CN110876687A - Rare earth environment-friendly nail polish and preparation method thereof - Google Patents
Rare earth environment-friendly nail polish and preparation method thereof Download PDFInfo
- Publication number
- CN110876687A CN110876687A CN201911224705.0A CN201911224705A CN110876687A CN 110876687 A CN110876687 A CN 110876687A CN 201911224705 A CN201911224705 A CN 201911224705A CN 110876687 A CN110876687 A CN 110876687A
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- rare earth
- nail polish
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- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 46
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 239000004014 plasticizer Substances 0.000 claims abstract description 29
- 239000000049 pigment Substances 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002518 antifoaming agent Substances 0.000 claims description 24
- 239000002562 thickening agent Substances 0.000 claims description 24
- -1 rare earth sulfide Chemical class 0.000 claims description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 239000000080 wetting agent Substances 0.000 claims description 12
- 239000004593 Epoxy Substances 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 235000010446 mineral oil Nutrition 0.000 claims description 6
- 239000002480 mineral oil Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 5
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 5
- 239000008158 vegetable oil Substances 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- MMXSKTNPRXHINM-UHFFFAOYSA-N cerium(3+);trisulfide Chemical group [S-2].[S-2].[S-2].[Ce+3].[Ce+3] MMXSKTNPRXHINM-UHFFFAOYSA-N 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 229920005749 polyurethane resin Polymers 0.000 claims description 4
- KKZKWPQFAZAUSB-UHFFFAOYSA-N samarium(iii) sulfide Chemical compound [S-2].[S-2].[S-2].[Sm+3].[Sm+3] KKZKWPQFAZAUSB-UHFFFAOYSA-N 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 235000013772 propylene glycol Nutrition 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 6
- 231100000331 toxic Toxicity 0.000 abstract description 6
- 230000002588 toxic effect Effects 0.000 abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 5
- 239000003086 colorant Substances 0.000 abstract description 4
- 230000036541 health Effects 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- 239000003960 organic solvent Substances 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 2
- 210000000282 nail Anatomy 0.000 description 43
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical group N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- VGHCVSPDKSEROA-UHFFFAOYSA-N 2-methyl-1,4-dioxecane-5,10-dione Chemical compound CC1COC(=O)CCCCC(=O)O1 VGHCVSPDKSEROA-UHFFFAOYSA-N 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000008037 PVC plasticizer Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910006501 ZrSiO Inorganic materials 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- WLZRMCYVCSSEQC-UHFFFAOYSA-N cadmium(2+) Chemical compound [Cd+2] WLZRMCYVCSSEQC-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- VYQRBKCKQCRYEE-UHFFFAOYSA-N ctk1a7239 Chemical compound C12=CC=CC=C2N2CC=CC3=NC=CC1=C32 VYQRBKCKQCRYEE-UHFFFAOYSA-N 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical class OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- SASYSVUEVMOWPL-NXVVXOECSA-N decyl oleate Chemical compound CCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC SASYSVUEVMOWPL-NXVVXOECSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 210000004904 fingernail bed Anatomy 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- QTDSLDJPJJBBLE-PFONDFGASA-N octyl (z)-octadec-9-enoate Chemical compound CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC QTDSLDJPJJBBLE-PFONDFGASA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 229910003447 praseodymium oxide Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a rare earth environment-friendly nail polish which comprises the following components in parts by weight: 50-80 parts of a film forming agent, 5-15 parts of a rare earth pigment, 1-3 parts of a plasticizer and 7-13 parts of water. The invention also provides a preparation method of the nail polish. The nail polish uses the rare earth pigment as a coloring agent, replaces toxic and harmful color paste and pigment in the traditional nail polish, does not contain toxic heavy metal ions, and is green and environment-friendly. The used solvent is completely free of organic solvents such as ethyl acetate, acetone, toluene and the like, belongs to water-based nail polish, is bright in color and strong in covering power, and does not have any threat to human health.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to rare earth environment-friendly nail polish and a preparation method thereof.
Background
Currently, nail polishes used by people are mainly classified into conventional oil-based nail polishes and novel water-based nail polishes. The film forming matter in the oil nail polish is mainly nitrocellulose, while the solvent capable of dissolving the nitrocellulose is generally esters, ketones, benzenes and alcohol ethers, such as ethyl acetate, acetone, phthalate compounds and formaldehyde. The above materials are highly volatile, irritant and toxic. The principle of the nail polish adhering to the nail surface is that the nail surface is firstly damaged, a plurality of rough concave holes are formed on the nail surface, and the nail polish permeates into the concave holes. After long-term use, the pigment is easy to precipitate, and the nails are easy to yellow and crack. Moreover, the solidified oily nail polish is very dense, can prevent the nail plate cells from exchanging gas with the outside, and can thin the surface layer of the nail after being smeared on the surface of the nail for a long time, so that the enamel of the nail is damaged, and the harm to the health of a human body is not negligible.
At present, water-based nail polish products are attracting attention gradually, and the water-based nail polish products are ideal substitutes of oil-based nail polish and have great development potential. Compared with solvent-based products, the water-based products take water as a medium, are nontoxic and tasteless, do not burn or explode, do not pollute the environment and do not bring about the life health problem caused by the volatilization of organic solvents. Meanwhile, the aqueous product has specific coating performance, the coating film has excellent elasticity, flexibility and air permeability, and the aqueous film forming agent has a porous structure after being cured, so that the gas exchange between the nail bed cells and the outside is not hindered. Of course, aqueous products also suffer from disadvantages such as low gloss, slow drying rate, low fullness, poor surface smoothness, low surface hardness, poor adhesion, low durability, and low water resistance.
In addition, the nail polish is colorful because pigments with various colors are added, most of the pigments are cosmetic banned substances, contain toxic heavy metals such as lead and cadmium ions, and have no negligible harm to the body after long-term use. The coloring matters used in nail polish production up to now mainly include color paste, pigment, mica powder, etc., such as CN 109833229A, CN 109970940A.
For the above reasons, there is a need for an aqueous nail varnish in which the colouring substances used are non-toxic and harmless and still have good water resistance, stability and gloss.
In view of this, the invention is particularly proposed.
Disclosure of Invention
The first purpose of the invention is to provide the rare earth environment-friendly nail polish.
The second purpose of the invention is to provide a preparation method of the rare earth environment-friendly nail polish.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the invention relates to a rare earth environment-friendly nail polish which comprises the following components in parts by weight:
50-80 parts of a film forming agent, 5-15 parts of a rare earth pigment, 1-3 parts of a plasticizer and 7-13 parts of water.
Preferably, the nail polish further comprises 0-3 parts of a wetting agent, 0-2 parts of a flatting agent, 0-2 parts of a defoaming agent, 0-2 parts of a thickening agent and 0-3 parts of edible essence.
Preferably, the film forming agent is at least one selected from the group consisting of aqueous polyurethane resins and aqueous polyacrylic acid resins.
Preferably, the rare earth pigment is a rare earth oxide pigment or a rare earth sulfide pigment, and the rare earth sulfide pigment is cerium sulfide or samarium sulfide.
Preferably, the plasticizer is selected from at least one of epoxy ester plasticizers, polyester plasticizers, and phosphate plasticizers.
Preferably, the wetting agent is at least one selected from ethanol, propylene glycol, glycerol, tween-80 and glycerol.
Preferably, the leveling agent is at least one selected from the group consisting of an organic silicon leveling agent and an acrylate leveling agent.
Preferably, the defoaming agent is selected from at least one of mineral oil defoaming agents, silicone defoaming agents, polyether defoaming agents and vegetable oil defoaming agents.
Preferably, the thickener is at least one selected from the group consisting of a cellulose-based thickener, a polyoxyethylene-based thickener, and a polyvinylpyrrolidone thickener.
The invention also relates to a preparation method of the rare earth environment-friendly nail polish, which comprises the following steps:
(1) mixing and uniformly dispersing a film forming agent, a rare earth pigment and a defoaming agent to obtain a first mixture;
(2) sequentially adding a flatting agent, a wetting agent and a plasticizer into the first mixture, and uniformly dispersing to obtain a second mixture;
(3) and adding essence, a thickening agent and water into the second mixture, and uniformly stirring to obtain the nail polish.
The invention has the advantages of
The invention provides a rare earth environment-friendly nail polish, which uses rare earth pigment as a coloring agent to replace toxic and harmful color paste and pigment in the traditional nail polish, does not contain toxic heavy metal ions, and is environment-friendly.
In a preferable scheme, the solvent used in the invention is completely free of organic solvents such as ethyl acetate, acetone, toluene and the like, belongs to water-based nail polish, and has bright color and strong covering power, and does not have any threat to human health.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
The embodiment of the invention relates to a rare earth environment-friendly nail polish which comprises the following components in parts by weight: 50-80 parts of a film forming agent, 5-15 parts of a rare earth pigment, 1-3 parts of a plasticizer and 7-13 parts of water.
Further, the nail polish also comprises 0-3 parts of a wetting agent, 0-2 parts of a flatting agent, 0-2 parts of a defoaming agent, 0-2 parts of a thickening agent and 0-3 parts of edible essence.
In one embodiment of the present invention, the film forming agent is selected from at least one of an aqueous polyurethane resin and an aqueous polyacrylic resin.
The waterborne polyurethane resin has good physical and mechanical properties, and excellent cold resistance and elasticity. The water-based polyacrylic resin has good water resistance and weather resistance. The film formed by the above substances has good water resistance and wear resistance. The nail polish can not swell and fall off when meeting water.
In one embodiment of the invention, the rare earth pigment is a rare earth oxide pigment or a rare earth sulfide pigment, and the rare earth sulfide pigment is cerium sulfide or samarium sulfide. Wherein, the cerium sulfide is red after being added, and the samarium sulfide is yellow after being added. The rare earth oxide is a compound containing one or more rare earth elements, such as a rare earth mixture containing cerium oxide, lanthanum oxide, praseodymium oxide and the like, and shows different colors according to different rare earth elements. Common rare earth oxide pigment such as praseodymium yellow contains zircon as main component, and praseodymium ions are doped in ZrSiO in tetravalent form4In the large lattice, it is lemon yellow. The particle size of the rare earth compound is about 1-10 microns, the color is bright, the color purity is high, and the chemical and physical properties are stable, so that the rare earth compound is harmless to a human body.
In one embodiment of the present invention, the plasticizer is selected from at least one of an epoxy ester plasticizer, a polyester plasticizer, and a phosphate ester plasticizer.
Wherein, the epoxy ester plasticizer is a compound containing a ternary epoxy group, not only has the plasticizing effect, but also can play a role of a stabilizing agent. Common epoxy plasticizers are classified into epoxidized oils, epoxy fatty acid monoesters and epoxy tetrahydrophthalates. Mainly comprises epoxidized soybean oil, epoxidized linseed oil and unsaturated fatty acid epoxidized ester, such as epoxy butyl oleate, epoxy octyl oleate, epoxy decyl oleate, etc. Most epoxy plasticizers have a heat stabilizing effect and are often used in combination with other stabilizers to provide stabilization. Epoxidized vegetable oils have good extraction and migration resistance and are used primarily as PVC plasticizers and stabilizers. The non-toxic epoxidized soybean oil and linseed oil can be used as plasticizers for food contact applications.
The polyester plasticizer has high molecular weight, low volatility, low migration, oil resistance and soapy water extraction resistance, and is a heat-resistant and durable plasticizer with good performance. It can be widely used in oil-resistant and high-temperature resistant special products. Such as poly (1, 2-propylene adipate), and the like.
The phosphate plasticizer is a flame-retardant plasticizer integrating flame-retardant and plasticizing effects, and has good compatibility with resin. Specific examples thereof include tributyl phosphate (TBP), trioctyl phosphate (TOP), and the like.
In one embodiment of the present invention, the wetting agent is generally a surfactant that is a substance that can make solid materials more susceptible to water wetting by reducing its surface energy. As the invention needs to dissolve the materials in an aqueous phase system, the wetting agent is selected from a solvent which has small surface tension and can be mixed with water, such as at least one of ethanol, propylene glycol, glycerol, tween-80 and glycerol.
In one embodiment of the present invention, the leveling agent is selected from at least one of an organic silicon-based leveling agent and an acrylate-based leveling agent.
Among them, surface tension is the main driving force for leveling a coating film, but the difference in surface tension is the main source for generating surface defects of the coating film. It is necessary to reduce the surface tension of the coating film to eliminate the surface tension difference, control the surface state of the coating film, and eliminate surface defects. The organic silicon flatting agent can be selected from polydimethylsiloxane, polyether polyester modified organic siloxane and alkyl modified organic siloxane. The number average molecular weight of the acrylate leveling agent is usually 6000-20000, the molecular weight distribution is relatively narrow, the glass transition temperature is controlled below-20 ℃, and the surface tension is controlled below 25-26 mN/m.
In one embodiment of the present invention, the defoaming agent is selected from at least one of mineral oil type defoaming agents, silicone type defoaming agents, polyether type defoaming agents, and vegetable oil defoaming agents.
Defoamers are substances that reduce the surface tension of water, solutions, suspensions, etc., prevent the formation of foam, or reduce or eliminate the original foam. The oil in the mineral oil defoamer may be mineral oil, vegetable oil, white oil or any other oil that is insoluble in the foaming medium other than silicone oil. Mineral oil defoamers also contain waxes and/or hydrophobic silicas to enhance performance. Typical waxes are ethylene bis stearamide, paraffin waxes, ester waxes and fatty alcohol waxes.
The main component of the silicone antifoaming agent is linear polysiloxane (also called silicone oil) capable of keeping liquid state at room temperature, which is mainly of the following types: polydimethyl siloxane, fluorosilicone, ethylene glycol siloxane, and the like.
The polyether defoamer can be classified into polyol type, fatty acid ester type and amine ether type according to different initiators used for synthesis, wherein the polyether defoamer is widely applied to the polyol type and the fatty acid ester type. The main products of this type are: GP type glyceryl polyether, GPE type polyoxyethylene (polyoxypropylene) ether, PPG type polypropylene glycol and the like.
In one embodiment of the present invention, the thickener is at least one selected from the group consisting of a cellulose-based thickener, a polyoxyethylene-based thickener, and a polyvinylpyrrolidone thickener.
The thickening agent can increase the viscosity of a system, so that the system can keep a uniform and stable suspension state, an emulsion state or form a gel, and most thickening agents have an emulsifying function. Wherein the cellulose thickener comprises methylcellulose, hydroxyethyl cellulose, hydroxypropyl methylcellulose, and sodium carboxymethylcellulose. The polyoxyethylene thickening agent mainly comprises fatty alcohol polyoxyethylene ether sulfate (AES), and can be prepared into proper viscosity only by inorganic salt under normal conditions.
The invention also relates to a preparation method of the rare earth environment-friendly nail polish, which comprises the following steps:
(1) mixing and uniformly dispersing a film forming agent, a rare earth pigment and a defoaming agent to obtain a first mixture;
(2) sequentially adding a flatting agent, a wetting agent and a plasticizer into the first mixture, and uniformly dispersing to obtain a second mixture;
(3) adding edible essence, thickening agent and water into the second mixture, and uniformly stirring to obtain the nail polish.
Examples/comparative examples
(1) Mixing the film forming agent, the rare earth pigment and the defoaming agent, and uniformly stirring by using a dispersion machine to obtain a first mixture;
(2) sequentially adding a flatting agent, a wetting agent and a plasticizer into the first mixture, and uniformly dispersing to obtain a second mixture;
(3) and adding essence, a thickening agent and water into the second mixture, and uniformly stirring to obtain the nail polish. The ingredients and amounts of the raw materials are shown in Table 1.
TABLE 1
The performance tests were performed on the above-described example and comparative product, comprising the following steps:
(1) waterproof performance test of nail polish:
coating the nail polish on the surface of a PET film, adopting an aluminum foil laminating process, curing and peeling the aluminum foil to prepare a film sample, wherein the thickness of the film sample is 0.5 +/-0.1 mm. The film sample was immersed in deionized water, and the degree of peeling of the surface of the film sample was observed after one week, and the results are shown in Table 2.
(2) Folding endurance test of nail polish:
coating the nail polish on the surface of a PET film, adopting an aluminum foil laminating process, curing and peeling the aluminum foil to prepare a film sample, wherein the thickness of the film sample is 0.5 +/-0.1 mm. The film samples were folded back and forth and the number of folds at which cracks appeared was calculated and the results are shown in Table 2.
TABLE 2
As can be seen from Table 2, when the amounts of the respective components are within the range of the present invention, the resulting rare earth nail polish has good water-repellent and folding resistance properties. However, when at least one of a film forming agent, 1 to 3 parts of a plasticizer, a wetting agent, a leveling agent, a defoaming agent, and a thickener is not used, the above properties are lowered.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.
Claims (10)
1. The rare earth environment-friendly nail polish is characterized by comprising the following components in parts by weight: 50-80 parts of a film forming agent, 5-15 parts of a rare earth pigment, 1-3 parts of a plasticizer and 7-13 parts of water.
2. The environment-friendly rare earth nail polish as claimed in claim 1, wherein the nail polish further comprises 0-3 parts of a wetting agent, 0-2 parts of a leveling agent, 0-2 parts of a defoaming agent, 0-2 parts of a thickening agent and 0-3 parts of an edible essence.
3. The rare earth environment-friendly nail polish according to claim 1, wherein the film forming agent is at least one selected from an aqueous polyurethane resin and an aqueous polyacrylic resin.
4. The rare earth environment-friendly nail polish as claimed in claim 1, wherein the rare earth pigment is a rare earth oxide pigment or a rare earth sulfide pigment, and the rare earth sulfide is cerium sulfide or samarium sulfide.
5. The rare earth environment-friendly nail polish according to claim 1, wherein the plasticizer is selected from at least one of epoxy ester plasticizers, polyester plasticizers and phosphate plasticizers.
6. The rare earth environment-friendly nail polish according to claim 2, wherein the wetting agent is at least one selected from ethanol, propylene glycol, glycerin, tween-80 and glycerol.
7. The rare earth environment-friendly nail polish as claimed in claim 2, wherein the leveling agent is at least one selected from a silicone leveling agent and an acrylate leveling agent.
8. The rare earth environment-friendly nail polish as claimed in claim 2, wherein the defoaming agent is at least one selected from mineral oil defoaming agents, silicone defoaming agents, polyether defoaming agents and vegetable oil defoaming agents.
9. The rare earth environment-friendly nail polish as claimed in claim 2, wherein the thickener is at least one selected from the group consisting of cellulose-based thickeners, polyoxyethylene-based thickeners, and polyvinylpyrrolidone thickeners.
10. The preparation method of the rare earth environment-friendly nail polish as claimed in claim 2, is characterized by comprising the following steps of:
(1) mixing and uniformly dispersing a film forming agent, a rare earth pigment and a defoaming agent to obtain a first mixture;
(2) sequentially adding a flatting agent, a wetting agent and a plasticizer into the first mixture, and uniformly dispersing to obtain a second mixture;
(3) and adding essence, a thickening agent and water into the second mixture, and uniformly stirring to obtain the nail polish.
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| CN201911224705.0A CN110876687A (en) | 2019-12-04 | 2019-12-04 | Rare earth environment-friendly nail polish and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0203838A2 (en) * | 1985-04-30 | 1986-12-03 | Rhone-Poulenc Chimie | Use of coloured pigments based on rare earths sulphurs in plastics, paints, or vanishes |
| CN106309168A (en) * | 2016-10-21 | 2017-01-11 | 熊廷珍 | Full-nutrition type aqueous nail enamel |
-
2019
- 2019-12-04 CN CN201911224705.0A patent/CN110876687A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0203838A2 (en) * | 1985-04-30 | 1986-12-03 | Rhone-Poulenc Chimie | Use of coloured pigments based on rare earths sulphurs in plastics, paints, or vanishes |
| CN106309168A (en) * | 2016-10-21 | 2017-01-11 | 熊廷珍 | Full-nutrition type aqueous nail enamel |
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Application publication date: 20200313 |