CN111295469A

CN111295469A - Methods and compositions for cooling yarns and fabrics and articles comprising cooled yarns and fabrics

Info

Publication number: CN111295469A
Application number: CN201880063867.8A
Authority: CN
Inventors: 苏泓源; 魏英斌
Original assignee: BRRR Inc
Current assignee: BRRR Inc
Priority date: 2017-11-01
Filing date: 2018-08-30
Publication date: 2020-06-16

Abstract

In one aspect, the present disclosure is directed to a composite yarn having a structure comprising a core component and a sheath layer, wherein each of the core component and the sheath layer independently comprises a polymer and the disclosed cooling composition. In various further aspects, the present disclosure relates to a double covered yarn comprising: an elastic core comprising elastic yarns; a first yarn in contact with the elastic core, and wherein the first yarn comprises a disclosed yarn comprising a core component and a sheath layer; and a second yarn in contact with the first yarn, and wherein the second yarn comprises a yarn comprising cellulosic fibers. In yet further aspects, the present disclosure relates to fabrics, such as denim fabrics. This abstract is intended as a search tool for search purposes in the particular art and is not intended to limit the present disclosure.

Description

Methods and compositions for cooling yarns and fabrics and articles comprising cooled yarns and fabrics

Cross Reference to Related Applications

The present application claims U.S. patent application No. 16/036,097 filed on 7, 16, 2018; U.S. provisional patent application No. 62/659,931, filed on 19/4/2018; taiwan patent application No. 106129771, filed on 31/8/2017; taiwan patent application No. 106129774, filed on 31/8/2017; taiwan patent application No. 106213242, filed on 7/9/2017; taiwan patent application No. 106213241, filed on 7/9/2017; chinese patent application No. 201711042927.1 filed on 1/11/2017; and the benefit of chinese patent application No. 201711055972.0 filed on 2.11.2017; each of the above patent applications is incorporated by reference herein in its entirety.

Background

The name denim (denim) is believed to originate from a french fabric called "stage de Nimes" worn in the 16 th century and having twill weaves (twill weaves) similar to today's denim fabrics. The durability and flexible application of denim has led it to become popular in England in the 17 th century. Another fabric that has gained popularity at the same time is a cotton corduroy fabric from therma italica and known as denim (jean) from where it originated. At the time, denim was made of two different cotton threads (threads of cotton), one colored and one white, while denim used two cotton threads of the same color. Both fabrics appear to be synonymous at this time and are known under both names.

This fabric passed to north america and in the late 18 th century, the textile mill in the united states produced denim/denim. The Book "The Weavers Draft Book and clothes Assistant" published in 1792 contains a technical sketch of The weaving method of various denim fabrics. The popularity of denim was ensured by the success of Levi Strauss corporation, who patented a riveting process for producing denim work pants in 1873 and sold them to miners in san Francisco. These pants are distinguished by their comfort, durability, and ability to maintain their shape. Denim is described as the "most important fabric in the workwear group" in john hoye's "Staple Cotton Fabrics," published in 1942. They are particularly strong in The warp (warp) direction, in which The fabric experiences greater wear than The filling (filling) (The most important fabric of The work-spraying … denier area string and serviceable; The y area particulate fabric in The warp direction, The cloth The textile is sub-jected to The area fabric.

The wide appeal of denim, especially in pants, based on its comfortable shape and durability, masks the disadvantages of this material, such as poor dryness, lack of stretchability, rough hand and poor thermal conductivity. The combination of spandex (spandex) brings reinforcement to the denim to make the fabric soft and give it stretchability. Other yarns are also added to improve the softness and hand of the fabric. However, little work has been done on improving the wicking, drying and thermal conductivity of fabrics. Denim naturally absorbs moisture, but does not effectively remove moisture from the skin (skin). When worn in a warm environment or when active, the fabric becomes "damp" (damp and hot-retaining the moisture and heat generated by the person wearing the material.

Thus, despite advances in textile research, there remains a significant need for yarns that can be used in denim fabrics that address known disadvantages of such fabrics, such as poor wicking, long drying times, and poor thermal conductivity, while maintaining hand and functionality. The present disclosure satisfies these needs and others.

SUMMARY

In accordance with the purposes of the present disclosure, as embodied and broadly described herein, the present disclosure relates in one aspect to a composite yarn having a core member and a sheath layer, wherein each of the core member and the sheath layer independently comprises a polymer and a disclosed cooling composition. In various further aspects, the present disclosure relates to a double covered yarn (double covered yarn) comprising: an elastic core comprising elastic yarns; a first yarn in contact with the elastic core, and wherein the first yarn comprises the disclosed composite yarn comprising a core component and a sheath layer; and a second yarn in contact with the first yarn, and wherein the second yarn comprises a yarn comprising cellulosic fibers. In yet further aspects, the present disclosure relates to a fabric, such as a denim fabric, comprising: a weft yarn comprising the disclosed double covered yarn; and warp yarns comprising cotton fibers.

Disclosed are cooling compositions comprising a cooling material, a cooling compound, a first cooling salt, or a combination thereof.

Also disclosed is a cooling polymer composition comprising a polymer and a cooling composition comprising a cooling material, a cooling compound, a first cooling salt, or a combination thereof.

Also disclosed is a composite yarn comprising a core component and a sheath layer, wherein: (a) the core member comprises a polyester polymer and a first cooling composition; and (b) the sheath comprises a polyamide polymer and a second cooling composition; wherein the first cooling composition comprises a first cooling material, a first cooling compound, a first cooling salt, or a combination thereof; and wherein the second cooling composition comprises a second cooling material, a second cooling compound, and a second cooling salt.

Also disclosed is a double covered yarn comprising: (a) an elastic core comprising elastic yarns; (b) a first yarn comprising the disclosed composite yarn comprising a core component comprising a polyester polymer and a first cooling composition and a sheath layer comprising a polyamide polymer and a second cooling composition; and (c) a second yarn comprising cellulosic fibers; wherein the first yarn is wound around the elastic core to form a single covered yarn; and wherein the second yarn is wrapped around the single wrap yarn to form a double wrap yarn.

Also disclosed is a fabric comprising: a weft yarn comprising the disclosed double covered yarn; and warp yarns comprising cotton fibers.

Also disclosed is an article comprising a yarn comprising a core component and a sheath layer, wherein: (a) the core member comprises a polyester polymer and a first cooling composition; and (b) the sheath comprises a polyamide polymer and a second cooling composition; wherein the first cooling composition comprises a first cooling material, a first cooling compound, a first cooling salt, or a combination thereof; and wherein the second cooling composition comprises a second cooling material, a second cooling compound, and a second cooling salt.

Articles comprising the disclosed double covered yarn are also disclosed.

Articles comprising the disclosed fabrics are also disclosed.

Other systems, methods, features and advantages of the disclosure will be or will become apparent to one with skill in the art upon examination of the following figures and detailed description. It is intended that all such additional systems, methods, features and advantages be included within this description, be within the scope of the present disclosure, and be protected by the accompanying claims. Furthermore, all optional and preferred features and modifications of the described embodiments are applicable to all aspects of the disclosure taught herein. Furthermore, the individual features of the dependent claims, as well as all optional and preferred features and modifications of the described embodiments, are combinable and interchangeable with each other.

Brief Description of Drawings

Many aspects of this disclosure can be better understood with reference to the following drawings. The components in the drawings are not necessarily to scale, emphasis instead being placed upon clearly illustrating the principles of the present disclosure. Moreover, in the figures, like reference numerals designate corresponding parts throughout the several views.

Fig. 1A-1D show representative schematic diagrams of the disclosed composite yarns. Fig. 1A shows a side cross-sectional view of a portion of the disclosed composite yarn, as well as a cross-sectional view of an end thereof. An enlarged view of the cross-sectional end view is highlighted. Key information (key) indicating the gray scale color associated with the distribution of the sheath, core, and one or more cooling compositions in each of the sheath and core is shown below the view. Fig. 1B shows a cross-sectional view of the disclosed composite yarn 100, with the following designated aspects: a polyester core 110; a first cooling composition 112; a polyamide sheath 115; and a second cooling composition 117. Fig. 1C shows a cross-sectional view of the disclosed composite yarn 120, with the following designated aspects: a polyester core 110; a polyamide sheath 115; and a second cooling composition 117. Fig. 1D shows a cross-sectional view of a disclosed composite yarn 130, with the following designated aspects: a polyester core 110; a first cooling composition 112; and a polyamide sheath 115.

Fig. 2A-2B show representative Scanning Electron Micrograph (SEM) images of the disclosed fabric, which includes a twill weave comprising: a weft yarn comprising the disclosed double covered yarn; and warp yarns, the warp yarns comprising cotton yarns. Fig. 2A shows the disclosed fabric in one magnification, showing a 1mm gauge on the lower left of the image. Fig. 2B shows the disclosed fabric at a higher magnification compared to fig. 2A, showing a scalar scale of 200 μm at the lower left of the image.

Fig. 3A-3B show representative Scanning Electron Micrograph (SEM) images of the disclosed warp yarns including the disclosed cotton yarns. Fig. 3A shows in one magnification a longitudinal view of the disclosed warp yarn comprising cotton denim yarn, showing a scalar scale of 200 μm at the lower left of the image. Fig. 3B shows the disclosed warp yarns comprising cotton denim yarns at a higher magnification compared to fig. 3A, showing a scalar scale of 100 μm at the lower left of the image.

Fig. 4A-4C show representative Scanning Electron Micrograph (SEM) images of the disclosed weft yarns including the disclosed double covered yarns. Fig. 4A shows a longitudinal view of the disclosed weft yarns including the disclosed double covered yarns at one magnification, showing a scalar scale of 200 μm at the lower left of the image. Fig. 4B shows the disclosed weft yarns including the disclosed double covered yarns at a higher magnification compared to fig. 4A, showing a scalar scale of 100 μm at the lower left of the image. Figure 4C shows a cross-sectional view of the disclosed double covered yarn with various components as labeled therein. The lower right of fig. 4C shows a scalar bar of 100 μm.

Fig. 5 shows a representative schematic of a disclosed process 500 for making the disclosed composite yarn, numbered as follows: a reservoir, such as a hopper, having a polyester polymer ("PET") melt pool comprising PET and a first cooling composition, 501; a reservoir, such as a hopper, having a melt pool of a polyamide polymer ("PA", e.g., nylon) comprising PA and a second cooling composition, 502; an inner spinneret assembly 510 for spraying a core member of composite yarn; an outer spinneret assembly 511 for spraying a sheath around the core member of the composite yarn; and a composite yarn 520 formed by the process.

Fig. 6A-6B show representative cross-sectional views of the disclosed double covered yarn. Fig. 6A shows a schematic cross-sectional view of a disclosed double covered yarn comprising a cellulosic fiber (e.g., viscose rayon), a composite yarn, and an elastic yarn (e.g., spandex yarn). Fig. 6B shows a cross-sectional view of the disclosed double covered yarn 1000 with the following specified aspects: (a) an elastic core 200 comprising elastic yarns; (b) a plurality of first yarns 100a-100h, each first yarn comprising a disclosed composite yarn, such as the composite yarn shown in fig. 1B comprising a core component comprising a polyester polymer and a first cooling composition and a sheath layer comprising a polyamide polymer and a second cooling composition; and (c) a plurality of second yarns 300a-300h comprising cellulosic fibers; a first yarn is wrapped around the elastic core to form a single covered yarn, such as shown in fig. 6B; and wherein the second yarn is wrapped around the single wrap yarn to form a double wrap yarn.

Additional advantages of the disclosure will be set forth in part in the description which follows, and in part will be obvious from the description, or may be learned by practice of the disclosure. The advantages of the disclosure will be realized and attained by means of the elements and combinations particularly pointed out in the appended claims. It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the disclosure, as claimed.

Detailed Description

Many modifications and other embodiments of the disclosure set forth herein will come to mind to one skilled in the art to which the disclosed compositions and methods pertain having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the disclosure is not to be limited to the specific embodiments disclosed and that modifications and other embodiments are intended to be included within the scope of the appended claims. The skilled person will recognise many variations and adaptations of the aspects described herein. Such modifications and adaptations are intended to be included within the teachings of this disclosure and are intended to be covered by the claims herein.

Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.

As will be apparent to those of skill in the art upon reading this disclosure, each of the individual embodiments described and illustrated herein has discrete components and features which may be readily separated from or combined with the features of any of the other several embodiments without departing from the scope or spirit of the present disclosure.

Any recited method may be performed in the order of the events listed or in any other order that is logically possible. That is, unless expressly stated otherwise, it is in no way intended that any method or aspect set forth herein be construed as requiring that its steps be performed in a specific order. Thus, where a method claim does not specifically state in the claims or specification that the steps are to be limited to a particular order, it is in no way intended that an order be inferred. This applies to any non-obvious basis for explanation including logical issues relating to step arrangement or operation flow, simple meanings derived from grammatical organization or punctuation, or the numbering or type of aspects described in the specification.

All publications mentioned herein are incorporated herein by reference to disclose and describe the methods and/or materials in connection with which the publications are cited. The publications discussed herein are provided solely for their disclosure prior to the filing date of the present application. Nothing herein is to be construed as an admission that the invention is not entitled to antedate such publication by virtue of prior invention. Further, the dates of publication provided herein may be different from the actual publication dates which may need to be independently confirmed.

Although aspects of the present disclosure may be described and claimed in particular legal categories, such as the system legal category, this is for convenience only and those skilled in the art will appreciate that each aspect of the present disclosure may be described and claimed in any legal category.

It is also to be understood that the terminology used herein is for the purpose of describing particular aspects only and is not intended to be limiting. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the disclosed compositions and methods belong. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the specification and relevant art and should not be interpreted in an idealized or overly formal sense unless expressly so defined herein.

Before describing aspects of the present disclosure, the following definitions are provided and should be used unless otherwise indicated. Additional terms may be defined elsewhere in the disclosure.

A. Definition of

As used herein, "comprising" should be interpreted as specifying the presence of the stated features, integers, steps or components as referred to, but does not preclude the presence or addition of one or more features, integers, steps or components, or groups thereof. Furthermore, the term "comprising" is intended to include the examples and aspects encompassed by the term "consisting essentially of. Similarly, the term "consisting essentially of is intended to include the examples covered by the term" consisting of.

As used in this specification and the appended claims, the singular forms "a," "an," and "the" include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to "a polymer," "a yarn," or "a fabric" includes, but is not limited to, two or more such polymers, yarns, or fabrics, and the like.

It should be noted that ratios, concentrations, amounts, and other numerical data may be represented herein in a range format. It will be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint, and independently of the other endpoint. It will also be understood that a number of values are disclosed herein, and that each value is disclosed herein as "about" that particular value in addition to the value itself. For example, if the value "10" is disclosed, then "about 10" is also disclosed. Ranges may be expressed herein as from "about" one particular value, and/or to "about" another particular value. Similarly, when values are expressed as approximations, by use of the antecedent "about," it will be understood that the particular value forms another aspect. For example, if the value "about 10" is disclosed, then "10" is also disclosed.

When ranges are expressed, additional aspects include from the one particular value and/or to the other particular value. For example, where the stated range includes one or both of the extremes, ranges excluding either or both of those included extremes are also included in the disclosure, e.g., the phrase "x to y" includes ranges from 'x' to 'y' as well as ranges greater than 'x' and less than 'y'. Ranges can also be expressed as upper limits, e.g., 'about x, y, z, or less', and should be interpreted to include specific ranges of 'about x', 'about y', and 'about z', as well as ranges of 'less than x', 'less than y', and 'less than z'. Likewise, the phrase 'about x, y, z or greater' should be construed to include specific ranges of 'about x', 'about y', and 'about z' as well as ranges of 'greater than x', 'greater than y', and 'greater than z'. In addition, the phrase "about 'x' to 'y'", when 'x' and 'y' are numerical values, includes "about 'x' to about 'y'".

It is to be understood that such a range format is used for convenience and brevity, and thus, should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For purposes of this specification, a numerical range of "about 0.1% to 5%" should be interpreted to include not only the explicitly recited values of about 0.1% to about 5%, but also include each of the values (e.g., about 1%, about 2%, about 3%, and about 4%) and the sub-ranges (e.g., about 0.5% to about 1.1%, about 5% to about 2.4%, about 0.5% to about 3.2%, and about 0.5% to about 4.4%, as well as other possible sub-ranges) within the indicated range.

As used herein, the terms "about (about)", "about (approximate)", "at (at) or about" and "substantially" mean that the amount or value in question may be an exact value or a value that provides an equivalent result or effect to that recited in the claims or taught herein. That is, it is to be understood that amounts, sizes, formulations, parameters, and other quantities and characteristics are not and need not be exact, but may be approximate and/or larger or smaller, as desired, reflecting tolerances, conversion factors, rounding off, measurement error and the like, and other factors known to those of skill in the art so that an equivalent result or effect is obtained. In some cases, values that provide equivalent results or effects cannot be reasonably determined. In such cases, it will generally be understood that, as used herein, "about" and "at or about" mean a variation of the nominal value indicated ± 10%, unless otherwise indicated or inferred. Generally, an amount, size, formulation, parameter, or other quantity or characteristic is "about", or "at or about", whether or not explicitly stated to be such. It is understood that where "about", "about" or "at or about" is used in advance of a quantitative value, a parameter also includes the specific quantitative value itself, unless specifically stated otherwise.

As used herein, the terms "weight percent," "wt%" and "wt.%," used interchangeably, indicate the percentage by weight of a given component based on the total weight of the composition, the given component being a component of the composition, unless otherwise specified. That is, all wt% values are based on the total weight of the composition, unless otherwise specified. It is understood that the sum of the wt% values of all components in the disclosed compositions or formulations is equal to 100. Alternatively, if the wt% values are based on the total weight of a subset of the components in the composition, then it is understood that the sum of the wt% values for the specified components in the disclosed composition or formulation is equal to 100.

As used herein, the term "effective amount" refers to an amount sufficient to effect the desired modification of the physical properties of a composition or material. For example, an "effective amount" of a cooling composition refers to an amount sufficient to achieve a desired improvement in a property modulated by the cooling composition (e.g., achieve a desired enhancement of Qmax as compared to not containing an effective amount of yarn or fabric). The specific level in terms of wt% required for an effective amount in the composition will depend on a variety of factors including the amount and type of polymer and yarn, the use of the fabric, and the like.

As used herein, the term "optional" or "optionally" means that the subsequently described event or circumstance may or may not occur, and that the description includes instances where said event or circumstance occurs and instances where it does not.

As used herein, the term "transition metal" means an element whose atoms have a partially filled d sub-layer, or which can generate cations with an incomplete d sub-layer, typically found in groups 3-12 of periods 4-7 of the periodic table. Exemplary, but non-limiting, transition metals include titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium, zirconium, silver, tungsten, platinum, and gold.

As used herein, "nanosilver" and "nanosilver oxide" may be used interchangeably and refer to silver oxide (i.e., silver (I) oxide, silver (II) oxide, or a combination thereof), wherein the silver oxide is in a form that generally includes particles, powder, or a combination thereof, wherein the particles and/or powder are nano-sized. That is, the particles or powders, as the case may be, typically have a size of about 1nm to about 1000 nm.

Unless otherwise indicated, the temperatures referred to herein are based on atmospheric pressure (i.e., one atmosphere).

B. The composition is cooled.

In one aspect, the present disclosure relates to cooling compositions that can be used to make yarns. More specifically, in one aspect, the present disclosure relates to a cooling polymer composition comprising a polymer and a cooling composition comprising a cooling material, a cooling compound, a cooling salt, or a combination thereof. The disclosed cooled polymer compositions can be made into chips (chips) or pellets (pellets) for use in yarn or filament spinning equipment or machines.

In various aspects, the polymer in the disclosed cooling polymer compositions can include a polyester polymer, such as polyethylene terephthalate, polypropylene terephthalate, or a combination thereof. In some aspects, the polyester can comprise polyethylene terephthalate. In a further aspect, the polyester can comprise polytrimethylene terephthalate. In yet further aspects, the polyester is a polyester copolymer comprising polyethylene terephthalate, polypropylene terephthalate, or a combination thereof. In still further aspects, the polyester can comprise a copolymer comprising polyethylene terephthalate. In a further aspect, the polyester can comprise a copolymer comprising polytrimethylene terephthalate.

In various aspects, the polymers in the disclosed cooling polymer compositions can include polyamide polymers such as nylon 6, nylon 4/6, nylon 6/6, nylon 6/10, nylon 6/12, nylon 11, nylon 12, or combinations thereof. In further aspects, the polyamide can include nylon 6/6. In still further aspects, the polyamide is a polyamide copolymer comprising nylon 6, nylon 4/6, nylon 6/6, nylon 6/10, nylon 6/12, nylon 11, nylon 12, or a combination thereof. In yet a further aspect, the polyamide is a polyamide copolymer comprising nylon 6/6.

In one aspect, the cooling composition can be present in the cooling polymer composition in an amount of about 0.001 wt% to about 5 wt%, based on the total weight of the polymer and the cooling composition. In further aspects, the cooling composition can comprise about 0.001 wt% based on the total weight of the polymer and the cooling composition; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the cooling composition can be present in an amount of about 5.0 wt% to about 25 wt%, based on the total weight of the polymer and the cooling composition. In a further aspect, the cooling composition can be about 5.0 wt% based on the total weight of the polymer and the cooling composition; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; about 10.1 wt%; about 10.2 wt%; about 10.3 wt%; about 10.4 wt%; about 10.5 wt%; about 10.6 wt%; about 10.7 wt%; about 10.8 wt%; about 10.9 wt%; about 11.0 wt%; about 11.1 wt%; about 11.2 wt%; about 11.3 wt%; about 11.4 wt%; about 11.5 wt%; about 11.6 wt%; about 11.7 wt%; about 11.8 wt%; about 11.9 wt%; about 12.0 wt%; about 12.1 wt%; about 12.2 wt%; about 12.3 wt%; about 12.4 wt%; about 12.5 wt%; about 12.6 wt%; about 12.7 wt%; about 12.8 wt%; about 12.9 wt%; about 13.0 wt%; about 13.1 wt%; about 13.2 wt%; about 13.3 wt%; about 13.4 wt%; about 13.5 wt%; about 13.6 wt%; about 13.7 wt%; about 13.8 wt%; about 13.9 wt%; about 14.0 wt%; about 14.1 wt%; about 14.2 wt%; about 14.3 wt%; about 14.4 wt%; about 14.5 wt%; about 14.6 wt%; about 14.7 wt%; about 14.8 wt%; about 14.9 wt%; about 15.0 wt%; about 15.1 wt%; about 15.2 wt%; about 15.3 wt%; about 15.4 wt%; about 15.5 wt%; about 15.6 wt%; about 15.7 wt%; about 15.8 wt%; about 15.9 wt%; about 16.0 wt%; about 16.1 wt%; about 16.2 wt%; about 16.3 wt%; about 16.4 wt%; about 16.5 wt%; about 16.6 wt%; about 16.7 wt%; about 16.8 wt%; about 16.9 wt%; about 17.0 wt%; about 17.1 wt%; about 17.2 wt%; about 17.3 wt%; about 17.4 wt%; about 17.5 wt%; about 17.6 wt%; about 17.7 wt%; about 17.8 wt%; about 17.9 wt%; about 18.0 wt%; about 18.1 wt%; about 18.2 wt%; about 18.3 wt%; about 18.4 wt%; about 18.5 wt%; about 18.6 wt%; about 18.7 wt%; about 18.8 wt%; about 18.9 wt%; about 19.0 wt%; about 19.1 wt%; about 19.2 wt%; about 19.3 wt%; about 19.4 wt%; about 19.5 wt%; about 19.6 wt%; about 19.7 wt%; about 19.8 wt%; about 19.9 wt%; about 20.0 wt%; about 20.1 wt%; about 20.2 wt%; about 20.3 wt%; about 20.4 wt%; about 20.5 wt%; about 20.6 wt%; about 20.7 wt%; about 20.8 wt%; about 20.9 wt%; about 21.0 wt%; about 21.1 wt%; about 21.2 wt%; about 21.3 wt%; about 21.4 wt%; about 21.5 wt%; about 21.6 wt%; about 21.7 wt%; about 21.8 wt%; about 21.9 wt%; about 22.0 wt%; about 22.1 wt%; about 22.2 wt%; about 22.3 wt%; about 22.4 wt%; about 22.5 wt%; about 22.6 wt%; about 22.7 wt%; about 22.8 wt%; about 22.9 wt%; about 23.0 wt%; about 23.1 wt%; about 23.2 wt%; about 23.3 wt%; about 23.4 wt%; about 23.5 wt%; about 23.6 wt%; about 23.7 wt%; about 23.8 wt%; about 23.9 wt%; about 24.0 wt%; about 24.1 wt%; about 24.2 wt%; about 24.3 wt%; about 24.4 wt%; about 24.5 wt%; about 24.6 wt%; about 24.7 wt%; about 24.8 wt%; about 24.9 wt%; about 25.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the cooling material can be present in an amount of about 0.2 wt% to about 2 wt% cooling material; about 0.02 wt% to about 0.07 wt% of a cooling compound; a cooling salt, or a combination thereof, is present in the cooling composition in an amount of about 0.001 wt% to about 0.02 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In yet further aspects, the cooling material can be about 0.5 wt% to about 1 wt% of the cooling material based on the total weight of the polymer and the cooling composition; about 0.03 wt% to about 0.05 wt% of a cooling compound; a cooling salt, or a combination thereof, is present in the cooling composition in an amount of about 0.001 wt% to about 0.01 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In still further aspects, the cooling material can be present in an amount of about 0.2 wt% to about 2 wt% cooling material; about 0.02 wt% to about 0.07 wt% of a cooling compound; and about 0.001 wt% to about 0.02 wt% of a cooling salt is present in the cooling composition; and wherein wt% is based on the total weight of the polymer and the cooling composition. In even further aspects, the cooling material can be present in an amount of about 0.5 wt% to about 1 wt% of the cooling material; about 0.03 wt% to about 0.05 wt% of a cooling compound; and about 0.001 wt% to about 0.01 wt% of a cooling salt is present in the cooling composition; and wherein wt% is based on the total weight of the polymer and the cooling composition.

In further aspects, the cooling material can be present in an amount of about 3.0 wt% to about 10.0 wt% cooling material; about 5.0 wt% to about 12.0 wt% of a cooling compound; a cooling salt, or a combination thereof, is present in the cooling composition in an amount of about 0.3 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In yet further aspects, the cooling material can be about 4.0 wt% to about 8.0 wt% of the cooling material based on the total weight of the polymer and the cooling composition; about 5.5 wt% to about 11.0 wt% of a cooling compound; a cooling salt, or a combination thereof, is present in the cooling composition in an amount of about 0.4 wt% to about 3.0 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In still further aspects, the cooling material can be present in an amount of about 4.5 wt% to about 7.7 wt% cooling material; about 5.9 wt% to about 11.0 wt% of a cooling compound; and about 0.4 wt% to about 2.5 wt% of a cooling salt is present in the cooling composition; and wherein wt% is based on the total weight of the polymer and the cooling composition. In even further aspects, the cooling material can be present in an amount of about 5.0 wt% to about 7.2 wt% cooling material; about 6.4 wt% to about 10.5 wt% of a cooling compound; and about 0.5 wt% to about 2.1 wt% of a cooling salt is present in the cooling composition; and wherein wt% is based on the total weight of the polymer and the cooling composition. In still further aspects, the cooling material can be present in an amount of about 5.0 wt% to about 7.0 wt% cooling material; about 6.7 wt% to about 10.0 wt% of a cooling compound; and about 0.59 wt% to about 2.0 wt% of a cooling salt is present in the cooling composition; and wherein wt% is based on the total weight of the polymer and the cooling composition.

In further aspects, the cooling material can be present in the cooling composition in an amount from about 0.2 wt% to about 2 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In yet further aspects, the cooling material can be present in an amount of about 0.4 wt% to about 1 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In yet further aspects, the cooling material can be present in an amount of about 0.5 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition.

In further aspects, the cooling material can be present in the cooling composition in an amount from about 3.0 wt% to about 10.0 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In yet further aspects, the cooling material can be present in an amount of about 4.0 wt% to about 8.0 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In yet further aspects, the cooling material can be present in an amount of about 4.5 wt% to about 7.7 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In yet further aspects, the cooling material can be present in an amount of about 5.0 wt% to about 7.2 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition. In even further aspects, the cooling material can be present in an amount of about 5.0 wt% to about 7.0 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition.

In a further aspect, the cooling material can be about 0.20 wt% based on the total weight of the polymer and the cooling composition; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values may be utilized in the cooling composition.

In a further aspect, the cooling material can be about 4.0 wt% based on the total weight of the polymer and the cooling composition; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%, about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%, about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values may be utilized in the cooling composition.

In various aspects, the cooling material comprises a metal, a metal alloy, a metal oxide, a carbon material, a ceramic material, a mineral, or a combination thereof.

In a further aspect, the cooling material comprises a metal oxide. Exemplary, but non-limiting, metal oxides that can be used to prepare the cooling material include metal oxides comprising gold (II) oxide, gold (III) oxide, silver (I) oxide, silver (II) oxide, silver (I, III) oxide, magnesium oxide, iron (II) oxide, iron (III) oxide, copper (I) oxide, copper (II) oxide, or combinations thereof. In yet further aspects, the metal oxide comprises silver (I) oxide, copper (II) oxide, or a combination thereof. In yet further aspects, the metal oxide comprises silver (I) oxide. In even further aspects, the metal oxide can be a mixture comprising two or more metal oxides.

In a further aspect, the cooling material comprises a mineral. Exemplary, but non-limiting, minerals that can be used in the disclosed cooling compositions include minerals comprising silicon, zirconium, titanium, or combinations thereof. For example, the zirconium-containing mineral may be alloneite, baddeleyite, eudikite, ytalitanite, menezite, or combinations thereof. In still further aspects, the titanium-containing mineral may be rutile (rutile), ilmenite (ilmenite), titanite (titanite), anatase (anatase), brookite (brookite), or a combination thereof. In yet further aspects, the silicon containing mineral is quartz, granite (granite), chalcedony (chalcedony), chlorimuron (chrysospase), garnet (garnet), beryllite (phenacite), olivine (olivine), mica, kaolinite (kaolinite), feldspar (feldspar), zeolite (zeolite), carnallite (carnelian), agate (agate), onyx (onyx), jasper (jasper), hengliote (heliotrope), flint (flint), or a combination thereof. In some cases, the mineral may contain both zirconium and titanium, including minerals such as calciumzirconate (calzirtite), ledikite (kobeite), peat rock (lakargite), brevitite (lindsleyite), cerolite (loveringite), alkaline ferntianite (mathiasite), tazzerite (tazzerite), zircon (zirconia), perovskite (zircolite), zirconolite (zirkelite), or combinations thereof.

In further aspects, the cooling material comprises a ceramic comprising alumina, aluminum titanate, zirconia, aluminum nitride, silicon carbide, silicon nitride, silicon aluminum nitride, or a combination thereof.

In further aspects, the cooling material comprises a metal, such as silver, aluminum, copper, or a combination thereof. In yet further aspects, the metal can comprise silver. In yet further aspects, the metal can include copper. In even further aspects, the metal can comprise a mixture of copper and silver. In various aspects, the metal can be a mixture comprising two or more metals.

In a further aspect, the cooling material comprises a metal alloy comprising silver, aluminum, copper, or a combination thereof. In yet further aspects, the metal alloy can comprise silver. In yet further aspects, the metal alloy may comprise copper. In even further aspects, the metal alloy can comprise a mixture of copper and silver. In various aspects, the metal alloy can be a mixture comprising two or more metal alloys.

In various aspects, the cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combination thereof may be in a form that facilitates incorporation into the cooled polymer composition, such as in the form of a powder, wire, filament, sheet, particle, or combination thereof. In other cases, the cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combinations thereof may be in the form of particles, powder, or combinations thereof. In some cases, the cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combination thereof is in the form of particles, including such forms as nanoparticles, microparticles, or a combination (or mixture) thereof.

In a further aspect, the cooling material comprises a metal, a metal alloy, a metal oxide, a carbon material, a ceramic material, a mineral, or a combination thereof, comprising nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the nanoparticles have a size of about 15nm to about 50 nm. In yet further aspects, the nanoparticles have a size of about 20nm to about 40 nm. In an even further aspect, the nanoparticles have a particle size of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a size utilizing any collection of the foregoing values.

In further aspects, the cooling material is a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combinations thereof, including particulates. The particulates in the cooling material may have a diameter of about 10 μm to about 200 μm; about 20 μm to about 100 μm; about 30 μm to about 90 μm; about 40 μm to about 80 μm; a size of about 50 μm to about 70 μm; a dimension or a collection of dimensions within any of the foregoing ranges or sub-ranges within the foregoing ranges.

In further aspects, the cooling compound can be present in an amount of about 0.02 wt% to about 0.07 wt%; about 0.03 wt% to about 0.07 wt%; about 0.03 wt% to about 0.06 wt%; present in the cooled polymer composition in an amount of from about 0.03 wt% to about 0.05 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition; and wherein wt% is based on the total weight of the polymer and the cooling composition.

In a further aspect, the cooling compound can be about 0.020 wt% based on the total weight of the polymer and the cooling composition; 0.025 wt%; about 0.030 wt%; about 0.035 wt%; about 0.040 wt%; about 0.045 wt%; about 0.050 wt%; about 0.055 wt%; about 0.060 wt%; about 0.065 wt%; about 0.070 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values may be utilized in the amount present in the cooled polymer composition.

In further aspects, the cooling compound can be present at 5.0 wt% to about 12.0 wt%; about 5.5 wt% to about 11.0 wt%; about 5.9 wt% to about 11.0 wt%; about 6.4 wt% to about 10.5 wt%; present in the cooled polymer composition in an amount of from about 6.7 wt% to about 10.0 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition.

In a further aspect, the cooling compound can be about 5.0 wt% based on the total weight of the polymer and the cooling composition; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; about 10.1 wt%; about 10.2 wt%; about 10.3 wt%; about 10.4 wt%; about 10.5 wt%; about 10.6 wt%; about 10.7 wt%; about 10.8 wt%; about 10.9 wt%; about 11.0 wt%; about 11.1 wt%; about 11.2 wt%; about 11.3 wt%; about 11.4 wt%; about 11.5 wt%; about 11.6 wt%; about 11.7 wt%; about 11.8 wt%; about 11.9 wt%; about 12.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values may be utilized in the amount present in the cooled polymer composition.

The cooling compound may include a transition metal oxide, a group 13 oxide, a group 14 oxide, a group 13 carbide, a group 14 carbide, or a mixture thereof. In some cases, the cooling compound can include alumina, silicon carbide, silicon dioxide, titanium oxide, titanium dioxide, titanium trioxide, zirconium dioxide, or a combination thereof. In further aspects, the cooling compound can include alumina, silica, titania, or a combination thereof. In yet further aspects, the cooling compound can include titanium dioxide. The cooling compound may be in the form of a powder, granules, or a combination thereof. In further aspects, the cooling compound can be in the form of particles, such as nanoparticles, microparticles, or a combination thereof.

In various aspects, the cooling compound can be in a form that facilitates incorporation into the cooled polymer composition, such as in the form of a powder, a thread, a filament, a sheet, a granule, or a combination thereof. In other cases, the cooling compound can be in the form of granules, a powder, or a combination thereof. In some cases, the cooling compound is in the form of particles, including, for example, nanoparticles, microparticles, or a combination thereof.

In various aspects, the cooling compound comprises a particulate form of the cooling compound and has a particle size of about 10 μm to about 200 μm; about 20 μm to about 100 μm; about 30 μm to about 90 μm; about 40 μm to about 80 μm; or from about 50 μm to about 70 μm; or a sub-range within any of the preceding ranges.

In a further aspect, the cooling compound comprises a particulate form of the cooling compound and has a particle size of about 10 μm; about 20 μm; about 30 μm; about 40 μm; about 50 μm; about 60 μm; about 70 μm; about 80 μm; about 90 μm; about 100 μm; about 110 μm; about 120 μm; about 130 μm; about 140 μm; about 150 μm; about 160 μm; about 170 μm; about 180 μm; about 190 μm; about 200 μm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any collection of values utilizing the foregoing values.

In a further aspect, the cooling compound can include nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the cooling compound can include nanoparticles having a size of about 15nm to about 50 nm. In yet further aspects, the cooling compound can include nanoparticles having a size of about 20nm to about 40 nm. In even further aspects, the cooling compound can include a compound having a wavelength of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or nanoparticles of a size utilizing any collection of the foregoing values.

In various aspects, the cooling composition comprises an antioxidant in an amount of about 0.001 wt% to about 0.02 wt%, based on the total weight of the polymer and the cooling composition; about 0.001 wt% to about 0.01 wt%; about 0.002 wt% to about 0.01 wt%; or any subrange within the foregoing range.

In a further aspect, the cooling composition comprises an antioxidant in an amount of about 0.001 wt%, based on the total weight of the polymer and the cooling composition; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.02 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or cooling salt present in an amount utilizing any collection of the foregoing values.

In various aspects, the cooling composition comprises an antioxidant in an amount of about 0.3 wt% to about 4.0 wt%, based on the total weight of the polymer and the cooling composition; about 0.4 wt% to about 3.0 wt%; about 0.4 wt% to about 2.5 wt%; about 0.5 wt% to about 2.1 wt%; about 0.59 wt% to about 2.0 wt%; or any subrange within the foregoing range.

In a further aspect, the cooling composition comprises an antioxidant in an amount of about 0.40 wt%, based on the total weight of the polymer and the cooling composition; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or cooling salt present in an amount utilizing any collection of the foregoing values.

The cooling composition comprises a cooling salt comprising a transition metal salt, a group I salt, a group II salt, or a combination thereof. In some cases, the cooling salt is a group I salt. In other cases, the cooling salt is a group II salt. In other cases, the cooling salt is a transition metal salt. The cooling salt may include a group I carbonate, a group I halide, a group I nitrate, or a combination thereof. Alternatively, the cooling salt may include a group II carbonate, a group II halide, a group II nitrate, or a combination thereof. In further aspects, the cooling salt can include a transition metal carbonate, a transition metal halide, a transition metal nitrate, or a combination thereof. In some cases, the salt includes a transition metal carbonate, a group I carbonate, a group II carbonate, or a combination thereof. In a particular aspect, the salt comprises calcium carbonate.

In various aspects, the cooling salt can be in a form that facilitates incorporation into the cooled polymer composition, such as in the form of a powder, a thread, a filament, a sheet, a granule, or a combination thereof. In other cases, the cooling salt may be in the form of granules, powder, or a combination thereof. In some cases, the cooling salt is in the form of particles, including, for example, nanoparticles, microparticles, or a combination thereof.

The cooling salt in the cooling composition may be in the form of a powder, granules, or a combination thereof. In some aspects, the cooling salt in the cooling composition comprises particles having a size of about 10 μm to about 1000 μm. In a further aspect, the salt in the cooling composition comprises particles having a size of about 30 μm to about 500 μm.

In various aspects, the cooling salt in the cooling composition comprises a salt having a particle size of about 10 μm; about 20 μm; about 30 μm; about 40 μm; about 50 μm; about 60 μm; about 70 μm; about 80 μm; about 90 μm; about 100 μm; 110 μm; about 120 μm; about 130 μm; about 140 μm; about 150 μm; about 160 μm; about 170 μm; about 180 μm; about 190 μm; about 200 μm; 210 μm; about 220 μm; about 230 μm; about 240 μm; about 250 μm; about 260 μm; about 270 μm; about 280 μm; about 290 μm; about 300 μm; 310 μm; about 320 μm; about 330 μm; about 340 μm; about 350 μm; about 360 μm; about 370 μm; about 380 μm; about 390 μm; about 400 μm; 410 mu m; about 420 μm; about 430 μm; about 440 μm; about 450 μm; about 460 μm; about 470 μm; about 480 μm; about 490 μm; about 500 μm; about 550 μm; about 600 μm; about 650 μm; about 700 μm; about 750 μm; about 800 μm; about 850 μm; about 900 μm; about 950 μm; about 1000 μm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or particles of a size utilizing any collection of the foregoing values.

In a further aspect, the cooling salt may include nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the cooling salt can include nanoparticles having a size of about 15nm to about 50 nm. In yet further aspects, the cooling salt can include nanoparticles having a size of about 20nm to about 40 nm. In even further aspects, the cooling salt can comprise a salt having a wavelength of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or nanoparticles of a size utilizing any collection of the foregoing values.

C. And (3) compounding the yarns.

In one aspect, the present disclosure relates to a composite yarn comprising a core component and a sheath layer, which may be used to make a double covered yarn or used to weave or knit a fabric. More specifically, in one aspect, the present disclosure relates to a composite yarn comprising a core component and a sheath layer, wherein: (a) the core member comprises a polyester polymer and a first cooling composition; and (b) the sheath comprises a polyamide polymer and a second cooling composition; wherein the first cooling composition comprises a first cooling material, a first cooling compound, a first cooling salt, or a combination thereof; and wherein the second cooling composition comprises a second cooling material, a second cooling compound, and a second cooling salt.

In various aspects, the disclosed composite yarns comprise from about 20 wt% to about 80 wt% polyester polymer and from about 80 wt% to about 20 wt% polyamide polymer, based on the total weight of the composite yarn. In a further aspect, the disclosed composite yarn comprises from about 50 wt% to about 70 wt% polyester polymer and from about 50 wt% to about 30 wt% polyamide polymer, based on the total weight of the composite yarn. In still further aspects, the disclosed composite yarn comprises from about 55 wt% to about 65 wt% of the polyester polymer and from about 45 wt% to about 35 wt% of the polyamide polymer, based on the total weight of the composite yarn. In still further aspects, the disclosed composite yarn comprises from about 57 wt% to about 63 wt% of the polyester polymer and from about 43 wt% to about 37 wt% of the polyamide polymer, based on the total weight of the composite yarn. The disclosed composite yarn comprises from about 58 wt% to about 62 wt% of a polyester polymer and from about 42 wt% to about 38 wt% of a polyamide polymer, based on the total weight of the composite yarn.

In a further aspect, the disclosed composite yarn comprises a blend of at least about 20 wt% based on the total weight of the composite yarn; about 21 wt%; about 22 wt%; about 23 wt%; about 24 wt%; about 25 wt%; about 26 wt%; about 27 wt%; about 28 wt%; about 29 wt%; about 30 wt%; about 31 wt%; about 32 wt%; about 33 wt%; about 34 wt%; about 35 wt%; about 36 wt%; about 37 wt%; about 38 wt%; about 39 wt%; about 40 wt%; about 41 wt%; about 42 wt%; about 43 wt%; about 44 wt%; about 45 wt%; about 46 wt%; about 47 wt%; about 48 wt%; about 49 wt%; about 50 wt%; about 51 wt%; about 52 wt%; about 53 wt%; about 54 wt%; about 55 wt%; about 56 wt%; about 57 wt%; about 58 wt%; about 59 wt%; about 60 wt%; about 61 wt%; about 62 wt%; about 63 wt%; about 64 wt%; about 65 wt%; about 66 wt%; about 67 wt%; about 68 wt%; about 69 wt%; about 70 wt%; about 71 wt%; about 72 wt%; about 73 wt%; about 74 wt%; about 75 wt%; about 76 wt%; about 77 wt%; about 78 wt%; about 79 wt%; about 80 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a weight percent amount utilizing a set of any of the foregoing values, provided that the total weight percent of polyamide polymer and polyester polymer in the composite is from about 80 wt% to about 100 wt%.

In a further aspect, the disclosed composite yarn comprises a blend of at least about 20 wt% based on the total weight of the composite yarn; about 21 wt%; about 22 wt%; about 23 wt%; about 24 wt%; about 25 wt%; about 26 wt%; about 27 wt%; about 28 wt%; about 29 wt%; about 30 wt%; about 31 wt%; about 32 wt%; about 33 wt%; about 34 wt%; about 35 wt%; about 36 wt%; about 37 wt%; about 38 wt%; about 39 wt%; about 40 wt%; about 41 wt%; about 42 wt%; about 43 wt%; about 44 wt%; about 45 wt%; about 46 wt%; about 47 wt%; about 48 wt%; about 49 wt%; about 50 wt%; about 51 wt%; about 52 wt%; about 53 wt%; about 54 wt%; about 55 wt%; about 56 wt%; about 57 wt%; about 58 wt%; about 59 wt%; about 60 wt%; about 61 wt%; about 62 wt%; about 63 wt%; about 64 wt%; about 65 wt%; about 66 wt%; about 67 wt%; about 68 wt%; about 69 wt%; about 70 wt%; about 71 wt%; about 72 wt%; about 73 wt%; about 74 wt%; about 75 wt%; about 76 wt%; about 77 wt%; about 78 wt%; about 79 wt%; about 80 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a weight percent amount utilizing a set of any of the foregoing values, provided that the total weight percent of polyamide polymer and polyester polymer in the composite is from about 80 weight percent to about 100 weight percent.

In various aspects, the polyester polymer is polyethylene terephthalate, polypropylene terephthalate, or a combination thereof. In a further aspect, the polyester polymer is polyethylene terephthalate. In yet a further aspect, the polyester polymer is poly (trimethylene terephthalate).

In various aspects, the polyamide polymer can include nylon 6, nylon 4/6, nylon 6/6, nylon 6/10, nylon 6/12, nylon 11, nylon 12, or a combination thereof. In further aspects, the polyamide polymer can include nylon 6, nylon 6/6, nylon 6/12, or a combination thereof. In still further aspects, the polyamide polymer can include nylon 6/6.

Referring now to fig. 1A-1D, representative schematic diagrams of the disclosed composite yarns are shown. Fig. 1A shows a side cross-sectional view of a portion of the disclosed composite yarn, as well as a cross-sectional view of an end thereof. An enlarged view of the cross-sectional end view is highlighted. Key information indicating the grey scale color associated with the distribution of the sheath, core and one or more cooling compositions in each of the sheath and core is shown below the view. Fig. 1B shows a cross-sectional view of the disclosed composite yarn 100, with the following designated aspects: a polyester core 110; a first cooling composition 112; a polyamide sheath 115; and a second cooling composition 117. Fig. 1C shows a cross-sectional view of the disclosed composite yarn 120, with the following designated aspects: a polyester core 110; a polyamide sheath 115; and a second cooling composition 117. Fig. 1D shows a cross-sectional view of a disclosed composite yarn 130, with the following designated aspects: a polyester core 110; a first cooling composition 112; and a polyamide sheath 115.

In one aspect, the first cooling composition can be present in an amount of about 0.001 wt% to about 5 wt%, based on the total weight of the polyester polymer and the first cooling composition. In a further aspect, the first cooling composition can be about 0.001 wt% based on the total weight of the polyester polymer and the first cooling composition; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the first cooling composition can be present in an amount of about 5.0 wt% to about 25 wt%, based on the total weight of the polyester polymer and the first cooling composition. In a further aspect, the first cooling composition can be about 5.0 wt% based on the total weight of the polyester polymer and the first cooling composition; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; about 10.1 wt%; about 10.2 wt%; about 10.3 wt%; about 10.4 wt%; about 10.5 wt%; about 10.6 wt%; about 10.7 wt%; about 10.8 wt%; about 10.9 wt%; about 11.0 wt%; about 11.1 wt%; about 11.2 wt%; about 11.3 wt%; about 11.4 wt%; about 11.5 wt%; about 11.6 wt%; about 11.7 wt%; about 11.8 wt%; about 11.9 wt%; about 12.0 wt%; about 12.1 wt%; about 12.2 wt%; about 12.3 wt%; about 12.4 wt%; about 12.5 wt%; about 12.6 wt%; about 12.7 wt%; about 12.8 wt%; about 12.9 wt%; about 13.0 wt%; about 13.1 wt%; about 13.2 wt%; about 13.3 wt%; about 13.4 wt%; about 13.5 wt%; about 13.6 wt%; about 13.7 wt%; about 13.8 wt%; about 13.9 wt%; about 14.0 wt%; about 14.1 wt%; about 14.2 wt%; about 14.3 wt%; about 14.4 wt%; about 14.5 wt%; about 14.6 wt%; about 14.7 wt%; about 14.8 wt%; about 14.9 wt%; about 15.0 wt%; about 15.1 wt%; about 15.2 wt%; about 15.3 wt%; about 15.4 wt%; about 15.5 wt%; about 15.6 wt%; about 15.7 wt%; about 15.8 wt%; about 15.9 wt%; about 16.0 wt%; about 16.1 wt%; about 16.2 wt%; about 16.3 wt%; about 16.4 wt%; about 16.5 wt%; about 16.6 wt%; about 16.7 wt%; about 16.8 wt%; about 16.9 wt%; about 17.0 wt%; about 17.1 wt%; about 17.2 wt%; about 17.3 wt%; about 17.4 wt%; about 17.5 wt%; about 17.6 wt%; about 17.7 wt%; about 17.8 wt%; about 17.9 wt%; about 18.0 wt%; about 18.1 wt%; about 18.2 wt%; about 18.3 wt%; about 18.4 wt%; about 18.5 wt%; about 18.6 wt%; about 18.7 wt%; about 18.8 wt%; about 18.9 wt%; about 19.0 wt%; about 19.1 wt%; about 19.2 wt%; about 19.3 wt%; about 19.4 wt%; about 19.5 wt%; about 19.6 wt%; about 19.7 wt%; about 19.8 wt%; about 19.9 wt%; about 20.0 wt%; about 20.1 wt%; about 20.2 wt%; about 20.3 wt%; about 20.4 wt%; about 20.5 wt%; about 20.6 wt%; about 20.7 wt%; about 20.8 wt%; about 20.9 wt%; about 21.0 wt%; about 21.1 wt%; about 21.2 wt%; about 21.3 wt%; about 21.4 wt%; about 21.5 wt%; about 21.6 wt%; about 21.7 wt%; about 21.8 wt%; about 21.9 wt%; about 22.0 wt%; about 22.1 wt%; about 22.2 wt%; about 22.3 wt%; about 22.4 wt%; about 22.5 wt%; about 22.6 wt%; about 22.7 wt%; about 22.8 wt%; about 22.9 wt%; about 23.0 wt%; about 23.1 wt%; about 23.2 wt%; about 23.3 wt%; about 23.4 wt%; about 23.5 wt%; about 23.6 wt%; about 23.7 wt%; about 23.8 wt%; about 23.9 wt%; about 24.0 wt%; about 24.1 wt%; about 24.2 wt%; about 24.3 wt%; about 24.4 wt%; about 24.5 wt%; about 24.6 wt%; about 24.7 wt%; about 24.8 wt%; about 24.9 wt%; about 25.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the first cooling material can be present in an amount of about 0.2 wt% to about 2 wt% of the first cooling material; about 0.02 wt% to about 0.07 wt% of a first cooling compound; from about 0.001 wt% to about 0.02 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In yet further aspects, the first cooling material can be about 0.5 wt% to about 1 wt% of the first cooling material based on the total weight of the polyester polymer and the first cooling composition; about 0.03 wt% to about 0.05 wt% of a first cooling compound; from about 0.001 wt% to about 0.01 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In still further aspects, the first cooling material can be present in an amount of about 0.2 wt% to about 2 wt% of the first cooling material; about 0.02 wt% to about 0.07 wt% of a first cooling compound; and the first cooling salt is present in the first cooling composition in an amount from about 0.001 wt% to about 0.02 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In even further aspects, the first cooling material can be present in an amount of about 0.5 wt% to about 1 wt% of the first cooling material; about 0.03 wt% to about 0.05 wt% of a first cooling compound; and the first cooling salt is present in the first cooling composition in an amount from about 0.001 wt% to about 0.01 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition.

In further aspects, the first cooling material can be present in an amount of about 3.0 wt% to about 10.0 wt% of the first cooling material; about 5.0 wt% to about 12.0 wt% of a first cooling compound; from about 0.3 wt% to about 4.0 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In yet further aspects, the first cooling material can be about 4.0 wt% to about 8.0 wt% of the first cooling material based on the total weight of the polyester polymer and the first cooling composition; about 5.5 wt% to about 11.0 wt% of a first cooling compound; from about 0.4 wt% to about 3.0 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In still further aspects, the first cooling material can be present in an amount of about 4.5 wt% to about 7.7 wt% of the first cooling material; about 5.9 wt% to about 11.0 wt% of a first cooling compound; and the amount of the first cooling salt present in the first cooling composition is from about 0.4 wt% to about 2.5 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In even further aspects, the first cooling material can be present in an amount of about 5.0 wt% to about 7.2 wt% of the first cooling material; about 6.4 wt% to about 10.5 wt% of a first cooling compound; and the first cooling salt is present in the first cooling composition in an amount from about 0.5 wt% to about 2.1 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In still further aspects, the first cooling material can be present in an amount of about 5.0 wt% to about 7.0 wt% of the first cooling material; about 6.7 wt% to about 10.0 wt% of a first cooling compound; and the first cooling salt is present in the first cooling composition in an amount from about 0.59 wt% to about 2.0 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition.

In further aspects, the first cooling material can be present in the first cooling composition in an amount from about 0.2 wt% to about 2 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In yet further aspects, the first cooling material can be present in an amount of about 0.4 wt% to about 1 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In still further aspects, the first cooling material can be present in an amount of about 0.5 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition.

In further aspects, the first cooling material can be present in the first cooling composition in an amount from about 3.0 wt% to about 10.0 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In yet further aspects, the first cooling material can be present in an amount of about 4.0 wt% to about 8.0 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In yet further aspects, the first cooling material can be present in an amount of about 4.5 wt% to about 7.7 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In yet further aspects, the first cooling material can be present in an amount of about 5.0 wt% to about 7.2 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition. In even further aspects, the first cooling material can be present in an amount of about 5.0 wt% to about 7.0 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition.

In a further aspect, the first cooling material can be about 0.20 wt% based on the total weight of the polyester polymer and the first cooling composition; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In a further aspect, the first cooling material can be about 4.0 wt% based on the total weight of the polyester polymer and the first cooling composition; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%, about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%, about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In various aspects, the first cooling material comprises a metal, a metal alloy, a metal oxide, a carbon material, a ceramic material, a mineral, or a combination thereof.

In a further aspect, the first cooling material comprises a metal oxide. Exemplary, but non-limiting, metal oxides that can be used to prepare the first cooling material include metal oxides comprising gold (II) oxide, gold (III) oxide, silver (I) oxide, silver (II) oxide, silver (I, III) oxide, magnesium oxide, iron (II) oxide, iron (III) oxide, copper (I) oxide, copper (II) oxide, or combinations thereof. In yet further aspects, the metal oxide comprises silver (I) oxide, copper (II) oxide, or a combination thereof. In yet further aspects, the metal oxide comprises silver (I) oxide. In even further aspects, the metal oxide can be a mixture comprising two or more metal oxides.

In a further aspect, the first cooling material comprises a mineral. Exemplary, but non-limiting, minerals that can be used in the disclosed cooling compositions include minerals comprising silicon, zirconium, titanium, or combinations thereof. For example, the zirconium-containing mineral may be alloneite, baddeleyite, heterite, ytalitanite, menezesite, or combinations thereof. In still further aspects, the titanium-containing mineral may be rutile, ilmenite, sphene, anatase, brookite, or a combination thereof. In yet further aspects, the silicon-containing mineral is quartz, granite, chalcedony, emerald, garnet, beryllite, olivine, mica, kaolinite, feldspar, zeolite, carnallite, agate, onyx, jasper, henry, flint, or a combination thereof. In some cases, the minerals may contain both zirconium and titanium, including minerals such as calciumzirconite, gazelite, peat, brewsterite, cerotaite, Alstrantitite, tatzgite, zircon, perovskite, zirconolite, or combinations thereof.

In further aspects, the first cooling material comprises a ceramic comprising alumina, aluminum titanate, zirconia, aluminum nitride, silicon carbide, silicon nitride, silicon aluminum nitride, or a combination thereof.

In further aspects, the first cooling material comprises a metal, such as silver, aluminum, copper, or a combination thereof. In yet further aspects, the metal can comprise silver. In yet further aspects, the metal can include copper. In even further aspects, the metal can comprise a mixture of copper and silver. In various aspects, the metal can be a mixture comprising two or more metals.

In further aspects, the first cooling material comprises a metal alloy comprising silver, aluminum, copper, or a combination thereof. In yet further aspects, the metal alloy can comprise silver. In yet further aspects, the metal alloy may comprise copper. In even further aspects, the metal alloy can comprise a mixture of copper and silver. In various aspects, the metal alloy can be a mixture comprising two or more metal alloys.

In various aspects, the first cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combination thereof may be in a form that facilitates incorporation into the first cooling polymer composition, such as in the form of a powder, a thread, a filament, a sheet, a particle, or a combination thereof. In other cases, the first cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combination thereof may be in the form of particles, powder, or combination thereof. In some cases, the first cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combination thereof is in the form of particles, including such forms as nanoparticles, microparticles, or a combination (or mixture) thereof.

In a further aspect, the first cooling material comprises a metal, a metal alloy, a metal oxide, a carbon material, a ceramic material, a mineral, or a combination thereof, comprising nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the nanoparticles have a size of about 15nm to about 50 nm. In yet further aspects, the nanoparticles have a size of about 20nm to about 40 nm. In an even further aspect, the nanoparticles have a particle size of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a size utilizing any collection of the foregoing values.

In further aspects, the first cooling material is a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combinations thereof, including particulates. The particulates in the first cooling material may have a diameter of about 10 μm to about 200 μm; about 20 μm to about 100 μm; about 30 μm to about 90 μm; about 40 μm to about 80 μm; a size of about 50 μm to about 70 μm; a dimension or a collection of dimensions within any of the foregoing ranges or sub-ranges within the foregoing ranges.

In further aspects, the first cooling compound can be present in an amount from about 0.02 wt% to about 0.07 wt%; about 0.03 wt% to about 0.07 wt%; about 0.03 wt% to about 0.06 wt%; present in the first cooled polymer composition in an amount of from about 0.03 wt% to about 0.05 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition.

In a further aspect, the first cooling compound can be about 0.020 wt% based on the total weight of the polyester polymer and the first cooling composition; 0.025 wt%; about 0.030 wt%; about 0.035 wt%; about 0.040 wt%; about 0.045 wt%; about 0.050 wt%; about 0.055 wt%; about 0.060 wt%; about 0.065 wt%; about 0.070 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized to provide the first cooled polymer composition.

In further aspects, the first cooling compound can be present at 5.0 wt% to about 12.0 wt%; about 5.5 wt% to about 11.0 wt%; about 5.9 wt% to about 11.0 wt%; about 6.4 wt% to about 10.5 wt%; present in the first cooled polymer composition in an amount of from about 6.7 wt% to about 10.0 wt%; and wherein wt% is based on the total weight of the polyester polymer and the first cooling composition.

In a further aspect, the first cooling compound can be about 5.0 wt% based on the total weight of the polyester polymer and the first cooling composition; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; about 10.1 wt%; about 10.2 wt%; about 10.3 wt%; about 10.4 wt%; about 10.5 wt%; about 10.6 wt%; about 10.7 wt%; about 10.8 wt%; about 10.9 wt%; about 11.0 wt%; about 11.1 wt%; about 11.2 wt%; about 11.3 wt%; about 11.4 wt%; about 11.5 wt%; about 11.6 wt%; about 11.7 wt%; about 11.8 wt%; about 11.9 wt%; about 12.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized to provide the first cooled polymer composition.

The first cooling compound may include a transition metal oxide, a group 13 oxide, a group 14 oxide, a group 13 carbide, a group 14 carbide, or a mixture thereof. In some cases, the first cooling compound can include alumina, silicon carbide, silicon dioxide, titanium oxide, titanium dioxide, titanium trioxide, zirconium dioxide, or a combination thereof. In further aspects, the first cooling compound can include alumina, silica, titania, or a combination thereof. In still further aspects, the first cooling compound can include titanium dioxide. The first cooling compound can be in the form of a powder, granules, or a combination thereof. In further aspects, the first cooling compound can be in the form of particles, such as nanoparticles, microparticles, or a combination thereof.

In various aspects, the first cooling compound can be in a form that facilitates incorporation into the first cooled polymer composition, such as in the form of a powder, a thread, a filament, a sheet, a granule, or a combination thereof. In other cases, the first cooling compound can be in the form of granules, a powder, or a combination thereof. In some cases, the first cooling compound is in the form of particles, including, for example, nanoparticles, microparticles, or a combination thereof.

In aspects, the first cooling compound comprises a particulate form of the first cooling compound and has a particle size of about 10 μm to about 200 μm; about 20 μm to about 100 μm; about 30 μm to about 90 μm; about 40 μm to about 80 μm; or from about 50 μm to about 70 μm; or a sub-range within any of the preceding ranges.

In a further aspect, the first cooling compound comprises a particulate form of the first cooling compound and has a particle size of about 10 μm; about 20 μm; about 30 μm; about 40 μm; about 50 μm; about 60 μm; about 70 μm; about 80 μm; about 90 μm; about 100 μm; about 110 μm; about 120 μm; about 130 μm; about 140 μm; about 150 μm; about 160 μm; about 170 μm; about 180 μm; about 190 μm; about 200 μm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any collection of values utilizing the foregoing values.

In a further aspect, the first cooling compound can include nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the first cooling compound can include nanoparticles having a size of about 15nm to about 50 nm. In still further aspects, the first cooling compound can include nanoparticles having a size of about 20nm to about 40 nm. In even further aspects, the first cooling compound can comprise a material having a wavelength of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or nanoparticles of a size utilizing any collection of the foregoing values.

In various aspects, the first cooling composition comprises an antioxidant in an amount of about 0.001 wt% to about 0.02 wt%, based on the total weight of the polyester polymer and the first cooling composition; about 0.001 wt% to about 0.01 wt%; about 0.002 wt% to about 0.01 wt%; or any subrange within the foregoing range.

In a further aspect, the first cooling composition comprises a polymer blend in an amount of about 0.001 wt%, based on the total weight of the polyester polymer and the first cooling composition; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.02 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or the first cooling salt is present in an amount utilizing any collection of the foregoing values.

In various aspects, the first cooling composition comprises a blend of a polyester polymer and a first cooling composition in an amount of about 0.3 wt% to about 4.0 wt%, based on the total weight of the polyester polymer and the first cooling composition; about 0.4 wt% to about 3.0 wt%; about 0.4 wt% to about 2.5 wt%; about 0.5 wt% to about 2.1 wt%; about 0.59 wt% to about 2.0 wt%; or any subrange within the foregoing range.

In a further aspect, the first cooling composition comprises a second cooling composition comprising a second polymer and a second polymer, wherein the second polymer is present in an amount of about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or the first cooling salt is present in an amount utilizing any collection of the foregoing values.

The first cooling composition includes a first cooling salt that includes a transition metal salt, a group I salt, a group II salt, or a combination thereof. In some cases, the first cooling salt is a group I salt. In other cases, the first cooling salt is a group II salt. In other cases, the first cooling salt is a transition metal salt. The first cooling salt may include a group I carbonate, a group I halide, a group I nitrate, or a combination thereof. Alternatively, the first cooling salt may include a group II carbonate, a group II halide, a group II nitrate, or a combination thereof. In further aspects, the first cooling salt can include a transition metal carbonate, a transition metal halide, a transition metal nitrate, or a combination thereof. In some cases, the salt includes a transition metal carbonate, a group I carbonate, a group II carbonate, or a combination thereof. In a particular aspect, the salt comprises calcium carbonate.

In various aspects, the first cooling salt can be in a form that facilitates incorporation into the first cooled polymer composition, such as in the form of a powder, a thread, a filament, a sheet, a granule, or a combination thereof. In other cases, the first cooling salt may be in the form of granules, a powder, or a combination thereof. In some cases, the first cooling salt is in the form of particles, including, for example, nanoparticles, microparticles, or a combination thereof.

The first cooling salt in the first cooling composition can be in the form of a powder, granules, or a combination thereof. In some aspects, the first cooling salt in the first cooling composition comprises particles having a size of about 10 μm to about 1000 μm. In a further aspect, the salt in the first cooling composition comprises particles having a size of about 30 μm to about 500 μm.

In aspects, the first cooling salt in the first cooling composition comprises a salt having a ph of about 10 μm; about 20 μm; about 30 μm; about 40 μm; about 50 μm; about 60 μm; about 70 μm; about 80 μm; about 90 μm; about 100 μm; 110 μm; about 120 μm; about 130 μm; about 140 μm; about 150 μm; about 160 μm; about 170 μm; about 180 μm; about 190 μm; about 200 μm; 210 μm; about 220 μm; about 230 μm; about 240 μm; about 250 μm; about 260 μm; about 270 μm; about 280 μm; about 290 μm; about 300 μm; 310 μm; about 320 μm; about 330 μm; about 340 μm; about 350 μm; about 360 μm; about 370 μm; about 380 μm; about 390 μm; about 400 μm; 410 mu m; about 420 μm; about 430 μm; about 440 μm; about 450 μm; about 460 μm; about 470 μm; about 480 μm; about 490 μm; about 500 μm; about 550 μm; about 600 μm; about 650 μm; about 700 μm; about 750 μm; about 800 μm; about 850 μm; about 900 μm; about 950 μm; about 1000 μm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or particles of a size utilizing any collection of the foregoing values.

In a further aspect, the first cooling salt can include nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the first cooling salt can include nanoparticles having a size of about 15nm to about 50 nm. In yet further aspects, the first cooling salt can include nanoparticles having a size of about 20nm to about 40 nm. In even further aspects, the first cooling salt can comprise a salt having a molecular weight of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or nanoparticles of a size utilizing any collection of the foregoing values.

In one aspect, the second cooling composition can be present in an amount of about 0.001 wt% to about 5 wt%, based on the total weight of the polyamide polymer and the second cooling composition. In a further aspect, the second cooling composition can be about 0.001 wt% based on the total weight of the polyamide polymer and the second cooling composition; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the second cooling composition can be present in an amount of about 5.0 wt% to about 25 wt%, based on the total weight of the polyamide polymer and the second cooling composition. In a further aspect, the second cooling composition can be about 5.0 wt% based on the total weight of the polyamide polymer and the second cooling composition; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; about 10.1 wt%; about 10.2 wt%; about 10.3 wt%; about 10.4 wt%; about 10.5 wt%; about 10.6 wt%; about 10.7 wt%; about 10.8 wt%; about 10.9 wt%; about 11.0 wt%; about 11.1 wt%; about 11.2 wt%; about 11.3 wt%; about 11.4 wt%; about 11.5 wt%; about 11.6 wt%; about 11.7 wt%; about 11.8 wt%; about 11.9 wt%; about 12.0 wt%; about 12.1 wt%; about 12.2 wt%; about 12.3 wt%; about 12.4 wt%; about 12.5 wt%; about 12.6 wt%; about 12.7 wt%; about 12.8 wt%; about 12.9 wt%; about 13.0 wt%; about 13.1 wt%; about 13.2 wt%; about 13.3 wt%; about 13.4 wt%; about 13.5 wt%; about 13.6 wt%; about 13.7 wt%; about 13.8 wt%; about 13.9 wt%; about 14.0 wt%; about 14.1 wt%; about 14.2 wt%; about 14.3 wt%; about 14.4 wt%; about 14.5 wt%; about 14.6 wt%; about 14.7 wt%; about 14.8 wt%; about 14.9 wt%; about 15.0 wt%; about 15.1 wt%; about 15.2 wt%; about 15.3 wt%; about 15.4 wt%; about 15.5 wt%; about 15.6 wt%; about 15.7 wt%; about 15.8 wt%; about 15.9 wt%; about 16.0 wt%; about 16.1 wt%; about 16.2 wt%; about 16.3 wt%; about 16.4 wt%; about 16.5 wt%; about 16.6 wt%; about 16.7 wt%; about 16.8 wt%; about 16.9 wt%; about 17.0 wt%; about 17.1 wt%; about 17.2 wt%; about 17.3 wt%; about 17.4 wt%; about 17.5 wt%; about 17.6 wt%; about 17.7 wt%; about 17.8 wt%; about 17.9 wt%; about 18.0 wt%; about 18.1 wt%; about 18.2 wt%; about 18.3 wt%; about 18.4 wt%; about 18.5 wt%; about 18.6 wt%; about 18.7 wt%; about 18.8 wt%; about 18.9 wt%; about 19.0 wt%; about 19.1 wt%; about 19.2 wt%; about 19.3 wt%; about 19.4 wt%; about 19.5 wt%; about 19.6 wt%; about 19.7 wt%; about 19.8 wt%; about 19.9 wt%; about 20.0 wt%; about 20.1 wt%; about 20.2 wt%; about 20.3 wt%; about 20.4 wt%; about 20.5 wt%; about 20.6 wt%; about 20.7 wt%; about 20.8 wt%; about 20.9 wt%; about 21.0 wt%; about 21.1 wt%; about 21.2 wt%; about 21.3 wt%; about 21.4 wt%; about 21.5 wt%; about 21.6 wt%; about 21.7 wt%; about 21.8 wt%; about 21.9 wt%; about 22.0 wt%; about 22.1 wt%; about 22.2 wt%; about 22.3 wt%; about 22.4 wt%; about 22.5 wt%; about 22.6 wt%; about 22.7 wt%; about 22.8 wt%; about 22.9 wt%; about 23.0 wt%; about 23.1 wt%; about 23.2 wt%; about 23.3 wt%; about 23.4 wt%; about 23.5 wt%; about 23.6 wt%; about 23.7 wt%; about 23.8 wt%; about 23.9 wt%; about 24.0 wt%; about 24.1 wt%; about 24.2 wt%; about 24.3 wt%; about 24.4 wt%; about 24.5 wt%; about 24.6 wt%; about 24.7 wt%; about 24.8 wt%; about 24.9 wt%; about 25.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the second cooling material can be present in an amount of about 0.2 wt% to about 2 wt% of the second cooling material; about 0.02 wt% to about 0.07 wt% of a second cooling compound; from about 0.001 wt% to about 0.02 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In yet further aspects, the second cooling material can be about 0.5 wt% to about 1 wt% of the second cooling material based on the total weight of the polyamide polymer and the second cooling composition; about 0.03 wt% to about 0.05 wt% of a second cooling compound; from about 0.001 wt% to about 0.01 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In still further aspects, the second cooling material can be present in an amount of about 0.2 wt% to about 2 wt% of the second cooling material; about 0.02 wt% to about 0.07 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.001 wt% to about 0.02 wt% in the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In even further aspects, the second cooling material can be present in an amount of about 0.5 wt% to about 1 wt% of the second cooling material; about 0.03 wt% to about 0.05 wt% of a second cooling compound; and a second cooling salt is present in the second cooling composition in an amount from about 0.001 wt% to about 0.01 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition.

In further aspects, the second cooling material can be present in an amount of about 3.0 wt% to about 10.0 wt% of the second cooling material; about 5.0 wt% to about 12.0 wt% of a second cooling compound; from about 0.3 wt% to about 4.0 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In yet further aspects, the second cooling material can be about 4.0 wt% to about 8.0 wt% of the second cooling material based on the total weight of the polyamide polymer and the second cooling composition; about 5.5 wt% to about 11.0 wt% of a second cooling compound; from about 0.4 wt% to about 3.0 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In still further aspects, the second cooling material can be present in an amount of about 4.5 wt% to about 7.7 wt% of the second cooling material; about 5.9 wt% to about 11.0 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.4 wt% to about 2.5 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In even further aspects, the second cooling material can be present in an amount of about 5.0 wt% to about 7.2 wt% of the second cooling material; about 6.4 wt% to about 10.5 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.5 wt% to about 2.1 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In still further aspects, the second cooling material can be present in an amount of about 5.0 wt% to about 7.0 wt% of the second cooling material; about 6.7 wt% to about 10.0 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.59 wt% to about 2.0 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition.

In further aspects, the second cooling material can be present in the second cooling composition in an amount from about 0.2 wt% to about 2 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In still further aspects, the second cooling material can be present in an amount from about 0.4 wt% to about 1 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In still further aspects, the second cooling material can be present in an amount from about 0.5 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition.

In further aspects, the second cooling material can be present in the second cooling composition in an amount from about 3.0 wt% to about 10.0 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In still further aspects, the second cooling material can be present in an amount of about 4.0 wt% to about 8.0 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In yet further aspects, the second cooling material can be present in an amount of about 4.5 wt% to about 7.7 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In yet further aspects, the second cooling material can be present in an amount of about 5.0 wt% to about 7.2 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition. In even further aspects, the second cooling material can be present in an amount of about 5.0 wt% to about 7.0 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition.

In further aspects, the second cooling material can be about 0.20 wt% based on the total weight of the polyamide polymer and the second cooling composition; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In a further aspect, the second cooling material can be about 4.0 wt% based on the total weight of the polyamide polymer and the second cooling composition; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%, about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%, about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In various aspects, the second cooling material comprises a metal, a metal alloy, a metal oxide, a carbon material, a ceramic material, a mineral, or a combination thereof.

In a further aspect, the second cooling material comprises a metal oxide. Exemplary, but non-limiting, metal oxides that can be used to prepare the second cooling material include metal oxides comprising gold (II) oxide, gold (III) oxide, silver (I) oxide, silver (II) oxide, silver (I, III) oxide, magnesium oxide, iron (II) oxide, iron (III) oxide, copper (I) oxide, copper (II) oxide, or combinations thereof. In yet further aspects, the metal oxide comprises silver (I) oxide, copper (II) oxide, or a combination thereof. In yet further aspects, the metal oxide comprises silver (I) oxide. In even further aspects, the metal oxide can be a mixture comprising two or more metal oxides.

In a further aspect, the second cooling material comprises a mineral. Exemplary, but non-limiting, minerals that can be used in the disclosed cooling compositions include minerals comprising silicon, zirconium, titanium, or combinations thereof. For example, the zirconium-containing mineral may be alloneite, baddeleyite, heterite, ytalitanite, menezesite, or combinations thereof. In still further aspects, the titanium-containing mineral may be rutile, ilmenite, sphene, anatase, brookite, or a combination thereof. In yet further aspects, the silicon-containing mineral is quartz, granite, chalcedony, emerald, garnet, beryllite, olivine, mica, kaolinite, feldspar, zeolite, carnallite, agate, onyx, jasper, henry, flint, or a combination thereof. In some cases, the minerals may contain both zirconium and titanium, including minerals such as calciumzirconite, gazelite, peat, brewsterite, cerotaite, Alstrantitite, tatzgite, zircon, perovskite, zirconolite, or combinations thereof.

In further aspects, the second cooling material comprises a ceramic comprising alumina, aluminum titanate, zirconia, aluminum nitride, silicon carbide, silicon nitride, silicon aluminum nitride, or a combination thereof.

In further aspects, the second cooling material comprises a metal, such as silver, aluminum, copper, or a combination thereof. In yet further aspects, the metal can comprise silver. In yet further aspects, the metal can include copper. In even further aspects, the metal can comprise a mixture of copper and silver. In various aspects, the metal can be a mixture comprising two or more metals.

In further aspects, the second cooling material comprises a metal alloy comprising silver, aluminum, copper, or a combination thereof. In yet further aspects, the metal alloy can comprise silver. In yet further aspects, the metal alloy may comprise copper. In even further aspects, the metal alloy can comprise a mixture of copper and silver. In various aspects, the metal alloy can be a mixture comprising two or more metal alloys.

In various aspects, the second cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combination thereof may be in a form that facilitates incorporation into the second cooling polymer composition, such as in the form of a powder, a thread, a filament, a sheet, a particle, or a combination thereof. In other cases, the second cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combinations thereof may be in the form of particles, powder, or combinations thereof. In some cases, the second cooling material comprising a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combination thereof is in the form of particles, including such forms as nanoparticles, microparticles, or a combination (or mixture) thereof.

In further aspects, the second cooling material comprises a metal, a metal alloy, a metal oxide, a carbon material, a ceramic material, a mineral, or a combination thereof, comprising nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the nanoparticles have a size of about 15nm to about 50 nm. In yet further aspects, the nanoparticles have a size of about 20nm to about 40 nm. In an even further aspect, the nanoparticles have a particle size of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a size utilizing any collection of the foregoing values.

In further aspects, the second cooling material is a metal, metal alloy, metal oxide, carbon material, ceramic material, mineral, or combinations thereof, including particulates. The particulates in the second cooling material may have a diameter of about 10 μm to about 200 μm; about 20 μm to about 100 μm; about 30 μm to about 90 μm; about 40 μm to about 80 μm; a size of about 50 μm to about 70 μm; a dimension or a collection of dimensions within any of the foregoing ranges or sub-ranges within the foregoing ranges.

In further aspects, the second cooling compound can be present in an amount from about 0.02 wt% to about 0.07 wt%; about 0.03 wt% to about 0.07 wt%; about 0.03 wt% to about 0.06 wt%; present in the second cooled polymer composition in an amount of from about 0.03 wt% to about 0.05 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition.

In a further aspect, the second cooling compound can be about 0.020 wt% based on the total weight of the polyamide polymer and the second cooling composition; 0.025 wt%; about 0.030 wt%; about 0.035 wt%; about 0.040 wt%; about 0.045 wt%; about 0.050 wt%; about 0.055 wt%; about 0.060 wt%; about 0.065 wt%; about 0.070 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooled polymer composition.

In further aspects, the second cooling compound can be present at 5.0 wt% to about 12.0 wt%; about 5.5 wt% to about 11.0 wt%; about 5.9 wt% to about 11.0 wt%; about 6.4 wt% to about 10.5 wt%; present in the second cooled polymer composition in an amount of from about 6.7 wt% to about 10.0 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the second cooling composition.

In a further aspect, the second cooling compound can be about 5.0 wt% based on the total weight of the polyamide polymer and the second cooling composition; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; about 10.1 wt%; about 10.2 wt%; about 10.3 wt%; about 10.4 wt%; about 10.5 wt%; about 10.6 wt%; about 10.7 wt%; about 10.8 wt%; about 10.9 wt%; about 11.0 wt%; about 11.1 wt%; about 11.2 wt%; about 11.3 wt%; about 11.4 wt%; about 11.5 wt%; about 11.6 wt%; about 11.7 wt%; about 11.8 wt%; about 11.9 wt%; about 12.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooled polymer composition.

The second cooling compound may include a transition metal oxide, a group 13 oxide, a group 14 oxide, a group 13 carbide, a group 14 carbide, or a mixture thereof. In some cases, the second cooling compound can include alumina, silicon carbide, silicon dioxide, titanium oxide, titanium dioxide, titanium trioxide, zirconium dioxide, or a combination thereof. In further aspects, the second cooling compound can include alumina, silica, titania, or a combination thereof. In still further aspects, the second cooling compound can include titanium dioxide. The second cooling compound can be in the form of a powder, granules, or a combination thereof. In further aspects, the second cooling compound can be in the form of particles, such as nanoparticles, microparticles, or a combination thereof.

In various aspects, the second cooling compound can be in a form that facilitates incorporation into the second cooled polymer composition, such as in the form of a powder, a thread, a filament, a sheet, a granule, or a combination thereof. In other cases, the second cooling compound can be in the form of granules, a powder, or a combination thereof. In some cases, the second cooling compound is in the form of particles, including, for example, nanoparticles, microparticles, or a combination thereof.

In aspects, the second cooling compound comprises a particulate form of the second cooling compound and has a particle size of about 10 μm to about 200 μm; about 20 μm to about 100 μm; about 30 μm to about 90 μm; about 40 μm to about 80 μm; or from about 50 μm to about 70 μm; or a sub-range within any of the preceding ranges.

In a further aspect, the second cooling compound comprises a particulate form of the second cooling compound and has a particle size of about 10 μm; about 20 μm; about 30 μm; about 40 μm; about 50 μm; about 60 μm; about 70 μm; about 80 μm; about 90 μm; about 100 μm; about 110 μm; about 120 μm; about 130 μm; about 140 μm; about 150 μm; about 160 μm; about 170 μm; about 180 μm; about 190 μm; about 200 μm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any collection of values utilizing the foregoing values.

In a further aspect, the second cooling compound can include nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the second cooling compound can include nanoparticles having a size of about 15nm to about 50 nm. In still further aspects, the second cooling compound can include nanoparticles having a size of about 20nm to about 40 nm. In even further aspects, the second cooling compound can comprise a polymer having a molecular weight of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or nanoparticles of a size utilizing any collection of the foregoing values.

In various aspects, the second cooling composition comprises an antioxidant in an amount of about 0.001 wt% to about 0.02 wt%, based on the total weight of the polyamide polymer and the second cooling composition; about 0.001 wt% to about 0.01 wt%; about 0.002 wt% to about 0.01 wt%; or a sub-range of any of the foregoing ranges.

In a further aspect, the second cooling composition comprises a second cooling agent in an amount of about 0.001 wt%, based on the total weight of the polyamide polymer and the second cooling composition; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.02 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a second cooling salt present in an amount utilizing any collection of the foregoing values.

In various aspects, the second cooling composition comprises a second cooling agent in an amount of about 0.3 wt% to about 4.0 wt%, based on the total weight of the polyamide polymer and the second cooling composition; about 0.4 wt% to about 3.0 wt%; about 0.4 wt% to about 2.5 wt%; about 0.5 wt% to about 2.1 wt%; about 0.59 wt% to about 2.0 wt%; or a sub-range of any of the foregoing ranges.

In a further aspect, the second cooling composition comprises a polyamide polymer and a second cooling composition in an amount of about 0.40 wt%, based on the total weight of the polyamide polymer and the second cooling composition; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a second cooling salt present in an amount utilizing any collection of the foregoing values.

The second cooling composition includes a second cooling salt that includes a transition metal salt, a group I salt, a group II salt, or a combination thereof. In some cases, the second cooling salt is a group I salt. In other cases, the second cooling salt is a group II salt. In other cases, the second cooling salt is a transition metal salt. The second cooling salt may include a group I carbonate, a group I halide, a group I nitrate, or a combination thereof. Alternatively, the second cooling salt may include a group II carbonate, a group II halide, a group II nitrate, or a combination thereof. In further aspects, the second cooling salt can include a transition metal carbonate, a transition metal halide, a transition metal nitrate, or a combination thereof. In some cases, the salt includes a transition metal carbonate, a group I carbonate, a group II carbonate, or a combination thereof. In a particular aspect, the salt comprises calcium carbonate.

In various aspects, the second cooling salt can be in a form that facilitates incorporation into the second cooled polymer composition, such as in the form of a powder, a thread, a filament, a sheet, a granule, or a combination thereof. In other cases, the second cooling salt may be in the form of granules, a powder, or a combination thereof. In some cases, the second cooling salt is in the form of particles, including, for example, nanoparticles, microparticles, or a combination thereof.

The second cooling salt in the second cooling composition can be in the form of a powder, granules, or a combination thereof. In some aspects, the second cooling salt in the second cooling composition comprises particles having a size of about 10 μm to about 1000 μm. In a further aspect, the salt in the second cooling composition comprises particles having a size of about 30 μm to about 500 μm.

In aspects, the second cooling salt in the second cooling composition comprises a second salt having a particle size of about 10 μm; about 20 μm; about 30 μm; about 40 μm; about 50 μm; about 60 μm; about 70 μm; about 80 μm; about 90 μm; about 100 μm; 110 μm; about 120 μm; about 130 μm; about 140 μm; about 150 μm; about 160 μm; about 170 μm; about 180 μm; about 190 μm; about 200 μm; 210 μm; about 220 μm; about 230 μm; about 240 μm; about 250 μm; about 260 μm; about 270 μm; about 280 μm; about 290 μm; about 300 μm; 310 μm; about 320 μm; about 330 μm; about 340 μm; about 350 μm; about 360 μm; about 370 μm; about 380 μm; about 390 μm; about 400 μm; 410 mu m; about 420 μm; about 430 μm; about 440 μm; about 450 μm; about 460 μm; about 470 μm; about 480 μm; about 490 μm; about 500 μm; about 550 μm; about 600 μm; about 650 μm; about 700 μm; about 750 μm; about 800 μm; about 850 μm; about 900 μm; about 950 μm; about 1000 μm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or particles of a size utilizing any collection of the foregoing values.

In a further aspect, the second cooling salt can include nanoparticles having a size of about 10nm to about 100 nm. In yet further aspects, the second cooling salt can include nanoparticles having a size of about 15nm to about 50 nm. In still further aspects, the second cooling salt can include nanoparticles having a size of about 20nm to about 40 nm. In even further aspects, the second cooling salt can comprise a salt having a molecular weight of about 10 nm; about 11 nm; about 12 nm; about 13 nm; about 14 nm; about 15 nm; about 16 nm; about 17 nm; about 18 nm; about 19 nm; about 20 nm; about 21 nm; about 22 nm; about 23 nm; about 24 nm; about 25 nm; about 26 nm; about 27 nm; about 28 nm; about 29 nm; about 30 nm; about 31 nm; about 32 nm; about 33 nm; about 34 nm; about 35 nm; about 36 nm; about 37 nm; about 38 nm; about 39 nm; about 40 nm; about 41 nm; about 42 nm; about 43 nm; about 44 nm; about 45 nm; about 46 nm; about 47 nm; about 48 nm; about 49 nm; about 50 nm; about 51 nm; about 52 nm; about 53 nm; about 54 nm; about 55 nm; about 56 nm; about 57 nm; about 58 nm; about 59 nm; about 60 nm; about 61 nm; about 62 nm; about 63 nm; about 64 nm; about 65 nm; about 66 nm; about 67 nm; about 68 nm; about 69 nm; about 70 nm; about 71 nm; about 72 nm; about 73 nm; about 74 nm; about 75 nm; about 76 nm; about 77 nm; about 78 nm; about 79 nm; about 80 nm; about 81 nm; about 82 nm; about 83 nm; about 84 nm; about 85 nm; about 86 nm; about 87 nm; about 88 nm; about 89 nm; about 90 nm; about 91 nm; about 92 nm; about 93 nm; about 94 nm; about 95 nm; about 96 nm; about 97 nm; about 98 nm; about 99 nm; about 100 nm; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or nanoparticles of a size utilizing any collection of the foregoing values.

In one aspect, the first cooling composition can be present in an amount of about 0.1 wt% to about 2 wt% based on the total weight of the composite yarn. In a further aspect, the first cooling composition can be about 0.10 wt% based on the total weight of the composite yarn; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the first cooling composition can be present in an amount of about 2.0 wt% to about 10 wt% based on the total weight of the composite yarn. In a further aspect, the first cooling composition can be about 2.0 wt% based on the total weight of the composite yarn; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the first cooling material can be present in an amount of about 0.1 wt% to about 1 wt% of the first cooling material; about 0.005 wt% to about 0.07 wt% of a first cooling compound; from about 0.0005 wt% to about 0.02 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the first cooling material can be about 0.2 wt% to about 0.9 wt% of the first cooling material based on the total weight of the composite yarn; about 0.01 wt% to about 0.06 wt% of a first cooling compound; from about 0.0005 wt% to about 0.01 wt% of the first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the first cooling material can be present in an amount of about 0.2 wt% to about 0.8 wt% of the first cooling material; about 0.01 wt% to about 0.05 wt% of a first cooling compound; and about 0.0005 wt% to about 0.015 wt% of a first cooling salt is present in the first cooling composition; and wherein wt% is based on the total weight of the composite yarn. In even further aspects, the first cooling material can be present in an amount of about 0.25 wt% to about 0.65 wt% of the first cooling material; about 0.015 wt% to about 0.40 wt% of a first cooling compound; and about 0.0005 wt% to about 0.01 wt% of a first cooling salt is present in the first cooling composition; and wherein wt% is based on the total weight of the composite yarn.

In further aspects, the first cooling material can be present in an amount of about 0.5 wt% to about 7.0 wt% of the first cooling material; about 1.0 wt% to about 10.0 wt% of a first cooling compound; from about 0.05 wt% to about 3.0 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the first cooling material can be about 1.0 wt% to about 6.0 wt% of the first cooling material based on the total weight of the composite yarn; about 1.5 wt% to about 7.0 wt% of a first cooling compound; from about 0.1 wt% to about 2.0 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the first cooling material can be present in an amount of about 1.0 wt% to about 5.0 wt% of the first cooling material; about 1.5 wt% to about 6.0 wt% of a first cooling compound; and the first cooling salt is present in the first cooling composition in an amount from about 0.1 wt% to about 1.5 wt%; and wherein wt% is based on the total weight of the composite yarn. In even further aspects, the first cooling material can be present in an amount of about 1.0 wt% to about 4.0 wt% of the first cooling material; about 2.0 wt% to about 5.0 wt% of a first cooling compound; and the amount of the first cooling salt present in the first cooling composition is from about 0.1 wt% to about 1.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the first cooling material can be present in an amount of about 1.5 wt% to about 3.0 wt% of the first cooling material; about 2.0 wt% to about 4.0 wt% of a first cooling compound; and the amount of the first cooling salt present in the first cooling composition is from about 0.15 wt% to about 1.0 wt%; and wherein wt% is based on the total weight of the composite yarn.

In further aspects, the first cooling material can be present in the first cooling composition in an amount from about 0.1 wt% to about 1 wt%; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the first cooling material can be present in an amount of about 0.2 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the first cooling material can be present in an amount of about 0.2 wt% to about 0.8 wt%; and wherein wt% is based on the total weight of the composite yarn. In even further aspects, the first cooling material can be present in an amount of about 0.25 wt% to about 0.65 wt%; and wherein wt% is based on the total weight of the composite yarn.

In a further aspect, the first cooling material can be about 0.10 wt% based on the total weight of the composite yarn; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling material can be present in the first cooling composition in an amount from about 0.5 wt% to about 7.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the first cooling material can be present in an amount of about 1.0 wt% to about 6.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the first cooling material can be present in an amount of about 1.0 wt% to about 5.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the first cooling material can be present in an amount of about 1.0 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In even further aspects, the first cooling material can be present in an amount of about 1.5 wt% to about 3.0 wt%; and wherein wt% is based on the total weight of the composite yarn.

In a further aspect, the first cooling material can be about 1.0 wt% based on the total weight of the composite yarn; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 2.0 wt%, about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%, about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%, about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%, about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%, about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling compound can be present in an amount from about 0.005 wt% to about 0.07 wt%; about 0.01 wt% to about 0.06 wt%; about 0.01 wt% to about 0.05 wt%; present in the first cooling composition in an amount of from about 0.015 wt% to about 0.40 wt%; and wherein wt% is based on the total weight of the composite yarn.

In a further aspect, the first cooling compound can be about 0.0050 wt% based on the total weight of the composite yarn; about 0.0051 wt%; about 0.0052 wt%; about 0.0053 wt%; about 0.0054 wt%; about 0.0055 wt%; about 0.0056 wt%; about 0.0057 wt%; about 0.0058 wt%; about 0.0059 wt%; about 0.0060 wt%; about 0.0061 wt%; about 0.0062 wt%; about 0.0063 wt%; about 0.0064 wt%; about 0.0065 wt%; about 0.0066 wt%; about 0.0067 wt%; about 0.0068 wt%; about 0.0069 wt%; about 0.0070 wt%; about 0.0071 wt%; about 0.0072 wt%; about 0.0073 wt%; about 0.0074 wt%; about 0.0075 wt%; about 0.0076 wt%; about 0.0077 wt%; about 0.0078 wt%; about 0.0079 wt%; about 0.0080 wt%; about 0.0081 wt%; about 0.0082 wt%; about 0.0083 wt%; about 0.0084 wt%; about 0.0085 wt%; about 0.0086 wt%; about 0.0087 wt%; about 0.0088 wt%; about 0.0089 wt%; about 0.0090 wt%; about 0.0091 wt%; about 0.0092 wt%; about 0.0093 wt%; about 0.0094 wt%; about 0.0095 wt%; about 0.0096 wt%; about 0.0097 wt%; about 0.0098 wt%; about 0.0099 wt%; about 0.0100 wt%; about 0.0110 wt%; about 0.0120 wt%; about 0.0130 wt%; about 0.0140 wt%; about 0.0150 wt%; about 0.0160 wt%; about 0.0170 wt%; about 0.0180 wt%; 0.0190 wt%; about 0.0200 wt%; about 0.0210 wt%; about 0.0220 wt%; about 0.0230 wt%; about 0.0240 wt%; about 0.0250 wt%; about 0.0260 wt%; about 0.0270 wt%; about 0.0280 wt%; 0.0290 wt%; about 0.0300 wt%; about 0.0310 wt%; about 0.0320 wt%; about 0.0330 wt%; about 0.0340 wt%; about 0.0350 wt%; about 0.0360 wt%; about 0.0370 wt%; about 0.0380 wt%; 0.0390 wt%; about 0.0400 wt%; about 0.0410 wt%; about 0.0420 wt%; about 0.0430 wt%; about 0.0440 wt%; about 0.0450 wt%; about 0.0460 wt%; about 0.0470 wt%; about 0.0480 wt%; 0.0490 wt%; about 0.0500 wt%; about 0.0510 wt%; about 0.0520 wt%; about 0.0530 wt%; about 0.0540 wt%; about 0.0550 wt%; about 0.0560 wt%; about 0.0570 wt%; about 0.0580 wt%; 0.0590 wt%; about 0.0600 wt%; about 0.0610 wt%; about 0.0620 wt%; about 0.0630 wt%; about 0.0640 wt%; about 0.06570 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling compound can be present in an amount of about 1.0 wt% to about 10.0 wt%; about 1.5 wt% to about 7.0 wt%; about 1.5 wt% to about 6.0 wt%; about 2.0 wt% to about 5.0 wt%; present in the first cooling composition in an amount of from about 2.0 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the composite yarn.

In a further aspect, the first cooling compound can be about 1.0 wt% based on the total weight of the composite yarn; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In a further aspect, the first cooling salt can be about 0.0005 wt% based on the total weight of the composite yarn; about 0.001 wt%; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.011 wt%; about 0.012 wt%; about 0.013 wt%; about 0.014 wt%; about 0.015 wt%; about 0.016 wt%; about 0.017 wt%; about 0.018 wt%; about 0.019 wt%; about 0.02 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In a further aspect, the first cooling salt can be about 0.0005 wt% based on the total weight of the composite yarn; about 0.0006 wt%; about 0.0007 wt%; about 0.0008 wt%; about 0.0009 wt%; about 0.0010 wt%; about 0.0011 wt%; about 0.0012 wt%; about 0.0013 wt%; about 0.0014 wt%; about 0.0015 wt%; about 0.0016 wt%; about 0.0017 wt%; about 0.0018 wt%; about 0.0019 wt%; about 0.0020 wt%; about 0.0021 wt%; about 0.0022 wt%; about 0.0023 wt%; about 0.0024 wt%; about 0.0025 wt%; about 0.0026 wt%; about 0.0027 wt%; about 0.0028 wt%; about 0.0029 wt%; about 0.0030 wt%; about 0.0031 wt%; about 0.0032 wt%; about 0.0033 wt%; about 0.0034 wt%; about 0.0035 wt%; about 0.0036 wt%; about 0.0037 wt%; about 0.0038 wt%; about 0.0039 wt%; about 0.0040 wt%; about 0.0041 wt%; about 0.0042 wt%; about 0.0043 wt%; about 0.0044 wt%; about 0.0045 wt%; about 0.0046 wt%; about 0.0047 wt%; about 0.0048 wt%; about 0.0049 wt%; about 0.0050 wt%; about 0.0051 wt%; about 0.0052 wt%; about 0.0053 wt%; about 0.0054 wt%; about 0.0055 wt%; about 0.0056 wt%; about 0.0057 wt%; about 0.0058 wt%; about 0.0059 wt%; about 0.0060 wt%; about 0.0061 wt%; about 0.0062 wt%; about 0.0063 wt%; about 0.0064 wt%; about 0.0065 wt%; about 0.0066 wt%; about 0.0067 wt%; about 0.0068 wt%; about 0.0069 wt%; about 0.0070 wt%; about 0.0071 wt%; about 0.0072 wt%; about 0.0073 wt%; about 0.0074 wt%; about 0.0075 wt%; about 0.0076 wt%; about 0.0077 wt%; about 0.0078 wt%; about 0.0079 wt%; about 0.0080 wt%; about 0.0081 wt%; about 0.0082 wt%; about 0.0083 wt%; about 0.0084 wt%; about 0.0085 wt%; about 0.0086 wt%; about 0.0087 wt%; about 0.0088 wt%; about 0.0089 wt%; about 0.0090 wt%; about 0.0091 wt%; about 0.0092 wt%; about 0.0093 wt%; about 0.0094 wt%; about 0.0095 wt%; about 0.0096 wt%; about 0.0097 wt%; about 0.0098 wt%; about 0.0099 wt%; about 0.0100 wt%; about 0.0101 wt%; about 0.0102 wt%; about 0.0103 wt%; about 0.0104 wt%; about 0.0105 wt%; about 0.0106 wt%; about 0.0107 wt%; about 0.0108 wt%; about 0.0109 wt%; about 0.0110 wt%; about 0.0111 wt%; about 0.0112 wt%; about 0.0113 wt%; about 0.0114 wt%; about 0.0115 wt%; about 0.0116 wt%; about 0.0117 wt%; about 0.0118 wt%; about 0.0119 wt%; about 0.0120 wt%; about 0.0121 wt%; about 0.0122 wt%; about 0.0123 wt%; about 0.0124 wt%; about 0.0125 wt%; about 0.0126 wt%; about 0.0127 wt%; about 0.0128 wt%; about 0.0129 wt%; about 0.0130 wt%; about 0.0131 wt%; about 0.0132 wt%; about 0.0133 wt%; about 0.0134 wt%; about 0.0135 wt%; about 0.0136 wt%; about 0.0137 wt%; about 0.0138 wt%; about 0.0139 wt%; about 0.0140 wt%; about 0.0141 wt%; about 0.0142 wt%; about 0.0143 wt%; about 0.0144 wt%; about 0.0145 wt%; about 0.0146 wt%; about 0.0147 wt%; about 0.0148 wt%; about 0.0149 wt%; about 0.0150 wt%; about 0.0151 wt%; about 0.0152 wt%; about 0.0153 wt%; about 0.0154 wt%; about 0.0155 wt%; about 0.0156 wt%; about 0.0157 wt%; about 0.0158 wt%; about 0.0159 wt%; about 0.0160 wt%; about 0.0161 wt%; about 0.0162 wt%; about 0.0163 wt%; about 0.0164 wt%; about 0.0165 wt%; about 0.0166 wt%; about 0.0167 wt%; about 0.0168 wt%; about 0.0169 wt%; about 0.0170 wt%; about 0.0171 wt%; about 0.0172 wt%; about 0.0173 wt%; about 0.0174 wt%; about 0.0175 wt%; about 0.0176 wt%; about 0.0177 wt%; about 0.0178 wt%; about 0.0179 wt%; about 0.0180 wt%; about 0.0181 wt%; about 0.0182 wt%; about 0.0183 wt%; about 0.0184 wt%; about 0.0185 wt%; about 0.0186 wt%; about 0.0187 wt%; about 0.0188 wt%; about 0.0189 wt%; about 0.0190 wt%; about 0.0191 wt%; about 0.0192 wt%; about 0.0193 wt%; about 0.0194 wt%; about 0.0195 wt%; about 0.0196 wt%; about 0.0197 wt%; about 0.0198 wt%; about 0.0199 wt%; about 0.0200 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In aspects, the first cooling salt can be about 0.05 wt% to about 3.0 wt% based on the total weight of the composite yarn; about 0.1 wt% to about 2.0 wt%; about 0.1 wt% to about 1.5 wt%; about 0.1 wt% to about 1.0 wt%; about 0.15 wt% to about 1.0 wt%; or any subrange within the foregoing range.

In a further aspect, the first cooling salt can be about 0.05 wt% based on the total weight of the composite yarn; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; about 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%, about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.00 wt%; about 1.01 wt%; about 1.02 wt%; about 1.03 wt%; about 1.04 wt%; about 1.05 wt%; about 1.06 wt%; about 1.07 wt%; about 1.08 wt%; about 1.09 wt%; about 1.10 wt%; about 1.11 wt%; about 1.12 wt%; about 1.13 wt%; about 1.14 wt%; about 1.15 wt%; about 1.16 wt%; about 1.17 wt%; about 1.18 wt%; about 1.19 wt%; about 1.20 wt%; about 1.21 wt%; about 1.22 wt%; about 1.23 wt%; about 1.24 wt%; about 1.25 wt%; about 1.26 wt%; about 1.27 wt%; about 1.28 wt%; about 1.29 wt%; about 1.30 wt%; about 1.31 wt%; about 1.32 wt%; about 1.33 wt%; about 1.34 wt%; about 1.35 wt%; about 1.36 wt%; about 1.37 wt%; about 1.38 wt%; about 1.39 wt%; about 1.40 wt%; about 1.41 wt%; about 1.42 wt%; about 1.43 wt%; about 1.44 wt%; about 1.45 wt%; about 1.46 wt%; about 1.47 wt%; about 1.48 wt%; about 1.49 wt%; about 1.50 wt%; about 1.51 wt%; about 1.52 wt%; about 1.53 wt%; about 1.54 wt%; about 1.55 wt%; about 1.56 wt%; about 1.57 wt%; about 1.58 wt%; about 1.59 wt%; about 1.60 wt%; about 1.61 wt%; about 1.62 wt%; about 1.63 wt%; about 1.64 wt%; about 1.65 wt%; about 1.66 wt%; about 1.67 wt%; about 1.68 wt%; about 1.69 wt%; about 1.70 wt%; about 1.71 wt%; about 1.72 wt%; about 1.73 wt%; about 1.74 wt%; about 1.75 wt%; about 1.76 wt%; about 1.77 wt%; about 1.78 wt%; about 1.79 wt%; about 1.80 wt%; about 1.81 wt%; about 1.82 wt%; about 1.83 wt%; about 1.84 wt%; about 1.85 wt%; about 1.86 wt%; about 1.87 wt%; about 1.88 wt%; about 1.89 wt%; about 1.90 wt%; about 1.91 wt%; about 1.92 wt%; about 1.93 wt%; about 1.94 wt%; about 1.95 wt%; about 1.96 wt%; about 1.97 wt%; about 1.98 wt%; about 1.99 wt%; about 2.00 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In one aspect, the second cooling composition can be present in an amount of about 0.1 wt% to about 2 wt% based on the total weight of the composite yarn. In a further aspect, the second cooling composition can be about 0.10 wt% based on the total weight of the composite yarn; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the second cooling composition can be present in an amount of about 2.0 wt% to about 10 wt% based on the total weight of the composite yarn. In a further aspect, the second cooling composition can be about 2.0 wt% based on the total weight of the composite yarn; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the second cooling material can be present in an amount of about 0.1 wt% to about 1 wt% of the second cooling material; about 0.005 wt% to about 0.07 wt% of a second cooling compound; from about 0.0005 wt% to about 0.02 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the second cooling material can be about 0.2 wt% to about 0.9 wt% of the second cooling material based on the total weight of the composite yarn; about 0.01 wt% to about 0.06 wt% of a second cooling compound; from about 0.0005 wt% to about 0.01 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the second cooling material can be present in an amount of about 0.2 wt% to about 0.8 wt% of the second cooling material; about 0.01 wt% to about 0.05 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.0005 wt% to about 0.015 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn. In even further aspects, the second cooling material can be present in an amount of about 0.25 wt% to about 0.65 wt% of the second cooling material; about 0.015 wt% to about 0.40 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.0005 wt% to about 0.01 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn.

In further aspects, the second cooling material can be present in an amount of about 0.5 wt% to about 7.0 wt% of the second cooling material; about 1.0 wt% to about 10.0 wt% of a second cooling compound; from about 0.05 wt% to about 3.0 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the second cooling material can be about 1.0 wt% to about 6.0 wt% of the second cooling material based on the total weight of the composite yarn; about 1.5 wt% to about 7.0 wt% of a second cooling compound; from about 0.1 wt% to about 2.0 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the second cooling material can be present in an amount of about 1.0 wt% to about 5.0 wt% of the second cooling material; about 1.5 wt% to about 6.0 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.1 wt% to about 1.5 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn. In even further aspects, the second cooling material can be present in an amount of about 1.0 wt% to about 4.0 wt% of the second cooling material; about 2.0 wt% to about 5.0 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.1 wt% to about 1.0 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the second cooling material can be present in an amount of about 1.5 wt% to about 3.0 wt% of the second cooling material; about 2.0 wt% to about 4.0 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.15 wt% to about 1.0 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the composite yarn.

In further aspects, the second cooling material can be present in the second cooling composition in an amount from about 0.1 wt% to about 1 wt%; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the second cooling material can be present in an amount from about 0.2 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the second cooling material can be present in an amount from about 0.2 wt% to about 0.8 wt%; and wherein wt% is based on the total weight of the composite yarn. In even further aspects, the second cooling material can be present in an amount from about 0.25 wt% to about 0.65 wt%; and wherein wt% is based on the total weight of the composite yarn.

In a further aspect, the second cooling material can be about 0.10 wt% based on the total weight of the composite yarn; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling material can be present in the second cooling composition in an amount from about 0.5 wt% to about 7.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In yet further aspects, the second cooling material can be present in an amount of about 1.0 wt% to about 6.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the second cooling material can be present in an amount of about 1.0 wt% to about 5.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In still further aspects, the second cooling material can be present in an amount of about 1.0 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the composite yarn. In even further aspects, the second cooling material can be present in an amount of about 1.5 wt% to about 3.0 wt%; and wherein wt% is based on the total weight of the composite yarn.

In a further aspect, the second cooling material can be about 1.0 wt% based on the total weight of the composite yarn; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 2.0 wt%, about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%, about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%, about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%, about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling compound can be present in an amount from about 0.005 wt% to about 0.07 wt%; about 0.01 wt% to about 0.06 wt%; about 0.01 wt% to about 0.05 wt%; present in the second cooling composition in an amount of from about 0.015 wt% to about 0.40 wt%; and wherein wt% is based on the total weight of the composite yarn; and wherein wt% is based on the total weight of the composite yarn.

In a further aspect, the second cooling compound can be about 0.0050 wt% based on the total weight of the composite yarn; about 0.0051 wt%; about 0.0052 wt%; about 0.0053 wt%; about 0.0054 wt%; about 0.0055 wt%; about 0.0056 wt%; about 0.0057 wt%; about 0.0058 wt%; about 0.0059 wt%; about 0.0060 wt%; about 0.0061 wt%; about 0.0062 wt%; about 0.0063 wt%; about 0.0064 wt%; about 0.0065 wt%; about 0.0066 wt%; about 0.0067 wt%; about 0.0068 wt%; about 0.0069 wt%; about 0.0070 wt%; about 0.0071 wt%; about 0.0072 wt%; about 0.0073 wt%; about 0.0074 wt%; about 0.0075 wt%; about 0.0076 wt%; about 0.0077 wt%; about 0.0078 wt%; about 0.0079 wt%; about 0.0080 wt%; about 0.0081 wt%; about 0.0082 wt%; about 0.0083 wt%; about 0.0084 wt%; about 0.0085 wt%; about 0.0086 wt%; about 0.0087 wt%; about 0.0088 wt%; about 0.0089 wt%; about 0.0090 wt%; about 0.0091 wt%; about 0.0092 wt%; about 0.0093 wt%; about 0.0094 wt%; about 0.0095 wt%; about 0.0096 wt%; about 0.0097 wt%; about 0.0098 wt%; about 0.0099 wt%; about 0.0100 wt%; about 0.0110 wt%; about 0.0120 wt%; about 0.0130 wt%; about 0.0140 wt%; about 0.0150 wt%; about 0.0160 wt%; about 0.0170 wt%; about 0.0180 wt%; 0.0190 wt%; about 0.0200 wt%; about 0.0210 wt%; about 0.0220 wt%; about 0.0230 wt%; about 0.0240 wt%; about 0.0250 wt%; about 0.0260 wt%; about 0.0270 wt%; about 0.0280 wt%; 0.0290 wt%; about 0.0300 wt%; about 0.0310 wt%; about 0.0320 wt%; about 0.0330 wt%; about 0.0340 wt%; about 0.0350 wt%; about 0.0360 wt%; about 0.0370 wt%; about 0.0380 wt%; 0.0390 wt%; about 0.0400 wt%; about 0.0410 wt%; about 0.0420 wt%; about 0.0430 wt%; about 0.0440 wt%; about 0.0450 wt%; about 0.0460 wt%; about 0.0470 wt%; about 0.0480 wt%; 0.0490 wt%; about 0.0500 wt%; about 0.0510 wt%; about 0.0520 wt%; about 0.0530 wt%; about 0.0540 wt%; about 0.0550 wt%; about 0.0560 wt%; about 0.0570 wt%; about 0.0580 wt%; 0.0590 wt%; about 0.0600 wt%; about 0.0610 wt%; about 0.0620 wt%; about 0.0630 wt%; about 0.0640 wt%; about 0.06570 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling compound can be present at about 1.0 wt% to about 10.0 wt%; about 1.5 wt% to about 7.0 wt%; about 1.5 wt% to about 6.0 wt%; about 2.0 wt% to about 5.0 wt%; present in the second cooling composition in an amount of from about 2.0 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the composite yarn.

In a further aspect, the second cooling compound can be about 1.0 wt% based on the total weight of the composite yarn; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In a further aspect, the second cooling salt can be about 0.0005 wt% based on the total weight of the composite yarn; about 0.001 wt%; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.011 wt%; about 0.012 wt%; about 0.013 wt%; about 0.014 wt%; about 0.015 wt%; about 0.016 wt%; about 0.017 wt%; about 0.018 wt%; about 0.019 wt%; about 0.02 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In a further aspect, the second cooling salt can be about 0.0005 wt% based on the total weight of the composite yarn; about 0.0006 wt%; about 0.0007 wt%; about 0.0008 wt%; about 0.0009 wt%; about 0.0010 wt%; about 0.0011 wt%; about 0.0012 wt%; about 0.0013 wt%; about 0.0014 wt%; about 0.0015 wt%; about 0.0016 wt%; about 0.0017 wt%; about 0.0018 wt%; about 0.0019 wt%; about 0.0020 wt%; about 0.0021 wt%; about 0.0022 wt%; about 0.0023 wt%; about 0.0024 wt%; about 0.0025 wt%; about 0.0026 wt%; about 0.0027 wt%; about 0.0028 wt%; about 0.0029 wt%; about 0.0030 wt%; about 0.0031 wt%; about 0.0032 wt%; about 0.0033 wt%; about 0.0034 wt%; about 0.0035 wt%; about 0.0036 wt%; about 0.0037 wt%; about 0.0038 wt%; about 0.0039 wt%; about 0.0040 wt%; about 0.0041 wt%; about 0.0042 wt%; about 0.0043 wt%; about 0.0044 wt%; about 0.0045 wt%; about 0.0046 wt%; about 0.0047 wt%; about 0.0048 wt%; about 0.0049 wt%; about 0.0050 wt%; about 0.0051 wt%; about 0.0052 wt%; about 0.0053 wt%; about 0.0054 wt%; about 0.0055 wt%; about 0.0056 wt%; about 0.0057 wt%; about 0.0058 wt%; about 0.0059 wt%; about 0.0060 wt%; about 0.0061 wt%; about 0.0062 wt%; about 0.0063 wt%; about 0.0064 wt%; about 0.0065 wt%; about 0.0066 wt%; about 0.0067 wt%; about 0.0068 wt%; about 0.0069 wt%; about 0.0070 wt%; about 0.0071 wt%; about 0.0072 wt%; about 0.0073 wt%; about 0.0074 wt%; about 0.0075 wt%; about 0.0076 wt%; about 0.0077 wt%; about 0.0078 wt%; about 0.0079 wt%; about 0.0080 wt%; about 0.0081 wt%; about 0.0082 wt%; about 0.0083 wt%; about 0.0084 wt%; about 0.0085 wt%; about 0.0086 wt%; about 0.0087 wt%; about 0.0088 wt%; about 0.0089 wt%; about 0.0090 wt%; about 0.0091 wt%; about 0.0092 wt%; about 0.0093 wt%; about 0.0094 wt%; about 0.0095 wt%; about 0.0096 wt%; about 0.0097 wt%; about 0.0098 wt%; about 0.0099 wt%; about 0.0100 wt%; about 0.0101 wt%; about 0.0102 wt%; about 0.0103 wt%; about 0.0104 wt%; about 0.0105 wt%; about 0.0106 wt%; about 0.0107 wt%; about 0.0108 wt%; about 0.0109 wt%; about 0.0110 wt%; about 0.0111 wt%; about 0.0112 wt%; about 0.0113 wt%; about 0.0114 wt%; about 0.0115 wt%; about 0.0116 wt%; about 0.0117 wt%; about 0.0118 wt%; about 0.0119 wt%; about 0.0120 wt%; about 0.0121 wt%; about 0.0122 wt%; about 0.0123 wt%; about 0.0124 wt%; about 0.0125 wt%; about 0.0126 wt%; about 0.0127 wt%; about 0.0128 wt%; about 0.0129 wt%; about 0.0130 wt%; about 0.0131 wt%; about 0.0132 wt%; about 0.0133 wt%; about 0.0134 wt%; about 0.0135 wt%; about 0.0136 wt%; about 0.0137 wt%; about 0.0138 wt%; about 0.0139 wt%; about 0.0140 wt%; about 0.0141 wt%; about 0.0142 wt%; about 0.0143 wt%; about 0.0144 wt%; about 0.0145 wt%; about 0.0146 wt%; about 0.0147 wt%; about 0.0148 wt%; about 0.0149 wt%; about 0.0150 wt%; about 0.0151 wt%; about 0.0152 wt%; about 0.0153 wt%; about 0.0154 wt%; about 0.0155 wt%; about 0.0156 wt%; about 0.0157 wt%; about 0.0158 wt%; about 0.0159 wt%; about 0.0160 wt%; about 0.0161 wt%; about 0.0162 wt%; about 0.0163 wt%; about 0.0164 wt%; about 0.0165 wt%; about 0.0166 wt%; about 0.0167 wt%; about 0.0168 wt%; about 0.0169 wt%; about 0.0170 wt%; about 0.0171 wt%; about 0.0172 wt%; about 0.0173 wt%; about 0.0174 wt%; about 0.0175 wt%; about 0.0176 wt%; about 0.0177 wt%; about 0.0178 wt%; about 0.0179 wt%; about 0.0180 wt%; about 0.0181 wt%; about 0.0182 wt%; about 0.0183 wt%; about 0.0184 wt%; about 0.0185 wt%; about 0.0186 wt%; about 0.0187 wt%; about 0.0188 wt%; about 0.0189 wt%; about 0.0190 wt%; about 0.0191 wt%; about 0.0192 wt%; about 0.0193 wt%; about 0.0194 wt%; about 0.0195 wt%; about 0.0196 wt%; about 0.0197 wt%; about 0.0198 wt%; about 0.0199 wt%; about 0.0200 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In aspects, the second cooling salt can be about 0.05 wt% to about 3.0 wt% based on the total weight of the composite yarn; about 0.1 wt% to about 2.0 wt%; about 0.1 wt% to about 1.5 wt%; about 0.1 wt% to about 1.0 wt%; about 0.15 wt% to about 1.0 wt%; or any subrange within the foregoing range.

In a further aspect, the second cooling salt can be about 0.05 wt% based on the total weight of the composite yarn; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; about 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.00 wt%; about 1.01 wt%; about 1.02 wt%, about 1.03 wt%; about 1.04 wt%; about 1.05 wt%; about 1.06 wt%; about 1.07 wt%; about 1.08 wt%; about 1.09 wt%; about 1.10 wt%; about 1.11 wt%; about 1.12 wt%; about 1.13 wt%; about 1.14 wt%; about 1.15 wt%; about 1.16 wt%; about 1.17 wt%; about 1.18 wt%; about 1.19 wt%; about 1.20 wt%; about 1.21 wt%; about 1.22 wt%; about 1.23 wt%; about 1.24 wt%; about 1.25 wt%; about 1.26 wt%; about 1.27 wt%; about 1.28 wt%; about 1.29 wt%; about 1.30 wt%; about 1.31 wt%; about 1.32 wt%; about 1.33 wt%; about 1.34 wt%; about 1.35 wt%; about 1.36 wt%; about 1.37 wt%; about 1.38 wt%; about 1.39 wt%; about 1.40 wt%; about 1.41 wt%; about 1.42 wt%; about 1.43 wt%; about 1.44 wt%; about 1.45 wt%; about 1.46 wt%; about 1.47 wt%; about 1.48 wt%; about 1.49 wt%; about 1.50 wt%; about 1.51 wt%; about 1.52 wt%; about 1.53 wt%; about 1.54 wt%; about 1.55 wt%; about 1.56 wt%; about 1.57 wt%; about 1.58 wt%; about 1.59 wt%; about 1.60 wt%; about 1.61 wt%; about 1.62 wt%; about 1.63 wt%; about 1.64 wt%; about 1.65 wt%; about 1.66 wt%; about 1.67 wt%; about 1.68 wt%; about 1.69 wt%; about 1.70 wt%; about 1.71 wt%; about 1.72 wt%; about 1.73 wt%; about 1.74 wt%; about 1.75 wt%; about 1.76 wt%; about 1.77 wt%; about 1.78 wt%; about 1.79 wt%; about 1.80 wt%; about 1.81 wt%; about 1.82 wt%; about 1.83 wt%; about 1.84 wt%; about 1.85 wt%; about 1.86 wt%; about 1.87 wt%; about 1.88 wt%; about 1.89 wt%; about 1.90 wt%; about 1.91 wt%; about 1.92 wt%; about 1.93 wt%; about 1.94 wt%; about 1.95 wt%; about 1.96 wt%; about 1.97 wt%; about 1.98 wt%; about 1.99 wt%; about 2.00 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

D. Double covered yarns.

In one aspect, the present disclosure relates to double covered yarns that may be used in woven or knitted fabrics. More specifically, in one aspect, the present disclosure relates to a double covered yarn comprising: (a) an elastic core comprising elastic yarns; (b) a first yarn comprising the disclosed composite yarn; and (c) a second yarn comprising cellulosic fibers; wherein the first yarn is wound around the elastic core to form a single covered yarn; and wherein the second yarn is wrapped around the single wrap yarn to form a double wrap yarn.

In various aspects, the disclosed double covered yarns comprise from about 1 wt% to about 15 wt% of an elastic yarn; about 35 wt% to about 55 wt% of a first yarn comprising the disclosed composite yarn; and about 35 wt% to about 60 wt% of a second yarn comprising cellulosic fibers; and wherein the weight percentages are based on the total weight of the double covered yarn, and with the proviso that the total weight percentage of the elastic yarn, the first yarn, and the second yarn is from about 90 wt% to about 100 wt%. In a further aspect, the disclosed double covered yarn comprises from about 3 wt% to about 12 wt% of an elastic yarn; from about 38 wt% to about 52 wt% of a first yarn comprising the disclosed composite yarn; and about 40 wt% to about 50 wt% of a second yarn comprising cellulosic fibers; and wherein the weight percentages are based on the total weight of the double covered yarn, and with the proviso that the total weight percentage of the elastic yarn, the first yarn, and the second yarn is from about 90 wt% to about 100 wt%. In yet further aspects, the disclosed double covered yarns comprise from about 5 wt% to about 10 wt% of an elastic yarn; about 40 wt% to about 50 wt% of a first yarn comprising the disclosed composite yarn; and about 42 wt% to about 48 wt% of a second yarn comprising cellulosic fibers; and wherein the weight percentages are based on the total weight of the double covered yarn, and with the proviso that the total weight percentage of the elastic yarn, the first yarn, and the second yarn is from about 90 wt% to about 100 wt%.

In a further aspect, the double covered yarn comprises about 1.0 wt%, based on the total weight of the double covered yarn; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; about 10.1 wt%; about 10.2 wt%; about 10.3 wt%; about 10.4 wt%; about 10.5 wt%; about 10.6 wt%; about 10.7 wt%; about 10.8 wt%; about 10.9 wt%; about 11.0 wt%; about 11.1 wt%; about 11.2 wt%; about 11.3 wt%; about 11.4 wt%; about 11.5 wt%; about 11.6 wt%; about 11.7 wt%; about 11.8 wt%; about 11.9 wt%; about 12.0 wt%; about 12.1 wt%; about 12.2 wt%; about 12.3 wt%; about 12.4 wt%; about 12.5 wt%; about 12.6 wt%; about 12.7 wt%; about 12.8 wt%; about 12.9 wt%; about 13.0 wt%; about 13.1 wt%; about 13.2 wt%; about 13.3 wt%; about 13.4 wt%; about 13.5 wt%; about 13.6 wt%; about 13.7 wt%; about 13.8 wt%; about 13.9 wt%; about 14.0 wt%; about 14.1 wt%; about 14.2 wt%; about 14.3 wt%; about 14.4 wt%; about 14.5 wt%; about 14.6 wt%; about 14.7 wt%; about 14.8 wt%; about 14.9 wt%; about 15.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or an elastic yarn in a weight percent amount utilizing a set of any of the foregoing values, and with the proviso that the total weight percent of the elastic yarn, the first yarn, and the second yarn is from about 90 wt% to about 100 wt%.

In a further aspect, the double covered yarn comprises about 35 wt%, based on the total weight of the double covered yarn; about 36 wt%; about 37 wt%; about 38 wt%; about 39 wt%; about 40 wt%; about 41 wt%; about 42 wt%; about 43 wt%; about 44 wt%; about 45 wt%; about 46 wt%; about 47 wt%; about 48 wt%; about 49 wt%; about 50 wt%; about 51 wt%; about 52 wt%; about 53 wt%; about 54 wt%; about 55 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a weight percent amount utilizing a set of any of the foregoing values, and with the proviso that the total weight percent of the elastic yarn, the first yarn, and the second yarn is from about 90 wt% to about 100 wt%.

In a further aspect, the double covered yarn comprises about 35 wt%, based on the total weight of the double covered yarn; about 36 wt%; about 37 wt%; about 38 wt%; about 39 wt%; about 40 wt%; about 41 wt%; about 42 wt%; about 43 wt%; about 44 wt%; about 45 wt%; about 46 wt%; about 47 wt%; about 48 wt%; about 49 wt%; about 50 wt%; about 51 wt%; about 52 wt%; about 53 wt%; about 54 wt%; about 55 wt%; about 56 wt%; about 57 wt%; about 58 wt%; about 59 wt%; about 60 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a weight percent amount utilizing a set of any of the foregoing values, and with the proviso that the total weight percent of the elastic yarn, the first yarn, and the second yarn is from about 90 wt% to about 100 wt%.

In further aspects, the elastic core of the double covered yarn comprises an elastic yarn, such as a spandex yarn, a polyester yarn, or a combination thereof. The polyester yarn in the elastic core of the double covered yarn may comprise polyethylene terephthalate, polypropylene terephthalate, or a combination thereof. In some aspects, the elastic core of the double covered yarn may comprise a composite filament of polyethylene terephthalate and polytrimethylene terephthalate; and wherein the filament has polyethylene terephthalate and polypropylene terephthalate arranged side-by-side.

In further aspects, the elastic core of the double covered yarn can comprise a spandex yarn and a polyester yarn comprising polyethylene terephthalate, polytrimethylene terephthalate, or a combination thereof.

Reference is now made to fig. 6A-6B, which illustrate representative cross-sectional views of the disclosed double covered yarn. Fig. 6A shows a schematic cross-sectional view of a disclosed double covered yarn comprising viscose rayon, a composite yarn and a spandex yarn. Fig. 6B shows a cross-sectional view of the disclosed double covered yarn 1000 with the following specified aspects: (a) an elastic core 200 comprising elastic yarns; (b) a plurality of first yarns 100a-100h, each first yarn comprising a disclosed composite yarn, such as the composite yarn shown in fig. 1B comprising a core component comprising a polyester polymer and a first cooling composition and a sheath layer comprising a polyamide polymer and a second cooling composition; and (c) a plurality of second yarns 300a-300h comprising cellulosic fibers; a first yarn is wrapped around the elastic core to form a single covered yarn, such as shown in fig. 6B; and wherein the second yarn is wrapped around the single wrap yarn to form a double wrap yarn.

In aspects, the elastic yarns in the elastic core of the double covered yarns have a denier of about 30 to about 50; about 35 denier to about 45 denier; about 36 denier to about 44 denier; about 37 denier to about 43 denier; about 38 denier to about 42 denier; about 39 denier to about 41 denier; or a subrange of any of the foregoing ranges.

In a further aspect, the elastic yarn in the elastic core of the double covered yarn has a weight ratio of about 2.5 to about 5; about 3 to about 4; about 3.2 to about 3.8; or a sub-range of stretch rates within any of the foregoing ranges.

The cellulosic fibers of the double covered yarn may include viscose fibers including, but not limited to, viscose rayon, or a combination thereof. In some cases, the cellulosic fiber of the double covered yarn is viscose rayon.

In various aspects, the second yarn of the double coated yarns has a yarn length of about 105d/20f to about 130d/40 f; about 110d/20f to about 130d/40 f; about 115d/20f to about 130d/40 f; about 105d/20f to about 130d/35 f; about 110d/35f to about 130d/35 f; about 115d/20f to about 130d/35 f; about 105d/20f to about 130d/30 f; about 110d/20f to about 130d/30 f; about 115d/20f to about 130d/30 f; or a subrange of the foregoing ranges.

In a further aspect, the second yarn of the double covered yarn has a tenacity of about 120d/20f ± 10%; about 120d/20f + -5%; about 120d/20 f. + -. 3%; 121d/20f +/-10 percent; about 121d/20f ± 5%; about 121d/20f + -3%; 122d/20f +/-10 percent; about 122d/20 f. + -. 5%; about 122d/20 f. + -. 3%; 123d/20f +/-10 percent; about 123d/20f ± 5%; about 123d/20f ± 3%; 124d/20f +/-10 percent; about 124d/20f ± 5%; about 124d/20f + -3%; 125d/20f +/-10 percent; about 125d/20f + -5%; about 125d/20 f. + -. 3%; 126d/20f +/-10 percent; about 126d/20 f. + -. 5%; about 126d/20 f. + -. 3%; 127d/20f +/-10 percent; about 127d/20f + -5%; about 127d/20 f. + -. 3%; 128d/20f +/-10 percent; about 128d/20f + -5%; about 128d/20f + -3%; 129d/20f +/-10 percent; about 129d/20f ± 5%; about 129d/20f + -3%; 130d/20f +/-10 percent; about 130d/20 f. + -. 5%; about 130d/20 f. + -. 3%; about 120d/25f ± 10%; about 120d/25f ± 5%; about 120d/25f + -3%; 121d/25f +/-10 percent; about 121d/25f ± 5%; about 121d/25f ± 3%; 122d/25f +/-10 percent; about 122d/25f ± 5%; about 122d/25f ± 3%; 123d/25f +/-10 percent; about 123d/25f ± 5%; about 123d/25f ± 3%; 124d/25f +/-10 percent; about 124d/25f ± 5%; about 124d/25f ± 3%; 125d/25f +/-10 percent; about 125d/25f + -5%; about 125d/25f + -3%; 126d/25f +/-10 percent; about 126d/25f ± 5%; about 126d/25f ± 3%; 127d/25f +/-10 percent; about 127d/25f ± 5%; about 127d/25f ± 3%; 128d/25f +/-10 percent; about 128d/25f ± 5%; about 128d/25f ± 3%; 129d/25f +/-10 percent; about 129d/25f ± 5%; about 129d/25f ± 3%; 130d/25f plus or minus 10 percent; about 130d/25f ± 5%; about 130d/25f + -3%; about 120d/30 f. + -. 10%; about 120d/30f ± 5%; about 120d/30f + -3%; 121d/30f +/-10 percent; about 121d/30f ± 5%; about 121d/30f ± 3%; 122d/30f +/-10 percent; about 122d/30f ± 5%; about 122d/30f ± 3%; 123d/30f +/-10 percent; about 123d/30f ± 5%; about 123d/30f ± 3%; 124d/30f +/-10 percent; about 124d/30f ± 5%; about 124d/30f ± 3%; 125d/30f +/-10 percent; about 125d/30f + -5%; about 125d/30 f. + -. 3%; 126d/30f +/-10 percent; about 126d/30f ± 5%; about 126d/30f ± 3%; 127d/30f +/-10 percent; about 127d/30f ± 5%; about 127d/30f + -3%; 128d/30f +/-10 percent; about 128d/30f ± 5%; about 128d/30f ± 3%; 129d/30f +/-10 percent; about 129d/30f ± 5%; about 129d/30f ± 3%; 130d/30f +/-10 percent; about 130d/30f ± 5%; about 130d/30 f. + -. 3%; about 120d/35 f. + -. 10%; about 120d/35 f. + -. 5%; about 120d/35 f. + -. 3%; 121d/35f +/-10 percent; about 121d/35f ± 5%; about 121d/35f ± 3%; 122d/35f +/-10 percent; about 122d/35 f. + -. 5%; about 122d/35 f. + -. 3%; 123d/35f +/-10 percent; about 123d/35f ± 5%; about 123d/35f ± 3%; 124d/35f +/-10 percent; about 124d/35f ± 5%; about 124d/35f ± 3%; 125d/35f +/-10 percent; about 125d/35 f. + -. 5%; about 125d/35 f. + -. 3%; 126d/35f +/-10 percent; about 126d/35 f. + -. 5%; about 126d/35 f. + -. 3%; 127d/35f +/-10 percent; about 127d/35f ± 5%; about 127d/35 f. + -. 3%; 128d/35f +/-10 percent; about 128d/35f ± 5%; about 128d/35 f. + -. 3%; 129d/35f +/-10 percent; about 129d/35f ± 5%; about 129d/35 f. + -. 3%; 130d/35f +/-10 percent; about 130d/35 f. + -. 5%; about 130d/35 f. + -. 3%; about 120d/40 f. + -. 10%; about 120d/40f ± 5%; about 120d/40f + -3%; 121d/40f +/-10 percent; about 121d/40f ± 5%; about 121d/40f ± 3%; 122d/40f +/-10 percent; about 122d/40f ± 5%; about 122d/40f ± 3%; 123d/40f +/-10 percent; about 123d/40f ± 5%; about 123d/40f ± 3%; 124d/40f +/-10 percent; about 124d/40f ± 5%; about 124d/40f ± 3%; 125d/40f +/-10 percent; about 125d/40f + -5%; about 125d/40 f. + -. 3%; 126d/40f +/-10 percent; about 126d/40f ± 5%; about 126d/40f ± 3%; 127d/40f +/-10 percent; about 127d/40f ± 5%; about 127d/40f ± 3%; 128d/40f +/-10 percent; about 128d/40f ± 5%; about 128d/40f + -3%; 129d/40f +/-10 percent; about 129d/40f ± 5%; about 129d/40f ± 3%; 130d/40f +/-10 percent; about 130d/40f ± 5%; about 130d/40f + -3%; ranges encompassing any of the foregoing values; or any combination of the foregoing values.

In various aspects, the double covered yarn has a denier of about 250 to about 370; about 260 denier to about 370 denier; about 270 denier to about 370 denier; about 280 denier to about 370 denier; about 290 denier to about 370 denier; about 300 denier to about 370 denier; about 310 denier to about 370 denier; about 320 denier to about 370 denier; about 330 denier to about 370 denier; about 340 denier to about 370 denier; about 350 denier to about 370 denier; about 355 denier to about 370 denier; about 360 denier to about 370 denier; about 250 denier to about 360 denier; about 260 denier to about 360 denier; about 270 denier to about 360 denier; about 280 denier to about 360 denier; about 290 denier to about 360 denier; about 300 denier to about 360 denier; about 310 denier to about 360 denier; about 320 denier to about 360 denier; about 330 denier to about 360 denier; about 340 denier to about 360 denier; about 350 denier to about 360 denier; about 250 denier to about 350 denier; about 260 denier to about 350 denier; about 270 denier to about 350 denier; about 280 denier to about 350 denier; about 290 denier to about 350 denier; about 300 denier to about 350 denier; about 310 denier to about 350 denier; about 320 denier to about 350 denier; about 330 denier to about 350 denier; about 340 denier to about 350 denier; about 250 denier to about 340 denier; about 260 denier to about 340 denier; about 270 denier to about 340 denier; about 280 denier to about 340 denier; about 290 denier to about 340 denier; about 300 denier to about 340 denier; about 310 denier to about 340 denier; about 320 denier to about 340 denier; about 330 denier to about 340 denier; about 250 denier to about 330 denier; about 260 denier to about 330 denier; about 270 denier to about 330 denier; about 280 denier to about 330 denier; about 285 denier to about 330 denier; about 290 denier to about 330 denier; about 300 denier to about 330 denier; about 310 denier to about 330 denier; about 320 denier to about 330 denier; about 250 denier to about 320 denier; about 260 denier to about 320 denier; about 270 denier to about 320 denier; about 280 denier to about 320 denier; about 290 denier to about 320 denier; about 300 denier to about 320 denier; about 310 denier to about 320 denier; about 250 denier to about 310 denier; about 260 denier to about 310 denier; about 270 denier to about 310 denier; about 280 denier to about 310 denier; about 290 denier to about 310 denier; about 300 denier to about 310 denier; about 250 denier to about 300 denier; about 260 denier to about 300 denier; about 270 denier to about 300 denier; about 280 denier to about 300 denier; about 290 denier to about 300 denier; or a value, collection of values, or sub-range of values within any of the preceding ranges.

In a further aspect, the double covered yarn has a denier of about 270 ± 10%; 270 deniers +/-5%; about 270 denier ± 3%; about 271 deniers ± 10%; 271 deniers ± 5%; about 271 deniers ± 3%; about 272 denier ± 10%; 272 denier ± 5%; about 272 denier ± 3%; about 273 denier ± 10%; 273 deniers +/-5%; about 273 denier ± 3%; about 274 denier ± 10%; 274 denier +/-5%; about 274 denier ± 3%; about 275 denier ± 10%; 275 deniers ± 5%; about 275 denier ± 3%; about 276 denier ± 10%; 276 denier +/-5%; about 276 denier ± 3%; about 277 deniers ± 10%; 277 deniers +/-5%; about 277 deniers ± 3%; about 278 denier ± 10%; 278 deniers ± 5%; about 278 denier ± 3%; about 279 deniers ± 10%; 279 deniers ± 5%; about 279 deniers ± 3%; about 280 deniers ± 10%; 280 deniers +/-5%; about 280 deniers ± 3%; about 281 denier ± 10%; 281 denier +/-5%; about 281 denier ± 3%; about 282 denier ± 10%; 282 denier ± 5%; about 282 denier ± 3%; about 283 denier ± 10%; 283 denier ± 5%; about 283 denier ± 3%; about 284 denier ± 10%; 284 deniers ± 5%; about 284 denier ± 3%; about 285 deniers ± 10%; 285 deniers plus or minus 5 percent; about 285 deniers ± 3%; about 286 denier ± 10%; 286 deniers +/-5%; about 286 denier ± 3%; about 287 denier ± 10%; 287 denier ± 5%; about 287 denier ± 3%; about 288 denier ± 10%; 288 denier +/-5%; about 288 denier ± 3%; about 289 denier ± 10%; 289 denier +/-5%; about 289 denier ± 3%; about 290 denier ± 10%; 290 denier ± 5%; about 290 denier ± 3%; about 291 denier ± 10%; 291 denier +/-5%; about 291 denier ± 3%; about 292 denier ± 10%; 292 deniers +/-5%; about 292 denier ± 3%; about 293 denier ± 10%; 293 deniers +/-5%; about 293 denier ± 3%; about 294 denier ± 10%; 294 denier ± 5%; about 294 denier ± 3%; about 295 deniers ± 10%; 295 deniers plus or minus 5 percent; about 295 deniers ± 3%; about 296 deniers ± 10%; 296 deniers +/-5%; about 296 deniers ± 3%; about 297 denier ± 10%; 297 denier ± 5%; about 297 denier ± 3%; about 298 denier ± 10%; 298 deniers plus or minus 5 percent; about 298 denier ± 3%; about 299 denier ± 10%; 299 deniers plus or minus 5 percent; about 299 denier ± 3%; about 300 denier ± 10%; 300 deniers +/-5%; about 300 denier ± 3%; about 301 denier ± 10%; 301 deniers ± 5%; about 301 denier ± 3%; about 302 denier ± 10%; 302 deniers ± 5%; about 302 denier ± 3%; about 303 denier ± 10%; 303 deniers +/-5%; about 303 denier ± 3%; about 304 deniers ± 10%; 304 deniers +/-5%; about 304 deniers ± 3%; about 305 denier ± 10%; 305 deniers ± 5%; about 305 denier ± 3%; about 306 denier ± 10%; 306 deniers +/-5%; about 306 denier ± 3%; about 307 denier ± 10%; 307 denier ± 5%; about 307 denier ± 3%; about 308 denier ± 10%; 308 deniers +/-5%; about 308 deniers ± 3%; about 309 denier ± 10%; 309 deniers +/-5%; about 309 denier ± 3%; about 310 denier ± 10%; 310 deniers +/-5%; about 310 denier ± 3%; about 311 denier ± 10%; 311 deniers ± 5%; about 311 denier ± 3%; about 312 denier ± 10%; 312 deniers ± 5%; about 312 denier ± 3%; about 313 denier ± 10%; 313 deniers ± 5%; about 313 denier ± 3%; about 314 denier ± 10%; 314 denier ± 5%; about 314 denier ± 3%; about 315 denier ± 10%; 315 deniers +/-5%; about 315 denier ± 3%; about 316 denier ± 10%; 316 deniers +/-5%; about 316 denier ± 3%; about 317 denier ± 10%; 317 deniers +/-5%; about 317 denier ± 3%; about 318 denier ± 10%; 318 denier +/-5%; about 318 denier ± 3%; about 319 denier ± 10%; 319 deniers ± 5%; about 319 denier ± 3%; about 320 denier ± 10%; 320 deniers +/-5%; about 320 denier ± 3%; about 321 deniers ± 10%; 321 deniers +/-5%; about 321 deniers ± 3%; about 322 denier ± 10%; 322 deniers +/-5%; about 322 denier ± 3%; about 323 denier ± 10%; 323 deniers plus or minus 5 percent; about 323 denier ± 3%; about 324 denier ± 10%; 324 deniers +/-5%; about 324 deniers ± 3%; about 325 denier ± 10%; 325 denier +/-5%; about 325 denier ± 3%; about 326 denier ± 10%; 326 denier ± 5%; about 326 denier ± 3%; about 327 denier ± 10%; 327 denier ± 5%; about 327 denier ± 3%; about 328 denier ± 10%; 328 deniers +/-5%; about 328 denier ± 3%; about 329 denier ± 10%; 329 denier +/-5%; about 329 denier ± 3%; about 330 deniers ± 10%; 330 deniers +/-5%; about 330 deniers ± 3%; about 331 denier ± 10%; 331 deniers +/-5%; about 331 denier ± 3%; about 332 denier ± 10%; 332 deniers +/-5%; about 332 denier ± 3%; about 333 denier ± 10%; 333 denier +/-5%; about 333 denier ± 3%; about 334 denier ± 10%; 334 deniers plus or minus 5%; about 334 deniers ± 3%; about 335 deniers ± 10%; 335 deniers ± 5%; about 335 deniers ± 3%; about 336 denier ± 10%; 336 deniers plus or minus 5 percent; about 336 denier ± 3%; about 337 denier ± 10%; 337 denier +/-5%; about 337 denier ± 3%; about 338 denier ± 10%; 338 deniers ± 5%; about 338 denier ± 3%; about 339 deniers ± 10%; 339 deniers plus or minus 5 percent; about 339 deniers ± 3%; about 340 denier ± 10%; 340 deniers +/-5%; about 340 denier ± 3%; about 341 deniers ± 10%; 341 deniers plus or minus 5 percent; about 341 deniers ± 3%; about 342 denier ± 10%; 342 deniers +/-5%; about 342 denier ± 3%; about 343 denier ± 10%; 343 deniers +/-5%; about 343 denier ± 3%; about 344 denier ± 10%; 344 denier ± 5%; about 344 denier ± 3%; about 345 denier ± 10%; 345 denier +/-5%; about 345 denier ± 3%; about 346 denier ± 10%; 346 denier ± 5%; about 346 denier ± 3%; about 347 denier ± 10%; 347 denier plus or minus 5%; about 347 denier ± 3%; about 348 denier ± 10%; 348 deniers. + -. 5%; about 348 denier ± 3%; about 349 denier ± 10%; 349 denier ± 5%; about 349 denier ± 3%; about 350 denier ± 10%; 350 deniers plus or minus 5 percent; about 350 denier ± 3%; about 351 deniers ± 10%; 351 deniers +/-5%; about 351 deniers ± 3%; about 352 denier ± 10%; 352 deniers +/-5%; about 352 denier ± 3%; about 353 denier ± 10%; 353 deniers plus or minus 5 percent; about 353 denier ± 3%; about 354 deniers ± 10%; 354 plus or minus 5 percent of denier; about 354 deniers ± 3%; about 355 denier ± 10%; 355 deniers +/-5%; about 355 denier ± 3%; about 356 denier ± 10%; 356 denier ± 5%; about 356 denier ± 3%; about 357 denier ± 10%; 357 denier plus or minus 5 percent; about 357 deniers ± 3%; about 358 denier ± 10%; 358 deniers plus or minus 5 percent; about 358 denier ± 3%; about 359 denier ± 10%; 359 deniers ± 5%; about 359 denier ± 3%; about 360 denier ± 10%; 360 deniers +/-5%; about 360 denier ± 3%; about 361 denier ± 10%; 361 deniers plus or minus 5 percent; about 361 denier ± 3%; about 362 denier ± 10%; 362 denier ± 5%; about 362 denier ± 3%; about 363 denier ± 10%; 363 deniers ± 5%; about 363 denier ± 3%; about 364 denier ± 10%; 364 deniers +/-5%; about 364 denier ± 3%; about 365 denier ± 10%; 365 denier +/-5%; about 365 denier ± 3%; about 366 denier ± 10%; 366 deniers +/-5%; about 366 denier ± 3%; about 367 deniers ± 10%; 367 deniers plus or minus 5 percent; about 367 deniers ± 3%; about 368 denier ± 10%; 368 denier ± 5%; about 368 denier ± 3%; about 369 denier ± 10%; about 369 denier ± 5%; about 369 denier ± 3%; about 370 denier ± 10%; 370 denier ± 5%; about 370 denier ± 3%; about 371 denier ± 10%; 371 deniers +/-5%; about 371 denier ± 3%; about 372 denier ± 10%; 372 denier +/-5%; about 372 denier ± 3%; about 373 denier ± 10%; 373 deniers +/-5%; about 373 denier ± 3%; about 374 denier ± 10%; 374 denier ± 5%; about 374 denier ± 3%; about 375 denier ± 10%; 375 denier ± 5%; about 375 denier ± 3%; about 376 denier ± 10%; 376 denier +/-5%; about 376 denier ± 3%; about 377 denier ± 10%; 377 deniers +/-5%; about 377 denier ± 3%; about 378 deniers ± 10%; 378 deniers +/-5%; about 378 deniers ± 3%; about 379 denier ± 10%; about 379 denier ± 5%; about 379 denier ± 3%; about 380 denier ± 10%; about 380 denier ± 5%; about 380 deniers ± 3%; ranges encompassing any of the foregoing values; or any combination of the foregoing values.

In one aspect, the first cooling composition can be present in an amount of about 0.01 wt% to about 1 wt% based on the total weight of the double covered yarn. In further aspects, the first cooling composition can be about 0.01 wt% based on the total weight of the double covered yarn; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the first cooling composition can be present in an amount of about 1.0 wt% to about 5 wt% based on the total weight of the double covered yarn. In a further aspect, the first cooling composition can be about 1.0 wt% based on the total weight of the double covered yarn; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the first cooling material can be present in an amount of about 0.01 wt% to about 0.9 wt% of the first cooling material; about 0.001 wt% to about 0.05 wt% of a first cooling compound; from about 0.0001 wt% to about 0.005 wt% of the first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the first cooling material can be about 0.05 wt% to about 0.9 wt% of the first cooling material based on the total weight of the double covered yarn; about 0.005 wt% to about 0.03 wt% of a first cooling compound; from about 0.0003 wt% to about 0.003 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the first cooling material can be present in an amount of about 0.07 wt% to about 0.5 wt% of the first cooling material; about 0.007 wt% to about 0.03 wt% of the first cooling compound; and the first cooling salt is present in the first cooling composition in an amount from about 0.0001 wt% to about 0.004 wt%; and wherein wt% is based on the total weight of the double covered yarn. In even further aspects, the first cooling material can be present in an amount of about 0.19 wt% to about 0.3 wt% of the first cooling material; about 0.007 wt% to about 0.20 wt% of the first cooling compound; and the amount of the first cooling salt present in the first cooling composition from about 0.0001 wt% to about 0.003 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the first cooling material can be present in an amount of about 0.1 wt% to about 4.0 wt% of the first cooling material; about 0.1 wt% to about 5.0 wt% of a first cooling compound; from about 0.01 wt% to about 2.0 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the first cooling material can be about 0.1 wt% to about 3.0 wt% of the first cooling material based on the total weight of the double covered yarn; about 0.1 wt% to about 4.0 wt% of a first cooling compound; from about 0.01 wt% to about 1.0 wt% of a first cooling salt, or a combination thereof, is present in the first cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the first cooling material can be present in an amount of about 0.1 wt% to about 2.5 wt% of the first cooling material; about 0.1 wt% to about 3.0 wt% of a first cooling compound; and the amount of the first cooling salt present in the first cooling composition is from about 0.01 wt% to about 0.75 wt%; and wherein wt% is based on the total weight of the double covered yarn. In even further aspects, the first cooling material can be present in an amount of about 0.3 wt% to about 2.0 wt% of the first cooling material; about 0.1 wt% to about 2.5 wt% of a first cooling compound; and the first cooling salt is present in the first cooling composition in an amount from about 0.05 wt% to about 0.5 wt%; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the first cooling material can be present in an amount of about 0.5 wt% to about 2.0 wt% of the first cooling material; about 0.5 wt% to about 2.2 wt% of a first cooling compound; and the first cooling salt is present in the first cooling composition in an amount from about 0.07 wt% to about 0.45 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the first cooling material can be present in the first cooling composition in an amount from about 0.01 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the first cooling material can be present in an amount of 0.05 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the first cooling material can be present in an amount of about 0.07 wt% to about 0.5 wt%; and wherein wt% is based on the total weight of the double covered yarn. In even further aspects, the first cooling material can be present in an amount of about 0.19 wt% to about 0.3 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the first cooling material can be about 0.10 wt% based on the total weight of the double covered yarn; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling material can be present in the first cooling composition in an amount from about 0.1 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the first cooling material can be present in an amount of about 0.1 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the first cooling material can be present in an amount of about 0.1 wt% to about 2.5 wt%; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the first cooling material can be present in an amount of about 0.3 wt% to about 2.0 wt% of the first cooling material; and wherein wt% is based on the total weight of the double covered yarn. In even further aspects, the first cooling material can be present in an amount of about 0.5 wt% to about 2.0 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the first cooling material can be about 0.0 wt%, about 0.1 wt%, based on the total weight of the double covered yarn; about 0.2 wt%; about 0.3 wt%; about 0.4 wt%; about 0.5 wt%; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; about 1.0 wt%, about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%, about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%, about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%, using subranges within any of the foregoing values; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling compound can be present at about 0.001 wt% to about 0.05 wt%; about 0.005 wt% to about 0.03 wt%; about 0.007 wt% to about 0.03 wt%; present in the first cooled polymer composition in an amount of from about 0.007 wt% to about 0.20 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In a further aspect, the first cooling compound can be about 0.001 wt% based on the total weight of the double covered yarn; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.010 wt%; about 0.015 wt%; about 0.020 wt%; about 0.025 wt%; about 0.030 wt%; about 0.035 wt%; about 0.040 wt%; about 0.045 wt%; about 0.050 wt%; about 0.055 wt%; about 0.060 wt%; about 0.065 wt%; about 0.070 wt%; about 0.075 wt%; about 0.080 wt%; about 0.085 wt%; about 0.090 wt%; about 0.090 wt%; about 0.095 wt%; about 0.100 wt%; about 0.110 wt%; about 0.115 wt%; about 0.120 wt%; about 0.125 wt%; about 0.130 wt%; about 0.135 wt%; about 0.140 wt%; about 0.145 wt%; about 0.150 wt%; about 0.155 wt%; about 0.160 wt%; about 0.165 wt%; about 0.170 wt%; about 0.175 wt%; about 0.180 wt%; about 0.185 wt%; about 0.190 wt%; about 0.190 wt%; about 0.195 wt%; about 0.200 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized to provide the first cooled polymer composition.

In further aspects, the first cooling compound can be present at about 0.1 wt% to about 5.0 wt%; about 0.1 wt% to about 4.0 wt%; about 0.1 wt% to about 3.0 wt%; about 0.1 wt% to about 2.5 wt%; present in the first cooled polymer composition in an amount of from about 0.5 wt% to about 2.2 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the first cooling compound can be about 0.1 wt% based on the total weight of the double covered yarn; about 0.2 wt%; about 0.3 wt%; about 0.4 wt%; about 0.5 wt%; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized to provide the first cooled polymer composition.

In a further aspect, the first cooling composition comprises an antioxidant in an amount from about 0.0001 wt% to about 0.005 wt%, based on the total weight of the double covered yarn; about 0.0003 wt% to about 0.003 wt%; about 0.007 wt% to about 0.03 wt%; about 0.0001 wt% to about 0.003 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or the first cooling salt is present in an amount utilizing any collection of the foregoing values.

In a further aspect, the first cooling composition comprises a blend of at least about 0.0001 wt% based on the total weight of the double covered yarn; about 0.0002 wt%; about 0.0003 wt%; about 0.0004 wt%; about 0.0005 wt%; about 0.0006 wt%; about 0.0007 wt%; about 0.0008 wt%; about 0.0009 wt%; about 0.0010 wt%; about 0.0011 wt%; about 0.0012 wt%; about 0.0013 wt%; about 0.0014 wt%; about 0.0015 wt%; about 0.0016 wt%; about 0.0017 wt%; about 0.0018 wt%; about 0.0019 wt%; about 0.0020 wt%; about 0.0021 wt%; about 0.0022 wt%; about 0.0023 wt%; about 0.0024 wt%; about 0.0025 wt%; about 0.0026 wt%; about 0.0027 wt%; about 0.0028 wt%; about 0.0029 wt%; about 0.0030 wt%; about 0.0031 wt%; about 0.0032 wt%; about 0.0033 wt%; about 0.0034 wt%; about 0.0035 wt%; about 0.0036 wt%; about 0.0037 wt%; about 0.0038 wt%; about 0.0039 wt%; about 0.0040 wt%; about 0.0041 wt%; about 0.0042 wt%; about 0.0043 wt%; about 0.0044 wt%; about 0.0045 wt%; about 0.0046 wt%; about 0.0047 wt%; about 0.0048 wt%; about 0.0049 wt%; about 0.0050 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or the first cooling salt is present in an amount utilizing any collection of the foregoing values.

In various aspects, the first cooling composition comprises an antioxidant in an amount of about 0.01 wt% to about 2.0 wt%, based on the total weight of the double covered yarn; about 0.01 wt% to about 1.0 wt%; about 0.01 wt% to about 0.75 wt%; about 0.05 wt% to about 0.5 wt%; about 0.07 wt% to about 0.45 wt%; or any subrange within the foregoing range.

In a further aspect, the first cooling composition comprises an antioxidant in an amount of about 0.01 wt% based on the total weight of the double covered yarn; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; about 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.000 wt%; about 1.01 wt%; about 1.02 wt%; about 1.03 wt%; about 1.04 wt%; about 1.05 wt%; about 1.06 wt%; about 1.07 wt%; about 1.08 wt%; about 1.09 wt%; about 1.10 wt%; about 1.11 wt%; about 1.12 wt%; about 1.13 wt%; about 1.14 wt%; about 1.15 wt%; about 1.16 wt%; about 1.17 wt%; about 1.18 wt%; about 1.19 wt%; about 1.20 wt%; about 1.21 wt%; about 1.22 wt%; about 1.23 wt%; about 1.24 wt%; about 1.25 wt%; about 1.26 wt%; about 1.27 wt%; about 1.28 wt%; about 1.29 wt%; about 1.30 wt%; about 1.31 wt%; about 1.32 wt%; about 1.33 wt%; about 1.34 wt%; about 1.35 wt%; about 1.36 wt%; about 1.37 wt%; about 1.38 wt%; about 1.39 wt%; about 1.40 wt%; about 1.41 wt%; about 1.42 wt%; about 1.43 wt%; about 1.44 wt%; about 1.45 wt%; about 1.46 wt%; about 1.47 wt%; about 1.48 wt%; about 1.49 wt%; about 1.50 wt%; about 1.51 wt%; about 1.52 wt%; about 1.53 wt%; about 1.54 wt%; about 1.55 wt%; about 1.56 wt%; about 1.57 wt%; about 1.58 wt%; about 1.59 wt%; about 1.60 wt%; about 1.61 wt%; about 1.62 wt%; about 1.63 wt%; about 1.64 wt%; about 1.65 wt%; about 1.66 wt%; about 1.67 wt%; about 1.68 wt%; about 1.69 wt%; about 1.70 wt%; about 1.71 wt%; about 1.72 wt%; about 1.73 wt%; about 1.74 wt%; about 1.75 wt%; about 1.76 wt%; about 1.77 wt%; about 1.78 wt%; about 1.79 wt%; about 1.80 wt%; about 1.81 wt%; about 1.82 wt%; about 1.83 wt%; about 1.84 wt%; about 1.85 wt%; about 1.86 wt%; about 1.87 wt%; about 1.88 wt%; about 1.89 wt%; about 1.90 wt%; about 1.91 wt%; about 1.92 wt%; about 1.93 wt%; about 1.94 wt%; about 1.95 wt%; about 1.96 wt%; about 1.97 wt%; about 1.98 wt%; about 1.99 wt%; about 2.00 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or the first cooling salt is present in an amount utilizing any collection of the foregoing values.

In one aspect, the second cooling composition can be present in an amount of about 0.01 wt% to about 1 wt% based on the total weight of the double covered yarn. In further aspects, the second cooling composition can be about 0.01 wt% based on the total weight of the double covered yarn; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the second cooling composition can be present in an amount of about 1.0 wt% to about 5 wt% based on the total weight of the double covered yarn. In a further aspect, the second cooling composition can be about 1.0 wt% based on the total weight of the double covered yarn; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the second cooling material can be present in an amount of about 0.01 wt% to about 0.9 wt% of the second cooling material; about 0.001 wt% to about 0.05 wt% of a second cooling compound; from about 0.0001 wt% to about 0.005 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the second cooling material can be about 0.05 wt% to about 0.9 wt% of the second cooling material based on the total weight of the double covered yarn; about 0.005 wt% to about 0.03 wt% of a second cooling compound; from about 0.0003 wt% to about 0.003 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the second cooling material can be present in an amount of about 0.07 wt% to about 0.5 wt% of the second cooling material; about 0.007 wt% to about 0.03 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.0001 wt% to about 0.004 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In even further aspects, the second cooling material can be present in an amount of about 0.19 wt% to about 0.3 wt% of the second cooling material; about 0.007 wt% to about 0.20 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.0001 wt% to about 0.003 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the second cooling material can be present in an amount of about 0.1 wt% to about 4.0 wt% of the second cooling material; about 0.1 wt% to about 5.0 wt% of a second cooling compound; from about 0.01 wt% to about 2.0 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the second cooling material can be about 0.1 wt% to about 3.0 wt% of the second cooling material based on the total weight of the double covered yarn; about 0.1 wt% to about 4.0 wt% of a second cooling compound; from about 0.01 wt% to about 1.0 wt% of a second cooling salt, or a combination thereof, is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the second cooling material can be present in an amount of about 0.1 wt% to about 2.5 wt% of the second cooling material; about 0.1 wt% to about 3.0 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.01 wt% to about 0.75 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In even further aspects, the second cooling material can be present in an amount of about 0.3 wt% to about 2.0 wt% of the second cooling material; about 0.1 wt% to about 2.5 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.05 wt% to about 0.5 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the second cooling material can be present in an amount of about 0.5 wt% to about 2.0 wt% of the second cooling material; about 0.5 wt% to about 2.2 wt% of a second cooling compound; and a second cooling salt in an amount from about 0.07 wt% to about 0.45 wt% is present in the second cooling composition; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the second cooling material can be present in the second cooling composition in an amount from about 0.01 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the second cooling material can be present in an amount of 0.05 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the second cooling material can be present in an amount from about 0.07 wt% to about 0.5 wt%; and wherein wt% is based on the total weight of the double covered yarn. In even further aspects, the second cooling material can be present in an amount from about 0.19 wt% to about 0.3 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the second cooling material can be about 0.10 wt% based on the total weight of the double covered yarn; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling material can be present in the second cooling composition in an amount from about 0.1 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the double covered yarn. In still further aspects, the second cooling material can be present in an amount of about 0.1 wt% to about 4.0 wt%; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the second cooling material can be present in an amount of about 0.1 wt% to about 2.5 wt%; and wherein wt% is based on the total weight of the double covered yarn. In yet further aspects, the second cooling material can be present in an amount of about 0.3 wt% to about 2.0 wt% of the second cooling material; and wherein wt% is based on the total weight of the double covered yarn. In even further aspects, the second cooling material can be present in an amount from about 0.5 wt% to about 2.0 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the second cooling material can be about 0.0 wt%, about 0.1 wt%, based on the total weight of the double covered yarn; about 0.2 wt%; about 0.3 wt%; about 0.4 wt%; about 0.5 wt%; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; about 1.0 wt%, about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%, about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%, about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%, using subranges within any of the foregoing values; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling compound can be present at about 0.001 wt% to about 0.05 wt%; about 0.005 wt% to about 0.03 wt%; about 0.007 wt% to about 0.03 wt%; present in the second cooled polymer composition in an amount of from about 0.007 wt% to about 0.20 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In a further aspect, the second cooling compound can be about 0.001 wt% based on the total weight of the double covered yarn; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.010 wt%; about 0.015 wt%; about 0.020 wt%; about 0.025 wt%; about 0.030 wt%; about 0.035 wt%; about 0.040 wt%; about 0.045 wt%; about 0.050 wt%; about 0.055 wt%; about 0.060 wt%; about 0.065 wt%; about 0.070 wt%; about 0.075 wt%; about 0.080 wt%; about 0.085 wt%; about 0.090 wt%; about 0.090 wt%; about 0.095 wt%; about 0.100 wt%; about 0.110 wt%; about 0.115 wt%; about 0.120 wt%; about 0.125 wt%; about 0.130 wt%; about 0.135 wt%; about 0.140 wt%; about 0.145 wt%; about 0.150 wt%; about 0.155 wt%; about 0.160 wt%; about 0.165 wt%; about 0.170 wt%; about 0.175 wt%; about 0.180 wt%; about 0.185 wt%; about 0.190 wt%; about 0.190 wt%; about 0.195 wt%; about 0.200 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooled polymer composition.

In further aspects, the second cooling compound can be present at about 0.1 wt% to about 5.0 wt%; about 0.1 wt% to about 4.0 wt%; about 0.1 wt% to about 3.0 wt%; about 0.1 wt% to about 2.5 wt%; present in the second cooled polymer composition in an amount of from about 0.5 wt% to about 2.2 wt%; and wherein wt% is based on the total weight of the double covered yarn.

In further aspects, the second cooling compound can be about 0.1 wt% based on the total weight of the double covered yarn; about 0.2 wt%; about 0.3 wt%; about 0.4 wt%; about 0.5 wt%; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooled polymer composition.

In a further aspect, the second cooling composition comprises an antioxidant in an amount from about 0.0001 wt% to about 0.005 wt%, based on the total weight of the double covered yarn; about 0.0003 wt% to about 0.003 wt%; about 0.007 wt% to about 0.03 wt%; about 0.0001 wt% to about 0.003 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a second cooling salt present in an amount utilizing any collection of the foregoing values.

In a further aspect, the second cooling composition comprises a second cooling agent in an amount of about 0.0001 wt%, based on the total weight of the double covered yarn; about 0.0002 wt%; about 0.0003 wt%; about 0.0004 wt%; about 0.0005 wt%; about 0.0006 wt%; about 0.0007 wt%; about 0.0008 wt%; about 0.0009 wt%; about 0.0010 wt%; about 0.0011 wt%; about 0.0012 wt%; about 0.0013 wt%; about 0.0014 wt%; about 0.0015 wt%; about 0.0016 wt%; about 0.0017 wt%; about 0.0018 wt%; about 0.0019 wt%; about 0.0020 wt%; about 0.0021 wt%; about 0.0022 wt%; about 0.0023 wt%; about 0.0024 wt%; about 0.0025 wt%; about 0.0026 wt%; about 0.0027 wt%; about 0.0028 wt%; about 0.0029 wt%; about 0.0030 wt%; about 0.0031 wt%; about 0.0032 wt%; about 0.0033 wt%; about 0.0034 wt%; about 0.0035 wt%; about 0.0036 wt%; about 0.0037 wt%; about 0.0038 wt%; about 0.0039 wt%; about 0.0040 wt%; about 0.0041 wt%; about 0.0042 wt%; about 0.0043 wt%; about 0.0044 wt%; about 0.0045 wt%; about 0.0046 wt%; about 0.0047 wt%; about 0.0048 wt%; about 0.0049 wt%; about 0.0050 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a second cooling salt present in an amount utilizing any collection of the foregoing values.

In various aspects, the second cooling composition comprises a blend of the double coated yarn and the second cooling composition in an amount of about 0.01 wt% to about 2.0 wt%, based on the total weight of the double coated yarn; about 0.01 wt% to about 1.0 wt%; about 0.01 wt% to about 0.75 wt%; about 0.05 wt% to about 0.5 wt%; about 0.07 wt% to about 0.45 wt%; or a sub-range of any of the foregoing ranges.

In a further aspect, the second cooling composition comprises a second cooling agent in an amount of about 0.01 wt% based on the total weight of the double covered yarn; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; about 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.000 wt%; about 1.01 wt%; about 1.02 wt%; about 1.03 wt%; about 1.04 wt%; about 1.05 wt%; about 1.06 wt%; about 1.07 wt%; about 1.08 wt%; about 1.09 wt%; about 1.10 wt%; about 1.11 wt%; about 1.12 wt%; about 1.13 wt%; about 1.14 wt%; about 1.15 wt%; about 1.16 wt%; about 1.17 wt%; about 1.18 wt%; about 1.19 wt%; about 1.20 wt%; about 1.21 wt%; about 1.22 wt%; about 1.23 wt%; about 1.24 wt%; about 1.25 wt%; about 1.26 wt%; about 1.27 wt%; about 1.28 wt%; about 1.29 wt%; about 1.30 wt%; about 1.31 wt%; about 1.32 wt%; about 1.33 wt%; about 1.34 wt%; about 1.35 wt%; about 1.36 wt%; about 1.37 wt%; about 1.38 wt%; about 1.39 wt%; about 1.40 wt%; about 1.41 wt%; about 1.42 wt%; about 1.43 wt%; about 1.44 wt%; about 1.45 wt%; about 1.46 wt%; about 1.47 wt%; about 1.48 wt%; about 1.49 wt%; about 1.50 wt%; about 1.51 wt%; about 1.52 wt%; about 1.53 wt%; about 1.54 wt%; about 1.55 wt%; about 1.56 wt%; about 1.57 wt%; about 1.58 wt%; about 1.59 wt%; about 1.60 wt%; about 1.61 wt%; about 1.62 wt%; about 1.63 wt%; about 1.64 wt%; about 1.65 wt%; about 1.66 wt%; about 1.67 wt%; about 1.68 wt%; about 1.69 wt%; about 1.70 wt%; about 1.71 wt%; about 1.72 wt%; about 1.73 wt%; about 1.74 wt%; about 1.75 wt%; about 1.76 wt%; about 1.77 wt%; about 1.78 wt%; about 1.79 wt%; about 1.80 wt%; about 1.81 wt%; about 1.82 wt%; about 1.83 wt%; about 1.84 wt%; about 1.85 wt%; about 1.86 wt%; about 1.87 wt%; about 1.88 wt%; about 1.89 wt%; about 1.90 wt%; about 1.91 wt%; about 1.92 wt%; about 1.93 wt%; about 1.94 wt%; about 1.95 wt%; about 1.96 wt%; about 1.97 wt%; about 1.98 wt%; about 1.99 wt%; about 2.00 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a second cooling salt present in an amount utilizing any collection of the foregoing values.

E. Fabric

In various aspects, the present disclosure relates to woven fabrics comprising the disclosed double covered yarns. More specifically, in one aspect, the present disclosure relates to a woven fabric comprising: a weft yarn comprising the disclosed double covered yarn; and warp yarns comprising cotton fibers. In a further aspect, the disclosed woven fabric is a denim fabric.

In various aspects, the woven fabric may be a warp-faced fabric. In some aspects, the disclosed woven fabric is right-handed twill weave (right-handed twill weave); and wherein the right-handed twill weave has a diagonal (diagonal) extending from the left to the right side of the fabric. The disclosed woven fabric may have a weave pattern that is a 3by 1(3by 1) weave; and wherein 3 warp yarns are woven above and below the weft yarns.

In various aspects, the disclosed woven fabrics comprise about 50 wt% to about 90 wt% cotton yarn; about 0.5 wt% to about 10 wt% of an elastic yarn; about 5 wt% to about 30 wt% of a first yarn comprising the disclosed composite yarn; and about 5 wt% to about 30 wt% of a second yarn comprising a braided fabric cover yarn. In a further aspect, the disclosed woven fabric comprises about 60 wt% to about 80 wt% cotton yarn; from about 0.5 wt% to about 7.5 wt% of an elastic yarn; about 5 wt% to about 20 wt% of a first yarn comprising the disclosed composite yarn; and about 5 wt% to about 20 wt% of a second yarn comprising cellulosic fibers; and wherein the weight percentages are based on the total weight of the woven fabric. In yet a further aspect, the disclosed woven fabric comprises about 65 wt% to about 80 wt% cotton yarn; from about 0.5 wt% to about 5.0 wt% of an elastic yarn; about 5 wt% to about 15 wt% of a first yarn comprising the disclosed composite yarn; and about 7.5 wt% to about 20 wt% of a second yarn comprising cellulosic fibers; and wherein the weight percentages are based on the total weight of the woven fabric.

In a further aspect, the disclosed woven fabric comprises about 50 wt%, based on the total weight of the disclosed woven fabric; about 51 wt%; about 52 wt%; about 53 wt%; about 54 wt%; about 55 wt%; about 56 wt%; about 57 wt%; about 58 wt%; about 59 wt%; about 60 wt%; about 61 wt%; about 62 wt%; about 63 wt%; about 64 wt%; about 65 wt%; about 66 wt%; about 67 wt%; about 68 wt%; about 69 wt%; about 70 wt%; about 71 wt%; about 72 wt%; about 73 wt%; about 74 wt%; about 75 wt%; about 76 wt%; about 77 wt%; about 78 wt%; about 79 wt%; about 80 wt%; about 81 wt%; about 82 wt%; about 83 wt%; about 84 wt%; about 85 wt%; about 86 wt%; about 87 wt%; about 88 wt%; about 89 wt%; about 90 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or cotton in a weight percent amount utilizing any of the aforementioned value sets.

In a further aspect, the disclosed woven fabric comprises about 0.5 wt%, based on the total weight of the disclosed woven fabric; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; about 2.1 wt%; about 2.2 wt%; about 2.3 wt%; about 2.4 wt%; about 2.5 wt%; about 2.6 wt%; about 2.7 wt%; about 2.8 wt%; about 2.9 wt%; about 3.0 wt%; about 3.1 wt%; about 3.2 wt%; about 3.3 wt%; about 3.4 wt%; about 3.5 wt%; about 3.6 wt%; about 3.7 wt%; about 3.8 wt%; about 3.9 wt%; about 4.0 wt%; about 4.1 wt%; about 4.2 wt%; about 4.3 wt%; about 4.4 wt%; about 4.5 wt%; about 4.6 wt%; about 4.7 wt%; about 4.8 wt%; about 4.9 wt%; about 5.0 wt%; about 5.1 wt%; about 5.2 wt%; about 5.3 wt%; about 5.4 wt%; about 5.5 wt%; about 5.6 wt%; about 5.7 wt%; about 5.8 wt%; about 5.9 wt%; about 6.0 wt%; about 6.1 wt%; about 6.2 wt%; about 6.3 wt%; about 6.4 wt%; about 6.5 wt%; about 6.6 wt%; about 6.7 wt%; about 6.8 wt%; about 6.9 wt%; about 7.0 wt%; about 7.1 wt%; about 7.2 wt%; about 7.3 wt%; about 7.4 wt%; about 7.5 wt%; about 7.6 wt%; about 7.7 wt%; about 7.8 wt%; about 7.9 wt%; about 8.0 wt%; about 8.1 wt%; about 8.2 wt%; about 8.3 wt%; about 8.4 wt%; about 8.5 wt%; about 8.6 wt%; about 8.7 wt%; about 8.8 wt%; about 8.9 wt%; about 9.0 wt%; about 9.1 wt%; about 9.2 wt%; about 9.3 wt%; about 9.4 wt%; about 9.5 wt%; about 9.6 wt%; about 9.7 wt%; about 9.8 wt%; about 9.9 wt%; about 10.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or by weight percent of the elastic yarn using any value in the set of values recited above.

In a further aspect, the disclosed woven fabric comprises about 5 wt%, based on the total weight of the disclosed woven fabric; about 6 wt%; about 7 wt%; about 8 wt%; about 9 wt%; about 10 wt%; about 11 wt%; about 12 wt%; about 13 wt%; about 14 wt%; about 15 wt%; about 16 wt%; about 17 wt%; about 18 wt%; about 19 wt%; about 20 wt%; about 21 wt%; about 22 wt%; about 23 wt%; about 24 wt%; about 25 wt%; about 26 wt%; about 27 wt%; about 28 wt%; about 29 wt%; about 30 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or the first yarn in a weight percent amount using any value in the set of values noted above.

In a further aspect, the disclosed woven fabric comprises about 5 wt%, based on the total weight of the disclosed woven fabric; about 6 wt%; about 7 wt%; about 8 wt%; about 9 wt%; about 10 wt%; about 11 wt%; about 12 wt%; about 13 wt%; about 14 wt%; about 15 wt%; about 16 wt%; about 17 wt%; about 18 wt%; about 19 wt%; about 20 wt%; about 21 wt%; about 22 wt%; about 23 wt%; about 24 wt%; about 25 wt%; about 26 wt%; about 27 wt%; about 28 wt%; about 29 wt%; about 30 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a weight percent amount using any value in the set of values recited above.

In further aspects, the warp yarns of the disclosed woven fabrics may comprise cotton yarns having a weight of about 8's to about 50's. In further aspects, the cotton yarn may have a yarn length of about 8's, about 9's, about 10's, about 11's, about 12's, about 13's, about 14's, about 15's, about 16's, about 17's, about 18's, about 19's, about 20's, about 21's, about 22's, about 23's, about 24's, about 25's, about 26's, about 27's, about 28's, about 29's, about 30's, about 31's, about 32's, about 33's, about 34's, about 35's, about 36's, about 37's, about 38's, about 39's, about 40's, about 41's, about 42's, about 43's, about 44's, about 45's, about 46's, about 47's, about 48's, about 49's, about 50's, any combination of the foregoing values, or any range of weight encompassed by two or more of the foregoing values.

In various aspects, the disclosed woven fabrics comprise about 50 wt% to about 70 wt% cotton fibers; about 1 wt% to about 15 wt% of a polyester polymer; about 1 wt% to about 10 wt% of a polyamide polymer; and about 0.1 wt% to about 5 wt% of an elastic fiber or elastic filament. In further aspects, the disclosed woven fabrics comprise about 55 wt% to about 70 wt% cotton fibers; about 8 wt% to about 12 wt% of a polyester polymer; about 4 wt% to about 8 wt% of a polyamide polymer; and about 1 wt% to about 4 wt% of an elastic fiber or elastic filament. In yet further aspects, the disclosed woven fabrics comprise from about 60 wt% to about 70 wt% cotton fibers; about 8 wt% to about 10 wt% of a polyester polymer; about 4 wt% to about 7 wt% of a polyamide polymer; and about 2 wt% to about 4 wt% of an elastic fiber or elastic filament.

In further aspects, the disclosed woven fabrics have from about 4oz/sy to about 10 oz/sy; about 5oz/sy to about 8 oz/sy; about 5oz/sy to about 7 oz/sy; about 5.5oz/sy to about 6.5 oz/sy; or a subrange within or overlapping any of the preceding ranges.

In a further aspect, the disclosed woven fabric has an intrinsic stiffness of about 6.20oz/sy ± 10%; about 6.20oz/sy ± 5%; about 6.20oz/sy ± 3%; about 6.21oz/sy ± 10%; about 6.21oz/sy ± 5%; about 6.21oz/sy ± 3%; about 6.22oz/sy ± 10%; about 6.22oz/sy ± 5%; about 6.22oz/sy ± 3%; about 6.23oz/sy ± 10%; about 6.23oz/sy ± 5%; about 6.23oz/sy ± 3%; about 6.24oz/sy ± 10%; about 6.24oz/sy ± 5%; about 6.24oz/sy ± 3%; about 6.25oz/sy ± 10%; about 6.25oz/sy ± 5%; about 6.25oz/sy ± 3%; about 6.27oz/sy ± 10%; about 6.27oz/sy ± 5%; about 6.27oz/sy ± 3%; about 6.28oz/sy ± 10%; about 6.28oz/sy ± 5%; about 6.28oz/sy ± 3%; about 6.29oz/sy ± 10%; about 6.29oz/sy ± 5%; about 6.29oz/sy ± 3%; about 6.30oz/sy ± 10%; about 6.30oz/sy ± 5%; about 6.30oz/sy ± 3%; about 6.40oz/sy ± 10%; about 6.40oz/sy ± 5%; about 6.40oz/sy ± 3%; about 6.50oz/sy ± 10%; about 6.50oz/sy ± 5%; about 6.50oz/sy ± 3%; about 6.60oz/sy ± 10%; about 6.60oz/sy ± 5%; about 6.60oz/sy ± 3%; about 6.70oz/sy ± 10%; about 6.70oz/sy ± 5%; about 6.70oz/sy ± 3%; about 6.80oz/sy ± 10%; about 6.80oz/sy ± 5%; about 6.80oz/sy ± 3%; about 6.90oz/sy ± 10%; about 6.90oz/sy ± 5%; about 6.90oz/sy ± 3%; about 7.00oz/sy ± 10%; about 7.00oz/sy ± 5%; about 7.00oz/sy ± 3%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or by weight of a collection of any of the foregoing values.

In a further aspect, the disclosed woven fabric has a Qmax value of about 0.15 to about 0.50, when determined in accordance with FTTS-FA-019 as specified by the Committee of compliance of assistance and certification functions and Technical Textiles (Taiwan). In yet further aspects, the disclosed woven fabrics have a Qmax value of about 0.17 to about 0.25, when determined in accordance with FTTS-FA-019 as specified by the functional and industrial textile certification and verification council (taiwan).

In a further aspect, the disclosed woven fabric has a weight percent of about 0.10 ± 10% when determined according to FTTS-FA-019 as specified by the functional and industrial textile certification and verification review board (taiwan, china); about 0.10 ± 5%; about 0.10 ± 3%; about 0.11 ± 10%; about 0.11 ± 5%; about 0.11 ± 3%; about 0.12 ± 10%; about 0.12 ± 5%; about 0.12 ± 3%; about 0.13 ± 10%; about 0.13 ± 5%; about 0.13 ± 3%; about 0.14 ± 10%; about 0.14 ± 5%; about 0.14 ± 3%; about 0.15 ± 10%; about 0.15 ± 5%; about 0.15 ± 3%; about 0.16 ± 10%; about 0.16 ± 5%; about 0.16 ± 3%; about 0.17 ± 10%; about 0.17 ± 5%; about 0.17 ± 3%; about 0.18 ± 10%; about 0.18 ± 5%; about 0.18 ± 3%; about 0.19 ± 10%; about 0.19 ± 5%; about 0.19 ± 3%; about 0.20 ± 10%; about 0.20 ± 5%; about 0.20 ± 3%; about 0.21 ± 10%; about 0.21 ± 5%; about 0.21 ± 3%; about 0.22 ± 10%; about 0.22 ± 5%; about 0.22 ± 3%; about 0.23 ± 10%; about 0.23 ± 5%; about 0.23 ± 3%; about 0.24 ± 10%; about 0.24 ± 5%; about 0.24 ± 3%; about 0.25 ± 10%; about 0.25 ± 5%; about 0.25 ± 3%; about 0.26 ± 10%; about 0.26 ± 5%; about 0.26 ± 3%; about 0.27 ± 10%; about 0.27 ± 5%; about 0.27 ± 3%; about 0.28 ± 10%; about 0.28 ± 5%; about 0.28 ± 3%; about 0.29 ± 10%; about 0.29 ± 5%; about 0.29 ± 3%; about 0.30 ± 10%; about 0.30 ± 5%; about 0.30 ± 3%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or a Qmax value using any set of the foregoing values.

In a further aspect, the disclosed woven fabric has a Qmax value that is about 20% higher than the Qmax value of a reference denim fabric, when determined in accordance with FTTS-FA-019 as specified by the functional and industrial textile certification and verification review board (taiwan). In this case, it is understood that the reference denim fabric consists essentially of cotton yarn, with a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric. In yet further aspects, the disclosed woven fabric has a Qmax value that is about 25% higher than the Qmax value of a reference denim fabric, when determined in accordance with FTTS-FA-019 as specified by the functional and industrial textile certification and verification review board (taiwan). In yet further aspects, the disclosed woven fabric has a Qmax value that is about 30% higher than the Qmax value of a reference denim fabric, when determined in accordance with FTTS-FA-019 as specified by the functional and industrial textile certification and verification review board (taiwan).

In a further aspect, the disclosed woven fabrics have a wicking time of less than about 5 minutes, as determined according to AATCC test method 197. In still further aspects, the disclosed woven fabrics have a time of less than about 4.9 minutes, less than about 4.8 minutes, less than about 4.7 minutes, less than about 4.6 minutes, less than about 4.5 minutes, less than about 4.4 minutes, less than about 4.3 minutes, less than about 4.2 minutes, less than about 4.1 minutes, less than about 4.0 minutes, less than about 3.9 minutes, less than about 3.8 minutes, less than about 3.7 minutes, less than about 3.6 minutes, less than about 3.5 minutes, less than about 3.4 minutes, less than about 3.3 minutes, less than about 3.2 minutes, less than about 3.1 minutes, less than about 3.0 minutes, less than about 2.9 minutes, less than about 2.8 minutes, less than about 2.7 minutes, less than about 2.6 minutes, less than about 2.5 minutes, less than about 2.4 minutes, less than about 2.3 minutes, less than about 2.2 minutes, less than about 1.8 minutes, less than about 2.7 minutes, less than about 2.6 minutes, less than about 2.5 minutes, less than about 2.4 minutes, less than about 2.3 minutes, less than about 2., A wicking time of less than about 1.7 minutes, less than about 1.6 minutes, less than about 1.5 minutes, less than about 1.4 minutes, less than about 1.3 minutes, less than about 1.2 minutes, less than about 1.1 minutes, or less than about 1.0 minute.

In further aspects, the disclosed woven fabrics have from about 0.5 minutes to about 4.9 minutes, about 0.5 minutes to about 4.8 minutes, about 0.5 minutes to about 4.7 minutes, about 0.5 minutes to about 4.6 minutes, about 0.5 minutes to about 4.5 minutes, about 0.5 minutes to about 4.4 minutes, about 0.5 minutes to about 4.3 minutes, about 0.5 minutes to about 4.2 minutes, about 0.5 minutes to about 4.1 minutes, about 0.5 minutes to about 4.0 minutes, about 0.5 minutes to about 3.9 minutes, about 0.5 minutes to about 3.8 minutes, about 0.5 minutes to about 3.7 minutes, about 0.5 minutes to about 3.6 minutes, about 0.5 minutes to about 3.5 minutes, about 0.5 minutes to about 3.4 minutes, about 0.5 minutes to about 3.5 minutes, about 0.5 minutes to about 2 minutes, about 0.5 minutes, about 0 minutes to about 3.5 minutes, about 2 minutes, about 0.5 minutes, about 3.5 minutes, about 3 minutes, about 3.5 minutes, about 3 minutes, about 3.5, From about 0.5 minutes to about 2.6 minutes, from about 0.5 minutes to about 2.5 minutes, from about 0.5 minutes to about 2.4 minutes, from about 0.5 minutes to about 2.3 minutes, from about 0.5 minutes to about 2.2 minutes, from about 0.5 minutes to about 2.1 minutes, from about 0.5 minutes to about 2.0 minutes, from about 0.5 minutes to about 1.9 minutes, from about 0.5 minutes to about 1.8 minutes, from about 0.5 minutes to about 1.7 minutes, from about 0.5 minutes to about 1.6 minutes, from about 0.5 minutes to about 1.5 minutes, from about 0.5 minutes to about 1.4 minutes, from about 0.5 minutes to about 1.3 minutes, from about 0.5 minutes to about 1.2 minutes, from about 0.5 minutes to about 1.1 minute, from about 0.5 minutes to about 1.0 minute, a subrange of any of the foregoing ranges, or any combination of values within the foregoing ranges.

In further aspects, the disclosed woven fabrics have from about 1.0 minute to about 4.9 minutes, about 1.0 minute to about 4.8 minutes, about 1.0 minute to about 4.7 minutes, about 1.0 minute to about 4.6 minutes, about 1.0 minute to about 4.5 minutes, about 1.0 minute to about 4.4 minutes, about 1.0 minute to about 4.3 minutes, about 1.0 minute to about 4.2 minutes, about 1.0 minute to about 4.1 minutes, about 1.0 minute to about 4.0 minutes, about 1.0 minute to about 3.9 minutes, about 1.0 minute to about 3.8 minutes, about 1.0 minute to about 3.7 minutes, about 1.0 minute to about 3.6 minutes, about 1.0 minute to about 3.5 minutes, about 1.0 minute to about 3.4 minutes, about 1.0 minute to about 3.7 minutes, about 1.0 minute to about 2 minutes, about 1.0 minute to about 3.0 minute, about 1.0 minute to about 2 minutes, about 1.0 minute to about 3.0 minute, about 3.0 minute to about 3.5 minutes, about 3.0 minute to about 3.0 minute, about 3.8 minutes, about 3.0 minute, about 2 minutes, about 3.0, From about 1.0 minute to about 2.6 minutes, from about 1.0 minute to about 2.5 minutes, from about 1.0 minute to about 2.4 minutes, from about 1.0 minute to about 2.3 minutes, from about 1.0 minute to about 2.2 minutes, from about 1.0 minute to about 2.1 minutes, from about 1.0 minute to about 2.0 minutes, from about 1.0 minute to about 1.9 minutes, from about 1.0 minute to about 1.8 minutes, from about 1.0 minute to about 1.7 minutes, from about 1.0 minute to about 1.6 minutes, from about 1.0 minute to about 1.5 minutes, from about 1.0 minute to about 1.4 minutes, from about 1.0 minute to about 1.3 minutes, from about 1.0 minute to about 1.2 minutes, from about 1.0 minute to about 1.1 minute, a subrange of any of the foregoing ranges, or a time for any value or a set of any value within the foregoing ranges.

In further aspects, the disclosed woven fabrics have a length of from about 1.5 minutes to about 4.9 minutes, from about 1.5 minutes to about 4.8 minutes, from about 1.5 minutes to about 4.7 minutes, from about 1.5 minutes to about 4.6 minutes, from about 1.5 minutes to about 4.5 minutes, from about 1.5 minutes to about 4.4 minutes, from about 1.5 minutes to about 4.3 minutes, from about 1.5 minutes to about 4.2 minutes, from about 1.5 minutes to about 4.1 minutes, from about 1.5 minutes to about 4.0 minutes, from about 1.5 minutes to about 3.9 minutes, from about 1.5 minutes to about 3.8 minutes, from about 1.5 minutes to about 3.7 minutes, from about 1.5 minutes to about 3.6 minutes, from about 1.5 minutes to about 3.5 minutes, from about 1.5 minutes to about 3.4 minutes, from about 1.5 minutes to about 3.5 minutes, from about 1.5 minutes to about 3.7 minutes, from about 1.5 minutes to about 2 minutes, from about 2.5 minutes, from about 3.5 minutes to about 3.5 minutes, from about 2 minutes, from about 3.5 minutes, and about 3.0 minutes, From about 1.5 minutes to about 2.6 minutes, from about 1.5 minutes to about 2.5 minutes, from about 1.5 minutes to about 2.4 minutes, from about 1.5 minutes to about 2.3 minutes, from about 1.5 minutes to about 2.2 minutes, from about 1.5 minutes to about 2.1 minutes, from about 1.5 minutes to about 2.0 minutes, from about 1.5 minutes to about 1.9 minutes, from about 1.5 minutes to about 1.8 minutes, from about 1.5 minutes to about 1.7 minutes, from about 1.5 minutes to about 1.6 minutes, a subrange of any of the foregoing ranges, or a wicking time for any value or set of values within any of the foregoing ranges.

In further aspects, the disclosed woven fabrics have from about 2.0 minutes to about 4.9 minutes, about 2.0 minutes to about 4.8 minutes, about 2.0 minutes to about 4.7 minutes, about 2.0 minutes to about 4.6 minutes, about 2.0 minutes to about 4.5 minutes, about 2.0 minutes to about 4.4 minutes, about 2.0 minutes to about 4.3 minutes, about 2.0 minutes to about 4.2 minutes, about 2.0 minutes to about 4.1 minutes, about 2.0 minutes to about 4.0 minutes, about 2.0 minutes to about 3.9 minutes, about 2.0 minutes to about 3.8 minutes, about 2.0 minutes to about 3.7 minutes, about 2.0 minutes to about 3.6 minutes, about 2.0 minutes to about 3.5 minutes, about 2.0 minutes to about 3.4 minutes, about 2.0 minutes to about 3.7 minutes, about 2.0 minutes to about 2.0 minutes, about 2 minutes to about 3.5 minutes, about 2.0 minutes, about 3.4 minutes, about 2 minutes, about 2.0 minutes to about 2.0 minutes, about 2 minutes, about 2.0 minutes, about 2 minutes to about 2.0 minutes, about 2 minutes to about 2.7 minutes, about 2 minutes, about 2.0 minutes, about 2 minutes, about 2.0, A wicking time of about 2.0 minutes to about 2.6 minutes, about 2.0 minutes to about 2.5 minutes, about 2.0 minutes to about 2.4 minutes, about 2.0 minutes to about 2.3 minutes, about 2.0 minutes to about 2.2 minutes, about 2.0 minutes to about 2.1 minutes, a subrange of any of the foregoing ranges, or any value or collection of values within any of the foregoing ranges.

In various aspects, the disclosed woven fabrics have a wicking time that is at least about 100% faster than the wicking time of a reference denim fabric, as determined according to AATCC test method 197. In this case, it is understood that the reference denim fabric consists essentially of cotton yarn, with a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric.

In further aspects, the disclosed woven fabrics have a wicking time that is at least about 50% faster than the wicking time of a reference denim fabric, as determined according to AATCC test method 197; at least about 55% faster than the wicking time of the reference denim fabric; at least about 60% faster than the wicking time of the reference denim fabric; at least about 65% faster than the wicking time of the reference denim fabric; at least about 70% faster than the wicking time of the reference denim fabric; at least about 75% faster than the wicking time of the reference denim fabric; at least about 80% faster than the wicking time of the reference denim fabric; at least about 85% faster than the wicking time of the reference denim fabric; at least about 90% faster than the wicking time of the reference denim fabric; at least about 95% faster than the wicking time of the reference denim fabric; at least about 100% faster than the wicking time of the reference denim fabric; at least about 110% faster than the wicking time of the reference denim fabric; at least about 115% faster than the wicking time of the reference denim fabric; at least about 120% faster than the wicking time of the reference denim fabric; wicking time at least about 125% faster than that of the reference denim fabric; at least about 130% faster than the wicking time of the reference denim fabric; at least about 135% faster than the wicking time of the reference denim fabric; at least about 140% faster than the wicking time of the reference denim fabric; wicking time at least about 145% faster than that of the reference denim fabric; wicking time at least about 150% faster than that of the reference denim fabric; wicking time at least about 155% faster than that of the reference denim fabric; at least about 160% faster than the wicking time of the reference denim fabric; wicking time at least about 165% faster than that of the reference denim fabric; at least about 170% faster than the wicking time of the reference denim fabric; at least about 175% faster than the wicking time of the reference denim fabric; at least about 180% faster than the wicking time of the reference denim fabric; at least about 185% faster than the wicking time of the reference denim fabric; at least about 190% faster than the wicking time of the reference denim fabric; at least about 195% faster than the wicking time of the reference denim fabric; or at least about 200% faster than the wicking time of the reference denim fabric.

In a further aspect, the disclosed woven fabrics have a dry time of less than about 60 seconds, as determined according to AATCC test method 79. In yet further aspects, the disclosed woven fabrics have a caliper of from about 8 seconds to about 30 seconds, when determined according to AATCC test method 79; about 10 seconds to about 20 seconds; about 10 seconds to about 15 seconds; or a sub-range of any of the foregoing ranges.

In a further aspect, the disclosed woven fabric has a drying time that is at least about 100% faster than the drying time of a reference denim fabric, as determined according to AATCC test method 79. In this case, it is understood that the reference denim fabric consists essentially of cotton yarn, with a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric. In yet further aspects, the disclosed woven fabric has a drying time that is about 100% faster than the drying time of a reference denim fabric, as determined according to AATCC test method 79; about 200%; about 300%, about 400%; about 500%; or any combination of the foregoing values.

In a further aspect, the disclosed woven fabrics have a drying rate of less than about 2.5ml/hr, as determined according to AATCC test method 201. In still further aspects, the disclosed woven fabrics have a weight average molecular weight of from about 0.5ml/hr to about 1.5ml/hr, when determined according to AATCC test method 201; about 0.5ml/hr to about 1.0 ml/hr; about 0.5ml/hr to about 0.7 ml/hr; or a sub-range of drying rates within any of the foregoing ranges.

In further aspects, the disclosed woven fabrics have UPF test values of at least about 1500 for dry evaluation (dry evaluation) and at least about 3500 for wet evaluation (wet evaluation) when tested according to AATCC test method 183. In yet further aspects, the disclosed woven fabrics have a dry rating of about 1500 to about 3000 and a wet rating of about 3500 to about 4500 when tested according to AATCC test method 183; about 1700 to about 2800 for dry evaluation and about 3700 to about 4300 for wet evaluation; about 2000 to about 2700 for dry evaluation and about 3800 to about 4200 for wet evaluation; or a subrange of the UPF test values within any of the foregoing ranges. In still further aspects, the disclosed woven fabrics have a dry rating of about 2500 ± 10% and a wet rating of about 4100 ± 10% when tested according to AATCC test method 183; about 2500 ± 5% for dry evaluation and about 4100 ± 5% for wet evaluation; UPF test values of about 2500 + -3% for dry evaluation and about 4100 + -3% for wet evaluation.

In further aspects, the disclosed woven fabrics have a UPF test value that is about 100% greater than the UPF test value of a reference denim fabric and about 100% greater for wet evaluation when tested according to AATCC test method 183. In this case, it is understood that the reference denim fabric consists essentially of cotton yarn, with a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric. In yet further aspects, the disclosed woven fabrics have a UPF test value that is about 150% greater than the UPF test value of a reference denim fabric and about 150% greater for wet evaluation when tested according to AATCC test method 183. In yet further aspects, the disclosed woven fabrics have a UPF test value that is about 200% greater than the UPF test value of a reference denim fabric and about 200% greater for wet evaluation when tested according to AATCC test method 183. In an even further aspect, the disclosed woven fabric has a UPF test value that is about 250% greater than the UPF test value of a reference denim fabric and about 250% greater for wet evaluation when tested according to AATCC test method 183. In yet further aspects, the disclosed woven fabrics have a UPF test value that is about 300% greater than the UPF test value of a reference denim fabric and about 300% greater for wet evaluation when tested according to AATCC test method 183.

In one aspect, the first cooling composition can be present in an amount of about 0.005 wt% to about 0.2 wt% based on the total weight of the woven fabric. In further aspects, the first cooling composition can be about 0.005 wt% based on the total weight of the woven fabric; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.011 wt%; about 0.012 wt%; about 0.013 wt%; about 0.014 wt%; about 0.015 wt%; about 0.016 wt%; about 0.017 wt%; about 0.018 wt%; about 0.019 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.020 wt%; about 0.021 wt%; about 0.022 wt%; about 0.023 wt%; about 0.024 wt%; about 0.025 wt%; about 0.026 wt%; about 0.027 wt%; about 0.028 wt%; about 0.029 wt%; about 0.030 wt%; about 0.031 wt%; about 0.032 wt%; about 0.033 wt%; about 0.034 wt%; about 0.035 wt%; about 0.036 wt%; about 0.037 wt%; about 0.038 wt%; about 0.039 wt%; about 0.040 wt%; about 0.041 wt%; about 0.042 wt%; about 0.043 wt%; about 0.044 wt%; about 0.045 wt%; about 0.046 wt%; about 0.047 wt%; about 0.048 wt%; about 0.049 wt%; about 0.050 wt%; about 0.051 wt%; about 0.052 wt%; about 0.053 wt%; about 0.054 wt%; about 0.055 wt%; about 0.056 wt%; about 0.057 wt%; about 0.058 wt%; about 0.059 wt%; about 0.060 wt%; about 0.061 wt%; about 0.062 wt%; about 0.063 wt%; about 0.064 wt%; about 0.065 wt%; about 0.066 wt%; about 0.067 wt%; about 0.068 wt%; about 0.069 wt%; about 0.070 wt%; about 0.071 wt%; about 0.072 wt%; about 0.073 wt%; about 0.074 wt%; about 0.075 wt%; about 0.076 wt%; about 0.077 wt%; about 0.078 wt%; about 0.079 wt%; about 0.080 wt%; about 0.081 wt%; about 0.082 wt%; about 0.083 wt%; about 0.084 wt%; about 0.085 wt%; about 0.086 wt%; about 0.087 wt%; about 0.088 wt%; about 0.089 wt%; about 0.090 wt%; about 0.091 wt%; about 0.092 wt%; about 0.093 wt%; about 0.094 wt%; about 0.095 wt%; about 0.096 wt%; about 0.097 wt%; about 0.098 wt%; about 0.099 wt%; about 0.100 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the first cooling composition can be present in an amount of about 0.1 wt% to about 2.0 wt% based on the total weight of the woven fabric. In further aspects, the first cooling composition can be about 0.1 wt% based on the total weight of the woven fabric; about 0.2 wt%; about 0.3 wt%; about 0.4 wt%; about 0.5 wt%; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the first cooling composition can comprise about 0.005 wt% to about 0.150 wt% of the first cooling material, based on the total weight of the woven fabric; about 0.0001 wt% to about 0.009 wt% of a first cooling compound; about 0.00005 wt% to about 0.002 wt% of a first cooling salt or a combination thereof; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the first cooling composition can comprise about 0.007 wt% to about 0.150 wt% of the first cooling material, based on the total weight of the woven fabric; about 0.0005 wt% to about 0.007 wt% of a first cooling compound; about 0.00005 wt% to about 0.0015 wt% of a first cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the first cooling composition can comprise about 0.010 wt% to about 0.100 wt% of the first cooling material based on the total weight of the woven fabric; about 0.0007 wt% to about 0.005 wt% of a first cooling compound; and about 0.00005 wt% to about 0.001 wt% of a first cooling salt; and wherein wt% is based on the total weight of the woven fabric. In even further aspects, the first cooling composition can comprise about 0.010 wt% to about 0.090 wt%, based on the total weight of the woven fabric, of the first cooling material; about 0.0010 wt% to about 0.0060 wt% of a first cooling compound; and about 0.0001 wt% to about 0.0003 wt% of a first cooling salt; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the first cooling composition can comprise about 0.01 wt% to about 1.0 wt% of the first cooling material based on the total weight of the woven fabric; about 0.01 wt% to about 1.5 wt% of a first cooling compound; about 0.001 wt% to about 0.20 wt% of a first cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the first cooling composition can comprise about 0.05 wt% to about 1.0 wt% of the first cooling material based on the total weight of the woven fabric; about 0.05 wt% to about 1.0 wt% of a first cooling compound; about 0.005 wt% to about 0.15 wt% of a first cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the first cooling composition can comprise about 0.1 wt% to about 0.75 wt% of the first cooling material based on the total weight of the woven fabric; about 0.1 wt% to about 0.9 wt% of a first cooling compound; and about 0.01 wt% to about 0.15 wt% of a first cooling salt; and wherein wt% is based on the total weight of the woven fabric. In even further aspects, the first cooling composition can comprise about 0.15 wt% to about 0.50 wt% of the first cooling material, based on the total weight of the woven fabric; about 0.15 wt% to about 0.75 wt% of a first cooling compound; and about 0.01 wt% to about 0.15 wt% of a first cooling salt; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the first cooling material can be present in the first cooling composition in an amount from about 0.005 wt% to about 0.150 wt%; and wherein wt% is based on the total weight of the woven fabric. In still further aspects, the first cooling material can be present in an amount of about 0.007 wt% to about 0.150 wt%; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the first cooling material can be present in an amount of about 0.010 wt% to about 0.100 wt%; and wherein wt% is based on the total weight of the woven fabric. In even further aspects, the first cooling material can be present in an amount of about 0.010 wt% to about 0.090 wt%; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the first cooling material can be about 0.005 wt% based on the total weight of the woven fabric; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.011 wt%; about 0.012 wt%; about 0.013 wt%; about 0.014 wt%; about 0.015 wt%; about 0.016 wt%; about 0.017 wt%; about 0.018 wt%; about 0.019 wt%; about 0.020 wt%; about 0.021 wt%; about 0.022 wt%; about 0.023 wt%; about 0.024 wt%; about 0.025 wt%; about 0.026 wt%; about 0.027 wt%; about 0.028 wt%; about 0.029 wt%; 0.030 wt%; about 0.031 wt%; about 0.032 wt%; about 0.033 wt%; about 0.034 wt%; about 0.035 wt%; about 0.036 wt%; about 0.037 wt%; about 0.038 wt%; about 0.039 wt%; about 0.040 wt%; about 0.041 wt%; about 0.042 wt%; about 0.043 wt%; about 0.044 wt%; about 0.045 wt%; about 0.046 wt%; about 0.047 wt%; about 0.048 wt%; about 0.049 wt%; about 0.050 wt%; about 0.051 wt%; about 0.052 wt%; about 0.053 wt%; about 0.054 wt%; about 0.055 wt%; about 0.056 wt%; about 0.057 wt%; about 0.058 wt%; about 0.059 wt%; about 0.060 wt%; about 0.061 wt%; about 0.062 wt%; about 0.063 wt%; about 0.064 wt%; about 0.065 wt%; about 0.066 wt%; about 0.067 wt%; about 0.068 wt%; about 0.069 wt%; about 0.070 wt%; about 0.071 wt%; about 0.072 wt%; about 0.073 wt%; about 0.074 wt%; about 0.075 wt%; about 0.076 wt%; about 0.077 wt%; about 0.078 wt%; about 0.079 wt%; about 0.080 wt%; about 0.081 wt%; about 0.082 wt%; about 0.083 wt%; about 0.084 wt%; about 0.085 wt%; about 0.086 wt%; about 0.087 wt%; about 0.088 wt%; about 0.089 wt%; about 0.090 wt%; about 0.091 wt%; about 0.092 wt%; about 0.093 wt%; about 0.094 wt%; about 0.095 wt%; about 0.096 wt%; about 0.097 wt%; about 0.098 wt%; about 0.099 wt%; about 0.100 wt%; about 0.110 wt%; about 0.111 wt%; about 0.112 wt%; about 0.113 wt%; about 0.114 wt%; about 0.115 wt%; about 0.116 wt%; about 0.117 wt%; about 0.118 wt%; about 0.119 wt%; about 0.120 wt%; about 0.121 wt%; about 0.122 wt%; about 0.123 wt%; about 0.124 wt%; about 0.125 wt%; about 0.126 wt%; about 0.127 wt%; about 0.128 wt%; about 0.129 wt%; 0.130 wt%; about 0.131 wt%; about 0.132 wt%; about 0.133 wt%; about 0.134 wt%; about 0.135 wt%; about 0.136 wt%; about 0.137 wt%; about 0.138 wt%; about 0.139 wt%; about 0.140 wt%; about 0.141 wt%; about 0.142 wt%; about 0.143 wt%; about 0.144 wt%; about 0.145 wt%; about 0.146 wt%; about 0.147 wt%; about 0.148 wt%; about 0.149 wt%; about 0.150 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling material can be present in the first cooling composition in an amount from about 0.01 wt% to about 1.0 wt%; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the first cooling material can be present in an amount of about 0.05 wt% to about 1.0 wt%; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the first cooling material can be present in an amount of about 0.1 wt% to about 0.75 wt%; and wherein wt% is based on the total weight of the woven fabric. In still further aspects, the first cooling material can be present in an amount of about 0.15 wt% to about 0.50 wt% of the first cooling material; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the first cooling material can be about 0.01 wt% based on the total weight of the woven fabric; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.1 wt%; about 0.2 wt%; about 0.3 wt%; about 0.4 wt%; about 0.5 wt%; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; about 1.0 wt%; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling compound can be present at about 0.0001 wt% to about 0.009 wt%; about 0.0005 wt% to about 0.007 wt%; about 0.0007 wt% to about 0.005 wt%; (ii) present in the first cooling composition in an amount of from about 0.0010 wt% to about 0.0060 wt%; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the first cooling compound can be about 0.0001 wt% based on the total weight of the woven fabric; about 0.0002 wt%; about 0.0003 wt%; about 0.0004 wt%; about 0.0005 wt%; about 0.0010 wt%; about 0.0015 wt%; about 0.0020 wt%; about 0.0025 wt%; about 0.0030 wt%; about 0.0035 wt%; about 0.0040 wt%; about 0.0045 wt%; about 0.0050 wt%; about 0.0055 wt%; about 0.0060 wt%; about 0.0065 wt%; about 0.0070 wt%; about 0.0075 wt%; about 0.0080 wt%; about 0.0085 wt%; about 0.0090 wt%; about 0.0090 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling compound can be present at about 0.01 wt% to about 1.5 wt%; about 0.05 wt% to about 1.0 wt%; about 0.1 wt% to about 0.9 wt%; present in the first cooling composition in an amount of from about 0.15 wt% to about 0.75 wt%; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the first cooling compound can be about 0.01 wt% based on the total weight of the woven fabric; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; about 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling salt can be about 0.00005 wt% to about 0.002 wt% based on the total weight of the woven fabric; about 0.00005 wt% to about 0.0015 wt%; about 0.00005 wt% to about 0.001 wt%; about 0.0001 wt% to about 0.0003 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In further aspects, the first cooling salt can be about 0.00005 wt% based on the total weight of the woven fabric; about 0.00006 wt%; about 0.00007 wt%; about 0.00008 wt%; about 0.00009 wt%; about 0.00010 wt%; about 0.00011 wt%; about 0.00012 wt%; about 0.00013 wt%; about 0.00014 wt%; about 0.00015 wt%; about 0.00016 wt%; about 0.00017 wt%; about 0.00018 wt%; about 0.00019 wt%; about 0.00020 wt%; about 0.00021 wt%; about 0.00022 wt%; about 0.00023 wt%; about 0.00024 wt%; about 0.00025 wt%; about 0.00026 wt%; about 0.00027 wt%; about 0.00028 wt%; about 0.00029 wt%; about 0.00030 wt%; about 0.00031 wt%; about 0.00032 wt%; about 0.00033 wt%; about 0.00034 wt%; about 0.00035 wt%; about 0.00036 wt%; about 0.00037 wt%; about 0.00038 wt%; about 0.00039 wt%; about 0.00040 wt%; about 0.00041 wt%; about 0.00042 wt%; about 0.00043 wt%; about 0.00044 wt%; about 0.00045 wt%; about 0.00046 wt%; about 0.00047 wt%; about 0.00048 wt%; about 0.00049 wt%; about 0.00050 wt%; about 0.00051 wt%; about 0.00052 wt%; about 0.00053 wt%; about 0.00054 wt%; about 0.00055 wt%; about 0.00056 wt%; about 0.00057 wt%; about 0.00058 wt%; about 0.00059 wt%; about 0.00060 wt%; about 0.00061 wt%; about 0.00062 wt%; about 0.00063 wt%; about 0.00064 wt%; about 0.00065 wt%; about 0.00066 wt%; about 0.00067 wt%; about 0.00068 wt%; about 0.00069 wt%; about 0.00070 wt%; about 0.00071 wt%; about 0.00072 wt%; about 0.00073 wt%; about 0.00074 wt%; about 0.00075 wt%; about 0.00076 wt%; about 0.00077 wt%; about 0.00078 wt%; about 0.00079 wt%; about 0.00080 wt%; about 0.00081 wt%; about 0.00082 wt%; about 0.00083 wt%; about 0.00084 wt%; about 0.00085 wt%; about 0.00086 wt%; about 0.00087 wt%; about 0.00088 wt%; about 0.00089 wt%; about 0.00090 wt%; about 0.00091 wt%; about 0.00092 wt%; about 0.00093 wt%; about 0.00094 wt%; about 0.00095 wt%; about 0.00096 wt%; about 0.00097 wt%; about 0.00098 wt%; about 0.00099 wt%; about 0.0010 wt%; about 0.0011 wt%; about 0.0012 wt%; about 0.0013 wt%; about 0.0014 wt%; about 0.0015 wt%; about 0.0016 wt%; about 0.0017 wt%; about 0.0018 wt%; about 0.0019 wt%; about 0.0020 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In various aspects, the first cooling salt can be about 0.001 wt% to about 0.20 wt% based on the total weight of the woven fabric; about 0.005 wt% to about 0.15 wt%; about 0.01 wt% to about 0.15 wt%; about 0.01 wt% to about 0.15 wt%; or any subrange within the foregoing range.

In further aspects, the first cooling salt can be about 0.001 wt% based on the total weight of the woven fabric; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.011 wt%; about 0.012 wt%; about 0.013 wt%; about 0.014 wt%; about 0.015 wt%; about 0.016 wt%; about 0.017 wt%; about 0.018 wt%; about 0.019 wt%; about 0.020 wt%; about 0.021 wt%; about 0.022 wt%; about 0.023 wt%; about 0.024 wt%; about 0.025 wt%; about 0.026 wt%; about 0.027 wt%; about 0.028 wt%; about 0.029 wt%; about 0.030 wt%; about 0.031 wt%; about 0.032 wt%; about 0.033 wt%; about 0.034 wt%; about 0.035 wt%; about 0.036 wt%; about 0.037 wt%; about 0.038 wt%; about 0.039 wt%; about 0.040 wt%; about 0.041 wt%; about 0.042 wt%; about 0.043 wt%; about 0.044 wt%; about 0.045 wt%; about 0.046 wt%; about 0.047 wt%; about 0.048 wt%; about 0.049 wt%; about 0.050 wt%; about 0.051 wt%; about 0.052 wt%; about 0.053 wt%; about 0.054 wt%; about 0.055 wt%; about 0.056 wt%; about 0.057 wt%; about 0.058 wt%; about 0.059 wt%; about 0.060 wt%; about 0.061 wt%; about 0.062 wt%; about 0.063 wt%; about 0.064 wt%; about 0.065 wt%; about 0.066 wt%; about 0.067 wt%; about 0.068 wt%; about 0.069 wt%; about 0.070 wt%; about 0.071 wt%; about 0.072 wt%; about 0.073 wt%; about 0.074 wt%; about 0.075 wt%; about 0.076 wt%; about 0.077 wt%; about 0.078 wt%; about 0.079 wt%; about 0.080 wt%; about 0.081 wt%; about 0.082 wt%; about 0.083 wt%; about 0.084 wt%; about 0.085 wt%; about 0.086 wt%; about 0.087 wt%; about 0.088 wt%; about 0.089 wt%; about 0.090 wt%; about 0.091 wt%; about 0.092 wt%; about 0.093 wt%; about 0.094 wt%; about 0.095 wt%; about 0.096 wt%; about 0.097 wt%; about 0.098 wt%; about 0.099 wt%; about 0.100 wt%; about 0.101 wt%; about 0.102 wt%; about 0.103 wt%; about 0.104 wt%; about 0.105 wt%; about 0.106 wt%; about 0.107 wt%; about 0.108 wt%; about 0.109 wt%; about 0.110 wt%; about 0.111 wt%; about 0.112 wt%; about 0.113 wt%; about 0.114 wt%; about 0.115 wt%; about 0.116 wt%; about 0.117 wt%; about 0.118 wt%; about 0.119 wt%; about 0.120 wt%; about 0.121 wt%; about 0.122 wt%; about 0.123 wt%; about 0.124 wt%; about 0.125 wt%; about 0.126 wt%; about 0.127 wt%; about 0.128 wt%; about 0.129 wt%; about 0.130 wt%; about 0.131 wt%; about 0.132 wt%; about 0.133 wt%; about 0.134 wt%; about 0.135 wt%; about 0.136 wt%; about 0.137 wt%; about 0.138 wt%; about 0.139 wt%; about 0.140 wt%; about 0.141 wt%; about 0.142 wt%; about 0.143 wt%; about 0.144 wt%; about 0.145 wt%; about 0.146 wt%; about 0.147 wt%; about 0.148 wt%; about 0.149 wt%; about 0.150 wt%; about 0.151 wt%; about 0.152 wt%; about 0.153 wt%; about 0.154 wt%; about 0.155 wt%; about 0.156 wt%; about 0.157 wt%; about 0.158 wt%; about 0.159 wt%; about 0.160 wt%; about 0.161 wt%; about 0.162 wt%; about 0.163 wt%; about 0.164 wt%; about 0.165 wt%; about 0.166 wt%; about 0.167 wt%; about 0.168 wt%; about 0.169 wt%; about 0.170 wt%; about 0.171 wt%; about 0.172 wt%; about 0.173 wt%; about 0.174 wt%; about 0.175 wt%; about 0.176 wt%; about 0.177 wt%; about 0.178 wt%; about 0.179 wt%; about 0.180 wt%; about 0.181 wt%; about 0.182 wt%; about 0.183 wt%; about 0.184 wt%; about 0.185 wt%; about 0.186 wt%; about 0.187 wt%; about 0.188 wt%; about 0.189 wt%; about 0.190 wt%; about 0.191 wt%; about 0.192 wt%; about 0.193 wt%; about 0.194 wt%; about 0.195 wt%; about 0.196 wt%; about 0.197 wt%; about 0.198 wt%; about 0.199 wt%; about 0.200 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized.

In one aspect, the second cooling composition can be present in an amount of about 0.005 wt.% to about 0.2 wt.%, based on the total weight of the woven fabric. In further aspects, the second cooling composition can be about 0.005 wt% based on the total weight of the woven fabric; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.011 wt%; about 0.012 wt%; about 0.013 wt%; about 0.014 wt%; about 0.015 wt%; about 0.016 wt%; about 0.017 wt%; about 0.018 wt%; about 0.019 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.020 wt%; about 0.021 wt%; about 0.022 wt%; about 0.023 wt%; about 0.024 wt%; about 0.025 wt%; about 0.026 wt%; about 0.027 wt%; about 0.028 wt%; about 0.029 wt%; about 0.030 wt%; about 0.031 wt%; about 0.032 wt%; about 0.033 wt%; about 0.034 wt%; about 0.035 wt%; about 0.036 wt%; about 0.037 wt%; about 0.038 wt%; about 0.039 wt%; about 0.040 wt%; about 0.041 wt%; about 0.042 wt%; about 0.043 wt%; about 0.044 wt%; about 0.045 wt%; about 0.046 wt%; about 0.047 wt%; about 0.048 wt%; about 0.049 wt%; about 0.050 wt%; about 0.051 wt%; about 0.052 wt%; about 0.053 wt%; about 0.054 wt%; about 0.055 wt%; about 0.056 wt%; about 0.057 wt%; about 0.058 wt%; about 0.059 wt%; about 0.060 wt%; about 0.061 wt%; about 0.062 wt%; about 0.063 wt%; about 0.064 wt%; about 0.065 wt%; about 0.066 wt%; about 0.067 wt%; about 0.068 wt%; about 0.069 wt%; about 0.070 wt%; about 0.071 wt%; about 0.072 wt%; about 0.073 wt%; about 0.074 wt%; about 0.075 wt%; about 0.076 wt%; about 0.077 wt%; about 0.078 wt%; about 0.079 wt%; about 0.080 wt%; about 0.081 wt%; about 0.082 wt%; about 0.083 wt%; about 0.084 wt%; about 0.085 wt%; about 0.086 wt%; about 0.087 wt%; about 0.088 wt%; about 0.089 wt%; about 0.090 wt%; about 0.091 wt%; about 0.092 wt%; about 0.093 wt%; about 0.094 wt%; about 0.095 wt%; about 0.096 wt%; about 0.097 wt%; about 0.098 wt%; about 0.099 wt%; about 0.100 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In one aspect, the second cooling composition can be present in an amount of about 0.1 wt% to about 2.0 wt% based on the total weight of the woven fabric. In further aspects, the second cooling composition can be about 0.1 wt% based on the total weight of the woven fabric; about 0.2 wt%; about 0.3 wt%; about 0.4 wt%; about 0.5 wt%; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; about 1.6 wt%; about 1.7 wt%; about 1.8 wt%; about 1.9 wt%; about 2.0 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or may exist using any collection of the preceding values.

In further aspects, the second cooling composition can comprise about 0.005 wt% to about 0.150 wt% of the second cooling material, based on the total weight of the woven fabric; about 0.0001 wt% to about 0.009 wt% of a second cooling compound; about 0.00005 wt% to about 0.002 wt% of a second cooling salt or a combination thereof; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the second cooling composition can comprise about 0.007 wt% to about 0.150 wt% of the second cooling material, based on the total weight of the woven fabric; about 0.0005 wt% to about 0.007 wt% of a second cooling compound; about 0.00005 wt% to about 0.0015 wt% of a second cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the second cooling composition can comprise about 0.010 wt% to about 0.100 wt% of the second cooling material based on the total weight of the woven fabric; about 0.0007 wt% to about 0.005 wt% of a second cooling compound; and about 0.00005 wt% to about 0.001 wt% of a second cooling salt; and wherein wt% is based on the total weight of the woven fabric. In even further aspects, the second cooling composition can comprise about 0.010 wt% to about 0.090 wt%, based on the total weight of the woven fabric, of the second cooling material; about 0.0010 wt% to about 0.0060 wt% of a second cooling compound; and about 0.0001 wt% to about 0.0003 wt% of a second cooling salt; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the second cooling composition can comprise about 0.01 wt% to about 1.0 wt% of the second cooling material based on the total weight of the woven fabric; about 0.01 wt% to about 1.5 wt% of a second cooling compound; about 0.001 wt% to about 0.20 wt% of a second cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the second cooling composition can comprise about 0.05 wt% to about 1.0 wt% of the second cooling material based on the total weight of the woven fabric; about 0.05 wt% to about 1.0 wt% of a second cooling compound; about 0.005 wt% to about 0.15 wt% of a second cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the woven fabric. In yet further aspects, the second cooling composition can comprise about 0.1 wt% to about 0.75 wt% of the second cooling material based on the total weight of the woven fabric; about 0.1 wt% to about 0.9 wt% of a second cooling compound; and about 0.01 wt% to about 0.15 wt% of a second cooling salt; and wherein wt% is based on the total weight of the woven fabric. In even further aspects, the second cooling composition can comprise about 0.15 wt% to about 0.50 wt% of the second cooling material, based on the total weight of the woven fabric; about 0.15 wt% to about 0.75 wt% of a second cooling compound; and about 0.01 wt% to about 0.15 wt% of a second cooling salt; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the second cooling material can be present in the second cooling composition in an amount from about 0.005 wt% to about 0.150 wt%; and wherein wt% is based on the total weight of the woven fabric. In still further aspects, the second cooling material can be present in an amount of about 0.007 wt% to about 0.150 wt%; and wherein wt% is based on the total weight of the woven fabric. In still further aspects, the second cooling material can be present in an amount of about 0.010 wt% to about 0.100 wt%; and wherein wt% is based on the total weight of the woven fabric. In even further aspects, the second cooling material can be present in an amount of about 0.010 wt% to about 0.090 wt%; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the second cooling material can be about 0.005 wt% based on the total weight of the woven fabric; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.011 wt%; about 0.012 wt%; about 0.013 wt%; about 0.014 wt%; about 0.015 wt%; about 0.016 wt%; about 0.017 wt%; about 0.018 wt%; about 0.019 wt%; about 0.020 wt%; about 0.021 wt%; about 0.022 wt%; about 0.023 wt%; about 0.024 wt%; about 0.025 wt%; about 0.026 wt%; about 0.027 wt%; about 0.028 wt%; about 0.029 wt%; 0.030 wt%; about 0.031 wt%; about 0.032 wt%; about 0.033 wt%; about 0.034 wt%; about 0.035 wt%; about 0.036 wt%; about 0.037 wt%; about 0.038 wt%; about 0.039 wt%; about 0.040 wt%; about 0.041 wt%; about 0.042 wt%; about 0.043 wt%; about 0.044 wt%; about 0.045 wt%; about 0.046 wt%; about 0.047 wt%; about 0.048 wt%; about 0.049 wt%; about 0.050 wt%; about 0.051 wt%; about 0.052 wt%; about 0.053 wt%; about 0.054 wt%; about 0.055 wt%; about 0.056 wt%; about 0.057 wt%; about 0.058 wt%; about 0.059 wt%; about 0.060 wt%; about 0.061 wt%; about 0.062 wt%; about 0.063 wt%; about 0.064 wt%; about 0.065 wt%; about 0.066 wt%; about 0.067 wt%; about 0.068 wt%; about 0.069 wt%; about 0.070 wt%; about 0.071 wt%; about 0.072 wt%; about 0.073 wt%; about 0.074 wt%; about 0.075 wt%; about 0.076 wt%; about 0.077 wt%; about 0.078 wt%; about 0.079 wt%; about 0.080 wt%; about 0.081 wt%; about 0.082 wt%; about 0.083 wt%; about 0.084 wt%; about 0.085 wt%; about 0.086 wt%; about 0.087 wt%; about 0.088 wt%; about 0.089 wt%; about 0.090 wt%; about 0.091 wt%; about 0.092 wt%; about 0.093 wt%; about 0.094 wt%; about 0.095 wt%; about 0.096 wt%; about 0.097 wt%; about 0.098 wt%; about 0.099 wt%; about 0.100 wt%; about 0.110 wt%; about 0.111 wt%; about 0.112 wt%; about 0.113 wt%; about 0.114 wt%; about 0.115 wt%; about 0.116 wt%; about 0.117 wt%; about 0.118 wt%; about 0.119 wt%; about 0.120 wt%; about 0.121 wt%; about 0.122 wt%; about 0.123 wt%; about 0.124 wt%; about 0.125 wt%; about 0.126 wt%; about 0.127 wt%; about 0.128 wt%; about 0.129 wt%; 0.130 wt%; about 0.131 wt%; about 0.132 wt%; about 0.133 wt%; about 0.134 wt%; about 0.135 wt%; about 0.136 wt%; about 0.137 wt%; about 0.138 wt%; about 0.139 wt%; about 0.140 wt%; about 0.141 wt%; about 0.142 wt%; about 0.143 wt%; about 0.144 wt%; about 0.145 wt%; about 0.146 wt%; about 0.147 wt%; about 0.148 wt%; about 0.149 wt%; about 0.150 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling material can be present in the second cooling composition in an amount from about 0.01 wt% to about 1.0 wt%; and wherein wt% is based on the total weight of the woven fabric. In still further aspects, the second cooling material can be present in an amount of about 0.05 wt% to about 1.0 wt%; and wherein wt% is based on the total weight of the woven fabric. In still further aspects, the second cooling material can be present in an amount from about 0.1 wt% to about 0.75 wt%; and wherein wt% is based on the total weight of the woven fabric. In still further aspects, the second cooling material can be present in an amount of about 0.15 wt% to about 0.50 wt% of the second cooling material; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the second cooling material can be about 0.01 wt% based on the total weight of the woven fabric; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.1 wt%; about 0.2 wt%; about 0.3 wt%; about 0.4 wt%; about 0.5 wt%; about 0.6 wt%; about 0.7 wt%; about 0.8 wt%; about 0.9 wt%; about 1.0 wt%, utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling compound can be present at about 0.0001 wt% to about 0.009 wt%; about 0.0005 wt% to about 0.007 wt%; about 0.0007 wt% to about 0.005 wt%; (ii) present in the second cooling composition in an amount of from about 0.0010 wt% to about 0.0060 wt%; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the second cooling compound can be about 0.0001 wt% based on the total weight of the woven fabric; about 0.0002 wt%; about 0.0003 wt%; about 0.0004 wt%; about 0.0005 wt%; about 0.0010 wt%; about 0.0015 wt%; about 0.0020 wt%; about 0.0025 wt%; about 0.0030 wt%; about 0.0035 wt%; about 0.0040 wt%; about 0.0045 wt%; about 0.0050 wt%; about 0.0055 wt%; about 0.0060 wt%; about 0.0065 wt%; about 0.0070 wt%; about 0.0075 wt%; about 0.0080 wt%; about 0.0085 wt%; about 0.0090 wt%; about 0.0090 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling compound can be present at about 0.01 wt% to about 1.5 wt%; about 0.05 wt% to about 1.0 wt%; about 0.1 wt% to about 0.9 wt%; present in the second cooling composition in an amount of from about 0.15 wt% to about 0.75 wt%; and wherein wt% is based on the total weight of the woven fabric.

In further aspects, the second cooling compound can be about 0.01 wt% based on the total weight of the woven fabric; about 0.02 wt%; about 0.03 wt%; about 0.04 wt%; about 0.05 wt%; about 0.06 wt%; about 0.07 wt%; about 0.08 wt%; about 0.09 wt%; about 0.10 wt%; about 0.11 wt%; about 0.12 wt%; about 0.13 wt%; about 0.14 wt%; about 0.15 wt%; about 0.16 wt%; about 0.17 wt%; about 0.18 wt%; about 0.19 wt%; about 0.20 wt%; about 0.21 wt%; about 0.22 wt%; about 0.23 wt%; about 0.24 wt%; about 0.25 wt%; about 0.26 wt%; about 0.27 wt%; about 0.28 wt%; about 0.29 wt%; about 0.30 wt%; about 0.31 wt%; about 0.32 wt%; about 0.33 wt%; about 0.34 wt%; about 0.35 wt%; about 0.36 wt%; about 0.37 wt%; about 0.38 wt%; about 0.39 wt%; about 0.40 wt%; about 0.41 wt%; about 0.42 wt%; about 0.43 wt%; about 0.44 wt%; about 0.45 wt%; about 0.46 wt%; about 0.47 wt%; about 0.48 wt%; about 0.49 wt%; about 0.50 wt%; about 0.51 wt%; about 0.52 wt%; about 0.53 wt%; about 0.54 wt%; about 0.55 wt%; about 0.56 wt%; about 0.57 wt%; about 0.58 wt%; about 0.59 wt%; about 0.60 wt%; about 0.61 wt%; about 0.62 wt%; about 0.63 wt%; about 0.64 wt%; about 0.65 wt%; about 0.66 wt%; about 0.67 wt%; about 0.68 wt%; about 0.69 wt%; about 0.70 wt%; about 0.71 wt%; about 0.72 wt%; about 0.73 wt%; about 0.74 wt%; about 0.75 wt%; about 0.76 wt%; about 0.77 wt%; about 0.78 wt%; about 0.79 wt%; about 0.80 wt%; about 0.81 wt%; about 0.82 wt%; about 0.83 wt%; about 0.84 wt%; about 0.85 wt%; about 0.86 wt%; about 0.87 wt%; about 0.88 wt%; about 0.89 wt%; about 0.90 wt%; about 0.91 wt%; about 0.92 wt%; about 0.93 wt%; about 0.94 wt%; about 0.95 wt%; about 0.96 wt%; about 0.97 wt%; about 0.98 wt%; about 0.99 wt%; about 1.0 wt%; about 1.1 wt%; about 1.2 wt%; about 1.3 wt%; about 1.4 wt%; about 1.5 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling salt can be about 0.00005 wt% to about 0.002 wt% based on the total weight of the woven fabric; about 0.00005 wt% to about 0.0015 wt%; about 0.00005 wt% to about 0.001 wt%; about 0.0001 wt% to about 0.0003 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In further aspects, the second cooling salt can be about 0.00005 wt% based on the total weight of the woven fabric; about 0.00006 wt%; about 0.00007 wt%; about 0.00008 wt%; about 0.00009 wt%; about 0.00010 wt%; about 0.00011 wt%; about 0.00012 wt%; about 0.00013 wt%; about 0.00014 wt%; about 0.00015 wt%; about 0.00016 wt%; about 0.00017 wt%; about 0.00018 wt%; about 0.00019 wt%; about 0.00020 wt%; about 0.00021 wt%; about 0.00022 wt%; about 0.00023 wt%; about 0.00024 wt%; about 0.00025 wt%; about 0.00026 wt%; about 0.00027 wt%; about 0.00028 wt%; about 0.00029 wt%; about 0.00030 wt%; about 0.00031 wt%; about 0.00032 wt%; about 0.00033 wt%; about 0.00034 wt%; about 0.00035 wt%; about 0.00036 wt%; about 0.00037 wt%; about 0.00038 wt%; about 0.00039 wt%; about 0.00040 wt%; about 0.00041 wt%; about 0.00042 wt%; about 0.00043 wt%; about 0.00044 wt%; about 0.00045 wt%; about 0.00046 wt%; about 0.00047 wt%; about 0.00048 wt%; about 0.00049 wt%; about 0.00050 wt%; about 0.00051 wt%; about 0.00052 wt%; about 0.00053 wt%; about 0.00054 wt%; about 0.00055 wt%; about 0.00056 wt%; about 0.00057 wt%; about 0.00058 wt%; about 0.00059 wt%; about 0.00060 wt%; about 0.00061 wt%; about 0.00062 wt%; about 0.00063 wt%; about 0.00064 wt%; about 0.00065 wt%; about 0.00066 wt%; about 0.00067 wt%; about 0.00068 wt%; about 0.00069 wt%; about 0.00070 wt%; about 0.00071 wt%; about 0.00072 wt%; about 0.00073 wt%; about 0.00074 wt%; about 0.00075 wt%; about 0.00076 wt%; about 0.00077 wt%; about 0.00078 wt%; about 0.00079 wt%; about 0.00080 wt%; about 0.00081 wt%; about 0.00082 wt%; about 0.00083 wt%; about 0.00084 wt%; about 0.00085 wt%; about 0.00086 wt%; about 0.00087 wt%; about 0.00088 wt%; about 0.00089 wt%; about 0.00090 wt%; about 0.00091 wt%; about 0.00092 wt%; about 0.00093 wt%; about 0.00094 wt%; about 0.00095 wt%; about 0.00096 wt%; about 0.00097 wt%; about 0.00098 wt%; about 0.00099 wt%; about 0.0010 wt%; about 0.0011 wt%; about 0.0012 wt%; about 0.0013 wt%; about 0.0014 wt%; about 0.0015 wt%; about 0.0016 wt%; about 0.0017 wt%; about 0.0018 wt%; about 0.0019 wt%; about 0.0020 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

In various aspects, the second cooling salt can be about 0.001 wt% to about 0.20 wt% based on the total weight of the woven fabric; about 0.005 wt% to about 0.15 wt%; about 0.01 wt% to about 0.15 wt%; about 0.01 wt% to about 0.15 wt%; or any subrange within the foregoing range.

In further aspects, the second cooling salt can be about 0.001 wt% based on the total weight of the woven fabric; about 0.002 wt%; about 0.003 wt%; about 0.004 wt%; about 0.005 wt%; about 0.006 wt%; about 0.007 wt%; about 0.008 wt%; about 0.009 wt%; about 0.010 wt%; about 0.011 wt%; about 0.012 wt%; about 0.013 wt%; about 0.014 wt%; about 0.015 wt%; about 0.016 wt%; about 0.017 wt%; about 0.018 wt%; about 0.019 wt%; about 0.020 wt%; about 0.021 wt%; about 0.022 wt%; about 0.023 wt%; about 0.024 wt%; about 0.025 wt%; about 0.026 wt%; about 0.027 wt%; about 0.028 wt%; about 0.029 wt%; about 0.030 wt%; about 0.031 wt%; about 0.032 wt%; about 0.033 wt%; about 0.034 wt%; about 0.035 wt%; about 0.036 wt%; about 0.037 wt%; about 0.038 wt%; about 0.039 wt%; about 0.040 wt%; about 0.041 wt%; about 0.042 wt%; about 0.043 wt%; about 0.044 wt%; about 0.045 wt%; about 0.046 wt%; about 0.047 wt%; about 0.048 wt%; about 0.049 wt%; about 0.050 wt%; about 0.051 wt%; about 0.052 wt%; about 0.053 wt%; about 0.054 wt%; about 0.055 wt%; about 0.056 wt%; about 0.057 wt%; about 0.058 wt%; about 0.059 wt%; about 0.060 wt%; about 0.061 wt%; about 0.062 wt%; about 0.063 wt%; about 0.064 wt%; about 0.065 wt%; about 0.066 wt%; about 0.067 wt%; about 0.068 wt%; about 0.069 wt%; about 0.070 wt%; about 0.071 wt%; about 0.072 wt%; about 0.073 wt%; about 0.074 wt%; about 0.075 wt%; about 0.076 wt%; about 0.077 wt%; about 0.078 wt%; about 0.079 wt%; about 0.080 wt%; about 0.081 wt%; about 0.082 wt%; about 0.083 wt%; about 0.084 wt%; about 0.085 wt%; about 0.086 wt%; about 0.087 wt%; about 0.088 wt%; about 0.089 wt%; about 0.090 wt%; about 0.091 wt%; about 0.092 wt%; about 0.093 wt%; about 0.094 wt%; about 0.095 wt%; about 0.096 wt%; about 0.097 wt%; about 0.098 wt%; about 0.099 wt%; about 0.100 wt%; about 0.101 wt%; about 0.102 wt%; about 0.103 wt%; about 0.104 wt%; about 0.105 wt%; about 0.106 wt%; about 0.107 wt%; about 0.108 wt%; about 0.109 wt%; about 0.110 wt%; about 0.111 wt%; about 0.112 wt%; about 0.113 wt%; about 0.114 wt%; about 0.115 wt%; about 0.116 wt%; about 0.117 wt%; about 0.118 wt%; about 0.119 wt%; about 0.120 wt%; about 0.121 wt%; about 0.122 wt%; about 0.123 wt%; about 0.124 wt%; about 0.125 wt%; about 0.126 wt%; about 0.127 wt%; about 0.128 wt%; about 0.129 wt%; about 0.130 wt%; about 0.131 wt%; about 0.132 wt%; about 0.133 wt%; about 0.134 wt%; about 0.135 wt%; about 0.136 wt%; about 0.137 wt%; about 0.138 wt%; about 0.139 wt%; about 0.140 wt%; about 0.141 wt%; about 0.142 wt%; about 0.143 wt%; about 0.144 wt%; about 0.145 wt%; about 0.146 wt%; about 0.147 wt%; about 0.148 wt%; about 0.149 wt%; about 0.150 wt%; about 0.151 wt%; about 0.152 wt%; about 0.153 wt%; about 0.154 wt%; about 0.155 wt%; about 0.156 wt%; about 0.157 wt%; about 0.158 wt%; about 0.159 wt%; about 0.160 wt%; about 0.161 wt%; about 0.162 wt%; about 0.163 wt%; about 0.164 wt%; about 0.165 wt%; about 0.166 wt%; about 0.167 wt%; about 0.168 wt%; about 0.169 wt%; about 0.170 wt%; about 0.171 wt%; about 0.172 wt%; about 0.173 wt%; about 0.174 wt%; about 0.175 wt%; about 0.176 wt%; about 0.177 wt%; about 0.178 wt%; about 0.179 wt%; about 0.180 wt%; about 0.181 wt%; about 0.182 wt%; about 0.183 wt%; about 0.184 wt%; about 0.185 wt%; about 0.186 wt%; about 0.187 wt%; about 0.188 wt%; about 0.189 wt%; about 0.190 wt%; about 0.191 wt%; about 0.192 wt%; about 0.193 wt%; about 0.194 wt%; about 0.195 wt%; about 0.196 wt%; about 0.197 wt%; about 0.198 wt%; about 0.199 wt%; about 0.200 wt%; ranges of any of the foregoing values are utilized; utilizing subranges within the range of any preceding value; or any combination of the foregoing values, is utilized in the second cooling composition.

F. Article with a cover

In one aspect, the present disclosure is directed to an article comprising the disclosed composite yarn. In further aspects, the articles comprising the disclosed composite yarns are articles of apparel, including, but not limited to, pants, shirts, jackets, dresses, gloves, skirts, T-shirts, vests, multi-tops (poly tops), pullovers, men's or women's shorts, undergarments, long-underwear (long-jehn), beddings such as pajamas, bras, sweaters, shirts (skits), dresses, shirts, trousers, sportswear pants, shorts, socks, ties, jeans, gloves, coats, jackets, mittens (mitts), hats (hats), caps (caps), incontinence caps, helmets, morning clothing, infant clothing, such as gowns, pleats (drapes), overalls, mouth masks, uniforms such as chef jackets and aprons, and linings and towels for clothing. In yet further aspects, the articles comprising the disclosed composite yarns are sportswear articles. Apparel includes footwear, such as insoles, shoes, sandals, and athletic shoes (rainers). The fabric comprising the disclosed yarns and fabrics may constitute a part of, or preferably all of, a garment fabric. For example, it is possible to construct pants, shirts, T-shirts, each of which is a fabric of the present disclosure. Alternatively, only a portion of the garment may comprise the fabric of the present disclosure. For example, a garment such as a T-shirt or shirt may include the fabric of the present disclosure at locations (such as the 'armpits' or back of the garment) that are typically associated with greater heat and/or moisture production.

In further aspects, the article comprising the disclosed composite yarn is a drapery (drapery) article, a household textile, home furnishings, upholstery covering (upholstery cover), mattress, bed cover, mattress ticking, blanket, bed linen, table linen, bed sheets, quilt cover, blanket (throw), sleeping bag, or a combination of the foregoing. Items in the form of upholstery covers include, but are not limited to, upholstery covers for furniture, the institutional and commercial market (institutional and commercial market), and vehicle seats. In yet further aspects, the article comprising the disclosed composite yarn is a floor covering. In still further aspects, the article comprising the disclosed composite yarn is a handbag, furniture covering, tarpaulin, or vehicle seat.

In one aspect, the present disclosure is directed to an article comprising the disclosed double covered yarn. In further aspects, the articles comprising the disclosed double covered yarns are articles of apparel including, but not limited to, pants, shirts, jackets, dresses, gloves, skirts, T-shirts, vests, multi-tops, pullovers, men's or women's shorts, undergarments, gowns, such as pajamas, bras, woollen sweater, shorts, dress, shirts, trousers, sportswear pants, shorts, socks, ties, jeans, gloves, coats, jackets, mittens, hats, caps, topcoats, helmets, morning clothing, infant clothing, such as gowns, pleats, overalls, masks, uniforms such as chef jackets and aprons, and linings and towels for clothing. In yet further aspects, the article comprising the disclosed double covered yarn is a sportswear article. Apparel includes footwear such as insoles, shoes, sandals, and athletic shoes. The fabric comprising the disclosed yarns and fabrics may constitute a part of, or preferably all of, a garment fabric. For example, it is possible to construct pants, shirts, T-shirts, each of which is a fabric of the present disclosure. Alternatively, only a portion of the garment may comprise the fabric of the present disclosure. For example, a garment such as a T-shirt or shirt may include the fabric of the present disclosure at locations (such as the 'armpits' or back of the garment) that are typically associated with greater heat and/or moisture production.

In further aspects, the article comprising the disclosed double covered yarn is a drapery article, a household textile, a home decoration, an upholstery covering, a mattress, a bed cover, a mattress ticking, a blanket, a bed linen, a table linen, a bed sheet, a quilt cover, a coverlet, a sleeping bag, or a combination of the foregoing. Items in the form of upholstery covers include, but are not limited to, upholstery covers for furniture, the institutional and commercial markets, and transportation seats. In yet further aspects, the article comprising the disclosed double covered yarn is a floor covering. In still further aspects, the article comprising the disclosed double covered yarn is a handbag, furniture covering, tarpaulin, or vehicle seat.

In one aspect, the present disclosure is directed to an article comprising the disclosed fabric. In further aspects, the articles comprising the disclosed fabrics are articles of apparel, including, but not limited to, pants, shirts, jackets, dresses, gloves, skirts, T-shirts, vests, multi-tops, pullovers, men's or women's shorts, undergarments, coveralls, beddings such as pajamas, bras, woollen sweater, shorts, dress coats, blouses, trousers, sportswear pants, shorts, socks, ties, jeans, gloves, coats, jackets, boxing gloves, mittens, hats, caps, topcoats, helmets, morning clothing, infant clothing, such as gowns, pleats, overalls, masks, uniforms such as chef jackets and aprons, and linings and towels for clothing. In yet further aspects, the article comprising the disclosed fabric is a sportswear article. Apparel includes footwear such as insoles, shoes, sandals, and athletic shoes. The fabric comprising the disclosed yarns and fabrics may constitute a part of, or preferably all of, a garment fabric. For example, it is possible to construct pants, shirts, T-shirts, each of which is a fabric of the present disclosure. Alternatively, only a portion of the garment may comprise the fabric of the present disclosure. For example, a garment such as a T-shirt or shirt may include the fabric of the present disclosure at locations (such as the 'armpits' or back of the garment) that are typically associated with greater heat and/or moisture production.

In further aspects, the article comprising the disclosed fabric is a drapery article, a household textile, a home decoration, an upholstery covering, a mattress, a bed cover, a mattress ticking, a blanket, a bed cloth, a table cloth, a bed sheet, a quilt cover, a coverlet, a sleeping bag, or a combination of the foregoing. Items in the form of upholstery covers include, but are not limited to, upholstery covers for furniture, the institutional and commercial markets, and transportation seats. In yet further aspects, the article comprising the disclosed fabric is a floor covering. In still further aspects, the article comprising the disclosed fabric is a handbag, furniture covering, tarpaulin, or vehicle seat.

G. Aspects of the disclosure

The following list of exemplary aspects supports and is supported by the disclosure provided herein.

Aspect 1. a composite yarn comprising a core component and a sheath, wherein: (a) the core member comprises a polyester polymer and a first cooling composition; and (b) the sheath comprises a polyamide polymer and a second cooling composition; wherein the first cooling composition comprises a first cooling material, a first cooling compound, a first cooling salt, or a combination thereof; and wherein the second cooling composition comprises a second cooling material, a second cooling compound, and a second cooling salt.

Aspect 2. the composite yarn of aspect 1, wherein the polyester polymer is polyethylene terephthalate, polytrimethylene terephthalate, or a combination thereof.

Aspect 3. the composite yarn of aspect 2, wherein the polyester polymer is polyethylene terephthalate.

Aspect 4. the composite yarn of any one of aspects 1-3, wherein the first cooling composition can be present in an amount of about 0.001 wt% to about 5 wt%, based on the total weight of the polyester polymer and the cooling composition.

Aspect 5. the composite yarn of any one of aspects 1-4, wherein the first cooling composition comprises about 0.2 wt% to about 2 wt% of the first cooling material; about 0.02 wt% to about 0.07 wt% of the first cooling compound; about 0.001 wt% to about 0.02 wt% of the first cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

The composite yarn of any of aspects 1-5, wherein the first cooling composition comprises about 0.5 wt% to about 1 wt% of the first cooling material; about 0.03 wt% to about 0.05 wt% of the first cooling compound; about 0.001 wt% to about 0.01 wt% of the first cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 7. the composite yarn of any one of aspects 1-6, wherein the first cooling composition comprises about 0.2 wt% to about 2 wt% of the first cooling material; about 0.02 wt% to about 0.07 wt% of the first cooling compound; and about 0.001 wt% to about 0.02 wt% of the first cooling salt; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

The composite yarn of any of aspects 1-7, wherein the first cooling composition comprises about 0.5 wt% to about 1 wt% of the first cooling material; about 0.03 wt% to about 0.05 wt% of the first cooling compound; and about 0.001 wt% to about 0.01 wt% of the first cooling salt; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 9. the composite yarn of any one of aspects 1-8, wherein the first cooling material may be present in an amount of about 0.2 wt% to about 2 wt%; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 10. the composite yarn of aspect 9, wherein the first cooling material may be present in an amount of about 0.4 wt% to about 1 wt%; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 11. the composite yarn of aspect 9, wherein the first cooling material may be present in an amount of about 0.5 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 12 the composite yarn of any one of aspects 1-11, wherein the first cooling material is a metal, a metal alloy, a metal oxide, a carbon material, a ceramic material, a mineral, or a combination thereof.

The composite yarn of aspect 13. the composite yarn of aspect 12, wherein the mineral comprises silicon, zirconium, titanium, or a combination thereof.

Aspect 14. the composite yarn of aspect 13, wherein the zirconium-containing mineral is alloneite, baddeleyite, heterite, yttrialite, menezesite, or a combination thereof.

Aspect 15 the composite yarn of aspect 13, wherein the titanium-containing mineral is rutile, ilmenite, sphene, anatase, brookite, or a combination thereof.

Aspect 16 the composite yarn of aspect 13, wherein the mineral comprising silicon is quartz, granite, chalcedony, emerald, garnet, beryllite, olivine, mica, kaolinite, feldspar, zeolite, nephrite, agate, onyx, jasper, henry, flint, or a combination thereof.

Aspect 17 the composite yarn of aspect 13, wherein the mineral comprises zirconium and titanium; and wherein the mineral is perovskite, rare-earth gold, peat, brewsterite, cerite, Alasonite, Tatzgite, zircon, perovskite, TiZr thorite, or a combination thereof.

Aspect 18 the composite yarn of aspect 12, wherein the ceramic comprises alumina, aluminum titanate, zirconia, aluminum nitride, silicon carbide, silicon nitride, silicon aluminum nitride, or a combination thereof.

Aspect 19. the composite yarn of aspect 12, wherein the metal comprises silver, aluminum, copper, or combinations thereof.

Aspect 20 the composite yarn of aspect 19, wherein the metal comprises silver.

Aspect 21 the composite yarn of aspect 19, wherein the metal comprises copper.

Aspect 22 the composite yarn of aspect 19, wherein the metal comprises a mixture of copper and silver.

Aspect 23. the composite yarn of aspect 12, wherein the metal alloy comprises silver, aluminum, copper, or a combination thereof.

Aspect 24. the composite yarn of aspect 23, wherein the metal alloy comprises silver.

Aspect 25 the composite yarn of aspect 23, wherein the metal alloy comprises copper.

Aspect 26. the composite yarn of aspect 23, wherein the metal alloy comprises silver and copper.

Aspect 27 the composite yarn of aspect 12, wherein the metal oxide comprises gold (II) oxide, gold (III) oxide, silver (I) oxide, silver (II) oxide, silver (I, III) oxide, magnesium oxide, iron (II) oxide, iron (III) oxide, copper (I) oxide, copper (II) oxide, or a combination thereof.

Aspect 28. the composite yarn of aspect 27, wherein the metal oxide comprises silver (I) oxide, copper (II) oxide, or a combination thereof.

Aspect 29 the composite yarn of aspect 27, wherein the metal oxide comprises silver (I) oxide.

Aspect 30 the composite yarn of any one of aspects 4-26, wherein the first cooling material is a powder, a thread, a filament, a sheet, a granule, or a combination thereof.

Aspect 31 the composite yarn of aspect 30, wherein the first cooling material is a particulate, a powder, or a combination thereof.

Aspect 32 the composite yarn of aspect 31, wherein the first cooling material is particulate.

Aspect 33. the composite yarn of aspect 32, wherein the first cooling material is a nanoparticle, a microparticle, or a combination thereof.

Aspect 34 the composite yarn of aspect 33, wherein the nanoparticles have a size of about 10nm to about 100 nm.

The composite yarn of aspect 33, wherein the nanoparticles have a size of about 15nm to about 50 nm.

Aspect 36. the composite yarn of aspect 33, wherein the nanoparticles have a size of about 20nm to about 40 nm.

Aspect 37 the composite yarn of aspect 33, wherein the microparticles have a size of about 10 μ ι η to about 200 μ ι η.

Aspect 38 the composite yarn of aspect 33, wherein the microparticles have a size of about 20 μ ι η to about 100 μ ι η.

Aspect 39 the composite yarn of aspect 33, wherein the microparticles have a size of about 30 μ ι η to about 90 μ ι η.

Aspect 40 the composite yarn of aspect 33, wherein the microparticles have a size of about 40 μ ι η to about 80 μ ι η.

Aspect 41 the composite yarn of aspect 33, wherein the microparticles have a size of about 50 μ ι η to about 70 μ ι η.

Aspect 42. the composite yarn of any one of aspects 1-41, wherein the first cooling compound can be present in an amount of about 0.02 wt% to about 0.07 wt% of the first cooling compound; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

The composite yarn of any of aspects 43. 42, wherein the first cooling compound can be present in an amount of about 0.03 wt% to about 0.07 wt% of the first cooling compound; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

The composite yarn of any of aspects 44, 42, wherein the first cooling compound can be present in an amount of about 0.03 wt% to about 0.06 wt% of the first cooling compound; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

The composite yarn of any of aspects 45, 42, wherein the first cooling compound can be present in an amount of about 0.03 wt% to about 0.05 wt% of the first cooling compound; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 46. the composite yarn of any one of aspects 1-45, wherein the first cooling compound comprises a transition metal oxide, a group 13 oxide, a group 14 oxide, a transition metal carbide, a group 13 carbide, a group 14 carbide, a transition metal nitride, a group 13 nitride, a group 14 nitride, or a mixture thereof.

Aspect 47 the composite yarn of aspect 46, wherein the first cooling compound comprises alumina, silicon carbide, silica, titania trioxide, zirconia, or combinations thereof.

Aspect 48. the composite yarn of aspect 47, wherein the first cooling compound comprises alumina, silica, titania, or a combination thereof.

Aspect 49 the composite yarn of aspect 48, wherein the first cooling compound comprises titanium dioxide.

Aspect 50 the composite yarn of any one of aspects 42-49, wherein the first cooling compound is a powder, a thread, a filament, a sheet, a granule, or a combination thereof.

Aspect 51. the composite yarn of aspect 50, wherein the first cooling compound is a powder, a granule, or a combination thereof.

Aspect 52. the composite yarn of aspect 51, wherein the first cooling compound is a particulate.

Aspect 53 the composite yarn of aspect 52, wherein the particles are nanoparticles, microparticles, or a combination thereof.

Aspect 54 the composite yarn of aspect 53, wherein the nanoparticles have a size of about 10nm to about 100 nm.

Aspect 55 the composite yarn of aspect 53, wherein the nanoparticles have a size of about 15nm to about 50 nm.

Aspect 56 the composite yarn of aspect 53, wherein the nanoparticles have a size of about 20nm to about 40 nm.

Aspect 57 the composite yarn of aspect 53, wherein the microparticles have a size of about 10 μ ι η to about 200 μ ι η.

Aspect 58. the composite yarn of aspect 53, wherein the microparticles have a size of about 20 μm to about 100 μm.

Aspect 59. the composite yarn of aspect 53, wherein the microparticles have a size of about 30 μm to about 90 μm.

Aspect 60 the composite yarn of aspect 53, wherein the microparticles have a size of about 40 μm to about 80 μm.

Aspect 61 the composite yarn of aspect 53, wherein the microparticles have a size of about 50 μm to about 70 μm.

Aspect 62. the composite yarn of any one of aspects 1-61, wherein the first cooling salt may be present in an amount of about 0.001 wt% to about 0.02 wt% of the first cooling salt; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 63. the composite yarn of aspect 62, wherein the first cooling salt may be present in an amount of about 0.001 wt% to about 0.01 wt% of the first cooling salt; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 64. the composite yarn of aspect 62, wherein the first cooling salt may be present in an amount of about 0.002 wt% to about 0.01 wt% of the first cooling salt; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 65 the composite yarn of any one of aspects 1-64, wherein the first cooling salt is a group I salt, a group II salt, a transition metal salt, or a combination thereof.

Aspect 66. the composite yarn of aspect 65, wherein the first cooling salt is a group I salt.

Aspect 67. the composite yarn of aspect 65, wherein the first cooling salt is a group II salt.

Aspect 68. the composite yarn of aspect 65, wherein the first cooling salt is a transition metal salt.

Aspect 69 the composite yarn of aspect 68, wherein the first cooling salt is a transition metal salt comprising a cation of silver, copper, titanium, iron, nickel, zinc, gold, or a combination thereof.

Aspect 70 the composite yarn of any one of aspects 65-69, wherein the first cooling salt comprises a group I carbonate, a group I halide, a group I nitrate, or a combination thereof.

Aspect 71. the composite yarn of any one of aspects 65-69, wherein the first cooling salt comprises a group II carbonate, a group II halide, a group II nitrate, or a combination thereof.

Aspect 72 the composite yarn of any one of aspects 65-69, wherein the first cooling salt comprises a transition metal carbonate, a transition metal halide, a transition metal nitrate, or a combination thereof.

Aspect 73. the composite yarn of any one of aspects 65-72, wherein the first cooling salt comprises a group I carbonate, a group II carbonate, a transition metal carbonate, or a combination thereof.

Aspect 74 the composite yarn of aspect 73, wherein the first cooling salt comprises calcium carbonate.

Aspect 75 the composite yarn of any one of aspects 62-74, wherein the first cooling salt is a powder, a thread, a filament, a sheet, a granule, or a combination thereof.

Aspect 76. the composite yarn of aspect 75, wherein the first cooling salt is a powder, a granule, or a combination thereof.

Aspect 77 the composite yarn of aspect 76, wherein the first cooling salt is particulate.

Aspect 78 the composite yarn of aspect 77, wherein the particles have a size of about 10 μ ι η to about 1000 μ ι η.

Aspect 79 the composite yarn of aspect 77, wherein the particles have a size of about 30 μ ι η to about 500 μ ι η.

Aspect 80 the composite yarn of aspect 76, wherein the particles are nanoparticles, microparticles, or a combination thereof.

Aspect 81 the composite yarn of aspect 80, wherein the nanoparticles have a size of about 10nm to about 100 nm.

Aspect 82. the composite yarn of aspect 80, wherein the nanoparticles have a size of about 15nm to about 50 nm.

The composite yarn of aspect 80, wherein the nanoparticles have a size of about 20nm to about 40 nm.

Aspect 84. the composite yarn of aspect 80, wherein the microparticles have a size of about 10 μ ι η to about 200 μ ι η.

Aspect 85. the composite yarn of aspect 80, wherein the microparticles have a size of about 20 μ ι η to about 100 μ ι η.

Aspect 86 the composite yarn of aspect 80, wherein the microparticles have a size of about 30 μ ι η to about 90 μ ι η.

The composite yarn of aspect 80, wherein the microparticles have a size of about 40 μ ι η to about 80 μ ι η.

Aspect 88. the composite yarn of aspect 80, wherein the microparticles have a size of about 50 μ ι η to about 70 μ ι η.

The composite yarn of any one of aspects 1-88, wherein the polyamide polymer is nylon 6, nylon 4/6, nylon 6/6, nylon 6/10, nylon 6/12, nylon 11, nylon 12, or a combination thereof.

Aspect 90. the composite yarn of aspect 89, wherein the polyamide polymer is nylon 6/6.

Aspect 91 the composite yarn of any one of aspects 1-90, wherein the second cooling composition can be present in an amount of about 1 wt% to about 20 wt% based on the total weight of the polyamide polymer and the cooling composition.

The composite yarn of any of aspects 1-91, wherein the second cooling composition comprises from about 1 wt% to about 10 wt% of the second cooling material; about 1 wt% to about 15 wt% of the second cooling compound; about 0.1 wt% to about 5 wt% of the second cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

The composite yarn of any of aspects 1-92, wherein the second cooling composition comprises about 4 wt% to about 8 wt% of the second cooling material; about 5 wt% to about 10 wt% of the second cooling compound; about 0.3 wt% to about 2.5 wt% of the second cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 94. the composite yarn of any one of aspects 1-93, wherein the second cooling composition comprises about 1 wt% to about 10 wt% of the second cooling material; about 1 wt% to about 15 wt% of the second cooling compound; about 0.1 wt% to about 5 wt% of the second cooling salt; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 95 the composite yarn of any one of aspects 1-94, wherein the second cooling composition comprises about 4 wt% to about 8 wt% of the second cooling material; about 5 wt% to about 10 wt% of the second cooling compound; about 0.3 wt% to about 2.5 wt% of the second cooling salt; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 96 the composite yarn of any one of aspects 1-95, wherein the second cooling material may be present in an amount of about 1 wt% to about 10 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 97 the composite yarn of aspect 96, wherein the second cooling material may be present in an amount of about 4 wt% to about 8 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 98. the composite yarn of aspect 96, wherein the second cooling material may be present in an amount of about 5 wt% to about 7 wt%; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 99 the composite yarn of any one of aspects 1-98, wherein the second cooling material is a metal, a metal alloy, a metal oxide, a carbon material, a ceramic material, a mineral, or a combination thereof.

Aspect 100 the composite yarn of aspect 99, wherein the mineral comprises silicon, zirconium, titanium, or a combination thereof.

Aspect 101. the composite yarn of aspect 100, wherein the zirconium-containing mineral is alloneite, baddeleyite, heterite, yttrialite, menezesite, or a combination thereof.

Aspect 102. the composite yarn of aspect 100, wherein the titanium-containing mineral is rutile, ilmenite, sphene, anatase, brookite, or a combination thereof.

Aspect 103. the composite yarn of aspect 100, wherein the mineral comprising silicon is quartz, granite, chalcedony, emerald, garnet, beryllite, olivine, mica, kaolinite, feldspar, zeolite, nephrite, agate, onyx, jasper, henry, flint, or a combination thereof.

Aspect 104 the composite yarn of aspect 100, wherein the mineral comprises zirconium and titanium; and wherein the mineral is perovskite, rare-earth gold, peat, brewsterite, cerite, Alasonite, Tatzgite, zircon, perovskite, TiZr thorite, or a combination thereof.

Aspect 105 the composite yarn of aspect 99, wherein the ceramic comprises alumina, aluminum titanate, zirconia, aluminum nitride, silicon carbide, silicon nitride, silicon aluminum nitride, or a combination thereof.

Aspect 106 the composite yarn of aspect 99, wherein the metal comprises silver, aluminum, copper, or a combination thereof.

Aspect 107 the composite yarn of aspect 106, wherein the metal comprises silver.

Aspect 108. the composite yarn of aspect 106, wherein the metal comprises copper.

Aspect 109. the composite yarn of aspect 106, wherein the metal comprises a mixture of silver and copper.

Aspect 110 the composite yarn of aspect 99, wherein the metal alloy comprises silver, aluminum, copper, or a combination thereof.

Aspect 111 the composite yarn of aspect 110, wherein the metal alloy comprises silver.

Aspect 112 the composite yarn of aspect 110, wherein the metal alloy comprises copper.

Aspect 113 the composite yarn of aspect 110, wherein the metal alloy comprises silver and copper.

Aspect 114. the composite yarn of aspect 99, wherein the metal oxide comprises gold (II) oxide, gold (III) oxide, silver (I) oxide, silver (II) oxide, silver (I, III) oxide, magnesium oxide, iron (II) oxide, iron (III) oxide, copper (I) oxide, copper (II) oxide, or a combination thereof.

Aspect 115 the composite yarn of aspect 114, wherein the metal oxide comprises silver (I) oxide, copper (II) oxide, or a combination thereof.

Aspect 116 the composite yarn of aspect 114, wherein the metal oxide comprises silver (I) oxide.

The composite yarn of any of aspects 91-116, wherein the second cooling material is a powder, a thread, a filament, a sheet, a granule, or a combination thereof.

Aspect 118 the composite yarn of aspect 117, wherein the second cooling material is a particulate, a powder, or a combination thereof.

Aspect 119 the composite yarn of aspect 118, wherein the second cooling material is particulate.

Aspect 120 the composite yarn of aspect 119, wherein the particles are nanoparticles, microparticles, or a combination thereof.

Aspect 121 the composite yarn of aspect 120, wherein the nanoparticles have a size of about 10nm to about 100 nm.

Aspect 122. the composite yarn of aspect 120, wherein the nanoparticles have a size of about 15nm to about 50 nm.

Aspect 123 the composite yarn of aspect 120, wherein the nanoparticles have a size of about 20nm to about 40 nm.

The composite yarn of aspect 120, wherein the microparticles have a size of about 10 μ ι η to about 200 μ ι η.

Aspect 125 the composite yarn of aspect 120, wherein the microparticles have a size of about 20 μ ι η to about 100 μ ι η.

Aspect 126. the composite yarn of aspect 120, wherein the microparticles have a size of about 30 μ ι η to about 90 μ ι η.

Aspect 127. the composite yarn of aspect 120, wherein the microparticles have a size of about 40 μ ι η to about 80 μ ι η.

Aspect 128 the composite yarn of aspect 120, wherein the microparticles have a size of about 50 μ ι η to about 70 μ ι η.

The composite yarn of any of aspects 1-128, wherein the second cooling compound can be present in an amount of about 1 wt% to about 15 wt% of the second cooling compound; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 130. the composite yarn of any aspect 121, wherein the second cooling compound can be present in an amount of about 4 wt% to about 12 wt% of the second cooling compound; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 131 the composite yarn of any aspect 121, wherein the second cooling compound can be present in an amount of about 5 wt% to about 11 wt% of the second cooling compound; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

The composite yarn of any of aspects 121, wherein the second cooling compound can be present in an amount of about 6 wt% to about 10 wt% of the second cooling compound; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

Aspect 133 the composite yarn of any one of aspects 1-132, wherein the second cooling compound comprises a transition metal oxide, a group 13 oxide, a group 14 oxide, a transition metal carbide, a group 13 carbide, a group 14 carbide, a transition metal nitride, a group 13 nitride, a group 14 nitride, or a mixture thereof.

Aspect 134 the composite yarn of aspect 133, wherein the second cooling compound comprises alumina, silicon carbide, silica, titania trioxide, zirconia, or combinations thereof.

Aspect 135 the composite yarn of aspect 134, wherein the second cooling compound comprises alumina, silica, titania, or a combination thereof.

Aspect 136 the composite yarn of aspect 135, wherein the second cooling compound comprises titanium dioxide.

Aspect 137. the composite yarn of any one of aspects 129-136, wherein the first cooling compound is a powder, a thread, a filament, a sheet, a particle, or a combination thereof.

Aspect 138 the composite yarn of aspect 137, wherein the first cooling compound is a powder, a granule, or a combination thereof.

Aspect 139 the composite yarn of aspect 138, wherein the first cooling compound is a particulate.

Aspect 140 the composite yarn of aspect 139, wherein the particles are nanoparticles, microparticles, or a combination thereof.

Aspect 141. the composite yarn of aspect 140, wherein the nanoparticles have a size of about 10nm to about 100 nm.

Aspect 142 the composite yarn of aspect 140, wherein the nanoparticles have a size of about 15nm to about 50 nm.

Aspect 143 the composite yarn of aspect 140, wherein the nanoparticles have a size of about 20nm to about 40 nm.

Aspect 144 the composite yarn of aspect 140, wherein the microparticles have a size of about 10 μ ι η to about 200 μ ι η.

Aspect 145 the composite yarn of aspect 140, wherein the microparticles have a size of about 20 μ ι η to about 100 μ ι η.

Aspect 146 the composite yarn of aspect 140, wherein the microparticles have a size of about 30 μ ι η to about 90 μ ι η.

Aspect 147 the composite yarn of aspect 140, wherein the microparticles have a size of about 40 μ ι η to about 80 μ ι η.

Aspect 148 the composite yarn of aspect 140, wherein the microparticles have a size of about 50 μ ι η to about 70 μ ι η.

Aspect 149. the composite yarn of any one of aspects 1-148, wherein the second cooling salt can be present in an amount of about 0.1 wt% to about 5 wt% of the second cooling salt; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 150 the composite yarn of aspect 149, wherein the second cooling salt may be present in an amount of about 0.3 wt% to about 2.5 wt% of the second cooling salt; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 151. the composite yarn of aspect 149, wherein the second cooling salt can be present in an amount of about 0.5 wt% to about 2 wt% of the second cooling salt; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

Aspect 152 the composite yarn of any one of aspects 1-151, wherein the second cooling salt is a group I salt, a group II salt, a transition metal salt, or a combination thereof.

Aspect 153 the composite yarn of aspect 152, wherein the second cooling salt is a group I salt.

Aspect 154. the composite yarn of aspect 152, wherein the second cooling salt is a group II salt.

Aspect 155 the composite yarn of aspect 152, wherein the second cooling salt is a transition metal salt.

Aspect 156 the composite yarn of aspect 155, wherein the second cooling salt is a transition metal salt comprising a cation of silver, copper, titanium, iron, nickel, zinc, gold, or a combination thereof.

Aspect 157. the composite yarn of any one of aspects 152-156, wherein the second cooling salt comprises a group I carbonate, a group I halide, a group I nitrate, or a combination thereof.

Aspect 158 the composite yarn of any one of aspects 152-156, wherein the second cooling salt comprises a group II carbonate, a group II halide, a group II nitrate, or a combination thereof.

Aspect 159. the composite yarn of any one of aspects 152-156, wherein the second cooling salt comprises a transition metal carbonate, a transition metal halide, a transition metal nitrate, or a combination thereof.

Aspect 160 the composite yarn of any one of aspects 152-156, wherein the second cooling salt comprises a group I carbonate, a group II carbonate, a transition metal carbonate, or a combination thereof.

Aspect 161. the composite yarn of aspect 160, wherein the second cooling salt comprises calcium carbonate.

Aspect 162 the composite yarn of any one of aspects 149-161, wherein the second cooling salt is a powder, a thread, a filament, a sheet, a pellet, or a combination thereof.

Aspect 163. the composite yarn of aspect 162, wherein the second cooling salt is a powder, a granule, or a combination thereof.

Aspect 164. the composite yarn of aspect 163, wherein the second cooling salt is particulate.

Aspect 165 the composite yarn of aspect 164, wherein the particles have a size of about 10 μ ι η to about 1000 μ ι η.

Aspect 166. the composite yarn of aspect 164, wherein the particles have a size of about 30 μ ι η to about 500 μ ι η.

Aspect 167 the composite yarn of aspect 164, wherein the particle is a nanoparticle, a microparticle, or a combination thereof.

Aspect 168. the composite yarn of aspect 167, wherein the nanoparticles have a size of about 10nm to about 100 nm.

Aspect 169 the composite yarn of aspect 167, wherein the nanoparticles have a size of about 15nm to about 50 nm.

Aspect 170 the composite yarn of aspect 167, wherein the nanoparticles have a size of about 20nm to about 40 nm.

The composite yarn of aspect 171, aspect 167, wherein the microparticles have a size of about 10 μ ι η to about 200 μ ι η.

Aspect 172. the composite yarn of aspect 167, wherein the microparticles have a size of about 20 μ ι η to about 100 μ ι η.

Aspect 173 the composite yarn of aspect 167, wherein the microparticles have a size of about 30 μ ι η to about 90 μ ι η.

Aspect 174 the composite yarn of aspect 167, wherein the microparticles have a size of about 40 μ ι η to about 80 μ ι η.

Aspect 175 the composite yarn of aspect 167, wherein the microparticles have a size of about 50 μ ι η to about 70 μ ι η.

The composite yarn of any one of aspects 1-175, wherein the composite yarn has a weight of about 70d/30f to about 80d/40 f.

Aspect 177. the composite yarn of aspect 152, wherein the composite yarn has a weight of about 75d/36f ± 10%.

The composite yarn of aspect 152, wherein the composite yarn has a weight of about 75d/36f ± 5%.

Aspect 179. the composite yarn of aspect 152, wherein the composite yarn has a weight of about 75d/36f ± 3%.

The composite yarn of any of aspects 1-179, wherein the composite yarn comprises from about 30 wt% to about 60 wt% of the polyester and the first cooling composition and from about 30 wt% to about 60 wt% of the polyamide and the second cooling composition.

Aspect 181 the composite yarn of aspect 180, wherein the composite yarn comprises about 45 wt% to about 55 wt% of the polyester and the first cooling composition and about 45 wt% to about 55 wt% of the polyamide and the second cooling composition.

The composite yarn of aspect 180, wherein the composite yarn comprises about 48 wt% to about 52 wt% of the polyester and the first cooling composition and about 48 wt% to about 52 wt% of the polyamide and the second cooling composition.

The composite yarn of aspect 180, wherein the composite yarn comprises about 50 wt% of the polyester and the first cooling composition and about 50 wt% of the polyamide and the second cooling composition.

Aspect 184. an article comprising the composite yarn of any one of aspects 1-183.

Aspect 185 the article of aspect 184, wherein the article is an article of apparel.

Aspect 186 the article of aspect 185, wherein the article of apparel is a pair of pants, a shirt, a jacket, a dress, or a skirt.

Aspect 187 the article of aspect 184, wherein the article is a sportswear article.

Aspect 188 is the article of aspect 184, wherein the article is a drape article.

Aspect 189 the article of aspect 184, wherein the article is a floor covering.

Aspect 190 the article of aspect 184, wherein the article is a purse, furniture covering, tarpaulin, or vehicle seat.

Aspect 191. a double covered yarn, comprising: (a) an elastic core comprising elastic yarns; (b) a first yarn comprising the composite yarn of any one of aspects 1-183; and (c) a second yarn comprising cellulosic fibers; wherein the first yarn is wound around a core yarn to form a single covered yarn; and wherein the second yarn is wrapped around the single covered yarn to form a double covered yarn.

Aspect 192. the double-covered yarn of aspect 191, wherein the elastic core comprises spandex yarn, polyester yarn, or a combination thereof.

Aspect 193 the double-covered yarn of aspect 192, wherein the polyester yarn is a yarn comprising polyethylene terephthalate, polytrimethylene terephthalate, or a combination thereof.

Aspect 194. the double-covered yarn of aspect 193, wherein the polyester yarn comprises a composite filament of polyethylene terephthalate and polypropylene terephthalate; and wherein the filaments have polyethylene terephthalate and polypropylene terephthalate arranged side-by-side.

Aspect 195. the double-covered yarn of aspect 192-194, wherein the elastic core comprises spandex yarn and polyester yarn, the polyester yarn comprising polyethylene terephthalate, polypropylene terephthalate, or a combination thereof.

Aspect 196. the double-coated yarn of aspect 191-196, wherein the elastic yarn has a weight of about 30 denier to about 50 denier.

Aspect 197. the double covered yarn of aspect 196, wherein the elastic yarn has a weight of about 35 denier to about 45 denier.

Aspect 198. the double-covered yarn of aspect 196, wherein the elastic yarn has a weight of about 36 denier to about 44 denier.

Aspect 199 the double covered yarn of aspect 196, wherein the elastic yarn has a weight of about 37 denier to about 43 denier.

Aspect 200 the double-covered yarn of aspect 196, wherein the elastic yarn has a weight of about 38 denier to about 42 denier.

Aspect 201. the double-covered yarn of aspect 196, wherein the elastic yarn has a weight of about 39 denier to about 41 denier.

Aspect 202. the double coated yarn of any one of aspects 191-201, wherein the draw ratio is from about 2.5 to about 5.

Aspect 203. the double covered yarn of aspect 202, wherein the draw ratio is from about 3 to about 4.

Aspect 204. the double-covered yarn of aspect 202, wherein the draw ratio is about 3.2 to about 3.8.

Aspect 205. the double-coated yarn of any one of aspects 191-204, wherein the cellulosic fiber is viscose.

Aspect 206. the double-covered yarn of aspect 205, wherein the viscose fiber is viscose rayon, or a combination thereof.

Aspect 207 the double-covered yarn of aspect 205, wherein the viscose is viscose rayon.

Aspect 208. the double coated yarn of any one of aspects 191-207, wherein the second yarn has a weight of about 105d/20f to about 130d/40 f.

Aspect 209. the double covered yarn of aspect 208, wherein the second yarn has a weight of about 115d/25f to about 135d/35 f.

Aspect 210. the double-covered yarn of aspect 208, wherein the second yarn has a weight of about 120d/30f ± 10%.

Aspect 211. the double-covered yarn of aspect 208, wherein the second yarn has a weight of about 120d/30f ± 5%.

Aspect 212. the double-covered yarn of aspect 208, wherein the second yarn has a weight of about 120d/30f ± 3%.

Aspect 213. the double coated yarn of any one of aspects 191-212, wherein the double coated yarn has a weight of about 250 denier to about 350 denier.

Aspect 214 double covered yarn of aspect 213, wherein the double covered yarn has a weight of about 270 denier to about 330 denier.

Aspect 215 the double-covered yarn of aspect 213, wherein the double-covered yarn has a weight of about 280 denier to about 320 denier.

Aspect 216 the double-covered yarn of aspect 213, wherein the double-covered yarn has a weight of about 285 denier to about 310 denier.

Aspect 217. the double covered yarn of aspect 213, wherein the double covered yarn has a weight of about 290 denier ± 10%.

Aspect 218 the double covered yarn of aspect 213, wherein the double covered yarn has a weight of about 290 denier ± 5%.

Aspect 219 the double-covered yarn of aspect 213, wherein the double-covered yarn has a weight of about 290 denier ± 3%.

Aspect 220. the double-covered yarn of any one of aspects 191-212, wherein the double-covered yarn has a weight of about 250 denier to about 360 denier.

Aspect 221 the double-covered yarn of aspect 213, wherein the double-covered yarn has a weight of about 270 denier to about 360 denier.

Aspect 222 the double-covered yarn of aspect 213, wherein the double-covered yarn has a weight of about 280 denier to about 360 denier.

Aspect 223 the double-covered yarn of aspect 213, wherein the double-covered yarn has a weight of about 285 denier to about 360 denier.

Aspect 224. the double-covered yarn of aspect 213, wherein the double-covered yarn has a weight of about 350 denier ± 10%.

Aspect 225 the double covered yarn of aspect 213, wherein the double covered yarn has a weight of about 350 denier ± 5%.

Aspect 226. the double covered yarn of aspect 213, wherein the double covered yarn has a weight of about 350 denier ± 3%.

Aspect 227. an article comprising the double-coated yarn of any one of aspects 191 and 226.

Aspect 228 the article of aspect 227, wherein the article is an article of apparel.

Aspect 229 the article of aspect 228, wherein the article of apparel is a pant, shirt, jacket, dress, or skirt.

Aspect 230 the article of aspect 227, wherein the article is a sportswear article.

Aspect 231. the article of aspect 227, wherein the article is a drape article.

Aspect 232 the article of aspect 227, wherein the article is a floor covering.

Aspect 233 the article of aspect 227, wherein the article is a handbag, furniture covering, tarpaulin, or vehicle seat.

Aspect 234. a fabric, comprising: weft yarns comprising the double coated yarns described in any one of aspects 191-219; and warp yarns comprising cotton fibers.

Aspect 235 the fabric of aspect 234, wherein the warp yarn is cotton yarn having a weight of about 8's to about 50's.

Aspect 236. the fabric of aspect 234 or 235, wherein the fabric is a warp-faced fabric.

Aspect 237. the fabric of any one of aspects 234 and 236, wherein the fabric is a left-handed twill weave; and wherein the left-handed twill weave has a diagonal extending from the right side to the left side of the fabric.

Aspect 238. the fabric of any one of aspects 234-236, wherein the fabric is a right-handed twill weave; and wherein the right-handed twill weave has a diagonal extending from the left side to the right side of the fabric.

Aspect 239 the fabric of any of aspects 234-238, wherein the weave pattern is a 3by 1 weave; and wherein 3 warp yarns are woven above and below the weft yarns.

Aspect 240 the fabric of any one of aspects 234-239, wherein the fabric comprises about 50 wt% to about 80 wt% cotton fibers; about 1 wt% to about 15 wt% of a polyester polymer; about 1 wt% to about 10 wt% of a polyamide polymer; and about 0.1 wt% to about 5 wt% of an elastic fiber or elastic filament.

Aspect 241. the fabric of aspect 240, wherein the fabric comprises about 55 wt% to about 75 wt% cotton fibers; about 8 wt% to about 12 wt% of a polyester polymer; about 4 wt% to about 8 wt% of a polyamide polymer; and about 1 wt% to about 4 wt% of an elastic fiber or elastic filament.

The fabric of aspect 240, aspect 242, wherein the fabric comprises about 60 wt% to about 75 wt% cotton fibers; about 8 wt% to about 10 wt% of a polyester polymer; about 4 wt% to about 7 wt% of a polyamide polymer; and about 2 wt% to about 4 wt% of an elastic fiber or elastic filament.

The fabric of aspect 240, wherein the fabric comprises about 55 wt% to about 70 wt% cotton fibers; about 8 wt% to about 12 wt% of a polyester polymer; about 4 wt% to about 8 wt% of a polyamide polymer; and about 1 wt% to about 4 wt% of an elastic fiber or elastic filament.

Aspect 244. the fabric of aspect 240, wherein the fabric comprises about 60 wt% to about 70 wt% cotton fibers; about 8 wt% to about 10 wt% of a polyester polymer; about 4 wt% to about 7 wt% of a polyamide polymer; and about 2 wt% to about 4 wt% of an elastic fiber or elastic filament.

Aspect 245 the fabric of any one of aspects 234 and 244, wherein the fabric has a weight of about 4oz/sy to about 12 oz/sy.

Aspect 246. the fabric of aspect 245, wherein the fabric has a weight of about 5oz/sy to about 10 oz/sy.

Aspect 247. the fabric of aspect 245, wherein the fabric has a weight of about 6oz/sy to about 10 oz/sy.

Aspect 248 the fabric of aspect 245, wherein the fabric has a weight of about 9.5oz/sy to about 10.5 oz/sy.

Aspect 249. the fabric of aspect 245, wherein the fabric has a weight of about 10oz/sy ± 10%.

Aspect 250. the fabric of aspect 245, wherein the fabric has a weight of about 10oz/sy ± 5%.

Aspect 251 the fabric of aspect 245, wherein the fabric has a weight of about 10oz/sy ± 3%.

Aspect 252. the fabric of aspect 245, wherein the fabric has a weight of about 4oz/sy to about 10 oz/sy.

Aspect 253. the fabric of aspect 245, wherein the fabric has a weight of about 5oz/sy to about 8 oz/sy.

Aspect 254 the fabric of aspect 245, wherein the fabric has a weight of about 5oz/sy to about 7 oz/sy.

Aspect 255 the fabric of aspect 245, wherein the fabric has a weight of about 5.5oz/sy to about 6.5 oz/sy.

Aspect 256. the fabric of aspect 245, wherein the fabric has a weight of about 6.25oz/sy ± 10%.

Aspect 257 the fabric of aspect 245, wherein the fabric has a weight of about 6.25oz/sy ± 5%.

Aspect 258. the fabric of aspect 245, wherein the fabric has a weight of about 6.25oz/sy ± 3%.

Aspect 259, the fabric of any of aspects 234-258, wherein the fabric has a Qmax value of about 0.15 to about 0.50, as determined according to FTTS-FA-019 as specified by the functional and industrial textile certification and verification council (taiwan).

Aspect 260. the fabric of aspect 259, wherein the fabric has a Qmax value of about 0.16 to about 0.25.

Aspect 261. the fabric of aspect 260, wherein the fabric has a Qmax value of about 0.16 ± 10%.

Aspect 262. the fabric of aspect 260, wherein the fabric has a Qmax value of about 0.16 ± 5%.

Aspect 263 the fabric of aspect 260, wherein the fabric has a Qmax value of about 0.16 ± 3%.

Aspect 264 the fabric of aspect 259, wherein the fabric has a Qmax value of about 0.17 to about 0.25.

Aspect 265. the fabric of aspect 264, wherein the fabric has a Qmax value of about 0.20 ± 10%.

Aspect 266. the fabric of aspect 264, wherein the fabric has a Qmax value of about 0.20 ± 5%.

Aspect 267. the fabric of aspect 264, wherein the fabric has a Qmax value of about 0.20 ± 3%.

Aspect 268. the fabric of any one of aspects 234-; and wherein the reference denim fabric consists essentially of cotton yarn, having a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric.

Aspect 269. the fabric of aspect 268, wherein the fabric has a Qmax value that is about 25% higher than the Qmax value of a reference denim fabric.

Aspect 270. the fabric of aspect 268, wherein the fabric has a Qmax value that is about 30% higher than the Qmax value of a reference denim fabric.

Aspect 271. the fabric of any one of aspects 234-270, wherein the fabric has a Qmax value that is about 20% higher than the Qmax value of a reference denim fabric; and wherein the reference denim fabric consists essentially of cotton yarn, having a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric.

Aspect 272. the fabric of aspect 271, wherein the fabric has a drying time of about 8 seconds to about 30 seconds.

Aspect 273. the fabric of aspect 271, wherein the fabric has a drying time of about 10 seconds to about 20 seconds.

Aspect 274 the fabric of aspect 271, wherein the fabric has a dry time of about 10 seconds to about 15 seconds.

Aspect 275. the fabric of any one of aspects 234 and 274, wherein the fabric has a wicking time of less than about 5 minutes to raise water to a length of 20mm when determined according to AATCC test method 197.

Aspect 276. the fabric of aspect 275, wherein the fabric has a wicking time of about 2 minutes to raise water to a length of 20 mm.

Aspect 277. the fabric of aspect 275, wherein the fabric has a wicking time of about 5 minutes to raise water to a length of 20 mm.

Aspect 278. the fabric of aspect 275, wherein the fabric has a wicking time of about 1 minute to raise water to a length of 20 mm.

Aspect 279. the fabric of any of aspects 234 and 278, wherein the fabric has a drying time that is at least about 100% faster than the drying time of a reference denim fabric, when determined according to AATCC test method 201; and wherein the reference denim fabric consists essentially of cotton yarn, having a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric.

Aspect 280. the fabric of aspect 275, wherein the fabric has a drying time that is at least about 20% faster than the drying time of the reference denim fabric.

Aspect 281. the fabric of aspect 275, wherein the fabric has a drying time that is at least about 25% faster than the drying time of the reference denim fabric.

Aspect 282. the fabric of aspect 275, wherein the fabric has a drying time that is at least about 30% faster than the drying time of the reference denim fabric.

Aspect 283 the fabric of aspect 275, wherein the fabric has a drying time that is at least about 40% faster than the drying time of the reference denim fabric.

Aspect 284 the fabric of aspect 275, wherein the fabric has a drying time that is at least about 50% faster than the drying time of the reference denim fabric.

Aspect 285. the fabric of any one of aspects 234-284, wherein the fabric has a drying rate of less than about 2.5ml/hr when determined according to AATCC test method 201.

Aspect 286 the fabric of aspect 271, wherein the fabric has a drying rate of about 0.5ml/hr to about 1.5 ml/hr.

Aspect 287. the fabric of aspect 271, wherein the fabric has a drying rate of about 0.5ml/hr to about 1.0 ml/hr.

Aspect 288 the fabric of aspect 271, wherein the fabric has a drying rate of about 0.7ml/hr to about 1.0 ml/hr.

Aspect 289. the fabric of aspect 271, wherein the fabric has a drying rate of about 0.5ml/hr to about 0.7 ml/hr.

Aspect 290. the fabric of any one of aspects 234-289, wherein the fabric has a UPF test value of at least about 1500 for dry evaluation and at least about 3500 for wet evaluation when tested according to AATCC test method 183.

Aspect 291 the fabric of aspect 290, wherein the fabric has a UPF test value of about 1500 to about 3000 for dry evaluation and about 3500 to about 4500 for wet evaluation.

Aspect 292. the fabric of aspect 290, wherein the fabric has a UPF test value of about 1700 to about 2800 for a dry evaluation and about 3700 to about 4300 for a wet evaluation.

The fabric of aspect 290, wherein the fabric has a UPF test value of about 2000 to about 2700 for dry evaluation and about 3800 to about 4200 for wet evaluation.

Aspect 294 the fabric of aspect 290, wherein the fabric has a UPF test value of about 2500 ± 10% for dry evaluation and about 4100 ± 10% for wet evaluation.

Aspect 295. the fabric of aspect 290, wherein the fabric has a UPF test value of about 2500 ± 5% for dry evaluation and about 4100 ± 5% for wet evaluation.

Aspect 296. the fabric of aspect 290, wherein the fabric has a UPF test value of about 2500 ± 3% for dry evaluation and about 4100 ± 3% for wet evaluation.

Aspect 297. the fabric of any of aspects 234-296, wherein the fabric has a UPF test value that is about 100% higher for dry evaluation and about 100% higher for wet evaluation than the UPF test value of a reference denim fabric, when determined according to AATCC test method 183; and wherein the reference denim fabric consists essentially of cotton yarn, having a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric.

Aspect 298. the fabric of aspect 297, wherein the fabric has a UPF test value that is about 200% higher for dry evaluation and about 200% higher for wet evaluation than the UPF test value of the reference denim fabric.

Aspect 299 the fabric of aspect 297, wherein the fabric has a UPF test value that is about 200% higher for dry evaluation and about 200% higher for wet evaluation than the UPF test value of the reference denim fabric.

Aspect 300. the fabric of aspect 297, wherein the fabric has a UPF test value that is about 300% higher for dry evaluation and about 300% higher for wet evaluation than the UPF test value of the reference denim fabric.

Aspect 301. an article comprising the fabric of any one of aspects 234 and 300.

Aspect 302 the article of aspect 301, wherein the article is an article of apparel.

Aspect 303 the article of aspect 302, wherein the article of apparel is a pair of pants, a shirt, a jacket, a dress, or a skirt.

Aspect 304 the article of aspect 301, wherein the article is a sportswear article.

Aspect 305 the article of aspect 301, wherein the article is a drape article.

Aspect 306 the article of aspect 301, wherein the article is a floor covering.

Aspect 307 the article of aspect 301, wherein the article is a handbag, furniture covering, tarpaulin, or vehicle seat.

Aspect 308. a cooling polymer composition comprising a polymer and a cooling composition comprising a cooling material, a cooling compound, a salt, or a combination thereof.

Aspect 309 the cooling polymer composition of aspect 308, wherein the polymer comprises a polyester polymer.

Aspect 310. the cooling polymer composition of aspect 308 or 309, wherein the polymer comprises polyethylene terephthalate, polytrimethylene terephthalate, or a combination thereof.

Aspect 311. the cooled polymer composition of any of aspects 308-310, wherein the polymer comprises polyethylene terephthalate.

Aspect 312. the cooling polymer composition of aspect 308, wherein the polymer comprises a polyamide.

Aspect 313. the cooling polymer composition of aspect 308 or 312, wherein the polyamide polymer is nylon 6, nylon 4/6, nylon 6/6, nylon 6/10, nylon 6/12, nylon 11, nylon 12, or a combination thereof.

Aspect 314. the cooling polymer composition of aspects 308 or 312-313 wherein the polyamide polymer is nylon 6/6.

Aspect 315 the cooled polymer composition of any of aspects 308-314, wherein the cooled composition can be present in an amount of about 0.001 wt% to about 5 wt%, based on the total weight of the polymer and the cooled composition.

Aspect 316. the cooled polymer composition of any of aspects 308-315, wherein the cooled composition comprises about 0.2 wt% to about 2 wt% of the first cooling material; about 0.02 wt% to about 0.07 wt% of a first cooling compound; about 0.001 wt% to about 0.02 wt% of a first cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 317 the cooled polymer composition of any one of aspects 308-316, wherein the cooled composition comprises from about 0.5 wt% to about 1 wt% of the first cooling material; about 0.03 wt% to about 0.05 wt% of a first cooling compound; about 0.001 wt% to about 0.01 wt% of a first cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 318. the cooled polymer composition of any one of aspects 308-317, wherein the cooled composition comprises about 0.2 wt% to about 2 wt% of the first cooling material; about 0.02 wt% to about 0.07 wt% of a first cooling compound; and about 0.001 wt% to about 0.02 wt% of a first cooling salt; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 319. the cooled polymer composition of any one of aspects 308-318, wherein the cooled composition comprises about 0.5 wt% to about 1 wt% of the first cooling material; about 0.03 wt% to about 0.05 wt% of a first cooling compound; and about 0.001 wt% to about 0.01 wt% of a first cooling salt; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 320. the cooled polymer composition of any of aspects 308-319, wherein the cooling material can be present in an amount of about 0.2 wt% to about 2 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition.

The cooled polymer composition of aspect 321. the cooled polymer composition of aspect 320, wherein the cooling material can be present in an amount of about 0.4 wt% to about 1 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 322. the cooled polymer composition of aspect 320, wherein the cooling material can be present in an amount from about 0.5 wt% to about 0.9 wt%; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 323. the cooling polymer composition of any one of aspects 308-322, wherein the cooling material is a metal, a metal alloy, a carbon material, a ceramic material, a mineral, or a combination thereof.

Aspect 324. the cooling polymer composition of aspect 323, wherein the metal is silver, aluminum, copper, or a combination thereof.

Aspect 325 the cooling polymer composition of aspect 324, wherein the metal is silver.

Aspect 326. the cooled polymer composition of aspect 323, wherein the metal alloy comprises silver, aluminum, copper, or a combination thereof.

Aspect 327. the cooled polymer composition of aspect 326, wherein the metal alloy comprises silver.

Aspect 328. the cooled polymer composition of aspect 324 or 326, wherein the metal or the metal alloy is a powder, a wire, a filament, a sheet, a particle, or a combination thereof.

Aspect 329. the cooled polymer composition of aspect 328, wherein the metal or the metal alloy is a particle, a powder, or a combination thereof.

Aspect 330 the cooling polymer composition of aspect 329, wherein the metal or the metal alloy is particulate.

The cooling polymer composition of aspect 330, aspect 331, wherein the metal is a nanoparticle, a microparticle, or a combination thereof.

Aspect 332 the cooling polymer composition of aspect 331, wherein the nanoparticles have a size of about 10nm to about 100 nm.

Aspect 333 the cooling polymer composition of aspect 331, wherein the nanoparticles have a size of about 15nm to about 50 nm.

Aspect 334 the cooling polymer composition of aspect 331, wherein the nanoparticles have a size of about 20nm to about 40 nm.

Aspect 335. the cooled polymer composition of any of aspects 308-334, wherein the cooling compound may be present in an amount of from about 0.02 wt% to about 0.07 wt% of the cooling compound; and wherein wt% is based on the total weight of the polymer and the cooling composition.

The cooled polymer composition of any aspect 335, wherein the first cooling compound can be present in an amount of about 0.03 wt% to about 0.07 wt% of the cooling compound; and wherein wt% is based on the total weight of the polymer and the cooling composition.

The cooled polymer composition of any aspect 337, wherein a cooling compound can be present in an amount of about 0.03 wt% to about 0.06 wt% of the cooling compound; and wherein wt% is based on the total weight of the polymer and the cooling composition.

The cooled polymer composition of any aspect 335, wherein a cooling compound can be present in an amount of about 0.03 wt% to about 0.05 wt% of the cooling compound; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 339 the cooled polymer composition of any of aspects 308-338, wherein the cooling compound comprises a transition metal oxide, a group 13 oxide, a group 14 oxide, a group 13 carbide, a group 14 carbide, or a mixture thereof.

Aspect 340. the cooling composition of aspect 339, wherein the cooling compound comprises magnesium oxide, aluminum oxide, silicon carbide, silicon dioxide, titanium dioxide, or a combination thereof.

Aspect 341 the cooling polymer composition of aspect 339, wherein the cooling compound comprises titanium dioxide.

Aspect 342. the cooled polymer composition of any one of aspects 339-341, wherein the cooling material is a powder, a pellet, or a combination thereof.

Aspect 343. the cooled polymer composition of aspect 342, wherein the particles are nanoparticles, microparticles, or a combination thereof.

Aspect 344. the cooled polymer composition of aspect 342 or 343, wherein the particles have a size of about 10 μ ι η to about 200 μ ι η.

Aspect 345 the cooled polymer composition of aspect 342 or 343, wherein the particles have a size of about 20 μ ι η to about 100 μ ι η.

Aspect 346. the cooled polymer composition of aspect 342 or 343, wherein the particles have a size of about 30 μ ι η to about 90 μ ι η.

Aspect 347 the cooled polymer composition of aspect 342 or 343, wherein the particles have a size of about 40 μ ι η to about 80 μ ι η.

Aspect 348. the cooled polymer composition of aspect 342 or 343, wherein the particles have a size of about 50 μ ι η to about 70 μ ι η.

Aspect 349. the cooled polymer composition of any one of aspects 308-348, wherein the salt can be present in an amount of from about 0.001 wt% to about 0.02 wt% of the salt; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 350. the cooled polymer composition of aspect 349, wherein the salt can be present in an amount of about 0.001 wt% to about 0.01 wt% of the salt; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 351. the cooled polymer composition of aspect 349, wherein the salt can be present in an amount of about 0.002 wt% to about 0.01 wt% of the salt; and wherein wt% is based on the total weight of the polymer and the cooling composition.

Aspect 352. the cooled polymer composition of any of aspects 308-351, wherein the salt is a group I salt, a group II salt, or a combination thereof.

Aspect 353. the cooling polymer composition of aspect 352, wherein the salt is a group I salt.

Aspect 354 the cooling polymer composition of aspect 352, wherein the salt is a group II salt.

Aspect 355. the cooled polymer composition of any of aspects 352 and 354, wherein the salt comprises a group I carbonate, a group I halide, a group I nitrate, or a combination thereof.

Aspect 356. the cooled polymer composition of any of aspects 352 and 354, wherein the salt comprises a group II carbonate, a group II halide, a group II nitrate, or a combination thereof.

Aspect 357 the cooled polymer composition of any of aspects 352 and 356, wherein the salt comprises a group I carbonate, a group II carbonate, or a combination thereof.

Aspect 358. the cooled polymer composition of any of aspects 352 and 356, wherein the salt comprises calcium carbonate.

Aspect 359. the cooled polymer composition of any one of aspects 352 and 358, wherein the salt is a powder, a granulate, or a combination thereof.

Aspect 360. the cooled polymer composition of aspect 359, wherein the particles have a size of about 10 μm to about 1000 μm.

Aspect 361 the cooled polymer composition of aspect 359, wherein the particles have a size of about 30 μ ι η to about 500 μ ι η.

Before the embodiments are explained, it is to be understood that this disclosure is not limited to particular aspects described, and as such may, of course, vary. Other systems, methods, features and advantages of the disclosed cooling compositions, yarns and fabrics will be or become apparent to one with skill in the art upon examination of the following figures and detailed description. It is intended that all such additional systems, methods, features and advantages be included within this description, be within the scope of the present disclosure, and be protected by the accompanying claims. It is also to be understood that the terminology used herein is for the purpose of describing particular aspects only and is not intended to be limiting. The skilled person will recognise many variations and alterations to the aspects described herein. Such modifications and variations are intended to be included herein within the teachings of this disclosure and encompassed by the claims herein.

H. Examples of the embodiments

The following examples are put forth so as to provide those of ordinary skill in the art with a complete disclosure and description of how the compounds, compositions, articles, devices, and/or methods claimed herein are made and evaluated, and are intended to be purely exemplary of the disclosure and are not intended to limit the scope of what the inventors regard as their disclosure. Efforts have been made to ensure accuracy with respect to numbers (e.g., amounts, temperature, etc.) but some errors and deviations may result. Unless otherwise indicated, parts are parts by weight, temperature is in degrees celsius or at ambient temperature, and pressure is at or near atmospheric.

Example 1.

Exemplary disclosed fabrics. Representative disclosed fabric samples were prepared with the following characteristics: 48 "X6.25 oz/sy; 67% cotton, 15% rayon, 9% polyester, 6% nylon, 3% spandex in aggregate fiber content; a warp-faced fabric having a pattern of 3/1 twill weaves. The fabric has warp yarns comprising cotton fibers and weft yarns comprising the disclosed double covered yarns. The warp yarn had a yarn count of 62.0Tex (9.5's/1) and the weft yarn was 40.0Tex (360.0 denier). The double covered yarn in the weft comprises a composite yarn comprising a core part and a sheath layer, the composite yarn comprising: (a) a core component of polyester yarn comprising: titanium oxide (0.034-0.05% by weight based on the total weight of the core member; particle size 50-70 μm), silver oxide (0.5-0.912% by weight based on the total weight of the core member; particle size: 20-35.5 nm) and calcium carbonate (0.002-0.01% by weight based on the total weight of the core member; particle size 35-500 μm); and (b) a sheath of nylon yarn comprising: titanium oxide (6.7-10.0% by weight based on the total weight of the sheath; particle size 50 μm-70 μm), silver oxide (5-7.0% by weight based on the total weight of the sheath; particle size 20nm-35.5nm), and calcium carbonate (0.59-2.0% by weight based on the total weight of the sheath; particle size 35 μm-500 μm).

The amounts of the foregoing cooling compositions were those determined in the sheath and core members by elemental analysis and quantitative compositional analysis using Field Emission Scanning Electron Microscopy (FESEM) performed with a FEI Teneo scanning electron microscope (FEI, inc., Hillsboro, Oregon, US) equipped with an ultra-large area detector for Energy dispersive spectroscopy (INCA Energy detector; Oxford Instruments, Concord, massachusssetts, US). The elemental analysis capabilities were provided using OXFORD XMAX software (OXFORD Instruments). The analysis area is selected under the "Scan Image" option. The original elemental analysis was performed under the "acquired spectra" option, and the final average analysis was presented under the "Fitted spectra tool".

Standard jean fabric. A comparative denim sample representing a commonly used standard denim fabric was prepared with the following characteristics: 52'. times.6.5 oz/sy; cotton with aggregate fiber content of 100%; a warp-faced fabric having a pattern of 3/1 twill weaves.

Representative disclosed fabric samples and comparative denim samples were tested to determine the following: (a) qmax was determined according to FTTS-FA-019 as specified by the functional and industrial textile certification and verification review Board (Taiwan, China); (b) the Drying time and Rate are determined according to AATCC 200 ("Drying Rate of textiles at their water absorption Capacity: Air Flow Method") and AATCC 201 ("Drying Rate of textiles: Hot Plate Method"); and (c) determining the UPF dry and wet assessments from AATCC 183 ("Transmission or Blocking of erythema Weighted Ultraviolet radiation through the fabric)"). The data obtained in these tests are given in table 1 below. All tests were performed by Intertek Testing Services Taiwan ltd. (8F, No.423, reiguang Rd., NeihuDistrict, Taipei 11492, Taiwan (r.o.c.)).

Table 1.

Not applicable according to AATCC 200 standard, i.e. the fabric takes more than 30 seconds to absorb water (absobency).

The data in table 1 show that the representative disclosed fabrics, i.e., the disclosed denim fabrics, have surprisingly superior thermal properties, as represented by the enhanced Qmax value of 34%; and the drying characteristics and UPF characteristics are significantly improved. For example, the representative disclosed fabric wicked 500% faster than the standard denim sample (reference, drying time of the representative disclosed fabric was 11.9 seconds, over 60 seconds relative to the drying time of the standard denim sample), and the drying rate was greatly improved (reference, drying rate of the representative disclosed fabric was 0.65ml/hr under test conditions, versus drying rate of the unmeasurable standard denim sample, i.e., the standard denim sample showed a water absorption capacity of greater than 30 seconds, thus failing to make a determination of a few ml/hr). Further, with respect to UPF properties, representative disclosed fabrics show a 320% improvement in dry evaluation and a 413% improvement in wet evaluation. The foregoing improvements are achievable when 100% cotton yarn is used in the warp weave, but the disclosed double covered yarn is incorporated in the weft weave.

Representative Scanning Electron Micrograph (SEM) images of representative disclosed fabric samples used in this example are shown in fig. 2A-2B. Representative SEM images of the warp yarns used in representative disclosed fabric samples of this example are shown in fig. 3A-3B. Representative SEM images of the weft yarns used in representative disclosed fabric samples of this example are shown in fig. 4A-4B. All SEM images were obtained from Georgia Electron Microscopy Center (University of Georgia, 151 Barrow Hall, 115 D.W. Brooks Drive, Athens GA 30602, USA).

Example 2.

Exemplary disclosed fabrics. Representative disclosed fabric samples were prepared with the following characteristics: 52 ". times.10 oz/sy; the content of the aggregated fiber is 72% of cotton, 8% of polyester, 5% of nylon, 13% of rayon and 2% of spandex; a warp-faced fabric having an 3/1 twill weave pattern and an 89 x 46 fabric count. The fabric has warp yarns comprising cotton fibers and weft yarns comprising the disclosed double covered yarns. The warp yarn had a yarn count of 62.0Tex (9.5's/1) and the weft yarn was 40.0Tex (360.0 denier). The double covered yarn in the weft comprises a composite yarn comprising a core part and a sheath layer, the composite yarn comprising: (a) a core component comprising a polyester and a cooling composition, comprising: titanium oxide (0.034-0.05% by weight based on the total weight of the core member; particle size 50-70 μm), silver oxide (0.5-0.912% by weight based on the total weight of the core member; particle size: 20-35.5 nm) and calcium carbonate (0.002-0.01% by weight based on the total weight of the core member; particle size 35-500 μm); and (b) a sheath of nylon yarn comprising: titanium oxide (6.7-10.0% by weight based on the total weight of the sheath; particle size 50-70 μm), silver oxide (5-7.0% by weight based on the total weight of the sheath; particle size 20-35.5 nm), and calcium carbonate (based on the total weight of the sheath; particle size 20-35.5 nm)0.59-2.0% by weight; particle size 35 μm to 500 μm).

Comparative fabric. The comparative fabric used and shown in table 2 below represents a conventional denim fabric commonly used. The conventional denim fabric used was: 98.0% cotton, 2.0% spandex, having an 3/1 twill weave pattern and a fabric count of 78 x 61 and a weight of 10 ounces per square yard; the warp yarn had a yarn count of 67.8Tex (8.7's/1) and the weft yarn was 67.3Tex (15.8's/1).

Representative disclosed fabric samples and comparative denim samples were tested to determine the following: (a) qmax was determined according to FTTS-FA-019 as specified by the functional and industrial textile certification and verification review Board (Taiwan, China); (b) the drying time and rate were determined according to AATCC 201 ("drying rate of fabric: Hot plate method"); (c) heat resistance was determined according to ISO 11092:2014 ("textile-Physiological effects-Measurement of heat resistance and resistance to water vapor under steady-state conditions (protective perspiration-hot plate test)"; and (d) vertical wicking as determined by AATCC 197. The data obtained in these tests are given in table 2 below. All tests were performed by Intertek Testing Services Taiwan ltd. (8F, No.423, reiguang Rd., Neihu discrict, Taipei 11492, Taiwan (r.o.c.)).

Table 2.

¹In terms of W/cm²Reported, and performed according to FTTS-FA-019.

²In Km²the/W is reported and is done according to ISO 11092: 2014.

Reported as cfm and performed according to ASTM 737.

Reported in minutes and performed according to AATCC 201.

Reported in ml/hr and performed according to AATCC 201.

Time to reach 20mm in length (minutes) as water level reported and performed according to AATCC 197.

According to AATCC 197, reported as the time (minutes) for the water level to reach 20mm in width.

Table 2, continue.

The data in table 2 shows that representative disclosed fabrics, i.e., disclosed denim fabrics comprising the disclosed double covered yarns and cotton yarns, have surprisingly superior fabric properties as demonstrated in Q max, moisture wicking and drying properties. For example, the representative disclosed fabric has a 500% faster moisture wicking rate (reference, wicking time of the representative disclosed fabric is 2 minutes, relative to wicking time of a standard denim sample is 13 minutes) and a substantially improved drying rate (reference, drying rate of the representative disclosed fabric under test conditions is 1.03ml/hr, relative to drying rate of a standard denim fabric is 0.53ml/hr) compared to a standard denim fabric.

Furthermore, the data in table 2 shows the Qmax values of the disclosed representative fabrics improved compared to standard denim fabrics. In particular, the Qmax value is improved by 16.8% compared to the standard denim fabric.

Overall, the disclosed representative fabrics show a surprisingly significant improvement in many characteristics and properties compared to conventional denim fabrics.

Example 3.

Exemplary disclosed fabrics. As described above for example 2.

Comparative fabric. The comparative fabric used and shown in table 3 below represents a standard denim fabric or other cooling fabric commonly used. Comparative fabric a: 9.7 oz/sy; the aggregate fiber content was 75% cotton, 23% polyester, 2% Lycra Elastane; a warp-faced fabric having an 3/1 twill weave pattern and a 116 x 66 fabric count. Comparative fabric B: 11 oz/sy; the content of the aggregated fiber is 70% of cotton, 28% of polyester and 2% of spandex; a warp-faced fabric having an 3/1 twill weave pattern and an 80 x 51 fabric count.

Representative disclosed fabric samples and comparative denim samples were tested to determine the following: (a) qmax was determined according to FTTS-FA-019 as specified by the functional and industrial textile certification and verification review Board (Taiwan, China); (b) the drying time and rate were determined according to AATCC 201 ("drying rate of fabric: Hot plate method"); (c) the heat resistance was determined according to ISO 11092:2014 ("textile-physiological effects-measurement of heat resistance and resistance to water vapor under steady state conditions (protective perspiration-hot plate test)"); and (d) vertical wicking as determined by AATCC 197. The data obtained in these tests are given in table 2 below. All tests were performed by Intertek Testing Services Taiwan ltd. (8F, No.423, reiguang Rd., Neihu discrict, Taipei 11492, Taiwan (r.o.c.)).

Table 3.

¹In terms of W/cm²Reported, and performed according to FTTS-FA-019.

²In Km²the/W is reported and is done according to ISO 11092: 2014.

Reported as cfm and performed according to ASTM 737.

Reported in minutes and performed according to AATCC 201.

Reported in ml/hr and performed according to AATCC 201.

Table 2, continue.

The data in table 2 shows that representative disclosed fabrics, i.e., disclosed denim fabrics comprising the disclosed double covered yarns and cotton yarns, have surprisingly superior fabric properties as evidenced by heat resistance, air permeability, and improved drying and wicking properties. For example, representative disclosed denim fabrics have a Qmax value increase of 48% -57% compared to the comparative conventional cooled denim fabrics, i.e., comparative fabrics a and B. It should be noted that the Qmax method determines the maximum heat loss or instantaneous cooling sensation of the fabric between temperatures of 25 ℃ and 35 ℃, i.e. the cooling characteristics associated with a short period of time.

Further, the representative disclosed denim fabric had a 50% increase in moisture wicking (reference, wicking time of the representative disclosed fabric was 2 minutes, wicking time of the cooled denim fabric was 4 minutes relative to the comparative), and a substantially increased drying rate (reference, drying rate of the representative disclosed fabric was 1.03ml/hr under test conditions, drying rate of the representative disclosed fabric was 0.83ml/hr relative to the comparative fabric a) compared to the comparative conventional cooled denim fabric.

Overall, the disclosed representative fabrics show surprisingly significant improvements in many properties and properties compared to conventional.

It will be apparent to those skilled in the art that various modifications and variations can be made in the present disclosure without departing from the scope or spirit of the disclosure. Other embodiments of the disclosure will be apparent to those skilled in the art from consideration of the specification and practice of the disclosure disclosed herein. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the disclosure being indicated by the following claims.

Claims

1. A composite yarn comprising a core component and a sheath layer, wherein:

(a) the core member comprises a polyester polymer and a first cooling composition; and is

(b) The sheath layer comprises a polyamide polymer and a second cooling composition;

wherein the first cooling composition comprises a first cooling material, a first cooling compound, a first cooling salt, or a combination thereof; and is

Wherein the second cooling composition comprises a second cooling material, a second cooling compound, a second cooling salt, or a combination thereof.

2. The composite yarn of claim 1, wherein the first cooling composition comprises: about 0.2 wt% to about 2 wt% of the first cooling material; about 0.02 wt% to about 0.07 wt% of the first cooling compound; about 0.001 wt% to about 0.02 wt% of the first cooling salt, or a combination thereof; and wherein wt% is based on the total weight of the polyester polymer and the cooling composition.

3. The composite yarn of claim 1, wherein the first cooling material comprises silver oxide, aluminum oxide, copper oxide, or combinations thereof.

4. The composite yarn of claim 1, wherein the first cooling material comprises nanoparticles; and wherein the nanoparticles have a size of about 10nm to about 100 nm.

5. The composite yarn of claim 1, wherein the first cooling compound comprises magnesium oxide, silicon carbide, silica, titanium dioxide, or combinations thereof.

6. The composite yarn of claim 1, wherein the first cooling compound is a nanoparticle; and wherein the nanoparticles have a size of about 10 μm to about 200 μm.

7. The composite yarn of claim 1, wherein the first cooling salt comprises a group II carbonate, a group II halide, a group II nitrate, or a combination thereof.

8. The composite yarn of claim 1, wherein the first cooling salt comprises particles having a size of about 10 μ ι η to about 1000 μ ι η.

9. The composite yarn of claim 1, wherein the polyamide polymer is nylon 6, nylon 4/6, nylon 6/6, nylon 6/10, nylon 6/12, nylon 11, nylon 12, or combinations thereof.

10. The composite yarn of claim 1, wherein the second cooling composition comprises: about 1 wt% to about 10 wt% of the second cooling material; about 1 wt% to about 15 wt% of the second cooling compound; about 0.1 wt% to about 5 wt% of the second cooling salt; and wherein wt% is based on the total weight of the polyamide polymer and the cooling composition.

11. The composite yarn of claim 1, wherein the yarn has a weight of about 75d/36f ± 10%.

12. The composite yarn of claim 1, wherein the yarn comprises from about 45 wt% to about 55 wt% of the polyester and the first cooling composition and from about 45 wt% to about 55 wt% of the polyamide and the second cooling composition.

13. A fabric, the fabric comprising:

a weft yarn comprising a double covered yarn; and

warp yarns comprising cotton fibers;

wherein the double covered yarn comprises:

(a) an elastic core comprising elastic yarns;

(b) a first yarn comprising a composite yarn; and

(c) a second yarn comprising cellulosic fibers;

wherein the composite yarn comprises:

(a) a core component comprising a polyester polymer and a first cooling composition; and

(b) a sheath comprising a polyamide polymer and a second cooling composition;

Wherein the second cooling composition comprises a second cooling material, a second cooling compound, a second cooling salt, or a combination thereof;

wherein the first yarn is wound around a core yarn to form a single covered yarn;

wherein the second yarn is wrapped around the single covered yarn to form a double covered yarn.

14. The fabric of claim 13, wherein said fabric comprises from about 50 wt% to about 70 wt% cotton fibers; about 1 wt% to about 15 wt% of a polyester polymer; about 1 wt% to about 10 wt% of a polyamide polymer; and about 0.1 wt% to about 5 wt% of an elastic fiber or elastic filament.

15. The fabric of claim 13 wherein the fabric has a weight of from about 4oz/sy to about 10 oz/sy.

16. The fabric of claim 13, wherein said fabric has a Qmax value of about 0.15 to about 0.50, when determined in accordance with FTTS-FA-019 as specified by the functional and industrial textile certification and verification council (taiwan).

17. The fabric of claim 13, wherein said fabric has a Qmax value that is about 20% higher than the Qmax value of a reference denim fabric; wherein the Qmax value is determined according to FTTS-FA-019 as specified by the functional and industrial textile certification and verification and review Committee (Taiwan, China); and wherein the reference denim fabric consists essentially of cotton yarn, having a fabric weight of ± 10% of the fabric and the same weave pattern as the fabric.

18. A fabric of claim 13, wherein said fabric has a wicking time of less than about 60 seconds, as determined according to AATCC test method 197.

19. A fabric of claim 13, wherein said fabric has a drying rate of less than about 2.5ml/hr as determined according to AATCC test method 200.

20. An article of apparel comprising the fabric of claim 13.