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CN110885991A - Novel plate-shaped cathode - Google Patents

Novel plate-shaped cathode Download PDF

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Publication number
CN110885991A
CN110885991A CN201911315905.7A CN201911315905A CN110885991A CN 110885991 A CN110885991 A CN 110885991A CN 201911315905 A CN201911315905 A CN 201911315905A CN 110885991 A CN110885991 A CN 110885991A
Authority
CN
China
Prior art keywords
cathode
plate
novel
shaped cathode
antimony
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911315905.7A
Other languages
Chinese (zh)
Inventor
陈晓春
康钦科
谢雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xinshao State Antimony Industry Co Ltd
Original Assignee
Xinshao State Antimony Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xinshao State Antimony Industry Co Ltd filed Critical Xinshao State Antimony Industry Co Ltd
Priority to CN201911315905.7A priority Critical patent/CN110885991A/en
Publication of CN110885991A publication Critical patent/CN110885991A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02Electrodes; Connections thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/22Electrolytic production, recovery or refining of metals by electrolysis of solutions of metals not provided for in groups C25C1/02 - C25C1/20

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

The invention provides a novel plate-shaped cathode, which consists of a conductive beam, a titanium plate and a fixed support, wherein the titanium plate is provided with a plurality of uniformly distributed flow holes. The invention prolongs the service life of the cathode, and the service life of the novel cathode is more than 2 years. The longitudinal stress of cathode antimony deposition is reduced, and favorable conditions are provided for automatic antimony stripping. The current utilization rate of the cathode is improved, and the yield of cathode antimony is improved.

Description

Novel plate-shaped cathode
Technical Field
The invention relates to the technical field of electrochemistry, in particular to a novel plate-shaped cathode.
Background
The high-arsenic antimony gold concentrate ore pulp electrolysis project is a novel technology for producing antimony by wet electrolysis, which is jointly developed by Beijing university of technology and New Shachen antimony industry Limited liability company, wherein the cathode adopted in electrolysis is a net-shaped titanium material, each cathode is formed by welding two specially-treated titanium nets, and the upper end of each cathode is in a full-welding form. In the use, often influence negative pole efficiency because electrically conductive effect is not good, and because of metal antimony is too big at negative pole electrodeposition deposit longitudinal stress to lead to shelling the antimony difficulty, in addition because netted negative plate bulk strength is low excessively, thereby appear damaging easily in the use, the maintenance degree of difficulty is big and the cost is higher, has produced certain influence to production.
Disclosure of Invention
The invention aims to provide a novel plate-shaped cathode, which prolongs the service life of the cathode and has the service life of more than 2 years.
The technical scheme of the invention is realized as follows:
the invention provides a novel plate-shaped cathode, which consists of a conductive beam, a titanium plate and a fixed support, wherein the titanium plate is provided with a plurality of uniformly distributed flow holes.
As a further improvement of the invention, the fixing splint is made of metal.
As a further improvement of the invention, the fixing splint is made of copper or iron.
As a further improvement of the invention, the fixing splint is made of copper.
As a further improvement of the invention, the titanium plate is fixed on the fixed bracket by welding.
As a further development of the invention, the number of flow openings is at least 15.
As a further improvement of the invention, the width of the titanium plate is 1.5-2 m.
As a further improvement of the invention, the conductive beam is made of copper or silver.
As a further improvement of the present invention, the conductive beam is made of copper.
The invention has the following beneficial effects:
1. the service life of the cathode is prolonged, and the service life of the novel cathode is more than 2 years.
2. The longitudinal stress of cathode antimony deposition is reduced, and favorable conditions are provided for automatic antimony stripping.
3. The current utilization rate of the cathode is improved, and the yield of cathode antimony is improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
FIG. 1 is a schematic structural diagram of a novel plate-shaped cathode according to the present invention;
wherein, 1, the conductive beam; 2. a titanium plate; 3. a flow aperture; 4. and fixing the bracket.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The utility model provides a novel platelike negative pole, comprises electrically conductive roof beam 1, titanium board 2, fixed bolster 4, be equipped with a plurality of evenly distributed flow holes 3 on the titanium board, be convenient for the circulation of negative pole fluid infusion.
The fixing splint 4 is made of copper.
The titanium plate 2 is fixed on the fixed support 4 by welding, and the width of the titanium plate 2 is 1.5 m.
There are at least 15 flow holes 3.
The conductive beam 1 is made of copper.
Example 2
The utility model provides a novel platelike negative pole, comprises electrically conductive roof beam 1, titanium board 2, fixed bolster 4, be equipped with a plurality of evenly distributed flow holes 3 on the titanium board, be convenient for the circulation of negative pole fluid infusion.
The fixing splint 4 is made of iron.
The titanium plate 2 is fixed on the fixed support 4 by welding, and the width of the titanium plate 2 is 2 m.
There are at least 15 flow holes 3.
The conductive beam 1 is made of silver.
Example 3
The utility model provides a novel platelike negative pole, comprises electrically conductive roof beam 1, titanium board 2, fixed bolster 4, be equipped with a plurality of evenly distributed flow holes 3 on the titanium board, be convenient for the circulation of negative pole fluid infusion.
The fixing splint 4 is made of iron.
The titanium plate 2 is fixed on the fixed support 4 by welding, and the width of the titanium plate 2 is 1.7 m.
There are at least 15 flow holes 3.
The conductive beam 1 is made of copper.
Compared with the prior art, the invention prolongs the service life of the cathode, and the service life of the novel cathode is more than 2 years. The longitudinal stress of cathode antimony deposition is reduced, and favorable conditions are provided for automatic antimony stripping. The current utilization rate of the cathode is improved, and the yield of cathode antimony is improved.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (9)

1. The novel plate-shaped cathode is characterized by comprising a conductive beam, a titanium plate and a fixed support, wherein a plurality of uniformly distributed flow holes are formed in the titanium plate.
2. The novel plate-shaped cathode according to claim 1, wherein the fixing clamping plate is made of metal.
3. The novel plate-shaped cathode according to claim 2, wherein the fixing clamp plate is made of copper or iron.
4. The novel plate-shaped cathode according to claim 3, wherein the fixing clamping plate is made of copper.
5. The novel plate-shaped cathode according to claim 1, wherein the titanium plate is fixed on the fixing bracket by welding.
6. The novel plate-shaped cathode according to claim 1, wherein said flow holes are at least 15.
7. The novel plate-shaped cathode according to claim 1, wherein the width of the titanium plate is 1.5-2 m.
8. The novel plate-shaped cathode according to claim 1, wherein the conductive beam is made of copper or silver.
9. The novel plate-shaped cathode according to claim 8, wherein the conductive beam is made of copper.
CN201911315905.7A 2019-12-19 2019-12-19 Novel plate-shaped cathode Pending CN110885991A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911315905.7A CN110885991A (en) 2019-12-19 2019-12-19 Novel plate-shaped cathode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911315905.7A CN110885991A (en) 2019-12-19 2019-12-19 Novel plate-shaped cathode

Publications (1)

Publication Number Publication Date
CN110885991A true CN110885991A (en) 2020-03-17

Family

ID=69752516

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911315905.7A Pending CN110885991A (en) 2019-12-19 2019-12-19 Novel plate-shaped cathode

Country Status (1)

Country Link
CN (1) CN110885991A (en)

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4776941A (en) * 1985-06-21 1988-10-11 Tezanos Enrique H Cathode for metal electrowinning
RU1489U1 (en) * 1993-05-31 1996-01-16 Московский химический завод "Синтез" ELECTROLYZER
CN201024215Y (en) * 2006-12-08 2008-02-20 倪国年 Electrolytic type ozone generator film electrode assembly
CN101660179A (en) * 2009-09-23 2010-03-03 南京宝色股份公司 Titanium copper rod suspended type titanium negative plate
CN202881415U (en) * 2012-08-17 2013-04-17 惠州中京电子科技股份有限公司 Electrolytic copper anode device
CN103726068A (en) * 2013-12-13 2014-04-16 杭州帝洛森科技有限公司 Novel cathode conductive cross beam
CN203938742U (en) * 2014-01-17 2014-11-12 北京矿冶研究总院 pulp electrolysis cathode device
CN204982117U (en) * 2015-08-28 2016-01-20 上海八菱环保科技有限公司 Electrolysis trough negative pole titanium board
CN207418880U (en) * 2017-11-13 2018-05-29 昆明理工恒达科技股份有限公司 A kind of hydrometallurgy electrowinning zinc novel aluminum cathode plate
CN108101162A (en) * 2017-12-20 2018-06-01 西安博岳环保科技有限公司 A kind of preparation method in the stannic oxide pole plate interlayer of titanium-based Sb doped
CN208151498U (en) * 2018-04-03 2018-11-27 金川集团股份有限公司 A kind of annular button Winning cell novel cathode board structure
CN208183088U (en) * 2018-02-11 2018-12-04 天水师范学院 A kind of titanium net anode frame of metal waste wet underwater welding recycling
CN109750322A (en) * 2019-03-15 2019-05-14 北京矿冶科技集团有限公司 A kind of enclosed type electrolytic tank permanent cathode

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4776941A (en) * 1985-06-21 1988-10-11 Tezanos Enrique H Cathode for metal electrowinning
RU1489U1 (en) * 1993-05-31 1996-01-16 Московский химический завод "Синтез" ELECTROLYZER
CN201024215Y (en) * 2006-12-08 2008-02-20 倪国年 Electrolytic type ozone generator film electrode assembly
CN101660179A (en) * 2009-09-23 2010-03-03 南京宝色股份公司 Titanium copper rod suspended type titanium negative plate
CN202881415U (en) * 2012-08-17 2013-04-17 惠州中京电子科技股份有限公司 Electrolytic copper anode device
CN103726068A (en) * 2013-12-13 2014-04-16 杭州帝洛森科技有限公司 Novel cathode conductive cross beam
CN203938742U (en) * 2014-01-17 2014-11-12 北京矿冶研究总院 pulp electrolysis cathode device
CN204982117U (en) * 2015-08-28 2016-01-20 上海八菱环保科技有限公司 Electrolysis trough negative pole titanium board
CN207418880U (en) * 2017-11-13 2018-05-29 昆明理工恒达科技股份有限公司 A kind of hydrometallurgy electrowinning zinc novel aluminum cathode plate
CN108101162A (en) * 2017-12-20 2018-06-01 西安博岳环保科技有限公司 A kind of preparation method in the stannic oxide pole plate interlayer of titanium-based Sb doped
CN208183088U (en) * 2018-02-11 2018-12-04 天水师范学院 A kind of titanium net anode frame of metal waste wet underwater welding recycling
CN208151498U (en) * 2018-04-03 2018-11-27 金川集团股份有限公司 A kind of annular button Winning cell novel cathode board structure
CN109750322A (en) * 2019-03-15 2019-05-14 北京矿冶科技集团有限公司 A kind of enclosed type electrolytic tank permanent cathode

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Application publication date: 20200317

RJ01 Rejection of invention patent application after publication