透明的能与橡胶粘合的材料。Preferably, the transparent insulating gasket II72 and the transparent insulating gasket III82 are both transparent plastic insulating gaskets, but of course they can also be other transparent materials that can be bonded to rubber.
进一步地,所述透明绝缘密封垫Ⅱ72和透明绝缘密封垫Ⅲ82均为平面状且位于壳体1外,所述绝缘密封圈Ⅳ81与绝缘密封圈Ⅲ71均为L型,L型的一边沿电极极柱Ⅳ向壳体1开孔处延伸且位于壳体1开孔端面与电极极柱Ⅳ之间,透明绝缘密封垫Ⅱ72和透明绝缘密封垫Ⅲ82分别与绝缘密封圈Ⅲ71、绝缘密封圈Ⅳ81相接触。Further, the transparent insulating sealing gasket II72 and the transparent insulating sealing gasket III82 are both planar and located outside the
所述靠近壳体1开口端的电极组件Ⅳ8与靠近壳体1开孔端的电极组件Ⅲ7的结构相同,靠近壳体1开口端的电极组件Ⅳ8和端盖Ⅱ6之间的连接方式与靠近壳体1开孔端的电极组件Ⅲ7和壳体1开孔端面的连接方式相同,即端盖Ⅱ6上事先注塑有透明绝缘密封垫Ⅲ82,上述极柱Ⅳ、汇流片Ⅳ、绝缘密封圈Ⅳ81连接好后,再将绝缘密封圈Ⅳ81与透明绝缘密封垫Ⅲ82粘结后通过激光穿透焊焊接在一起。The electrode assembly IV8 close to the open end of the
进一步地,所述电芯3的两端形成有正极全极耳和负极全极耳,正极全极耳和负极全极耳分别与电极组件Ⅳ8、电极组件Ⅲ7焊接。Further, both ends of the
本发明电化学器件的制备方法如下:The preparation method of the electrochemical device of the present invention is as follows:
(1)壳体1的制备:以铝材或铝镁合金为原材料,采用冷拔精抽方法成型出壳体1,壳体1开孔处注塑透明绝缘密封垫,即透明绝缘密封垫Ⅱ72;(1) Preparation of shell 1: Using aluminum material or aluminum-magnesium alloy as raw material, the
(2)端盖的制备:以铝材或铝镁合金为原材料,运用冲压方法成型出中部开孔的端盖Ⅱ6,端盖Ⅱ6中部开孔处的外侧注塑有透明绝缘密封垫Ⅲ82;(2) Preparation of end cover: Using aluminum or aluminum-magnesium alloy as raw material, the end cover II6 with the middle opening is formed by stamping method, and the outer side of the opening in the middle of the end cover II6 is injected with a transparent insulating gasket III82;
(3)电芯3的制备:采用全极耳卷绕方式制取电芯3,电芯3上形成有正极全极耳和负极全极耳;(3) Preparation of battery core 3: The
(4)电极组件的制备:将极柱Ⅲ、汇流片Ⅲ连接在一起,极柱Ⅲ上注塑有绝缘密封圈Ⅲ71,绝缘密封圈Ⅲ71外侧面涂覆有绝缘胶水,形成电极组件Ⅲ7;将极柱Ⅳ、汇流片Ⅳ连接在一起,极柱Ⅳ上注塑绝缘密封圈Ⅳ81,绝缘密封圈Ⅳ81的外侧面涂覆有绝缘胶水,极柱Ⅳ从端盖Ⅱ6中部穿出,绝缘密封圈Ⅳ81与透明绝缘密封垫Ⅲ82压紧粘结在一起,形成电极组件Ⅳ8;(4) Preparation of the electrode assembly: connect the pole III and the busbar III together, the pole III is injected with an insulating sealing ring III71, and the outer surface of the insulating sealing ring III71 is coated with insulating glue to form the electrode assembly III7; Column Ⅳ and busbar Ⅳ are connected together, and the insulating sealing ring Ⅳ81 is injected on the pole Ⅳ. The outer side of the insulating sealing ring Ⅳ81 is coated with insulating glue. The pole Ⅳ passes through the middle of the end cap Ⅱ6. The insulating gasket III82 is pressed and bonded together to form the electrode assembly IV8;
(5)将电极组件与电芯3连接:采用超声波焊接或超声波焊接后激光焊加强或电磁脉冲焊工艺将电极组件Ⅲ7和电极组件Ⅳ8分别固定连接到电芯3上的全极耳,形成电芯极柱;(5) Connect the electrode assembly to the battery core 3: Use ultrasonic welding or ultrasonic welding followed by laser welding enhancement or electromagnetic pulse welding to fix the electrode assembly III7 and electrode assembly IV8 to the all-pole lugs on the
(6)组装入壳:电芯极柱从壳体1开口端进入,电极组件Ⅲ7朝上,电极组件Ⅳ8朝下,使极柱Ⅲ从壳体1的开孔处穿出,先采用激光焊或摩擦焊焊接工艺将电极组件Ⅳ8上连接的端盖Ⅱ6焊接、封堵固定于壳体1的开口边缘,然后使绝缘密封圈Ⅲ71与透明绝缘密封垫Ⅱ72压紧粘结,接着采用激光穿透焊将透明绝缘密封垫Ⅱ72与绝缘密封圈Ⅲ71焊接、密封,再采用激光穿透焊将绝缘密封圈Ⅳ81与透明绝缘密封垫Ⅲ82焊接、密封,组装入壳完成;从壳体1端部注入电解液,将注入口焊接密封,从而制成锂电池。此处注入口设置在端盖Ⅱ6上,为现有技术,在此不再赘述。(6) Assembling into the shell: the pole of the battery core enters from the open end of the
以上所述的仅是本发明的优选实施方式,应当指出,对于本领域的技术人员来说,在不脱离本发明整体构思前提下,还可以作出若干改变和改进,这些也应该视为本发明的保护范围,这些都不会影响本发明实施的效果和专利的实用性。The above are only the preferred embodiments of the present invention. It should be pointed out that for those skilled in the art, some changes and improvements can be made without departing from the overall concept of the present invention, and these should also be regarded as the present invention. the scope of protection, these will not affect the effect of the implementation of the present invention and the practicability of the patent.
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