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CN110744649A - Anti-cracking low-aldehyde multi-layer eucalyptus board and production method thereof - Google Patents

Anti-cracking low-aldehyde multi-layer eucalyptus board and production method thereof Download PDF

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CN110744649A
CN110744649A CN201911208439.2A CN201911208439A CN110744649A CN 110744649 A CN110744649 A CN 110744649A CN 201911208439 A CN201911208439 A CN 201911208439A CN 110744649 A CN110744649 A CN 110744649A
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陈姗姗
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Guangxi Hengxian Zhenglin Wood Industry Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • B27D1/04Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • B27D1/04Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
    • B27D1/08Manufacture of shaped articles; Presses specially designed therefor

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Abstract

本发明提供了一种防裂低醛多层桉木板及其生产方法,该多层板的生产方法包括单板薄板分选、薄板涂胶、冷压、热压、静置养生和刮灰、砂光、修补、切边和贴面板的步骤,其特点是:在第一次热压和最后一次热压之前在板坯四周和上下表面喷涂一层固化膜,保护防止胶水在热压过程过快干燥,并保持多层板内部的应力,还可以使脲醛胶水充分反应完全,使之成型后的多层板不易开裂,用户使用过程减少了挥发性甲醛,热压以后板材经过静置养生、砂光及贴面板,即可锯边包装得到防裂低醛多层桉木板产品。

Figure 201911208439

The invention provides an anti-cracking low-aldehyde multi-layer eucalyptus board and a production method thereof. The production method of the multi-layer board comprises veneer sheet sorting, sheet gluing, cold pressing, hot pressing, standing for curing and scraping dust, The steps of sanding, repairing, trimming and veneering, which are characterized by spraying a cured film around and on the upper and lower surfaces of the slab before the first hot pressing and the last hot pressing to protect the glue from passing through the hot pressing process. It dries quickly and maintains the internal stress of the multi-layer board. It can also make the urea-formaldehyde glue fully react, so that the formed multi-layer board is not easy to crack. The user's use process reduces the volatile formaldehyde. After sanding and veneering, it can be sawed and packaged to obtain crack-resistant low-aldehyde multi-layer eucalyptus board products.

Figure 201911208439

Description

防裂低醛多层桉木板及其生产方法Anti-cracking low-aldehyde multi-layer eucalyptus board and production method thereof

技术领域technical field

本发明涉及一种多层木板及其生产方法,特别是防裂低醛多层桉木板及其生产方法。The invention relates to a multi-layer wood board and a production method thereof, in particular to a crack-resistant low-aldehyde multi-layer eucalyptus wood board and a production method thereof.

背景技术Background technique

多层木板是由木段旋切成单板或由木方刨切成薄木,再用胶粘剂胶合而成的多层的板状材料,通常并使相邻层单板的纤维方向互相垂直胶合而成,外面根据需要贴面或不贴面,也称胶合多层板。The multi-layer board is a multi-layer board material made of wood segments that are cut into veneers or sliced into veneers, and then glued with adhesives. Usually, the fiber directions of adjacent layers of veneers are glued perpendicular to each other. The outside is veneered or not veneered as needed, also known as plywood.

多层木板是家具常用材料之一,为人造板三大板之一,亦可供飞机、船舶、火车、汽车、建筑和包装箱等作用材。通常其表板和内层板对称地配置在中心层或板芯的两侧。用涂胶后的单板按木纹方向纵横交错配成的板坯,在加热或不加热的条件下压制而成。层数一般为奇数,少数也有偶数。纵横方向的物理、机械性质差异较小。常用的胶合板类型有三合板、五合板,目前有七层以上。胶合板能提高木材利用率,是节约木材的一个主要途径。主要树种有:榉木、山樟、柳按、杨木、桉木等。Multi-layer wood is one of the commonly used materials for furniture, one of the three major wood-based panels, and can also be used for aircraft, ships, trains, automobiles, buildings and packaging boxes. Usually, the surface plate and the inner layer are symmetrically arranged on both sides of the center layer or the core. It is a slab made of glued veneers crisscrossed in the direction of the wood grain, and pressed under the condition of heating or no heating. The number of layers is generally odd, and a few are even. The physical and mechanical properties in the vertical and horizontal directions are slightly different. Commonly used plywood types are three plywood and five plywood, and there are currently more than seven layers. Plywood can improve the utilization rate of wood and is a main way to save wood. The main tree species are: beech, camphor, willow, poplar, eucalyptus and so on.

为了尽量改善天然木材各向异性的特性,使胶合板特性均匀、形状稳定,一般胶合板在结构上都要遵守两个基本原则:一是对称;二是相邻层单板纤维互相垂直。对称原则就是要求胶合板对称中心平面两侧的单板,无论木材性质、单板厚度,层数、纤维方向,含水率等,都应该互相对称。在同一张胶合板中,可以使用单一树种和厚度的单板,也可以使用不同树种和厚度的单板;但对称中心平面两侧任何两层互相对称的单板树种和厚度要一样。面背板允许不是同一树种。In order to improve the anisotropic properties of natural wood as much as possible, so that the properties of plywood are uniform and the shape is stable, generally plywood must comply with two basic principles in structure: one is symmetry; the other is that adjacent layers of veneer fibers are perpendicular to each other. The principle of symmetry is that the veneers on both sides of the symmetrical center plane of the plywood should be symmetrical to each other regardless of the nature of the wood, the thickness of the veneer, the number of layers, the direction of the fibers, and the moisture content. In the same plywood, veneers of a single species and thickness can be used, or veneers of different species and thicknesses can be used; however, any two layers of veneer that are symmetrical to each other on both sides of the symmetrical center plane must be of the same species and thickness. The front and back panels are not allowed to be of the same tree species.

为了充分合理地利用森林资源发展胶合板生产,做到材尽其用,我国新制订的国家标准根据胶合扳使用情况,将胶合板分为涂饰用胶合板(用于表面需要涂饰透明涂料的家具、缝纫机台板和各种电器外壳等制品)、装修用胶合板(用作建筑、家具,车辆和船舶、地板的装修材料),一般用胶合板(适用于包装,垫衬及其它方面用途)和薄木装饰胶合板(用作建筑,家具,车辆,船舶等的高级装饰材料)。In order to make full and rational use of forest resources to develop plywood production and make the best use of materials, the newly formulated national standard in my country divides plywood into plywood for painting (for furniture and sewing machine tables that need to be painted with transparent paint) according to the use of plywood. panels and various electrical enclosures and other products), plywood for decoration (used as decoration materials for buildings, furniture, vehicles and ships, floors), plywood for general use (for packaging, padding and other purposes) and veneer decorative plywood ( Used as a high-grade decorative material for buildings, furniture, vehicles, ships, etc.).

近年来,我国南方的两广、云南、福建、贵州、海南等省开始引种由广西国有东门林场培育的速生桉树种,速生桉木是一种浅色的阔叶木,木纹紧密而不规则,边材层比较宽,呈白至淡粉色;心材有的浅棕红色。目前速生桉生长速度快,3年可成才,山区农民大量种植,已经占南方可利用木材的50%以上,加上原有树种如松树、杉树、苦楝树等树木生长较慢,作为天然林不再能够乱砍伐,而且1亩速生桉的木材产量相当于5亩以上的天然林产量,In recent years, Guangdong and Guangxi, Yunnan, Fujian, Guizhou, Hainan and other provinces in southern my country have begun to introduce fast-growing eucalyptus species cultivated by the state-owned Dongmen Forest Farm in Guangxi. The sapwood layer is relatively broad, white to pale pink; the heartwood is slightly brownish red. At present, fast-growing eucalyptus grows fast and can become a talent in 3 years. Farmers in mountainous areas plant a large number of them, which have accounted for more than 50% of the available wood in the south. In addition, the original tree species such as pine, fir, neem and other trees grow slowly, and it is not a natural forest. It can be cut down again, and the wood output of 1 mu of fast-growing eucalyptus is equivalent to the output of more than 5 mu of natural forest.

桉树只占广西森林面积的13.7%,却解决了广西80%以上、全国20%以上的木材需求。而目前我国成功地开发了高性能桉木重组材、桉木单板层积材、竹桉复合材料、厚芯桉树实木复合板材和无醛桉木胶合板制造技术等,桉木在人造板的应用越来越普及。Eucalyptus only accounts for 13.7% of Guangxi's forest area, but it meets more than 80% of Guangxi's and more than 20% of the country's wood demand. At present, my country has successfully developed high-performance eucalyptus reconstituted lumber, eucalyptus veneer laminated lumber, bamboo eucalyptus composite materials, thick-core eucalyptus solid wood composite boards and formaldehyde-free eucalyptus plywood manufacturing technology, etc. The application of eucalyptus in wood-based panels increasingly popular.

而实木复合多层板的芯层多采用桉树单片通过胶黏剂压合而成。桉树是桃金娘科Myrtaceae 桉属 Eucalyptus 植物的统称,桉树适应性强,贫瘠的土壤中也能够生长,且生长速度快,护理成本低,因此种植面积逐年增加。桉树木材红色、有光泽、无特殊气味、纹理交错、结构密、材质硬重,易弯曲。径级较大的桉树通过旋切成单板,作为芯板生产胶合板或单板层积材,而小径级、枝丫材或难以旋切的桉树加工成木片,用于造纸或生产纤维板,因此桉树的综合利用率可以提高至90%以上。The core layer of the solid wood composite multi-layer board is mostly made of eucalyptus single sheet through adhesive pressing. Eucalyptus is a general term for Eucalyptus plants in the Myrtaceae family. Eucalyptus has strong adaptability and can grow in poor soil with fast growth and low maintenance costs, so the planting area is increasing year by year. Eucalyptus wood is red, shiny, no special odor, interlaced texture, dense structure, hard and heavy material, easy to bend. Eucalyptus with larger diameter grades is cut into veneer by rotary cutting and used as core board to produce plywood or laminated veneer lumber, while eucalyptus with small diameter grade, branch wood or difficult rotary cutting is processed into wood chips for papermaking or production of fiberboard, so eucalyptus The comprehensive utilization rate can be increased to more than 90%.

本申请人广西横县正林木业有限公司目前是采用实木复合多层板的生产企业,这几年根据国内外的市场需求,对目前桉木复合板的工艺特点进行了很多改进,生产了挥发性甲醛少、强度高、适合建筑、家具,车辆和船舶的装修材料的桉木复合板,也申请了多项中国专利,例如:The applicant, Guangxi Hengxian Zhenglin Wood Industry Co., Ltd. is currently a manufacturer of solid wood composite multi-layer boards. Eucalyptus wood composite panels with less formaldehyde and high strength, suitable for decoration materials of buildings, furniture, vehicles and ships, have also applied for a number of Chinese patents, such as:

[1]采用防虫防霉复合脲醛树脂生产全桉木胶合板的方法,201610746220.8;106182218B,申请人:广西横县正林木业有限公司,申请日:2016-08-29,摘要:本发明采用防虫防霉复合脲醛树脂生产全桉木胶合板的方法,包括如下步骤:木板旋片→单板干燥→涂胶→三次冷压→静置养生→三次热压→散热养生→板坯定厚砂光。本发明生产方法的关键是采用三聚氰胺改性脲醛树脂为胶黏剂主料,添加氧化淀粉为粘性复合剂;[1] The method for producing all-eucalyptus plywood by using the compound urea-formaldehyde resin for insect and mildew control, 201610746220.8; 106182218B, applicant: Guangxi Hengxian Zhenglin Wood Industry Co., Ltd., application date: 2016-08-29, abstract: the present invention adopts insect and mildew control The method for producing all-eucalyptus plywood with composite urea-formaldehyde resin comprises the following steps: board rotation → veneer drying → gluing → three cold pressings → standing and curing → three hot pressings → heat dissipation and curing → slab thickness sanding. The key of the production method of the present invention is to use melamine-modified urea-formaldehyde resin as the main material of the adhesive, and add oxidized starch as the adhesive compound;

[2]采用耐高温复合脲醛树脂生产桉木桦木复合地板的方法,201610747076.X;106272849B,申请人:广西横县正林木业有限公司,申请日:2016-08-29 ,摘要:本发明采用耐高温复合脲醛树脂生产桉木桦木复合地板的方法,步骤为:木板旋片→单板干燥→涂胶→三次冷压→静置养生→三次热压→散热养生→板坯定厚砂光→基材表层涂胶→养生开槽→淋漆干燥定型。本发明生产方法的关键是采用三聚氰胺改性脲醛树脂为胶黏剂主料。[2] The method for producing eucalyptus birch wood composite floor by using high temperature-resistant composite urea-formaldehyde resin, 201610747076.X; 106272849B, applicant: Guangxi Hengxian Zhenglin Wood Industry Co., Ltd., application date: 2016-08-29, abstract: the present invention adopts resistant The method for producing eucalyptus birch composite floor with high temperature composite urea-formaldehyde resin, the steps are: plank rotation → veneer drying → gluing → three cold pressing → standing and curing → three hot pressing → heat dissipation and curing → slab thickness sanding → base Glue coating on the surface of the material → health grooving → lacquer drying and shaping. The key of the production method of the present invention is to use melamine-modified urea-formaldehyde resin as the main material of the adhesive.

[3]采用防腐复合脲醛树脂生产全桉木胶合板的方法,201610747071.7,106313201B,申请人:广西横县正林木业有限公司,申请日:2016-08-29,摘要:本发明采用防腐复合脲醛树脂生产全桉木胶合板的方法,包括如下步骤:木板旋片→单板干燥→涂胶→三次冷压→静置养生→三次热压→散热养生→板坯定厚砂光。本发明生产方法的关键是采用三聚氰胺改性脲醛树脂为胶黏剂主料,添加氧化淀粉为粘性复合剂;[3] Method for producing all-eucalyptus plywood by using anti-corrosion composite urea-formaldehyde resin, 201610747071.7, 106313201B, applicant: Guangxi Hengxian Zhenglin Wood Industry Co., Ltd., application date: 2016-08-29, abstract: the present invention adopts anti-corrosion composite urea-formaldehyde resin to produce The method for the whole eucalyptus plywood comprises the following steps: board rotation → veneer drying → gluing → three cold pressing → standing for curing → three hot pressing → heat dissipation and curing → slab thickness sanding. The key of the production method of the present invention is to use melamine-modified urea-formaldehyde resin as the main material of the adhesive, and add oxidized starch as the adhesive compound;

[4]采用防虫防霉复合脲醛树脂生产桉木桦木复合地板的方法,201610747086.3;106335120B,申请人:广西横县正林木业有限公司,申请日:2016-08-29 ,摘要:采用防虫防霉复合脲醛树脂生产桉木桦木复合地板的方法,步骤为:木板旋片→单板干燥→涂胶→三次冷压→静置养生→三次热压→散热养生→板坯定厚砂光→基材表层涂胶→养生开槽→淋漆干燥定型。本发明生产方法的关键是采用三聚氰胺改性脲醛树脂为胶黏剂主料。[4] The method of producing eucalyptus birch wood composite floor by using insect-proof and mildew-proof compound urea-formaldehyde resin, 201610747086.3; 106335120B, applicant: Guangxi Hengxian Zhenglin Wood Industry Co., Ltd., application date: 2016-08-29, abstract: the use of insect-proof and mildew-proof composite floor The method for producing eucalyptus birch composite floor from urea-formaldehyde resin comprises the following steps: plank rotation → veneer drying → gluing → three cold pressings → standing and curing → three hot pressings → heat dissipation and curing → slab thickness sanding → substrate surface Gluing → health grooving → lacquer drying and shaping. The key of the production method of the present invention is to use melamine-modified urea-formaldehyde resin as the main material of the adhesive.

[5]采用耐候性复合脲醛树脂生产桉木桦木复合地板的方法,201610746169.0,106272848B,申请人:广西横县正林木业有限公司,申请日:2016-08-29 ,摘要:本发明采用耐候性复合脲醛树脂生产桉木桦木复合地板的方法,步骤为:木板旋片→单板干燥→涂胶→三次冷压→静置养生→三次热压→散热养生→板坯定厚砂光→基材表层涂胶→养生开槽→淋漆干燥定型。本发明生产方法的关键是采用三聚氰胺改性脲醛树脂为胶黏剂主料。[5] The method for producing eucalyptus birch composite floor by using weather-resistant composite urea-formaldehyde resin, 201610746169.0, 106272848B, applicant: Guangxi Hengxian Zhenglin Wood Industry Co., Ltd., application date: 2016-08-29, abstract: the present invention adopts weather-resistant composite floor The method for producing eucalyptus birch composite floor from urea-formaldehyde resin comprises the following steps: plank rotation → veneer drying → gluing → three cold pressings → standing and curing → three hot pressings → heat dissipation and curing → slab thickness sanding → substrate surface Gluing → health grooving → lacquer drying and shaping. The key of the production method of the present invention is to use melamine-modified urea-formaldehyde resin as the main material of the adhesive.

[6]采用阻燃复合脲醛树脂生产橱柜板的方法,201610752586.6,申请人:广西横县正林木业有限公司,申请日:2016-08-29,摘要:本发明涉及一种家居建材,尤其涉及采用阻燃复合脲醛树脂生产橱柜板的方法,该橱柜板由上至下的结构依次为:装饰纸、杉木单板、刨花板、背板;橱柜板的四周用铝合金镶边;杉木单板与刨花板之间涂覆阻燃复合脲醛树脂胶黏剂,刨花板与背板之间涂覆阻燃复合脲醛树脂。[6] Method for producing cabinet board by using flame-retardant composite urea-formaldehyde resin, 201610752586.6, applicant: Guangxi Hengxian Zhenglin Wood Industry Co., Ltd., application date: 2016-08-29, abstract: the present invention relates to a kind of home building materials, in particular to adopting A method for producing a cabinet board with flame retardant composite urea-formaldehyde resin, the cabinet board has the following structure from top to bottom: decorative paper, fir veneer, particle board, backboard; aluminum alloy trimming around the cabinet board; fir veneer and particle board The flame-retardant composite urea-formaldehyde resin adhesive is coated between the particleboards and the flame-retardant composite urea-formaldehyde resin is coated between the particleboard and the backboard.

本申请人在生产产品和应用的过程中,虽然在复合脲醛树脂胶黏剂想了很多技术方案,如加入防虫防霉剂、阻燃剂、防腐剂、耐高温剂等,也克服了现有许多脲醛树脂胶黏剂释放甲醛较多的缺点,但是在一些方面还有存在缺点,比如在热压过程中有时候施压不够均匀时产品容易变形,有时干燥的过程不够均匀,有开裂的现象,有的施胶不均匀,也不能保证产品甲醛超标,很多技术指标还有待于改进。In the process of product production and application, although the applicant has come up with many technical solutions in the compound urea-formaldehyde resin adhesive, such as adding insect and mildew repellants, flame retardants, preservatives, high temperature resistant agents, etc., it also overcomes the existing problems. Many urea-formaldehyde resin adhesives have the disadvantage of releasing more formaldehyde, but there are still shortcomings in some aspects. For example, during the hot pressing process, sometimes the product is easily deformed when the pressure is not uniform, and sometimes the drying process is not uniform, and there is a phenomenon of cracking , Some sizing is uneven, and it cannot guarantee that the product formaldehyde exceeds the standard, and many technical indicators still need to be improved.

发明内容SUMMARY OF THE INVENTION

本发明的技术方案如下:The technical scheme of the present invention is as follows:

本发明提供了一种防裂低醛多层桉木板及其生产方法,该多层板的生产方法包括单板薄板分选、薄板涂胶、冷压、热压、静置养生和刮灰、砂光、修补、切边和贴面板的步骤,其特征在于:在第一次热压和最后一次热压之前在板坯四周和上下表面喷涂一层固化膜,保护防止胶水在热压过程过快干燥,并保持多层板内部的应力,还可以使之脲醛胶水充分反应完全,使之成型后的多层板不易开裂,用户使用过程减少了挥发性甲醛,热压以后板材经过静置养生、砂光及贴面板,即可锯边包装得到防裂低醛多层桉木板产品。The invention provides an anti-cracking low-aldehyde multi-layer eucalyptus board and a production method thereof. The production method of the multi-layer board comprises veneer sheet sorting, sheet gluing, cold pressing, hot pressing, standing for curing and scraping dust, The steps of sanding, repairing, trimming and veneering are characterized in that: before the first hot pressing and the last hot pressing, a layer of cured film is sprayed on the surrounding and upper and lower surfaces of the slab to protect and prevent the glue from passing through the hot pressing process. Fast drying, and maintain the internal stress of the multi-layer board, and can also make the urea-formaldehyde glue fully react, so that the formed multi-layer board is not easy to crack, and the volatile formaldehyde is reduced during the user's use process. , sanding and veneer, can be sawed and packaged to obtain crack-resistant low-aldehyde multi-layer eucalyptus board products.

固化膜的施工方式是将热固型树脂、固化剂和助剂制成粉末,混合以后喷涂在板坯表面四周和上下面。通过热压过程的高温将固化膜牢牢附在板坯外表面。The construction method of the cured film is to make the thermosetting resin, curing agent and auxiliary agent into powder, and after mixing, spray it around and above and below the surface of the slab. The cured film is firmly attached to the outer surface of the slab by the high temperature of the hot pressing process.

以上所述的冷压、热压为2次或3次,所述的冷压温度为室温,压力为 0.8 ~1.0MPa,热压压力为1.5~2.0MPa ;第一次热压的温度为 120 ~ 125℃;第二次热压的温度为 115 ~120℃,第三次热压的温度为 125 ~ 130℃ ;所述的静置养生温度为 80 ~90℃,时间为 4 ~6h。The above-mentioned cold pressing and hot pressing are 2 or 3 times, the cold pressing temperature is room temperature, the pressure is 0.8-1.0 MPa, and the hot pressing pressure is 1.5-2.0 MPa; the temperature of the first hot pressing is 120 ~125℃; the temperature of the second hot pressing is 115 ~ 120℃, and the temperature of the third hot pressing is 125 ~ 130℃; the temperature of the static curing is 80 ~ 90℃, and the time is 4 ~ 6h.

所述的薄板涂胶的胶黏剂为脲醛树脂或酚醛树脂。The adhesive used for coating the thin plate is urea-formaldehyde resin or phenolic resin.

所述的贴面板是在多层桉木板的上面或上下两面粘贴免漆板或平整度、光滑度的木板,包括杨木板、杉木板、榉木板。The veneer board is a paint-free board or a board with flatness and smoothness, including poplar board, fir board and beech board, on the top or the upper and lower sides of the multi-layer eucalyptus board.

以上所述的固化膜是由热固型树脂、固化剂和助剂组成,热固型树脂采用三聚氰胺甲醛树脂、糠醇树脂或丙烯酸树脂,所述的固化剂为缩二脲,所述的助剂或填充剂包括玻璃纤维、有机硅、二氧化钛、碳酸钙。其中热固型树脂的重量份数为40-60;固化剂3-8;助剂或填充剂余量。The above-mentioned cured film is composed of thermosetting resin, curing agent and auxiliary agent. The thermosetting resin adopts melamine formaldehyde resin, furfuryl alcohol resin or acrylic resin, the curing agent is biuret, and the auxiliary agent Or fillers include fiberglass, silicone, titanium dioxide, calcium carbonate. The parts by weight of the thermosetting resin are 40-60; the curing agent is 3-8; and the remainder of the auxiliary or filler.

在上述的热固型树脂中:各种热固型树脂的物理化学性质如下:In the above-mentioned thermosetting resins: the physical and chemical properties of various thermosetting resins are as follows:

三聚氰胺甲醛树脂(英文名称melamine-formaldehyde resin),三聚氰胺与甲醛反应所得到的聚合物。加工成型时发生交联反应,制品为不熔的热固性树脂。固化后的三聚氰胺甲醛树脂无色透明,在沸水中稳定,甚至可以在150℃使用,且具有自熄性、抗电弧性和良好的力学性能。Melamine-formaldehyde resin (English name melamine-formaldehyde resin), a polymer obtained by the reaction of melamine and formaldehyde. The cross-linking reaction occurs during processing and molding, and the product is an infusible thermosetting resin. The cured melamine formaldehyde resin is colorless and transparent, stable in boiling water, and can even be used at 150 ° C, and has self-extinguishing, arc resistance and good mechanical properties.

糠醇树脂,英文名称 furfuryl alcohol resin 定义 以糠醇为原料制得的呋喃树脂。室温下加入固化剂能迅速固化为热固性材料。Furfuryl alcohol resin, English name furfuryl alcohol resin Definition Furan resin prepared from furfuryl alcohol as raw material. Adding a curing agent at room temperature can quickly cure into a thermoset material.

丙烯酸树脂,丙烯酸树脂是丙烯酸、甲基丙烯酸及其衍生物聚合物的总称。丙烯酸树脂涂料就是以(甲基) 丙烯酸酯、苯乙烯为主体,同其他丙烯酸酯共聚所得丙烯酸树脂制得的热塑性或热固性树脂涂料,或丙烯酸辐射涂料。Acrylic resin, acrylic resin is a general term for acrylic acid, methacrylic acid and its derivative polymers. Acrylic resin coating is a thermoplastic or thermosetting resin coating, or acrylic radiation coating, which is made of (meth)acrylate and styrene as the main body, and acrylic resin obtained by copolymerization with other acrylates.

热固性丙烯酸树脂是指在结构中带有一定的官能团,在制漆时通过和加入的氨基树脂、环氧树脂、聚氨酯等中的官能团反应形成网状结构,热固性树脂一般相对分子量较低。热固性丙烯酸涂料有优异的丰满度、光泽、硬度、耐溶剂性、耐候性、在高温烘烤时不变色、不返黄。Thermosetting acrylic resin refers to a certain functional group in the structure, which forms a network structure by reacting with the functional groups in the amino resin, epoxy resin, polyurethane, etc. added during the paint making process. The relative molecular weight of thermosetting resin is generally low. Thermosetting acrylic coatings have excellent fullness, gloss, hardness, solvent resistance, weather resistance, no discoloration and no yellowing during high temperature baking.

固化剂缩二脲,缩二脲是白色长片形结晶。无气味。有吸湿性。水中结晶者含4分子结晶水。在约110℃时失水,193℃时分解,温度再高时成三聚氰胺。易溶于乙醇,微溶于乙醚。Curing agent biuret, biuret is a long white crystal. Odorless. Hygroscopic. Those who crystallize in water contain 4 molecules of crystal water. It loses water at about 110 ° C, decomposes at 193 ° C, and becomes melamine when the temperature is higher. Soluble in ethanol, slightly soluble in ether.

缩二脲作为脂肪族聚氨酯固化剂,具备良好的耐候性,与多元醇或醋酸丁酯等溶剂良好的相容性,与含多元醇的聚合物固化后良好的高温耐溶性。As an aliphatic polyurethane curing agent, biuret has good weather resistance, good compatibility with solvents such as polyols or butyl acetate, and good high temperature solubility with polymers containing polyols after curing.

有机硅,有机硅产品是以硅-氧(Si-O)键为主链结构的,C-C键的键能为82.6千卡/克分子,Si-O键的键能在有机硅中为121千卡/克分子,所以有机硅产品的热稳定性高,高温下(或辐射照射)分子的化学键不断裂、不分解。有机硅不但可耐高温,而且也耐低温,可在一个很宽的温度范围内使用。无论是化学性能还是物理机械性能,随温度的变化都很小。本发明可以选取硅烷偶联剂、硅油(硅脂、硅乳液、硅表面活性剂)、硅树脂等;有机硅独特的结构,兼备了无机材料与有机材料的性能,具有表面张力低、粘温系数小、压缩性高、气体渗透性高等基本性质,并具有耐高低温、电气绝缘、耐氧化稳定性、耐候性、难燃、憎水、耐腐蚀、无毒无味以及生理惰性等优异特性。Silicone, silicone products are based on silicon-oxygen (Si-O) bond as the main chain structure, the bond energy of C-C bond is 82.6 kcal/mol, and the bond energy of Si-O bond in silicone is 82.6 kcal/mol. 121 kcal/mol, so the thermal stability of silicone products is high, and the chemical bonds of the molecules are not broken or decomposed under high temperature (or radiation exposure). Silicone is not only resistant to high temperatures, but also low temperatures, and can be used in a wide temperature range. Whether it is chemical properties or physical and mechanical properties, the change with temperature is very small. In the present invention, silane coupling agent, silicone oil (silicone grease, silicone emulsion, silicone surfactant), silicone resin, etc. can be selected; the unique structure of organic silicon combines the properties of inorganic materials and organic materials, and has low surface tension, viscosity and temperature It has the basic properties of small coefficient, high compressibility, high gas permeability, and has excellent characteristics such as high and low temperature resistance, electrical insulation, oxidation resistance stability, weather resistance, flame retardancy, hydrophobicity, corrosion resistance, non-toxic and tasteless, and physiological inertness.

本发明有以下突出的实质性特点和显著的进步:The present invention has the following outstanding substantive features and remarkable progress:

1、随着人民生活水平的提高,对家庭装修的要求也不断的提高。多层板因其自然优美的纹路、良好的质感,成为了家庭家具或地面装修的首选材料。而多层复合板克服了实木板湿胀干缩的缺点,具有较好的尺寸稳定性,同时保留了实木地板的自然木纹和舒适脚感,从而成为地板中的重要品种。实木复合板可以由不同树种的板材交错层压而成,克服了实木板单向同性的缺点,干缩湿胀率小。实木复合板兼具强化板的稳定性与实木板的美观性,而且具有环保优势,并且实木复合板既有普通实木板的优点,又有效地调整了木材之间的内应力,改进了木材随季节干湿度变化而变形量大的缺点,因此,受到消费者的喜爱。1. With the improvement of people's living standards, the requirements for home decoration are also constantly improving. Due to its natural and beautiful texture and good texture, multi-layer boards have become the first choice for home furniture or floor decoration. The multi-layer composite board overcomes the shortcomings of solid wood board's wet expansion and dry shrinkage, has good dimensional stability, and at the same time retains the natural wood grain and comfortable foot feel of solid wood flooring, thus becoming an important variety in flooring. The solid wood composite board can be made by interlaced lamination of boards of different tree species, which overcomes the shortcoming of unidirectional homogeneity of solid wood boards, and has a small dry shrinkage and wet expansion rate. The solid wood composite board has both the stability of the reinforced board and the aesthetics of the solid wood board, and has the advantages of environmental protection, and the solid wood composite board not only has the advantages of the ordinary solid wood board, but also effectively adjusts the internal stress between the wood and improves the performance of the wood. Due to the large amount of deformation due to seasonal changes in dryness and humidity, it is favored by consumers.

2、现有技术如果在多层板在热压过程中有时候施压不够均匀时产品容易变形,有时干燥的过程不够均匀,有开裂的现象,有的施胶不均匀,也不能保证产品甲醛超标,采用本发明第一次热压和最后一次热压之前在板坯表面四周和上下喷涂一层固化膜,保护防止胶水在热压过程过快干燥,并保持多层板内部的应力,还可以使之脲醛胶水充分反应完全,使之成型后的多层板不易开裂,用户使用过程减少了挥发性甲醛。2. In the prior art, if the multi-layer board is sometimes pressed evenly during the hot pressing process, the product is easily deformed, and sometimes the drying process is not uniform enough, there is a phenomenon of cracking, and some sizing is uneven, and the product formaldehyde cannot be guaranteed. Exceed the standard, use the present invention to spray a layer of cured film around and up and down the surface of the slab before the first hot pressing and the last hot pressing to protect the glue from drying too quickly during the hot pressing process, and maintain the internal stress of the multi-layer board. The urea-formaldehyde glue can be fully reacted, so that the formed multilayer board is not easy to crack, and the volatile formaldehyde is reduced during the user's use.

3、本发明多层实木复合板可以应用在卧室、客厅、书房及办公室的制作,也可以作为木地板用途,其使用年限较长,需要经过长时间的环境破坏检验。目前市场上应用于实木复合板胶黏剂的脲醛、酚醛胶甲醛释放较大,而本发明第一次热压和最后一次热压之前在板坯表面四周和上下喷涂一层固化膜,强度有所提高,甲醛释放浓度大大减少。3. The multi-layer solid wood composite board of the present invention can be used in the production of bedrooms, living rooms, study rooms and offices, and can also be used as wooden floors. At present, the urea-formaldehyde and phenol-formaldehyde glues used in the solid wood composite board adhesives on the market release relatively large amounts of formaldehyde, while in the present invention, a layer of cured film is sprayed around and on the top and bottom of the surface of the slab before the first hot pressing and the last hot pressing. The increase, the formaldehyde emission concentration is greatly reduced.

附图说明Description of drawings

图1是本发明防裂低醛多层桉木板的生产方法工艺流程图。Fig. 1 is the process flow diagram of the production method of crack-resistant low-aldehyde multi-layer eucalyptus wood board of the present invention.

图中体现本发明的多层板的生产方法包括单板薄板分选、薄板涂胶、三次冷压、三次热压、二次静置养生和刮灰、砂光、修补、切边和贴面板的步骤,其特征在于 :在第一次冷压,修补切边、第一次热压和第三次次热压之前在板坯表面四周和上下喷涂一层固化膜,保护防止胶水在热压过程过快干燥,并保持多层板内部的应力,还可以使之脲醛胶水充分反应完全,使之成型后的多层板不易开裂,用户使用过程减少了挥发性甲醛,第三次热压以后板材经过静置养生、砂光及贴面板,即可锯边包装得到防裂低醛多层桉木板产品。The production method of the multi-layer board embodying the present invention in the figure includes veneer sheet sorting, sheet gluing, three cold pressing, three hot pressing, secondary standing and curing and scraping, sanding, repairing, trimming and veneer. It is characterized in that: before the first cold pressing, repair trimming, the first hot pressing and the third hot pressing, a layer of cured film is sprayed around the surface of the slab and up and down to protect the glue from being hot-pressed. The drying process is too fast, and the internal stress of the multi-layer board is maintained, and the urea-formaldehyde glue can be fully reacted, so that the formed multi-layer board is not easy to crack, and the volatile formaldehyde is reduced during the user's use process. After standing, sanding and veneering, the board can be sawed and packaged to obtain crack-resistant low-aldehyde multi-layer eucalyptus board products.

具体实施方式Detailed ways

实施例1Example 1

一种防裂低醛多层桉木板的生产方法,该多层板的生产方法包括单板薄板分选、薄板涂胶、三次冷压、三次热压、二次静置养生和刮灰、砂光、修补、切边和贴面板的步骤,其特征在于 :在第一次冷压,修补切边、第一次热压和最后一次热压之前在板坯表面四周和上下喷涂一层固化膜,保护防止胶水在热压过程过快干燥,并保持多层板内部的应力,还可以使之脲醛胶水充分反应完全,使之成型后的多层板不易开裂,用户使用过程减少了挥发性甲醛,第三次热压以后板材经过静置养生、砂光及贴面板,即可锯边包装得到防裂低醛多层桉木板产品。 A method for producing crack-resistant and low-aldehyde multi-layer eucalyptus boards, the production method of the multi-layer board comprises veneer sheet sorting, sheet gluing, three times of cold pressing, three times of hot pressing, two times of standing and curing and scraping ash and sand. The steps of lightening, repairing, trimming and veneering are characterized in that: before the first cold pressing, repairing trimming, the first hot pressing and the last hot pressing, a layer of cured film is sprayed around and up and down the surface of the slab , to protect the glue from drying too quickly during the hot pressing process, and to maintain the internal stress of the multi-layer board. It can also make the urea-formaldehyde glue fully react, so that the formed multi-layer board is not easy to crack, and the user process reduces volatile formaldehyde. , After the third hot pressing, the board can be left to stand, sanded and veneered, and then sawed and packaged to obtain crack-resistant low-aldehyde multi-layer eucalyptus board products.

固化膜的施工方式是将热固型树脂、固化剂和助剂制成粉末,混合以后喷涂在板坯表面四周和上下面。通过热压过程的高温将固化膜牢牢附在板坯外表面。The construction method of the cured film is to make the thermosetting resin, curing agent and auxiliary agent into powder, and after mixing, spray it around and above and below the surface of the slab. The cured film is firmly attached to the outer surface of the slab by the high temperature of the hot pressing process.

以上所述的冷压温度为室温,压力为 0.8 ~1.0MPa,热压压力为1.5~2.0MPa ;第一次热压的温度为 120 ~ 125℃;第二次热压的温度为 115 ~120℃,第三次热压的温度为 125 ~ 130℃ ;所述的静置养生温度为 80 ~ 90℃,时间为 4 ~6h 。The above-mentioned cold pressing temperature is room temperature, the pressure is 0.8-1.0MPa, and the hot-pressing pressure is 1.5-2.0MPa; the temperature of the first hot-pressing is 120-125°C; the temperature of the second hot-pressing is 115-120 ℃, the temperature of the third hot-pressing is 125-130 ℃; the temperature of the static curing is 80-90 ℃, and the time is 4-6h.

所述的薄板涂胶的胶黏剂为脲醛树脂。The adhesive used for coating the thin plate is urea-formaldehyde resin.

所述的贴面板是在多层桉木板的上面或上下两面粘贴免漆板或平整度、光滑度的木板,包括杨木板、杉木板、榉木板。The veneer board is a paint-free board or a board with flatness and smoothness, including poplar board, fir board and beech board, on the top or the upper and lower sides of the multi-layer eucalyptus board.

以上所述的固化膜是由热固型树脂、固化剂和助剂组成,热固型树脂采用三聚氰胺甲醛树脂,所述的固化剂为缩二脲,所述的助剂或填充剂包括玻璃纤维、有机硅、二氧化钛、碳酸钙。其中热固型树脂的重量份数为40-50;固化剂5;助剂和填充剂玻璃纤维、有机硅、二氧化钛、碳酸钙余量,其中玻璃纤维10-15;有机硅5,二氧化钛9, 碳酸钙余量。The above-mentioned cured film is composed of thermosetting resin, curing agent and auxiliary agent. The thermosetting resin adopts melamine formaldehyde resin, the curing agent is biuret, and the auxiliary agent or filler includes glass fiber. , Silicone, Titanium Dioxide, Calcium Carbonate. Among them, the parts by weight of thermosetting resin are 40-50; curing agent 5; auxiliary and filler glass fiber, silicone, titanium dioxide, calcium carbonate balance, wherein glass fiber 10-15; silicone 5, titanium dioxide 9, Calcium carbonate balance.

实施例2Example 2

一种防裂低醛多层桉木板的生产方法,该多层板的生产方法包括单板薄板分选、薄板涂胶、一次冷压、二次热压、二次静置养生和刮灰、砂光、修补、切边和贴面板的步骤,其特征在于 :在第一次冷压,修补切边、第一次热压和第二次热压之前在板坯表面四周和上下喷涂一层固化膜,保护防止胶水在热压过程过快干燥,并保持多层板内部的应力,还可以使之脲醛胶水充分反应完全,使之成型后的多层板不易开裂,用户使用过程减少了挥发性甲醛,第三次热压以后板材经过静置养生、砂光及贴面板,即可锯边包装得到防裂低醛多层桉木板产品。A method for producing crack-resistant and low-aldehyde multi-layer eucalyptus boards, the production method of the multi-layer board comprises veneer sheet sorting, sheet gluing, primary cold pressing, secondary hot pressing, secondary standing and curing and scraping ash, The steps of sanding, repairing, trimming and veneering are characterized in that: before the first cold pressing, repairing trimming, the first hot pressing and the second hot pressing, a layer is sprayed around and above and below the surface of the slab The cured film protects and prevents the glue from drying too quickly during the hot pressing process, and maintains the internal stress of the multi-layer board. It can also make the urea-formaldehyde glue fully react, so that the formed multi-layer board is not easy to crack, and the user's use process reduces volatilization After the third hot pressing, the board can be left to stand, sanded and veneered, and then sawed and packaged to obtain crack-resistant low-formaldehyde multi-layer eucalyptus board products.

固化膜的施工方式是将热固型树脂、固化剂和助剂制成粉末,混合以后喷涂在板坯表面四周和上下面。通过热压过程的高温将固化膜牢牢附在板坯外表面。The construction method of the cured film is to make the thermosetting resin, curing agent and auxiliary agent into powder, and after mixing, spray it around and above and below the surface of the slab. The cured film is firmly attached to the outer surface of the slab by the high temperature of the hot pressing process.

以上所述的冷压温度为室温,压力为 0.8 ~1.0MPa,热压压力为1.5~2.0MPa ;第一次热压的温度为 120 ~ 125℃;第二次热压的温度为120 ~ 130℃ ;所述的静置养生温度为 80 ~ 90℃,时间为 4 ~6h 。The above-mentioned cold pressing temperature is room temperature, the pressure is 0.8 to 1.0 MPa, and the hot pressing pressure is 1.5 to 2.0 MPa; the temperature of the first hot pressing is 120 to 125 ° C; the temperature of the second hot pressing is 120 to 130 ℃; the temperature of the static curing is 80-90 ℃, and the time is 4-6h.

所述的薄板涂胶的胶黏剂为改性酚醛树脂。The adhesive used for coating the thin plate is modified phenolic resin.

所述的贴面板是在多层桉木板的上面或上下两面粘贴免漆板或平整度、光滑度的木板,包括杨木板、杉木板、榉木板。The veneer board is a paint-free board or a board with flatness and smoothness, including poplar board, fir board and beech board, on the top or the upper and lower sides of the multi-layer eucalyptus board.

以上所述的固化膜是由热固型树脂、固化剂和助剂组成,热固型树脂采用丙烯酸树脂,所述的固化剂为缩二脲,所述的助剂或填充剂包括玻璃纤维、有机硅、二氧化钛、碳酸钙。其中丙烯酸树脂的重量份数为50-60;固化剂5;助剂和填充剂玻璃纤维、有机硅、二氧化钛、碳酸钙余量,其中玻璃纤维10-15;有机硅8,二氧化钛5,碳酸钙加够100%。The above-mentioned cured film is composed of thermosetting resin, curing agent and auxiliary agent. The thermosetting resin adopts acrylic resin, the curing agent is biuret, and the auxiliary agent or filler includes glass fiber, Silicone, titanium dioxide, calcium carbonate. Wherein the parts by weight of acrylic resin are 50-60; curing agent 5; auxiliary and filler glass fiber, organosilicon, titanium dioxide, calcium carbonate balance, wherein glass fiber 10-15; organosilicon 8, titanium dioxide 5, calcium carbonate Add enough 100%.

本发明加入固化膜产品与未加固化层产品特点对比:The present invention adds the cured film product and does not add the cured layer product characteristic contrast:

Figure DEST_PATH_IMAGE003
Figure DEST_PATH_IMAGE003

Claims (5)

1. the production method of the anti-cracking low-formaldehyde multi-layer eucalyptus board comprises the steps of single board sheet separation, sheet gluing, cold pressing, hot pressing, standing, health preserving, dust scraping, sanding, repairing, trimming and panel pasting, and is characterized in that: spraying a layer of curing film on the periphery, the upper surface and the lower surface of the plate blank before the first hot pressing and the last hot pressing, protecting and preventing the glue from being dried too fast in the hot pressing process, keeping the stress in the multilayer board, fully reacting the urea-formaldehyde glue, and preventing the formed multilayer board from cracking easily, wherein the volatile formaldehyde is reduced in the using process;
the curing film is composed of thermosetting resin, curing agent and auxiliary agent, wherein the thermosetting resin is melamine formaldehyde resin, furfuryl alcohol resin or acrylic resin, the curing agent is biuret, and the auxiliary agent comprises glass fiber, organic silicon, titanium dioxide and calcium carbonate; wherein the weight portion of the thermosetting resin is 40-60; 3-8 parts of a curing agent; the balance of auxiliary agents or fillers.
2. The production method of the anti-cracking low-aldehyde multi-layer eucalyptus board as claimed in claim 1, wherein the production method comprises the following steps: the construction mode of the cured film is that the thermosetting resin, the curing agent and the auxiliary agent are made into powder, and the powder is sprayed on the periphery and the upper and lower surface of the plate blank after being mixed.
3. The production method of the anti-cracking low-aldehyde multi-layer eucalyptus board as claimed in claim 1, wherein the production method comprises the following steps: the cold pressing and the hot pressing are carried out for 2 times or 3 times, the cold pressing temperature is room temperature, the pressure is 0.8-1.0 MPa, and the hot pressing pressure is 1.5-2.0 MPa; the temperature of the first hot pressing is 120-125 ℃; the temperature of the second hot pressing is 115-120 ℃, and the temperature of the third hot pressing is 125-130 ℃; the standing and curing temperature is 80-90 ℃, and the time is 4-6 h.
4. The production method of the anti-cracking low-aldehyde multi-layer eucalyptus board as claimed in claim 1, wherein the production method comprises the following steps: the adhesive for gluing the thin plate is urea-formaldehyde resin or phenolic resin.
5. The method for producing anti-cracking low-formaldehyde multi-layer eucalyptus board according to claim 1, wherein the veneer is made by sticking paint-free boards or boards with flatness and smoothness on the upper surface or the upper and lower surfaces of the multi-layer eucalyptus board, including poplar boards, fir boards and beech boards.
CN201911208439.2A 2019-11-30 2019-11-30 Anti-cracking low-aldehyde multi-layer eucalyptus board and production method thereof Pending CN110744649A (en)

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CA2445096C (en) * 2000-04-11 2012-03-06 Forrest C. Bacon Water-resistant plywood substitutes made from recycled carpets or textiles
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CN108587277A (en) * 2018-04-28 2018-09-28 嘉宝莉化工集团股份有限公司 A kind of environmentally protective spray paint of anti-cracking type and preparation method thereof
CN109551576A (en) * 2018-12-13 2019-04-02 柳州市荣森新型材料科技有限公司 A kind of wear-resistant impregnated bond paper facing ecological board and preparation method thereof

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CA2445096C (en) * 2000-04-11 2012-03-06 Forrest C. Bacon Water-resistant plywood substitutes made from recycled carpets or textiles
CN101643136A (en) * 2008-08-08 2010-02-10 胜狮货柜技术研发(上海)有限公司 Floor board of container
CN103406966A (en) * 2013-08-14 2013-11-27 广西南宁绿园北林木业有限公司 Production method for all eucalyptus thickened lamination board for wood floor
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WO2025108730A1 (en) * 2023-11-21 2025-05-30 Raimund Beck Nageltechnik Gmbh Plywood and wooden nail

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Application publication date: 20200204