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CN111331767A - Method for manufacturing surface conductance nonlinear insulator by centrifugal technology - Google Patents

Method for manufacturing surface conductance nonlinear insulator by centrifugal technology Download PDF

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CN111331767A
CN111331767A CN202010004202.9A CN202010004202A CN111331767A CN 111331767 A CN111331767 A CN 111331767A CN 202010004202 A CN202010004202 A CN 202010004202A CN 111331767 A CN111331767 A CN 111331767A
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mold
centrifugal
nonlinear
silicon carbide
insulator
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杜伯学
梁虎成
李进
王泽华
冉昭玉
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Tianjin University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/003Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/02Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C39/021Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles by casting in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/02Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C39/04Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles using movable moulds not applied
    • B29C39/08Introducing the material into the mould by centrifugal force
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2509/00Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
    • B29K2509/02Ceramics
    • B29K2509/04Carbides; Nitrides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/34Electrical apparatus, e.g. sparking plugs or parts thereof
    • B29L2031/3412Insulators

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Insulating Bodies (AREA)

Abstract

本发明公开一种离心技术制造表面电导非线性绝缘子的方法,包括如下步骤:1)模具准备;2)离心机准备;3)浇注料准备:在130℃的真空条件下将环氧树脂基体(型号CT‑5531)、固化剂(型号HY‑5533)按照100:85的比例混合,然后加入α型号碳化硅颗粒,储存在真空和130℃的环境中待用;4)两步浇注法:向步骤3)的浇注料中加入促进剂后迅速进行浇注工作,使浇注料刚好填满整个模具,将模具用盖子密封以免离心过程中浇注料泄露。离心法制备的表面电导非线性支柱绝缘子的本体与表面非线性碳化硅层实现了一体固化成型,因而具有极好的界面稳定性,还能有效调控电场分布。

Figure 202010004202

The invention discloses a method for manufacturing surface conductance nonlinear insulators by centrifugal technology, which comprises the following steps: 1) mold preparation; 2) centrifuge preparation; 3) casting material preparation: under the vacuum condition of 130 DEG C, an epoxy resin matrix ( Model CT-5531) and curing agent (model HY-5533) were mixed in a ratio of 100:85, and then α-type silicon carbide particles were added, and stored in a vacuum and 130 ℃ environment for later use; 4) Two-step casting method: to After adding the accelerator to the castable in step 3), the casting work is carried out quickly, so that the castable just fills the entire mold, and the mold is sealed with a lid to prevent the castable from leaking during the centrifugation process. The body and the surface nonlinear silicon carbide layer of the surface conductive nonlinear pillar insulator prepared by the centrifugal method are integrally solidified and formed, so they have excellent interface stability and can effectively control the electric field distribution.

Figure 202010004202

Description

一种离心技术制造表面电导非线性绝缘子的方法A method for fabricating surface conductance nonlinear insulators by centrifugal technology

技术领域technical field

本发明属于绝缘子制备技术领域,具体涉及一种离心技术制造表面电导非线性绝缘子的方法。The invention belongs to the technical field of insulator preparation, and in particular relates to a method for manufacturing surface conductance nonlinear insulators by centrifugal technology.

背景技术Background technique

高压直流管道输电具有传输容量大、可靠性高和占地面积小等诸多优点。支柱绝缘子沿面闪络是直流GIL(Gas Insulated Lines)的常见故障形式与限制因素。因此,设法提高直流 GIL支柱绝缘子的沿面闪络电压,对于提高GIL的工作可靠性和进一步缩小管道尺寸具有重要意义。表面电导非线性绝缘子不仅具有良好的表面电场调控功能,而且电导损耗也较小,在直流GIL中具有广阔的应用前景。本发明利用离心法制造表面电导非线性绝缘子,实现了绝缘子基体与表面非线性层的一体固化成型,具有极好的界面结合能力。HVDC pipeline transmission has many advantages, such as large transmission capacity, high reliability and small footprint. The creepage flashover of pillar insulators is a common fault form and limiting factor of DC GIL (Gas Insulated Lines). Therefore, trying to improve the creepage flashover voltage of the DC GIL pillar insulator is of great significance for improving the working reliability of the GIL and further reducing the size of the pipeline. The surface conductance nonlinear insulator not only has good surface electric field regulation function, but also has small conductance loss, and has broad application prospects in DC GIL. The invention utilizes the centrifugal method to manufacture the surface conductivity nonlinear insulator, realizes the integral solidification molding of the insulator matrix and the surface nonlinear layer, and has excellent interface bonding ability.

发明内容SUMMARY OF THE INVENTION

本发明以简化的圆台型支柱绝缘子为原型,旨在提供一种利用离心法制造表面电导非线性绝缘子的技术,从而提高直流GIL绝缘子的工作可靠性和进一步缩小GIL管道尺寸。The invention takes a simplified circular truncated pillar insulator as a prototype, and aims to provide a technology for manufacturing a surface conductance nonlinear insulator by a centrifugal method, thereby improving the working reliability of the DC GIL insulator and further reducing the size of the GIL pipeline.

为解决上述技术问题,本发明采用的技术方案为:一种离心技术制造表面电导非线性绝缘子的方法,包括如下步骤:In order to solve the above-mentioned technical problems, the technical solution adopted in the present invention is: a method for manufacturing surface conductance nonlinear insulators by centrifugal technology, comprising the following steps:

1)模具准备1) Mold preparation

本发明采用的模具如图1所示,其关键特征为:一是旋转对称结构;二是模具浇口在顶部,且配备具有密封功能的盖子。The mold used in the present invention is shown in Figure 1, and its key features are: first, a rotationally symmetric structure; second, the mold gate is on the top, and is equipped with a cover with a sealing function.

2)离心机准备2) Centrifuge preparation

本发明所采用的离心机结构如图2所示,其关键特征为:一是具有速度可调的旋转平台,用于提供所需的离心力;二是具有温度可调的恒温箱,为绝缘子的固化提供温度条件。The structure of the centrifuge used in the present invention is shown in Figure 2, and its key features are: first, it has a rotating platform with adjustable speed, which is used to provide the required centrifugal force; Curing provides temperature conditions.

3)浇注料准备3) Castable preparation

在130℃的真空条件下将环氧树脂基体(型号CT-5531)、固化剂(型号HY-5533)按照 100:85的比例混合,然后按需加入适量比例的α型号碳化硅颗粒,储存在真空和130℃的环境中待用。The epoxy resin matrix (type CT-5531) and the curing agent (type HY-5533) were mixed in a ratio of 100:85 under vacuum conditions at 130 °C, and then an appropriate proportion of α-type silicon carbide particles was added as needed, and stored in Standby in vacuum and 130°C environment.

4)两步浇注法4) Two-step casting method

向步骤3)的浇注料中加入促进剂后迅速进行浇注工作,使浇注料刚好填满整个模具,将模具用盖子密封以免离心过程中浇注料泄露。After adding the accelerator to the castable in step 3), the casting work is carried out quickly, so that the castable just fills the entire mold, and the mold is sealed with a lid to prevent the castable from leaking during the centrifugation process.

第一步:采用短时高速离心,此时离心力在模具表面的分量远大于(重力+粘滞力),碳化硅颗粒沿模具表面向上运动并聚集于模具顶部。Step 1: Use short-term high-speed centrifugation. At this time, the centrifugal force on the mold surface is much larger than (gravity + viscous force), and the silicon carbide particles move up along the mold surface and gather on the top of the mold.

第二部:采用长时间低速离心,此时(离心力+粘滞力)在模具表面的分量小于重力,聚集于模具顶部的碳化硅颗粒在环氧树脂固化过程中沿着模具表面下滑,最终形成厚度均匀的碳化硅层,如图3所示。The second part: using long-time low-speed centrifugation, at this time (centrifugal force + viscous force) on the surface of the mold is less than gravity, the silicon carbide particles gathered on the top of the mold slide along the surface of the mold during the curing process of the epoxy resin, and finally form A silicon carbide layer of uniform thickness is shown in Figure 3.

有益效果beneficial effect

离心法制备的表面电导非线性支柱绝缘子的本体与表面非线性碳化硅层实现了一体固化成型,因而具有极好的界面稳定性。The body and the surface nonlinear silicon carbide layer of the surface-conductivity nonlinear post insulator prepared by the centrifugal method are integrally solidified and formed, so they have excellent interface stability.

离心法制备的表面电导非线性绝缘子可以有效调控电场分布,如图4所示。The surface conductance nonlinear insulator prepared by centrifugal method can effectively control the electric field distribution, as shown in Figure 4.

附图说明Description of drawings

图1所示为模具示意图(a)和实物图(b)。Figure 1 shows the schematic diagram of the mold (a) and the physical map (b).

图2所示为离心机结构示意图。Figure 2 shows a schematic diagram of the structure of the centrifuge.

图3所示为两步离心法示意图(a)和表层非线性绝缘子断面照片(b)。Figure 3 shows the schematic diagram of the two-step centrifugation method (a) and the cross-sectional photo of the surface nonlinear insulator (b).

图4所示为绝缘子电场分布图:(a)传统支柱绝缘子,(b)表面电导非线性绝缘子。Figure 4 shows the electric field distribution of the insulators: (a) traditional pillar insulator, (b) surface conductance nonlinear insulator.

具体实施方式Detailed ways

以下结合附图和具体实施例来对本发明作进一步的说明。The present invention will be further described below with reference to the accompanying drawings and specific embodiments.

利用离心法制造表面电导非线性支柱绝缘子的最佳实施方案如下:The best embodiment of manufacturing surface conductance nonlinear strut insulators by centrifugal method is as follows:

1、浇注料的最佳配方(质量比)如下:环氧树脂基体(型号CT-5531):固化剂(型号HY-5533):促进剂:碳化硅(α型20μm)=100:85:0.2:15。碳化硅含量越高,表面非线性层厚度越大。按照最佳配方浇注的表面电导非线性绝缘子的非线性表层的厚度约为0.1mm,厚度均匀且过程容易控制。1. The optimal formula (mass ratio) of the castable is as follows: epoxy resin matrix (model CT-5531): curing agent (model HY-5533): accelerator: silicon carbide (α type 20μm) = 100:85:0.2 :15. The higher the silicon carbide content, the greater the thickness of the surface nonlinear layer. The thickness of the nonlinear surface layer of the surface conductance nonlinear insulator poured according to the optimal formula is about 0.1 mm, the thickness is uniform and the process is easy to control.

2、若采用不同的配方,需要根据环氧树脂的粘度和填料的密度、粒径等信息适当调整离心速度和时间。环氧粘度越高、填料密度和粒径越小,需要的离心速度越大,时间越长。2. If different formulas are used, the centrifugal speed and time need to be adjusted appropriately according to the viscosity of the epoxy resin and the density and particle size of the filler. The higher the epoxy viscosity, the smaller the filler density and particle size, the higher the centrifugal speed and the longer the time required.

一种离心技术制造表面电导非线性绝缘子的方法,包括如下步骤:A method for manufacturing a surface conductance nonlinear insulator by centrifugal technology, comprising the following steps:

1)模具准备1) Mold preparation

本发明采用的模具如图1所示,其关键特征为:一是旋转对称结构;二是模具浇口在顶部,且配备具有密封功能的盖子。The mold used in the present invention is shown in Figure 1, and its key features are: first, a rotationally symmetric structure; second, the mold gate is on the top, and is equipped with a cover with a sealing function.

2)离心机准备2) Centrifuge preparation

本发明所采用的离心机结构如图2所示,其关键特征为:一是具有速度可调的旋转平台,用于提供所需的离心力;二是具有温度可调的恒温箱,为绝缘子的固化提供温度条件。The structure of the centrifuge used in the present invention is shown in Figure 2, and its key features are: first, it has a rotating platform with adjustable speed, which is used to provide the required centrifugal force; Curing provides temperature conditions.

3)浇注料准备3) Castable preparation

在130℃的真空条件下将环氧树脂基体(型号CT-5531)、固化剂(型号HY-5533)按照 100:85的比例混合,然后按需加入适量比例的α型号碳化硅颗粒,储存在真空和130℃的环境中待用。The epoxy resin matrix (type CT-5531) and the curing agent (type HY-5533) were mixed in a ratio of 100:85 under vacuum conditions at 130 °C, and then an appropriate proportion of α-type silicon carbide particles was added as needed, and stored in Standby in vacuum and 130°C environment.

4)两步浇注法4) Two-step casting method

向步骤三的浇注料中加入少量促进剂后迅速进行浇注工作,使浇注料刚好填满整个模具,将模具用盖子密封以免离心过程中浇注料泄露。After adding a small amount of accelerator to the castable in step 3, the pouring work is carried out quickly, so that the castable just fills the entire mold, and the mold is sealed with a lid to prevent the castable from leaking during the centrifugation process.

第一步:采用短时高速离心,此时离心力在模具表面的分量远大于重力和粘滞力的合力,碳化硅颗粒沿模具表面向上运动并聚集于模具顶部。Step 1: Use short-term high-speed centrifugation. At this time, the component of centrifugal force on the mold surface is much larger than the combined force of gravity and viscous force, and the silicon carbide particles move upward along the mold surface and gather on the top of the mold.

第二部:采用长时间低速离心,此时离心力和粘滞力的合力在模具表面的分量小于重力,聚集于模具顶部的碳化硅颗粒在环氧树脂固化过程中沿着模具表面下滑,最终形成厚度均匀的碳化硅层,如图3所示。The second part: using long-time low-speed centrifugation, at this time, the combined force of centrifugal force and viscous force on the mold surface is less than gravity, and the silicon carbide particles gathered on the top of the mold slide along the surface of the mold during the curing process of the epoxy resin, and finally form A silicon carbide layer of uniform thickness is shown in Figure 3.

本发明最佳配方的离心过程的最佳实施方式如下:(1)130℃环境下,离心机转速1400 r/min,时间2min;(2)130℃环境下,离心机转速140r/min,时间30min。最后将模具放入温度为130℃的烤箱进行2h的二次固化。The best embodiment of the centrifugation process of the optimal formula of the present invention is as follows: (1) under the environment of 130°C, the rotation speed of the centrifuge is 1400 r/min, and the time is 2 minutes; (2) under the environment of 130°C, the rotation speed of the centrifuge is 140 r/min, and the time 30min. Finally, the mold was put into an oven with a temperature of 130 °C for 2 hours of secondary curing.

Claims (4)

1. A method for manufacturing a surface conductance nonlinear insulator by a centrifugal technology is characterized by comprising the following steps:
1) preparing a mould: the requirement is met by a rotational symmetric structure, a mold gate is arranged at the top, and a cover with a sealing function is arranged;
2) preparing a centrifuge: the requirement is satisfied that the rotary platform has adjustable speed and is used for providing required centrifugal force;
the device is provided with a temperature-adjustable thermostat which provides temperature conditions for the solidification of the insulator;
3) preparing a casting material:
mixing an epoxy resin matrix and a curing agent according to the proportion of 100:85 at the temperature of 130 ℃ under vacuum, adding α type silicon carbide particles, and storing in a vacuum environment at the temperature of 130 ℃ for later use;
4) the two-step casting method comprises the following steps: adding an accelerant into the pouring material obtained in the step 3), and then quickly pouring, so that the pouring material just fills the whole mould, and sealing the mould by using a cover to prevent the pouring material from leaking in the centrifugal process;
(1) the short-time high-speed centrifugation is adopted, the component of the centrifugal force on the surface of the mold is far larger than the resultant force of gravity and viscous force, and silicon carbide particles move upwards along the surface of the mold and gather at the top of the mold;
(2) adopting long-time low-speed centrifugation, wherein the component of the resultant force of the centrifugal force and the viscous force on the surface of the mold is smaller than the gravity, and the silicon carbide particles gathered on the top of the mold slide down along the surface of the mold in the curing process of the epoxy resin;
(3) finally, a silicon carbide layer with uniform thickness is formed.
2. The method for manufacturing surface conduction nonlinear insulator by centrifugal technology according to claim 1, wherein the technical parameters in step 4) (1) are as follows: the rotating speed of the centrifuge is 1400r/min under the environment of 130 ℃, and the time is 2 min.
3. The method for manufacturing surface conduction nonlinear insulator by centrifugal technology according to claim 1, wherein the technical parameters in step 4) (2) are as follows: under the environment of 130 ℃, the rotating speed of the centrifuge is 140r/min, and the time is 30 min.
4. The method for manufacturing surface conduction nonlinear insulator by centrifugal technology according to claim 1, wherein the technical parameters in step 4) (3) are as follows: putting the mould into an oven with the temperature of 130 ℃ for secondary curing for 2 h.
CN202010004202.9A 2020-01-03 2020-01-03 Method for manufacturing surface conductance nonlinear insulator by centrifugal technology Pending CN111331767A (en)

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GB1051851A (en) * 1963-02-04 1966-12-21
GB1348432A (en) * 1970-08-25 1974-03-20 Micafil Ag Casting process for producing electrical bushings
DE2901528A1 (en) * 1979-01-16 1980-07-17 Siemens Ag Cast insulator with ribs of high thermal conductivity - which are of higher density around lower density trunk and made by centrifugal casting
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Application publication date: 20200626