CN111205932B - 一种存放稳定性高的泡腾型洗涤用品及其制备方法 - Google Patents
一种存放稳定性高的泡腾型洗涤用品及其制备方法 Download PDFInfo
- Publication number
- CN111205932B CN111205932B CN202010020404.2A CN202010020404A CN111205932B CN 111205932 B CN111205932 B CN 111205932B CN 202010020404 A CN202010020404 A CN 202010020404A CN 111205932 B CN111205932 B CN 111205932B
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- Prior art keywords
- organic acid
- effervescent
- acid
- storage stability
- sodium
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- 238000005406 washing Methods 0.000 title claims abstract description 61
- 238000003860 storage Methods 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 150000007524 organic acids Chemical class 0.000 claims abstract description 120
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 25
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 22
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 19
- 230000002378 acidificating effect Effects 0.000 claims abstract description 18
- 238000001816 cooling Methods 0.000 claims abstract description 16
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910001868 water Inorganic materials 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 11
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 11
- 239000007921 spray Substances 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 239000003599 detergent Substances 0.000 claims description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- 239000013078 crystal Substances 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 10
- -1 carbon peroxide Chemical class 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- 239000002518 antifoaming agent Substances 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 5
- 235000005985 organic acids Nutrition 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- 102000004190 Enzymes Human genes 0.000 claims description 4
- 108090000790 Enzymes Proteins 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 239000005639 Lauric acid Substances 0.000 claims description 3
- 235000021314 Palmitic acid Nutrition 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 2
- 239000006082 mold release agent Substances 0.000 claims 2
- 239000004711 α-olefin Substances 0.000 claims 2
- 229940079919 digestives enzyme preparation Drugs 0.000 claims 1
- 229940088598 enzyme Drugs 0.000 claims 1
- 239000013538 functional additive Substances 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 238000004090 dissolution Methods 0.000 abstract description 6
- 230000007774 longterm Effects 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 description 10
- 238000010669 acid-base reaction Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000007884 disintegrant Substances 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000003287 bathing Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000007938 effervescent tablet Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000005714 functional activity Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/2079—Monocarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
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Abstract
本发明公开了一种存放稳定性高的泡腾型洗涤用品，包括酸性阴离子表面活性剂、有机酸配合物、碳酸钠和碳酸氢钠；所述的有机酸配合物由有机酸A和有机酸B组成，所述的有机酸A为水溶性的无水有机酸，所述的有机酸B为难溶于水的有机酸；且所述的有机酸配合物通过以下方法制备：将所述的有机酸A和有机酸B混合后，在搅拌的条件下加热至熔融状态，再通过顺流式喷雾冷却法进行冷却，得到有机酸配合物。该泡腾型洗涤用品组分简单，在长期存放后依然能保持泡腾体系的有效性，使用时溶解速度快，能很好地适应泡腾型洗涤用品的使用要求。本发明还公开了所述泡腾型洗涤用品的制备方法。
Description
技术领域
本发明属于泡腾型洗涤剂技术领域，具体涉及一种存放稳定性高的泡腾型洗涤用品及其制备方法。
背景技术
块状洗涤用品，是一种定量的洗涤用品，即每一块洗涤用品的质量是一定的。这样的洗涤用品便于计量，消费者在使用这种洗涤用品时，只需根据实际使用的需要投放相应数量的块状洗涤用品，即可精确地控制洗涤用品的使用量。另一方面，块状洗涤用品不含水，其活性组分的含量可以实现比液态洗涤用品更高，更便于运输和储存。
块状洗涤用品在使用的过程中，需要能快速地溶解。为了保证其溶解速度，现有技术中常用的方法是加入崩解剂。
一种常见的崩解剂包括可快速溶胀的聚合物或者是聚乙烯吡咯烷酮、改性纤维素等，但可快速溶胀的聚合物在长期存放后容易失效，而聚乙烯吡咯烷酮和改性纤维素对崩解速度的改善程度非常有限。
另一种常见的崩解剂，也是目前最有效的崩解剂，是酸碱反应的泡腾体系。如CN1354780A公开了一种泡腾组分，其包括了酸源和二氧化碳源(碱)。但这样的酸碱反应泡腾体系酸源和碱源直接接触，在存放过程中两者容易发生反应，导致其存放稳定性差。尤其是在潮湿的环境下，反应更加容易发生，酸碱中和反应后生成的水被其他发组分吸收，形成结晶水合物，使得泡腾体系失效。
另一方面，为了保证块状洗涤剂在使用时的溶解速度，其组分基本上为粉状的无水组分。由于粉状的无水物质不具有粘性，得到的块状洗涤剂容易在外力的作用下散开。解决的方法之一是使用较高的压力进行压片，但是使用的压力越高，制成的块状洗涤剂崩解性能就越差；另一种方式是使用粘结剂，如CN103966029A公开的茶垢清洗泡腾片及其制备方法，其配方中包含氧化漂白剂、酸性崩解剂、碱性崩解剂、粘结剂和表面活性剂。加入了粘结剂后，所需的压片压力减小。常见的粘结剂包括聚乙二醇、聚乙烯吡咯烷酮、纤维素等。粘结剂的一般在熔融或者融化的状态下，在压片之前的混料期间喷洒在洗涤剂粉末的表面。虽然粘结剂能解决块状洗涤剂机械强度低的问题，但是其提高了块状洗涤剂的原料成本，而且在洗涤过程中，传统的粘结剂是没有洗涤相关的功能活性的物质，有可能会对洗涤效果造成不利影响。
发明内容
本发明的第一个目的在于提供一种存放稳定性高的泡腾型洗涤用品，该泡腾型洗涤用品组分简单，在长期存放后依然能保持泡腾体系的有效性，使用时溶解速度快，能很好地适应泡腾型洗涤用品的使用要求。
本发明的第二个目的在于提供所述存放稳定性高的泡腾型洗涤用品的制备方法。
本发明的第一个目的通过以下技术方案实现：
一种存放稳定性高的泡腾型洗涤用品，包括酸性阴离子表面活性剂、有机酸配合物、碳酸钠和碳酸氢钠；
所述的有机酸配合物由有机酸A和有机酸B组成，所述的有机酸A为水溶性的无水有机酸，所述的有机酸B为难溶于水的有机酸；
且所述的有机酸配合物通过以下方法制备：
将所述的有机酸A和有机酸B混合后，在搅拌的条件下加热至熔融状态，再通过顺流式喷雾冷却法进行冷却，得到有机酸配合物。
所述的有机酸A为多元羧酸，选自柠檬酸、酒石酸、苹果酸中的一种或多种；所述的有机酸B选择常压下熔点大于40℃，且沸点高于180℃的单一有机酸或者多种有机酸的混合物，优选地，包括月桂酸、肉豆蔻酸、棕榈酸、硬脂酸中的一种或多种。
本发明所述的有机酸配合物是保持泡腾体系有效性的关键：所述的有机酸A为易溶于水的有机酸，所述的有机酸B为难溶于水的有机酸。有机酸A和有机酸B混合熔融后，经过顺流式喷雾冷却法冷却的过程中重新造粒，如此得到的有机酸配合物不是简单的混合物。两种类型的有机酸重新结晶，在分子间的结构和晶体形态上发生了改变：
所述的有机酸A的熔点相对较高，在冷却的过程中比有机酸B先结晶。如此一来，有机酸A成为了有机酸配合物的晶核；而有机酸B的相对熔点较低，在冷却的过程中结晶速度慢，更倾向于形成晶壳。
有机酸A为多元羧酸，空间位阻大，在空间结构上，碳链在内，羧基在外。当有机酸A形成晶核以后，其羧基上的氢原子处于缺电子状态，吸引了有机酸B羧基上富电子的羰基氧，如此使得有机酸B在形成晶壳时，羧基朝内，碳链朝外排布。这样的结果是，晶体形成后，晶壳的最外沿均为有机碳链，因而增加了有机酸配合物的疏水性。因而，即使放置于潮湿的环境中，有机酸配合物受潮的概率也很低，不容易与泡腾洗涤剂中的碱发生反应，从而保持酸碱反应泡腾体系的稳定性。
而在使用过程中，将所述泡腾型洗涤用品投入水中后，其中的碳酸钠和碳酸氢钠溶解，碱性增加，有机酸配合物中的晶体结构瓦解，使得酸碱反应迅速发生，产生“泡腾效果”，原本是片状的洗涤剂迅速溶解。在反应的过程中，有机酸B可以形成的脂肪酸皂，还能有效抑制泡腾过程中产生的过量泡沫，在洗涤衣物时，达到过水容易的效果；用于沐浴时，给予皮肤更清爽的感觉。
作为本发明的一种实施方式，所述的存放稳定性高的泡腾型洗涤用品各组分的质量百分比含量如下：
酸性阴离子表面活性剂 8～15％
有机酸配合物 30～40％
碳酸钠 20～35％
碳酸氢钠 10～20％。
作为本发明的一种优选实施方式，所述的有机酸配合物中，所述有机酸B的质量为有机酸A质量的5～10％。
在所述有机酸配合物的制备过程中，加热的温度依据具体选用的有机酸A和有机酸B的具体种类而定，只要使得有机酸A和有机酸B全部都达到熔融状态即可，一般而言不超过175℃。
所述有机酸配合物的粒径优选为60～180目，更优选地，为80～120目。
所述的泡腾型洗涤用品中的酸性阴离子表面活性剂能起到粘结剂的作用，在此情况下，本发明已无需再添加传统的粘结剂就能使所述的泡腾型洗涤用品具有良好的机械性能。而且在将所述泡腾型洗涤用品投入水中后，所述的酸性阴离子表面活性剂能与碳酸钠发生反应并迅速地溶解于水中，该溶解速度比物理溶解过程更为迅速，从而使得所述泡腾型洗涤用品迅速溶解。所述的酸性阴离子表面活性剂选自直链烷基苯磺酸和/或脂肪醇聚氧乙烯醚羧酸。
所述顺流式喷雾冷却法进行冷却的过程中，喷雾塔的进风口温度为150～180℃，出风口温度不高于55℃。
本发明所述的泡腾型洗涤用品还可以根据实际的使用需要添加其他对洗涤剂有益的成分，包括固体高分子助洗剂、层状硅酸钠、过氧化碳、4A沸石、固体脂肪醇硫酸钠、粉状α-烯基磺酸钠、酶制剂、膨润土、香精、脂肪醇聚氧乙烯醚、脂肪酸甲酯磺酸钠、柠檬酸钠、聚丙烯酸盐、脱模剂和消泡剂中的一种或多种。其添加量按照一般洗涤用品的使用需求添加即可。
本发明的第二个目的通过以下技术方案实现：
一种存放稳定性高的泡腾型洗涤用品的制备方法，包括以下步骤：
(1)将酸性阴离子表面活性剂与碳酸钠混合，令所述酸性阴离子表面活性剂被碳酸钠完全吸附，然后加入碳酸氢钠和所述的有机酸配合物并混合均匀；
(2)将步骤(1)混合后的粉体进行压片，得到存放稳定性高的泡腾型洗涤用品。
在所述的制备方法中：
步骤(1)中，可以将包括固体高分子助洗剂、层状硅酸钠、过氧化碳、4A沸石、固体脂肪醇硫酸钠、粉状α-烯基磺酸钠、酶制剂、膨润土、香精、脂肪醇聚氧乙烯醚、脂肪酸甲酯磺酸钠、柠檬酸钠、聚丙烯酸盐、脱模剂和消泡剂中的一种或多种功能性助剂与碳酸氢钠、有机酸配合物一起混合均匀。
步骤(2)中压片过程的压力为60～150kN。
所述的存放稳定性高的泡腾型洗涤用品的制备方法常见的用途包括餐具清洗剂、衣物洗涤剂和泡泡浴盐。
与现有技术相比，本发明具有以下有益效果：
1、本发明解决了现有技术中酸碱反应的泡腾体系存放稳定性差的问题，通过具有疏水性晶壳的有机酸组合物降低了在存放过程中受潮的几率，从而避免在存放过程中因受潮引起泡腾型洗涤用品中发生酸碱反应而导致该泡腾体系失效的问题；
2、本发明中所述的酸性阴离子表面活性剂能起到粘结的作用，提高泡腾型洗涤用品的机械强度，避免压片所需的压力过大而导致泡腾型洗涤用品的溶解性变差，也而无需再加入传统的粘结剂；在使用的过程中，所述的酸性阴离子表面活性剂能与碳酸钠发生反应并迅速地溶解于水中，一方面不会影响洗涤的效果，另一方面能进一步加快泡腾型洗涤用品的溶解速度；
3、本发明在使用的过程中，有机酸B可以形成的脂肪酸皂，能有效抑制泡腾过程中产生的过量泡沫，在洗涤衣物时，达到过水容易的效果；用于沐浴时，给予皮肤更清爽的感觉。
具体实施方式
以下通过具体的实施例对本发明作进一步的说明。
有机酸配合物a～e的制备
通过以下方法制备有机酸配合物a～e：
将所述的有机酸A和有机酸B混合后，在搅拌的条件下加热至熔融状态，保温至所有的有机酸A和有机酸B完全熔融至透明，再通过顺流式喷雾冷却法进行冷却，然后将产品过筛，以筛选出粒径在特定目数范围内的有机酸配合物。
具体的组分和制备条件如下表所示：
实施例1～8
通过以下方法制备泡腾型洗涤用品：
(1)将酸性阴离子表面活性剂与碳酸钠混合，令所述酸性阴离子表面活性剂被碳酸钠完全吸附，然后加入碳酸氢钠、有机酸配合物和其他对洗涤剂有益的成分，并混合均匀；
(2)将混合后的粉体进行压片，得到存放稳定性高的泡腾型洗涤用品。
制备完成通过强化处理，并进行崩解时间测试。
所述的强化处理为将泡腾型洗涤用品置于35℃、85％湿度的条件下放置两周。
崩解时间测试方法：
将待测泡腾型洗涤用品样品(30g/片)放置于25℃，体积为1L的水中，计算样品从泡入水中至完全崩解的时间。
实施例1～8的具体组分和测试结果如下表所示，表中的数据均以质量百分比表示；表中的对比例为组分含量与对应的实施例相同，但有机酸A和有机酸B仅采用简单的物理混合，而没有经过上述有机酸配合物a～e制备过程所制得的泡腾型洗涤用品：
对比实施例与对比例的崩解时间可见，本发明所述的泡腾型洗涤用品相对于将两种有机酸简单进行混合制得的泡腾型洗涤用品而言，崩解速度明显更快；经过强化处理后这种差距更加明显，而且本发明所述的泡腾型洗涤用品在强化处理前后的崩解时间几无区别，这也反映出本发明所述的泡腾型洗涤用品能切实有效地解决现有泡腾型洗涤用品存放稳定性差的问题。
有机酸配合物粒径对崩解速度的影响
测试有机酸配合物的粒径对泡腾型洗涤用品崩解速度的影响，下表中的实施例1～8与上表的区别仅在于有机酸配合物的粒径不同，表中数据表示崩解时间(s)：
由上表可见，当有机酸配合物的粒径在80～120目范围内时，泡腾型洗涤用品的崩解时间更短。
上述实施例仅是对本发明的示例性说明，各组分之间及含量可以在本发明所限定的范围内随意替换，不影响本发明目的的实现。
具体地，按质量百分比计算，本发明所述的泡腾型洗涤用品包括酸性阴离子表面活性剂8～15％；有机酸配合物30～40％；碳酸钠20～35％；碳酸氢钠10～20％。
所述的有机酸配合物中，所述有机酸B的质量为有机酸A质量的5～10％。
所述的有机酸A为多元羧酸，可以是柠檬酸、酒石酸、苹果酸中的一种或多种；所述的有机酸B选择常压下熔点大于40℃，且沸点高于180℃的单一有机酸或者多种有机酸的混合物，可以是月桂酸、肉豆蔻酸、棕榈酸、硬脂酸中的一种或多种。
所述的酸性阴离子表面活性剂选自直链烷基苯磺酸和/或脂肪醇聚氧乙烯醚羧酸。
其他对洗涤用品有益的成分为可选择性添加组分，本领域技术人员可根据实际需要选择添加/或不添加，具体包括固体高分子助洗剂、层状硅酸钠、过氧化碳、4A沸石、固体脂肪醇硫酸钠、粉状α-烯基磺酸钠、酶制剂、膨润土、香精、脂肪醇聚氧乙烯醚、脂肪酸甲酯磺酸钠、柠檬酸钠、聚丙烯酸盐、脱模剂和消泡剂中的一种或多种。
需要指出的是，上述实施例仅是对本发明的进一步说明，而不是限制，本领域技术人员在与本发明技术方案的相当的含义和范围内的任何调整或改变，都应认为是包括在本发明的保护范围内。
Claims (14)
1.一种存放稳定性高的泡腾型洗涤用品，其特征在于，包括酸性阴离子表面活性剂、有机酸配合物、碳酸钠和碳酸氢钠；
所述的有机酸配合物由有机酸A和有机酸B组成，所述的有机酸A为水溶性的无水有机酸，所述的有机酸B为难溶于水的有机酸；
且所述的有机酸配合物通过以下方法制备：
将所述的有机酸A和有机酸B混合后，在搅拌的条件下加热至熔融状态，所述有机酸A的熔点高于所述有机酸B的熔点，再通过顺流式喷雾冷却法进行冷却，得到的有机酸配合物为有机酸A为晶核，有机酸B为晶壳。
2.根据权利要求1所述的存放稳定性高的泡腾型洗涤用品，其特征在于，各组分的质量百分比含量如下：
酸性阴离子表面活性剂8～15％
有机酸配合物30～40％
碳酸钠20～35％
碳酸氢钠10～20％。
3.根据权利要求2所述的存放稳定性高的泡腾型洗涤用品，其特征在于，所述的有机酸配合物中，所述有机酸B的质量为有机酸A质量的5～10％。
4.根据权利要求3所述的存放稳定性高的泡腾型洗涤用品，其特征在于，所述的有机酸A为多元羧酸；所述的有机酸B为常压下熔点大于40℃，且沸点高于180℃的单一有机酸或者多种有机酸的混合物。
5.根据权利要求4所述的存放稳定性高的泡腾型洗涤用品，其特征在于，所述的有机酸A选自柠檬酸、酒石酸、苹果酸中的一种或多种。
6.根据权利要求4所述的存放稳定性高的泡腾型洗涤用品，其特征在于，所述的有机酸B包括月桂酸、肉豆蔻酸、棕榈酸、硬脂酸中的一种或多种。
7.根据权利要求4所述的存放稳定性高的泡腾型洗涤用品，其特征在于，所述有机酸配合物的粒径为60～180目。
8.根据权利要求7所述的存放稳定性高的泡腾型洗涤用品，其特征在于，所述有机酸配合物的粒径为80～120目。
9.根据权利要求4所述的存放稳定性高的泡腾型洗涤用品，其特征在于，所述的酸性阴离子表面活性剂选自直链烷基苯磺酸和/或脂肪醇聚氧乙烯醚羧酸。
10.根据权利要求4所述的存放稳定性高的泡腾型洗涤用品，其特征在于，所述顺流式喷雾冷却法进行冷却的过程中，喷雾塔的进风口温度为150～180℃，出风口温度不高于55℃。
11.根据权利要求4所述的存放稳定性高的泡腾型洗涤用品，其特征在于，还包括固体高分子助洗剂、层状硅酸钠、过氧化碳、4A沸石、固体脂肪醇硫酸钠、粉状α-烯基磺酸钠、酶制剂、膨润土、香精、脂肪醇聚氧乙烯醚、脂肪酸甲酯磺酸钠、柠檬酸钠、聚丙烯酸盐、脱模剂和消泡剂中的一种或多种。
12.一种权利要求1～11任一项所述存放稳定性高的泡腾型洗涤用品的制备方法，其特征在于：包括以下步骤：
(1)将酸性阴离子表面活性剂与碳酸钠混合，令所述酸性阴离子表面活性剂被碳酸钠完全吸附，然后加入碳酸氢钠和所述的有机酸配合物并混合均匀；
(2)将步骤(1)混合后的粉体进行压片，得到存放稳定性高的泡腾型洗涤用品。
13.根据权利要求12所述的存放稳定性高的泡腾型洗涤用品的制备方法，其特征在于，步骤(1)中，将包括固体高分子助洗剂、层状硅酸钠、过氧化碳、4A沸石、固体脂肪醇硫酸钠、粉状α-烯基磺酸钠、酶制剂、膨润土、香精、脂肪醇聚氧乙烯醚、脂肪酸甲酯磺酸钠、柠檬酸钠、聚丙烯酸盐、脱模剂和消泡剂中的一种或多种功能性助剂与碳酸氢钠、有机酸配合物一起混合均匀。
14.根据权利要求12所述的存放稳定性高的泡腾型洗涤用品的制备方法，其特征在于，步骤(2)中压片过程的压力为60～150kN。
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