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CN110734685A - low-temperature curing resin anticorrosive paint - Google Patents

low-temperature curing resin anticorrosive paint Download PDF

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Publication number
CN110734685A
CN110734685A CN201911085100.8A CN201911085100A CN110734685A CN 110734685 A CN110734685 A CN 110734685A CN 201911085100 A CN201911085100 A CN 201911085100A CN 110734685 A CN110734685 A CN 110734685A
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parts
agent
resin
curing agent
low
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Withdrawn
Application number
CN201911085100.8A
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Chinese (zh)
Inventor
徐晶
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Chuzhou City Quan Feng Goods And Materials Co Ltd
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Chuzhou City Quan Feng Goods And Materials Co Ltd
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Priority to CN201911085100.8A priority Critical patent/CN110734685A/en
Publication of CN110734685A publication Critical patent/CN110734685A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4028—Isocyanates; Thioisocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C08K2003/2272—Ferric oxide (Fe2O3)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses low-temperature curing resin anticorrosive paint, wherein the component comprises, by mass, 45-55 parts of epoxy resin and 12-16 parts of composite addition type resin, and the second component comprises, by mass, 10-12 parts of a curing agent A, 15-17 parts of a curing agent B and 25-30 parts of a second solvent, wherein the curing agent A comprises aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane, and the curing agent B comprises a cashew nut shell oil epoxy resin curing agent and a YH-82 epoxy low-temperature curing agent.

Description

low-temperature curing resin anticorrosive paint
Technical Field
The invention relates to the field of anticorrosive coatings, in particular to low-temperature curing resin anticorrosive coatings.
Background
The type of coating which adopts epoxy resin as a film forming material is mostly adopted in the general anticorrosive coating products in the market at present, the coating has the advantages that 1, the epoxy resin endows excellent adhesion performance due to the molecular structure of the epoxy resin, 2, the epoxy coating has low volume shrinkage rate (only about 2 percent) during curing, so that the internal stress is small, the adhesion is not lost, the coating has excellent adhesion to polar substrates such as metal (steel, aluminum and the like), ceramic, glass, concrete, wood and the like, 3, the epoxy coating has good chemical resistance, and is in a three-dimensional network structure and strong compactness after curing, so that the epoxy coating is widely used for anticorrosion prime coats and antirust prime coats.
Disclosure of Invention
Aiming at the problems, the invention provides low-temperature curing resin anticorrosive coatings, which are added with a curing agent A consisting of aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane and a curing agent B consisting of a cashew nut shell oil epoxy resin curing agent and a YH-82 epoxy low-temperature curing agent.
The invention provides low-temperature curing resin anticorrosive paint which comprises a -th component and a second component, wherein the -th component comprises, by mass, 45-55 parts of epoxy resin, 12-16 parts of composite addition type resin, 2-6 parts of pigment, 35-40 parts of -th solvent, 4-6 parts of auxiliary agent, 3-8 parts of antirust additive, 10-14 parts of filler and 5-7 parts of metal ion crosslinking agent, and the second component comprises, by mass, 10-12 parts of curing agent A, 15-17 parts of curing agent B and 25-30 parts of second solvent;
the curing agent A comprises aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane, and the curing agent B comprises cashew nut shell oil epoxy resin curing agent and YH-82 epoxy low-temperature curing agent;
the metal ion cross-linking agent is any of zinc acetate, ammonium zirconium carbonate salt or ammonium zinc carbonate salt.
The further improvement is that the component comprises 50 parts of epoxy resin, 14 parts of composite additive resin, 5 parts of pigment, 38 parts of th solvent, 5 parts of auxiliary agent, 5 parts of antirust additive, 12 parts of filler and 6 parts of metal ion crosslinking agent according to the mass ratio, and the second component comprises 11 parts of curing agent A, 16 parts of curing agent B and 28 second solvent according to the mass ratio.
is further improved in that the composite addition type resin is or more of bisphenol A modified epoxy resin, nitrile rubber modified epoxy resin, polyester resin or hydroxy acrylic resin.
is further improved in that the filler is a mixture of quartz powder and white carbon black, and the mass ratio of the quartz powder to the white carbon black is 20: 1.
is further improved in that the auxiliary agent comprises fumed silica, active diluent, dispersant, accelerator, leveling agent, defoaming agent, coupling agent, sealant, corrosion inhibitor and ultraviolet absorbent.
the improvement is that the antirust additive is any or two of iron oxide red, iron phosphate, zinc oxide, aluminum tripolyphosphate and mica iron oxide which are mixed in equal amount.
the improvement is that the th solvent and the second solvent are any of methyl isobutyl ketone, butanone, PMA, n-butanol or aromatic hydrocarbon solvents.
The invention has the beneficial effects that: by adding the curing agent A consisting of aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane and the curing agent B consisting of cashew nut shell oil epoxy resin curing agent and YH-82 epoxy low-temperature curing agent, the resin anticorrosive paint disclosed by the application is stable to cure in a low-temperature environment, and a coating formed by the paint is high in mechanical strength, has excellent performances such as alkali resistance, acid resistance, wear resistance and ultraviolet resistance, has good adhesive force on the surface of various treated or untreated base materials, and is not easy to fall off.
Detailed Description
For the purpose of enhancing understanding of the present invention, the present invention will be described in further detail in with reference to the following examples, which are provided for illustration only and are not to be construed as limiting the scope of the present invention.
Example
low-temperature curing resin anticorrosive paint comprises a component and a second component, wherein the component comprises the following components in parts by mass, namely 45 parts of epoxy resin, 12 parts of composite additive resin, 2 parts of pigment, 35 parts of solvent, 4 parts of auxiliary agent, 3 parts of antirust additive, 10 parts of filler and 5 parts of metal ion crosslinking agent, and the second component comprises the following components in parts by mass, namely 10 parts of curing agent A, 15 parts of curing agent B and 25 parts of second solvent;
the curing agent A comprises aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane, and the curing agent B comprises cashew nut shell oil epoxy resin curing agent and YH-82 epoxy low-temperature curing agent;
the metal ion cross-linking agent is zinc acetate.
The composite addition type resin is a mixture of bisphenol A modified epoxy resin, nitrile rubber modified epoxy resin, polyester resin and hydroxy acrylic resin.
The filler is a mixture of quartz powder and white carbon black, and the mass ratio of the quartz powder to the white carbon black is 20: 1.
The auxiliary agent comprises fumed silica, an active diluent, a dispersing agent, an accelerating agent, a flatting agent, a defoaming agent, a coupling agent, a sealing agent, a corrosion inhibitor and an ultraviolet absorbent.
The antirust additive is formed by mixing red iron oxide and zinc oxide in equal amount.
The th solvent and the second solvent are both methyl isobutyl ketone.
Example two
low-temperature curing resin anticorrosive paint comprises a component and a second component, wherein the component comprises the following components in parts by mass, namely 50 parts of epoxy resin, 14 parts of composite additive resin, 5 parts of pigment, 38 parts of solvent, 5 parts of auxiliary agent, 5 parts of antirust additive, 12 parts of filler and 6 parts of metal ion crosslinking agent, and the second component comprises the following components in parts by mass, namely 11 parts of curing agent A, 16 parts of curing agent B and 28 second solvent;
the curing agent A comprises aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane, and the curing agent B comprises cashew nut shell oil epoxy resin curing agent and YH-82 epoxy low-temperature curing agent;
the metal ion cross-linking agent is zinc acetate.
The composite addition type resin is a mixture of bisphenol A modified epoxy resin, nitrile rubber modified epoxy resin, polyester resin and hydroxy acrylic resin.
The filler is a mixture of quartz powder and white carbon black, and the mass ratio of the quartz powder to the white carbon black is 20: 1.
The auxiliary agent comprises fumed silica, an active diluent, a dispersing agent, an accelerating agent, a flatting agent, a defoaming agent, a coupling agent, a sealing agent, a corrosion inhibitor and an ultraviolet absorbent.
The antirust additive is formed by mixing red iron oxide and zinc oxide in equal amount.
The th solvent and the second solvent are both methyl isobutyl ketone.
EXAMPLE III
low-temperature curing resin anticorrosive paint comprises a component and a second component, wherein the component comprises 55 parts of epoxy resin, 16 parts of composite additive resin, 6 parts of pigment, 40 parts of solvent, 6 parts of auxiliary agent, 8 parts of antirust additive, 14 parts of filler and 7 parts of metal ion crosslinking agent in mass ratio, and the second component comprises 12 parts of curing agent A, 17 parts of curing agent B and 30 parts of second solvent in mass ratio;
the curing agent A comprises aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane, and the curing agent B comprises cashew nut shell oil epoxy resin curing agent and YH-82 epoxy low-temperature curing agent;
the metal ion cross-linking agent is zinc acetate.
The composite addition type resin is a mixture of bisphenol A modified epoxy resin, nitrile rubber modified epoxy resin, polyester resin and hydroxy acrylic resin.
The filler is a mixture of quartz powder and white carbon black, and the mass ratio of the quartz powder to the white carbon black is 20: 1.
The auxiliary agent comprises fumed silica, an active diluent, a dispersing agent, an accelerating agent, a flatting agent, a defoaming agent, a coupling agent, a sealing agent, a corrosion inhibitor and an ultraviolet absorbent.
The antirust additive is formed by mixing red iron oxide and zinc oxide in equal amount.
The th solvent and the second solvent are both methyl isobutyl ketone.
According to the embodiment , the second embodiment and the third embodiment, the component comprises, by mass, 45-55 parts of epoxy resin, 12-16 parts of composite additive resin, 2-6 parts of pigment, 35-40 parts of th solvent, 4-6 parts of auxiliary agent, 3-8 parts of antirust additive, 10-14 parts of filler and 5-7 parts of metal ion crosslinking agent, and the second component comprises, by mass, 10-12 parts of curing agent A, 15-17 parts of curing agent B and 25-30 parts of second solvent, so that the prepared grease anticorrosive paint has the advantages of best mechanical strength, low-temperature curing capability and good coating adhesion.
Adding solvent into a reaction kettle, heating to 45 ℃, adding epoxy resin into the reaction kettle under the stirring condition for stirring, adding the composite additive resin into the reaction kettle for stirring in multiple times, wherein the dissolving time is 150 minutes each time, until the composite additive resin is completely dissolved, then heating the temperature in the reaction kettle to 65 ℃, adding pigment, auxiliary agent, antirust additive, filler and metal ion crosslinking agent into the reaction kettle for mixing and stirring, and then cooling to 25 ℃ for later use;
adding the second solvent into a stirring kettle, adding the curing agent A and the curing agent B under the stirring condition, and mixing and stirring for 120 minutes for later use;
and adding the materials in the stirring kettle into the reaction kettle, and mixing and stirring for 25 minutes to obtain the resin anticorrosive paint.
Experimental example
Taking four equal parts of the resin anticorrosive paint to perform a mechanical strength test, respectively brushing the four equal parts of the resin anticorrosive paint on four same base materials, and then respectively performing the following experiments on coatings formed on the four base materials:
coating of substrate 1: spraying with 10% CHCOOH, standing for 480 hr, and observing the change of the coating;
coating of substrate 2: spraying with 10% NaOH, standing for 240 hours, and observing the change of the coating;
coating of substrate 3: soaking the coating on the substrate with butanone for 24 hours, and observing the change of the coating;
coating of the substrate 4: the coating of substrate 4 was tested for 1000 hours using GB/T1740-78(89) paint film wet heat test to observe the change in coating.
The experimental result shows that the coating surface of the base material 1 has no bubbles and no damage; the coating surface of the base material 2 has no bubbles and is not damaged; the coating surface of the base material 3 has no bubbles and is not damaged; the coated surface of substrate 4 was bubble free, slightly tarnished and negligible.
Experimental example two
Taking four equal parts of resin anticorrosive paint to perform a mechanical strength test, respectively brushing five equal parts of resin anticorrosive paint on five same base materials to ensure that the thicknesses of the coatings are the same, then respectively putting the five base materials with the coatings with the same thickness into simulated environments of 38 ℃, 20 ℃, 10 ℃, 0 ℃ and-8 ℃ for curing, and observing the time required by curing.
Experimental results show that the resin anticorrosive paint can be cured in a simulated environment of-8 ℃ to 38 ℃.
By adding the curing agent A consisting of aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane and the curing agent B consisting of cashew nut shell oil epoxy resin curing agent and YH-82 epoxy low-temperature curing agent, the resin anticorrosive paint disclosed by the application is stable to cure in a low-temperature environment, and a coating formed by the paint is high in mechanical strength, has excellent performances such as alkali resistance, acid resistance, wear resistance and ultraviolet resistance, has good adhesive force on the surface of various treated or untreated base materials, and is not easy to fall off.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (7)

  1. The low-temperature curing resin anticorrosive paint is characterized by comprising an th component and a second component, wherein the th component comprises, by mass, 45-55 parts of epoxy resin, 12-16 parts of composite addition type resin, 2-6 parts of pigment, 35-40 parts of th solvent, 4-6 parts of auxiliary agent, 3-8 parts of antirust additive, 10-14 parts of filler and 5-7 parts of metal ion crosslinking agent, and the second component comprises, by mass, 10-12 parts of curing agent A, 15-17 parts of curing agent B and 25-30 parts of second solvent;
    the curing agent A comprises aromatic isocyanate, aromatic polyurethane and aliphatic polyurethane, and the curing agent B comprises cashew nut shell oil epoxy resin curing agent and YH-82 epoxy low-temperature curing agent;
    the metal ion cross-linking agent is any of zinc acetate, ammonium zirconium carbonate salt or ammonium zinc carbonate salt.
  2. 2. The kinds of low-temperature curing resin anticorrosive paint of claim 1, wherein the th component comprises, by mass, 50 parts of epoxy resin, 14 parts of composite additive resin, 5 parts of pigment, 38 parts of th solvent, 5 parts of auxiliary agent, 5 parts of antirust additive, 12 parts of filler and 6 parts of metal ion crosslinking agent, and the second component comprises, by mass, 11 parts of curing agent A, 16 parts of curing agent B and 28 second solvent.
  3. 3. The kinds of low-temperature curing resin anticorrosive paint of claim 1, wherein the composite addition type resin is or more of bisphenol A modified epoxy resin, nitrile rubber modified epoxy resin, polyester resin or hydroxy acrylic resin.
  4. 4. The kinds of low-temperature curing resin anticorrosive paint of claim 1, wherein the filler is a mixture of quartz powder and white carbon black, and the mass ratio of the quartz powder to the white carbon black is 20: 1.
  5. 5. The kinds of low-temperature curing resin anticorrosive paint of claim 1, wherein the auxiliary agent comprises fumed silica, reactive diluent, dispersant, accelerator, leveling agent, defoaming agent, coupling agent, blocking agent, corrosion inhibitor and ultraviolet absorber.
  6. 6. The kinds of low-temperature curing resin anticorrosive paint of claim 1, wherein the antirust additive is any kinds of red iron oxide, iron phosphate, zinc oxide, aluminum tripolyphosphate, mica iron oxide or a mixture of two kinds of red iron oxide, iron phosphate, zinc oxide, aluminum tripolyphosphate and mica iron oxide in equal amount.
  7. 7. The kinds of low-temperature curing resin anticorrosive paint of claim 1, wherein the th solvent and the second solvent are any kinds of methyl isobutyl ketone, butanone, PMA, n-butanol or aromatic hydrocarbon solvents.
CN201911085100.8A 2019-11-08 2019-11-08 low-temperature curing resin anticorrosive paint Withdrawn CN110734685A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112063277A (en) * 2020-09-23 2020-12-11 滁州市全丰物资有限公司 Resin for metal coiled material and preparation method thereof
CN112574644A (en) * 2020-12-17 2021-03-30 深圳市旭龙光电有限公司 Antibacterial coating suitable for pc/pma composite base material and preparation method thereof
CN112980316A (en) * 2021-03-23 2021-06-18 石家庄市油漆厂 Low-temperature curing epoxy coating and preparation method thereof
CN114032019A (en) * 2021-12-03 2022-02-11 江苏奥净嘉环保科技有限公司 Preparation method of high-weather-resistance wear-resistant coating for surface of PC (polycarbonate) plate
CN114752298A (en) * 2022-03-31 2022-07-15 山东天盾矿用设备有限公司 Embedded channel sealing coating and preparation method and application thereof
CN118064049A (en) * 2024-02-21 2024-05-24 山东交通学院 Corrosion-resistant coating capable of being rapidly cured in water and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112063277A (en) * 2020-09-23 2020-12-11 滁州市全丰物资有限公司 Resin for metal coiled material and preparation method thereof
CN112574644A (en) * 2020-12-17 2021-03-30 深圳市旭龙光电有限公司 Antibacterial coating suitable for pc/pma composite base material and preparation method thereof
CN112980316A (en) * 2021-03-23 2021-06-18 石家庄市油漆厂 Low-temperature curing epoxy coating and preparation method thereof
CN114032019A (en) * 2021-12-03 2022-02-11 江苏奥净嘉环保科技有限公司 Preparation method of high-weather-resistance wear-resistant coating for surface of PC (polycarbonate) plate
CN114752298A (en) * 2022-03-31 2022-07-15 山东天盾矿用设备有限公司 Embedded channel sealing coating and preparation method and application thereof
CN118064049A (en) * 2024-02-21 2024-05-24 山东交通学院 Corrosion-resistant coating capable of being rapidly cured in water and preparation method thereof

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Application publication date: 20200131