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CN110902984A - Curing agent for sludge treatment and application thereof - Google Patents

Curing agent for sludge treatment and application thereof Download PDF

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Publication number
CN110902984A
CN110902984A CN201911234561.7A CN201911234561A CN110902984A CN 110902984 A CN110902984 A CN 110902984A CN 201911234561 A CN201911234561 A CN 201911234561A CN 110902984 A CN110902984 A CN 110902984A
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CN
China
Prior art keywords
percent
oxide
curing agent
less
sludge treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911234561.7A
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Chinese (zh)
Inventor
周静海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Chengrun Environmental Engineering Co Ltd
Original Assignee
Hebei Chengrun Environmental Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Chengrun Environmental Engineering Co Ltd filed Critical Hebei Chengrun Environmental Engineering Co Ltd
Priority to CN201911234561.7A priority Critical patent/CN110902984A/en
Publication of CN110902984A publication Critical patent/CN110902984A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/008Sludge treatment by fixation or solidification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/143Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/143Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances
    • C02F11/145Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances using calcium compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses a curing agent for sludge treatment, and relates to the field of chemical products; the curing agent comprises the following raw materials in percentage by weight: 18 to 24 percent of silicon dioxide, 5.3 to 7.3 percent of aluminum oxide, 56.3 to 64.3 percent of calcium oxide, 5.6 to 7.6 percent of sulfur trioxide and 4.8 to 6.8 percent of trace component. The main raw material of the curing agent adopts an electrodeless, environment-friendly and low-carbon new material which is deeply processed by a nanotechnology, has the characteristic of environmental protection, can effectively act on sludge treatment, and has higher use value and economic value.

Description

Curing agent for sludge treatment and application thereof
Technical Field
The invention relates to the field of chemical products, in particular to a curing agent for sludge stabilization and harmless treatment and application thereof.
Background
Along with the trend of increasing the discharge amount of wastewater year by year, the increase of sludge after treatment, such as municipal sludge, river sludge, building sludge and the like, follows. Because the initial water content of the sludge is high, even after conventional dehydration, the water content of the sludge is usually over 80 percent, and the sludge is particularly suitable for the growth of pathogenic bacteria, wherein the pathogenic bacteria mainly comprise bacteria, viruses and ova, and contain heavy metal ions and the like. When exposed to these pathogens, humans may suffer from various diseases.
At present, no suitable chemical reagent can well treat the sludge comprehensively, so that an economical, environment-friendly and efficient novel curing agent needs to be found.
Disclosure of Invention
In view of the problems in the prior art, the invention aims to provide a curing agent for sludge treatment.
In order to achieve the purpose, the invention provides the following technical scheme:
a curing agent for sludge treatment comprises the following raw materials in percentage by weight: 18 to 24 percent of silicon dioxide, 5.3 to 7.3 percent of aluminum oxide, 56.3 to 64.3 percent of calcium oxide, 5.6 to 7.6 percent of sulfur trioxide, and the balance of trace components.
In a further aspect: the composite material comprises the following raw materials in percentage by weight: 19 to 23 percent of silicon dioxide, 5.8 to 6.8 percent of aluminum oxide, 58.3 to 62.3 percent of calcium oxide, 6.1 to 7.1 percent of sulfur trioxide, and the balance of trace components.
In a further aspect: the composite material comprises the following raw materials in percentage by weight: 21% of silicon dioxide, 6.3% of aluminum oxide, 60.3% of calcium oxide, 6.6% of sulfur trioxide and the balance of trace components.
In a further aspect: the trace components comprise the following raw materials in parts by weight: less than 1 percent of potassium oxide, less than 1 percent of sodium oxide, less than 1 percent of titanium oxide, less than 1 percent of manganese oxide, less than 1 percent of strontium oxide and less than 1 percent of copper oxide.
Specifically, the curing agent of the present invention has the following mechanism of action:
hydration: the various compounds react with water in the sludge and are combined with water molecules in the sludge to change free water into crystal water to generate new crystal hydrates, and the hydrates are combined with soil particles to form a stable structure.
Inhibiting heavy metal precipitation: when hydration reaction occurs, hydroxide ions are generated to make the environment strongly alkaline, and further, the hydroxide ions react with metal ions in water to generate hydroxide precipitates with low solubility, and metal atoms are spatially bound in a newly formed structure and are not easily precipitated. The aim of solidifying the heavy metal is achieved, and the leaching toxicity of the heavy metal is reduced.
Removal/reduction of harmful substances: under the strong alkaline environment (PH is more than or equal to 12), hydrogen bonds in the protein in the bacteria are broken, and the hydrogen bonds can be combined with free amino groups or carboxyl groups to form salts, so that the protein is modified, and most bacteria can be killed quickly. Indexes of harmful pollutants such as BOD, COD and the like are greatly reduced due to the alkaline environment.
And (3) enhancing the soil strength: calcium oxide and sulfur trioxide in the curing agent in the sludge generate calcium sulfate hydrate, calcium oxide and aluminum oxide generate tricalcium aluminate, the calcium oxide and the aluminum oxide interact with each other to generate ettringite, the tricalcium aluminate is prevented from hydrating, and the air-hardening cementing material is an air-hardening cementing material and can obviously improve the strength of the cured soil.
And (3) malodor reduction: the odor in the sludge mainly comes from organic matters in the sludge, and hydrogen sulfide and mercaptan compound gas are generated through bacterial decomposition; the strong basicity generated in the curing process can make the hydrogen sulfide and the calcium hydroxide react to generate calcium sulfide, thereby achieving the effect of reducing the malodor.
Removing phosphorus components: the sludge contains phosphate radical and dihydrogen phosphate radical, and reacts with calcium ion in the curing agent to form a difficult-to-dissolve compound, so that the aim of removing phosphorus component is fulfilled.
Compared with the prior art, the invention has the following beneficial effects:
the main raw materials of the curing agent are natural mineral substances, so that the curing agent has the characteristics of environmental protection, and the components are easy to obtain and easy to prepare, are prepared by stirring the components according to a certain weight percentage, and are convenient to use; the performance of soil/sludge particle clusters can be improved, the soil water-shielding property is improved, the soil compactness is enhanced, the sludge strength is enhanced, the frost resistance is good, and the soil expansion coefficient is reduced; can effectively eliminate or reduce various pollutants in the sludge, particularly harmful microorganisms, organic phosphorus and the like, and strongly solidify harmful heavy metal components in the sludge to prevent secondary environmental pollution caused by seepage; the solidified sludge is suitable for vegetation growth and has good ecological planting function.
Detailed Description
The examples are given solely for the purpose of illustration and are not intended to limit the scope of the invention. Any obvious modifications or variations can be made to the present invention without departing from the spirit or scope of the present invention.
Example 1
In the embodiment of the invention, the curing agent for sludge treatment comprises the following raw materials in percentage by weight: 24% of silicon dioxide, 7.3% of aluminum oxide, 56.3% of calcium oxide, 7.6% of sulfur trioxide and the balance of trace components.
Wherein the trace components comprise the following raw materials in parts by weight: less than 1 percent of potassium oxide, less than 1 percent of sodium oxide, less than 1 percent of titanium oxide, less than 1 percent of manganese oxide, less than 1 percent of strontium oxide and less than 1 percent of copper oxide.
Example 2
In the embodiment of the invention, the curing agent for sludge treatment comprises the following raw materials in percentage by weight: 19% of silicon dioxide, 5.8% of aluminum oxide, 62.3% of calcium oxide, 6.1% of sulfur trioxide and the balance of trace components.
Wherein the trace components comprise the following raw materials in parts by weight: less than 1 percent of potassium oxide, less than 1 percent of sodium oxide, less than 1 percent of titanium oxide, less than 1 percent of manganese oxide, less than 1 percent of strontium oxide and less than 1 percent of copper oxide.
Example 3
In the embodiment of the invention, the curing agent for sludge treatment comprises the following raw materials in percentage by weight: 21% of silicon dioxide, 6.3% of aluminum oxide, 60.3% of calcium oxide, 6.6% of sulfur trioxide and the balance of trace components.
Wherein the trace components comprise the following raw materials in parts by weight: less than 1 percent of potassium oxide, less than 1 percent of sodium oxide, less than 1 percent of titanium oxide, less than 1 percent of manganese oxide, less than 1 percent of strontium oxide and less than 1 percent of copper oxide.
Example 4
In the embodiment of the invention, the curing agent for sludge treatment comprises the following raw materials in percentage by weight: 23% of silicon dioxide, 6.8% of aluminum oxide, 58.3% of calcium oxide, 7.1% of sulfur trioxide and the balance of trace components.
Wherein the trace components comprise the following raw materials in parts by weight: less than 1 percent of potassium oxide, less than 1 percent of sodium oxide, less than 1 percent of titanium oxide, less than 1 percent of manganese oxide, less than 1 percent of strontium oxide and less than 1 percent of copper oxide.
Example 5
In the embodiment of the invention, the curing agent for sludge treatment comprises the following raw materials in percentage by weight: 18 percent of silicon dioxide, 5.3 percent of aluminum oxide, 64.3 percent of calcium oxide, 5.6 percent of sulfur trioxide, and the balance of trace components.
Wherein the trace components comprise the following raw materials in parts by weight: less than 1 percent of potassium oxide, less than 1 percent of sodium oxide, less than 1 percent of titanium oxide, less than 1 percent of manganese oxide, less than 1 percent of strontium oxide and less than 1 percent of copper oxide.
Example 6
In the embodiment of the invention, the curing agent for sludge treatment comprises the following raw materials in percentage by weight: 21.3% of silicon dioxide, 6.1% of aluminum oxide, 62.3% of calcium oxide, 6.8% of sulfur trioxide and the balance of trace components.
Wherein the trace components comprise the following raw materials in parts by weight: less than 1 percent of potassium oxide, less than 1 percent of sodium oxide, less than 1 percent of titanium oxide, less than 1 percent of manganese oxide, less than 1 percent of strontium oxide and less than 1 percent of copper oxide.
Example 7
In the embodiment of the invention, the curing agent described in any one of embodiments 1 to 6 is described in application by combining different application scenes.
River and lake sludge ecological resource treatment, namely in the river dredging process, river sludge is solidified to be used as a base material for slope protection, vegetation with water and soil conservation is planted to enhance the slope protection effect and realize the landscape ecological effect.
The wetland sludge solidification builds ecological landscape-when the wetland landscape is reformed, the sludge solidification technology is utilized to improve the soil of the original sludge accumulation area, so that specific vegetation can grow in the area, the landscape improvement is facilitated, the ecological bearing capacity of the wetland is greatly improved, and meanwhile, the water and soil loss condition in the flood season is improved and the water quality is purified.
Harbor construction-a large amount of soft muddy soil is excavated in the harbor construction process, and the soil is not suitable for being used as a matrix paving material, and can only be used as waste to be transported and treated, so the cost is high. If the curing agent is adopted for treatment, the curing agent is improved into the compliant soil which can be used for construction to be utilized on site, so that a large amount of capital is saved, the environmental damage is reduced, and the reduction and the resource of wastes are realized.
Soil ecological restoration-in the restoration and ecological reconstruction work of land suffering from serious disturbance (such as mining field land, forest felling field, refuse landfill, land surface serious destruction and the like which needs to be reclaimed), the curing agent is adopted for treatment, so that the sludge can be used as covering and backfilling soil, the skill meets the requirements of vegetation growth and ecological bearing capacity restoration, and the resource strategy can be realized.
In road construction, when road construction is carried out, soil for paving a roadbed is often required to be transported for a long distance, or the stability of the roadbed is enhanced by adopting high-cost modes such as burying a large number of cement pile foundations and the like. If the curing agent is adopted to improve the strength of the on-site sludge, the construction difficulty is reduced, and a large amount of cost is saved.
Municipal stock sludge: a large amount of municipal sludge is stored for a long time due to no corresponding treatment and disposal way, the surrounding environment is seriously influenced, the underground water is threatened, the sludge is solidified and treated in a harmless way by adopting a curing agent and then is used for backfilling and covering planting, and the problem of the sludge direction in storage is solved at low cost.
The above description is only for the specific embodiments of the present disclosure, but the scope of the present disclosure is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present disclosure, and all the changes or substitutions should be covered within the scope of the present disclosure. Therefore, the protection scope of the present disclosure shall be subject to the protection scope of the claims.

Claims (6)

1. The curing agent for sludge treatment is characterized by comprising the following raw materials in percentage by weight: 18 to 24 percent of silicon dioxide, 5.3 to 7.3 percent of aluminum oxide, 56.3 to 64.3 percent of calcium oxide, 5.6 to 7.6 percent of sulfur trioxide, and the balance of trace components.
2. The curing agent for sludge treatment according to claim 1, characterized by comprising the following raw materials in percentage by weight: 19 to 23 percent of silicon dioxide, 5.8 to 6.8 percent of aluminum oxide, 58.3 to 62.3 percent of calcium oxide, 6.1 to 7.1 percent of sulfur trioxide, and the balance of trace components.
3. The curing agent for sludge treatment according to claim 2, characterized by comprising the following raw materials in percentage by weight: 21% of silicon dioxide, 6.3% of aluminum oxide, 60.3% of calcium oxide, 6.6% of sulfur trioxide and the balance of trace components.
4. The curing agent for sludge treatment according to claim 1, wherein the minor components comprise the following raw materials in parts by weight: less than 1 percent of potassium oxide, less than 1 percent of sodium oxide, less than 1 percent of titanium oxide, less than 1 percent of manganese oxide, less than 1 percent of strontium oxide and less than 1 percent of copper oxide.
5. Use of the solidifying agent for sludge treatment according to any one of claims 1 to 4 in sludge treatment.
6. Use of the curing agent for sludge treatment according to any one of claims 1 to 4 for the preparation of a compound or composition for sludge treatment.
CN201911234561.7A 2019-12-05 2019-12-05 Curing agent for sludge treatment and application thereof Pending CN110902984A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911234561.7A CN110902984A (en) 2019-12-05 2019-12-05 Curing agent for sludge treatment and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911234561.7A CN110902984A (en) 2019-12-05 2019-12-05 Curing agent for sludge treatment and application thereof

Publications (1)

Publication Number Publication Date
CN110902984A true CN110902984A (en) 2020-03-24

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Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113582475A (en) * 2020-04-30 2021-11-02 天津富兰克能源科技有限公司 Sludge curing agent for municipal sewage treatment plant and curing treatment process thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1534727A (en) * 1976-03-26 1978-12-06 Ni I Promy Str Building materials
JPH10495A (en) * 1996-06-14 1998-01-06 Nippon Kosan Kk Method for recycling construction sludge
JP2000210700A (en) * 1999-01-27 2000-08-02 Nippon Kosan Kk Method of reutilization of construction sludge
KR20020003423A (en) * 2000-06-28 2002-01-12 소재한 A method for treating heavy metals-containing wastes to preserve the ecosystem of seawater
CN102603153A (en) * 2012-03-14 2012-07-25 河海大学 Curing agent for solidification/stabilization of dewatered sludge of sewage plant and application of curing agent
CN109354355A (en) * 2018-11-29 2019-02-19 广州珞珈环境技术有限公司 A kind of adjusting material and its preparation method and application for sludge solidification

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1534727A (en) * 1976-03-26 1978-12-06 Ni I Promy Str Building materials
JPH10495A (en) * 1996-06-14 1998-01-06 Nippon Kosan Kk Method for recycling construction sludge
JP2000210700A (en) * 1999-01-27 2000-08-02 Nippon Kosan Kk Method of reutilization of construction sludge
KR20020003423A (en) * 2000-06-28 2002-01-12 소재한 A method for treating heavy metals-containing wastes to preserve the ecosystem of seawater
CN102603153A (en) * 2012-03-14 2012-07-25 河海大学 Curing agent for solidification/stabilization of dewatered sludge of sewage plant and application of curing agent
CN109354355A (en) * 2018-11-29 2019-02-19 广州珞珈环境技术有限公司 A kind of adjusting material and its preparation method and application for sludge solidification

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113582475A (en) * 2020-04-30 2021-11-02 天津富兰克能源科技有限公司 Sludge curing agent for municipal sewage treatment plant and curing treatment process thereof

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Application publication date: 20200324

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