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CN111364244A - Antibacterial shirt - Google Patents

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Publication number
CN111364244A
CN111364244A CN202010137744.3A CN202010137744A CN111364244A CN 111364244 A CN111364244 A CN 111364244A CN 202010137744 A CN202010137744 A CN 202010137744A CN 111364244 A CN111364244 A CN 111364244A
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Prior art keywords
antibacterial
shirt
parts
weight
fabric
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Chinese (zh)
Inventor
王桉
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Wuxi Xinyouda Garment Technology Co ltd
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Wuxi Xinyouda Garment Technology Co ltd
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Priority to CN202010137744.3A priority Critical patent/CN111364244A/en
Publication of CN111364244A publication Critical patent/CN111364244A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/335Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/352Heterocyclic compounds having five-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15Proteins or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/04Linen
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/06Jute
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Manufacturing & Machinery (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses an antibacterial shirt, wherein shirt fabric is formed by blending and weaving the following fibers in parts by weight: 40-45 parts of cotton fibers; 5-8 parts of polyester fiber; 10-15 parts of flax fiber; 2-4 parts of jute fiber. According to the antibacterial shirt, the cotton fibers, the polyester fibers, the flax fibers, the jute fibers and the Modal fibers are blended and woven into the fabric, the antibacterial treatment liquid is compatible, and the components of the antibacterial treatment liquid have a synergistic effect, so that the prepared fabric has antibacterial performance and wearing comfort is improved.

Description

Antibacterial shirt
Technical Field
The invention relates to the technical field of clothes, in particular to an antibacterial shirt.
Background
With the development of the second industry, white collar class is increased, and western style clothes which are standard styles of gentleman and business people are also determined. Shirts are gradually pushed around white in combination with western-style clothes and ties, and the material is also developed from cotton into chemical fibers. As is well known, the garment materials have a large number of fiber gaps and micropores (Wuhui Ying 2006) due to the cross superposition of fibers, so that a good microenvironment is provided for the breeding of microorganisms, and meanwhile, the fiber gaps also absorb a large number of human body surface secretions to become an ideal nutrient source for the microorganisms. It is important to provide clothes with an antibacterial function to prevent the above-mentioned situations, and the existing shirt fabric has poor antibacterial performance.
Disclosure of Invention
The invention provides an antibacterial shirt, aiming at the problem that the existing shirt is poor in antibacterial performance.
In order to solve the technical problems, the invention adopts the technical scheme that:
an antibacterial shirt, wherein: the shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000011
preferably, the antibacterial shirt further comprises 0.5-2 parts by weight of Modal fibers.
Preferably, the antibacterial shirt comprises 2-4 wt% of ceramic powder, 0.5-1 wt% of coupling agent and 3-5 wt% of bacteriostatic agent.
Preferably, the antibacterial shirt comprises, by weight, 1-3 parts of titanium dioxide and 0.4-0.8 part of yttrium oxide.
Preferably, the antibacterial shirt is characterized in that the coupling agent is bis-1, 2- (trimethoxysilyl) ethane.
Preferably, the antibacterial shirt comprises, by weight, 2-4 parts of zinc oxide, 1-3 parts of guanidine stearate, 0.5-2 parts of methacryloyloxy-benzyl-dimethyl ammonium chloride and 0.5-2 parts of methacryloyl chloride-benzisothiazolinone.
Preferably, the antibacterial shirt is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average grain diameter of 80-100 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
Preferably, the antibacterial shirt is obtained by padding the blended and woven fabric with an antibacterial treatment fluid; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000021
Figure BDA0002397737120000031
preferably, the antibacterial shirt comprises the following specific operations: and applying the antibacterial treatment liquid to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment liquid, drying the gray fabric padded with the antibacterial treatment liquid, and baking to obtain the shirt fabric.
Preferably, the antibacterial shirt is characterized in that the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 3-5; the padding mode is one-padding-one-dipping.
Has the advantages that:
according to the antibacterial shirt, the cotton fibers, the polyester fibers, the flax fibers, the jute fibers and the Modal fibers are blended and woven into the fabric, the antibacterial treatment liquid is compatible, and the components of the antibacterial treatment liquid have a synergistic effect, so that the prepared fabric has antibacterial performance and wearing comfort is improved.
Detailed Description
The following examples further illustrate embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
The invention provides an antibacterial shirt, wherein: the shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000032
Figure BDA0002397737120000041
the cotton fiber is a porous substance, and cellulose macromolecules of the cotton fiber have a plurality of hydrophilic groups (-OH), so the cotton fiber has better hygroscopicity, and the moisture regain of the cotton fiber can reach about 8.5 percent under the common atmospheric condition; since the main constituent material of cotton fiber is cellulose, it is more alkali-resistant and not acid-resistant; caustic soda can cause cotton fibers to swell violently, increase in diameter, and shorten in length, so as to cause strong shrinkage of cotton products. At this time, if tension is applied to limit the shrinkage, the surface of the cotton product becomes flat and bright and the dyeing performance is greatly improved, and the processing is called mercerization; if the tension is not added, the shrinkage is called alkali shrinkage. The knitted fabric becomes compact and elastic after alkali shrinkage, and has good shape retention. The acid can deteriorate the strength of cotton fibers, particularly strong acid and concentrated acid are contraindicated, the acid can be dissolved in concentrated sulfuric acid with the concentration of more than 70 percent, and the concentrated hydrochloric acid and the concentrated nitric acid also have serious influence on the strength of the cotton fibers; the polyester fiber has good crease resistance and shape retention, high strength and elastic recovery capability, firmness and durability, crease resistance and non-ironing; the flax fiber improves the anti-allergic, anti-static and antibacterial properties of the shirt; the jute fiber improves the gloss performance and the moisture absorption performance of the fabric;
preferably, the antibacterial shirt further comprises 0.5-2 parts by weight of Modal fibers. The Modal fiber has the moisture absorption capacity, wrinkle resistance, easy-care property and softness.
As another embodiment of the present invention, the polyester fiber comprises 2 to 4 wt% of ceramic powder, 0.5 to 1 wt% of coupling agent, and 3 to 5 wt% of bacteriostatic agent.
In another embodiment, the ceramic powder includes, by weight, 1 to 3 parts of titanium dioxide and 0.4 to 0.8 part of yttrium oxide. The titanium dioxide and the yttrium oxide improve the wear resistance of the fabric.
In yet another embodiment, the coupling agent is bis-1, 2- (trimethoxysilyl) ethane.
In another embodiment of the present disclosure, the bacteriostatic agent includes, by weight, 2 to 4 parts of zinc oxide, 1 to 3 parts of guanidine stearate, 0.5 to 2 parts of methacryloxy-benzyl-dimethylammonium chloride, and 0.5 to 2 parts of methacryloyl chloride-benzisothiazolinone. The zinc oxide, guanidine stearate, methacryloxy-benzyl-dimethyl ammonium chloride and methacryloyl chloride-benzisothiazolinone are synergistically used as the antibacterial agent to synergistically improve the antibacterial performance of the fabric.
As another embodiment of the present disclosure, the polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average grain diameter of 80-100 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
As another embodiment of the scheme, the blended and woven fabric is further padded with an antibacterial treatment fluid to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000051
the chitin, the 2, 4-thiazolidinedione and the shrimp shell powder can interact with groups or elements in organisms to destroy normal substance and energy metabolism of the organisms, have a killing or inhibiting effect on microorganisms (including bacteria, fungi, viruses and the like) and have certain biological activity, and the N-phenyl- α -naphthylamine can improve the washing fastness of the fabric, so that the long-term property of the antibacterial property of the fabric is improved.
As another embodiment of the present disclosure, the padding specifically operates as follows: and applying the antibacterial treatment liquid to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment liquid, drying the gray fabric padded with the antibacterial treatment liquid, and baking to obtain the shirt fabric.
As another embodiment of the scheme, the mass ratio of the blended and woven fabric to the antibacterial treatment solution is 100: 3-5; the padding mode is one-padding-one-dipping.
Specific examples and comparative examples are listed below:
example 1:
an antibacterial shirt is characterized in that shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000061
the polyester fiber contains 2 wt% of ceramic powder, 0.5 wt% of coupling agent and 3 wt% of bacteriostatic agent; the ceramic powder comprises 1 part by weight of titanium dioxide and 0.4 part by weight of yttrium oxide; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 2 parts by weight of zinc oxide, 1 part by weight of guanidine stearate, 0.5 part by weight of methacryloxy-benzyl-dimethyl ammonium chloride and 0.5 part by weight of methacryloyl chloride-benzisothiazolinone.
The polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average particle size of 80 nm; (2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder; (3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices; (4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000071
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 3; the padding mode is one-padding-one-padding.
Example 2:
an antibacterial shirt, wherein: the shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000072
the polyester fiber contains 3 wt% of ceramic powder, 0.7 wt% of coupling agent and 4 wt% of bacteriostatic agent; the ceramic powder comprises 2 parts of titanium dioxide and 0.6 part of yttrium oxide by weight; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 3 parts of zinc oxide, 2 parts of guanidine stearate, 1 part of methacryloxy-benzyl-dimethyl ammonium chloride and 0.7 part of methacryloyl chloride-benzisothiazolinone; the polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average particle size of 90 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000081
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 4; the padding mode is one-padding-one-padding.
Example 3:
an antibacterial shirt is characterized in that shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000082
Figure BDA0002397737120000091
the polyester fiber contains 4 wt% of ceramic powder, 1 wt% of coupling agent and 5 wt% of bacteriostatic agent; the ceramic powder comprises 3 parts of titanium dioxide and 0.8 part of yttrium oxide in parts by weight; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 4 parts of zinc oxide, 3 parts of guanidine stearate, 2 parts of methacryloxy-benzyl-dimethyl ammonium chloride and 2 parts of methacryloyl chloride-benzisothiazolinone.
The polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average grain diameter of 100 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000092
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 5; the padding mode is one-padding-one-padding.
Comparative example 1:
an antibacterial shirt is characterized in that shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000101
the polyester fiber contains 2 wt% of ceramic powder, 0.5 wt% of coupling agent and 3 wt% of bacteriostatic agent; the ceramic powder comprises 1 part by weight of titanium dioxide and 0.4 part by weight of yttrium oxide; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 2 parts by weight of zinc oxide, 1 part by weight of guanidine stearate, 0.5 part by weight of methacryloxy-benzyl-dimethyl ammonium chloride and 0.5 part by weight of methacryloyl chloride-benzisothiazolinone.
The polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average particle size of 80 nm; (2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder; (3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices; (4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000102
Figure BDA0002397737120000111
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 3; the padding mode is one-padding-one-padding.
Comparative example 2:
an antibacterial shirt is characterized in that shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000112
the polyester fiber contains 2 wt% of ceramic powder, 0.5 wt% of coupling agent and 3 wt% of bacteriostatic agent; the ceramic powder includes 1 part by weight of titanium dioxide; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 2 parts by weight of zinc oxide, 1 part by weight of guanidine stearate, 0.5 part by weight of methacryloxy-benzyl-dimethyl ammonium chloride and 0.5 part by weight of methacryloyl chloride-benzisothiazolinone.
The polyester fiber is prepared by the following steps:
(1) sintering titanium dioxide, and crushing to obtain ceramic powder with the average particle size of 80 nm; (2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder; (3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices; (4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000121
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 3; the padding mode is one-padding-one-padding.
Comparative example 3:
an antibacterial shirt, wherein: the shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000122
the polyester fiber contains 3 wt% of ceramic powder, 0.7 wt% of coupling agent and 4 wt% of bacteriostatic agent; the ceramic powder comprises 2 parts of titanium dioxide and 0.6 part of yttrium oxide by weight; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 3 parts of zinc oxide, 2 parts of guanidine stearate and 0.7 part of methacryloyl chloride-benzisothiazolinone; the polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average particle size of 90 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000131
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 4; the padding mode is one-padding-one-padding.
Comparative example 4:
an antibacterial shirt, wherein: the shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000132
Figure BDA0002397737120000141
the polyester fiber contains 3 wt% of ceramic powder, 0.7 wt% of coupling agent and 4 wt% of bacteriostatic agent; the ceramic powder comprises 2 parts of titanium dioxide and 0.6 part of yttrium oxide by weight; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 3 parts of zinc oxide, 2 parts of guanidine stearate and 1 part of methacryloyloxy-benzyl-dimethyl ammonium chloride; the polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average particle size of 90 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000142
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 4; the padding mode is one-padding-one-padding.
Comparative example 5:
an antibacterial shirt is characterized in that shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000151
the polyester fiber contains 4 wt% of ceramic powder, 1 wt% of coupling agent and 5 wt% of bacteriostatic agent; the ceramic powder comprises 3 parts of titanium dioxide and 0.8 part of yttrium oxide in parts by weight; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 4 parts of zinc oxide, 3 parts of guanidine stearate, 2 parts of methacryloxy-benzyl-dimethyl ammonium chloride and 2 parts of methacryloyl chloride-benzisothiazolinone.
The polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average grain diameter of 100 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000161
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 5; the padding mode is one-padding-one-padding.
Comparative example 6:
an antibacterial shirt is characterized in that shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure BDA0002397737120000162
the polyester fiber contains 4 wt% of ceramic powder, 1 wt% of coupling agent and 5 wt% of bacteriostatic agent; the ceramic powder comprises 3 parts of titanium dioxide and 0.8 part of yttrium oxide in parts by weight; the coupling agent is bis-1, 2- (trimethoxysilyl) ethane; the bacteriostatic agent comprises 4 parts of zinc oxide, 3 parts of guanidine stearate, 2 parts of methacryloxy-benzyl-dimethyl ammonium chloride and 2 parts of methacryloyl chloride-benzisothiazolinone.
The polyester fiber is prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average grain diameter of 100 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
Padding the blended and woven fabric with an antibacterial treatment solution to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure BDA0002397737120000171
the padding operation is as follows: applying the antibacterial treatment solution to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment solution, drying the gray fabric padded with the antibacterial treatment solution, and baking to obtain shirt fabric; the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 5; the padding mode is one-padding-one-padding.
The results of the performance tests of the examples and comparative examples are set forth below:
Figure BDA0002397737120000172
Figure BDA0002397737120000181
as is clear from the data of examples 1 to 3 and comparative examples 1 to 5, the shirts of the present invention have excellent antibacterial properties.
The embodiments of the present invention have been described in detail with reference to the examples, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.

Claims (10)

1. An antibacterial shirt, characterized in that: the shirt fabric is formed by blending and weaving the following fibers in parts by weight:
Figure FDA0002397737110000011
2. the antibacterial shirt of claim 1, further comprising 0.5-2 parts by weight of Modal fibers.
3. The antibacterial shirt of claim 1, wherein the polyester fibers comprise 2-4 wt% of ceramic powder, 0.5-1 wt% of coupling agent and 3-5 wt% of bacteriostatic agent.
4. The antibacterial shirt of claim 3, wherein the ceramic powder comprises 1-3 parts by weight of titanium dioxide and 0.4-0.8 part by weight of yttrium oxide.
5. The antiseptic shirt of claim 3 wherein the coupling agent is bis-1, 2- (trimethoxysilyl) ethane.
6. The antibacterial shirt of claim 3, wherein the antibacterial agent comprises 2-4 parts by weight of zinc oxide, 1-3 parts by weight of guanidine stearate, 0.5-2 parts by weight of methacryloyloxy-benzyl-dimethylammonium chloride, and 0.5-2 parts by weight of methacryloyl chloride-benzisothiazolinone.
7. The antibacterial shirt of any one of claims 3 to 6, wherein the polyester fibers are prepared by the following steps:
(1) mixing titanium dioxide and yttrium oxide, sintering and crushing to ceramic powder with the average grain diameter of 80-100 nm;
(2) mixing bis-1, 2- (trimethoxysilyl) ethane with the ceramic powder to obtain a modified ceramic powder;
(3) blending the modified ceramic powder with an antibacterial agent and polyester, extruding and slicing to obtain polyester slices;
(4) heating and melting the polyester chip, extruding, and performing spinning forming.
8. The antibacterial shirt of claim 1, wherein the blended and woven fabric is further padded with an antibacterial treatment fluid to obtain a shirt fabric; the antibacterial treatment fluid comprises the following components in parts by weight:
Figure FDA0002397737110000021
9. the antibacterial shirt of claim 8, wherein the padding is performed by: and applying the antibacterial treatment liquid to the blended and woven fabric by a padding method to obtain gray fabric padded with the antibacterial treatment liquid, drying the gray fabric padded with the antibacterial treatment liquid, and baking to obtain the shirt fabric.
10. The method for preparing the moisture-absorbing and sweat-releasing antibacterial fabric according to claim 8, wherein the mass ratio of the blended and woven fabric to the antibacterial treatment liquid is 100: 3-5; the padding mode is one-padding-one-dipping.
CN202010137744.3A 2020-03-02 2020-03-02 Antibacterial shirt Pending CN111364244A (en)

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