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CN110923048A - Petroleum lubricating oil - Google Patents

Petroleum lubricating oil Download PDF

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Publication number
CN110923048A
CN110923048A CN201911252080.9A CN201911252080A CN110923048A CN 110923048 A CN110923048 A CN 110923048A CN 201911252080 A CN201911252080 A CN 201911252080A CN 110923048 A CN110923048 A CN 110923048A
Authority
CN
China
Prior art keywords
parts
lubricating oil
oil
stirring
raw materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911252080.9A
Other languages
Chinese (zh)
Inventor
刘强喜
刘钢锤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Ruista Petroleum Co Ltd
Original Assignee
Anhui Ruista Petroleum Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Ruista Petroleum Co Ltd filed Critical Anhui Ruista Petroleum Co Ltd
Priority to CN201911252080.9A priority Critical patent/CN110923048A/en
Publication of CN110923048A publication Critical patent/CN110923048A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12Polysaccharides, e.g. cellulose, biopolymers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses petroleum lubricating oil which is prepared from the following raw materials in parts by weight: 120 parts of neutral base oil 110-5 parts, 30-45 parts of coconut oil, 35-46 parts of sucrose polyester, 3-5 parts of mixed fatty glyceride, 2-4 parts of sorbitol, 5-8 parts of viscosity index improver, 6-15 parts of silane coupling agent kh550, 1-3 parts of tricresyl phosphate, 3-5 parts of modified thickening defoaming agent and 4-6 parts of preservative. The petroleum lubricating oil obtained by the invention has good low-temperature fluidity, good abrasion resistance and long service life, and can adjust the technological parameter performance of the lubricating oil while quickly finishing defoaming work through the compounded thickening defoaming agent, so that the petroleum lubricating oil can meet the requirements of various occasions.

Description

Petroleum lubricating oil
Technical Field
The invention relates to the field of lubricating oil, in particular to petroleum lubricating oil.
Background
The lubricating oil is liquid or semisolid lubricating oil which is used on various types of automobiles and mechanical equipment to reduce friction and protect machines and workpieces, and mainly plays roles in lubrication, auxiliary cooling, rust prevention, cleaning, sealing, buffering and the like. The lubricating oil is used between two objects which move relatively, and has the function of reducing the friction and the abrasion caused by the contact of the two objects, namely the lubricating oil.
The petroleum is distilled to separate hydrocarbon with different molecular weights according to the light weight, and the hydrocarbon is sequentially petroleum gas, naphtha, gasoline, kerosene, diesel oil, heavy fraction and residual oil, wherein the heavy fraction and the residual oil are the raw materials of the lubricating oil base oil.
The existing petroleum lubricating oil has single function and cannot meet diversified requirements.
Disclosure of Invention
The invention aims to provide a petroleum lubricating oil which can be suitable for requirements under various environments.
The above purpose is achieved by the following scheme:
the petroleum lubricating oil is characterized by being prepared from the following raw materials in parts by weight:
120 parts of neutral base oil 110-5 parts, 30-45 parts of coconut oil, 35-46 parts of sucrose polyester, 3-5 parts of mixed fatty glyceride, 2-4 parts of sorbitol, 5-8 parts of viscosity index improver, 6-15 parts of silane coupling agent kh 5506, 1-3 parts of tricresyl phosphate, 3-5 parts of modified thickening defoaming agent and 4-6 parts of preservative;
the modified thickening defoaming agent is prepared from the following raw materials in parts by weight:
20-35 parts of water, 3-6 parts of pine oil, 1-2 parts of water glass, 2-3 parts of acrylic acid, 22-25 parts of hydroxyethyl cellulose, 1-3 parts of stearic acid, 4-9 parts of limestone powder, 601-3 parts of span, 1-5 parts of polyisobutylene and 2-4 parts of a crosslinking agent TAC.
The preparation method of the modified thickening defoaming agent comprises the following steps: adding pine oil, water glass, acrylic acid, hydroxyethyl cellulose and a proper amount of water into a reaction kettle, uniformly stirring, adding the other raw materials of the modified thickening defoaming agent, and stirring at 40-50 ℃ at the rotating speed of 350-450r/min for 3-6min to obtain the modified thickening defoaming agent.
The preparation method of the petroleum lubricating oil comprises the following steps:
(1) adding the mixed fatty glyceride, sorbitol, the viscosity index improver and the silane coupling agent kh550 into a reaction kettle, stirring at the temperature of 35-40 ℃, the rotating speed of 100-150r/min and the stirring time of 13-16min, and taking out to obtain a compound modified material for later use;
(2) adding the rest raw materials into a reaction kettle, stirring at normal temperature at the rotation speed of 50-100r/min for 10-20min, and taking out after stirring.
The invention has the beneficial effects that: the petroleum lubricating oil obtained by the invention has good high temperature resistance and wear resistance and long service life, and the complex thickening defoamer can quickly complete defoaming work and adjust the technological parameter performance of the lubricating oil, so that the lubricating oil can meet the requirements of various occasions.
Detailed Description
A petroleum oil, which is prepared from the following raw materials by weight (kg):
110 parts of neutral base oil, 30 parts of coconut oil, 35 parts of sucrose polyester, 3 parts of mixed fatty glyceride, 2 parts of sorbitol, 8 parts of viscosity index improver, kh 5508 parts of silane coupling agent, 3 parts of tricresyl phosphate, 5 parts of modified thickening defoaming agent and 6 parts of preservative;
the modified thickening defoaming agent is prepared from the following raw materials in parts by weight (kg):
20 parts of water, 6 parts of pine oil, 2 parts of water glass, 3 parts of acrylic acid, 25 parts of hydroxyethyl cellulose, 3 parts of stearic acid, 9 parts of limestone powder, 601 parts of span, 3 parts of polyisobutylene and a crosslinking agent TAC 2.
The preparation method of the modified thickening defoaming agent comprises the following steps: adding oleum Pini, water glass, acrylic acid, hydroxyethyl cellulose and appropriate amount of water into a reaction kettle, stirring, adding the rest raw materials of modified thickening defoamer, stirring at 40 deg.C at rotation speed of 350r/min for 6min to obtain the final product.
The preparation method of the petroleum lubricating oil comprises the following steps:
(1) adding mixed fatty glyceride, sorbitol, a viscosity index improver and a silane coupling agent kh550 into a reaction kettle, stirring at 35 ℃ for 15min at the rotation speed of 150r/min, and taking out to obtain a compound modified material for later use;
(2) adding the rest raw materials into a reaction kettle, stirring at normal temperature at the rotation speed of 100r/min for 20min, and taking out after stirring.
Lubricating property evaluation experiment:
the lubricating oil prepared in this example was subjected to a four-ball test at 220 ℃ and 800rpm, and the corresponding test results were: the wear-resisting lubricating oil has the advantages that the wear-resisting wear.

Claims (3)

1. The petroleum lubricating oil is characterized by being prepared from the following raw materials in parts by weight:
120 parts of neutral base oil 110-5 parts, 30-45 parts of coconut oil, 35-46 parts of sucrose polyester, 3-5 parts of mixed fatty glyceride, 2-4 parts of sorbitol, 5-8 parts of viscosity index improver, 6-15 parts of silane coupling agent kh 5506, 1-3 parts of tricresyl phosphate, 3-5 parts of modified thickening defoaming agent and 4-6 parts of preservative;
the modified thickening defoaming agent is prepared from the following raw materials in parts by weight:
20-35 parts of water, 3-6 parts of pine oil, 1-2 parts of water glass, 2-3 parts of acrylic acid, 22-25 parts of hydroxyethyl cellulose, 1-3 parts of stearic acid, 4-9 parts of limestone powder, 601-3 parts of span, 1-5 parts of polyisobutylene and 2-4 parts of a crosslinking agent TAC.
2. The petroleum lubricating oil of claim 1, wherein the modified thickening defoamer is prepared by the following steps: adding pine oil, water glass, acrylic acid, hydroxyethyl cellulose and a proper amount of water into a reaction kettle, uniformly stirring, adding the other raw materials of the modified thickening defoaming agent, and stirring at 40-50 ℃ at the rotating speed of 350-450r/min for 3-6min to obtain the modified thickening defoaming agent.
3. The petroleum oil of claim 1, wherein: the preparation method comprises the following steps:
(1) adding the mixed fatty glyceride, sorbitol, the viscosity index improver and the silane coupling agent kh550 into a reaction kettle, stirring at the temperature of 35-40 ℃, the rotating speed of 100-150r/min and the stirring time of 13-16min, and taking out to obtain a compound modified material for later use;
(2) adding the rest raw materials into a reaction kettle, stirring at normal temperature at the rotation speed of 50-100r/min for 10-20min, and taking out after stirring.
CN201911252080.9A 2019-12-09 2019-12-09 Petroleum lubricating oil Pending CN110923048A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911252080.9A CN110923048A (en) 2019-12-09 2019-12-09 Petroleum lubricating oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911252080.9A CN110923048A (en) 2019-12-09 2019-12-09 Petroleum lubricating oil

Publications (1)

Publication Number Publication Date
CN110923048A true CN110923048A (en) 2020-03-27

Family

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Family Applications (1)

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CN201911252080.9A Pending CN110923048A (en) 2019-12-09 2019-12-09 Petroleum lubricating oil

Country Status (1)

Country Link
CN (1) CN110923048A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120214720A1 (en) * 2004-07-22 2012-08-23 Malcera, L.L.C. Chemical Composition of Matter for the Liquefaction and Dissolution of Asphaltene and Paraffin Sludges into Petroleum Crude Oils and Refined Products at Ambient Temperatures and Method of Use
CN104830475A (en) * 2015-04-29 2015-08-12 防城港港美家建材市场投资股份有限公司 Preparation method of automobile oil with high viscosity
CN105385487A (en) * 2015-11-26 2016-03-09 杨桂望 Low-cost and long-service-life lubricating oil
CN106334348A (en) * 2016-11-01 2017-01-18 合肥新万成环保科技有限公司 Compound defoaming agent capable of improving toughness
CN106635264A (en) * 2015-10-30 2017-05-10 徐勤凤 Lubricating oil
CN109468153A (en) * 2018-11-17 2019-03-15 江苏金润润滑油科技股份有限公司 A kind of thickening of lubricating oils agent prescription
CN109486548A (en) * 2017-09-11 2019-03-19 江苏瑞腾涂装科技有限公司 Lubricating oil

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120214720A1 (en) * 2004-07-22 2012-08-23 Malcera, L.L.C. Chemical Composition of Matter for the Liquefaction and Dissolution of Asphaltene and Paraffin Sludges into Petroleum Crude Oils and Refined Products at Ambient Temperatures and Method of Use
CN104830475A (en) * 2015-04-29 2015-08-12 防城港港美家建材市场投资股份有限公司 Preparation method of automobile oil with high viscosity
CN106635264A (en) * 2015-10-30 2017-05-10 徐勤凤 Lubricating oil
CN105385487A (en) * 2015-11-26 2016-03-09 杨桂望 Low-cost and long-service-life lubricating oil
CN106334348A (en) * 2016-11-01 2017-01-18 合肥新万成环保科技有限公司 Compound defoaming agent capable of improving toughness
CN109486548A (en) * 2017-09-11 2019-03-19 江苏瑞腾涂装科技有限公司 Lubricating oil
CN109468153A (en) * 2018-11-17 2019-03-15 江苏金润润滑油科技股份有限公司 A kind of thickening of lubricating oils agent prescription

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
司航: "《有机化工原料》", 31 January 1995 *
石得中等: "《世界精细化工产品技术经济手册》", 31 December 1988 *
黄礼煌: "《浮选》", 31 March 2018 *

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Application publication date: 20200327