CN110846104A - Aluminum plate and foil rolling additive composition - Google Patents
Aluminum plate and foil rolling additive composition Download PDFInfo
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- CN110846104A CN110846104A CN201911162958.XA CN201911162958A CN110846104A CN 110846104 A CN110846104 A CN 110846104A CN 201911162958 A CN201911162958 A CN 201911162958A CN 110846104 A CN110846104 A CN 110846104A
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- percent
- additive composition
- foil rolling
- ester
- aluminum plate
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- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 239000000654 additive Substances 0.000 title claims abstract description 34
- 230000000996 additive effect Effects 0.000 title claims abstract description 33
- 239000011888 foil Substances 0.000 title claims abstract description 28
- 238000005096 rolling process Methods 0.000 title claims abstract description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 20
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 19
- -1 fatty acid ester Chemical class 0.000 claims abstract description 17
- 150000002148 esters Chemical class 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 9
- 229920000570 polyether Polymers 0.000 claims abstract description 9
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 6
- 229930195729 fatty acid Natural products 0.000 claims abstract description 6
- 239000000194 fatty acid Substances 0.000 claims abstract description 6
- 239000010452 phosphate Substances 0.000 claims abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 8
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 claims description 5
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 4
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 abstract description 7
- 239000003814 drug Substances 0.000 abstract description 6
- 229940079593 drug Drugs 0.000 abstract description 6
- 239000003921 oil Substances 0.000 description 7
- 238000009736 wetting Methods 0.000 description 5
- 239000010725 compressor oil Substances 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000005097 cold rolling Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000010731 rolling oil Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M165/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/02—Well-defined aliphatic compounds
- C10M2203/022—Well-defined aliphatic compounds saturated
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses an aluminum plate and foil rolling additive composition, which comprises the following components: C14-C18 isoparaffin, C10-C18 mixed fatty alcohol, C10-C18 mixed fatty acid ester, low molecular weight polyether ester and phosphate extreme pressure agent. The aluminum plate and foil rolling additive composition adopts medium-carbon-chain high-purity fatty alcohol, high-purity synthetic ester and compound low-molecular-weight polyether ester, is a volatile and low-residue compound rolling additive, has the oil film strength far higher than that of a traditional alcohol ester compound additive, and meets the special requirements of drug foil rolling.
Description
Technical Field
The invention relates to an additive for cold rolling of aluminum plate and strip foil, in particular to an additive composition for rolling of drug foil.
Background
The medicinal aluminum foil is used in a large amount on packaging materials of various medicines such as tablets, pills, capsules, granules and the like, and is packaged in an aluminum-plastic bubble cap mode, and the package not only can better protect the quality performance of the medicines, but also has the characteristics of high packaging production speed, low cost, light weight, small storage space, convenience in transportation and use and the like.
At present, 8011 alloy foil is mostly adopted as the medicinal aluminum foil, the thickness is 0.02mm, and the state is H18. The quality control of the medicinal foil has the requirement of surface wetting property, the surface wetting tension is required to be more than or equal to 34dyn/mm, the surface wetting property is closely related to the oil carried on the surface of a finished medicinal foil product, and the surface wetting property of the medicinal foil is influenced because the surface tension is reduced due to the fact that more oil is carried on the surface. The contradiction between the oil film strength and the residue of the rolling oil additive can occur when the traditional alcohol ester acid additive is adopted, the volatility of the additive is good, the residue is less, the oil film strength is insufficient, the rolling process is influenced, and vice versa.
Disclosure of Invention
The invention aims to provide an aluminum plate and foil rolling additive composition, which adopts medium-carbon chain high-purity fatty alcohol, high-purity synthetic ester and compound low-molecular-weight polyether ester, is a volatile and low-residue compound rolling additive, has oil film strength far higher than that of a traditional alcohol ester compound additive, and meets the special requirements of drug foil rolling.
In order to achieve the purpose, the technical scheme of the invention is to design an aluminum plate, strip and foil rolling additive composition, which comprises the following components in percentage by weight:
5 to 15 percent of C14 to C18 isoparaffin,
20 to 60 percent of C10 to C18 mixed fatty alcohol,
20 to 60 percent of C10 to C18 mixed fatty acid ester,
10 to 30 percent of low molecular weight polyether ester,
0.01 to 0.1 percent of phosphate extreme pressure agent.
Preferably, the isoparaffin is a C16 isoparaffin.
Preferably, the mixed fatty alcohol is a mixture of C12 straight chain fatty alcohol and C14 isomeric fatty alcohol.
Preferably, the mixed fatty acid ester is a mixture of methyl C12-carboxylate and isopropyl C12-carboxylate.
Preferably, the low molecular weight polyether ester is an esterified derivative of PEG 200.
Preferably, the phosphate ester extreme pressure agents include triphenyl phosphate and tributyl phosphate.
The invention has the advantages and beneficial effects that: the aluminum plate and foil rolling additive composition adopts medium-carbon-chain high-purity fatty alcohol, high-purity synthetic ester and compound low-molecular-weight polyether ester, is a volatile and low-residue compound rolling additive, has the oil film strength far higher than that of a traditional alcohol ester compound additive, and meets the special requirements of drug foil rolling.
The aluminum plate and strip foil cold rolling is carried out by adopting the composite additive of the invention, and the composite additive has the following characteristics:
1. the aluminum foil can be rolled only by adopting the composite additive, and other additives do not need to be added at the same time, so that the complexity of compounding is reduced;
2. the volatility of the additive is accurately controlled, the residue is very little, and the additive is easy to purge;
3. the additive has high oil film strength, and can reduce the use amount by 10-20% compared with the traditional compound additive;
4. by adopting the additive, the wetting tension of the finished aluminum foil product is high, can easily reach more than 34dyn/mm, and the attenuation is little.
Detailed Description
The following further describes embodiments of the present invention with reference to examples. The following examples are only for illustrating the technical solutions of the present invention more clearly, and the protection scope of the present invention is not limited thereby.
The invention relates to an aluminum plate, strip and foil rolling additive composition, which comprises the following components in percentage by weight:
5 to 15 percent of C14 to C18 isoparaffin,
20 to 60 percent of C10 to C18 mixed fatty alcohol,
20 to 60 percent of C10 to C18 mixed fatty acid ester,
10 to 30 percent of low molecular weight polyether ester,
0.01 to 0.1 percent of phosphate extreme pressure agent.
The specific embodiment of the invention is as follows:
example 1
The polyol ester air compressor oil composition comprises the following components in percentage by weight:
c14 isoparaffin: 5 percent of the total weight of the mixture,
mixture of C12 straight chain fatty alcohols and C14 isomeric fatty alcohols: the content of the active carbon is 58 percent,
mixture of methyl C12 acid and isopropyl C12 acid: 25 percent of the total weight of the mixture,
esterified derivatives of PEG 200: 11.9 percent of the total weight of the steel,
triphenyl phosphate: 0.1 percent.
Example 2
The polyol ester air compressor oil composition comprises the following components in percentage by weight:
c18 isoparaffin: 15 percent of the total weight of the mixture is less than or equal to 15 percent,
mixture of C12 straight chain fatty alcohols and C14 isomeric fatty alcohols: 24.9 percent of the total weight of the steel,
mixture of methyl C12 acid and isopropyl C12 acid: 30 percent of the total weight of the mixture,
esterified derivatives of PEG 200: 30 percent of the total weight of the mixture,
tributyl phosphate ester: 0.1 percent.
Example 3
The polyol ester air compressor oil composition comprises the following components in percentage by weight:
c16 isoparaffin: 10 percent of the total weight of the mixture,
mixture of C12 straight chain fatty alcohols and C14 isomeric fatty alcohols: 42.9 percent of the total weight of the steel,
mixture of methyl C12 acid and isopropyl C12 acid: 24 percent of the total weight of the mixture,
esterified derivatives of PEG 200: 23 percent of the total weight of the mixture,
mixture of triphenyl phosphate and tributyl phosphate: 0.1 percent.
The polyol ester air compressor oil composition of example 3 had the following performance test results:
appearance: a colorless transparent liquid;
density: 0.849 g/mL;
kinematic viscosity @40 ℃: 5.832 mm2/s；
Closed flash point: 93 ℃;
hydroxyl value: 170 mgKOH/g;
saponification value: 100 mgKOH/g;
pb value (10% dissolved in D80 base oil): 44 kg.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the technical principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (6)
1. The aluminum plate and foil rolling additive composition is characterized by comprising the following components in percentage by weight:
5 to 15 percent of C14 to C18 isoparaffin,
20 to 60 percent of C10 to C18 mixed fatty alcohol,
20 to 60 percent of C10 to C18 mixed fatty acid ester,
10 to 30 percent of low molecular weight polyether ester,
0.01 to 0.1 percent of phosphate extreme pressure agent.
2. The aluminum plate and strip foil rolling additive composition of claim 1, wherein the isoparaffin is a C16 isoparaffin.
3. The aluminum and strip foil rolling additive composition of claim 1, wherein the mixed fatty alcohol is a mixture of a C12 straight chain fatty alcohol and a C14 isomeric fatty alcohol.
4. The aluminum foil rolling additive composition of claim 1 wherein the mixed fatty acid ester is a mixture of methyl C12 acid ester and isopropyl C12 ester.
5. The additive composition for aluminum foil rolling as claimed in claim 1, wherein the low molecular weight polyether ester is an esterified derivative of PEG 200.
6. The aluminum sheet, strip, foil rolling additive composition of claim 1, wherein the phosphate extreme pressure agent comprises triphenyl phosphate and tributyl phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911162958.XA CN110846104A (en) | 2019-11-25 | 2019-11-25 | Aluminum plate and foil rolling additive composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911162958.XA CN110846104A (en) | 2019-11-25 | 2019-11-25 | Aluminum plate and foil rolling additive composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110846104A true CN110846104A (en) | 2020-02-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911162958.XA Pending CN110846104A (en) | 2019-11-25 | 2019-11-25 | Aluminum plate and foil rolling additive composition |
Country Status (1)
| Country | Link |
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| CN (1) | CN110846104A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111548847A (en) * | 2020-05-27 | 2020-08-18 | 华阳新兴科技（天津）集团有限公司 | Aluminum foil rolling lubricating oil, preparation method and application |
| CN113293050A (en) * | 2021-05-10 | 2021-08-24 | 内蒙古联晟新能源材料有限公司 | Rolling oil for realizing large reduction amount by two-continuous rolling and production method thereof |
| CN113444559A (en) * | 2021-07-30 | 2021-09-28 | 奎克化学（中国）有限公司 | Battery foil rolling additive and preparation method and application thereof |
| CN116024030A (en) * | 2022-12-12 | 2023-04-28 | 石家庄新泰特种油有限公司 | Additive for rolling power battery foil and preparation method and application thereof |
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|---|---|---|---|---|
| JP2009029913A (en) * | 2007-07-26 | 2009-02-12 | Sumitomo Light Metal Ind Ltd | Aluminum pipe drawing lubricating oil and aluminum pipe drawing method using the same |
| CN102199476A (en) * | 2011-04-29 | 2011-09-28 | 上海德润宝特种润滑剂有限公司 | Volatile stamping cutting oil composite for machining for machining of moderate-thickness aluminum plate and preparation method thereof |
| CN102952611A (en) * | 2011-08-25 | 2013-03-06 | 中国石油化工股份有限公司 | Rolling oil composition for cold-rolled sheet |
| CN105925342A (en) * | 2016-04-27 | 2016-09-07 | 中铝润滑科技有限公司 | A kind of composite high-pressure additive for aluminum cold rolling and its application |
| CN109705970A (en) * | 2019-03-04 | 2019-05-03 | 福建嘉富顿环保科技有限公司 | A kind of dedicated cutting fluid of full synthetic aluminum alloy and preparation method thereof |
-
2019
- 2019-11-25 CN CN201911162958.XA patent/CN110846104A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009029913A (en) * | 2007-07-26 | 2009-02-12 | Sumitomo Light Metal Ind Ltd | Aluminum pipe drawing lubricating oil and aluminum pipe drawing method using the same |
| CN102199476A (en) * | 2011-04-29 | 2011-09-28 | 上海德润宝特种润滑剂有限公司 | Volatile stamping cutting oil composite for machining for machining of moderate-thickness aluminum plate and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111548847A (en) * | 2020-05-27 | 2020-08-18 | 华阳新兴科技（天津）集团有限公司 | Aluminum foil rolling lubricating oil, preparation method and application |
| CN111548847B (en) * | 2020-05-27 | 2022-03-18 | 华阳新兴科技（天津）集团有限公司 | Aluminum foil rolling lubricating oil, preparation method and application |
| CN113293050A (en) * | 2021-05-10 | 2021-08-24 | 内蒙古联晟新能源材料有限公司 | Rolling oil for realizing large reduction amount by two-continuous rolling and production method thereof |
| CN113444559A (en) * | 2021-07-30 | 2021-09-28 | 奎克化学（中国）有限公司 | Battery foil rolling additive and preparation method and application thereof |
| CN116024030A (en) * | 2022-12-12 | 2023-04-28 | 石家庄新泰特种油有限公司 | Additive for rolling power battery foil and preparation method and application thereof |
| CN116024030B (en) * | 2022-12-12 | 2024-05-03 | 石家庄新泰特种油有限公司 | Additive for rolling power battery foil and preparation method and application thereof |
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Application publication date: 20200228 |
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