CN110898678A - Preparation method of degradable anti-haze fiber film - Google Patents
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- CN110898678A CN110898678A CN201911180890.8A CN201911180890A CN110898678A CN 110898678 A CN110898678 A CN 110898678A CN 201911180890 A CN201911180890 A CN 201911180890A CN 110898678 A CN110898678 A CN 110898678A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/02—Solvent extraction of solids
- B01D11/0261—Solvent extraction of solids comprising vibrating mechanisms, e.g. mechanical, acoustical
- B01D11/0265—Applying ultrasound
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/54—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms
- B01D46/543—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms using membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/10—Filtering material manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/39—Electrospinning
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- Manufacturing & Machinery (AREA)
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Abstract
The invention discloses a preparation method of a degradable anti-haze fiber film, which comprises the following specific steps: pulverizing Chinese herbal medicines for clearing lung and moistening lung, loading into an ultrasonic extraction device, adding ethanol water solution with certain concentration, and performing ultrasonic extraction treatment at set temperature and power for a period of time to obtain Chinese herbal medicine extract solution; soaking polybutylene succinate in the Chinese herbal medicine extract solution for a period of time, drying at 80 ℃ for 3h, dissolving in DMF solution, and preparing the fiber membrane by adopting an electrostatic spinning process. According to the invention, the completely biodegradable poly (butylene succinate) is used as a base material, and the Chinese herbal medicine extract for clearing lung and moistening lung is added, so that the prepared fiber membrane is green and environment-friendly, has high haze prevention and filtration efficiency, and has a wide application prospect.
Description
Technical Field
The invention relates to the technical field of polymer fiber membranes. In particular to a preparation method of a degradable anti-haze fiber film.
Background
Haze is a special weather phenomenon caused by the current environmental pollution. Haze generally contains certain PM2.5 and PM10 particles, and can enter a respiratory system through the nasopharynx part of a human body, so that the damage to the functions of main organs such as heart and lung is caused, and the symptoms of dryness, itching, stabbing pain, bleeding, cough, expectoration, chest distress, palpitation and the like of the nose and throat part are often presented. The continuous haze contact can cause lung cancer, myocardial damage, infertility and other diseases, and the health and the daily life of human beings are greatly damaged. At present, people mainly adopt air filter material to alleviate the influence that the haze brought. The commonly used air filter material is mainly prepared from synthetic fibers of plastics such as polypropylene, polytetrafluoroethylene and the like, which brings difficulty to recycling of waste products, and causes environmental pollution easily due to improper treatment, so that the environment-friendly multifunctional material becomes one of the future development trends of the air filter material market. Due to the advantages of cost and strong functionality, biopolymers and their polymers have led us to focus on the development of environmentally friendly air filtration materials.
The poly (butylene succinate) (PBS) is synthesized by condensation polymerization of succinic acid and butanediol, is easily decomposed and metabolized by various microorganisms or enzymes in animals and plants in the nature, and is finally decomposed into carbon dioxide and water, is a typical fully degradable polymer material, and compared with degradable plastics such as PCL, PHB, PHA and the like, the PBS has the characteristics of low price, excellent mechanical property and the like; compared with PLA with a similar price, PBS has the characteristics of convenient processing, adaptability to the conventional plastic processing technology at present and good heat resistance, the heat deformation temperature can exceed 100 ℃ (the heat resistance temperature of PLA is only about 60 ℃), and the raw material source for synthesizing PBS can be petroleum resources and can also be obtained by fermenting biomass resources, thereby drawing high attention to science and technology and the industry.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a preparation method of a degradable anti-haze fiber film.
The purpose of the invention is realized by the following scheme: a preparation method of a degradable anti-haze fiber film is characterized in that an ultrasonic extraction method is utilized to quickly and efficiently prepare a Chinese herbal medicine extract solution, and an electrostatic spinning method is adopted to prepare the fiber film; the method comprises the following specific steps:
the first step is as follows: preparing a Chinese herbal medicine extract solution: pulverizing the Chinese medicinal materials with lung heat clearing and moistening effects to 1um, and loading into a super-therapeutic apparatus
Adding 30-50% ethanol water solution into a sound extraction device, wherein the ratio of material to liquid (Kg: L) is 1: 10-15, and performing ultrasonic extraction treatment at a set temperature of 20-80 ℃ and a power of 100-500 w for 20-50min to obtain a Chinese herbal medicine extract solution;
the second step is that: preparing a fiber membrane:
a. soaking 100g of poly (butylene succinate) in the Chinese herbal medicine extract solution for 2-5 h, and drying at 80 ℃ for 3 h;
b. and (3) dissolving the treated polybutylene succinate in a DMF (dimethyl formamide) solution at the temperature of 80 ℃ to form a mixed solution with the concentration of 20-50%, and performing electrostatic spinning under certain process conditions to obtain the fiber membrane.
The Chinese herbal medicine comprises 3-10 parts of honeysuckle, 2-8 parts of momordica grosvenori, 5-15 parts of mint, 3-8 parts of boat-fruited sterculia seed, 3-8 parts of liquorice, 2-10 parts of lily, 2-10 parts of green tea, 5-15 parts of sea buckthorn, 2-10 parts of common camptotheca fruit and 3-10 parts of purslane.
The electrostatic spinning process conditions are as follows: the temperature is 60-80 ℃, the voltage is 5-10 KV, and the distance is 10-25 cm.
Pulverizing Chinese herbal medicines for clearing lung and moistening lung, loading into an ultrasonic extraction device, adding ethanol water solution with certain concentration, and performing ultrasonic extraction treatment at set temperature and power for a period of time to obtain Chinese herbal medicine extract solution; the preparation method comprises the steps of soaking polybutylene succinate in the Chinese herbal medicine extract solution for a period of time, drying at 80 ℃ for 3 hours, dissolving in DMF solution, and preparing the fiber membrane by adopting an electrostatic spinning process, wherein the fiber membrane can be processed into a mask according to the preparation method and the procedure of the mask, can also be processed into a filter element with a specified size and used for an air conditioner or an air purifier, or can be used as a material for manufacturing an anti-haze screen window. The process is simple, the activity of the effective components of the Chinese herbal medicines is kept at low temperature, and the lung clearing and haze preventing functions of the fiber film are enhanced.
The degradable anti-haze fiber film has the beneficial effects that:
1. the degradable anti-haze fiber film adopts the fully degradable polymer material PBS as the matrix material, is easy to be decomposed and metabolized by various microorganisms or enzymes in animals and plants in the nature, and is finally decomposed into carbon dioxide and water, so that the degradable anti-haze fiber film is green and environment-friendly.
2. According to the degradable anti-haze fiber film, a large number of Chinese herbal medicine active factors with the functions of clearing away the lung-heat and moistening the lung are used as anti-haze active ingredients, and the prepared fiber film has good lung-heat clearing and anti-haze filtering performances.
Detailed Description
The present invention is described in detail below with reference to specific examples, but the scope of the present invention is not limited to these examples.
Example 1:
a degradable anti-haze fiber membrane is prepared by quickly and efficiently preparing a Chinese herbal medicine extract solution by using an ultrasonic extraction method, preparing the fiber membrane by using an electrostatic spinning method and preparing the fiber membrane by the following steps:
the first step is as follows: preparing a Chinese herbal medicine extract solution:
taking 5 parts of honeysuckle, 3 parts of momordica grosvenori, 10 parts of mint, 5 parts of boat-fruited sterculia seed, 4 parts of liquorice, 5 parts of lily, 8 parts of green tea, 10 parts of sea-buckthorn, 8 parts of common camptotheca fruit and 8 parts of purslane, crushing the Chinese herbal medicines with the total mass of 500g for clearing lung and moistening lung into powder with the length of about 1 mu m, putting the powder into an ultrasonic extraction device, adding 6L of 35% ethanol aqueous solution, and performing ultrasonic extraction treatment for 40min at the set temperature of 40 ℃ and the power of 200w to obtain a Chinese herbal medicine extract solution;
the second step is that: preparing a fiber membrane:
a. soaking 100g of polybutylene succinate (PBS) in the Chinese herbal medicine extract solution for 3h, and drying at 80 ℃ for 3 h;
b. and dissolving the treated polybutylene succinate in a Dimethylformamide (DMF) solution at the temperature of 80 ℃ to form a mixed solution with the concentration of 35%, and performing electrostatic spinning under the conditions that the temperature is 70 ℃, the voltage is 6KV and the distance is 10cm to obtain the fiber membrane.
The fiber membranes prepared in this example were tested for degradation efficiency and filtration efficiency, and the results are shown in tables 1 and 2, respectively.
Example 2:
a degradable anti-haze fiber film is prepared by the following steps similar to example 1:
the first step is as follows: preparing a Chinese herbal medicine extract solution: taking 8 parts of honeysuckle, 6 parts of momordica grosvenori, 12 parts of mint, 7 parts of boat-fruited sterculia seed, 6 parts of liquorice, 8 parts of lily, 8 parts of green tea, 13 parts of sea buckthorn, 8 parts of common camptotheca fruit and 7 parts of purslane, crushing the Chinese herbal medicines with the total mass of 600g for clearing lung and moistening lung into powder with the length of about 1 mu m, putting the powder into an ultrasonic extraction device, adding 9L of 45% ethanol aqueous solution, and performing ultrasonic extraction treatment for 30min at the set temperature of 60 ℃ and the power of 300w to obtain a Chinese herbal medicine extract solution;
the second step is that: preparing a fiber membrane:
a. soaking 100g PBS in the above Chinese herbal extract solution for 4h, and drying at 80 deg.C for 3 h;
b. and dissolving the treated PBS in a DMF solution at the temperature of 80 ℃ to form a mixed solution with the concentration of 45%, and performing electrostatic spinning under the conditions that the temperature is 60 ℃, the voltage is 8KV and the distance is 15cm to obtain the fiber membrane.
The fiber membranes prepared in this example were tested for degradation efficiency and filtration efficiency, and the results are shown in tables 1 and 2, respectively.
Example 3:
a degradable anti-haze fiber film is prepared by the following steps similar to example 1:
the first step is as follows: preparing a Chinese herbal medicine extract solution: taking 10 parts of honeysuckle, 3 parts of momordica grosvenori, 6 parts of mint, 4 parts of boat-fruited sterculia seed, 4 parts of liquorice, 3 parts of lily, 4 parts of green tea, 7 parts of sea-buckthorn, 3 parts of common camptotheca fruit and 4 parts of purslane, crushing the Chinese herbal medicines with the total mass of 300g for clearing lung and moistening lung into powder with the length of about 1 mu m, putting the powder into an ultrasonic extraction device, adding 3.5L of 50% ethanol aqueous solution, and performing ultrasonic extraction treatment for 25min at the set temperature of 70 ℃ and the power of 400w to obtain a Chinese herbal extract solution;
the second step is that: preparing a fiber membrane:
a. soaking 100g PBS in the above Chinese herbal extract solution for 3.5 hr, and drying at 80 deg.C for 3 hr;
b. and dissolving the treated PBS in a DMF solution at the temperature of 80 ℃ to form a mixed solution with the concentration of 50%, and performing electrostatic spinning under the conditions that the temperature is 80 ℃, the voltage is 10KV and the distance is 20cm to obtain the fiber membrane.
The fiber membranes prepared in this example were tested for degradation efficiency and filtration efficiency, and the results are shown in tables 1 and 2, respectively.
First, degradation efficiency of the fiber membranes prepared in examples 1 to 3: the fiber membranes were subjected to controlled aerobic composting experiments and the degradation efficiencies of the fiber membranes prepared in examples 1-3 at 30 days and 90 days are shown in table 1:
second, filtration efficiency of the fiber membranes prepared in examples 1 to 3 for PM 2.5:
the results of the filtration efficiency of the fiber membranes prepared in examples 1-3, measured according to GB/T18801-2015 test method and standard, are shown in Table 2:
Claims (3)
1. a preparation method of a degradable anti-haze fiber film is characterized in that an ultrasonic extraction method is used for quickly and efficiently preparing a Chinese herbal medicine extract solution, and an electrostatic spinning method is used for preparing the fiber film, and comprises the following steps:
the first step is as follows: preparing a Chinese herbal medicine extract solution: crushing the Chinese herbal medicines for clearing away the lung-heat and moistening the lung to about 1 mu m, putting the crushed Chinese herbal medicines into an ultrasonic extraction device, adding 30-50% ethanol water solution with the concentration of 1 (10-15) of the ratio of materials to liquid (Kg: L), and performing ultrasonic extraction treatment for 20-50min at the set temperature of 20-80 ℃ and the power of 100-500 w to obtain a Chinese herbal medicine extract solution;
the second step is that: preparing a fiber membrane:
a. soaking 100g of poly (butylene succinate) in the Chinese herbal medicine extract solution for 2-5 h, and drying at 80 ℃ for 3 h;
b. and (3) dissolving the treated polybutylene succinate in a DMF (dimethyl formamide) solution at the temperature of 80 ℃ to form a mixed solution with the concentration of 20-50%, and performing electrostatic spinning to obtain the fiber membrane.
2. The preparation method of the degradable anti-haze fiber film according to claim 1, characterized in that: the Chinese herbal medicines comprise the following components in parts by weight: 3-10 parts of honeysuckle, 2-8 parts of momordica grosvenori, 5-15 parts of mint, 3-8 parts of boat-fruited sterculia seed, 3-8 parts of liquorice, 2-10 parts of lily, 2-10 parts of green tea, 5-15 parts of sea buckthorn, 2-10 parts of common camptotheca fruit and 3-10 parts of purslane.
3. The preparation method of the degradable anti-haze fiber film according to claim 1, wherein the method comprises the following steps: the electrostatic spinning process conditions are as follows: the temperature is 60-80 ℃, the voltage is 5-10 KV, and the distance is 10-25 cm.
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| CN201911180890.8A CN110898678A (en) | 2019-11-27 | 2019-11-27 | Preparation method of degradable anti-haze fiber film |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5951745A (en) * | 1997-05-28 | 1999-09-14 | Gibbs; Douglas P. | Environmentally benign, washable wet filter |
| CN103451849A (en) * | 2012-05-30 | 2013-12-18 | 中国科学院理化技术研究所 | Nano-silver-containing polybutylene succinate nanofiber membrane and preparation method and application thereof |
| CN105597575A (en) * | 2016-01-13 | 2016-05-25 | 北京化工大学 | Degradable bio-based air filter membrane and preparation method thereof |
| CN105755676A (en) * | 2016-04-20 | 2016-07-13 | 徐海涛 | Method for producing gas filtration material with needleless electrospinning technology and application of gas filtration material |
| CN106861466A (en) * | 2017-03-15 | 2017-06-20 | 张天奇 | A kind of haze tunica fibrosa |
-
2019
- 2019-11-27 CN CN201911180890.8A patent/CN110898678A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5951745A (en) * | 1997-05-28 | 1999-09-14 | Gibbs; Douglas P. | Environmentally benign, washable wet filter |
| CN103451849A (en) * | 2012-05-30 | 2013-12-18 | 中国科学院理化技术研究所 | Nano-silver-containing polybutylene succinate nanofiber membrane and preparation method and application thereof |
| CN105597575A (en) * | 2016-01-13 | 2016-05-25 | 北京化工大学 | Degradable bio-based air filter membrane and preparation method thereof |
| CN105755676A (en) * | 2016-04-20 | 2016-07-13 | 徐海涛 | Method for producing gas filtration material with needleless electrospinning technology and application of gas filtration material |
| CN106861466A (en) * | 2017-03-15 | 2017-06-20 | 张天奇 | A kind of haze tunica fibrosa |
Non-Patent Citations (2)
| Title |
|---|
| 杨鸣波，黄锐主编: "《塑料成型工艺学 第3版》", 30 June 2014, 中国轻工业出版社 * |
| 靳学远，董海丽编著: "《天然产物降血糖功能性成分研究》", 30 June 2009, 上海交通大学出版社 * |
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Application publication date: 20200324 |