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CN111102587A - Ultra-clean exhaust gas treatment system and treatment method - Google Patents

Ultra-clean exhaust gas treatment system and treatment method Download PDF

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Publication number
CN111102587A
CN111102587A CN201911282493.1A CN201911282493A CN111102587A CN 111102587 A CN111102587 A CN 111102587A CN 201911282493 A CN201911282493 A CN 201911282493A CN 111102587 A CN111102587 A CN 111102587A
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CN
China
Prior art keywords
torch
water
gas
tank
clean
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Pending
Application number
CN201911282493.1A
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Chinese (zh)
Inventor
郭宏新
何松
赵志红
刘丰
王建果
陈飞
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Jiangsu Sunpower Technology Co Ltd
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Jiangsu Sunpower Technology Co Ltd
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Publication date
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Priority to CN201911282493.1A priority Critical patent/CN111102587A/en
Publication of CN111102587A publication Critical patent/CN111102587A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/07Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • F23G5/46Recuperation of heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/061Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
    • F23G7/063Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating electric heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00Combustion
    • F23G2202/60Combustion in a catalytic combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2204/00Supplementary heating arrangements
    • F23G2204/20Supplementary heating arrangements using electric energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chimneys And Flues (AREA)

Abstract

The invention discloses an ultra-clean discharged waste gas treatment system and a treatment method, wherein the system comprises a combustible gas recovery pipeline and a non-combustible gas recovery pipeline, wherein a combustible gas collection system is connected with a liquid separation tank, the liquid separation tank is respectively connected with a gas recovery system and a water-sealed tank, and the water-sealed tank is connected with a conventional torch system; the non-combustible gas recovery pipeline is connected with a flameless torch feed inlet, and the flameless torch feed inlet is also connected with a torch gas condensate discharge port of the liquid separation tank and a wastewater outlet of the water seal tank; and a purified water outlet of the flameless torch is connected with a clean water inlet of the water-sealed tank. The invention is combined with the traditional torch system, the waste gas is treated according to the quality, the flameless ultra-clean discharge and the resource recycling are realized, and the environmental pollution is reduced to the maximum extent.

Description

Ultra-clean exhaust gas treatment system and treatment method
Technical Field
The invention belongs to the technical field of waste gas treatment, and particularly relates to an ultra-clean discharged waste gas treatment system and an ultra-clean discharged waste gas treatment method.
Background
Traditional flare systems fall into two broad categories, elevated flare and ground flare. The diffusion influence range of the ground torch is small, the influence on the unorganized emission of a factory boundary is obvious, and the indirect supervision on the ground torch can be realized by means of the supervision on the unorganized emission of the factory boundary; the overhead torch has large heat radiation range, serious noise pollution and light pollution, is more suitable for being built in areas with rare population, has undesirable burnout rate when the flow of the torch gas is large, needs a large amount of steam for combustion supporting and has higher cost. In addition, overhead torch is located the hectometer high altitude, and difficult realization real time monitoring can't effectively supervise, and the condition that usually not natural gas directly discharges the torch takes place.
Among the prior art, waste water that waste gas recovery system and torch system produced at the operation in-process, like the waste water in torch gas condensate and the water seal jar in the branch fluid reservoir, often directly discharge into the trench and get into the sewer line, do not carry out recycle, caused the waste of water resource, increased the sewage treatment expense simultaneously, and easily caused environmental pollution.
In addition to the conventional flare system, conventional waste gas treatment technologies such as incinerator, activated carbon adsorption, UV photolysis, adsorption, etc. have certain limitations in the aspects of waste gas treatment capacity, organic waste gas concentration, load regulation ratio, etc., and these devices also need to be matched with corresponding post-treatment facilities (such as additional facilities for desulfurization and denitrification, etc.), and sometimes produce secondary pollution. Therefore, the flare system is still the best scheme for treating the waste gas with complex discharge working condition, large load change range and large flow.
With the increasing environmental requirements, the regulations and policies for exhaust emission will become more stringent.
The 'Nanjing city elevated torch environment management method' released in the Nanjing city in 2019 clearly suggests that the elevated torch should be used for emergency disposal, and cannot be used as a daily atmospheric pollution treatment measure, and the waste gas treated by the elevated torch is only the combustible gas which cannot be effectively recovered in emergency states such as process unit startup and shutdown, fire accidents and other accidents. Waste gases with too high a proportion of nitrogen, etc. must not be discharged into the flare system.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides an ultra-clean exhaust gas treatment system and an ultra-clean exhaust gas treatment method. The invention combines the flameless torch with the traditional torch system, carries out the treatment of waste gas according to the quality, realizes the flameless ultra-clean discharge and the resource recycling, and reduces the environmental pollution to the maximum extent.
The technical scheme adopted by the invention for solving the technical problems is as follows:
an ultra-clean discharged waste gas treatment system comprises a combustible gas recovery pipeline and a non-combustible gas recovery pipeline, wherein the combustible gas recovery pipeline is connected with a liquid separation tank, the liquid separation tank is respectively connected with a gas recovery system and a water-sealed tank, and the water-sealed tank is connected with a conventional torch system; the non-combustible gas recovery pipeline is connected with a flameless torch feed inlet, and the flameless torch feed inlet is also connected with a torch gas condensate discharge port of the liquid separation tank and a wastewater outlet of the water seal tank; and a purified water outlet of the flameless torch is connected with a clean water inlet of the water-sealed tank.
As a preferred technical scheme of the application, the flameless torch is followed by a waste heat recovery device.
Preferably, the waste heat recovery device is a finned tube, a heat pipe with intermediate circulation or a corrosion-resistant flexible metal coating tube.
As a preferred technical scheme of the application, a preheater is further connected in front of the flameless torch according to needs.
More preferably, an electric heating device is arranged between the flameless torch and the preheater.
The treatment method of the ultra-clean emission waste gas treatment system comprises the following steps:
organic gas with recoverable value in the combustible gas discharged from the chemical device enters a gas recovery system through a liquid separation tank and serves as fuel gas in the production process; when the process device is started and stopped, a fire accident or other emergency situations occur, and the combustible gas which cannot be effectively recovered enters the liquid separating tank and the water sealing tank in sequence, is treated by using a conventional torch system, and is decomposed into exhaust gas after high-temperature combustion and discharged;
for the non-combustible gas discharged from a chemical plant device, such as device purge gas, tank area tail gas containing air, tank truck loading and barreling station tail gas and the like, the proportion of the waste gas nitrogen and the like is too high, and the waste gas nitrogen and the like enter a flameless torch for treatment; in other cases, the non-combustible gas, such as non-tissue exhaust gas, leakage gas in the process of storing and conveying organic materials and the like, is collected by a non-combustible gas recovery pipeline and then enters a flameless torch for treatment;
all waste liquid generated in the waste gas treatment process, such as flare gas condensate discharged by a liquid separating tank, water seal waste water discharged by a water seal tank and the like, enters a flameless flare for treatment, and finally clean liquid water is separated out and enters the water seal tank for recycling.
The organic gas with recyclable value needs to be combined with customer requirements, and the working condition and the gas source form comprehensive definition; if the working condition is stable, the concentration of the organic matters is high, and the organic matters can be recycled by a client, the gas with the recycling value can be considered to enter a gas recycling system through a liquid separating tank; if the accident working condition is valuable but not too late to be recovered, the organic matter concentration in the gas source is too low, the components are too complex, the impurities are too many, and if the client feels that the recovered components cannot be effectively utilized, the components pass through the liquid separating tank and the water sealing tank, then the components are treated by using a conventional torch system, and the components are decomposed into exhaust gas after high-temperature combustion and then the exhaust gas is discharged.
The flameless torch preferably adopts a low-temperature catalytic oxidation mode to crack and oxidize organic matters in the waste gas and waste water, the catalytic oxidation reaction is carried out at the temperature of 300-600 ℃, the reaction temperature is low, no NOx is discharged in the whole process, the organic matters are thoroughly converted into harmless carbon dioxide, water, nitrogen and the like, and ultra-clean discharge is realized; the system saves a high-cost off-sale system, reduces the investment cost of chemical enterprises, can recycle the heat of the generated exhaust gas by a waste heat recovery device, and can lead the generated steam to be merged into a steam pipe network of a whole plant for utilization.
The flameless torch has no flame leakage and radiation radius, the exhaust gas does not contain NOx and organic matters, the whole system can realize waste heat recovery and water resource recycling, the catalyst can also be recycled, and flameless ultra-clean emission is realized. The technology optimizes the traditional torch system to the maximum extent, solves the problem of direct discharge of the prior non-combustible gas, performs resource utilization on the wastewater of the torch system, and realizes benefit type environmental protection.
The exhaust gas discharged from the chemical plant apparatus is classified into combustible gas and noncombustible gas according to the discharge characteristics. (wherein the definition of the incombustible exhaust gas refers to the design Specification for combustible gas discharge System for petrochemical industry (SH3009-2013), which is a gas having a low calorific value and requiring calorific value adjustment.)
Drawings
FIG. 1 is a schematic diagram of an ultra-clean emission exhaust treatment system according to the present invention;
wherein 1-chemical plant; 11-a combustible gas recovery line; 121-purge gas recovery line; 122-a tank farm tail gas recovery pipeline containing air; 123-a tail gas recovery pipeline of the barreling station; 124-an unorganized waste gas recovery pipeline; 2-liquid separation tank; 3-a gas recovery system; 4-water sealing the tank; 5-traditional torch; 6-flameless torch; 7-waste heat recovery device.
Detailed Description
In order that the present invention may be more clearly understood, the following detailed description is given in conjunction with the examples. The present invention will now be described in further detail with reference to the accompanying drawings. These drawings are simplified schematic views illustrating only the basic structure of the present invention in a schematic manner, and thus show only the constitution related to the present invention.
Example 1:
fig. 1 shows an embodiment of the present invention, wherein fig. 1 is a schematic structural diagram of the present invention. Referring to fig. 1, an ultra-clean exhaust gas treatment system comprises a combustible gas recovery pipeline 11 and a non-combustible gas recovery pipeline, wherein the non-combustible gas recovery pipeline mainly comprises a device purge gas recovery pipeline 121, an air-containing tank region tail gas recovery pipeline 122, a barreling station tail gas recovery pipeline 123 and an unorganized waste gas recovery pipeline 124; the combustible gas recovery pipeline 11 is connected with a liquid separation tank 2, the liquid separation tank 2 is respectively connected with a gas recovery system 3 and a water-sealed tank 4, and the water-sealed tank 4 is connected with a traditional torch 5; the non-combustible gas recovery pipeline 12 is connected with a feed inlet of a flameless torch 6, and the feed inlet of the flameless torch 6 is also respectively connected with a torch gas condensate discharge port of the liquid separation tank 2 and a wastewater outlet of the water seal tank 4; the purified water outlet of the flameless torch 6 is connected with the clean water inlet of the water seal tank 4; the flameless torch 6 is connected with a waste heat recovery device 7.
According to the requirement, the waste heat recovery device 7 can be a finned tube, a heat pipe with intermediate circulation or a corrosion-resistant flexible metal coating tube.
The treatment method of the ultra-clean emission waste gas treatment system comprises the following steps:
organic gas with recoverable value in the combustible gas discharged from the chemical device 1 can enter a gas recovery system 3 through a liquid separation tank 2 and serve as fuel gas in the production process; when the process device is started and stopped, fire accidents or other emergency situations occur, the combustible gas which cannot be effectively recovered enters the liquid separating tank 2 and the water sealing tank 4 in sequence, then the combustible gas is treated by the conventional torch 5 system, and the combustible gas is decomposed into exhaust gas after high-temperature combustion and is discharged.
For the non-combustible gas discharged from the chemical device 1, such as device purge gas, tank area tail gas containing air, tank truck loading and barreling station tail gas and the like, the proportion of the waste gas nitrogen and the like is too high, and the waste gas nitrogen and the like directly enters a flameless torch 6 through a recovery pipeline for treatment; in other cases, the non-combustible gas, such as the unorganized exhaust gas, the leakage gas during the storage and transportation of the organic materials, etc., is collected by the unorganized exhaust gas recovery pipeline 124 and then enters the flameless torch for treatment.
All waste liquid generated in the waste gas treatment process, such as flare gas condensate discharged from the liquid separating tank 2, water seal waste water discharged from the water seal tank 4 and the like, enters the flameless flare 6 for treatment, and finally, clean liquid water is separated out and enters the water seal tank 4 for recycling.
The flameless torch 6 preferably adopts a low-temperature catalytic oxidation mode to crack and oxidize organic matters in the waste gas and waste water, the catalytic oxidation reaction is carried out at the temperature of 300-600 ℃, the reaction temperature is low, no NOx is discharged in the whole process, the organic matters are thoroughly converted into harmless carbon dioxide, water, nitrogen and the like, and ultra-clean discharge is realized; the system saves a high-cost off-sale system, reduces the investment cost of chemical enterprises, can recycle the heat of the generated exhaust gas by a waste heat recovery device, and can lead the generated steam to be merged into a steam pipe network of a whole plant for utilization.
The flameless torch has no flame leakage and radiation radius, the exhaust gas does not contain NOx and organic matters, the whole system can realize waste heat recovery and water resource recycling, the catalyst can also be recycled, and flameless ultra-clean emission is realized. The technology optimizes the traditional torch system to the maximum extent, solves the problem of direct discharge of the prior non-combustible gas, performs resource utilization on the wastewater of the torch system, and realizes benefit type environmental protection.
It will be understood by those skilled in the art that, unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the prior art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
The meaning of "and/or" as used herein is intended to include both the individual components or both.
The term "connected" as used herein may mean either a direct connection between components or an indirect connection between components via other components.
The protection of the present invention is not limited to the above embodiments. Variations and advantages that may occur to those skilled in the art may be incorporated into the invention without departing from the spirit and scope of the inventive concept and the scope of the appended claims is intended to be protected.

Claims (6)

1. An ultra-clean discharged waste gas treatment system comprises a combustible gas recovery pipeline and a non-combustible gas recovery pipeline, and is characterized in that the combustible gas recovery pipeline is connected with a liquid separation tank, the liquid separation tank is respectively connected with a gas recovery system and a water-sealed tank, and the water-sealed tank is connected with a conventional torch system; the non-combustible gas recovery pipeline is connected with a flameless torch feed inlet, and the flameless torch feed inlet is also connected with a torch gas condensate discharge port of the liquid separation tank and a wastewater outlet of the water seal tank; and a purified water outlet of the flameless torch is connected with a clean water inlet of the water-sealed tank.
2. The ultra-clean emission exhaust gas treatment system of claim 1, wherein the flameless torch is followed by a waste heat recovery device.
3. The ultra-clean emission exhaust gas treatment system of claim 1, wherein the waste heat recovery device is a finned tube, a tube with intermediate flow heat, or a corrosion-resistant flexible metal coated tube waste heat recovery device.
4. The ultra-clean emission exhaust gas treatment system of claim 1, wherein a preheater is also connected before the flameless torch.
5. The method for treating the ultra-clean exhaust gas treatment system of claim 1, wherein the organic gas with recyclable value in the combustible gas discharged from the chemical plant device enters the gas recovery system through the liquid separation tank to be used as fuel gas in the production process; combustible gas which cannot be effectively recovered enters a liquid separating tank and a water seal tank in sequence, is treated by a conventional torch system, and is decomposed into exhaust gas after high-temperature combustion and discharged; collecting the non-combustible gas discharged from the chemical device by using a non-combustible gas recovery pipeline, and then introducing the collected gas into a flameless torch for treatment;
and (3) feeding the torch gas condensate discharged from the liquid separation tank and the water seal wastewater discharged from the water seal tank into a flameless torch for treatment, finally separating out clean liquid water, and then feeding the clean liquid water into the water seal tank for recycling.
6. The treatment method of the ultra-clean emission waste gas treatment system according to claim 5, wherein the flameless torch cracks and oxidizes organic matters in the waste gas and waste water by adopting a low-temperature catalytic oxidation mode, the catalytic oxidation reaction is carried out at a temperature of 300-600 ℃, the reaction temperature is low, no NOx is discharged in the whole process, and the organic matters are completely converted into harmless carbon dioxide, water and nitrogen, so that ultra-clean emission is realized.
CN201911282493.1A 2019-12-13 2019-12-13 Ultra-clean exhaust gas treatment system and treatment method Pending CN111102587A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911282493.1A CN111102587A (en) 2019-12-13 2019-12-13 Ultra-clean exhaust gas treatment system and treatment method

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Application Number Priority Date Filing Date Title
CN201911282493.1A CN111102587A (en) 2019-12-13 2019-12-13 Ultra-clean exhaust gas treatment system and treatment method

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1699827A (en) * 2004-11-19 2005-11-23 中国科学院山西煤炭化学研究所 Method and incinerator for treating dinitrogen tetroxide waste liquid and/or unsymmetrical dimethylhydrazine waste liquid
CN201093512Y (en) * 2007-04-04 2008-07-30 中国石油化工股份有限公司 Mobile waste gas treater
CN104645798A (en) * 2015-03-22 2015-05-27 富阳鸿祥技术服务有限公司 Method for treating organic waste gas in chemical plant
CN104964291A (en) * 2015-07-02 2015-10-07 北京航天动力研究所 Direct recovery method and device applicable to industrial high-flow large-regulation-ratio flare gas
CN209431427U (en) * 2018-12-24 2019-09-24 东营联合石化有限责任公司 A kind of novel Venting and Flare Stack System
CN209522632U (en) * 2018-11-30 2019-10-22 苏州新能环境技术股份有限公司 A kind of low-temperature catalytic oxidation equipment for treatment of Organic Wastewater
CN211976905U (en) * 2019-12-13 2020-11-20 江苏中圣高科技产业有限公司 Ultra-clean exhaust gas treatment system

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1699827A (en) * 2004-11-19 2005-11-23 中国科学院山西煤炭化学研究所 Method and incinerator for treating dinitrogen tetroxide waste liquid and/or unsymmetrical dimethylhydrazine waste liquid
CN201093512Y (en) * 2007-04-04 2008-07-30 中国石油化工股份有限公司 Mobile waste gas treater
CN104645798A (en) * 2015-03-22 2015-05-27 富阳鸿祥技术服务有限公司 Method for treating organic waste gas in chemical plant
CN104964291A (en) * 2015-07-02 2015-10-07 北京航天动力研究所 Direct recovery method and device applicable to industrial high-flow large-regulation-ratio flare gas
CN209522632U (en) * 2018-11-30 2019-10-22 苏州新能环境技术股份有限公司 A kind of low-temperature catalytic oxidation equipment for treatment of Organic Wastewater
CN209431427U (en) * 2018-12-24 2019-09-24 东营联合石化有限责任公司 A kind of novel Venting and Flare Stack System
CN211976905U (en) * 2019-12-13 2020-11-20 江苏中圣高科技产业有限公司 Ultra-clean exhaust gas treatment system

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