CN111280496A - Functional underwear - Google Patents
Functional underwear Download PDFInfo
- Publication number
- CN111280496A CN111280496A CN202010102156.6A CN202010102156A CN111280496A CN 111280496 A CN111280496 A CN 111280496A CN 202010102156 A CN202010102156 A CN 202010102156A CN 111280496 A CN111280496 A CN 111280496A
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- Prior art keywords
- parts
- wire
- rubber sleeve
- core wire
- outer layer
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Links
- 229920001971 elastomer Polymers 0.000 claims abstract description 64
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 32
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 28
- 239000004952 Polyamide Substances 0.000 claims abstract description 27
- 229920002647 polyamide Polymers 0.000 claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 26
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims abstract description 22
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 20
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 16
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 15
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 15
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 15
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 15
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 14
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 14
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000454 talc Substances 0.000 claims abstract description 14
- 229910052623 talc Inorganic materials 0.000 claims abstract description 14
- 238000005034 decoration Methods 0.000 claims abstract description 4
- 238000005096 rolling process Methods 0.000 claims description 16
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 10
- 238000004898 kneading Methods 0.000 claims description 10
- 238000009941 weaving Methods 0.000 claims description 10
- 229920002943 EPDM rubber Polymers 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical group C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003723 Smelting Methods 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000004804 winding Methods 0.000 claims description 5
- 229920006052 Chinlon® Polymers 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 230000035807 sensation Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 49
- 238000000034 method Methods 0.000 description 16
- 230000006872 improvement Effects 0.000 description 10
- 239000010936 titanium Substances 0.000 description 9
- 238000005452 bending Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000007493 shaping process Methods 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 229920006235 chlorinated polyethylene elastomer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 210000003462 vein Anatomy 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- -1 polyethylene, ethylene propylene Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41C—CORSETS; BRASSIERES
- A41C1/00—Corsets or girdles
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41C—CORSETS; BRASSIERES
- A41C1/00—Corsets or girdles
- A41C1/12—Component parts
- A41C1/14—Stays; Steels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/286—Chlorinated polyethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/06—Insulating conductors or cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/06—Insulating conductors or cables
- H01B13/14—Insulating conductors or cables by extrusion
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/22—Sheathing; Armouring; Screening; Applying other protective layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/22—Sheathing; Armouring; Screening; Applying other protective layers
- H01B13/24—Sheathing; Armouring; Screening; Applying other protective layers by extrusion
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/04—Flexible cables, conductors, or cords, e.g. trailing cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/44—Donning facilities
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Materials Engineering (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a functional underwear, which comprises: an inner layer in contact with human skin; the outer layer is arranged on the inner layer and used for decoration, and decorative grains are arranged on the outer layer; and the electric wire is arranged on the outer layer and is superposed with the decorative lines; the electric wire comprises at least one strand of core wire and a rubber sleeve wrapped outside the core wire; the rubber sleeve is mainly prepared from the following raw materials in parts by weight: 40-60 parts of chlorinated polyethylene, 10-30 parts of ethylene propylene rubber, 10-30 parts of polyamide, 3-10 parts of a silane coupling agent, 50-80 parts of talc, 40-80 parts of calcium carbonate, 1-10 parts of dioctyl phthalate, 5-15 parts of magnesium oxide, 1-5 parts of an antioxidant and 1-10 parts of a crosslinking agent. The electric wire is arranged on the outer layer of the functional underwear, so that the functional underwear is free of foreign body sensation when being worn, and does not need to be lined, the overall thickness of the functional underwear is reduced, and the wearing comfort is improved; and the electric wire is superposed with the decorative lines, thereby achieving the solid effects of invisibility, compactness and no shaking.
Description
Technical Field
The invention relates to the field of underwear, in particular to functional underwear.
Background
With the development of society and the improvement of quality of life, people increasingly have an increasing demand for functionality of clothes. Functional underwear is one of the products produced by the user, and not only has the warm-keeping function of common clothes, but also has the functions of vibration, massage, heating and the like. Functional underwear such as body shaping clothes, bras, underpants and the like exist on the market. In order to endow the underwear with corresponding functions of heating, vibration and the like, electrical elements such as heating wires, vibrators and the like need to be arranged on each part of the underwear; this requires that electrical wires be placed in the corresponding portion of the undergarment to allow electrical conduction.
In the existing functional body shaping clothes and bras, the adopted conductive wire is generally a copper wire, the wire diameter of the wire core is about 300 mu m, and the integral rigidity of the copper battery core is larger; on the basis of adopting this kind of copper core, the electric wire external diameter is about 1mm on the whole. For the sake of beauty and convenience of washing, the electric wire is generally disposed between the decorative layer and the interlayer of the inner layer, which makes the foreign body feel heavy when worn; therefore, the thickness of the inner layer is required to be increased, so that the underwear is heavy and has poor comfort. In addition, because copper core wire rigidity is higher, in order to prevent that it from receiving local force in the cleaning process, take place the broken string, consequently the electric wire often is unfixed in the intermediate layer, rocks easily during the washing, shifts, and the friction to electric wire, ectonexine is great for underwear easily wears out, short service life.
In order to solve the problems, a nano titanium crystal heating wire is developed in the industry, and the heating wire has high flexibility and excellent bending performance; however, the film is generally coated with a polyamide film, which is not wear-resistant, has a short service life, and is liable to cause electrical leakage after being worn through, thus causing harm to human body. Such a heater is often disposed between the interlayers as an integral module. In addition, the structure of the nanometer titanium crystal heating wire and the film has high cost and is difficult to popularize and utilize.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a functional underwear which is high in wearing comfort and low in cost; the washing resistance and the rubbing resistance are realized, and the service life is long.
In order to solve the above technical problems, the present invention provides a functional undergarment comprising:
an inner layer in contact with human skin;
the outer layer is arranged on the inner layer and used for decoration, and decorative grains are arranged on the outer layer; and
the electric wire is arranged on the outer layer and is superposed with the decorative grains;
the electric wire comprises at least one strand of core wire and a rubber sleeve wrapped outside the core wire; the rubber sleeve is mainly prepared from the following raw materials in parts by weight:
40-60 parts of chlorinated polyethylene, 10-30 parts of ethylene propylene rubber, 10-30 parts of polyamide, 3-10 parts of a silane coupling agent, 50-80 parts of talc, 40-80 parts of calcium carbonate, 1-10 parts of dioctyl phthalate, 5-15 parts of magnesium oxide, 1-5 parts of an antioxidant and 1-10 parts of a crosslinking agent.
As an improvement of the technical scheme, the thickness of the rubber sleeve is 0.05-0.3 mm;
the outer diameter of the core wire is less than or equal to 10 mu m;
the outer diameter of the wire is 0.3-0.75 mm.
As an improvement of the technical scheme, the outer layer is made of a chinlon gauze fabric; the thickness of the outer layer is less than or equal to 100 mu m.
As an improvement of the technical scheme, the chlorinated polyethylene has the chlorine mass fraction of 32-38 wt%, the tensile strength of more than or equal to 9MPa and the elongation at break of more than or equal to 700 percent;
the ethylene propylene rubber is ethylene propylene diene monomer.
As an improvement of the technical scheme, the polyamide is selected from one or more of PA, PA66 and PA 1010;
the cross-linking agent is triallyl cyanurate and/or triallyl isocyanurate.
As an improvement of the technical scheme, the polyamide is a mixture of PA66 and PA1010, and the weight ratio of PA66 to PA1010 is (1-5) to (5-10).
As an improvement of the technical scheme, the core wire is made of the following raw materials in percentage by weight: 1.5-3% of Fe, 0.5-5% of Ni, 0.5-2% of Ti, 0.05-1% of Cr and the balance of Al.
As an improvement of the above technical solution, at least 12 strands of core wires are arranged in the electric wire; the surface of each strand of core wire is provided with an ethylene propylene rubber insulating layer.
As an improvement of the above technical solution, the preparation method of the electric wire comprises:
(1) preparing a core wire; preparing various raw materials according to a core wire formula, and extruding and drawing after smelting to form a core wire with a preset outer diameter;
(2) preparing a rubber sleeve intermediate: mixing and rolling the raw materials of the rubber sleeve to obtain a rubber sleeve intermediate;
(3) winding and wrapping an insulating layer on the surface of each strand of core wire;
(4) weaving the wrapped wire core into a plurality of strands through weaving equipment;
(5) and (4) placing the rubber sleeve intermediate in an extruder, and wrapping the multi-strand braid after extrusion to obtain a finished wire product.
As an improvement of the technical scheme, the step (2) comprises the following steps:
(2.1) plasticating the chlorinated polyethylene, the ethylene propylene rubber and the polyamide at the temperature of 100-150 ℃;
(2.2) adding magnesium oxide, talc and calcium carbonate, and kneading for 2-5 min;
(2.3) adding dioctyl phthalate, a cross-linking agent and an antioxidant, and kneading for 2-5 min;
(2.4) adding a silane coupling agent, mixing for 2-5 minutes, passing through for 2-8 times, rolling on a rolling machine for 1-3 times, and then passing through a powder box to obtain a rubber sleeve intermediate.
The implementation of the invention has the following beneficial effects:
1. the electric wire is arranged on the outer layer of the functional underwear, so that the functional underwear is free of foreign body sensation when being worn, and does not need to be lined, the overall thickness of the functional underwear is reduced, and the wearing comfort is improved.
2. The electric wire is moderate in thickness and soft in whole, can be fixed on the outer-layer tissue through an embroidery process, and is good in decorative and invisible effects and simple in preparation process. The fixing structure can not lead the electric wire to shake when being cleaned, has little friction on the electric wire and prolongs the service life.
3. The core wire and the rubber sleeve in the wire are reasonable in formula, extremely high in flexibility, capable of resisting bending times of more than 10 thousands of times and convenient to use in daily life.
4. The rubber sleeve disclosed by the invention is reasonable in formula, so that the rubber sleeve is excellent in high temperature resistance, wear resistance and tearing resistance.
Drawings
FIG. 1 is a schematic view of the construction of a functional undergarment in accordance with an embodiment of the invention;
FIG. 2 is a schematic view of the structure of the outer layer of the functional undergarment and the electrical wires according to one embodiment of the present invention;
FIG. 3 is a schematic structural diagram of an electrical wire according to an embodiment of the present invention;
fig. 4 is a schematic structural view of a functional undergarment in embodiment 3 of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the accompanying drawings. It is only noted that the invention is intended to be limited to the specific forms set forth herein, including any reference to the drawings, as well as any other specific forms of embodiments of the invention.
Referring to fig. 1, the present invention provides a functional underwear, which comprises an inner layer 1 contacting with human skin, an outer layer 2 arranged on the inner layer 1 for decoration, and decorative lines 21 arranged on the outer layer 2; the outer layer 2 is provided with an electric wire 3 superposed with the decorative veins 21. The arrangement can integrate the electric wire 3 with the decorative pattern, thereby having elegant appearance; meanwhile, the electric wire is arranged on the outer layer, so that the clothes are free of foreign body sensation during wearing and high in comfort. The functional undergarment may also include functional components such as a vibrator (massager), a heater, etc., which one skilled in the art can select according to the corresponding function of the functional undergarment. In addition, it should be noted that the overall shape of the functional underwear may be, but is not limited to, a body-shaping garment, a brassiere, underwear, and the like.
Specifically, the electric wire 3 includes a core wire 31, a rubber cover 32, and an insulating layer 33; wherein the outer diameter of the core wire 31 is less than or equal to 10 μm, preferably 5-8 μm; the thickness of the rubber sleeve 32 is 0.05-0.3 mm, preferably 0.1-0.2 mm; the outer diameter of the whole wire 3 is 0.3-0.75 mm, preferably 0.3-0.5 mm; the wire 3 with the wire diameter can be well fused with the decorative lines on the outer layer, has no abrupt feeling, is beautiful and elegant, and has strong bending resistance.
Further, in order to improve the bending resistance, the electric wire 3 comprises at least 12 strands of core wires, the outer layer of each strand of core wire 31 is wrapped with an insulating layer, and the outer layer of the whole electric wire is also wrapped with a rubber sleeve 32; preferably, the electric wire comprises 16-20 strands of core wires, so that the electric conductivity of the electric wire is not greatly influenced under the condition that some core wires are broken, and the scrub resistance and the bending resistance are improved.
After the electric wire 3 is fused with the decorative lines, the electric wire 3 and the outer layer 2 can be fixed by adopting an embroidery process; specifically, the electric wire 3 can be sewn on the surface of the outer layer 2 by adopting a fish silk thread; more specifically, the electric wire 3 is fixed around the surface of the outer layer 2 by a fishwire. After the fixing, the electric wire does not shake in the cleaning process, so that the friction and damage of the cleaning process to the electric wire are reduced.
In addition, in order to prevent the electric wire from being damaged by pulling, rubbing and washing and other operations in the daily use process, the outer layer 2 material in the invention can be high-elasticity nylon gauze, the elasticity is high, a certain degree of tension can be eliminated in the pulling process, and the acting force on the electric wire is reduced.
It should be noted that, in the existing functional body-shaping clothes and bras, the adopted conductive wire is generally a copper wire, the wire diameter of the wire core is about 300 μm, and the overall outer diameter of the wire is about 1 mm; for pleasing to the eye and abluent convenience, generally with the electric wire setting between the intermediate layer of decorative layer and inlayer, this just makes when dressing the foreign matter sense heavier, consequently often needs to promote the thickness of inlayer for the underwear is whole heavy, and the comfort is relatively poor. In addition, the existing electric wire is not fixed in the interlayer, is easy to shake and shift during cleaning, has larger friction on the electric wire and the inner and outer layers, and ensures that the underwear is easy to wear and has short service life. According to the invention, the electric wire is fixed on the decorative outer layer and is fused with the decorative pattern of the outer layer, so that the functional underwear is attractive and elegant in appearance, the service life of the underwear is prolonged, and the feeling of wearing foreign bodies is reduced.
In addition, in order to provide the electric wire in the outer layer, it is necessary to select a material of the electric wire. Specifically, in one aspect, in the present invention, the core wire 31 is made of the following raw materials in percentage by weight: 1.5-3% of Fe, 0.5-5% of Ni, 0.5-2% of Ti, 0.05-1% of Cr and the balance of Al. The raw materials are melted, extruded and drawn to form the core wire with the wire diameter less than or equal to 10 mu m, so that the bending resistance of the core wire can be greatly improved, and the bending resistance times of the core wire can reach more than 10 ten thousand times. In addition, the core wire has strong flexibility and can be arranged on the decorative outer layer by combining with an embroidery process.
On the other hand, in the invention, the rubber sleeve is mainly prepared from the following raw materials in parts by weight:
40-60 parts of chlorinated polyethylene, 10-30 parts of ethylene propylene rubber, 10-30 parts of polyamide, 3-10 parts of a silane coupling agent, 50-80 parts of talc, 40-80 parts of calcium carbonate, 1-10 parts of dioctyl phthalate, 5-15 parts of magnesium oxide, 1-5 parts of an antioxidant and 1-10 parts of a crosslinking agent. The rubber sleeve has strong tearing resistance and excellent mechanical property; and has high flexibility.
Specifically, in the formula of the rubber sleeve, the mass fraction of chlorine in the chlorinated polyethylene is 32-38 wt%, the tensile strength is not less than 9MPa, and the elongation at break is not less than 700%; preferably, the mass fraction of chlorine in the chlorinated polyethylene is 35-37 wt%. The addition weight part of the chlorinated polyethylene is 40-60 parts, preferably 50-60 parts.
Specifically, in the formula of the rubber sleeve, the ethylene propylene rubber is ethylene propylene diene monomer, and the flexibility of the rubber sleeve can be effectively improved by adding the ethylene propylene diene monomer.
Specifically, in the formula of the rubber sleeve, the polyamide is selected from one or more of PA, PA66 and PA 1010; preferably, the polyamide is a mixture of PA66 and PA1010, and the weight ratio of PA66 to PA1010 is (1-5): 5-10); further preferably, PA 66: PA1010 ═ 1: 4. The polyamide is added in the chlorinated polyethylene and ethylene propylene rubber system, so that the compatibility of the chlorinated polyethylene and the ethylene propylene rubber system can be improved, and the phase separation phenomenon is reduced, thereby greatly improving the tensile strength, the tearing strength and the elongation at break. The polyamide is added in 10-30 parts by weight, preferably 10-20 parts by weight. When the weight part of the added polyamide is less than 10 parts, the elongation at break and the tensile strength of the rubber sleeve are small; when it is added in an amount of more than 30 parts by weight, the crosslink density between the three is reduced, thereby decreasing the hardness.
Specifically, in the formula of the rubber sleeve, the silane coupling agent can graft and crosslink the chlorinated polyethylene, the ethylene propylene rubber and the polyamide, so that the molecules with linear structures are converted into macromolecules with three-dimensional network structures, and the rubber sleeve has the properties of high tensile strength, high elasticity, high wear resistance and the like. Specifically, the silane coupling agent is added in an amount of 3 to 10 parts by weight, preferably 5 to 10 parts by weight.
Furthermore, in order to promote crosslinking, 1-10 parts of a crosslinking agent is also contained in the formula of the rubber sleeve; specifically, the crosslinking agent can be triallyl cyanurate (TAC) and/or triallyl isocyanurate (TAIC); preferably, TAIC is selected. When the amount of the crosslinking agent is more than 10 parts, the elongation is greatly reduced. TAIC and silane coupling agent are mixed for use, so that reasonable crosslinking degree of chlorinated polyethylene, ethylene propylene rubber and polyamide can be fully ensured, and a rubber sleeve product with reasonable tensile strength, elongation at break, elasticity and wear resistance can be obtained.
Specifically, in the formula of the rubber sleeve, talc, calcium carbonate, dioctyl phthalate, an antioxidant and magnesium oxide are added in order to coordinate the performance of each aspect of the rubber sleeve.
Furthermore, for the sake of beauty, the formula of the rubber sleeve can also contain 1-5 parts of pigment.
In addition, in order to ensure the excellent performance of the electric wire of the present invention, the preparation method of the electric wire needs to be optimized. Specifically, in the present invention, the method for manufacturing the electric wire is as follows:
(1) preparing a core wire; preparing various raw materials according to a core wire formula, and extruding and drawing after smelting to form a core wire with a preset outer diameter;
specifically, Al, Fe, Ni, Ti and Cr are melted, extruded and drawn to form a core wire with corresponding outer diameter.
(2) Preparing a rubber sleeve intermediate: mixing and rolling the raw materials of the rubber sleeve to obtain a rubber sleeve intermediate;
specifically, the method comprises the following steps:
(2.1) plasticating the chlorinated polyethylene, the ethylene propylene rubber and the polyamide at the temperature of 100-150 ℃;
(2.2) adding magnesium oxide, talc and calcium carbonate, and kneading for 2-5 min;
(2.3) adding dioctyl phthalate and a cross-linking agent, and kneading for 2-5 min;
(2.4) adding a silane coupling agent, mixing for 2-5 minutes, passing through for 2-8 times, rolling on a rolling machine for 1-3 times, and then passing through a powder box to obtain a rubber sleeve intermediate.
(3) Winding and wrapping an insulating layer on the surface of each strand of core wire;
specifically, an ethylene propylene rubber layer is wrapped on the surface of the core wire; the ethylene-propylene rubber layer can adopt ethylene-propylene rubber in the prior art as a raw material
(4) Weaving the wrapped wire core into a plurality of strands through weaving equipment;
(5) and (4) placing the rubber sleeve intermediate in an extruder, and wrapping the multi-strand braid after extrusion to obtain a finished wire product.
The invention is illustrated below in specific examples:
example 1
The embodiment provides a functional underwear, in particular to a body shaping underwear of a heating type; referring to fig. 3, it includes an inner layer 1, an outer layer 2, and a wire 3; the outer layer 2 is provided with decorative lines 21. The wire is overlapped with part of the decorative vein 21.
Wherein, the electric wire 3 is composed of a core wire 31 and a rubber sleeve 32, wherein, the outer diameter of the core wire is 8 μm, and the thickness of the rubber sleeve is 0.3 mm; the overall outer diameter of the wire is 0.5 mm. The outer layer 2 is made of chinlon gauze fabric, and the thickness of the chinlon gauze fabric is 85 microns.
The core wire is prepared from the following raw materials in percentage by weight: 1.6% of Fe, 2.5% of Ni, 1.5% of Ti, 0.45% of Cr0.45% and the balance of Al.
The rubber sleeve is mainly prepared from the following raw materials in parts by weight:
48 parts of chlorinated polyethylene, 14 parts of ethylene propylene diene monomer, 25 parts of polyamide, 6 parts of a silane coupling agent, 55 parts of talc, 65 parts of calcium carbonate, 3 parts of dioctyl phthalate, 10 parts of magnesium oxide, 2 parts of an antioxidant and 4 parts of a crosslinking agent.
Wherein, the content of chlorine in the chlorinated polyethylene is 35 wt%, the tensile strength is 9MPa, and the elongation at break is 735%; PA66 is selected as polyamide and TAC is selected as cross-linking agent.
The preparation method of the wire comprises the following steps:
(1) preparing a core wire; preparing various raw materials according to a core wire formula, and extruding and drawing after smelting to form a core wire with a preset outer diameter;
specifically, Al, Fe, Ni, Ti and Cr are melted, extruded and drawn to form a core wire of 8 μm.
(2) Preparing a rubber sleeve intermediate: mixing and rolling the raw materials of the rubber sleeve to obtain a rubber sleeve intermediate;
specifically, the method comprises the following steps:
(2.1) plasticating the chlorinated polyethylene, the ethylene propylene rubber and the polyamide at 120 ℃;
(2.2) adding magnesium oxide, talc and calcium carbonate, and kneading for 5 min;
(2.3) adding dioctyl phthalate, a cross-linking agent and an antioxidant, and kneading for 5 min;
and (2.4) adding a silane coupling agent, mixing for 5min, thinly passing for 5 times, rolling for 3 times on a rolling machine, and discharging sheets through a powder box to obtain the intermediate of the rubber sleeve.
(3) Winding and wrapping an insulating layer on the surface of each strand of core wire;
specifically, the surface of the core wire is wrapped with an ethylene propylene rubber layer.
(4) Weaving the wrapped wire core into a plurality of strands through weaving equipment;
(5) and (4) placing the rubber sleeve intermediate in an extruder, and wrapping the multi-strand braid after extrusion to obtain a finished wire product.
Example 2
The present embodiment provides an electric wire, which is composed of a core wire and a rubber sleeve, wherein the outer diameter of the core wire is 5 μm, and the thickness of the rubber sleeve is 0.5 mm; the overall outer diameter of the wire is 0.6 mm. 12 strands of core wires are arranged in the wire.
The core wire is prepared from the following raw materials in percentage by weight: 2.1% of Fe, 3.2% of Ni, 1.8% of Ti, 0.25% of Cr0.25% and the balance of Al.
The rubber sleeve is mainly prepared from the following raw materials in parts by weight:
52 parts of chlorinated polyethylene, 20 parts of ethylene propylene diene monomer, 15 parts of polyamide, 7 parts of silane coupling agent, 75 parts of talc, 45 parts of calcium carbonate, 4 parts of dioctyl phthalate, 8 parts of magnesium oxide, 3 parts of antioxidant and 3 parts of crosslinking agent.
Wherein, the content of chlorine in the chlorinated polyethylene is 35 wt%, the tensile strength is 9MPa, and the elongation at break is 735%; the polyamide is selected from a mixture of PA66 and PA1010, and the ratio of PA 66: PA1010 is 1:8, and TAIC is selected as a cross-linking agent.
The preparation method of the wire comprises the following steps:
(1) preparing a core wire; preparing various raw materials according to a core wire formula, and extruding and drawing after smelting to form a core wire with a preset outer diameter;
specifically, Al, Fe, Ni, Ti and Cr are melted, extruded and drawn to form a core wire of 8 μm.
(2) Preparing a rubber sleeve intermediate: mixing and rolling the raw materials of the rubber sleeve to obtain a rubber sleeve intermediate;
specifically, the method comprises the following steps:
(2.1) plasticating the chlorinated polyethylene, the ethylene propylene rubber and the polyamide at 140 ℃;
(2.2) adding magnesium oxide, talc and calcium carbonate, and kneading for 5 min;
(2.3) adding dioctyl phthalate, a cross-linking agent and an antioxidant, and kneading for 3 min;
and (2.4) adding a silane coupling agent, mixing for 5min, thinly passing for 5 times, rolling for 3 times on a rolling machine, and discharging sheets through a powder box to obtain the intermediate of the rubber sleeve.
(3) Winding and wrapping an insulating layer on the surface of each strand of core wire;
specifically, the surface of the core wire is wrapped with an ethylene propylene rubber layer.
(4) Weaving the wrapped wire core into a plurality of strands through weaving equipment;
(5) and (4) placing the rubber sleeve intermediate in an extruder, and wrapping the multi-strand braid after extrusion to obtain a finished wire product.
Example 3
The present embodiment provides an electric wire, which is composed of a core wire and a rubber sleeve, wherein the outer diameter of the core wire is 5 μm, and the thickness of the rubber sleeve is 0.5 mm; the overall outer diameter of the wire is 0.6 mm. 12 strands of core wires are arranged in the wire.
The formulation of the core wire was the same as in example 2.
The rubber sleeve is mainly prepared from the following raw materials in parts by weight:
50 parts of chlorinated polyethylene, 20 parts of ethylene propylene diene monomer, 18 parts of polyamide, 6 parts of silane coupling agent, 70 parts of talc, 50 parts of calcium carbonate, 4 parts of dioctyl phthalate, 8 parts of magnesium oxide, 2 parts of antioxidant and 4 parts of crosslinking agent.
Wherein, the content of chlorine in the chlorinated polyethylene is 35 wt%, the tensile strength is 9MPa, and the elongation at break is 735%; the polyamide is selected from a mixture of PA66 and PA1010, and the ratio of PA 66: PA1010 ═ 1: and 4, selecting TAIC as the crosslinking agent.
The wire was prepared in the same manner as in example 2.
Comparative example 1
The comparative example provides a gum cover, and the formula is as follows:
100 parts of chlorinated polyethylene, 4 parts of dicumyl peroxide, 4 parts of TAIC, 40 parts of talc, 80 parts of calcium carbonate, 5 parts of carbon black, 12 parts of magnesium oxide, 5 parts of antioxidant and 4 parts of dioctyl phthalate.
The preparation method comprises the following steps:
plasticating chlorinated polyethylene at 70 deg.C for 3min, adding pulvis Talci, calcium carbonate, and carbon black, and mixing for 2 min; then adding the rest raw materials, and mixing for 3 min; passing through the sheet for 1 time, and then rolling and discharging the sheet.
Comparative example 2
The comparative example provides a gum cover, and the formula is as follows:
60 parts of chlorinated polyethylene, 10 parts of ethylene propylene diene monomer, 5 parts of TAC, 4 parts of TAIC, 30 parts of carbon black, 50 parts of calcium carbonate, 5 parts of magnesium oxide and 2 parts of antioxidant;
the preparation method comprises the following steps:
plasticating chlorinated polyethylene and ethylene propylene diene monomer rubber at 100 ℃ for 3min, adding the rest raw materials, uniformly mixing and tabletting.
The rubber sleeves in examples 1-3 and comparative examples 1-2 are subjected to performance tests, wherein the tensile strength and the elongation at break are measured by a method in GB/T528, and the tear strength is measured by a method in GB/T529; the Shore hardness is determined by a method in GB/T531; the flex crack resistance was determined by the method described in GB/T13934.
The results are given in the following table:
from the above, the gum cover material of the invention has good tensile strength, elongation at break and flex crack, and provides good performance foundation for daily use such as scrubbing, bending and the like.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.
Claims (10)
1. A functional undergarment, comprising:
an inner layer in contact with human skin;
the outer layer is arranged on the inner layer and used for decoration, and decorative grains are arranged on the outer layer; and
the electric wire is arranged on the outer layer and is superposed with the decorative grains;
the electric wire comprises at least one strand of core wire and a rubber sleeve wrapped outside the core wire; the rubber sleeve is mainly prepared from the following raw materials in parts by weight:
40-60 parts of chlorinated polyethylene, 10-30 parts of ethylene propylene rubber, 10-30 parts of polyamide, 3-10 parts of a silane coupling agent, 50-80 parts of talc, 40-80 parts of calcium carbonate, 1-10 parts of dioctyl phthalate, 5-15 parts of magnesium oxide, 1-5 parts of an antioxidant and 1-10 parts of a crosslinking agent.
2. The functional undergarment according to claim 1 wherein the thickness of the rubber cover is 0.05 to 0.3 mm;
the outer diameter of the core wire is less than or equal to 10 mu m;
the outer diameter of the wire is 0.3-0.75 mm.
3. The functional undergarment according to claim 1 or 2 wherein the outer layer is a chinlon tissue fabric; the thickness of the outer layer is less than or equal to 100 mu m.
4. The functional undergarment according to claim 1 wherein the chlorinated polyethylene has a chlorine mass fraction of 32 to 38 wt%, a tensile strength of 9MPa or more and an elongation at break of 700% or more;
the ethylene propylene rubber is ethylene propylene diene monomer.
5. The functional undergarment according to claim 1 wherein the polyamide is selected from one or more of PA, PA66, PA 1010;
the cross-linking agent is triallyl cyanurate and/or triallyl isocyanurate.
6. The functional undergarment according to claim 1 or 5 wherein the polyamide is a mixture of PA66 and PA1010, and the weight ratio of PA66 to PA1010 is (1-5): (5-10).
7. The functional undergarment according to claim 1 wherein the core is made from the following raw materials in weight percent: 1.5-3% of Fe, 0.5-5% of Ni, 0.5-2% of Ti, 0.05-1% of Cr and the balance of Al.
8. The functional undergarment according to claim 1 or 7 wherein at least 12 strands of core wire are provided in the wire; the surface of each strand of core wire is provided with an ethylene propylene rubber insulating layer.
9. The functional undergarment according to claim 8 wherein the wires are prepared by:
(1) preparing a core wire; preparing various raw materials according to a core wire formula, and extruding and drawing after smelting to form a core wire with a preset outer diameter;
(2) preparing a rubber sleeve intermediate: mixing and rolling the raw materials of the rubber sleeve to obtain a rubber sleeve intermediate;
(3) winding and wrapping an insulating layer on the surface of each strand of core wire;
(4) weaving the wrapped wire core into a plurality of strands through weaving equipment;
(5) and (4) placing the rubber sleeve intermediate in an extruder, and wrapping the multi-strand braid after extrusion to obtain a finished wire product.
10. The functional undergarment according to claim 8 wherein step (2) includes:
(2.1) plasticating the chlorinated polyethylene, the ethylene propylene rubber and the polyamide at the temperature of 100-150 ℃;
(2.2) adding magnesium oxide, talc and calcium carbonate, and kneading for 2-5 min;
(2.3) adding dioctyl phthalate, a cross-linking agent and an antioxidant, and kneading for 2-5 min;
(2.4) adding a silane coupling agent, mixing for 2-5 minutes, passing through for 2-8 times, rolling on a rolling machine for 1-3 times, and then passing through a powder box to obtain a rubber sleeve intermediate.
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CN103014460A (en) * | 2012-11-26 | 2013-04-03 | 吴高峰 | Preparation method of aluminum alloy lead wire |
CN103497427A (en) * | 2013-08-28 | 2014-01-08 | 绿宝电缆(集团)有限公司 | High-storage-stability cable material |
CN105256204A (en) * | 2015-11-12 | 2016-01-20 | 郭芙 | Aluminum alloy conductor |
CN106821706A (en) * | 2017-03-16 | 2017-06-13 | 中科(深圳)精准医疗技术有限公司 | A kind of brassiere for preventing and treating mammary gland disease |
CN109312429A (en) * | 2016-07-13 | 2019-02-05 | 古河电气工业株式会社 | Aluminium alloy wires, aluminium alloy stranded conductor, coated electric wire and harness |
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2020
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CN103014460A (en) * | 2012-11-26 | 2013-04-03 | 吴高峰 | Preparation method of aluminum alloy lead wire |
CN103497427A (en) * | 2013-08-28 | 2014-01-08 | 绿宝电缆(集团)有限公司 | High-storage-stability cable material |
CN105256204A (en) * | 2015-11-12 | 2016-01-20 | 郭芙 | Aluminum alloy conductor |
CN109312429A (en) * | 2016-07-13 | 2019-02-05 | 古河电气工业株式会社 | Aluminium alloy wires, aluminium alloy stranded conductor, coated electric wire and harness |
CN106821706A (en) * | 2017-03-16 | 2017-06-13 | 中科(深圳)精准医疗技术有限公司 | A kind of brassiere for preventing and treating mammary gland disease |
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