CN111109285A - Chlorine dioxide instant dissolving substance with strong selectivity for indoor spraying - Google Patents
Chlorine dioxide instant dissolving substance with strong selectivity for indoor spraying Download PDFInfo
- Publication number
- CN111109285A CN111109285A CN201911143914.2A CN201911143914A CN111109285A CN 111109285 A CN111109285 A CN 111109285A CN 201911143914 A CN201911143914 A CN 201911143914A CN 111109285 A CN111109285 A CN 111109285A
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- China
- Prior art keywords
- solid
- chlorine dioxide
- antioxidant
- food
- sodium chlorite
- Prior art date
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 122
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 61
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 61
- 238000005507 spraying Methods 0.000 title claims abstract description 10
- 239000000126 substance Substances 0.000 title abstract description 12
- 239000007787 solid Substances 0.000 claims abstract description 59
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 46
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 43
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 28
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims abstract description 28
- 229960002218 sodium chlorite Drugs 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 235000011056 potassium acetate Nutrition 0.000 claims abstract description 18
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 15
- 239000002245 particle Substances 0.000 claims abstract description 14
- 229920002472 Starch Polymers 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 235000019698 starch Nutrition 0.000 claims abstract description 13
- 239000008107 starch Substances 0.000 claims abstract description 13
- 230000003647 oxidation Effects 0.000 claims abstract description 12
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
- 239000000341 volatile oil Substances 0.000 claims abstract description 8
- 230000008569 process Effects 0.000 claims abstract description 7
- 238000003825 pressing Methods 0.000 claims abstract description 5
- 238000000748 compression moulding Methods 0.000 claims abstract description 3
- 235000006708 antioxidants Nutrition 0.000 claims description 43
- 239000003921 oil Substances 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 11
- 239000007921 spray Substances 0.000 claims description 8
- 239000000645 desinfectant Substances 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 6
- 239000000686 essence Substances 0.000 claims description 5
- 239000003205 fragrance Substances 0.000 claims description 4
- 241001122767 Theaceae Species 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- XMYHHSMIUHHPEW-UHFFFAOYSA-N azane;molybdenum Chemical compound N.[Mo] XMYHHSMIUHHPEW-UHFFFAOYSA-N 0.000 claims description 3
- 239000002304 perfume Substances 0.000 claims description 3
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 3
- 235000013824 polyphenols Nutrition 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 239000002530 phenolic antioxidant Substances 0.000 claims description 2
- JEBFVOLFMLUKLF-IFPLVEIFSA-N Astaxanthin Natural products CC(=C/C=C/C(=C/C=C/C1=C(C)C(=O)C(O)CC1(C)C)/C)C=CC=C(/C)C=CC=C(/C)C=CC2=C(C)C(=O)C(O)CC2(C)C JEBFVOLFMLUKLF-IFPLVEIFSA-N 0.000 claims 1
- 241000168517 Haematococcus lacustris Species 0.000 claims 1
- 235000013793 astaxanthin Nutrition 0.000 claims 1
- MQZIGYBFDRPAKN-ZWAPEEGVSA-N astaxanthin Chemical compound C([C@H](O)C(=O)C=1C)C(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)C(=O)[C@@H](O)CC1(C)C MQZIGYBFDRPAKN-ZWAPEEGVSA-N 0.000 claims 1
- 229940022405 astaxanthin Drugs 0.000 claims 1
- 239000001168 astaxanthin Substances 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 3
- 244000005700 microbiome Species 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 abstract description 2
- 229960002715 nicotine Drugs 0.000 abstract description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 abstract description 2
- 241000894006 Bacteria Species 0.000 abstract 1
- 241000195493 Cryptophyta Species 0.000 abstract 1
- 241000700605 Viruses Species 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000004659 sterilization and disinfection Methods 0.000 description 12
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 8
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 8
- 230000001954 sterilising effect Effects 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000001590 oxidative effect Effects 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000006378 damage Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 4
- 230000004913 activation Effects 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000012024 dehydrating agents Substances 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920002401 polyacrylamide Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 206010063409 Acarodermatitis Diseases 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- ITRJWOMZKQRYTA-RFZYENFJSA-N Cortisone acetate Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)COC(=O)C)(O)[C@@]1(C)CC2=O ITRJWOMZKQRYTA-RFZYENFJSA-N 0.000 description 1
- 239000004593 Epoxy Chemical group 0.000 description 1
- WJOHZNCJWYWUJD-IUGZLZTKSA-N Fluocinonide Chemical compound C1([C@@H](F)C2)=CC(=O)C=C[C@]1(C)[C@]1(F)[C@@H]2[C@@H]2C[C@H]3OC(C)(C)O[C@@]3(C(=O)COC(=O)C)[C@@]2(C)C[C@@H]1O WJOHZNCJWYWUJD-IUGZLZTKSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- 241000447727 Scabies Species 0.000 description 1
- 229910020489 SiO3 Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- FPVRUILUEYSIMD-RPRRAYFGSA-N [(8s,9r,10s,11s,13s,14s,16r,17r)-9-fluoro-11-hydroxy-17-(2-hydroxyacetyl)-10,13,16-trimethyl-3-oxo-6,7,8,11,12,14,15,16-octahydrocyclopenta[a]phenanthren-17-yl] acetate Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1C[C@@H](C)[C@@](C(=O)CO)(OC(C)=O)[C@@]1(C)C[C@@H]2O FPVRUILUEYSIMD-RPRRAYFGSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229940022663 acetate Drugs 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229960002537 betamethasone Drugs 0.000 description 1
- UREBDLICKHMUKA-DVTGEIKXSA-N betamethasone Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1C[C@H](C)[C@@](C(=O)CO)(O)[C@@]1(C)C[C@@H]2O UREBDLICKHMUKA-DVTGEIKXSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229960003290 cortisone acetate Drugs 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229960003657 dexamethasone acetate Drugs 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229960000785 fluocinonide Drugs 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 238000009920 food preservation Methods 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000021552 granulated sugar Nutrition 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 208000005687 scabies Diseases 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental Sciences (AREA)
- Biomedical Technology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Dispersion Chemistry (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a chlorine dioxide instant dissolving material for indoor spraying with strong selectivity and strong oxidation, which comprises solid sodium chlorite, solid potassium acetate, solid silicic acid, starch, water, solid antioxidant and aromatic hydrocarbon or essential oil, wherein the starch, the potassium acetate and the water are put into a food-grade stirrer to be stirred, then the sodium chlorite, the solid antioxidant and the solid silicic acid are respectively put into the stirrer to be continuously stirred, then the mixture is completely put into a food-grade crusher to be crushed, the crushed powder is put into a pressing mould according to the weight of tablets, and the solid particles with the diameter of 1-3mm and the length of 1-3mm are formed by compression molding. The invention provides a chlorine dioxide instant dissolving substance for indoor spraying with strong selectivity, which does not contain chlorine dioxide in the storage process of a composition, has no defects of shelf life and potential safety hazard, reacts chlorine dioxide gas after being soaked in water, efficiently kills bacteria, algae, viruses and microorganisms for a long time, and decomposes harmful substances such as methanol, nicotine and the like.
Description
The technical field is as follows:
the invention relates to the field of disinfectants, in particular to a chlorine dioxide instant dissolving material for indoor spraying with selective strong oxidation.
Background art:
chlorine dioxide is a fourth generation disinfectant, has particularly excellent performance, has great progress in sterilization, disinfection and strong oxidizing property compared with the conventional disinfectants of other types, and is used as an oxidant, a deodorizer, a biocide, a preservative, a bleaching agent and the like. Chlorine dioxide is popular among people because of its characteristics of strong bactericidal power, no harm to human bodies and animals, no secondary pollution to the environment, and the like. Chlorine dioxide is not only a broad-spectrum environment-friendly type sterilization disinfectant which does not generate carcinogens, but also has obvious effects on sterilization, food preservation, deodorization and the like.
Chlorine dioxide is a gas at normal temperature, has active chemical properties, strong oxidizing property, is easy to decompose or oxidize and decompose other substances, is easy to dissolve in water, is easy to explode when the content in the air reaches 10 percent, is dissolved in water, is easy to explode when the content is more than 30 percent, has obvious advantages and defects, has broad spectrum, sterilization, disinfection, safety, no toxicity, no residue, is friendly to human bodies and cultured objects, has short shelf life, is easy to decompose and reduce the performance activity, and has potential safety hazards in storage and transportation.
The molecular formula of sodium chlorite is NaClO2The main application is as follows: 1. it is used for bleaching paper pulp, fibre, flour, starch and oil, etc., purifying drinking water and sewage, removing hair from leather and preparing aqueous solution of chlorine dioxide. Is a high-efficiency bleaching agent and an oxidant, and can also be used as a discharging agent, an oxidant, a bactericide, purified water and a fabric bleaching agent for dyeing indanthrene. 2. The bleaching agent is used as a bleaching agent in the food industry, and a corrosion-resistant container is required for bleaching, so that a metal container cannot be used. 3. High-efficiency bleaching agent and oxidant for paper pulp, paper and various fibers, and white granulated sugar, flour, starch, oil and wax can also be bleached. 4. The method is used for purifying drinking water, and the sewage is treated without residual chlorine smell, and has the functions of sterilization, phenol removal and deodorization.
Potassium acetate is also called potassium acetate, and the molecular formula is C2H3KO2Molecular weight 98.1423, which is used as dehydrating agent, fiber treating agent and analytical reagent, and has the main application: 1. the product is used as dehydrating agent, fiber treating agent and analytical reagent. As a penicillium culture medium in the pharmaceutical industry, potassium acetate is used as a raw material in the production of cortisone acetate, hydroprednism birch acetate, dexamethasone acetate, betamethasone, fluocinonide and the like. 2. Used as analytical reagents and catalysts. 3. Used as an analytical reagent to adjust ph. Used as a desiccant. Transparent glass is manufactured. Used in the pharmaceutical industry. 4. Can be used for treating fluoroplastic in a molten state at 295 ℃/30min, and improves the bonding property of the surface. It can also be used as dehydrating agent and buffering agent. It can also catalyze the reaction of CTBN terminal carboxyl and epoxy.
The antioxidant effect of different antioxidants in the same oil is different, and the antioxidant effect is best to play the synergistic effect of different antioxidants and use a synergist. In addition, antioxidants also show different antioxidant effects in different oils.
The master paper 'preparation of chlorine dioxide solid preparation and research on its stability' of the Zhushiqi of the Harbin Industrial university introduces: chlorine dioxide is a strong oxidant, has strong sterilization capability and is widely applied. However, chlorine dioxide is unstable and inconvenient to transport and store, and must be prepared on site, so that "stable" chlorine dioxide arises at the discretion of the user and needs to be activated for use. The chlorine dioxide solid preparation as one kind of stable chlorine dioxide has the features of high stability, high chlorine dioxide content, convenient use, etc. and has wide application. The method aims at providing an activating agent, an activation promoter and a stabilizing agent which can quickly release chlorine dioxide, have high chlorine dioxide content and good stability. The method for preparing chlorine dioxide by sodium chlorite is systematically researched, the optimal reaction conditions are determined through orthogonal experiments, and the influence of single factors on the concentration and purity of chlorine dioxide is examined. The research finds that: sodium persulfate, lactic acid, citric acid and malic acid are respectively used as activators, and the reaction is very slow and the conversion rate is low at room temperature; phosphoric acid and sodium bisulfate are respectively used as activating agents, and the reaction speed is higher but the conversion rate is low under the condition of room temperature; the chlorine dioxide generation can be carried out at room temperature by using sodium chlorite as a generating agent, sodium bisulfate as an activating agent and glucose and S as activating promoters respectively, the reaction time is short, the conversion rate can reach more than 71 percent, and the purity can reach more than 98 percent. Because the reaction conditions are easy to control, the 2 formula components are decided to be applied to the development and research of the chlorine dioxide solid preparation. On the basis of the research on the activation method, the formula composition of the binary chlorine dioxide solid preparation is researched and developed. The optimal formula of the solid preparation is screened out by taking high activation rate, high chlorine dioxide concentration and low production cost as formula selection standards. Wherein, sodium chlorite, sodium bisulfate and S are used as the components of the formula, and the optimal components are as follows: 2.50g of sodium chlorite, 5.0g of sodium bisulfate and 2.0g of S. Sodium chlorite, sodium bisulfate, glucose and S are used as formula components, and the optimal composition is as follows: 2.50g of sodium chlorite, 5.0g of sodium bisulfate, 10.0g of glucose and 0.25g of S. Both of these optimum compositions produce 1000mg/L chlorine dioxide solution when dissolved in 1L water. On the basis of the research on the formulation composition of the binary chlorine dioxide solid preparation, the unitary chlorine dioxide solid preparation is researched and developed. In order to ensure the stability of the unitary chlorine dioxide solid preparation, 3 high molecular organic matters of polyvinylpyrrolidone, polyvinyl alcohol and polyacrylamide are respectively added into the components as stabilizers, and sodium chlorite is microencapsulated, so that a uniform film is formed on the surface layer of the sodium chlorite, and the aim of effectively isolating the sodium chlorite from other components is fulfilled. The monoprotic chlorine dioxide solid preparation is developed by taking good activation effect, high conversion rate, low cost, good stability and easy operability of the industrial preparation process as a process breakthrough point. Wherein, when the polyvinylpyrrolidone is used as the stabilizer, the polyvinylpyrrolidone is eliminated because of easy moisture absorption and poor stability; when polyacrylamide is used as a stabilizer, the optimal composition is as follows: 0.57g of polyacrylamide, 2.50g of sodium chlorite, 5.0g of sodium bisulfate and 2.0g of S; when polyvinyl alcohol is used as a stabilizer, the optimal composition is as follows: polyvinyl alcohol 0.76g, sodium chlorite 2.50g, sodium bisulfate 5.0g, S2.0 g. The product developed by the two formulas can ensure that the storage period of the product is 1 year, and solves the problem of poor stability of the unitary chlorine dioxide solid preparation. The researched and developed novel chlorine dioxide solid preparation has important use value and application prospect.
The invention content is as follows:
the invention aims to overcome the problems in the prior art, provides a chlorine dioxide instant dissolving substance for selective strong oxidation indoor spraying, the composition does not contain chlorine dioxide, and the inherent quality guarantee period and potential safety hazard defects of the chlorine dioxide do not exist, chlorine dioxide gas is continuously, slowly, long-term and stably reacted after water immersion and slow permeation and complex chemical reaction, the chlorine dioxide instant dissolving substance is particularly suitable for quickly and uniformly providing chlorine dioxide spraying for the local environment of a user by using an ultrasonic sprayer, carrying out high-efficiency comfortable environmental disinfection, sterilization and humidification, selecting a proper antioxidant according to microorganisms needing to be protected, selectively offsetting the strong oxidation influence of the chlorine dioxide, and specifically reducing certain harm, avoiding injuring or protecting plants and pets grown in the user environment.
In order to solve the technical problems, the invention is realized by the following technical scheme:
a chlorine dioxide instant dissolving material for indoor spraying with strong selectivity comprises solid sodium chlorite, solid potassium acetate, solid silicic acid, starch (the particle size is below 40 meshes), water, a solid antioxidant and aromatic hydrocarbon or essential oil, wherein the starch, the potassium acetate and the water are placed into a food-grade stirring machine according to the mass ratio of 60:35: 5-10 and are stirred for 3-5 minutes, then the sodium chlorite, the solid antioxidant and the solid silicic acid are respectively placed into the stirring machine according to the molar ratio of 30:1:20, the total weight of the sodium chlorite, the solid antioxidant and the solid silicic acid accounts for 7-15% of the total weight, the stirring is continued for 5-10 minutes, the mixture is placed into a food-grade crushing machine to be crushed for 15-60 seconds, an 80-mesh screen is used for filtering impurities, the crushed powder is placed into a pressing die according to the weight of tablets, and is pressed into solid particles with.
And further, the food grade anti-oxidant additive also comprises blending oil, wherein the solid anti-oxidant is firstly added into the blending oil, the added solid anti-oxidant accounts for 1-3% of the mass ratio of the mixture, and the blending oil is put into the food grade stirrer in the second stirring procedure and is stirred together with the powdery mixture.
Further, the antioxidant is an organic antioxidant, comprising: the content of the phenolic antioxidant or the amine antioxidant or the molybdenum-ammonia complex is 0.01 to 0.05 percent of the total mass.
Further, the antioxidant is a plant antioxidant rich in tea polyphenol, comprising: the content of pulverized material (particle size below 40 mesh) of folium Camelliae sinensis, folium Camelliae sinensis residue, branch powder, and leftover is 0.1-0.5% of total mass.
Furthermore, according to the preference of the user, a proper amount of perfume or essence or essential oil is added into the blend oil, so that the taste of the light disinfectant in the chlorine dioxide spray is covered, and the flavor which the user likes is given off.
Compared with the prior art, the invention has the beneficial effects that:
1. the problems that chlorine dioxide is easy to deteriorate (decomposed into toxic chlorine and oxygen) and short in shelf life are solved, and the problem that chlorine dioxide is easy to explode when packaged and stored (when the content in air reaches 10%, the chlorine dioxide is easy to explode, and is dissolved in water, and when the content is more than 30%, the water solution is easy to explode);
2. the ultrasonic sprayer is suitable for quickly and uniformly providing chlorine dioxide spray for local environment of a user continuously, and high-efficiency and comfortable environment disinfection, sterilization and humidification are carried out;
3. the variety of the blend oil or the fragrance type of the essence and the concentration of the fragrance are controlled, so that the most suitable individual preference taste can be prepared;
4. the complex operation of professionals is not needed, and the fixed-point quantification is convenient and more accurate to apply;
5. the selection of the antioxidant is particularly suitable for killing, decomposing and protecting flora, microorganisms and toxic substances in hospitals, and the released concentration is harmless to respiratory tracts, skins and pets of human bodies;
6. has obvious improvement effect on removing harmful substances such as methanol and the like in indoor decoration and removing nicotine in smoke generated by smoking.
The foregoing is a summary of the present invention, and in order to provide a clear understanding of the technical means of the present invention and to be implemented in accordance with the present specification, the following is a detailed description of the preferred embodiments of the present invention with reference to the accompanying drawings. The detailed description of the present invention is given in detail by the following examples and the accompanying drawings.
Description of the drawings:
the accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the invention and together with the description serve to explain the invention without limiting the invention. In the drawings:
FIG. 1 is a schematic view of a column structure according to an embodiment of the present invention;
fig. 2 is a schematic diagram of the working principle of an embodiment of the present invention.
The reference numbers in the figures illustrate: 1. solid sodium chlorite, 2 solid potassium acetate, 3 solid silicic acid, 4 starch, 5 solid antioxidant, 6 aromatic substances.
The specific implementation mode is as follows:
the invention is described in detail below with reference to the following figures and embodiments:
referring to fig. 1-2, the chlorine dioxide instant dissolving material for indoor spraying with strong selectivity oxidation comprises solid sodium chlorite, solid potassium acetate, solid silicic acid, starch (the particle size is below 40 meshes), water, and also comprises solid antioxidant and aromatic hydrocarbon or essential oil, the mass ratio of the starch, the potassium acetate and the water is 60:35: 5-10, the starch, the potassium acetate and the water are placed into a food grade stirrer to be stirred for 3-5 minutes, then the sodium chlorite, the solid antioxidant and the solid silicic acid are respectively placed into the stirrer according to the mol ratio of 30:1:20, the total weight of the three accounts for 7% -15% of the total weight, the stirring is continued for 5-10 minutes, the mixture is completely placed into a food grade crusher to be crushed for 15-60 seconds, the crushed powder is placed into a pressing mold according to the weight of tablets, and is pressed into solid particles with the diameter of 1-3mm and the length, according to the mass ratio of the mixture of 100: 1-3, the blend oil is put into a food-grade stirrer in the stirring process, the blend oil and the powdery mixture are stirred together, the applied solid antioxidant can selectively counteract the strong oxidation influence of chlorine dioxide in some aspects, and different antioxidants are selected to purposefully reduce some damages and avoid injuring or protecting plants and pets raised in the user environment to different degrees.
And further, the method also comprises blending oil, wherein the solid antioxidant is added into the blending oil firstly, the added solid antioxidant accounts for 1-3% of the mass ratio of the mixture, and the blending oil is added into the food-grade stirrer in the second stirring process and is stirred together with the powdery mixture.
Furthermore, according to the preference of the user, a proper amount of perfume or essence or essential oil is added into the blend oil, so that the taste of the light disinfectant in the chlorine dioxide spray is covered, and the flavor which the user likes is given off.
Further, the antioxidant is a phenol antioxidant, an amine antioxidant or a molybdenum-ammonia complex, and the content of the antioxidant is 0.01-0.05% of the total mass.
Furthermore, the antioxidant can also be selected from plant antioxidant rich in tea polyphenols, such as folium Camelliae sinensis, residue of folium Camelliae sinensis, branch powder, and crushed material of leftover (particle size below 40 mesh), with content of 0.1-0.5% of total mass.
The working principle of the embodiment is as follows:
the composition particles are purchased by a user and put into an ultrasonic sprayer according to the recommended using amount, water is added, the composition particles sink to the water bottom, solid potassium acetate is very soluble in water and has extremely high solubility, 256 grams of water with the temperature of 100 grams and 20 ℃ can be dissolved, the potassium acetate meeting the water is quickly dissolved and diffused, the composition particles quickly generate scabies and are disintegrated, the diffusion motion of the potassium acetate drives water flow to circulate, the composition particles are quickly and completely dissolved by the ultrasonic vibration of the ultrasonic sprayer, solid sodium chlorite and solid silicic acid respectively absorb water to be changed into sodium chlorite solution and silicic acid solution, the sodium chlorite solution and the silicic acid solution are mutually fused while being diffused, and chemical reaction is carried out to generate sodium silicate, sodium chloride water and chlorine dioxide, and the chemical reaction formula is as follows: 3NaClO2+2H2SiO3= Na2SiO3+NaCl+ 2H2O+2ClO2×) @, the production of chlorine dioxide without direct use of hydrochloric acid is due to the fact that hydrochloric acid is corrosive, easily corrodes the container, and is liquid, and cannot be made into solid particles together with sodium chlorite without chemical reaction, while sodium chlorite, potassium acetate, silicic acid, starchThe antioxidant can be solid, even if the antioxidant is mixed in a solid state, the antioxidant hardly generates chemical reaction due to the lack of necessary free ions, so the antioxidant can be preserved and stored for a long time, potassium acetate and starch are used for maintaining the shape of compression molding, and after the antioxidant is quickly dissolved in water, chlorine dioxide can be quickly generated by utilizing the diffusion speed, so that the strong oxidation effect of the chlorine dioxide is inhibited, the strong oxidation influence of the chlorine dioxide can be selectively counteracted by adding different types of antioxidants according to different requirements, and the harm can be reduced, and the harm to plants and pets planted in the user environment can be avoided or protected. The fragrant oil, aromatic hydrocarbon, essence or essential oil can be mixed in the process of stirring and pressing, the aromatic substances are also diffused in water, and the fragrant substances are dispersed along with fog in the process of ultrasonic atomization, so that the fragrance is diffused all around and is distributed in the environment of a user.
It is to be emphasized that: the above embodiments are only preferred embodiments of the present invention, and are not intended to limit the present invention in any way, and all simple modifications, equivalent changes and modifications made to the above embodiments according to the technical spirit of the present invention are within the scope of the technical solution of the present invention.
Claims (5)
1. The chlorine dioxide instant dissolving material for indoor spraying with strong selectivity comprises solid sodium chlorite, solid potassium acetate, solid silicic acid, starch (the grain diameter is less than 40 meshes) and water, and is characterized in that: the preparation method comprises the steps of adding starch, potassium acetate and water into a food-grade stirrer at a mass ratio of 60:35: 5-10, stirring for 3-5 minutes, adding sodium chlorite, a solid antioxidant and solid silicic acid into the stirrer at a molar ratio of 30:1:20, wherein the sodium chlorite, the solid antioxidant and the solid silicic acid account for 7-15% of the total weight, continuously stirring for 5-10 minutes, completely adding the mixture into a food-grade crusher, crushing for 15-60 seconds, filtering impurities by using a 80-mesh screen, adding the crushed powder into a pressing mold according to the weight of tablets, and performing compression molding to obtain solid particles with the diameter of 1-3mm and the length of 1-3 mm.
2. A chlorine dioxide fast dissolving product for indoor spray with selective strong oxidation according to claim 1, characterized in that: the food-grade mixed oil is characterized by further comprising mixed oil, wherein the solid antioxidant is added into the mixed oil firstly, the added solid antioxidant accounts for 1-3% of the mass ratio of the mixture, the mixed oil is placed into the food-grade stirrer in the second stirring process, and the mixed oil and the powdery mixture are stirred together.
3. A chlorine dioxide fast dissolving product for indoor spray with selective strong oxidation according to claim 1, characterized in that: the antioxidant is an organic antioxidant, and comprises: the content of the phenolic antioxidant or the amine antioxidant or the molybdenum-ammonia complex is 0.01 to 0.05 percent of the total mass.
4. A chlorine dioxide fast dissolving product for indoor spray with selective strong oxidation according to claim 1, characterized in that: the antioxidant is a plant antioxidant rich in tea polyphenol, and comprises the following components: the content of folium Camelliae sinensis, residue of folium Camelliae sinensis, branch powder, crushed material of leftover (particle size below 40 mesh) or astaxanthin-containing Haematococcus pluvialis powder is 0.1-0.5% of the total mass.
5. A chlorine dioxide fast dissolving product for spray in a selective strong oxidation chamber according to claim 2, characterized in that: the blended oil is also added with a proper amount of perfume or essence or essential oil according to the preference of a user, so that the taste of the light disinfectant in the chlorine dioxide spray is covered, and the fragrance liked by the user is given off.
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