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CN111211378A - A kind of power battery and thermal management method thereof - Google Patents

A kind of power battery and thermal management method thereof Download PDF

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Publication number
CN111211378A
CN111211378A CN202010064809.6A CN202010064809A CN111211378A CN 111211378 A CN111211378 A CN 111211378A CN 202010064809 A CN202010064809 A CN 202010064809A CN 111211378 A CN111211378 A CN 111211378A
Authority
CN
China
Prior art keywords
battery
heat
battery box
box
copper strip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010064809.6A
Other languages
Chinese (zh)
Inventor
裴波
刘飞
秦江
卢北虎
胡棋威
张斌
王洋洋
卢鑫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Harbin Institute of Technology Shenzhen
Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC
Original Assignee
Harbin Institute of Technology Shenzhen
Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Harbin Institute of Technology Shenzhen, Wuhan Institute of Marine Electric Propulsion China Shipbuilding Industry Corp No 712 Institute CSIC filed Critical Harbin Institute of Technology Shenzhen
Priority to CN202010064809.6A priority Critical patent/CN111211378A/en
Publication of CN111211378A publication Critical patent/CN111211378A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/613Cooling or keeping cold
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/62Heating or cooling; Temperature control specially adapted for specific applications
    • H01M10/625Vehicles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/64Heating or cooling; Temperature control characterised by the shape of the cells
    • H01M10/643Cylindrical cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6556Solid parts with flow channel passages or pipes for heat exchange
    • H01M10/6557Solid parts with flow channel passages or pipes for heat exchange arranged between the cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/656Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
    • H01M10/6567Liquids
    • H01M10/6568Liquids characterised by flow circuits, e.g. loops, located externally to the cells or cell casings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The invention discloses a power battery and a heat management method thereof, and the power battery comprises a battery box and a plurality of battery packs arranged in the battery box, wherein the battery packs are formed by sequentially arranging a plurality of cylindrical batteries, a copper foam strip with a pore is inserted between the gaps of two adjacent battery packs, the copper foam strip is partially contacted with the surfaces of the batteries, heat conduction resistance fuel oil is filled in the battery box, and the battery box is provided with an inlet and an outlet; when the environmental temperature is lower, thermal conductive and thermal resistant fuel oil is introduced through an inlet of the battery box to exchange heat with the surface of the battery and the foam copper strip so as to preheat the battery pack, thereby ensuring that the battery pack is maintained in an ideal temperature range; when the battery is at high temperature, cold-state heat conduction resistance fuel oil is introduced through the inlet of the battery box, continuously flows in from the inlet of the battery box, contacts with the surface of the battery and the foam copper strip for heat exchange, flows out from the outlet of the battery box, takes away the heat of the battery, and reduces the temperature of the battery pack.

Description

Power battery and thermal management method thereof
Technical Field
The invention belongs to the technical field of power battery thermal management, and particularly relates to a power battery combining foamy copper and heat-conducting flame-retardant oil, and a heating/cooling thermal management method thereof.
Background
The lithium ion battery as a more ideal power source in the future has the advantages of high specific energy, high specific rate, long service life, quick charge, unobvious memory effect and the like, but the lithium ion battery has poor abuse resistance, the service life of the battery is quickly attenuated due to overhigh temperature, and meanwhile, the risk of thermal runaway and the like is brought, and the thermal-related problem of the battery is one of the key factors for determining the service performance, safety, service life and use cost of the battery.
The large-scale of the power battery pack relatively reduces the ratio of the surface area to the volume, and the dense arrangement of the single battery cells leads to the over-high energy density of the battery pack, the heat inside the battery pack cannot be easily dissipated, the heat cannot be transferred and evacuated in time, the heat is easily accumulated, the local over-temperature and the temperature difference of each part are too large, and even dangerous conditions such as thermal runaway are caused.
Therefore, the invention discloses a battery heat management method for quickly conducting heat and equalizing temperature and effectively inhibiting thermal runaway.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a quick temperature equalization, effective flame-retardant and explosion-proof power battery.
The technical scheme adopted by the invention for solving the technical problems is as follows: a power battery comprises a battery box and a plurality of battery packs arranged in the battery box, wherein the battery packs are formed by sequentially arranging a plurality of cylindrical batteries, a copper foam strip with a pore is inserted between every two adjacent battery pack gaps, the copper foam strip is partially contacted with the surface of the battery, heat conduction resistance fuel oil is filled in the battery box, the heat conduction resistance fuel oil is filled in the battery gaps and the pores of the copper foam strip, the heat conduction resistance fuel oil has heat conductivity and flame retardance, and the heat conductivity coefficient of the heat conduction resistance fuel oil is greater than that of air; the heat conductivity coefficient of the foam copper strip is larger than that of the heat-conducting resistance fuel oil, and the battery box is provided with an inlet and an outlet.
Further, the heat conduction resistance fuel oil is silicone oil.
According to the power battery, the thickness of the foam copper strip is equal to the width of a gap between battery packs, so that the foam copper strip is tightly attached to the surface of the battery to reduce thermal resistance, and the foam copper strip is effectively fixed.
The power battery is characterized in that the battery box is filled with heat-conducting flame-retardant oil, and the copper foam strips and the battery are immersed in the heat-conducting flame-retardant oil.
The invention also discloses a heat management method of the power battery, which comprises the following steps: when the environmental temperature is lower, thermal conductive and thermal resistant fuel oil is introduced through an inlet of the battery box to exchange heat with the surface of the battery and the foam copper strip so as to preheat the battery pack, thereby ensuring that the battery pack is maintained in an ideal temperature range; when the battery is at high temperature, cold-state heat conduction resistance fuel oil is introduced through the inlet of the battery box, continuously flows in from the inlet of the battery box, contacts with the surface of the battery and the foam copper strip for heat exchange, flows out from the outlet of the battery box, takes away the heat of the battery, and reduces the temperature of the battery pack.
The invention has the beneficial effects that: the battery box is provided with an inlet and an outlet for the inflow and outflow of heat-conducting and heat-resistant fuel oil, and the heat-conducting and heat-resistant fuel oil in the battery box flows and carries out heat convection with the foam copper and the surface of the battery; only the temperature of the heat-conducting flame-retardant oil at the inlet of the battery box needs to be controlled, when the environmental temperature is low, the heat-conducting resistance fuel oil in a hot state is introduced to exchange heat with the surface of the battery and the foam copper strip, so that the preheating of the battery pack is realized, and when the temperature of the battery pack is high, the heat-conducting resistance fuel oil in a cold state is introduced to exchange heat with the surface of the battery and the foam copper strip, so that the temperature of the battery pack is reduced; the foam copper strips have porosity, the heat-conducting flame-retardant oil can fill the foam copper structure, and the contact area of the foam copper and the heat-conducting resistance fuel oil is increased, namely the heat exchange area of the foam copper and the heat-conducting flame-retardant oil is increased; the battery gap and the foam copper gap are filled with heat conduction resistance fuel oil, so that the heat resistance can be reduced; therefore, the invention can solve the temperature management problem of the tight space battery pack and effectively reduce the risks of thermal runaway and fire of the battery pack.
Drawings
FIG. 1 is a schematic view of the present invention in a front view;
FIG. 2 is a schematic top view of the present invention;
FIG. 3 is a schematic diagram of the arrangement of the battery according to the present invention;
FIG. 4 is a schematic structural view of a copper foam strip according to the present invention;
fig. 5 is a schematic view illustrating the copper foam strips inserted in the battery pack according to the present invention.
The notation in the figure is: 1-battery box, 2-copper foam strip, 3-thermal conductive resistance fuel and 4-battery.
Detailed Description
The invention is further described below with reference to the accompanying drawings and the detailed description.
As shown in figures 1 and 2, the invention discloses a power battery combining a copper foam strip 2 and heat conduction resistance fuel oil 3, which consists of a battery box 1, the copper foam strip 2, the heat conduction resistance fuel oil 3 and a battery 4. A plurality of cylindrical batteries 4 are sequentially arranged to form a battery pack, which is arranged as shown in fig. 3. A copper foam strip 2 with porosity and high thermal conductivity is shown in figure 4. The copper foam strips 2 having the same thickness as the gap width of the cells 4 are inserted into the gap of the battery pack as shown in fig. 5. The battery box 1 with the inlet and the outlet is filled with heat conduction resistance fuel oil 3, the battery 4 groups and the foam copper strip 2 are completely immersed, and the battery gaps and the foam copper pores are filled.
The foam copper strip 2 has the pore characteristics, so that the heat conduction and resistance fuel oil 3 can circulate in the foam copper pores; the foam copper strip 2 is in contact with the surface part of the battery 4, so that the heat of the battery 4 can be more quickly transferred to the foam copper 2; the heat conduction resistance fuel oil 3 has heat conductivity and flame retardance at the same time, and the heat conductivity coefficient of the heat conduction resistance fuel oil is larger than that of air; the heat conductivity coefficient of the copper foam strips 2 is larger than that of the heat-conducting resistance fuel oil 3, and when the heat conductivity coefficient of the copper foam strips 2 is far higher than that of the heat-conducting resistance fuel oil 3, the heat conductivity of the heat-conducting resistance fuel oil 3 can be improved, and the quick temperature equalization of the battery pack is realized. As a specific example, the heat-conducting flame-retardant oil 3 is silicone oil.
The thickness of the foam copper bar 2 is equal to the width of a gap between battery packs, so that the foam copper bar 2 is tightly attached to the surface of the battery 4 to reduce thermal resistance, and the foam copper bar 2 is effectively fixed; the foam copper strips 2 and the battery 4 are immersed in the heat-conducting flame-retardant oil 3, and the battery box 1 is completely filled with the heat-conducting resistance-retardant oil 3, so that the heat storage capacity can be increased, and the flame-retardant and explosion-proof capabilities can be improved.
When the environmental temperature is lower, the thermal conductive resistance fuel oil 3 in a thermal state is introduced through the inlet of the battery box 1 to exchange heat with the surface of the battery 4 and the foam copper strip 2 so as to preheat the battery pack, thereby ensuring that the battery pack is maintained in an ideal temperature range.
When the battery 4 is at a high temperature, the cold-state heat-conducting flame-retardant oil 3 is introduced through the inlet of the battery box 1, the cold-state heat-conducting resistance fuel continuously flows in from the inlet of the battery box, and flows out from the outlet of the battery box 1 after contacting and exchanging heat with the surface of the battery 4 and the foam copper strip 2, so that the heat of the battery is taken away, and the temperature of the battery pack is reduced. The battery pack is immersed in the heat-conducting flame-retardant oil 3, so that thermal runaway is effectively prevented.
The above description is only a preferred embodiment of the present invention, and does not describe the limitation of the present invention, and the system and the method for detecting a high temperature superconducting magnet should be regarded as the protection scope of the present invention.

Claims (5)

1.一种动力电池,其特征在于:包括电池箱(1)以及排列在电池箱(1)内的多个电池组,所述的电池组由多个圆柱形电池(4)顺序排列形成,相邻的两个电池组之间均穿插有带孔隙的泡沫铜条(2),所述的泡沫铜条(2)与电池(4)表面接触,所述的电池箱(1)内充有导热阻燃油(3),所述导热阻燃油(3)的导热系数大于空气;所述泡沫铜条(2)的导热系数大于导热阻燃油(3),所述的电池箱(1)具有进口和出口。1. A power battery, characterized by comprising a battery box (1) and a plurality of battery packs arranged in the battery box (1), the battery packs being formed by sequentially arranging a plurality of cylindrical batteries (4), A foamed copper strip (2) with pores is interspersed between two adjacent battery packs, the foamed copper strip (2) is in contact with the surface of the battery (4), and the battery box (1) is filled with A thermally conductive flame retardant oil (3), the thermal conductivity of the thermally conductive flame retardant oil (3) is greater than that of air; the thermal conductivity of the foamed copper strip (2) is greater than that of the thermally conductive flame retardant oil (3), and the battery box (1) ) has imports and exports. 2.根据权利要求1所述的一种动力电池,其特征在于,所述的导热阻燃油(3)为硅油。2 . The power battery according to claim 1 , wherein the thermally conductive flame retardant oil ( 3 ) is silicone oil. 3 . 3.根据权利要求1或2所述的一种动力电池,其特征在于,所述的泡沫铜条(2)厚度等于电池组之间的间隙宽度。3. A power battery according to claim 1 or 2, characterized in that, the thickness of the foamed copper strip (2) is equal to the width of the gap between the battery packs. 4.根据权利要求1或2所述的一种动力电池,其特征在于,所述的导热阻燃油(3)充满电池箱(1),所述的泡沫铜条(2)和电池(4)浸没在导热阻燃油(3)内。4. A power battery according to claim 1 or 2, characterized in that the thermally conductive flame retardant oil (3) is filled with the battery box (1), the foamed copper strip (2) and the battery (4) ) is immersed in thermally conductive flame retardant oil (3). 5.一种如权利要求1所述动力电池的热管理方法,其特征在于,当环境温度较低时,通过电池箱(1)的进口通入热态的导热阻燃油(3),与电池(4)表面及泡沫铜条(2)进行换热以实现电池组的预热;当电池(4)处于高温时,通过电池箱(1)的进口通入冷态的导热阻燃油(3),与电池(4)表面及泡沫铜条(2)接触换热后,从电池箱(1)的出口流出将电池热量带走。5. A thermal management method for a power battery according to claim 1, characterized in that, when the ambient temperature is low, the thermally conductive flame retardant oil (3) in a hot state is introduced through the inlet of the battery box (1), and the The surface of the battery (4) and the foam copper strip (2) exchange heat to realize the preheating of the battery pack; when the battery (4) is at a high temperature, a cold heat-conducting flame retardant oil ( 3) After contacting with the surface of the battery (4) and the foam copper strip (2) for heat exchange, the battery will flow out from the outlet of the battery box (1) to take away the heat of the battery.
CN202010064809.6A 2020-01-20 2020-01-20 A kind of power battery and thermal management method thereof Pending CN111211378A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ310052B6 (en) * 2020-09-10 2024-06-19 Qoolers S.R.O. A liquid-filled heat exchanger for cylindrical battery cells

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102544622A (en) * 2011-12-31 2012-07-04 广东工业大学 Power battery cooling system based on foam metal/composite phase change material
CN103474711A (en) * 2012-06-08 2013-12-25 中国人民解放军63971部队 Heat management system of power supply
CN205646054U (en) * 2016-02-03 2016-10-12 上海工程技术大学 Power battery heat radiation structure
CN206685510U (en) * 2017-04-14 2017-11-28 华霆(合肥)动力技术有限公司 Heat-transfer device and supply unit
KR101814774B1 (en) * 2017-04-28 2018-01-03 이택근 Portable power supply device
CN108075081A (en) * 2017-12-29 2018-05-25 广州中国科学院工业技术研究院 Battery pack, battery pack and the vehicle with the battery pack

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102544622A (en) * 2011-12-31 2012-07-04 广东工业大学 Power battery cooling system based on foam metal/composite phase change material
CN103474711A (en) * 2012-06-08 2013-12-25 中国人民解放军63971部队 Heat management system of power supply
CN205646054U (en) * 2016-02-03 2016-10-12 上海工程技术大学 Power battery heat radiation structure
CN206685510U (en) * 2017-04-14 2017-11-28 华霆(合肥)动力技术有限公司 Heat-transfer device and supply unit
KR101814774B1 (en) * 2017-04-28 2018-01-03 이택근 Portable power supply device
CN108075081A (en) * 2017-12-29 2018-05-25 广州中国科学院工业技术研究院 Battery pack, battery pack and the vehicle with the battery pack

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ310052B6 (en) * 2020-09-10 2024-06-19 Qoolers S.R.O. A liquid-filled heat exchanger for cylindrical battery cells

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Application publication date: 20200529