CN110922986A

CN110922986A - A kind of liquid crystal composition containing dibenzofuran polymerizable compound and its application

Info

Publication number: CN110922986A
Application number: CN201811102478.XA
Authority: CN
Inventors: 苏学辉; 于海龙; 陈卯先; 储士红; 田会强; 未欣; 姜天孟; 陈海光
Original assignee: Beijing Bayi Space LCD Technology Co Ltd
Current assignee: Beijing Bayi Space LCD Technology Co Ltd
Priority date: 2018-09-20
Filing date: 2018-09-20
Publication date: 2020-03-27

Abstract

本发明涉及液晶材料领域，具体涉及一种含有二苯并呋喃类可聚合化合物的液晶组合物及其应用。所述液晶组合物包括一种或多种如通式I所示的可聚合化合物；所述液晶组合物还包括液晶基础体系，所述的通式I所代表的可聚合化合物的用量占所述液晶基础体系总质量的0.1～5％；本发明所提供的液晶组合物具有快速的反应速度，可以缩短可聚合化合物聚合所用时间，大幅缩短液晶显示器聚合工序所需要的时间，提升液晶显示器的产量，缩短液晶显示器在环境中暴露时间，提升液晶显示器的品质性能。因此，本发明所提供的液晶组合物适用于PSVA、SAVA显示模式液晶显示器件；尤其适用于PSVA液晶显示器件。

The invention relates to the field of liquid crystal materials, in particular to a liquid crystal composition containing dibenzofuran polymerizable compounds and applications thereof. The liquid crystal composition includes one or more polymerizable compounds represented by the general formula I; the liquid crystal composition also includes a liquid crystal base system, and the amount of the polymerizable compound represented by the general formula I accounts for the 0.1-5% of the total mass of the liquid crystal base system; the liquid crystal composition provided by the present invention has a fast reaction speed, which can shorten the time required for the polymerization of the polymerizable compound, greatly shorten the time required for the polymerization process of the liquid crystal display, and improve the output of the liquid crystal display. , shorten the exposure time of the liquid crystal display in the environment, and improve the quality and performance of the liquid crystal display. Therefore, the liquid crystal composition provided by the present invention is suitable for PSVA and SAVA display mode liquid crystal display devices; especially suitable for PSVA liquid crystal display devices.

Description

Liquid crystal composition containing dibenzofuran polymerizable compound and application thereof

Technical Field

The invention relates to a liquid crystal material, in particular to a liquid crystal composition containing dibenzofuran polymerizable compounds and application thereof.

Background

Negative liquid crystals, which were proposed at the beginning of the 80's last century, are mainly used in the VA mode, which has very excellent contrast performance, but has significant viewing angle problems and response time problems, and in order to solve the viewing angle problems, display technologies such as MVA, PVA, CPA, etc., which are essentially to solve the viewing angle problems using multi-domains and achieve good effects, have been proposed. However, the display industry has been plagued by problems of increased difficulty and response time in the art, until PSVA (polymer stabilized vertical alignment) technology has been proposed, which uses polymers to achieve multi-domain and pretilt angle control to achieve fast response and wide viewing angle liquid crystal displays.

The polymerizable compound and the liquid crystal cause the voltage holding ratio of the liquid crystal to be reduced, so the residual polymerizable compound needs to be added in the production process of the liquid crystal display to fully react, and in order to ensure the full reaction, the time is usually longer, so the process time is prolonged, and the productivity is reduced; on the other hand, since the glass substrate needs to be exposed for a period of time after the completion of the preceding process, the surface layer of the panel is contaminated by the pollution source in the environment, which results in the degradation of the quality of the liquid crystal display.

The invention aims to provide a liquid crystal composition capable of reacting quickly, shortening the polymerization time of a polymerizable compound and improving the production capacity of a liquid crystal display; the interval time of the working procedures in the production process of the liquid crystal display is shortened, and the quality of the liquid crystal display is improved.

Disclosure of Invention

The liquid crystal composition provided by the invention has high reaction speed and is characterized by at least comprising a polymerizable compound shown in a general formula I:

wherein, the ring A₁And ring A₂Each independently represents 1, 4-phenylene, 1, 4-cyclohexylene, 1, 4-cyclohexenylene, or 1, 4-phenylene in which 1 to 4 hydrogen atoms are each independently substituted by F or Cl;

the P is₁、P₂、P₃Each independently represents an acrylate group, a methacrylate group, a fluoroacrylate group, a chloroacrylate group, a vinyloxy group, an oxetane group or an epoxy group;

z is₁、Z₄Each independently represents a single bond, -O-, -S-, -CO-O-, -O-CO-O-, -CH ═ N-, -N ═ CH-, -N ═ N-, -C ≡ C-, C1-C12 alkylene or alkenyl, wherein one or more hydrogen atoms in the C1-C12 alkylene or alkenyl may each independently be substituted by F, Cl, or CN, and one or more non-adjacent-CH 2-groups may each independently be substituted by-O-, -S-, -NH-, -CO-, COO-, -OCO-, -OCOO-, -SCO-, -COS-or an olefinic bond is replaced in a manner not directly linked to each other;

z is₂、Z₃Each independently represents a single bond, -O-, -S-, -CO-O-, -O-CO-O-, -CH-N-, -N-CH-, -N-, -C.ident.C-, or C₁-C₁₂Alkylene or alkenyl of, said C₁-C₁₂May each independently be substituted with F, Cl, or CN, and one or more non-adjacent-CH₂The-groups may each independently be-O-, -S-, -NH-, -CO-, COO-, -OCO-, -OCOO-, -SCO-or-COS-is replaced in a manner not directly linked to each other;

L₁，L₂each independently represents-F, -Cl, -CN, -NO2, -CH3, -C2H5, -C (CH3)3, -CH (CH3)2, -CH2CH (CH3) C2H5, -OCH3, -OC2H5, -COCH3, -COC2H5, -COOCH3, -COOC2H5, -CF3, -OCF3, -OCHF2 or-OC 2F 5;

r, s each independently represent 0, 1, 2 or 3; m and n independently represent 0 or 1.

Preferably, in formula I: the ring A₁And ring A₂Independently of one another, 1, 4-phenylene, 1, 4-cyclohexylene or 1, 4-phenylene in which 1 to 4 hydrogen atoms have been replaced by F or Cl atoms; preferably, said ring A₁And ring A₂Independently of one another, 1, 4-phenylene, 1, 4-cyclohexylene, 2-fluoro-1, 4-phenylene;

and/or, said P₁、P₂、P₃Independently of one another, a methacrylate group or an acrylate group;

and/or r, s independently of one another denote 0 or 1

And/or m, n independently of one another represent 0 or 1, and m + n ≦ 1;

and/or, said Z₁、Z₄Independently of one another, represents a single bond, -O-, -S-, -CO-O-, -O-CO-O-, -CH ═ N-, -N ═ CH-, -N ═ N-, -C ≡ C-, C₁-C₁₂Alkylene or alkenyl of (a), wherein said C₁-C₁₂May be independently of each other substituted by F, Cl or CN, and one or more non-adjacent-CH₂The radicals may be replaced, independently of one another, by-O-, -S-, -NH-, -CO-, -COO-, -OCO-, -OCOO-, -SCO-, -COS-or an olefinic bond in such a way that they are not linked directly to one another; preferably, Z is₁、Z₄Independently of one another, represents a single bond, -O-or C₁-C₅Alkylene and alkoxy groups of (a);

and/or, said Z₂、Z₃Independently of one another, represents a single bond or- (CH)₂)_k-, k represents 1 to 8; preferably, k represents 1, 2, 3, 4 or 5; further onK represents 1, 2 or 3;

and/or, said L₁，L₂Independently of one another denotes-F, -Cl, -CN, or C₁-C₃Alkyl or alkoxy of (a); preferably, L₁、L₂Identical or different and independently of one another represent-F, -Cl, -CN, -CH₃、-OCH₃、-CF₃、-OCF₃or-OCHF₂(ii) a Further, said L₁、L₂Identical or different, independently of one another, represent-F, -Cl;

and/or, m ═ n ═ 0, L₁And L₂Each represents-F, r and s are independently from each other selected from 0 or 1; or, m is 1, n is 0, L₁And L₂Each represents-F, ring A is selected from 1, 4-phenylene, 1, 4-cyclohexylene or 1, 4-phenylene in which 1 to 2 hydrogen atoms are substituted by one or more of F or Cl atoms, r and s are independently from each other selected from 0 or 1; or, m is 0, n is 1, L₁And L₂Both represent-F, ring B is selected from 1, 4-phenylene, 1, 4-cyclohexylene or 1, 4-phenylene in which 1 to 2 hydrogen atoms are substituted by one or more of F or Cl atoms, r and s are independently from each other selected from 0 or 1.

The liquid crystal composition provided by the invention also comprises a liquid crystal base system, and the liquid crystal base system also comprises one or more compounds represented by general formulas II to V:

wherein R is₁、R₂、R₃、R₄、R₅、R₆、R₇、R₈Each independently represents C₁～C₁₂Linear alkyl, linear alkoxy or C₂～C₁₂A linear alkenyl group of (a); z₅、Z₆Each independently represents CH₂O、CH₂CH₂；A₃、A₄Each independently represents trans-1, 4-cyclohexyl or 1, 4-phenylene.

With respect to R₁、R₂、R₃、R₄、R₅、R₆、R₇、R₈: preferably, R₁、R₂、R₃、R₄、R₅、R₆、R₇、R₈Each independently represents C₁～C₇Linear alkyl, linear alkoxy or C₂～C₁₂A linear alkenyl group of (a); more preferably, R₁、R₃、R₅、R₇Each independently represents C₁～C₇Straight chain alkyl or C₂～C₅Straight-chain alkenyl group (more preferably C)₁～C₅Straight chain alkyl or C₂～C₅Linear alkenyl groups of (a); and/or, R₂、R₄、R₆、R₈Each independently represents C₁～C₇Straight-chain alkyl group or straight-chain alkoxy group (more preferably C)₁～C₄Linear alkyl or linear alkoxy groups of (a).

The compound of the general formula I provided by the invention is a polymerizable compound monomer, and the compound is polymerized under the irradiation of ultraviolet light to form a stable structure, so that the stable alignment of liquid crystal molecules is promoted.

Specifically, the compound of the general formula I provided by the invention is selected from one or more of the general formulas I-1 to I-42:

in the liquid crystal basic system, the compound provided by the general formula II is a compound with a two-ring structure and containing a2, 3-difluorobenzene structure, and the compound has large negative dielectric anisotropy and excellent intersolubility, and has remarkable effects of improving the negative dielectric anisotropy of the liquid crystal composition and improving the low temperature.

Specifically, the compound shown in the general formula II is selected from one or more of the following formulas IIA and IIB:

wherein R is₁Represents C₁～C₇Straight chain alkyl or C₂～C₅A linear alkenyl group of (a); r₂Represents C₁～C₇Linear alkyl or linear alkoxy groups of (1).

In the liquid crystal basic system, the compound represented by the general formula III is a tricyclic compound containing a2, 3-difluorobenzene structure, and the compound has large negative dielectric anisotropy and high clearing point, and can improve the clearing point and the negative dielectric anisotropy of the liquid crystal composition.

Specifically, the compound represented by the general formula III is selected from one or more of formula IIIA and formula IIIB:

wherein R is₃Represents C₁～C₇Straight chain alkyl or C₂～C₅A linear alkenyl group of (a); r₄Represents C₁～C₇Linear alkyl or linear alkoxy groups of (1).

In the liquid crystal basic system, the compound provided by the general formula IV is a compound with a two-ring structure and a2, 3-difluorobenzene structure, and the compound has large negative dielectric anisotropy and excellent intersolubility, and has remarkable effects of improving the negative dielectric anisotropy of the liquid crystal composition and improving the low temperature.

Specifically, the compound of formula IV is selected from one or more of formula IVA, formula IVB:

wherein R is₅Represents C₁～C₇Straight chain alkyl or C₂～C₅A linear alkenyl group of (a); r₆Represents C₁～C₇Linear alkyl or linear alkoxy groups of (1).

In the liquid crystal basic system, the compound provided by the general formula V is a tricyclic compound containing a2, 3-difluorobenzene structure, and the compound has large negative dielectric anisotropy and high clearing point, and can improve the clearing point and the negative dielectric anisotropy of the liquid crystal composition.

Specifically, the compound shown in the general formula V is selected from one or more of formula VA and formula VB:

wherein R is₇Represents C₁～C₇Straight chain alkyl or C₂～C₅A linear alkenyl group of (a); r₈Represents C₁～C₇Linear alkyl or linear alkoxy groups of (1).

Preferably, the polymerizable compound represented by formula I is selected from one or more of the following structures:

preferably, the compound represented by the general formula II is selected from one or more of IIA 1-IIB 24:

more preferably, the compound represented by the general formula II provided by the invention is selected from one or more of IIA14, IIA16, IIA22, IIB16, IIB17, IIB24 and IIB 26; particularly preferably, the compound represented by the general formula II provided by the invention is selected from one or more of IIA14, IIA16, IIA22, IIB16, IIB17 and IIB 24.

Preferably, the compound represented by formula III is selected from one or more of IIIA 1-IIIB 24:

more preferably, the compound represented by the general formula III provided by the present invention is selected from one or more of IIIA1, IIIA2, IIIA10, IIIA13, IIIA14, IIIA15, IIIA16, IIIA18, IIIB1, IIIB2, IIIB13, IIIB14, IIIB15, IIIB 22; particularly, one or more of IIIA1, IIIA2, IIIA10, IIIA13, IIIA14, IIIA15, IIIB13, IIIB14, and IIIB22 are preferable.

Preferably, the compound represented by formula IV is selected from one or more of IVA 1-IVB 24:

more preferably, the compound represented by formula IV is selected from one or more of IVA10, IVA14, IVA16, IVA22, IVB14, IVB 16; particularly preferably, the compound represented by the general formula IV is selected from one or more of IVA10, IVA14, IVB 14.

Preferably, the compound represented by the general formula V is selected from one or more of VA 1-VB 16:

more preferably, the compound represented by the general formula V is selected from one or more of VA5, VA6, VA7, VA8, VB5 and VB 6; particularly preferably, the compound represented by the general formula V is selected from one or more of VA5, VA6, VB5 and VB 6.

In the liquid crystal composition provided by the present invention, the liquid crystal base system may further comprise one or more compounds selected from compounds represented by formula VI:

wherein R is₉、R₁₀Each independently represents C₁～C₁₂Linear alkyl, linear alkoxy or C₂～C₁₂A linear alkenyl group of (a); n is₁、n₂Each independently represents 0 or 1 (preferably n)₁、n₂Not 1 at the same time); a. the₅Represents trans-1, 4-cyclohexyl, 1, 4-phenylene in which one or more H atoms on the phenyl ring may each independently be substituted by F.

The compound represented by the general formula VI is a compound containing a cyclohexene structure and a2, 3-difluorobenzene structure, and the structure has larger dielectric anisotropy.

Specifically, the compound represented by formula VI is selected from one or more of VIA to VID:

wherein R is₉Represents C₂～C₇Linear alkyl or alkenyl of (preferably C)₂～C₅A linear alkyl or linear alkenyl group of); r₁₀Represents C₁～C₅Linear alkyl or alkoxy radical (preferably C)₁～C₄Linear alkyl or linear alkoxy groups of (a).

Preferably, the compound represented by formula VI is selected from one or more of VIA 1-VID 16:

more preferably, the compound represented by the general formula VI provided by the present invention is selected from one or more of VIA6, VIA8, VIA14, VIB6, VIB7, VIB10, VIB14, VIC5, VIC6, VIC14, VID5, VID 6; particularly preferably, the compound represented by formula VI is selected from one or more of VIB6, VIB10, VIC5, VIC6, VID5, VID 6.

In the liquid crystal composition provided by the invention, the liquid crystal base system can further comprise one or more compounds represented by a general formula VII:

wherein R is₁₁、R₁₂Each independently represents C₁～C₁₂Linear alkyl, linear alkoxy or C₂～C₁₂Linear alkenyl of (preferably C)₁～C₇Linear alkyl, linear alkoxy or C₂～C₇Linear alkenyl groups of (a); a. the₆、A₇Each independently represents trans-1, 4-cyclohexyl or 1, 4-phenylene.

The compound represented by the general formula VII is a two-ring structure neutral compound, and the structure has very low rotational viscosity, so that the rotational viscosity of the liquid crystal composition is reduced, and the response time is effectively prolonged.

Specifically, the compound represented by the general formula VII is selected from one or more of VIIA to VIIC:

wherein R is₁₁Represents C₁～C₇Straight chain alkyl or C₂～C₇A linear alkenyl group of (a); r₁₂Represents C₁～C₇Linear alkyl, linear alkoxy or C₂～C₇Linear alkenyl of (preferably represents C)₁～C₅Linear alkyl, linear alkoxy or C₂～C₅Linear alkenyl groups of (ii).

Preferably, the compound represented by formula VII is selected from one or more of VIIA 1-VIIC 25:

more preferably, the compound represented by the general formula VII is selected from one or more of VIIA2, VIIA6, VIIA14, VIIA18, VIIA20, VIIA22, VIIA24, VIIA26, VIIA27, VIIA32, VIIA36, VIIB2, VIIB8, VIIB14, VIIB18, VIIB26, VIIC2, VIIC4, VIIC6, VIIC17, VIIC18, VIIC28, VIIC30, VIIC32, VIIC34, VIIC43, VIIC 44; particularly preferably, the compound represented by the general formula VII is selected from one or more of VIIA2, VIIA6, VIIA22, VIIA26, VIIA27, VIIB14, VIIB18, VIIC4, VIIC6, VIIC18, VIIC28, VIIC 32.

In the liquid crystal composition provided by the present invention, the liquid crystal base system may further comprise one or more compounds represented by general formula VIII:

wherein R is₁₃、R₁₄Each independently represents C₁～C₁₂Linear alkyl, linear alkoxy or C₂～C₁₂A linear alkenyl group of (a); a. the₈Represents trans-1, 4-cyclohexyl or 1, 4-phenylene.

The compound represented by the general formula VIII has a high clearing point and a large elastic constant, and is very effective in increasing the clearing point and increasing the elastic constant of the liquid crystal composition.

Specifically, the compound represented by formula VIII is selected from one or more of VIIIA to VIIIB:

wherein R is₁₃Represents C₂～C₇Linear alkyl or alkenyl of (preferably represents C)₂～C₅A linear alkyl or linear alkenyl group of); r₁₄Represents C₁～C₇Linear alkyl, linear alkoxy or C₂～C₇Linear alkenyl of (preferably represents C)₁～C₄Linear alkyl, linear alkoxy or C₂～C₄Linear alkenyl groups of (ii).

Preferably, the compound represented by formula VIII is selected from one or more of VIIIA1 to VIIIB 24:

more preferably, the compound represented by formula VIII is selected from one or more of VIIIA2, VIIIA6, VIIIA10, VIIIA17, VIIIA18, VIIIA25, VIIIA31, VIIIA37, VIIIB2, VIIIB6, VIIIB8, VIIIB25, VIIIB27, VIIIB31, VIIIB33, VIIIB 50; more preferably, the compound represented by formula VIII is selected from one or more of VIIIA2, VIIIA6, VIIIA17, VIIIA25, VIIIA37, VIIIB2, VIIIB6, VIIIB8, VIIIB 50.

In the liquid crystal composition provided by the present invention, the liquid crystal base system may further comprise one or more compounds represented by formula IX:

wherein R is₁₅Represents C₁～C₁₂Linear alkyl, linear alkoxy or C₂～C₁₂A linear alkenyl group of (a); r₁₆Representative F, C₁～C₁₂Linear alkyl, linear alkoxy or C₂～C₁₂A linear alkenyl group of (a); l is₃、L₅、L₆Each independently represents H or F; l is₄Representative H, CH₃F; preferably, L₃、L₄、L₅、L₆Not H at the same time; or not both as F.

The compound represented by the general formula IX is a terphenyl compound, and the compound has large optical anisotropy and can effectively improve the optical anisotropy of the liquid crystal composition.

Specifically, the compound represented by the general formula IX is selected from one or more of IXA to IXF:

wherein R is₁₅Represents C₁～C₇Linear alkyl radical of (preferably represents C)₁～C₅Linear alkyl groups of (a); r₁₆Representative F, C₁～C₇Linear alkyl or alkoxy radical of (preferably representing F, C)₁～C₅Linear alkyl or linear alkoxy groups of (a).

Preferably, the compound represented by formula IX is selected from one or more of IXA 1-IXI 24:

more preferably, the compound represented by formula IX is selected from one or more of IXA2, IXA3, IXA4, IXA8, IXB1, IXB2, IXC1, IXC2, IXD1, IXD2, IXE2, IXE3, IXF1, IXG2, IXH2, IXI2, IXI14, IXI21, IXI 22; particularly preferably, the compound represented by the general formula IX is selected from one or more of IXA2, IXA3, IXE2, IXE3, IXG2, IXH2, IXI2, IXI14, IXI 21.

In the liquid crystal composition provided by the invention, the liquid crystal base system can further comprise one or more compounds represented by the general formula X:

wherein R is₁₇、R₁₈Each independently represents C₁～C₁₂Linear alkyl, linear alkoxy, C₂～C₁₂The linear alkenyl group of (a), cyclopropylmethylene group, cyclopropylmethylenoxy group, cyclopentyl group, cyclopentylidene group, cyclopentyloxy group or cyclopentylmethenoxy group; l is₇Represents O or S.

The compound represented by the general formula X provided by the invention has very large negative dielectric anisotropy, and can effectively improve the negative dielectric anisotropy of the liquid crystal composition.

Specifically, the compound represented by the general formula X is selected from one or more of XA to XF:

wherein R is₁₇Represents C₁～C₇Linear alkyl or alkoxy (more preferably represents C)₁～C₅Linear alkyl or linear alkoxy groups of (a).

Preferably, the compound represented by the general formula X is selected from one or more of XA1 to XI 4:

more preferably, the compound represented by the general formula X is selected from one or more of XA36, XA37, XA38, XB9, XB10, XC9, XC10, XD9, XD10, XE36, XE37, XE38, XF9, XF10, XG9, XG10, XH9, XH 10; particularly preferably, the compound represented by the general formula X is selected from one or more of XA37, XA38, XB9, XB10, XC9, XC10, XD9, XD10, XE37, XE38, XF9, XF10, XG9, XG10, XH9, XH 10.

The amount of the polymerizable compound represented by the general formula I accounts for 0.1-5% of the total mass of the liquid crystal basic system, and preferably 0.2-0.5%.

Specifically, the liquid crystal composition provided by the invention comprises a liquid crystal basic system and at least one polymerizable compound represented by a general formula I; the liquid crystal base system comprises the following components in percentage by mass (consisting of the following components in percentage by mass):

(1) 10-75% of a compound represented by general formula II-V; (2)0 to 45% of a compound represented by the general formula VI; (3)1 to 70% of a compound represented by the general formula VII; (4)0 to 30% of a compound represented by the general formula VIII; (5)0 to 40% of a compound represented by the general formula IX; (6)0 to 40% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.1-5% of the total mass of the liquid crystal basic system.

Preferably, the liquid crystal base system comprises (consists of) the following components in mass percent:

(1) 15-70% of a compound represented by general formula II-V; (2)0 to 35% of a compound represented by the general formula VI; (3) 4-65% of a compound represented by formula VII; (4)0 to 25% of a compound represented by the general formula VIII; (5)0 to 30% of a compound represented by the general formula IX; (6)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

More preferably, the liquid crystal base system comprises (consists of) the following components in mass percent:

(1) 22-65% of compounds represented by general formulas II-V; (2)0 to 29% of a compound represented by the general formula VI; (3) 6-58% of a compound represented by the general formula VII; (4)0 to 21% of a compound represented by the general formula VIII; (5)0 to 25% of a compound represented by the general formula IX; (6)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1)25 to 65% of compounds represented by general formulas III to V; (2)0 to 35% of a compound represented by the general formula VI; (3) 4-55% of a compound represented by formula VII; (4)0 to 20% of a compound represented by the general formula VIII; (5)0 to 10% of a compound represented by the general formula IX; (6)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 32-58% of a compound represented by general formula II-V; (2)0 to 29% of a compound represented by the general formula VI; (3) 6-53% of a compound represented by formula VII; (4)0 to 15% of a compound represented by general formula VIII; (5)0 to 5% of a compound represented by the general formula IX; (6)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1) 1-36% of a compound represented by general formula II; (2) 5-60% of a compound represented by general formulae III-V; (3)0 to 20% of a compound represented by the general formula VI; (4) 21-63% of a compound represented by formula VII; (5)0 to 25% of a compound represented by the general formula VIII; (6)0 to 30% of a compound represented by the general formula IX; (7)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 2-33% of a compound represented by general formula II; (2) 10-56% of a compound represented by general formulae III-V; (3)0 to 16% of a compound represented by the general formula VI; (4)26 to 58% of a compound represented by the general formula VII; (5)0 to 21% of a compound represented by the general formula VIII; (6)0 to 25% of a compound represented by the general formula IX; (7)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1)0 to 10% of a compound represented by the general formula II; (2) 10-55% of a compound represented by the general formula III; (3) 3-20% of a compound represented by formula IV; (4)0 to 26% of a compound represented by the general formula V; (5)25 to 56% of a compound represented by the general formula VII; (6)0 to 20% of a compound represented by the general formula VIII; (7)0 to 10% of a compound represented by the general formula IX; (8)0 to 10% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1)0 to 6% of a compound represented by the general formula II; (2)14 to 51% of a compound represented by the general formula III; (3) 4-16% of a compound represented by formula IV; (4)0 to 23% of a compound represented by the general formula V; (5) 30-53% of a compound represented by formula VII; (6)0 to 15% of a compound represented by general formula VIII; (7)0 to 5% of a compound represented by the general formula IX; (8)0 to 5% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1)0 to 10% of a compound represented by the general formula II; (2) 20-55% of a compound represented by the general formula III; (3) 3-20% of a compound represented by formula IV; (4) 35-56% of a compound represented by formula VII; (5)0 to 20% of a compound represented by the general formula VIII; (6)0 to 7% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1)0 to 6% of a compound represented by the general formula II; (2) 24-51% of a compound represented by the general formula III; (3) 4-16% of a compound represented by formula IV; (4) 40-53% of a compound represented by formula VII; (5)0 to 15% of a compound represented by general formula VIII; (6)0 to 4% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1) 10-42% of a compound represented by the general formula III; (2) 5-18% of a compound represented by formula IV; (3) 3-26% of a compound represented by formula V; (4) 25-55% of a compound represented by formula VII; (5)0 to 15% of a compound represented by general formula VIII; (6)0 to 10% of a compound represented by the general formula IX; (7)0 to 10% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1)14 to 37% of a compound represented by the general formula III; (2) 8-14% of a compound represented by formula IV; (3) 5-23% of a compound represented by formula V; (4)30 to 50% of a compound represented by the general formula VII; (5)0 to 11% of a compound represented by the general formula VIII; (6)0 to 5% of a compound represented by the general formula IX; (7)0 to 5% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1) 1-38% of a compound represented by general formula II; (2) 5-45% of a compound represented by general formula III; (3) 20-65% of a compound represented by formula VII; (4)0 to 25% of a compound represented by the general formula VIII; (5)0 to 30% of a compound represented by the general formula IX; (6)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 2-33% of a compound represented by general formula II; (2) 10-39% of a compound represented by the general formula III; (3)26 to 58% of a compound represented by the general formula VII; (4)0 to 21% of a compound represented by the general formula VIII; (5)0 to 25% of a compound represented by the general formula IX; (6)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1) 17-55% of compounds represented by general formulas II-V; (2)3 to 33% of a compound represented by the general formula VI; (3) 4-65% of a compound represented by formula VII; (4)0 to 15% of a compound represented by general formula VIII; (5)0 to 30% of a compound represented by the general formula IX; (6)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 22-51% of compounds represented by general formulas II-V; (2) 4-29% of a compound represented by formula VI; (3) 6-58% of a compound represented by the general formula VII; (4)0 to 12% of a compound represented by the general formula VIII; (5)0 to 25% of a compound represented by the general formula IX; (6)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1)27 to 70% of a compound represented by general formula II to general formula V; (2) 21-65% of a compound represented by formula VII; (3)0 to 25% of a compound represented by the general formula VIII; (4)0 to 20% of a compound represented by the general formula IX; (5)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 32-65% of compounds represented by general formulas II-V; (2)26 to 58% of a compound represented by the general formula VII; (3)0 to 21% of a compound represented by the general formula VIII; (4)0 to 15% of a compound represented by the general formula IX; (5)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1)18 to 70% of a compound represented by general formula II to general formula V; (2)0 to 35% of a compound represented by the general formula VI; (3) 3-63% of a compound represented by formula VII; (4)0 to 30% of a compound represented by the general formula IX; (5)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 22-65% of compounds represented by general formulas II-V; (2)0 to 29% of a compound represented by the general formula VI; (3) 6-58% of a compound represented by the general formula VII; (4)0 to 25% of a compound represented by the general formula IX; (5)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1)27 to 59% of compounds represented by general formulas II to V; (2)0 to 18% of a compound represented by the general formula VI; (3) 21-55% of a compound represented by formula VII; (4)1 to 25% of a compound represented by general formula VIII; (5)0 to 18% of a compound represented by the general formula IX; (6)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 32-59% of compounds represented by general formulas II-V; (2)0 to 14% of a compound represented by the general formula VI; (3)26 to 51% of a compound represented by the general formula VII; (4)2 to 21% of a compound represented by general formula VIII; (5)0 to 14% of a compound represented by the general formula IX; (6)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1)27 to 70% of a compound represented by general formula II to general formula V; (2)0 to 33% of a compound represented by the general formula VI; (3) 3-65% of a compound represented by formula VII; (4)0 to 25% of a compound represented by the general formula VIII; (6)0 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 32-65% of compounds represented by general formulas II-V; (2)0 to 29% of a compound represented by the general formula VI; (3) 6-58% of a compound represented by the general formula VII; (4)0 to 21% of a compound represented by the general formula VIII; (6)0 to 25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1) 18-65% of compounds represented by general formulas II-V; (2)0 to 20% of a compound represented by the general formula VI; (3) 21-65% of a compound represented by formula VII; (4)0 to 25% of a compound represented by the general formula VIII; (5) 1-30% of a compound represented by formula IX; (6)0 to 18% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 22-60% of a compound represented by general formula II-V; (2)0 to 16% of a compound represented by the general formula VI; (3)26 to 58% of a compound represented by the general formula VII; (4)0 to 21% of a compound represented by the general formula VIII; (5) 2-25% of a compound represented by formula IX; (6)0 to 14% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1)27 to 70% of a compound represented by general formula II to general formula V; (2)0 to 18% of a compound represented by the general formula VI; (3) 21-63% of a compound represented by formula VII; (4)0 to 25% of a compound represented by the general formula VIII; (5)0 to 18% of a compound represented by the general formula IX; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 33-65% of compounds represented by general formulas II-V; (2)0 to 14% of a compound represented by the general formula VI; (3)26 to 58% of a compound represented by the general formula VII; (4)0 to 21% of a compound represented by the general formula VIII; (5)0 to 14% of a compound represented by the general formula IX; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

(1) 18-55% of compounds represented by general formulas II-V; (2)0 to 33% of a compound represented by the general formula VI; (3) 5-55% of a compound represented by formula VII; (4)0 to 18% of a compound represented by the general formula VIII; (5)0 to 30% of a compound represented by the general formula IX; (6)1 to 30% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal basic system.

(1) 22-53% of compounds represented by general formulas II-V; (2)0 to 29% of a compound represented by the general formula VI; (3)6 to 50% of a compound represented by the general formula VII; (4)0 to 14% of a compound represented by the general formula VIII; (5)0 to 25% of a compound represented by the general formula IX; (6) 2-25% of a compound represented by the general formula X; the amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal basic system.

Or, preferably, in said liquid crystal base system:

when the compound represented by formula II is used in an amount of 0 and the compound represented by formula IV or V or VIII is used in an amount of 0, the compound represented by formula IX is also used in an amount of 0;

or the dosage of the compounds represented by the general formula II and the general formula VII is not 0 at the same time;

or, when the compound represented by the general formula II and the general formula X is used in an amount of 0, the compound represented by the general formula VI is also used in an amount of 0;

or, when the amount of the compound represented by the general formula III and the general formula IV is 0, the amount of the compound represented by the general formula IX is 0;

or, the amount of the compound represented by the formula III is not 0 when different from the amount of the compound represented by any one of the formula V, the formula VII, the formula VIII, the formula IX or the formula X;

or when the compound represented by the general formula III and the general formula VI is used in an amount of 0, the compound represented by the general formula II, IV, V, VII, VIII, IX and X is not used in an amount of 0;

or the dosage of the compounds represented by the general formula IV and the general formula VII is not 0 at the same time;

or when the dosage of the compounds represented by the general formulas IV and VIII is 0, the dosage of the compound represented by the general formula V is 0;

or when the dosage of the compounds represented by the general formula IV and the general formula X is 0, the dosage of the compounds represented by the general formula IV is also 0;

or, the dosage of the compounds represented by the general formula V and the general formula VII is not 0 at the same time;

or, the amount of the compound represented by the general formula VI and the compound represented by the general formula VII are not 0 at the same time;

or, the amount of the compound represented by any one of the general formula VII and the general formula VIII, the general formula IX or the general formula X is not 0 at the same time; more preferably, the liquid crystal base system includes (consists only of) compounds represented by general formulae II to X; the liquid crystal base system comprises (consists of compounds represented by the following general formulas II to X):

(1) 8-15% of a compound represented by formula II; (2) 0% of a compound represented by the general formula III; (3) 5-10% of a compound represented by formula IV; (4) 20-25% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 30-35% of a compound represented by formula VII; (7) 10-15% of a compound represented by formula VIII; (8) 5-10% of a compound represented by formula IX; (9) 5-8% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 35-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-50% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 10-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0-20% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 40-50% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-15% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 40-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 25-30% of a compound represented by formula VI; (6) 5-50% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 10-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0-20% of a compound represented by formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-50% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 50-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 40-50% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 20-55% of a compound represented by formula III; (3) 0-20% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 40-55% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-5% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 35-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-55% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 20-55% of a compound represented by formula III; (3) 0-20% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-55% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 1-55% of a compound represented by formula III; (3) 2-20% of a compound represented by formula IV; (4) 3-5% of a compound represented by formula V; (5) 3-5% of a compound represented by formula VI; (6) 5-55% of a compound represented by formula VII; (7) 5-15% of a compound represented by formula VIII; (8) 5-10% of a compound represented by formula IX; (9) 5-10% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 25-55% of a compound represented by formula III; (3) 0-20% of a compound represented by formula IV; (4) 0-15% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 40-55% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 12-55% of a compound represented by formula III; (3) 0-20% of a compound represented by formula IV; (4) 0-23% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 30-55% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-15% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 14-55% of a compound represented by formula III; (3) 0-20% of a compound represented by formula IV; (4) 0-25% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 30-55% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0-5% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 25-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0-15% of a compound represented by formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-55% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 25-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0-15% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 40-55% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 10-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0-25% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 30-55% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 5-10% of a compound represented by formula II; (2) 0% of a compound represented by the general formula III; (3) 0% of a compound represented by the general formula IV; (4) 25-35% of a compound represented by formula V; (5) 5-10% of a compound represented by formula VI; (6) 30-35% of a compound represented by formula VII; (7) 5-15% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 5-15% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-33% of a compound represented by formula II; (2) 10-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 10-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-25% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 10-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-15% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 10-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0-20% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7)0 to 22% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 10-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-28% of a compound represented by formula II; (2) 30-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-28% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-5% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-33% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-10% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-28% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 30-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0-5% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 10-55% of a compound represented by formula III; (3) 0-20% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 30-55% of a compound represented by formula III; (3) 0-20% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-5% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-10% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0-15% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-5% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0-15% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0-25% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0-25% of a compound represented by formula IV; (4) 0-15% of a compound represented by formula V; (5) 0-5% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X; still more preferably, the liquid crystal base system comprises (consists of) the following components in mass percent:

(1) 0% of a compound represented by the general formula II; (2) 50-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 45-50% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 40-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-50% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 50-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 45-55% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 35-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 40-55% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 20-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 40-55% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-5% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 20-55% of a compound represented by formula III; (3) 0-28% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 40-55% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 20-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0-18% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 40-55% of a compound represented by formula VII; (7) 0-15% of a compound represented by general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 30-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0-5% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 00% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 30-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-30% of a compound represented by formula VI; (6) 5-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-25% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-5% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-10% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 30-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 0% of a compound represented by the general formula VII; (7) 35-60% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-5% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 30-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0-5% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-45% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0-15% of a compound represented by formula V; (5) 0% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X; still more preferably, the liquid crystal base system comprises (consists of) the following components in mass percent:

or the like, or, alternatively,

(1) 0% of a compound represented by the general formula II; (2) 20-55% of a compound represented by formula III; (3) 0-18% of a compound represented by formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 40-55% of a compound represented by formula VII; (7) 0-18% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 30-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0% of a compound represented by formula IX; (9) 0-5% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-30% of a compound represented by formula II; (2) 25-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 35-60% of a compound represented by formula VII; (7) 0% of a compound represented by the general formula VIII; (8) 0-15% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X;

or the like, or, alternatively,

(1) 0-35% of a compound represented by formula II; (2) 15-55% of a compound represented by formula III; (3) 0% of a compound represented by the general formula IV; (4) 0% of a compound represented by the general formula V; (5) 0% of a compound represented by formula VI; (6) 25-60% of a compound represented by formula VII; (7) 0-25% of a compound represented by formula VIII; (8) 0% of a compound represented by formula IX; (9) 0% of a compound represented by the general formula X.

Preferably, the liquid crystal composition of the present invention is composed of the compound represented by the general formula I and the liquid crystal base system.

Any of the liquid crystal base systems described above in the present invention can refer to the same concept.

The method for producing the liquid crystal composition of the present invention is not particularly limited, and a production can be carried out by mixing a plurality of compounds by a conventional method such as a method of mixing different components at a high temperature and dissolving each other, in which a liquid crystal composition is dissolved and mixed in a solvent for the compound, and then the solvent is distilled off under reduced pressure; alternatively, the liquid crystal composition of the present invention can be prepared by a conventional method, for example, by dissolving the component having a smaller content in the main component having a larger content at a higher temperature, or by dissolving each of the components in an organic solvent, for example, acetone, chloroform or methanol, and then mixing the solutions to remove the solvent.

The liquid crystal composition provided by the invention has a fast reaction speed, can shorten the time for polymerizing the polymerizable compound, greatly shortens the time required by the polymerization process of the liquid crystal display, improves the yield of the liquid crystal display, shortens the exposure time of the liquid crystal display in the environment and improves the quality and performance of the liquid crystal display. Therefore, the invention also provides the application of the liquid crystal composition in PSVA and SAVA display mode liquid crystal display devices; the method is particularly suitable for PSVA liquid crystal display devices.

The method for preparing the liquid crystal device by adopting the liquid crystal composition provided by the invention specifically comprises the following steps: the liquid crystal composition containing the polymerizable compound provided by the invention is poured into a liquid crystal screen, and then polymerized by UV light irradiation, and voltage is continuously applied in the irradiation process. The polymerizable compound in the liquid crystal composition is polymerized under the irradiation of UV light, so that the liquid crystal is promoted to form stable alignment. In order to fully polymerize the monomers, the voltage was removed after a period of time following which the voltage was continued to be applied and irradiated with UV light. As a preferred embodiment of the present invention, UV (313nm, 5 mw/cm) may be used²) Irradiating the liquid crystal composition for 60s under a voltage of 10V, removing the voltage, and further UV (365nm, 6 mw/cm)²) Irradiating with light for 60 min.

Detailed Description

The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.

In the present invention, the percentages are by weight, the temperature is given in degrees Celsius, △ n represents the optical anisotropy (25 ℃), △ ε represents the dielectric anisotropy, unless otherwise stated(25℃，1000Hz)；V₁₀Represents a threshold voltage, which is a characteristic voltage (V, 25 ℃) at which the relative transmittance changes by 10%; γ 1 represents rotational viscosity (mpa.s, 25 ℃); cp represents the clearing point (. degree. C.) of the liquid crystal composition; k₁₁、K₂₂、K₃₃Respectively represent the splay, twist and bend elastic constants (pN, 25 ℃); VHR represents the voltage holding ratio (%, 60 ℃, 1V, 0.5 Hz).

In the following examples, the group structures in the liquid crystal compounds are represented by codes shown in Table 1.

Table 1: radical structure code of liquid crystal compound

Take the following compound structure as an example:

expressed as: 3PWO2

Expressed as: 3PGIWO2

In the following examples, the liquid crystal composition was prepared by a thermal dissolution method, comprising the steps of: weighing the liquid crystal compound by a balance according to the weight percentage, wherein the weighing and adding sequence has no specific requirements, generally weighing and mixing the liquid crystal compound in sequence from high melting point to low melting point, heating and stirring at 60-100 ℃ to uniformly melt all the components, filtering, performing rotary evaporation, and finally packaging to obtain the target sample.

The preparation method of the liquid crystal display device comprises the steps of injecting a liquid crystal composition containing a polymerizable compound into a glass interlayer with an electrode, polymerizing the polymerizable compound under the irradiation of UV light of 300-320 nm under the application of voltage to form a stable pretilt angle, removing the voltage, and completely reacting the residual polymerizable compound under the irradiation of UV light of 320-400 nm.

In the following examples, the weight percentages of the components in the liquid crystal composition and the performance parameters of the liquid crystal composition are shown in the following tables.

Example 1

Table 2: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.3 percent by mass of polymerizable compounds with the following structures into the nematic liquid crystal composition:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.3 °.

Example 2

Table 3: the weight percentage and performance parameters of each component in the liquid crystal composition

filling the prepared PSVA mixtureInto a standard VA test cell using UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.5 °.

Example 3

Table 4: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.1 °.

Example 4

Table 5: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.5 °.

Example 5

Table 6: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.4 °.

Example 6

Table 7: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 7

Table 8: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 8

Table 9: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 9

Table 10: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 10

Table 11: the weight percentage and performance parameters of each component in the liquid crystal composition

filling the prepared PSVA mixture into a standard VA test boxUsing UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.2 °.

Example 11

Table 12: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 12

Table 13: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 13

Table 14: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 14

Table 15: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under voltage of 10V, and removing voltageIn the presence of UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.3 °.

Example 15

Table 16: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 16

Table 17: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min with light to fully react residual polymerizable compound, and testing liquid crystal in the test boxThe pretilt angle in (1) is 88.0 deg.

Example 17

Table 18: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 18

Table 19: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating with light for 60min to sufficiently remove residual polymerizable compoundThe reaction was complete and the pretilt angle of the test liquid crystal in the test cell was 87.8 °.

Example 19

Table 20: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 20

Table 21: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Light irradiation 60min, the residual polymerizable compound was fully reacted, and the pretilt angle of the test liquid crystal in the test cell was 88.3 °.

Example 21

Table 22: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.2 °.

Example 22

Table 23: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 23

Table 24: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.6 °.

Example 24

Table 25: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 25

Table 26: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 26

Table 27: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.0 °.

Example 27

Table 28: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 28

Table 29: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 29

Table 30: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 30

Table 31: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 31

Table 32: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 32

Table 33: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted to completion by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.9 °.

Example 33

Table 34: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 34

Table 35: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted to completion by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.6 °.

Example 35

Table 36: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.5 °.

Example 36

Table 37: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted to completion by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.4 °.

Example 37

Table 38: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 38

Table 39: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 39

Table 40: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 40

Table 41: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.3 °.

EXAMPLE 41

Table 42: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 42

Table 43: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 43

Table 44: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 44

Table 45: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 45

Table 46: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.8 °.

Example 46

Table 47: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 47

Table 48: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 48

Table 49: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 49

Table 50: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 50

Table 51: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 51

Table 52: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 52

Table 53: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 53

Table 54: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 54

Table 55: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 55

Table 56: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 56

Table 57: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.2 °.

Example 57

Table 58: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 58

Table 59: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 59

Table 60: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 60

Table 61: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 61

Table 62: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 62

Table 63: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 63

Table 64: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 64

Table 65: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 65

Table 66: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 66

Table 67: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 67

Table 68: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 68

Table 69: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 69

Table 70: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 70

Table 71: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 71

Table 72: the weight percentage and performance parameters of each component in the liquid crystal composition

the formulated PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw)/cm²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.2 °.

Example 72

Table 73: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 73

Table 74: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating with light for 60min, and chargingThe residual polymerizable compound was completely reacted and the pretilt angle of the test liquid crystal in the test cell was 88.0 °.

Example 74

Table 75: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 75

Table 76: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 76

Table 77: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 77

Table 78: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 78

Table 79: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 79

Table 80: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 80

Table 81: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 81

Table 82: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 82

Table 83: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 83

Table 84: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 84

Table 85: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 85

Table 86: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 86

Table 87: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 87

Table 88: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 88

Table 89: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 89

Table 90: the weight percentage and performance parameters of each component in the liquid crystal composition

The nematic liquid crystal composition is added with the following polymerizable compounds in the mass percentage of 0.3 percent:

Example 90

Table 91: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 91

Table 92: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 92

Table 93: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 93

Table 94: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.3 percent by mass of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

Example 94

Table 95: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.25 mass percent of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

Example 95

Table 96: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.35 percent by mass of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 86.5 °.

Example 96

Table 97: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.4 percent by mass of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 86.0 °.

Example 97

Table 98: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 98

Table 99: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 99

Table 100: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating with light for 60min to completely react residual polymerizable compound, and measuringThe pretilt angle of the test liquid crystal in the test cell was 88.3 °.

Example 100

Table 101: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 101

Table 102: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 102

Table 103: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 103

Table 104: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.28 mass percent of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) In the application ofIrradiating at 10V for 40s, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted to completion by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.6 °.

Example 104

Table 105: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.29 percent by mass of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min to fully react residual polymerizable compounds, and testing the pretilt angle of the liquid crystal in a test box to be 88.2 °

Example 105

Table 106: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.30 mass percent of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Light irradiationAfter 60min, the residual polymerizable compound is fully reacted, and the pretilt angle of the test liquid crystal in the test box is 87.2 DEG

Example 106

Table 107: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min to fully react residual polymerizable compounds, and testing the pretilt angle of the liquid crystal in a test box to be 87.6 °

Example 107

Table 108: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min by light, fully reacting residual polymerizable compounds, and testing the pretilt angle of the liquid crystal in the test box to be87.0°

Example 108

Table 109: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min to fully react residual polymerizable compounds, and testing the pretilt angle of the liquid crystal in a test box to be 87.8 °

Example 109

Table 110: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.33 percent by mass of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating with light for 60min to fully polymerize the residueThe compound is completely reacted, and the pretilt angle of the tested liquid crystal in the test box is 87.2 DEG

Example 110

Table 111: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min to fully react residual polymerizable compounds, and testing the pretilt angle of the liquid crystal in a test box to be 87.0 °

Example 111

Table 112: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.36 mass percent of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

Example 112

Table 113: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 113

Table 114: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating with light for 60min to fully react residual polymerizable compoundCompletely, the pretilt angle of the test liquid crystal in the test cell was 87.3 °.

Example 114

Table 115: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 115

Table 116: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 116

Table 117: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 117

Table 118: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 118

Table 119: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.32 mass percent of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

Example 119

Table 120: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 87.0 °.

Example 120

Table 121: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 121

Table 122: the weight percentage and performance parameters of each component in the liquid crystal composition

Adding 0.31 percent by mass of the following polymerizable compounds selected from the structures of the general formula I into the nematic liquid crystal composition:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min to fully react residual polymerizable compounds, and testing the pretilt angle of the liquid crystal in a test box to be 87.1 °

Example 122

Table 123: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 123

Table 124: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 124

Table 125: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min to fully react residual polymerizable compounds, and testing the pretilt angle of the liquid crystal in a test box to be 87.4 °

Example 125

Table 126: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 126

Table 127: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 127

Table 128: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 128

Table 129: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 129

Table 130: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) Irradiating for 60min by light, fully reacting residual polymerizable compounds, and testing the pretilt angle of the liquid crystal in the test box to be 87.8°。

Example 130

Table 131: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 131

Table 132: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 132

Table 133: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.8 °.

Example 133

Table 134: the weight percentage and performance parameters of each component in the liquid crystal composition

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 40s under a voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 60min, and the pretilt angle of the test liquid crystal in the test cell was 88.7 °.

Example 134

Table 135: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 135

Table 136: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 136

Table 137: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 137

Table 138: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 138

Table 139: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 139

Table 140: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 140

Table 141: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 141

Table 142: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 142

Table 1433: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 143

Table 144: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 144

Table 145: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 145

Table 146: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 146

Table 147: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 147

Table 148: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 148

Table 149: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 149

Table 150: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 150

Table 151: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 151

Example 152

Table 153: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 153

Table 154: the weight percentage and performance parameters of each component in the liquid crystal composition

Example 154

Table 155: the weight percentage and performance parameters of each component in the liquid crystal composition

Comparative example 1:

this comparative example differs from example 1 in that the polymerizable compound added in example 1 was replaced with a polymerizable compound of the following structure:

the prepared PSVA mixture was filled into a standard VA test cell and UV (313nm, 4 mw/cm)²) Irradiating for 120s under the voltage of 10V, removing the voltage, and irradiating with UV (365nm, 5 mw/cm)²) The residual polymerizable compound was sufficiently reacted completely by irradiating light for 100min, and the pretilt angle of the test liquid crystal in the test cell was 88.6 °. Comparing example 1 with comparative example 1, the polymerizable compound provided by the present invention has a faster polymerization speed, can rapidly react, promotes the rapid alignment of liquid crystal molecules, greatly reduces the time required for the production of liquid crystal displays, and improves the production efficiency.

From the above embodiments, the liquid crystal composition provided by the present invention can rapidly reach a stable alignment state under UV light irradiation, and the production efficiency is improved.

Although the invention has been described in detail hereinabove with respect to a general description and specific embodiments thereof, it will be apparent to those skilled in the art that modifications and improvements can be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims

1. a liquid crystal composition, is characterized in that, comprises one or more polymerizable compounds as shown in general formula I;

The Ring A ₁ and Ring A ₂ each independently represent 1,4-phenylene, 1,4-cyclohexylene, 1,4-cyclohexenylene, or 1 to 4 hydrogen atoms are each independently 1,4-phenylene substituted with F or Cl;

The P ₁ , P ₂ and P ₃ each independently represent an acrylate group, a methacrylate group, a fluoroacrylate group, a chloroacrylate group, a vinyloxy group, an oxetanyl group or an epoxy group ;

Said Z ₁ and Z ₄ each independently represent a single bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH=N _- , -N=CH-, -N=N-, -C≡C-, C1-C12 alkylene or alkenyl, wherein said _C1 -C12 alkylene or C2 _- C12 _alkylene One or more hydrogen atoms in the alkenyl group may each independently be replaced by F, Cl, or CN, and one or more non-adjacent -CH2- groups may each independently be replaced by -O-, -S-, -NH-, -CO-, COO-, -OCO-, -OCOO-, -SCO-, -COS- or olefinic bonds are replaced in a way that they are not directly connected to each other;

The Z ₂ and Z ₃ each independently represent a single bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH=N -, -N=CH-, -N=N-, -C≡C-, C ₁ -C ₁₂ alkylene or alkenyl, one of the C ₁ -C ₁₂ alkylene or alkenyl or more hydrogen atoms can each independently be replaced by F, Cl, or CN, and one or more non-adjacent _-CH2- groups can each independently be replaced by -O-, -S-, -NH-, -CO-, COO-, -OCO-, -OCOO-, -SCO- or -COS- are replaced in a way that is not directly connected to each other;

L ₁ and L ₂ independently represent -F, -Cl, -CN, -NO2, -CH3, -C2H5, -C(CH3)3, -CH(CH3)2, -CH2CH(CH3)C2H5, -OCH3 , -OC2H5, -COCH3, -COC2H5, -COOCH3, -COOC2H5, -CF3, -OCF3, -OCHF2 or -OC2F5;

r and s independently represent 0, 1, 2 or 3; m and n independently represent 0 or 1;

Preferably, the liquid crystal composition further includes a liquid crystal base system, and the amount of the polymerizable compound represented by the general formula I accounts for 0.1-5% of the total mass of the liquid crystal base system, more preferably 0.2-0.5%.

2 . The liquid crystal composition according to claim 1 , wherein the liquid crystal composition further comprises a liquid crystal base system, and the liquid crystal base system further comprises one or more selected from the group consisting of general formula II to general formula V 2 . Compounds represented:

Wherein, R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ , and R ₈ each independently represent a C ₁ -C ₁₂ straight-chain alkyl group, a straight-chain alkoxy group or a C ₂ -C The straight-chain alkenyl of ₁₂ ; Z ₅ and Z ₆ each independently represent -CH ₂ O, -CH ₂ CH ₂ ; A ₃ and A ₄ each independently represent trans-1,4-cyclohexyl or 1,4-idene phenyl;

Preferably, R ₁ , R ₂ , R ₃ , R ₄ , R ₅ , R ₆ , R ₇ , R ₈ each independently represent a C ₁ -C ₇ straight-chain alkyl group, a straight-chain alkoxy group or a C ₂ -C C ₁₂ straight-chain alkenyl;

More preferably, R ₁ , R ₃ , R ₅ , and R ₇ each independently represent a C ₁ -C ₇ straight-chain alkyl group or a C ₂ -C ₅ straight-chain alkenyl group; still more preferably, C ₁ -C ₅ straight-chain alkyl or C ₂ -C ₅ straight-chain alkenyl);

And/or, R ₂ , R ₄ , R ₆ , and R ₈ each independently represent a C ₁ -C ₇ straight-chain alkyl group or a straight-chain alkoxy group; more preferably, a C ₁ -C ₄ straight-chain alkyl group or straight-chain alkoxy.

3. The liquid crystal composition according to claim 1 or 2, wherein in the polymerizable compound represented by the general formula I:

Said ring A ₁ and ring A ₂ independently of each other represent 1,4-phenylene, 1,4-cyclohexylene or 1,4-phenylene in which 1-4 hydrogen atoms are substituted by F or Cl atoms; Preferably, the ring A ₁ and the ring A ₂ independently of each other represent 1,4-phenylene, 1,4-cyclohexylene, 2-fluoro-1,4-phenylene, 2-fluoro-1, 4-phenylene;

And/or, the P ₁ , P ₂ , P ₃ independently represent a methacrylate group or an acrylate group;

And/or, the r, s represent 0 or 1 independently of each other

And/or, the m and n independently represent 0 or 1, and m+n≤1;

And/or, the Z ₁ and Z ₄ independently represent a single bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH=N-, -N=CH-, -N=N-, -C≡C-, C ₁ -C ₁₂ alkylene or alkenyl, wherein the C ₁ -C ₁₂ alkylene or One or more hydrogen atoms in an alkenyl group can be independently replaced by F, Cl or CN, and one or more non-adjacent _-CH2- groups can be independently replaced by -O-, -S-, -NH-, -CO-, -COO-, -OCO-, -OCOO-, -SCO-, -COS- or ethylenic bonds are replaced in a way that they are not directly connected to each other; preferably, the Z ₁ and Z ₄ are each other independently represent a single bond, -O- or C ₁ -C ₅ alkylene and alkoxy;

And/or, the Z ₂ and Z ₃ independently represent a single bond or -(CH ₂ ) _k -, and k represents 1-8; preferably, k represents 1, 2, 3, 4 or 5; further, k means 1, 2 or 3;

And/or, said L ₁ , L ₂ independently represent -F, -Cl, -CN, or C ₁ -C ₃ alkyl or alkoxy; preferably, L ₁ , L ₂ are the same or different, independently represent -F, -Cl, -CN, -CH ₃ , -OCH ₃ , -CF ₃ , -OCF ₃ or -OCHF ₂ ; further, the L ₁ and L ₂ are the same or different, independently of each other Represents -F, -Cl;

and/or, m=n=0, both L ₁ and L ₂ represent -F, and r and s are independently selected from 0 or 1; or, m=1, n=0, both L ₁ and L ₂ represent - F, Ring A is selected from 1,4-phenylene, 1,4-cyclohexylene or 1,4-phenylene in which 1-2 hydrogen atoms are substituted with one or more of F or Cl atoms, r and s are independently selected from 0 or 1; or, m=0, n=1, both L ₁ and L ₂ represent -F, and ring B is selected from 1,4-phenylene, 1,4-cyclohexylene or 1,4-phenylene in which 1-2 hydrogen atoms are substituted with one or more of F or Cl atoms, r and s are independently selected from 0 or 1;

Or, the compound of general formula I is selected from one or more of general formulae I-1 to I-42:

More preferably, the polymerizable compound represented by the general formula I is selected from one or more of the following compounds:

4. The liquid crystal composition according to any one of claims 2-3, wherein, in the liquid crystal base system, the compound of formula II is selected from one or more of formula IIA and formula IIB :

Wherein, R ₁ represents a C ₁ -C ₇ straight-chain alkyl group or a C ₂ -C ₅ straight-chain alkenyl group; R ₂ represents a C ₁ -C ₇ straight-chain alkyl group or a straight-chain alkoxy group;

Preferably, the compound represented by the general formula II is selected from one or more of IIA1-IIB24:

More preferably, the compound represented by the general formula II is selected from one or more of IIA14, IIA16, IIA22, IIB16, IIB17, IIB24, and IIB26; particularly preferably, the compound represented by the general formula II is selected from One or more of IIA14, IIA16, IIA22, IIB16, IIB17, IIB24.

5. The liquid crystal composition according to any one of claims 2-4, wherein, in the liquid crystal base system, the compound represented by general formula III is selected from one or more of formula IIIA and formula IIIB :

Wherein, R ₃ represents C ₁ -C ₇ straight-chain alkyl or C ₂ -C ₅ straight-chain alkenyl; R ₄ represents C ₁ -C ₇ straight-chain alkyl or straight-chain alkoxy;

Preferably, the compound represented by the general formula III is selected from one or more of IIIA1-IIIB24:

More preferably, the compound represented by general formula III is selected from one or more of IIIA1, IIIA2, IIIA10, IIIA13, IIIA14, IIIA15, IIIA16, IIIA18, IIIB1, IIIB2, IIIB13, IIIB14, IIIB15, IIIB22; particularly preferred One or more of IIIA1, IIIA2, IIIA10, IIIA13, IIIA14, IIIA15, IIIB13, IIIB14, IIIB22.

6. The liquid crystal composition according to any one of claims 2-5, wherein in the liquid crystal base system, the compound represented by the general formula IV is selected from one or more of IVA1-IVB24:

More preferably, the compound represented by general formula IV is selected from one or more of IVA10, IVA14, IVA16, IVA22, IVB14, and IVB16; particularly preferably, the compound represented by general formula IV is selected from IVA10, IVA14, IVB14 one or more of;

and / or,

In the liquid crystal base system, the compound represented by the general formula V is selected from one or more of VA1 to VB16:

More preferably, the compound represented by general formula V is selected from one or more of VA5, VA6, VA7, VA8, VB5, VB6; particularly preferably, the compound represented by general formula V is selected from VA5, VA6, VB5 , one or more of VB6.

7. The liquid crystal composition according to any one of claims 1-6, wherein the liquid crystal composition further comprises a liquid crystal base system, and the liquid crystal base system further comprises one or more selected from the formula Compounds represented by VI:

Wherein, R ₉ and R ₁₀ each independently represent a C ₁ -C ₁₂ straight-chain alkyl group, a straight-chain alkoxy group or a C ₂ -C ₁₂ straight-chain alkenyl group; n ₁ and n ₂ each independently represent 0 or 1; A ₅ represents trans 1,4-cyclohexyl, 1,4-phenylene, wherein one or more H atoms on the benzene ring can be independently substituted by F; preferably n ₁ and n ₂ are not 1 at the same time ;

Preferably, the compound represented by the general formula VI is selected from one or more of VIA～VID:

Wherein, R ₉ represents a straight-chain alkyl or straight-chain alkenyl of C ₂ -C ₇ ; R ₁₀ represents a straight-chain alkyl or straight-chain alkoxy of C ₁ -C ₅ ;

More preferably, the compound represented by general formula VI is selected from one or more of VIA1～VID16:

Further preferably, the compound represented by the general formula VI is selected from one or more of VIA6, VIA8, VIA14, VIB6, VIB7, VIB10, VIB14, VIC5, VIC6, VIC14, VID5, VID6; particularly preferably , the compound represented by the general formula VI is selected from one or more of VIB6, VIB10, VIC5, VIC6, VID5, VID6;

and / or,

The liquid crystal composition further includes a liquid crystal base system, and the liquid crystal base system further includes one or more compounds represented by the general formula VII:

Wherein, R ₁₁ and R ₁₂ each independently represent a C ₁ -C ₁₂ straight-chain alkyl group, a straight-chain alkoxy group or a C ₂ -C ₁₂ straight-chain alkenyl group; A ₆ and A ₇ each independently represent a trans 1,4-cyclohexyl or 1,4-phenylene;

Preferably, the compound represented by general formula VII is selected from one or more of VIIA～VIIC:

Wherein, R ₁₁ represents a C ₁ -C ₇ straight-chain alkyl group or a C ₂ -C ₇ straight-chain alkenyl group; R ₁₂ represents a C ₁ -C ₇ straight-chain alkyl group, a straight-chain alkoxy group or a C ₂ -C 7 straight-chain alkyl group C ₇ straight-chain alkenyl;

More preferably, the compound represented by general formula VII is selected from one or more of VIIA1～VIIC25:

More preferably, the compound represented by the general formula VII is selected from VIIA2, VIIA6, VIIA14, VIIA18, VIIA20, VIIA22, VIIA24, VIIA26, VIIA27, VIIA32, VIIA36, VIIB2, VIIB8, VIIB14, VIIB18, VIIB26, VIIC2, VIIA4, One or more of VIIC6, VIIC17, VIIC18, VIIC28, VIIC30, VIIC32, VIIC34, VIIC43, VIIC44; particularly preferably, the compound represented by the general formula VII is selected from VIIA2, VIIA6, VIIA22, VIIA26, VIIA27, VIIB14, One or more of VIIB18, VIIC4, VIIC6, VIIC18, VIIC28, VIIC32;

and / or,

The liquid crystal composition further includes a liquid crystal base system, and the liquid crystal base system may further comprise one or more compounds represented by the general formula VIII:

Wherein, R ₁₃ and R ₁₄ each independently represent a C ₁ -C ₁₂ straight-chain alkyl group, a straight-chain alkoxy group or a C ₂ -C ₁₂ straight-chain alkenyl group; A ₈ represents a trans-1,4-cyclohexyl group or 1,4-phenylene;

Preferably, the compound represented by the general formula VIII is selected from one or more of VIIIA-VIIIB:

Wherein, R ₁₃ represents a C ₂ -C ₇ straight-chain alkyl or straight-chain alkenyl; R ₁₄ represents a C ₁ -C ₇ straight-chain alkyl, straight-chain alkoxy or C ₂ -C ₇ straight-chain alkene base;

More preferably, the compound represented by the general formula VIII is selected from one or more of VIIIA1 to VIIIB24:

More preferably, the compound represented by the general formula VIII is selected from one or Multiple; particularly preferably, the compound represented by the general formula VIII is selected from one or more of VIIIA2, VIIIA6, VIIIA17, VIIIA25, VIIIA37, VIIIB2, VIIIB6, VIIIB8, and VIIIB50.

8. The liquid crystal composition according to any one of claims 1-7, characterized in that, the liquid crystal composition further comprises a liquid crystal base system, and the liquid crystal base system further comprises one or more general formula IX. Representative compounds:

Wherein, R ₁₅ represents a linear alkyl group of C ₁ -C ₁₂ , a linear alkoxy group or a linear alkenyl group of C ₂ -C ₁₂ ; R ₁₆ represents F, a linear alkyl group of C ₁ -C ₁₂ , a linear Alkoxy or C ₂ -C ₁₂ straight-chain alkenyl; L ₃ , L ₅ , L ₆ each independently represent H or F; L ₄ represents H, CH ₃ or F; preferably, L ₃ , L ₄ , L ₅ , L ₆ are not H at the same time; or are not F at the same time;

More preferably, the compound represented by general formula IX is selected from one or more of IXA-IXF:

Wherein, R ₁₅ represents a C ₁ -C ₇ straight-chain alkyl group; R ₁₆ represents F, a C ₁ -C ₇ straight-chain alkyl group or a straight-chain alkoxy group;

More preferably, the compound represented by general formula IX is selected from one or more of IXA1～IXI24:

Still further preferably, the compound represented by general formula IX is selected from IXA2, IXA3, IXA4, IXA8, IXB1, IXB2, IXC1, IXC2, IXD1, IXD2, IXE2, IXE3, IXF1, IXG2, IXH2, IXI2, IXI14, IXI21, One or more of IXI22; particularly preferably, the compound represented by general formula IX is selected from one or more of IXA2, IXA3, IXE2, IXE3, IXG2, IXH2, IXI2, IXI14, IXI21;

and / or,

The liquid crystal composition further includes a liquid crystal base system, and the liquid crystal base system further includes one or more compounds represented by the general formula X:

Wherein, R ₁₇ and R ₁₈ each independently represent a C ₁ -C ₁₂ straight-chain alkyl group, a straight-chain alkoxy group, a C ₂ -C ₁₂ straight-chain alkenyl group, a cyclopropyl methylene group, and a cyclopropyl methylene oxide group. group, cyclopentyl, cyclopentylmethylene, cyclopentyloxy or cyclopentylmethyleneoxy; L ₇ represents O or S;

Preferably, the compound represented by the general formula X is selected from one or more of XA～XF:

wherein, R ₁₇ represents a straight-chain alkyl or straight-chain alkoxy group of C ₁ -C ₇ ;

More preferably, the compound represented by the general formula X is selected from one or more of XA1-XI4:

Further preferably, the compound represented by the general formula X is selected from the group consisting of XA36, XA37, XA38, XB9, XB10, XC9, XC10, XD9, XD10, XE36, XE37, XE38, XF9, XF10, XG9, XG10, XH9, XH10 One or more; particularly preferably, the compound represented by the general formula X is selected from XA37, XA38, XB9, XB10, XC9, XC10, XD9, XD10, XE37, XE38, XF9, XF10, XG9, XG10, XH9, XH10 one or more of.

9 . The liquid crystal composition according to claim 1 , wherein the liquid crystal composition further comprises a liquid crystal base system, and the liquid crystal base system comprises the following components by mass percentage: 10 .

(1) 10-75% of compounds represented by general formula II to general formula V;

(2) 0～45% of the compound represented by the general formula VI;

(3) 1-70% of the compound represented by the general formula VII;

(4) 0～30% of the compound represented by the general formula VIII;

(5) 0～40% of the compound represented by the general formula IX;

(6) 0～40% of the compound represented by the general formula X;

The amount of the polymerizable compound represented by the general formula I accounts for 0.1-5% of the total mass of the liquid crystal base system;

Preferably, the liquid crystal base system comprises the following components in mass percentage:

(1) 15-70% of compounds represented by general formula II to general formula V;

(2) 0～35% of the compound represented by the general formula VI;

(3) 4-65% of the compound represented by the general formula VII;

(4) 0～25% of the compound represented by the general formula VIII;

(5) 0～30% of the compound represented by the general formula IX;

(6) 0～30% of the compound represented by the general formula X;

The amount of the polymerizable compound represented by the general formula I accounts for 0.2-1.0% of the total mass of the liquid crystal base system;

More preferably, the liquid crystal base system comprises the following components in mass percentage:

(1) 22-65% of compounds represented by general formula II to general formula V;

(2) 0～29% of the compound represented by the general formula VI;

(3) 6-58% of the compound represented by the general formula VII;

(4) 0～21% of the compound represented by the general formula VIII;

(5) 0～25% of the compound represented by the general formula IX;

(6) 0～25% of the compound represented by the general formula X;

The amount of the polymerizable compound represented by the general formula I accounts for 0.2-0.5% of the total mass of the liquid crystal base system;

Or, preferably, the liquid crystal base system comprises the following components in mass percentage:

(1) 25-65% of compounds represented by general formula III to general formula V;

(2) 0～35% of the compound represented by the general formula VI;

(3) 4-55% of the compound represented by the general formula VII;

(4) 0～20% of the compound represented by the general formula VIII;

(5) 0～10% of the compound represented by the general formula IX;

(6) 0～30% of the compound represented by the general formula X;

(1) 32-58% of compounds represented by general formula II to general formula V;

(2) 0～29% of the compound represented by the general formula VI;

(3) 6-53% of the compound represented by the general formula VII;

(4) 0-15% of the compound represented by the general formula VIII;

(5) 0～5% of the compound represented by the general formula IX;

(6) 0～25% of the compound represented by the general formula X;

(1) 1-36% of the compound represented by the general formula II;

(2) 5-60% of compounds represented by general formulas III-V;

(3) 0～20% of the compound represented by the general formula VI;

(4) 21-63% of the compound represented by the general formula VII;

(5) 0～25% of the compound represented by the general formula VIII;

(6) 0～30% of the compound represented by the general formula IX;

(7) 0～30% of the compound represented by the general formula X;

(1) 2-33% of the compound represented by the general formula II;

(2) 10-56% of compounds represented by general formulas III-V;

(3) 0～16% of the compound represented by the general formula VI;

(4) 26-58% of the compound represented by the general formula VII;

(5) 0～21% of the compound represented by the general formula VIII;

(6) 0～25% of the compound represented by the general formula IX;

(7) 0～25% of the compound represented by the general formula X;

(1) 0～10% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 3-20% of the compound represented by the general formula IV;

(4) 0～26% of the compound represented by the general formula V;

(5) 25-56% of the compound represented by the general formula VII;

(6) 0-20% of the compound represented by the general formula VIII;

(7) 0～10% of the compound represented by the general formula IX;

(8) 0～10% of the compound represented by the general formula X;

(1) 0-6% of the compound represented by the general formula II;

(2) 14-51% of the compound represented by the general formula III;

(3) 4-16% of the compound represented by the general formula IV;

(4) 0～23% of the compound represented by the general formula V;

(5) 30-53% of the compound represented by the general formula VII;

(6) 0-15% of the compound represented by the general formula VIII;

(7) 0～5% of the compound represented by the general formula IX;

(8) 0～5% of the compound represented by the general formula X;

(1) 0～10% of the compound represented by the general formula II;

(2) 20-55% of the compound represented by the general formula III;

(3) 3-20% of the compound represented by the general formula IV;

(4) 35-56% of the compound represented by the general formula VII;

(5) 0～20% of the compound represented by the general formula VIII;

(6) 0～7% of the compound represented by the general formula X;

(1) 0-6% of the compound represented by the general formula II;

(2) 24-51% of the compound represented by the general formula III;

(3) 4-16% of the compound represented by the general formula IV;

(4) 40-53% of the compound represented by the general formula VII;

(5) 0-15% of the compound represented by the general formula VIII;

(6) 0～4% of the compound represented by the general formula X;

(1) 10-42% of the compound represented by the general formula III;

(2) 5-18% of the compound represented by the general formula IV;

(3) 3-26% of the compound represented by the general formula V;

(4) 25-55% of the compound represented by the general formula VII;

(5) 0-15% of the compound represented by the general formula VIII;

(6) 0～10% of the compound represented by the general formula IX;

(7) 0-10% of the compound represented by the general formula X;

(1) 14-37% of the compound represented by the general formula III;

(2) 8-14% of the compound represented by the general formula IV;

(3) 5-23% of the compound represented by the general formula V;

(4) 30-50% of the compound represented by the general formula VII;

(5) 0～11% of the compound represented by the general formula VIII;

(6) 0～5% of the compound represented by the general formula IX;

(7) 0～5% of the compound represented by the general formula X;

(1) 1-38% of the compound represented by the general formula II;

(2) 5-45% of the compound represented by the general formula III;

(3) 20-65% of the compound represented by the general formula VII;

(4) 0～25% of the compound represented by the general formula VIII;

(5) 0～30% of the compound represented by the general formula IX;

(6) 0～30% of the compound represented by the general formula X;

(1) 2-33% of the compound represented by the general formula II;

(2) 10-39% of the compound represented by the general formula III;

(3) 26-58% of the compound represented by the general formula VII;

(4) 0～21% of the compound represented by the general formula VIII;

(5) 0～25% of the compound represented by the general formula IX;

(6) 0～25% of the compound represented by the general formula X;

(1) 17-55% of compounds represented by general formula II to general formula V;

(2) 3-33% of the compound represented by the general formula VI;

(3) 4-65% of the compound represented by the general formula VII;

(4) 0-15% of the compound represented by the general formula VIII;

(5) 0～30% of the compound represented by the general formula IX;

(6) 0～30% of the compound represented by the general formula X;

(1) 22-51% of compounds represented by general formula II to general formula V;

(2) 4-29% of the compound represented by the general formula VI;

(3) 6-58% of the compound represented by the general formula VII;

(4) 0～12% of the compound represented by the general formula VIII;

(5) 0～25% of the compound represented by the general formula IX;

(6) 0～25% of the compound represented by the general formula X;

(1) 27-70% of compounds represented by general formula II to general formula V;

(2) 21-65% of the compound represented by the general formula VII;

(3) 0～25% of the compound represented by the general formula VIII;

(4) 0～20% of the compound represented by the general formula IX;

(5) 0～30% of the compound represented by the general formula X;

(1) 32-65% of compounds represented by general formula II to general formula V;

(2) 26-58% of the compound represented by the general formula VII;

(3) 0～21% of the compound represented by the general formula VIII;

(4) 0～15% of the compound represented by the general formula IX;

(5) 0～25% of the compound represented by the general formula X;

(1) 18-70% of compounds represented by general formula II to general formula V;

(2) 0～35% of the compound represented by the general formula VI;

(3) 3-63% of the compound represented by the general formula VII;

(4) 0～30% of the compound represented by the general formula IX;

(5) 0～30% of the compound represented by the general formula X;

(1) 22-65% of compounds represented by general formula II to general formula V;

(2) 0～29% of the compound represented by the general formula VI;

(3) 6-58% of the compound represented by the general formula VII;

(4) 0～25% of the compound represented by the general formula IX;

(5) 0～25% of the compound represented by the general formula X;

(1) 27-59% of compounds represented by general formula II to general formula V;

(2) 0～18% of the compound represented by the general formula VI;

(3) 21-55% of the compound represented by the general formula VII;

(4) 1-25% of the compound represented by the general formula VIII;

(5) 0-18% of the compound represented by the general formula IX;

(6) 0～30% of the compound represented by the general formula X;

(1) 32-59% of compounds represented by general formula II to general formula V;

(2) 0～14% of the compound represented by the general formula VI;

(3) 26-51% of the compound represented by the general formula VII;

(4) 2-21% of the compound represented by the general formula VIII;

(5) 0～14% of the compound represented by the general formula IX;

(6) 0～25% of the compound represented by the general formula X;

(1) 27-70% of compounds represented by general formula II to general formula V;

(2) 0～33% of the compound represented by the general formula VI;

(3) 3-65% of the compound represented by the general formula VII;

(4) 0～25% of the compound represented by the general formula VIII;

(6) 0～30% of the compound represented by the general formula X;

(1) 32-65% of compounds represented by general formula II to general formula V;

(2) 0～29% of the compound represented by the general formula VI;

(3) 6-58% of the compound represented by the general formula VII;

(4) 0～21% of the compound represented by the general formula VIII;

(6) 0～25% of the compound represented by the general formula X;

(1) 18-65% of compounds represented by general formula II to general formula V;

(2) 0～20% of the compound represented by the general formula VI;

(3) 21-65% of the compound represented by the general formula VII;

(4) 0～25% of the compound represented by the general formula VIII;

(5) 1-30% of the compound represented by the general formula IX;

(6) 0-18% of the compound represented by the general formula X;

(1) 22-60% of compounds represented by general formula II to general formula V;

(2) 0～16% of the compound represented by the general formula VI;

(3) 26-58% of the compound represented by the general formula VII;

(4) 0～21% of the compound represented by the general formula VIII;

(5) 2-25% of the compound represented by the general formula IX;

(6) 0-14% of the compound represented by the general formula X;

(1) 27-70% of compounds represented by general formula II to general formula V;

(2) 0～18% of the compound represented by the general formula VI;

(3) 21-63% of the compound represented by the general formula VII;

(4) 0～25% of the compound represented by the general formula VIII;

(5) 0-18% of the compound represented by the general formula IX;

(1) 33-65% of compounds represented by general formula II to general formula V;

(2) 0～14% of the compound represented by the general formula VI;

(3) 26-58% of the compound represented by the general formula VII;

(4) 0～21% of the compound represented by the general formula VIII;

(5) 0～14% of the compound represented by the general formula IX;

(1) 18-55% of compounds represented by general formula II to general formula V;

(2) 0～33% of the compound represented by the general formula VI;

(3) 5-55% of the compound represented by the general formula VII;

(4) 0-18% of the compound represented by the general formula VIII;

(5) 0～30% of the compound represented by the general formula IX;

(6) 1-30% of the compound represented by the general formula X;

(1) 22-53% of compounds represented by general formula II to general formula V;

(2) 0～29% of the compound represented by the general formula VI;

(3) 6-50% of the compound represented by the general formula VII;

(4) 0-14% of the compound represented by the general formula VIII;

(5) 0～25% of the compound represented by the general formula IX;

(6) 2-25% of the compound represented by the general formula X;

or,

Preferably, in the liquid crystal base system:

When the consumption of the compound represented by the general formula II is 0, and the consumption of the compound represented by the general formula IV or the general formula V or the general formula VIII is 0, the consumption of the compound represented by the general formula IX is also 0;

Or, the consumption of the compound represented by general formula II and general formula VII is not 0 at the same time;

Or, when the dosage of the compound represented by the general formula II and the general formula X is 0, the dosage of the compound represented by the general formula VI is also 0;

Or, when the consumption of the compound represented by the general formula III and the general formula IV is 0, the consumption of the compound represented by the general formula IX is also 0;

Or, the dosage of the compound represented by the general formula III and the dosage of the compound represented by any one of the general formula V, the general formula VII, the general formula VIII, the general formula IX or the general formula X is 0 at the same time;

Or, when the dosage of the compound represented by the general formula III and the general formula VI is 0, the dosage of the compound represented by the general formula II, IV, V, VII, VIII, IX, X is not 0;

Or, the compound dosages represented by general formula IV and general formula VII are not 0 at the same time;

Or, when the dosage of the compound represented by the general formula IV and the general formula VIII is 0, the dosage of the compound represented by the general formula V is also 0;

Or, when the consumption of the compound represented by general formula IV and general formula X is 0, the consumption of the compound represented by general formula IV is also 0;

Or, the consumption of the compound represented by general formula V and general formula VII is not 0 at the same time;

Or, the consumption of the compound represented by general formula VI and general formula VII is not 0 at the same time;

Or, the amount of the compound represented by any one of the general formula VII and the general formula VIII, the general formula IX or the general formula X is not 0 at the same time;

More preferably, the liquid crystal base system includes compounds represented by general formula II to general formula X, including:

(1) 8-15% of the compound represented by the general formula II;

(2) 0% of the compound represented by the general formula III;

(3) 5-10% of the compound represented by the general formula IV;

(4) 20-25% of the compound represented by general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 30-35% of the compound represented by the general formula VII;

(7) 10-15% of the compound represented by the general formula VIII;

(8) 5-10% of the compound represented by the general formula IX;

(9) 5-8% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 35-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-50% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0-20% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-50% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-15% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 40-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 25-30% of the compound represented by the general formula VI;

(6) 5-50% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0-20% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-50% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 50-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-50% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 20-55% of the compound represented by the general formula III;

(3) 0-20% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-5% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 35-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 20-55% of the compound represented by the general formula III;

(3) 0-20% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 1-55% of the compound represented by the general formula III;

(3) 2-20% of the compound represented by the general formula IV;

(4) 3-5% of the compound represented by general formula V;

(5) 3-5% of the compound represented by the general formula VI;

(6) 5-55% of the compound represented by the general formula VII;

(7) 5-15% of the compound represented by the general formula VIII;

(8) 5-10% of the compound represented by the general formula IX;

(9) 5-10% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-20% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 12-55% of the compound represented by the general formula III;

(3) 0-20% of the compound represented by the general formula IV;

(4) 0-23% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 30-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-15% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 14-55% of the compound represented by the general formula III;

(3) 0-20% of the compound represented by the general formula IV;

(4) 0-25% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 30-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0-5% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-25% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 30-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 5-10% of the compound represented by the general formula II;

(2) 0% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 25-35% of the compound represented by general formula V;

(5) 5-10% of the compound represented by the general formula VI;

(6) 30-35% of the compound represented by the general formula VII;

(7) 5-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 5-15% of the compound represented by the general formula X;

or,

(1) 0-33% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-25% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-15% of the compound represented by general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0-20% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-22% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-28% of the compound represented by the general formula II;

(2) 30-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-28% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-5% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-33% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-10% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-28% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 30-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0-5% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0-20% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 30-55% of the compound represented by the general formula III;

(3) 0-20% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-5% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-10% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-5% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-25% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-25% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0-5% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

Further preferably, the liquid crystal base system comprises the following components in mass percentage:

(1) 0% of the compound represented by the general formula II;

(2) 50-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 45-50% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 40-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-50% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 50-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 45-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 35-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 20-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-5% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 20-55% of the compound represented by the general formula III;

(3) 0-28% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 35-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 35-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 20-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-18% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-25% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 30-55% of the compound represented by the general formula VII;

(7) 0-15% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 30-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0-5% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 00% compound represented by general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 10-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 30-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-30% of the compound represented by the general formula VI;

(6) 5-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-25% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-5% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-10% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 30-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 0% of the compound represented by the general formula VII;

(7) 35-60% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-5% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 30-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0-5% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-45% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0-15% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

Still further preferably, the liquid crystal base system comprises the following components by mass percentage:

(1) 0% of the compound represented by the general formula II;

(2) 35-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0% of the compound represented by the general formula II;

(2) 20-55% of the compound represented by the general formula III;

(3) 0-18% of the compound represented by the general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 40-55% of the compound represented by the general formula VII;

(7) 0-18% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 30-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0-5% of the compound represented by the general formula X;

or,

(1) 0-30% of the compound represented by the general formula II;

(2) 25-55% of the compound represented by the general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 35-60% of the compound represented by the general formula VII;

(7) 0% of the compound represented by the general formula VIII;

(8) 0-15% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X;

or,

(1) 0-35% of the compound represented by the general formula II;

(2) 15-55% of the compound represented by general formula III;

(3) 0% compound represented by general formula IV;

(4) 0% of the compound represented by the general formula V;

(5) 0% of the compound represented by the general formula VI;

(6) 25-60% of the compound represented by the general formula VII;

(7) 0-25% of the compound represented by the general formula VIII;

(8) 0% of the compound represented by the general formula IX;

(9) 0% of the compound represented by the general formula X.

10. The application of the liquid crystal composition according to any one of claims 1 to 9 for liquid crystal display devices; preferably, the display devices are PSVA, SAVA; more preferably, PSVA.