CN111041277A - A kind of rare earth nano-hydrogen storage alloy for catalyzing hydrogen absorption and desorption of organic hydrogen storage liquid and preparation method thereof - Google Patents
A kind of rare earth nano-hydrogen storage alloy for catalyzing hydrogen absorption and desorption of organic hydrogen storage liquid and preparation method thereof Download PDFInfo
- Publication number
- CN111041277A CN111041277A CN202010024183.6A CN202010024183A CN111041277A CN 111041277 A CN111041277 A CN 111041277A CN 202010024183 A CN202010024183 A CN 202010024183A CN 111041277 A CN111041277 A CN 111041277A
- Authority
- CN
- China
- Prior art keywords
- hydrogen storage
- hydrogen
- rare earth
- earth nano
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/20—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2202/00—Physical properties
- C22C2202/04—Hydrogen absorbing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Fuel Cell (AREA)
Abstract
The invention belongs to the technical field of hydrogen storage, and particularly relates to a rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen and a preparation method thereof. The rare earth nano hydrogen storage alloy is LaNi5Alloy of the LaNi5The alloy is prepared by the following steps: 1) adding LaCl3∙7H2O and NiCl2∙6H2Adding concentrated alkali solution to react to obtain mixed hydroxide precursor after the mixed solution is obtained according to the proportion of O; 2) mixing the mixed hydroxide precursor with KCl and CaH2Mixing, and performing high-temperature reduction reaction to obtain LaNi5And (3) alloying. The rare earth nano hydrogen storage alloy simultaneously solvesTwo problems are: on one hand, the problems that the cost of the high-efficiency hydrogen absorption and desorption catalyst using the organic hydrogen storage liquid is higher and different noble metals are needed to be used in the prior art are solved; on the other hand, the problem of preparing nano LaNi in the prior art is solved5The process is complicated, and the obtained catalyst has poor stability.
Description
Technical Field
The invention belongs to the technical field of hydrogen storage, and particularly relates to a rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen and a preparation method thereof.
Background
The hydrogen energy has a series of advantages of cleanness, no pollution, high calorific value and the like, and is considered by many people as the best option for changing the current structure taking fossil energy as main energy and realizing the sustainable development of the human society. There are three major bottlenecks to the utilization of hydrogen energy: large scale production of hydrogen, storage of hydrogen and efficiency of fuel cells. Particularly in the hydrogen storage field, the commercially successful technologies at present are high-pressure hydrogen storage and low-temperature liquefied hydrogen, which have high requirements on the safety of storage equipment, and usually require high pressure (700-.
Organic hydrogen storage liquid represented by N-ethyl carbazole is one of the most possible solutions to the problem of hydrogen storage, and the safety and liquid characteristics of the organic hydrogen storage liquid are particularly suitable for large-scale storage and hydrogen transportation. However, the hydrogen absorption and desorption kinetics are poor, the hydrogen absorption and desorption catalysts which are commonly used at present are all noble metals, and the noble metals used in the two processes are different, so that the use cost is too high, and the catalyst is difficult to put into practical application. N-ethylcarbazole is exemplified, and the best catalyst for the hydrogen absorption process is Ru/Al2O3The best catalyst for the hydrogen discharge process is Pd/SiO2The two metals Ru and Pd form an alloy which can simultaneously catalyze the hydrogen absorption and desorption reaction.
LaNi5As the hydrogen absorbing alloy which was first discovered, there has been a history of several decades of research. Besides the traditional electric arc melting method, China invented a plurality of soft chemical synthesis methods in the eighties of the last century: such as oxalic acid precipitation, citric acid complex reduction, combustion propagation-CaH2A synthetic method of reduction.LaNi synthesized by soft chemistry method5The catalyst has small particle size (usually several microns or hundreds of nanometers), improved hydrogen storage performance and better catalytic activity in hydrogenation reaction. However, these methods generally use reduction temperatures greater than 900 ℃, are complicated in precursor preparation, and are used for catalytic hydrogenation of LaNi5The alloy is compatible and easy to decompose.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen and a preparation method thereof. The invention is based on hydrogen storage alloy LaNi5The characteristic of rapid reversible hydrogen absorption and desorption develops a non-noble metal catalyst with the capability of catalyzing the hydrogen absorption and desorption of the N-ethyl carbazole, obviously reduces the cost of the catalyst, realizes the assumption that the hydrogen storage alloy is applied to the reaction related to the hydrogen, and has important significance for the practicability of organic hydrogen storage liquid.
In order to solve the problems existing in the prior art, the specific technical scheme is as follows:
a rare-earth nano hydrogen-storing alloy for catalyzing organic hydrogen-storing liquid to absorb and release hydrogen is LaNi5Alloy of the LaNi5The alloy is prepared by the following steps: 1) adding LaCl3∙7H2O and NiCl2∙6H2Mixing O in proportion to obtain a mixed solution, and adding a concentrated alkali solution to react to obtain a mixed hydroxide precursor; 2) mixing the mixed hydroxide precursor with KCl and CaH2Mixing, and performing high-temperature reduction reaction to obtain LaNi5And (3) alloying.
Preferably, in step 1), the LaCl is3∙7H2O and NiCl2∙6H2The molar ratio of O is 1:5 to 5.5.
More preferably, in step 1), the LaCl is added3∙7H2O and NiCl2∙6H2Dissolving O in deionized water under stirring to obtain a mixed solution, wherein each millimole of LaCl3∙7H2O is dissolved in deionized water per 10 ml.
More preferably, in step 1), the concentrated alkali solution is a NaOH solution with a concentration of 4 mol/L, and the volume ratio of the concentrated alkali solution to the deionized water is 1: 1.
more preferably, in step 2), the mixed hydroxide precursor is mixed with KCl and CaH2The mass ratio of (1): 4: 1.5.
a preparation method of rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen comprises the following steps:
1) adding LaCl3∙7H2O and NiCl2∙6H2O is prepared by mixing the following components in a molar ratio of 1: 5-5.5, mixing, stirring and dissolving in deionized water;
2) adding a concentrated NaOH solution under vigorous stirring, reacting to obtain a mixed hydroxide precursor, and performing centrifugal separation;
3) washing the obtained separated substance with deionized water, drying in an oven, grinding the mixed hydroxide precursor under the protective gas Ar atmosphere, and mixing the ground mixed hydroxide precursor powder with KCl and CaH2Mixing uniformly to obtain mixed powder;
4) transferring the obtained mixed powder into a crucible, and carrying out high-temperature reduction reaction in a tubular furnace in protective gas Ar atmosphere to obtain a mixture;
5) washing the obtained mixture with diluted acetic acid under the condition of protective gas Ar atmosphere to remove CaO generated by reduction reaction and unreacted CaH2And KCl solid, and performing centrifugal separation;
6) and (3) respectively washing the precipitate obtained by centrifugal separation in the step 5) with water and ethanol, and finally drying in a vacuum oven for later use to obtain the rare earth nano hydrogen storage alloy for catalyzing the organic hydrogen storage liquid to absorb and release hydrogen.
Preferably, the volume ratio of the deionized water in the step 1) to the concentrated NaOH solution in the step 2) is 1: 1, the concentration of the concentrated NaOH solution is 4 mol/L, and the mixed hydroxide precursor powder is mixed with KCl and CaH2The mass ratio of (1): 4: 1.5.
more preferably, the high-temperature reduction reaction in the step 4) is carried out at the reaction temperature of 700 ℃ for 2 h.
The rare earth nano hydrogen storage alloy is used as a catalyst to be applied to hydrogen absorption and hydrogen desorption reactions of organic hydrogen storage liquid.
Preferably, the organic hydrogen storage liquid is N-ethylcarbazole.
Compared with the prior art, the invention has the following advantages:
1) the rare earth nano hydrogen storage alloy simultaneously solves two problems: on one hand, the problems that the cost of the high-efficiency hydrogen absorption and desorption catalyst using the organic hydrogen storage liquid is higher and different noble metals are needed to be used in the prior art are solved; on the other hand, the problem of preparing nano LaNi in the prior art is solved5The process is complicated, and the obtained catalyst has poor stability.
2) Nano LaNi with best hydrogen absorption and desorption effects by catalyzing N-ethyl carbazole5(La: Ni =1: 5.5) as an example, in nanometer LaNi5Under the catalysis of (2), the hydrogen absorption reaction of N-ethyl carbazole can be carried out at 180 ℃ and 7 MPa H2Under the condition of (1), the reaction is completely carried out for 8H, and the corresponding hydrogen release reaction can be carried out at 200 ℃ and 0.1 MPa H2The hydrogen release rate after 5 hours is more than 5.5 wt% (the hydrogen yield is 95%), the reaction rate and the selectivity are not obviously reduced after three hydrogen absorption and release cycles, the hydrogen absorption performance is slightly inferior to that of a Ru-based catalyst, but the hydrogen release performance can be comparable to that of a Pd-based catalyst. After three cycles, the catalyst is partially decomposed, but most of the catalyst still can maintain LaNi5The alloy phase of (3). According to measurement and calculation, when the hydrogen absorption and desorption speed of the N-ethyl carbazole is ensured to be 1 Kg/h, the cost of the Ru-based catalyst for hydrogen absorption is 2.4 ten thousand yuan; the cost of Pd-based catalyst used for hydrogen release is 40 ten thousand yuan, while the cost of hydrogen absorption catalyst is reduced to 0.68 ten thousand yuan and the cost of hydrogen release catalyst is reduced to 0.30 ten thousand yuan by using nano LaNi5 catalyst. This will strongly drive the practical application of organic hydrogen storage liquids in large scale hydrogen storage.
Drawings
FIG. 1 shows a nanometer LaNi prepared in example 1 of the present invention5Before and after three cycles of (a)The X-ray diffraction spectrum (b) is an X-ray photoelectron spectrum before and after three cycles.
FIG. 2 shows a nano-LaNi prepared in example 1 of the present invention5SEM electron micrograph of (1).
FIG. 3 shows nanometer LaNi prepared in example 1 of the present invention5A graph of catalyzing the hydrogen absorption and desorption process of N-ethyl carbazole.
FIG. 4 is a schematic diagram of an apparatus for testing hydrogen absorption/desorption kinetics curves of organic hydrogen storage liquid according to the present invention.
FIG. 5 is a schematic diagram of a hydrogen absorption and desorption kinetics curve of the test organic hydrogen storage liquid of the present invention.
Description of the drawings: the hydrogen absorption and desorption cycle tests of the N-ethyl carbazole are all carried out in a high-pressure reaction kettle as shown in figures 4-5. The hydrogen absorption amount is converted by the pressure drop in the autoclave, the hydrogen discharge amount is directly calculated by a connected gas flowmeter, and the final hydrogen absorption and discharge result is further corrected by using the nuclear magnetic resonance hydrogen spectrum of the liquid product. H generated in the presentation apparatus of FIG. 42Can be directly supplied to a fuel cell for use, and lights a 5 w LED lamp.
Detailed Description
The present invention will be described in further detail with reference to the following embodiments.
A rare earth nano hydrogen storage alloy catalyst for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen is prepared by the following steps: 1mmol of LaCl was added to a beaker3∙7H2O and NiCl in different molar ratios2∙6H2O (La: Ni =1:5, La: Ni =1: 5.5), dissolved in deionized water with stirring, and concentrated NaOH solution was added under vigorous stirring to obtain a mixed hydroxide precursor, and subjected to centrifugal separation, and the obtained centrifuge was washed with deionized water and dried in an oven overnight. Grinding the mixed hydroxide in a glove box filled with protective gas Ar, mixing the ground mixed hydroxide powder with KCl and CaH2Uniformly mixing, transferring into a crucible, carrying out high-temperature reaction in a tubular furnace in the atmosphere of protective gas Ar in the reduction process, washing the obtained mixture with dilute acetic acid under the condition of protective gas Ar to remove CaO generated by the reduction reaction and unreacted CaH2And KCl solid, and precipitatingCentrifuging, washing twice with water and ethanol respectively, and drying in a vacuum oven for later use. The catalyst is characterized by XRD, XPS, SEM and the like.
Performance testing of the catalyst: the hydrogen absorption and desorption performance of the sample is carried out in a hydrogen absorption and desorption testing system which is mainly assembled by a micro high-pressure reaction kettle. Hydrogen absorption test: putting an organic substrate (N-ethyl carbazole without hydrogenation) and a catalyst into a reaction kettle body in a glove box, sealing the reaction kettle, vacuumizing, and detecting leakage. And heating the reaction kettle to a set temperature, then quickly filling hydrogen with specified pressure, sealing the reaction kettle, and recording the pressure change by using a pressure sensor to obtain a hydrogen absorption curve. And (3) hydrogen discharge test: the hydrogen discharge test is directly carried out by using the mixture after hydrogen absorption, and after the reaction kettle is vacuumized and subjected to leak detection, H with the pressure of more than 1 MPa is filled2And the reaction kettle and a mass flow meter (D07, Beijing seven-star Hua Chuang electronic Co., Ltd., measuring range 50 mL/min, with a one-way valve inside) are communicated after the reaction kettle is closed, hydrogen is released to 1 bar pressure, then heating is started, and the flow of the flow meter is recorded, so that a hydrogen release curve is obtained. Neither solvent nor stirring was used for the hydrogen absorption and desorption tests. After the reaction, the reaction kettle is opened, and the supernatant is taken for H-NMR characterization.
Example 1
0.371 g of LaCl was added to the beaker3∙7H2O and 1.307 g NiCl2∙6H2O, stirring and dissolving in 10mL of deionized water, and dropwise adding 10mL of 4 mol/L concentrated NaOH solution under vigorous stirring to obtain a mixed hydroxide precursor; centrifuging, washing the obtained isolate with deionized water for three times, and drying in an oven at 80 deg.C overnight; the dried mixed hydroxide precursor was mixed with 4 g KCl and 1.5 g CaH in a glove box2Grinding and mixing to obtain mixed powder, transferring into a crucible, reducing at 700 deg.C for 2h in a tube furnace under protective gas Ar atmosphere to obtain a hardened solid mixture, washing with 0.1mol/L diluted acetic acid under protective gas Ar for three times, dissolving CaO produced by reaction, and unreacted CaH2And KCl solid, performing centrifugal separation, washing the separated precipitate with water and ethanol respectively, and drying in a vacuum oven for useRare earth nano hydrogen storage alloy LaNi for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen5A catalyst.
FIG. 1 shows a nanometer LaNi film prepared according to the present invention5An X-ray diffraction spectrum before and after three cycles of (a) and an X-ray photoelectron energy spectrum before and after three cycles of (b). As shown by the X-ray diffraction pattern in FIG. 1 (a), the alloy prepared by the method is pure LaNi5The phase and the crystallinity are better; after catalyzing N-ethyl carbazole to absorb and release hydrogen for three cycles, the spectral line is widened, the proportion of simple substance Ni is improved, but the main phase of the catalyst is still LaNi5. The X-ray photoelectron spectrum of FIG. 1 (b) shows that the alloy surface before reaction is mainly La2O3And NiO, which represents an oxide film formed on the surface of the alloy during the test and the sample transfer; after three catalytic reactions, simple substances Ni and LaH appear3The characteristic peak of (A) indicates that the surface of the alloy has phase separation phenomenon after catalytic reaction.
FIG. 2 shows a nanometer LaNi film prepared according to the present invention5SEM electron micrograph of (1). SEM electron micrograph shows LaNi synthesized by the method5Is particles with the diameter of tens to hundreds of nanometers, and has obvious difference with the bulk particles with the diameter of tens of micrometers obtained by grinding by a smelting method.
The obtained catalyst is subjected to evaluation of the hydrogen absorption and desorption performance of catalyzing N-ethyl carbazole, referring to fig. 3, for the hydrogen absorption reaction, the reaction can be completed in 8 h at 180 ℃ under 7 MPa, and the hydrogen absorption amount in 8 h reaches 5.7 wt%; corresponding hydrogen evolution reaction is carried out at 200 ℃ and 0.1 MPa H2Hydrogen is discharged for 5 hours under the condition of more than 5.5 wt percent (H)2Yield 95%).
Example 2
0.371 g of LaCl was added to the beaker3∙7H2O and 1.188 g NiCl2∙6H2O, stirring and dissolving in 10mL of deionized water, and dropwise adding 10mL of 4 mol/L concentrated NaOH solution under vigorous stirring to obtain a mixed hydroxide precursor; centrifuging, washing the obtained isolate with deionized water for three times, and drying in an oven at 80 deg.C overnight; the dried mixed hydroxide precursor was mixed with 4 g KCl and 1.5 g CaH in a glove box2Grinding and mixing to obtain mixed powder, transferring into a crucible, reducing at 700 deg.C for 2h in a tube furnace under protective gas Ar atmosphere to obtain a hardened solid mixture, washing with 0.1mol/L diluted acetic acid under protective gas Ar for three times, dissolving CaO produced by reaction, and unreacted CaH2And KCl solid, performing centrifugal separation, washing the separated precipitate with water and ethanol respectively, and drying in a vacuum oven for later use to obtain the rare earth nano hydrogen storage alloy LaNi for catalyzing the hydrogen absorption and desorption of the organic hydrogen storage liquid5A catalyst.
The obtained catalyst is evaluated in the performance of catalyzing the hydrogen absorption and desorption of N-ethylcarbazole, and 5.5 wt% of H can be absorbed for 20H under the conditions of 180 ℃ and 7 MPa in the hydrogen absorption reaction2The corresponding hydrogen releasing reaction is carried out at 200 ℃ and 0.1 MPa H2Hydrogen is discharged for 10 hours under the condition of more than 5.5 wt percent (H)2Yield 95%).
FIG. 4 is a schematic diagram of an apparatus for testing hydrogen absorption/desorption kinetics curves of organic hydrogen storage liquid according to the present invention. FIG. 5 is a schematic diagram of a hydrogen absorption and desorption kinetics curve of the test organic hydrogen storage liquid of the present invention. The N-ethylcarbazole hydrogen absorption and desorption cycle tests in examples 1 and 2 were conducted in a high-pressure reaction vessel as shown in fig. 4 to 5. The hydrogen absorption amount is converted by the pressure drop in the autoclave, the hydrogen discharge amount is directly calculated by a connected gas flowmeter, and the final hydrogen absorption and discharge result is further corrected by using the nuclear magnetic resonance hydrogen spectrum of the liquid product. H generated in the presentation apparatus of FIG. 42Can be directly supplied to a fuel cell for use, and lights a 5 w LED lamp.
Comparative example 1
0.371 g of LaCl was added to the beaker3∙7H2O，0.238 g CoCl2∙6H2O and 0.713 g NiCl2∙6H2O, stirring and dissolving in 10mL of deionized water, and dropwise adding 10mL of 4 mol/L concentrated NaOH solution under vigorous stirring to obtain a mixed hydroxide precursor; centrifuging, washing the obtained isolate with deionized water for three times, and drying in an oven at 80 deg.C overnight; the dried precursor was mixed with 4 g KCl and 1.5 g CaH in a glove box2Grinding, mixing, transferring into crucible, and keepingReducing for 2 hours at 700 ℃ in a tube furnace under the protective gas Ar atmosphere; the hardened solid mixture is obtained, and is washed three times by using 0.1M diluted acetic acid under the protection of protective gas Ar, CaO generated by the reaction and unreacted CaH are dissolved2And KCl, performing centrifugal separation, washing the separated precipitate with water and ethanol respectively, and drying in a vacuum oven for later use to obtain the rare earth nano hydrogen storage alloy LaNi for catalyzing the hydrogen absorption and desorption of the organic hydrogen storage liquid5A catalyst.
The obtained catalyst is subjected to evaluation of hydrogen absorption and desorption performance of catalyzing N-ethylcarbazole, and the hydrogen absorption reaction can be completed in 5 hours at 180 ℃ and 7 MPa, and the corresponding hydrogen desorption reaction is carried out at 200 ℃ and 0.1 MPa H2Hydrogen evolution for 13H under the condition is more than 5.0 wt percent (H)2Yield 86%).
Also using the method, a small amount of Co is doped in the precursor, and then the LaNi doped with a small amount of Co can be synthesized5Alloy, X-ray diffraction spectrum still shows LaNi5Characteristic spectral line of (1). The hydrogen absorption performance of the alloy catalyst is superior to that of single LaNi5However, the alloy phase becomes less stable after Co doping, and the catalytic hydrogen release performance is inferior to that of LaNi5 alloy.
Comparative example 2
0.371 g of LaCl was added to the beaker3∙7H2O，1.426 g NiCl2∙6H2O and 4 g KCl are stirred and dissolved in 10mL deionized water, and the water is evaporated at the heating temperature of 200 ℃ to obtain a mixed hydroxide precursor; the dried mixed hydroxide precursor was mixed with 1.5 g CaH in a glove box2Grinding, mixing, transferring into a crucible, and reducing for 2h at 700 ℃ in a tube furnace in protective gas Ar atmosphere; the hardened solid mixture is obtained, and is washed three times by using 0.1M diluted acetic acid under the protection of protective gas Ar, CaO generated by the reaction and unreacted CaH are dissolved2And KCl, performing centrifugal separation, washing the separated precipitate with water and ethanol respectively, and drying in a vacuum oven for later use to obtain the rare earth nano hydrogen storage alloy LaNi for catalyzing the hydrogen absorption and desorption of the organic hydrogen storage liquid5A catalyst.
The obtained catalyst is subjected to evaluation of hydrogen absorption and desorption performance of catalyzing N-ethylcarbazole, and the hydrogen absorption reaction can be completed in 5 hours at 180 ℃ and 7 MPa, and the corresponding hydrogen desorption reaction is carried out at 200 ℃ and 0.1 MPa H2The catalyst can not effectively catalyze and release hydrogen under the condition, and the release hydrogen is only 1.3 wt% in 24 h.
In this comparative example, the molar ratio of the metals in the precursor, La: Ni =1:6, and the X-ray diffraction spectrum shows that there is a phase of a small amount of elemental Ni in the alloy, which is superior to the pure-phase alloy when La: Ni =1:5 and 5.5 in catalytic hydrogen absorption performance, but poor in catalytic hydrogen desorption performance.
Claims (10)
1. A rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen is characterized in that: the rare earth nano hydrogen storage alloy is LaNi5Alloy of the LaNi5The alloy is prepared by the following steps: 1) adding LaCl3∙7H2O and NiCl2∙6H2Mixing O in proportion to obtain a mixed solution, and adding a concentrated alkali solution to react to obtain a mixed hydroxide precursor; 2) mixing the mixed hydroxide precursor with KCl and CaH2Mixing, and performing high-temperature reduction reaction to obtain LaNi5And (3) alloying.
2. The rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen according to claim 1, characterized in that: in step 1), the LaCl3∙7H2O and NiCl2∙6H2The molar ratio of O is 1:5 to 5.5.
3. The rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen according to claim 2, characterized in that: in step 1), LaCl is added3∙7H2O and NiCl2∙6H2Dissolving O in deionized water under stirring to obtain a mixed solution, wherein each mole of LaCl3∙7H2O was dissolved in deionized water per 10 ml.
4. The rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen according to claim 3, characterized in that: in the step 1), the concentrated alkali solution is a NaOH solution with the concentration of 4 mol/L, and the volume ratio of the concentrated alkali solution to the deionized water is 1: 1.
5. the rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen according to claim 1, characterized in that: in step 2), the mixed hydroxide precursor is mixed with KCl and CaH2The mass ratio of (1): 4: 1.5.
6. a method for preparing a rare earth nano hydrogen storage alloy of the type described in claim 1 for catalyzing hydrogen absorption and desorption from an organic hydrogen storage liquid, comprising: the preparation method comprises the following steps:
adding LaCl3∙7H2O and NiCl2∙6H2O is prepared by mixing the following components in a molar ratio of 1: 5-5.5, mixing, stirring and dissolving in deionized water;
adding a concentrated NaOH solution under vigorous stirring for reaction to obtain a mixed hydroxide precursor, and performing centrifugal separation;
washing the obtained separated substance with deionized water, drying in an oven, grinding the mixed hydroxide precursor under the protective gas Ar atmosphere, and mixing the ground mixed hydroxide precursor powder with KCl and CaH2Mixing uniformly to obtain mixed powder;
transferring the obtained mixed powder into a crucible, and carrying out high-temperature reduction reaction in a tubular furnace in protective gas Ar atmosphere to obtain a mixture;
washing the obtained mixture with diluted acetic acid under the condition of protective gas Ar atmosphere to remove CaO and unreacted CaH generated by reduction reaction2And KCl solid, and performing centrifugal separation;
and (3) respectively washing the precipitate obtained by centrifugal separation in the step 5) with water and ethanol, and finally drying in a vacuum oven for later use to obtain the rare earth nano hydrogen storage alloy for catalyzing the organic hydrogen storage liquid to absorb and release hydrogen.
7. The method for preparing the rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen according to claim 6, which is characterized in that: in the step 1), the volume ratio of the deionized water to the concentrated NaOH solution in the step 2) is 1: 1, the concentration of the concentrated NaOH solution is 4 mol/L, and the mixed hydroxide precursor powder is mixed with KCl and CaH2The mass ratio of (1): 4: 1.5.
8. the method for preparing the rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen according to claim 6, which is characterized in that: the high-temperature reduction reaction in the step 4) is carried out, the reaction temperature is 700 ℃, and the reaction time is 2 hours.
9. The use of a rare earth nano hydrogen storage alloy as claimed in claim 1 for catalyzing an organic hydrogen storage liquid to absorb and desorb hydrogen, wherein: the rare earth nano hydrogen storage alloy is used as a catalyst to be applied to hydrogen absorption and hydrogen desorption reactions of organic hydrogen storage liquid.
10. The use of a rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and desorb hydrogen according to claim 9, wherein: the organic hydrogen storage liquid is N-ethyl carbazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010024183.6A CN111041277B (en) | 2020-01-10 | 2020-01-10 | Rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010024183.6A CN111041277B (en) | 2020-01-10 | 2020-01-10 | Rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111041277A true CN111041277A (en) | 2020-04-21 |
| CN111041277B CN111041277B (en) | 2021-09-10 |
Family
ID=70244286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010024183.6A Active CN111041277B (en) | 2020-01-10 | 2020-01-10 | Rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111041277B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113430420A (en) * | 2021-06-25 | 2021-09-24 | 北京大学 | LaNiAl alloy and preparation method and application thereof |
| CN113745547A (en) * | 2021-09-07 | 2021-12-03 | 苏州清德氢能源科技有限公司 | Direct liquid organic hydrogen carrier fuel cell based on hydrogen storage alloy electrode |
| CN117443409A (en) * | 2023-11-07 | 2024-01-26 | 佛山清德氢能源科技有限公司 | A catalyst for catalyzing the absorption and release of hydrogen by a liquid organic hydrogen carrier and its preparation method |
| CN117735478A (en) * | 2023-12-19 | 2024-03-22 | 沈阳工业大学 | Lanthanum hydroxide doped LaNi 5 Preparation method of hydrogen storage material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11246923A (en) * | 1998-03-05 | 1999-09-14 | Mitsui Mining & Smelting Co Ltd | Hydrogen storage alloy and method for producing the same |
| CN1557701A (en) * | 2004-02-05 | 2004-12-29 | 武汉理工大学 | Fullerene hydrogen storage materials modified by hydrogen storage alloys or hydrogen storage metal nanoparticles |
| CN102586651A (en) * | 2012-03-05 | 2012-07-18 | 华中科技大学 | Preparation method of hydrogen storage alloy material |
| CN103352239A (en) * | 2013-07-03 | 2013-10-16 | 哈尔滨工程大学 | A method for directly preparing LaNi5 hydrogen storage alloy by molten salt electrolysis |
-
2020
- 2020-01-10 CN CN202010024183.6A patent/CN111041277B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11246923A (en) * | 1998-03-05 | 1999-09-14 | Mitsui Mining & Smelting Co Ltd | Hydrogen storage alloy and method for producing the same |
| CN1557701A (en) * | 2004-02-05 | 2004-12-29 | 武汉理工大学 | Fullerene hydrogen storage materials modified by hydrogen storage alloys or hydrogen storage metal nanoparticles |
| CN102586651A (en) * | 2012-03-05 | 2012-07-18 | 华中科技大学 | Preparation method of hydrogen storage alloy material |
| CN103352239A (en) * | 2013-07-03 | 2013-10-16 | 哈尔滨工程大学 | A method for directly preparing LaNi5 hydrogen storage alloy by molten salt electrolysis |
Non-Patent Citations (1)
| Title |
|---|
| 杨书廷 等: "新型纳米材料LaNi5相贮氢合金的制备与性能", 《电源技术》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113430420A (en) * | 2021-06-25 | 2021-09-24 | 北京大学 | LaNiAl alloy and preparation method and application thereof |
| CN113430420B (en) * | 2021-06-25 | 2022-05-06 | 北京大学 | LaNiAl alloy and preparation method and application thereof |
| CN113745547A (en) * | 2021-09-07 | 2021-12-03 | 苏州清德氢能源科技有限公司 | Direct liquid organic hydrogen carrier fuel cell based on hydrogen storage alloy electrode |
| CN113745547B (en) * | 2021-09-07 | 2023-08-15 | 苏州清德氢能源科技有限公司 | Direct liquid organic hydrogen carrier fuel cell based on hydrogen storage alloy electrode |
| CN117443409A (en) * | 2023-11-07 | 2024-01-26 | 佛山清德氢能源科技有限公司 | A catalyst for catalyzing the absorption and release of hydrogen by a liquid organic hydrogen carrier and its preparation method |
| CN117443409B (en) * | 2023-11-07 | 2025-08-29 | 佛山清德氢能源科技有限公司 | A catalyst for catalyzing the absorption and release of hydrogen by a liquid organic hydrogen carrier and a preparation method thereof |
| CN117735478A (en) * | 2023-12-19 | 2024-03-22 | 沈阳工业大学 | Lanthanum hydroxide doped LaNi 5 Preparation method of hydrogen storage material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111041277B (en) | 2021-09-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Yu et al. | LaNi5. 5 particles for reversible hydrogen storage in N-ethylcarbazole | |
| CN111041277B (en) | Rare earth nano hydrogen storage alloy for catalyzing organic hydrogen storage liquid to absorb and discharge hydrogen and preparation method thereof | |
| CN109759064B (en) | A kind of Co@C/biomass catalyst and its preparation method and application | |
| CN113522288B (en) | Catalyst for catalyzing the hydrolysis of ammonia borane to produce hydrogen and its preparation method and application | |
| CN110624550B (en) | In-situ carbon-coated copper-nickel alloy nanoparticle photocatalyst and preparation method and application thereof | |
| CN116786151B (en) | Bimetallic nitride catalyst and preparation method and application thereof | |
| CN113441160B (en) | Nickel hydroxide/titanium carbide photo-thermal catalytic material and preparation method and application thereof | |
| CN113101964B (en) | A kind of mesoporous cerium oxide photocatalyst and its preparation method and application | |
| CN112778243B (en) | Method for preparing 2,5-dimethylfuran by catalytic hydrogenation of 5-hydroxymethylfurfural | |
| CN109731579A (en) | A kind of nickel-supported mesoporous lanthanum oxide catalyst and preparation method thereof | |
| CN114804020B (en) | Slurry hydrogen storage material and preparation method thereof | |
| CN106944067B (en) | A kind of preparation method of the catalyst for synthesizing gas by reforming methane with co 2 | |
| CN113546631A (en) | A kind of La-modified Ni/Al2O3 catalyst, preparation method and application | |
| CN116251589A (en) | A kind of Pd/ZnO-ZrO2 catalyst for methanol steam reforming hydrogen production and its preparation method and application | |
| CN104607222B (en) | The preparation method of the carbon-supported lithium carbide of a kind of macropore and the application in hydrogen storage material | |
| CN115957734A (en) | Catalyst and preparation method thereof, hydrogen storage material containing the catalyst and preparation method thereof | |
| CN117427644A (en) | Co for low-temperature CO catalytic oxidation 3 O 4 -CeO 2 Catalyst and preparation method thereof | |
| CN107140601A (en) | A kind of composite hydrogen storage material of nano-sized nickel hydroxide doping and preparation method thereof | |
| CN111013663A (en) | A transition metal-boron-based catalyst for catalyzing hydrogen absorption and desorption of liquid organic hydrogen carrier and preparation method thereof | |
| CN114887661A (en) | Preparation method and application of Ti-based porphyrin material | |
| CN111569894B (en) | A kind of supported Cu-Fe base catalyst and its preparation method and application | |
| CN106629871B (en) | A kind of spherical NiMnO3The synthetic method of bimetallic oxide and its application | |
| CN113522293A (en) | Preparation method and application of a catalyst for hydrogen production by dry reforming of methane and carbon dioxide | |
| CN115159450B (en) | NbB-based 2 Catalytic lifting of MgH 2 Method for hydrogen storage performance | |
| CN118594580A (en) | A Cu2O@CS/rGO composite material and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220721 Address after: 215500 602, building 6, 88 Xianshi Road, Changshu high tech Industrial Development Zone, Suzhou City, Jiangsu Province Patentee after: Suzhou Qingde Hydrogen Energy Technology Co.,Ltd. Address before: 215500 602, building 6, 88 Xianshi Road, Changshu high tech Industrial Development Zone, Suzhou City, Jiangsu Province Patentee before: Suzhou Mingde New Energy Technology Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20250114 Address after: 528200 R&D Workshop 905-1, Building 10, Lihe Technology Industry Center, No. 99 Taoyuan East Road, Shishan Town, Nanhai District, Foshan City, Guangdong Province (Address Application) Patentee after: Foshan Qingde Hydrogen Energy Technology Co.,Ltd. Country or region after: China Address before: 215500 602, building 6, 88 Xianshi Road, Changshu high tech Industrial Development Zone, Suzhou City, Jiangsu Province Patentee before: Suzhou Qingde Hydrogen Energy Technology Co.,Ltd. Country or region before: China |
|
| TR01 | Transfer of patent right |