CN111287715B - A system for experimentally simulating the displacement of oil and gas by carbon dioxide - Google Patents
A system for experimentally simulating the displacement of oil and gas by carbon dioxide Download PDFInfo
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- CN111287715B CN111287715B CN202010238351.1A CN202010238351A CN111287715B CN 111287715 B CN111287715 B CN 111287715B CN 202010238351 A CN202010238351 A CN 202010238351A CN 111287715 B CN111287715 B CN 111287715B
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 30
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 27
- 238000006073 displacement reaction Methods 0.000 title claims abstract description 27
- 239000007788 liquid Substances 0.000 claims abstract description 50
- 238000004088 simulation Methods 0.000 claims abstract description 50
- 239000003208 petroleum Substances 0.000 claims abstract description 25
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 20
- 238000002347 injection Methods 0.000 claims abstract description 15
- 239000007924 injection Substances 0.000 claims abstract description 15
- 238000000605 extraction Methods 0.000 claims abstract description 14
- 239000000243 solution Substances 0.000 claims abstract description 14
- 239000004576 sand Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 51
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 35
- 239000003345 natural gas Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 7
- 208000010392 Bone Fractures Diseases 0.000 description 6
- 206010017076 Fracture Diseases 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005755 formation reaction Methods 0.000 description 5
- 239000003245 coal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003209 petroleum derivative Substances 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000013401 experimental design Methods 0.000 description 2
- 239000005431 greenhouse gas Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VTVVPPOHYJJIJR-UHFFFAOYSA-N carbon dioxide;hydrate Chemical compound O.O=C=O VTVVPPOHYJJIJR-UHFFFAOYSA-N 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- -1 coal bed gas Chemical compound 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011549 displacement method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/164—Injecting CO2 or carbonated water
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B49/00—Testing the nature of borehole walls; Formation testing; Methods or apparatus for obtaining samples of soil or well fluids, specially adapted to earth drilling or wells
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N13/00—Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N15/00—Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
- G01N15/08—Investigating permeability, pore-volume, or surface area of porous materials
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N13/00—Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects
- G01N2013/003—Diffusion; diffusivity between liquids
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N15/00—Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
- G01N2015/0007—Investigating dispersion of gas
- G01N2015/0015—Investigating dispersion of gas in solids
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N15/00—Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
- G01N15/08—Investigating permeability, pore-volume, or surface area of porous materials
- G01N2015/0866—Sorption
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
- Y02P90/70—Combining sequestration of CO2 and exploitation of hydrocarbons by injecting CO2 or carbonated water in oil wells
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Mining & Mineral Resources (AREA)
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- General Health & Medical Sciences (AREA)
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- Geochemistry & Mineralogy (AREA)
- Environmental & Geological Engineering (AREA)
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses an experimental system for simulating displacement of oil gas by carbon dioxide, which comprises a simulation chamber, a constant temperature box, a first booster pump, a first pressure sensing rod, a second booster pump, a second pressure sensing rod, a third booster pump, a third pressure sensing rod, a CH 4 gas cylinder, a CO 2 gas cylinder, a first conduit, a funnel, a liquid injection pipe, a liquid discharge pipe, a liquid container, a second conduit, a third conduit, a petroleum extraction bottle, a fourth conduit, a gas analyzer, a fifth conduit, a sixth conduit, a seventh conduit, a lime water solution bottle, an eighth conduit and an electronic balance.
Description
Technical Field
The invention belongs to the technical field of petroleum and natural gas exploitation, and relates to a system for experimentally simulating carbon dioxide displacement oil gas.
Background
Petroleum and natural gas are important strategic energy sources in China and have important significance in national economic development. In recent years, unconventional natural gas such as coal bed gas, shale gas and the like also develop rapidly in China, and the efficient exploitation and utilization of petroleum and natural gas can effectively relieve energy shortage. CO 2 is used as greenhouse gas, and large-scale emission can cause serious environmental damage, so that the temperature is increased, and the sea level is increased. The viscosity of petroleum can be effectively reduced, the natural gas can be replaced, and the oil and gas yield can be improved by replacing and displacing the petroleum and the natural gas with CO 2, and in addition, the carbon dioxide hydrate can be permanently sealed in an underground reservoir by replacing and displacing the petroleum and the natural gas, so that the method is a feasible method for reducing CO 2 emission. The advantages of carbon dioxide displacement and displacement of oil and gas are: carbon dioxide is injected into the stratum, so that the energy of the oil-gas layer can be improved, the viscosity of petroleum is reduced, and the flow of petroleum in the stratum is facilitated. The adsorption capacity of carbon dioxide to shale and coal rock is larger than that of methane, and when carbon dioxide is injected, CH 4 replacement efficiency can be effectively improved, and the yield of natural gas is improved. On one hand, with the increase of emission reduction pressure of greenhouse gases, carbon dioxide is injected into a stratum to displace and replace oil gas, so that the emission of carbon dioxide in the atmosphere can be reduced, the stability of an oil gas reservoir is maintained, and the environment-friendly value and the economic value are achieved.
At present, the development technology of carbon dioxide applied to oil and gas is still immature, the effect of improving the yield is controlled by different geological backgrounds of oil and gas reservoirs, and the difference of the survival states of different natural gases in stratum is large, such as the viscosity of petroleum and the survival state of the natural gases in stratum. Different formations may also have different configurations, such as fracture development, formation dip, etc. Regarding the carbon dioxide replacement and displacement efficiency and effect under different oil and gas stratum geological backgrounds, the replacement effect of carbon oxide replacement and displacement by different oil and gas saturation and natural gas storage states is not quantitatively evaluated yet, and related simulation experiment equipment is lacked.
Therefore, it is necessary to form an apparatus and system that experimentally simulates carbon dioxide displacement of hydrocarbon.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, and provides a system for experimentally simulating carbon dioxide displacement oil gas, which can simulate the development efficiency and effect of the oil gas under different geological backgrounds of a carbon dioxide displacement method.
In order to achieve the above purpose, the experimental simulation system for replacing displacement oil gas with carbon dioxide comprises a simulation chamber, a constant temperature box, a first booster pump, a first pressure sensing rod, a second booster pump, a second pressure sensing rod, a third booster pump, a third pressure sensing rod, a CH 4 gas cylinder, a CO 2 gas cylinder, a first conduit, a funnel, a liquid injection pipe, a liquid discharge pipe, a liquid container, a second conduit, a third conduit, a petroleum extraction bottle, a fourth conduit, a gas analyzer, a fifth conduit, a sixth conduit, a seventh conduit, a lime water solution bottle, an eighth conduit and an electronic balance;
The simulation chamber is positioned in the constant temperature box, sand bodies, mud and fracture plates are filled in the simulation chamber, a first pressure piston sheet is arranged on the outer side of the top of the simulation chamber, a second pressure piston sheet is arranged on the outer side of the right side of the simulation chamber, a third pressure piston sheet is arranged on the outer side of the front side of the simulation chamber, the first pressurizing pump is connected with the first pressure piston sheet through a first pressure sensing rod, the second pressurizing pump is connected with the second pressure piston sheet through a second pressure sensing rod, and the third pressurizing pump is connected with the third pressure piston sheet through a third pressure sensing rod;
The outlet of the CH 4 gas cylinder and the outlet of the CO 2 gas cylinder are communicated with one end of a first conduit, and the other end of the first conduit is communicated with an inlet on the left side surface of the simulation chamber;
the outlet of the funnel is communicated with the inlet at the top of the simulation chamber through a liquid injection pipe, and the liquid outlet at the bottom of the simulation chamber is communicated with the liquid container through a liquid discharge pipe;
The outlet on the right side surface of the simulation chamber is divided into two paths through a second conduit, one path is communicated with the petroleum extraction bottle through a third conduit, the other path is communicated with the inlet of the gas analyzer through a fourth conduit, the outlet of the gas analyzer is communicated with the inlet of a sixth conduit through a fifth conduit, one end of the seventh conduit is inserted into liquid in the petroleum extraction bottle, the other end of the seventh conduit is communicated with the inlet of the sixth conduit, the outlet of the sixth conduit is inserted into liquid in the lime water solution bottle, the inlet end of the eighth conduit is inserted into the lime water solution bottle, and the lime water solution bottle is positioned on an electronic balance.
The first conduit is provided with a first liquid pump, a first valve and a flowmeter.
The outlet of the CH 4 gas cylinder is provided with a second valve, the outlet of the CO 2 gas cylinder is provided with a third valve, and the outlet of the CH 4 gas cylinder is communicated with the first conduit through a ninth conduit.
The liquid injection pipe is provided with a fourth valve.
The liquid discharge pipe is provided with a fifth valve and a second liquid discharge pump.
The third conduit is provided with a sixth valve.
The fourth conduit is provided with a seventh valve.
The seventh conduit is provided with an eighth valve.
The eighth conduit is provided with a ninth valve.
The bottom of the incubator is provided with a bracket.
The invention has the following beneficial effects:
When the experimental system for simulating carbon dioxide displacement oil gas is specifically operated, the temperature and pressure conditions required by different geological strata are simulated by utilizing the constant temperature box and each pressurizing piston sheet, and the stratum spreading states of different experimental requirements are simulated according to the arrangement and combination of rock particles in a simulation chamber, the arrangement angles and the distribution of fracture plates. According to the pore distribution condition in the simulation chamber, petroleum or methane is injected into the simulation chamber to simulate the saturation of the oil-gas in the stratum. After stratum conditions conforming to actual geological conditions are arranged in the simulation chamber, CO 2 gas is injected into the simulation chamber, petroleum or methane gas is replaced and displaced through CO 2 gas, and replacement and displacement efficiency and effects under different conditions are calculated according to the petroleum quantity extracted by a petroleum extraction bottle or the methane quantity measured by a gas analyzer and the CO 2 gas quantity calculated in lime water, so that the aim of replacing and displacing different types of petroleum and gas by simulating carbon dioxide is fulfilled, and the device is simple in structure and convenient to operate.
Drawings
FIG. 1 is a schematic diagram of the structure of the present invention;
FIG. 2 is a schematic diagram of a low dip formation alignment;
FIG. 3 is a schematic view of a high angle formation and a fracture development formation.
Wherein 1 is CH 4 gas cylinder, 2 is CO 2 gas cylinder, 3 is second valve, 4 is ninth pipe, 5 is third valve, 6 is second drawing liquid pump, 7 is first valve, 8 is flowmeter, 9 is first pipe, 10 is funnel, 11 is fourth valve, 12 is annotate liquid pipe, 13 is thermostated container, 14 is first booster pump, 15 is first pressure sensing pole, 16 is second booster pump, 17 is second pressure sensing pole, 18 is third booster pump, 19 is third pressure sensing pole, 20 is simulation room, 21 is third pressure piston sheet, 22 is first pressure piston sheet, 23 is second pressure piston sheet, 24 is fifth valve, 25 is the drain pipe, 26 is second drawing liquid pump, 27 is liquid container, 28 is second pipe, 29 is sixth valve, 30 is fourth pipe, 31 is seventh valve, 32 is gas analyzer, 33 is fifth pipe, 34 is third pipe, 35 is petroleum extraction bottle, 36 is seventh pipe, 37 is eighth valve, 38 is eighth pipe, 39 is first pressure piston sheet, 23 is second pressure piston sheet, 24 is fifth pipe, 25 is fifth pipe, 29 is fourth pipe, 37 is fourth pipe, 43 is water bottle, 43 is a balance.
Detailed Description
The invention is described in further detail below with reference to the attached drawing figures:
Referring to fig. 1, the system for experimentally simulating carbon dioxide displacement oil and gas comprises a simulation chamber 20, an incubator 13, a first booster pump 14, a first pressure sensing rod 15, a second booster pump 16, a second pressure sensing rod 17, a third booster pump 18, a third pressure sensing rod 19, a CH 4 gas cylinder 1, a CO 2 gas cylinder 2, a first conduit 9, a funnel 10, a liquid injection pipe 12, a liquid discharge pipe 25, a liquid container 27, a second conduit 28, a third conduit 34, a petroleum extraction bottle 35, a fourth conduit 30, a gas analyzer 32, a fifth conduit 33, a sixth conduit 38, a seventh conduit 36, a lime water solution bottle 39, an eighth conduit 41 and an electronic balance 40; the simulation chamber 20 is positioned in the incubator 13, sand, mud and a fracture plate are filled in the simulation chamber 20, a first pressure piston piece 22 is arranged on the outer side of the top of the simulation chamber 20, a second pressure piston piece 23 is arranged on the outer side of the right side of the simulation chamber 20, a third pressure piston piece 21 is arranged on the outer side of the front side of the simulation chamber 20, the first booster pump 14 is connected with the first pressure piston piece 22 through a first pressure sensing rod 15, the second booster pump 16 is connected with the second pressure piston piece 23 through a second pressure sensing rod 17, and the third booster pump 18 is connected with the third pressure piston piece 21 through a third pressure sensing rod 19; the outlet of the CH 4 gas cylinder 1 and the outlet of the CO 2 gas cylinder 2 are communicated with one end of a first conduit 9, and the other end of the first conduit 9 is communicated with an inlet on the left side surface of the simulation chamber 20; the outlet of the funnel 10 is communicated with the inlet at the top of the simulation chamber 20 through the liquid injection pipe 12, and the liquid outlet at the bottom of the simulation chamber 20 is communicated with the liquid container 27 through the liquid discharge pipe 25; the outlet on the right side of the simulation chamber 20 is divided into two paths through the second conduit 28, one path is communicated with the petroleum extraction bottle 35 through the third conduit 34, the other path is communicated with the inlet of the gas analyzer 32 through the fourth conduit 30, the outlet of the gas analyzer 32 is communicated with the inlet of the sixth conduit 38 through the fifth conduit 33, one end of the seventh conduit 36 is inserted into the liquid in the petroleum extraction bottle 35, the other end of the seventh conduit 36 is communicated with the inlet of the sixth conduit 38, the outlet of the sixth conduit 38 is inserted into the liquid in the lime water bottle 39, the inlet end of the eighth conduit 41 is inserted into the lime water bottle 39, the lime water bottle 39 is positioned on the electronic balance 40, and the bottom of the incubator 13 is provided with a bracket 43.
The first catheter 9 is provided with a first liquid pump 6, a first valve 7 and a flowmeter 8; the outlet of the CH 4 gas cylinder 1 is provided with a second valve 3, the outlet of the CO 2 gas cylinder 2 is provided with a third valve 5, and the outlet of the CH 4 gas cylinder 1 is communicated with the first conduit 9 through a ninth conduit 4; the liquid injection pipe 12 is provided with a fourth valve 11; the liquid discharge pipe 25 is provided with a fifth valve 24 and a second liquid discharge pump 26; the third conduit 34 is provided with a sixth valve 29; a seventh valve 31 is arranged on the fourth conduit 30; the seventh conduit 36 is provided with an eighth valve 37; a ninth valve 42 is provided on the eighth conduit 41.
The petroleum extraction bottle 35 contains excessive chloroform to ensure that petroleum is completely absorbed; the lime water solution bottle 39 contains excessive lime water solution, so that CO 2 in the mixed gas is ensured to be completely absorbed.
The measuring ranges of the flow meters 8 are 1000ml/min, the precision is 0.1ml/min, and the pressure resistance is 50MPa; the measuring range of each pressure sensing rod is 0-50MPa, and the measuring precision is 0.1MPa; the measuring range of the electronic balance 40 is 0.00-3000.00g, and the measuring precision is 0.01g; the drain pipe 25 extends into the bottom of the liquid container 27 to prevent contamination by spillage.
The specific working process of the invention is as follows:
1) The sandstone particles and mudstones with different diameters are arranged in the simulation chamber 20 according to actual stratum conditions, stratum dip angles and fracture development conditions can be adjusted, the combination conditions of coal and rock, shale and sandstone are adjusted, and the temperature and pressure conditions of the simulation chamber 20 are set according to actual geological temperature and pressure by adjusting the incubator 13 and the first booster pump 14, the second booster pump 16 and the third booster pump 18;
2) Closing the first valve 7, the fourth valve 11, the sixth valve 29 and the seventh valve 31, opening the fifth valve 24, and enabling the interior of the simulation chamber 20 to reach a vacuum state through the second liquid pump 26;
3) Placing a lime water solution bottle 39 containing excess lime water solution on the electronic balance 40 and zeroing the electronic balance 40;
4) When the CO 2 is used for displacement petroleum simulation, according to the experimental design, a fourth valve 11 is opened, and a certain amount of petroleum is injected into a simulation chamber 20 by using a second liquid discharge pump 26 through an injection funnel 10 and an injection pipe 12; opening the third valve 5, the first valve 7, the sixth valve 29, the eighth valve 37 and the ninth valve 42, injecting CO 2 into the simulation chamber 20 by using the first liquid-extracting pump 6, closing all pumps and valves during experimental collection;
5) Analyzing the oil saturation condition in the stratum by injecting oil mass and stratum characteristics, recording the numerical value of the flowmeter 8 during CO 2 injection, the oil amount extracted in the oil extraction bottle 35 and the measured data in the lime water container 39, calculating the efficiency of CO 2 displacement to replace oil, and evaluating the displacement effect;
6) When CO 2 is used for replacing natural gas for simulation, according to the experimental design, the fourth valve 11 and the fifth valve 24 are closed, the second valve 3, the first valve 7, the seventh valve 31 and the ninth valve 42 are opened, and the CH4 is injected into the simulation chamber 20 by using the first liquid extracting pump 6; then the second valve 3 is closed, the third valve 5 is opened, and the first liquid pump 6 is used for injecting CO 2 into the simulation chamber 20;
7) Recording the value of the flowmeter 8 during CH 4 injection, analyzing the gas saturation condition in the stratum by injecting methane and stratum characteristics, recording the value of the flowmeter 8 during CO 2 injection, measuring the natural gas quantity by the gas analyzer 32 and measuring data in the lime water container 39, calculating the efficiency of CO 2 displacement to replace natural gas, and evaluating the displacement effect;
8) After the experiment was completed, the simulation chamber 20 was taken out and the valves were closed.
Claims (8)
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CN111879665B (en) * | 2020-06-19 | 2022-03-08 | 西安交通大学 | Device and method for measuring diffusion property of refrigerant/lubricating oil system |
CN115075783A (en) * | 2021-03-10 | 2022-09-20 | 中国石油天然气股份有限公司 | Displacement experiment device and method |
CN115163021B (en) * | 2022-07-13 | 2023-11-03 | 中国矿业大学 | Water injection and nitrogen injection gas extraction hole sealing device and drilling arrangement method |
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CN103383378B (en) * | 2013-07-19 | 2014-11-05 | 东北石油大学 | Oil gas adsorption-desorption displacement experiment device |
CN104453794B (en) * | 2014-11-20 | 2017-05-17 | 中国科学院广州能源研究所 | Simulation experiment system for whole process of natural gas hydrate exploitation and simulation method |
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