CN110919821A - Preparation method of ceramic tile with three-dimensional texture - Google Patents
Preparation method of ceramic tile with three-dimensional texture Download PDFInfo
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- CN110919821A CN110919821A CN201911148813.4A CN201911148813A CN110919821A CN 110919821 A CN110919821 A CN 110919821A CN 201911148813 A CN201911148813 A CN 201911148813A CN 110919821 A CN110919821 A CN 110919821A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 67
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 77
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000011449 brick Substances 0.000 claims abstract description 25
- 239000008187 granular material Substances 0.000 claims abstract description 24
- 238000001035 drying Methods 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 238000007641 inkjet printing Methods 0.000 claims abstract description 18
- 230000008569 process Effects 0.000 claims abstract description 16
- 238000005498 polishing Methods 0.000 claims abstract description 12
- 239000004744 fabric Substances 0.000 claims abstract description 11
- 238000003825 pressing Methods 0.000 claims abstract description 10
- 238000010009 beating Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000012780 transparent material Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000003892 spreading Methods 0.000 claims description 2
- 230000007480 spreading Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 29
- 238000010304 firing Methods 0.000 abstract description 10
- 238000011161 development Methods 0.000 abstract description 5
- 238000007639 printing Methods 0.000 abstract description 5
- 239000004579 marble Substances 0.000 abstract description 3
- 238000009776 industrial production Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 27
- 239000002245 particle Substances 0.000 description 17
- 239000000047 product Substances 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 8
- 239000004575 stone Substances 0.000 description 7
- 230000006872 improvement Effects 0.000 description 6
- 238000005034 decoration Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000003961 penetration enhancing agent Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
- B28B3/02—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/001—Applying decorations on shaped articles, e.g. by painting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/04—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
- B28B11/044—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers with glaze or engobe or enamel or varnish
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
- B28B11/241—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening using microwave heating means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
- B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a preparation method of a ceramic tile with three-dimensional texture, which comprises the following process steps: 1) uniformly mixing transparent granular materials and super white materials, then distributing the mixture at the bottom of a press mold core to form a mixed material layer, and then covering the mixed material layer with common ceramic brick materials until the press mold core is filled to form a base material layer; 2) adopting a reverse-beating cloth pressing and forming process to obtain a green body of the mixture under the upper common ceramic brick material; 3) and (4) polishing the green body, drying, printing by ink-jet printing, applying transparent glaze, and then firing in a kiln at high temperature to obtain a finished product. The invention leads the ink-jet printing pattern to form different color-developing effects in the areas of the transparent granular material and the super white material after the subsequent high-temperature firing, thereby leading the brick surface pattern effect of the ceramic brick to be varied and the line texture to be clear and highlighting the three-dimensional texture of the imitated natural marble. The preparation process is simple, and the surface of the green body can be directly subjected to ink-jet printing without applying overglaze, so that the color development of the printed pattern on the ultra-white material layer is natural and has no deviation, and the large-scale industrial production is facilitated.
Description
Technical Field
The invention relates to the field of building ceramic tiles, in particular to a ceramic tile with three-dimensional texture.
Background
In recent years, due to the rapid popularization of ink-jet printing technology, glazed tiles gradually replace polished tiles to occupy the mainstream of the market by virtue of rich patterns and fine textures, and from the initial full glaze polishing to the subsequent ceramic tile polishing, sinking glaze, candy glaze and the like, the products are all designed to better realize the effect of glazed tile differentiation so as to be better suitable for the market. Some ceramic manufacturers realize the three-dimensional effect of the surface of the ceramic tile by adopting certain specific processes, so that the ceramic tile looks more like natural marble, for example, a permeation enhancer is used on the surface of the ceramic tile to enable patterns to permeate into the ceramic tile to realize the three-dimensional effect, but the diffusion of the permeation enhancer can reduce the resolution of the patterns and influence the decorative effect of the ceramic tile, and a die with concave-convex effect is adopted to press the ceramic tile with concave-convex texture on the surface to realize the three-dimensional effect, the method is more complicated in the actual use process, because different concave-convex dies need to be replaced when a batch of tiles are made, the cost of an enterprise is increased, the time and labor are wasted when the die cores are frequently replaced, and the other method is to make the transparent glaze into dry particles and then realize the three-dimensional texture on the surface of the ceramic tile by adding glue and the dry particles, the concave-convex effect formed by the process is that the ceramic tile surface is not wear-resistant, is easy to wear for a long time, and may have certain antifouling problems. In addition, Chinese patent CN106863572A discloses a preparation process of a microcrystalline glass brick imitating natural stone, which comprises the steps of firstly arranging block materials wrapped with slurry layers, then filling gaps among the block materials by using a surface material, preventing a bottom material from running to the surface material layer through the gaps, preventing the bottom material from influencing the color development of the surface layer after subsequent firing, and firing the blank at the later stage by polishing a transparent frit to obtain the microcrystalline glass brick with decorative particles with larger particle sizes, wherein the boundaries of the large particles are clear, and the decorative effect is rich. However, the ceramic tile product formed by the process only forms a bulk decorative effect by the particles, cannot form line textures of natural stones, and has an unnatural decorative effect.
Disclosure of Invention
The invention aims to provide a preparation method of a ceramic tile with three-dimensional texture, aiming at the defects of the prior art, and the prepared ceramic tile can have the line texture of natural stone and has natural decorative effect.
The technical scheme adopted by the invention is as follows: a preparation method of a ceramic tile with three-dimensional texture comprises the following process steps:
1) preparing transparent materials into transparent granular materials with the grain diameter of 1-3 mm, uniformly mixing the transparent granular materials with the super white materials to obtain mixed materials, then distributing the mixed materials at the bottom of a press mold core to form a mixed material layer, and covering the mixed material layer with common ceramic bricks until the press mold core is filled to form a base material layer;
2) adopting a reverse-beating cloth pressing forming process, and turning over by a turning-over machine to obtain a green body with a mixture under an upper common ceramic brick material;
3) and (3) polishing, drying, ink-jet printing, spreading transparent glaze on the green body, and then putting the green body into a kiln to be fired at high temperature to obtain a ceramic tile finished product with three-dimensional texture.
The transparent granular material is a transparent material for the existing ceramic tile, and is in a transparent glass shape after being sintered at high temperature; the super white material is used for the existing ceramic tile, and the whiteness of the fired ceramic tile can reach over 65 ℃; the common ceramic brick material is an existing ceramic brick blank, and is not transparent after being fired at high temperature, and the whiteness is lower than 25 ℃; the transparent glaze is a known component of the existing ceramic tile transparent glaze, namely clay, feldspar, sand and the like are used as main raw materials, and pigments or additives are added according to different decoration requirements and performance requirements, so that the details are not repeated.
Specifically, the invention adopts a reverse cloth pressing and forming process, so that the mixed material can be better embedded in the green body, and the transparent granular materials in the mixed material are prevented from moving and being covered by the ultra-white material, thereby influencing the three-dimensional texture effect of the finished product. In addition, the transparent particle materials in the mixed material layer can obtain transparent color development effects with different colors in the high-temperature sintering process by directly carrying out ink-jet printing on the mixed material layer, and finally, a colorful and transparent particle decoration effect is formed, so that the three-dimensional texture of the ink-jet printing patterns is improved.
As a further improvement of the scheme, in the step 1), the transparent granular material accounts for 15-20% of the weight of the mixture. The invention effectively avoids the defect of brick surface deformation caused by the large melt range formed at high temperature by limiting the particle size range and the weight percentage of the transparent granular material.
As a further improvement of the scheme, in the step 1), the thickness of the mixed material layer is 3-5 mm, and the thickness of the base material layer is 8-10 mm. Specifically, the method does not need to apply overglaze, so that the requirement on the whiteness of the ceramic tile green body is high, the reasonable thickness of the mixed material layer and the base material layer is limited, and the green body with low production cost and remarkable whiteness can be obtained.
As a further improvement of the scheme, the depth of the polished blank in the step 3) is controlled within the range of 0.1-0.3 mm. Specifically, the depth of the blank polishing is limited, so that the transparent particle materials covered in the green blank can be exposed, the maximum section of the transparent particle materials is on the surface of the brick blank, and meanwhile, pits on the surface of the green blank are removed, so that the surface of the green blank is smooth, and the direct ink-jet printing can be realized without applying a cover glaze.
As a further improvement of the scheme, the drying in the step 3) adopts a microwave drying or kiln reverse drying mode. Specifically, the transparent granular material and the super white material have different components and have great difference in water retention performance, so that a special mode is needed for drying the green body. According to the invention, through limiting the drying mode, the surface delamination and even the dry cracking of the ceramic tile caused by too fast water evaporation of the transparent granular material are prevented.
As a further improvement of the above scheme, the pattern of the inkjet printing in step 3) is set according to the requirement of the decoration effect on the ceramic tile, and the selected printing pattern is exposed to a large amount of white to prevent the printing pattern from excessively covering the transparent particle material on the surface of the ceramic tile, so that the dislocation effect of the transparent particle material and the printing pattern and the transparent glaze applied subsequently supplement each other to form the decoration effect with a remarkable three-dimensional texture.
The invention has the beneficial effects that:
according to the invention, the transparent granular material and the super white material are used as the blank fabric of the ceramic tile, and the reverse printing cloth pressing forming and the ink-jet printing process are combined, so that the ink-jet printing pattern forms different color development effects in the transparent granular material and the super white material area after subsequent high-temperature firing, thus the tile surface pattern of the ceramic tile has various effects, the lines and the textures are clear, and the three-dimensional texture of the imitated natural marble is highlighted.
The preparation process is simple, and the surface of the green body can be directly subjected to ink-jet printing without applying overglaze, so that the color development of the printed pattern on the ultra-white material layer is natural and has no deviation, and the large-scale industrial production is facilitated.
Detailed Description
The present invention is specifically described below with reference to examples in order to facilitate understanding of the present invention by those skilled in the art. It should be particularly noted that the examples are given solely for the purpose of illustration and are not to be construed as limitations on the scope of the invention, as non-essential improvements and modifications to the invention may occur to those skilled in the art, which fall within the scope of the invention as defined by the appended claims. Meanwhile, the raw materials mentioned below are not specified in detail and are all commercial products; the process steps or preparation methods not mentioned in detail are all process steps or preparation methods known to the person skilled in the art.
Example 1
A preparation method of a ceramic tile with three-dimensional texture comprises the following process steps:
1) preparing transparent materials into transparent granular materials with the grain diameter of 1mm, uniformly mixing the transparent granular materials with the super white materials, wherein the transparent granular materials account for 20 percent of the mixture by weight to obtain the mixture, then distributing the mixture at the bottom of a mould core of a press to form a mixed material layer with the thickness of 3mm, and then covering the mixed material layer with common ceramic brick materials until the mould core of the press is filled to form a base material layer with the thickness of 10 mm;
2) adopting a reverse-beating cloth pressing forming process, and turning over by a turning-over machine to obtain a green body with a mixture under an upper common ceramic brick material;
3) and (3) polishing the green body to the depth of 0.1mm, and then performing microwave drying or kiln back drying, ink-jet printing, transparent glaze distribution and high-temperature firing in a kiln to obtain the ceramic tile finished product with the three-dimensional texture of the embodiment 1.
Example 2
A preparation method of a ceramic tile with three-dimensional texture comprises the following process steps:
1) preparing transparent materials into transparent granular materials with the grain diameter of 3mm, uniformly mixing the transparent granular materials with the super white materials, wherein the transparent granular materials account for 15 percent of the mixture by weight to obtain the mixture, then distributing the mixture at the bottom of a mould core of a press to form a mixed material layer with the thickness of 5mm, and then covering the mixed material layer with common ceramic brick materials until the mould core of the press is filled to form a base material layer with the thickness of 8 mm;
2) adopting a reverse-beating cloth pressing forming process, and turning over by a turning-over machine to obtain a green body with a mixture under an upper common ceramic brick material;
3) and (3) polishing the green body to the depth of 0.3mm, and then performing microwave drying or kiln back drying, ink-jet printing, transparent glaze distribution and high-temperature firing in a kiln to obtain the ceramic tile finished product with the three-dimensional texture of the embodiment 2.
Example 3
A preparation method of a ceramic tile with three-dimensional texture comprises the following process steps:
1) preparing transparent materials into transparent granular materials with the grain diameter of 2mm, uniformly mixing the transparent granular materials with the super white materials, wherein the transparent granular materials account for 18 percent of the mixture by weight to obtain the mixture, then distributing the mixture at the bottom of a mould core of a press to form a mixed material layer with the thickness of 4mm, and then covering the mixed material layer with common ceramic brick materials until the mould core of the press is filled to form a base material layer with the thickness of 9 mm;
2) adopting a reverse-beating cloth pressing forming process, and turning over by a turning-over machine to obtain a green body with a mixture under an upper common ceramic brick material;
3) and (3) polishing the green body to the depth of 0.2mm, and then performing microwave drying or kiln back drying, ink-jet printing, transparent glaze distribution and high-temperature firing in a kiln to obtain the ceramic tile finished product with the three-dimensional texture of the embodiment 3.
Comparative example 1
A preparation method of a ceramic tile comprises the following process steps:
1) distributing the super white material at the bottom of a press mold core to form a material layer with the thickness of 3mm, and then covering the material layer with common ceramic bricks until the press mold core is filled to form a base material layer with the thickness of 10 mm;
2) adopting a reverse-beating cloth pressing forming process, and turning over by a turning-over machine to obtain a green body with a mixture under an upper common ceramic brick material;
3) and (3) polishing the green body to the depth of 0.1mm, performing microwave drying or kiln back drying, ink-jet printing, applying transparent glaze, and then putting into a kiln for high-temperature firing to obtain the finished product of the ceramic tile in the comparative example 1.
Comparative example 2
A preparation method of a ceramic tile comprises the following process steps:
1) distributing the transparent material at the bottom of the press mold core to form a material layer with the thickness of 5mm, and then covering the material layer with common ceramic bricks until the press mold core is filled to form a base material layer with the thickness of 8 mm;
2) adopting a reverse-beating cloth pressing forming process, and turning over by a turning-over machine to obtain a green body with a mixture under an upper common ceramic brick material;
3) and (3) polishing the green body to the depth of 0.3mm, performing microwave drying or kiln back drying, ink-jet printing, applying transparent glaze, and then putting into a kiln for high-temperature firing to obtain the finished product of the ceramic tile in the comparative example 2.
Example 4: performance testing
The finished products obtained in examples 1 to 3 and the finished products obtained in comparative examples 1 to 2 were subjected to the related performance tests, and the test results are shown in table 1 below.
TABLE 1 relevant Performance test results for the finished products of the examples and comparative examples
| Test sample | Product effect |
| Example 1 | Has the decorative effect of transparent particles and lines and has the effect of natural stone |
| Example 2 | Has the decorative effect of transparent particles and lines and has the effect of natural stone |
| Example 3 | Has the decorative effect of transparent particles and lines and has the effect of natural stone |
| Comparative example 1 | Line decorative effect, unnatural compared with natural stone |
| Comparative example 2 | The transparent particles have poor high temperature resistance and more brick surface defects |
The above embodiments are preferred embodiments of the present invention, and all similar processes and equivalent variations to those of the present invention should fall within the scope of the present invention.
Claims (7)
1. A preparation method of ceramic tiles with three-dimensional texture is characterized by comprising the following process steps:
1) preparing transparent materials into transparent granular materials with the grain diameter of 1-3 mm, uniformly mixing the transparent granular materials with the super white materials to obtain mixed materials, then distributing the mixed materials at the bottom of a press mold core to form a mixed material layer, and covering the mixed material layer with common ceramic bricks until the press mold core is filled to form a base material layer;
2) adopting a reverse-beating cloth pressing forming process, and turning over by a turning-over machine to obtain a green body with a mixture under an upper common ceramic brick material;
3) and (3) polishing, drying, ink-jet printing, spreading transparent glaze on the green body, and then putting the green body into a kiln to be fired at high temperature to obtain a ceramic tile finished product with three-dimensional texture.
2. The method for preparing ceramic tile with stereo texture as claimed in claim 1, wherein: the transparent granular material accounts for 15-20% of the mixture in the step 1).
3. The method for preparing ceramic tile with stereo texture as claimed in claim 1, wherein: the thickness of the mixed material layer in the step 1) is 3-5 mm.
4. The method for preparing ceramic tile with stereo texture as claimed in claim 1, wherein: the thickness of the base material layer in the step 1) is 8-10 mm.
5. The method for preparing ceramic tile with stereo texture as claimed in claim 1, wherein: and 3) controlling the depth of the polished blank in the step 3) within the range of 0.1-0.3 mm.
6. The method for preparing ceramic tile with stereo texture as claimed in claim 1, wherein: and 3) drying by adopting a microwave drying or kiln back drying mode.
7. A ceramic tile having a three-dimensional texture produced by the production method according to any one of claims 1 to 6.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201911148813.4A CN110919821A (en) | 2019-11-21 | 2019-11-21 | Preparation method of ceramic tile with three-dimensional texture |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201911148813.4A CN110919821A (en) | 2019-11-21 | 2019-11-21 | Preparation method of ceramic tile with three-dimensional texture |
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| CN110919821A true CN110919821A (en) | 2020-03-27 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112939530A (en) * | 2020-12-04 | 2021-06-11 | 绍兴精工绿筑集成建筑系统工业有限公司 | White high-performance cement-based material special for external wall tile reverse-hitting process |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746129A (en) * | 2004-09-08 | 2006-03-15 | 广东蒙娜丽莎陶瓷有限公司 | Composite semi-transparent polish brick with micropowdery and production thereof |
| CN108424112A (en) * | 2018-04-19 | 2018-08-21 | 佛山市东鹏陶瓷有限公司 | A kind of preparation process and its entire body transparent brick of the entire body transparent brick of the single side bed of material |
| CN108972839A (en) * | 2018-08-10 | 2018-12-11 | 佛山市东鹏陶瓷有限公司 | A kind of preparation process and its ceramic tile of thin layer cloth solid Ceramic Tiles |
-
2019
- 2019-11-21 CN CN201911148813.4A patent/CN110919821A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746129A (en) * | 2004-09-08 | 2006-03-15 | 广东蒙娜丽莎陶瓷有限公司 | Composite semi-transparent polish brick with micropowdery and production thereof |
| CN108424112A (en) * | 2018-04-19 | 2018-08-21 | 佛山市东鹏陶瓷有限公司 | A kind of preparation process and its entire body transparent brick of the entire body transparent brick of the single side bed of material |
| CN108972839A (en) * | 2018-08-10 | 2018-12-11 | 佛山市东鹏陶瓷有限公司 | A kind of preparation process and its ceramic tile of thin layer cloth solid Ceramic Tiles |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112939530A (en) * | 2020-12-04 | 2021-06-11 | 绍兴精工绿筑集成建筑系统工业有限公司 | White high-performance cement-based material special for external wall tile reverse-hitting process |
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Application publication date: 20200327 |