CN110720463A - Plant growth regulating composition and regulator thereof - Google Patents
Plant growth regulating composition and regulator thereof Download PDFInfo
- Publication number
- CN110720463A CN110720463A CN201911093178.4A CN201911093178A CN110720463A CN 110720463 A CN110720463 A CN 110720463A CN 201911093178 A CN201911093178 A CN 201911093178A CN 110720463 A CN110720463 A CN 110720463A
- Authority
- CN
- China
- Prior art keywords
- plant growth
- growth regulating
- regulating composition
- parts
- benzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 92
- 230000008635 plant growth Effects 0.000 title claims abstract description 72
- 230000001105 regulatory effect Effects 0.000 title claims abstract description 71
- IXVMHGVQKLDRKH-KNBKMWSGSA-N brassinolide Chemical compound C1OC(=O)[C@H]2C[C@H](O)[C@H](O)C[C@]2(C)[C@H]2CC[C@]3(C)[C@@H]([C@H](C)[C@@H](O)[C@H](O)[C@@H](C)C(C)C)CC[C@H]3[C@@H]21 IXVMHGVQKLDRKH-KNBKMWSGSA-N 0.000 claims abstract description 29
- IXVMHGVQKLDRKH-VRESXRICSA-N Brassinolide Natural products O=C1OC[C@@H]2[C@@H]3[C@@](C)([C@H]([C@@H]([C@@H](O)[C@H](O)[C@H](C(C)C)C)C)CC3)CC[C@@H]2[C@]2(C)[C@@H]1C[C@H](O)[C@H](O)C2 IXVMHGVQKLDRKH-VRESXRICSA-N 0.000 claims abstract description 28
- 229930191978 Gibberellin Natural products 0.000 claims abstract description 26
- 239000003448 gibberellin Substances 0.000 claims abstract description 26
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims abstract description 23
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 claims abstract description 21
- XQSLKIBWQSTAGK-UHFFFAOYSA-N carpronium Chemical compound COC(=O)CCC[N+](C)(C)C XQSLKIBWQSTAGK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229950005472 carpronium Drugs 0.000 claims abstract description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 75
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 69
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 63
- YIMYUGFRPUNGOM-UHFFFAOYSA-N 4-(3,5,5-trimethylhexanoyloxy)benzenesulfonic acid Chemical compound CC(C)(C)CC(C)CC(=O)OC1=CC=C(S(O)(=O)=O)C=C1 YIMYUGFRPUNGOM-UHFFFAOYSA-N 0.000 claims description 32
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 claims description 25
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 claims description 25
- 229960000367 inositol Drugs 0.000 claims description 25
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 claims description 25
- 239000005648 plant growth regulator Substances 0.000 claims description 24
- 150000003458 sulfonic acid derivatives Chemical class 0.000 claims description 24
- 229910052708 sodium Inorganic materials 0.000 claims description 21
- 239000011734 sodium Substances 0.000 claims description 21
- ODLHGICHYURWBS-LKONHMLTSA-N trappsol cyclo Chemical compound CC(O)COC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COCC(O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1COCC(C)O ODLHGICHYURWBS-LKONHMLTSA-N 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- -1 4- (1-hydroxyethyl) -6-methyl-1, 2,3, 5-benzenetetraol Chemical compound 0.000 claims description 16
- 239000002671 adjuvant Substances 0.000 claims description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- PCWPQSDFNIFUPO-VDQKLNDWSA-N (1S,3R,5R,6S,8R,10R,11S,13R,15R,16S,18R,20R,21S,23R,25R,26S,28R,30R,31S,33R,35R,36R,37S,38R,39S,40R,41S,42R,43S,44R,45S,46R,47S,48R,49S)-37,39,41,43,45,47,49-heptakis(2-hydroxyethoxy)-5,10,15,20,25,30,35-heptakis(hydroxymethyl)-2,4,7,9,12,14,17,19,22,24,27,29,32,34-tetradecaoxaoctacyclo[31.2.2.23,6.28,11.213,16.218,21.223,26.228,31]nonatetracontane-36,38,40,42,44,46,48-heptol Chemical compound OCCO[C@H]1[C@H](O)[C@@H]2O[C@H]3O[C@H](CO)[C@@H](O[C@H]4O[C@H](CO)[C@@H](O[C@H]5O[C@H](CO)[C@@H](O[C@H]6O[C@H](CO)[C@@H](O[C@H]7O[C@H](CO)[C@@H](O[C@H]8O[C@H](CO)[C@@H](O[C@H]1O[C@@H]2CO)[C@@H](O)[C@@H]8OCCO)[C@@H](O)[C@@H]7OCCO)[C@@H](O)[C@@H]6OCCO)[C@@H](O)[C@@H]5OCCO)[C@@H](O)[C@@H]4OCCO)[C@@H](O)[C@@H]3OCCO PCWPQSDFNIFUPO-VDQKLNDWSA-N 0.000 claims description 3
- BGMYHTUCJVZIRP-SVZMEOIVSA-N (3r,4s,5s,6r)-6-(hydroxymethyl)piperidine-2,3,4,5-tetrol Chemical compound OC[C@H]1NC(O)[C@H](O)[C@@H](O)[C@H]1O BGMYHTUCJVZIRP-SVZMEOIVSA-N 0.000 claims description 3
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 3
- DSCFFEYYQKSRSV-UHFFFAOYSA-N 1L-O1-methyl-muco-inositol Natural products COC1C(O)C(O)C(O)C(O)C1O DSCFFEYYQKSRSV-UHFFFAOYSA-N 0.000 claims description 3
- KTFUNVBAGAPLLC-UHFFFAOYSA-N 2-amino-5-ethoxybenzenesulfonic acid Chemical compound CCOC1=CC=C(N)C(S(O)(=O)=O)=C1 KTFUNVBAGAPLLC-UHFFFAOYSA-N 0.000 claims description 3
- HYKDWGUFDOYDGV-UHFFFAOYSA-N 4-anilinobenzenesulfonic acid Chemical compound C1=CC(S(=O)(=O)O)=CC=C1NC1=CC=CC=C1 HYKDWGUFDOYDGV-UHFFFAOYSA-N 0.000 claims description 3
- OQSNLLFOSPUBIA-RZBHUTHNSA-N 6-o-hopr-cmhdextrin Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COC[C@H](O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO.OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COC[C@H](O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO.OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COC[C@H](O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO OQSNLLFOSPUBIA-RZBHUTHNSA-N 0.000 claims description 3
- 229920000858 Cyclodextrin Polymers 0.000 claims description 3
- VJXUJFAZXQOXMJ-UHFFFAOYSA-N D-1-O-Methyl-muco-inositol Natural products CC12C(OC)(C)OC(C)(C)C2CC(=O)C(C23OC2C(=O)O2)(C)C1CCC3(C)C2C=1C=COC=1 VJXUJFAZXQOXMJ-UHFFFAOYSA-N 0.000 claims description 3
- DSCFFEYYQKSRSV-KLJZZCKASA-N D-pinitol Chemical compound CO[C@@H]1[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@H]1O DSCFFEYYQKSRSV-KLJZZCKASA-N 0.000 claims description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 3
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 description 18
- 239000000463 material Substances 0.000 description 16
- 238000002156 mixing Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 229940077388 benzenesulfonate Drugs 0.000 description 13
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 12
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 12
- 238000003756 stirring Methods 0.000 description 10
- 235000013399 edible fruits Nutrition 0.000 description 8
- 230000000857 drug effect Effects 0.000 description 7
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 4
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- MXXDSLLVYZMTFA-UHFFFAOYSA-N octadecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 MXXDSLLVYZMTFA-UHFFFAOYSA-N 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 244000241257 Cucumis melo Species 0.000 description 3
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000005094 fruit set Effects 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- ORLPWCUCEDVJNN-UHFFFAOYSA-N sodium;tetradecyl benzenesulfonate Chemical group [Na].CCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 ORLPWCUCEDVJNN-UHFFFAOYSA-N 0.000 description 3
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 3
- YNTJKQDWYXUTLZ-UHFFFAOYSA-N 2-(3-chlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=CC(Cl)=C1 YNTJKQDWYXUTLZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000003375 plant hormone Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- UDPGUMQDCGORJQ-UHFFFAOYSA-N (2-chloroethyl)phosphonic acid Chemical compound OP(O)(=O)CCCl UDPGUMQDCGORJQ-UHFFFAOYSA-N 0.000 description 1
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 description 1
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- OORIKNJWZHTXDC-UHFFFAOYSA-N CCCC(CC)C(CC)(C(=O)OCC)N Chemical compound CCCC(CC)C(CC)(C(=O)OCC)N OORIKNJWZHTXDC-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 208000035240 Disease Resistance Diseases 0.000 description 1
- 239000005976 Ethephon Substances 0.000 description 1
- 239000005979 Forchlorfenuron Substances 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000005985 Paclobutrazol Substances 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- HFCYZXMHUIHAQI-UHFFFAOYSA-N Thidiazuron Chemical compound C=1C=CC=CC=1NC(=O)NC1=CN=NS1 HFCYZXMHUIHAQI-UHFFFAOYSA-N 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 230000005059 dormancy Effects 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- GPXLRLUVLMHHIK-UHFFFAOYSA-N forchlorfenuron Chemical compound C1=NC(Cl)=CC(NC(=O)NC=2C=CC=CC=2)=C1 GPXLRLUVLMHHIK-UHFFFAOYSA-N 0.000 description 1
- IXZISFNWUWKBOM-ARQDHWQXSA-N fructosamine Chemical compound NC[C@@]1(O)OC[C@@H](O)[C@@H](O)[C@@H]1O IXZISFNWUWKBOM-ARQDHWQXSA-N 0.000 description 1
- 230000005089 fruit drop Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003617 indole-3-acetic acid Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- ODLHGICHYURWBS-FOSILIAISA-N molport-023-220-444 Chemical compound CC(O)COC[C@@H]([C@@H]([C@H]([C@@H]1O)O)O[C@@H]2O[C@H]([C@H](O[C@@H]3O[C@@H](COCC(C)O)[C@@H]([C@H]([C@@H]3O)O)O[C@@H]3O[C@@H](COCC(C)O)[C@@H]([C@H]([C@@H]3O)O)O[C@@H]3O[C@@H](COCC(C)O)[C@@H]([C@H]([C@@H]3O)O)O[C@@H]3O[C@@H](COCC(C)O)[C@@H]([C@H]([C@@H]3O)O)O3)[C@@H](O)[C@@H]2O)COCC(O)C)O[C@H]1O[C@@H]1[C@@H](O)[C@H](O)[C@H]3O[C@H]1COCC(C)O ODLHGICHYURWBS-FOSILIAISA-N 0.000 description 1
- 150000002894 organic compounds Chemical group 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 230000008121 plant development Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of chemical pesticides, in particular to a plant growth regulating composition and a regulator thereof. The coating at least comprises the following components in parts by weight: 100-150 parts of carpronium, 0.005-0.02 part of brassinolide, 0.5-1.5 parts of gibberellin and 0.005-0.02 part of naphthylacetic acid. The plant growth regulating composition is prepared from the carposine, the brassinolide, the gibberellin, the naphthylacetic acid and the like, and the carposine, the brassinolide, the gibberellin, the naphthylacetic acid and the like have good synergistic effect.
Description
Technical Field
The invention relates to the technical field of chemical pesticides, in particular to a plant growth regulating composition and a regulator thereof.
Background
The plant growth regulator is an organic compound which is artificially synthesized (or extracted from microorganisms and is natural) and has the growth and development regulating effect similar to that of natural plant hormones. The plant growth regulator can improve the yield of crops per unit area, has the advantages of low cost, quick effect, high benefit and labor saving, and can be widely applied to controlling germination and dormancy, promoting rooting, controlling plant type, controlling flowering or sex, controlling fruit drop, promoting fruit setting, enhancing disease resistance and stress resistance and the like.
At present, commonly used plant growth regulators comprise 2,4-D, indoleacetic acid, paclobutrazol, ethephon, diethyl aminoethyl hexanoate, thidiazuron, forchlorfenuron and the like, and the using dosage is larger and smaller, and the using effect is not obvious.
Disclosure of Invention
In view of the above problems, a first aspect of the present invention provides a plant growth regulating composition comprising at least the following components in parts by weight: 100-150 parts of carpronium, 0.005-0.02 part of brassinolide, 0.5-1.5 parts of gibberellin and 0.005-0.02 part of naphthylacetic acid.
As a preferable technical scheme, the plant growth regulating composition further comprises 5-15 parts by weight of a sulfonic acid derivative containing benzene.
In a preferred embodiment, the benzene-containing sulfonic acid derivative is one or more selected from sodium alkylbenzenesulfonate having 10 to 14 carbon atoms, 2-amino-5-ethoxybenzenesulfonic acid, 4- (phenylamino) -benzenesulfonic acid, and 4- (3,5, 5-trimethylhexanoyloxy) benzenesulfonic acid.
In a preferable embodiment, in the benzene-containing sulfonic acid derivative, the weight ratio of sodium alkylbenzenesulfonate having 10 to 14 carbon atoms to 4- (3,5, 5-trimethylhexanoyloxy) benzenesulfonic acid is 1: (0.8 to 1.2).
As a preferable technical scheme, the plant growth regulating composition further comprises 0.005-0.02 part by weight of auxiliary materials.
As a preferable technical scheme, the auxiliary material is selected from one or more of maltose cyclodextrin, hydroxypropyl-beta-cyclodextrin, hydroxyethyl-beta-cyclodextrin and 6-O- (2-hydroxypropyl) -beta-cyclodextrin.
As a preferable technical scheme, the plant growth regulating composition further comprises 20-30 parts by weight of an auxiliary agent.
In a preferred embodiment, the adjuvant is one or more selected from ethanol, inositol, pinitol, glycerol, 4- (1-hydroxyethyl) -6-methyl-1, 2,3, 5-benzenetetraol, (3R,4S,5S,6R) -6- (hydroxymethyl) -2,3,4, 5-piperidintetraol.
As a preferable technical scheme, in the auxiliary agent, the weight ratio of ethanol, inositol and glycerol is (4-6): (3-5): 1.
in a second aspect of the present invention, there is provided a plant growth regulator comprising the plant growth regulating composition described above.
Has the advantages that: the plant growth regulating composition is prepared from the carposine, the brassinolide, the gibberellin, the naphthylacetic acid and the like, and the carposine, the brassinolide, the gibberellin, the naphthylacetic acid and the like have good synergistic effect.
Detailed Description
The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, but the scope of protection is not limited thereto.
"preferred", "more preferred", and the like, in the present invention, refer to embodiments of the invention that may provide certain benefits, under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention.
The invention provides a plant growth regulating composition, which at least comprises the following components in parts by weight: 100-150 parts of carpronium, 0.005-0.02 part of brassinolide, 0.5-1.5 parts of gibberellin and 0.005-0.02 part of naphthylacetic acid.
In a preferred embodiment, at least the following ingredients are included in parts by weight: 120 parts of carpronium, 0.01 part of brassinolide, 1 part of gibberellin and 0.01 part of naphthylacetic acid.
Fruit amine
Carpronide, also known as: m-chlorophenoxy isopropyl acid, 2- (3-chlorophenoxy) propionic acid, clorfrost acid and Zuo Gu' an.
The CAS number of the cyamide is 101-10-0, and the cyamide is purchased from Shanghai Tuoker chemical technology Co.
Brassinolide
Brassinolide is a novel green environment-friendly plant growth regulator, and can promote the growth of crops such as vegetables, melons, fruits and the like, improve the quality of the crops, increase the yield of the crops, enable the crops to be bright in color and luster and enable the leaves to be thicker and more solid through seed soaking with proper concentration and stem leaf spraying treatment. The tea leaf picking time can be advanced, and the melon and fruit can have higher sugar content, larger individual, higher yield and better storage stability.
The brassinolide has CAS number of 72962-43-7, and is available from Shanghai leaf Biotech limited.
Gibberellins
Gibberellins (GAs) are a very important class of plant hormones and are involved in many biological processes such as plant growth and development.
The CAS number for gibberellins is 77-06-5, available from Shanghai Michelin Biotech, Inc.
Naphthylacetic acid
The pure naphthylacetic acid is colorless needle crystal, the industrial product is tawny needle crystal, and is easy to dissolve in hot water, ethanol, acetic acid, acetone and benzene, and is a broad-spectrum plant growth regulator. Can be used for increasing effective tillering of wheat and rice, improving the ear forming rate, promoting the seed to be full and obviously increasing the yield. It is also used for increasing the yield of sweet potato and cotton. Can be used for solanaceous vegetables and melons, and can prevent flower and fruit dropping and seedless fruit formation, and increase plant drought and waterlogging resistance, saline-alkali resistance and lodging resistance.
The CAS number for naphthylacetic acid is 86-87-3, available from Shanghai Michelin Biotech, Inc.
In a preferred embodiment, the plant growth regulating composition further comprises 5 to 15 parts by weight of a sulfonic acid derivative containing benzene.
In a more preferred embodiment, the plant growth regulating composition further comprises 10 parts by weight of a sulfonic acid derivative containing benzene.
In one embodiment, the benzene-containing sulfonic acid derivative is one or more selected from sodium alkyl benzene sulfonate with 10 to 14 carbon atoms, 2-amino-5-ethoxy benzene sulfonic acid, 4- (phenylamino) -benzene sulfonic acid, and 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid.
In a preferred embodiment, the benzene-containing sulfonic acid derivative is sodium alkylbenzenesulfonate having 10 to 14 carbon atoms or 4- (3,5, 5-trimethylhexanoyloxy) benzenesulfonic acid.
In one embodiment, the weight ratio of the sodium alkyl benzene sulfonate with 10-14 carbon atoms to the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is 1: (0.8 to 1.2).
In a preferred embodiment, the weight ratio of the sodium alkyl benzene sulfonate with 10-14 carbon atoms to the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is 1: 1.
in a preferred embodiment, the sodium alkyl benzene sulfonate with 10 to 14 carbon atoms is sodium dodecyl benzene sulfonate.
The sodium dodecyl benzene sulfonate has a CAS number of 25155-30-0 and is available from Shanghai Michelin Biochemical technology Co.
The CAS number for the 4- (3,5, 5-trimethylhexanoyloxy) benzenesulfonic acid was 102568-17-2, available from Achemica.
The applicant finds that the compatibility of the composition with water can be improved by jointly preparing the composition by using the sodium alkyl benzene sulfonate with 10-14 carbon atoms and the 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid, and the compatibility of the composition with water can be improved because the surface tension of water can be reduced by the sodium alkyl benzene sulfonate with 10-14 carbon atoms and the 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid.
The applicant unexpectedly found that when a composition is prepared by using sodium alkyl benzene sulfonate with 10-14 carbon atoms and 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid together, and the weight ratio of the sodium alkyl benzene sulfonate with 10-14 carbon atoms to the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is controlled to be 1: (0.8 to 1.2), the stability of the composition obtained is good, and the applicant speculates that the possible reasons are: the sodium alkyl benzene sulfonate with 10-14 carbon atoms and the 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid can generate hydrophilic interaction and hydrophobic interaction with fruamide, brassinolide, gibberellin and the like in a system, and under specific conditions, the prepared composition has good stability due to electrostatic interaction between the sodium alkyl benzene sulfonate with 10-14 carbon atoms and the 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid. When the number of carbon atoms of the sodium alkyl benzene sulfonate is too small or too large, the stability of the prepared composition is poor; when the weight ratio of sodium alkyl benzene sulfonate with 10-14 carbon atoms to 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is not 1: when the amount is in the range of (0.8 to 1.2), the stability of the composition obtained is poor and the drug effect is also impaired.
In a preferred embodiment, the plant growth regulating composition further comprises 0.005 to 0.02 parts by weight of an adjuvant.
In a more preferred embodiment, the plant growth regulating composition further comprises 0.01 parts by weight of an adjuvant.
In one embodiment, the adjunct is selected from one or more of maltose cyclodextrin, hydroxypropyl- β -cyclodextrin, hydroxyethyl- β -cyclodextrin, 6-O- (2-hydroxypropyl) - β -cyclodextrin.
In a preferred embodiment, the excipient is hydroxypropyl- β -cyclodextrin.
The CAS number of the hydroxypropyl-beta-cyclodextrin is 128446-35-5, and the hydroxypropyl-beta-cyclodextrin is purchased from Shanghai leaf Biotech limited.
The applicant found that when hydroxypropyl-beta-cyclodextrin is used as an auxiliary material, the compatibility of the composition with water can be improved, which is probably due to the special structure of hydroxypropyl-beta-cyclodextrin, the inner cavity of the ring structure has hydrophobicity, the special structure can enable brassinolide to be dynamically included in the cavity, and the outer part of the ring structure has a plurality of hydroxyl groups and has hydrophilicity, so that the compatibility of the composition with water is improved. In addition, the hydroxypropyl-beta-cyclodextrin has good biodegradability and no pollution to crops and environment.
In a preferred embodiment, the plant growth regulating composition further comprises 20 to 30 parts by weight of an adjuvant.
In a more preferred embodiment, the plant growth regulating composition further comprises 25 parts by weight of an adjuvant.
In one embodiment, the adjuvant is selected from one or more of ethanol, inositol, pinitol, glycerol, 4- (1-hydroxyethyl) -6-methyl-1, 2,3, 5-benzenetetraol, (3R,4S,5S,6R) -6- (hydroxymethyl) -2,3,4, 5-piperidintetraol.
In a preferred embodiment, the adjuvant is ethanol, inositol, glycerol.
In one embodiment, the weight ratio of ethanol, inositol and glycerol is (4-6): (3-5): 1.
in a preferred embodiment, the weight ratio of ethanol, inositol and glycerol is 5: 4: 1.
the applicant finds that when the auxiliary agent consists of ethanol, inositol and glycerol together, and the composition is prepared by using the sodium dodecyl benzene sulfonate and the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid, the compatibility of the prepared composition with water is further improved; the applicant speculates that possible reasons are: under the existence of sodium dodecyl benzene sulfonate and 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid, gibberellin in the system can interact with inositol and the like to convert the gibberellin into various states such as a free state, a combined state and the like, so that the compatibility of the composition with water is improved; meanwhile, as gibberellin exists in a system in a bound state, the gibberellin can be stably stored in the bodies of crops during application, can be mutually converted between a free state and a bound state, can exert physiological effects when seeds germinate, and can be stored in a bound state when the seeds mature, so that the prepared composition has good drug effects.
In addition, the applicant unexpectedly finds that when hydroxypropyl-beta-cyclodextrin is used as an auxiliary material, the weight ratio of ethanol to inositol to glycerol is controlled to be (4-6): (3-5): 1, the prepared composition has better drug effect. The applicant speculates that possible reasons are: under specific conditions, non-covalent intermolecular forces such as van der waals force, hydrophobic bond effect, hydrogen bond and the like between hydrophobic cavities of the brassinolide and the hydroxypropyl-beta-cyclodextrin act together to improve the inclusion stability and the inclusion rate of the brassinolide and the hydroxypropyl-beta-cyclodextrin, and because the cavities of hydroxypropyl-beta-cyclodextrin molecules are hydrophobic, the brassinolide is positioned at a position which is favorable for the maximum area contact between a hydrophobic group and the hydrophobic cavities in the cavities, and a hydrophilic group of the brassinolide is far away from the hydrophobic cavities as possible, the hydroxypropyl-beta-cyclodextrin can better include the brassinolide, so that the drug effect of the composition is improved. When the weight ratio of ethanol, inositol and glycerol is not (4-6): (3-5): 1 range, the efficacy of the prepared composition is poor.
The synergistic effect of sodium dodecyl benzene sulfonate, 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid, hydroxypropyl-beta-cyclodextrin, inositol, brassinolide, gibberellin and the like can effectively enhance the compatibility of the composition with water and the stability of the composition, increase the absorption of crops to effective components and improve the drug effect of the prepared composition.
In one embodiment, the plant growth regulating composition is prepared by a process comprising at least the steps of: mixing gibberellin, benzene-containing sulfonic acid derivatives and auxiliaries, reacting for 4-6 hours at 40-55 ℃, sequentially adding brassinolide and auxiliary materials at 30-50 ℃, stirring and mixing for 1-3 hours, adding fructosamine and naphthylacetic acid at normal temperature, stirring and mixing to obtain the plant growth regulating composition.
In a preferred embodiment, the plant growth regulating composition is prepared by a process comprising at least the steps of: gibberellin, sulfonic acid derivatives containing benzene and an auxiliary agent are mixed and then react for 5 hours at the temperature of 48 ℃, brassinolide and the auxiliary material are sequentially added at the temperature of 40 ℃, after stirring and mixing for 2 hours, carpronium and naphthylacetic acid are added at the normal temperature, and the plant growth regulating composition is prepared after stirring and mixing.
In a second aspect of the present invention, there is provided a plant growth regulator comprising the plant growth regulating composition described above.
Methods of use of the plant growth regulating compositions: mixing a plant growth regulating composition with water in a ratio of 1: 1000 by weight ratio, and mixing.
Hereinafter, the present invention will be described in more detail by way of examples, but it should be understood that these examples are merely illustrative and not restrictive.
Examples
Example 1
Embodiment 1 of the present invention provides a plant growth regulating composition, comprising the following components in parts by weight: 120 parts of carpronium, 0.01 part of brassinolide, 1 part of gibberellin, 0.01 part of naphthylacetic acid, 10 parts of benzene-containing sulfonic acid derivatives, 0.01 part of auxiliary materials and 25 parts of auxiliary agents.
The sulfonic acid derivative containing benzene is sodium dodecyl benzene sulfonate and 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid.
The weight ratio of the sodium dodecyl benzene sulfonate to the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is 1: 1.
the auxiliary material is hydroxypropyl-beta-cyclodextrin.
The auxiliary agent is ethanol, inositol and glycerol.
The weight ratio of the ethanol to the inositol to the glycerol is 5: 4: 1.
the preparation method of the plant growth regulating composition comprises the following steps: gibberellin, sulfonic acid derivatives containing benzene and an auxiliary agent are mixed and then react for 5 hours at the temperature of 48 ℃, brassinolide and the auxiliary material are sequentially added at the temperature of 40 ℃, after stirring and mixing for 2 hours, carpronium and naphthylacetic acid are added at the normal temperature, and the plant growth regulating composition is prepared after stirring and mixing.
Example 1 of the present invention also provides a plant growth regulator comprising the above plant growth regulating composition.
Example 2
Embodiment 2 of the present invention provides a plant growth regulating composition, comprising the following components, by weight: 100 parts of carpolite, 0.005 part of brassinolide, 0.5 part of gibberellin, 0.005 part of naphthylacetic acid, 5 parts of sulfonic acid derivatives containing benzene, 0.005 part of auxiliary materials and 20 parts of auxiliary agents.
The sulfonic acid derivative containing benzene is sodium dodecyl benzene sulfonate and 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid.
The weight ratio of the sodium dodecyl benzene sulfonate to the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is 1: 0.8.
the CAS number of the sodium dodecyl benzene sulfonate is 2627-06-7, and is purchased from Bailingwei science and technology Co.
The auxiliary material is hydroxypropyl-beta-cyclodextrin.
The auxiliary agent is ethanol, inositol and glycerol.
The weight ratio of the ethanol to the inositol to the glycerol is 4: 3: 1.
the preparation method of the plant growth regulating composition comprises the following steps: gibberellin, sulfonic acid derivatives containing benzene and an auxiliary agent are mixed and then react for 5 hours at the temperature of 48 ℃, brassinolide and the auxiliary material are sequentially added at the temperature of 40 ℃, after stirring and mixing for 2 hours, carpronium and naphthylacetic acid are added at the normal temperature, and the plant growth regulating composition is prepared after stirring and mixing.
Example 2 of the present invention also provides a plant growth regulator comprising the above plant growth regulating composition.
Example 3
Embodiment 3 of the present invention provides a plant growth regulating composition, comprising the following components, by weight: 150 parts of carpamine, 0.02 part of brassinolide, 1.5 parts of gibberellin, 0.02 part of naphthylacetic acid, 15 parts of benzene-containing sulfonic acid derivatives, 0.02 part of auxiliary materials and 30 parts of auxiliary agents.
The sulfonic acid derivative containing benzene is sodium tetradecyl benzene sulfonate and 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid.
The weight ratio of the sodium tetradecyl benzene sulfonate to the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is 1: 1.2.
the CAS number for sodium tetradecyl benzenesulfonate is 1797-33-7, available from Achemica.
The auxiliary material is hydroxypropyl-beta-cyclodextrin.
The auxiliary agent is ethanol, inositol and glycerol.
The weight ratio of the ethanol to the inositol to the glycerol is 6: 5: 1.
the preparation method of the plant growth regulating composition comprises the following steps: gibberellin, sulfonic acid derivatives containing benzene and an auxiliary agent are mixed and then react for 5 hours at the temperature of 48 ℃, brassinolide and the auxiliary material are sequentially added at the temperature of 40 ℃, after stirring and mixing for 2 hours, carpronium and naphthylacetic acid are added at the normal temperature, and the plant growth regulating composition is prepared after stirring and mixing.
Example 3 of the present invention also provides a plant growth regulator comprising the above plant growth regulating composition.
Example 4
Embodiment 4 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment thereof is the same as embodiment 1, except that:
the sulfonic acid derivative containing benzene is sodium octadecyl benzene sulfonate and 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid.
The weight ratio of the sodium octadecyl benzene sulfonate to the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is 1: 1.
the CAS number of the sodium octadecyl benzene sulfonate is 27177-79-3, and the sodium octadecyl benzene sulfonate is purchased from Cheng Du Mei Kai biological science and technology limited company.
Example 5
Embodiment 5 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment thereof is the same as embodiment 1, except that:
the sulfonic acid derivative containing benzene is octa-sodium alkyl benzene sulfonate and 4- (3,5, 5-trimethyl hexanoyloxy) benzenesulfonic acid.
The weight ratio of the sodium octa-alkylbenzene sulfonate to the 4- (3,5, 5-trimethyl hexanoyloxy) benzene sulfonic acid is 1: 1.
the CAS number of the octa-alkyl benzene sodium sulfonate is 6149-03-7, and the octa-alkyl benzene sodium sulfonate is purchased from Bailingwei science and technology limited company.
Example 6
Embodiment 6 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment is the same as embodiment 1, except that the weight ratio of sodium dodecylbenzenesulfonate to 4- (3,5, 5-trimethylhexanoyloxy) benzenesulfonic acid is replaced with 1: 0.3.
example 7
Embodiment 7 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment is the same as embodiment 1, except that the weight ratio of sodium dodecylbenzenesulfonate to 4- (3,5, 5-trimethylhexanoyloxy) benzenesulfonic acid is replaced with 1: 2.
example 8
Embodiment 8 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment thereof is the same as embodiment 1, except that the content of the benzene-containing sulfonic acid derivative is replaced with 0.
Example 9
Embodiment 9 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment thereof is the same as embodiment 1, except that the content of the auxiliary material is replaced with 0.
Example 10
Embodiment 10 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment of the plant growth regulating composition is the same as that in embodiment 1, except that the auxiliary agent is ethanol.
Example 11
Example 11 of the present invention provides a plant growth regulating composition and also provides a plant growth regulator, in a specific embodiment the same as example 1 except that the adjuvant is inositol.
Example 12
Embodiment 12 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment thereof is the same as embodiment 1, except that the auxiliary agent is glycerol.
Example 13
Embodiment 13 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific implementation manner of the plant growth regulating composition is the same as that of embodiment 1, except that the auxiliary agent is ethanol and inositol, and the weight ratio of the ethanol to the inositol is 5: 4.
example 14
The embodiment 14 of the invention provides a plant growth regulating composition and a plant growth regulator, and the specific implementation manner of the plant growth regulating composition is the same as that of the embodiment 1, except that the auxiliary agent is ethanol and glycerol, and the weight ratio of the ethanol to the glycerol is 5: 1.
example 15
Embodiment 15 of the present invention provides a plant growth regulating composition and a plant growth regulator, and the specific embodiment of the plant growth regulating composition is the same as that of embodiment 1, except that the auxiliary agent is inositol and glycerol, and the weight ratio of the inositol to the glycerol is 4: 1.
example 16
Example 16 of the present invention provides a plant growth regulating composition and also provides a plant growth regulator, and the specific embodiment thereof is the same as example 1, except that the weight ratio of ethanol, inositol and glycerol is replaced by 5: 1: 1.
performance evaluation
1. Compatibility testing
The plant growth regulating composition prepared in examples 1 to 16 was mixed with 1000 times by weight of water, and the compatibility of the composition with water was observed. Compatibility evaluation criteria: good-no layering and precipitation are observed; poor-delamination, precipitation was observed.
2. Stability test
The plant growth regulating composition prepared in examples 1 to 16 was allowed to stand at room temperature for 1 month, and the stability was observed. And (3) stability evaluation standard: good-no layering and precipitation are observed; poor-delamination, precipitation was observed.
3. Test of field drug effect
Applying the plant growth regulating composition prepared in the embodiments 1-7 and 10-16 to the growth and development of the cherry, and mixing the plant growth regulating composition and water in a ratio of 1: 1000 parts by weight of the composition was mixed and applied at 40% of the time of flowering, and the fruit set rate was calculated.
Fruit set rate (%) (fruit real number/flowering number) × 100%
The experimental results are shown below:
TABLE 1 Performance test results of plant growth regulating compositions prepared in examples 1-16
| Compatibility | Stability of | Percentage of fruit set (%) | |
| Example 1 | Good taste | Good taste | 58 |
| Example 2 | Good taste | Good taste | 56 |
| Example 3 | Good taste | Good taste | 55 |
| Example 4 | Good taste | Difference (D) | 47 |
| Example 5 | Good taste | Difference (D) | 49 |
| Example 6 | Good taste | Difference (D) | 45 |
| Example 7 | Good taste | Difference (D) | 46 |
| Example 8 | Difference (D) | Difference (D) | - |
| Example 9 | Difference (D) | Difference (D) | - |
| Example 10 | Difference (D) | Difference (D) | 32 |
| Example 11 | Difference (D) | Difference (D) | 39 |
| Example 12 | Difference (D) | Difference (D) | 33 |
| Example 13 | Difference (D) | Difference (D) | 40 |
| Example 14 | Difference (D) | Difference (D) | 34 |
| Example 15 | Difference (D) | Difference (D) | 42 |
| Example 16 | Difference (D) | Difference (D) | 44 |
According to the performance test result, the plant growth regulating composition prepared by the invention has the advantages of good compatibility with water, good stability and excellent drug effect, and can promote the plant growth and improve the fruit setting rate of plants.
The foregoing examples are merely illustrative and serve to explain some of the features of the method of the present invention. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. The use of some numerical ranges in the claims also includes sub-ranges within their range, and variations in these ranges are also to be construed as being covered by the appended claims where possible.
Claims (10)
1. A plant growth regulating composition is characterized by comprising the following components in parts by weight: 100-150 parts of carpronium, 0.005-0.02 part of brassinolide, 0.5-1.5 parts of gibberellin and 0.005-0.02 part of naphthylacetic acid.
2. The plant growth regulating composition according to claim 1, further comprising 5 to 15 parts by weight of a sulfonic acid derivative containing benzene.
3. The plant growth regulating composition according to claim 2, wherein the benzene-containing sulfonic acid derivative is one or more selected from the group consisting of sodium alkylbenzenesulfonate having 10 to 14 carbon atoms, 2-amino-5-ethoxybenzenesulfonic acid, 4- (phenylamino) -benzenesulfonic acid, and 4- (3,5, 5-trimethylhexanoyloxy) benzenesulfonic acid.
4. The plant growth regulating composition according to claim 3, wherein the weight ratio of the sodium alkylbenzenesulfonate having 10 to 14 carbon atoms to the 4- (3,5, 5-trimethylhexanoyloxy) benzenesulfonic acid in the benzene-containing sulfonic acid derivative is 1: (0.8 to 1.2).
5. The plant growth regulating composition according to any one of claims 2 to 4, further comprising 0.005 to 0.02 parts by weight of an adjuvant.
6. The plant growth regulating composition according to claim 5, wherein the adjuvant is selected from one or more of maltose cyclodextrin, hydroxypropyl- β -cyclodextrin, hydroxyethyl- β -cyclodextrin, 6-O- (2-hydroxypropyl) - β -cyclodextrin.
7. The plant growth regulating composition according to claim 5, further comprising 20 to 30 parts by weight of an adjuvant.
8. The plant growth regulating composition according to claim 7, wherein the adjuvant is selected from one or more of ethanol, inositol, pinitol, glycerol, 4- (1-hydroxyethyl) -6-methyl-1, 2,3, 5-benzenetetraol, (3R,4S,5S,6R) -6- (hydroxymethyl) -2,3,4, 5-piperidintetraol.
9. The plant growth regulating composition according to claim 8, wherein the weight ratio of ethanol, inositol and glycerol in the adjuvant is (4-6): (3-5): 1.
10. a plant growth regulator, comprising the above plant growth regulating composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911093178.4A CN110720463B (en) | 2019-11-11 | 2019-11-11 | Plant growth regulating composition and regulator thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911093178.4A CN110720463B (en) | 2019-11-11 | 2019-11-11 | Plant growth regulating composition and regulator thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110720463A true CN110720463A (en) | 2020-01-24 |
| CN110720463B CN110720463B (en) | 2023-06-30 |
Family
ID=69225241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911093178.4A Active CN110720463B (en) | 2019-11-11 | 2019-11-11 | Plant growth regulating composition and regulator thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110720463B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116806834A (en) * | 2023-08-29 | 2023-09-29 | 江苏惠利生物科技有限公司 | Plant growth regulator |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1478390A (en) * | 2003-07-08 | 2004-03-03 | 云大科技股份有限公司 | Plant growth regulating agent mixture containing brassinolide like compound and its application |
| CN104872130A (en) * | 2015-04-07 | 2015-09-02 | 河南中天恒信生物化学科技有限公司 | Composite plant growth regulator containing choline chloride, cloprop and naphthylacetic acid |
-
2019
- 2019-11-11 CN CN201911093178.4A patent/CN110720463B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1478390A (en) * | 2003-07-08 | 2004-03-03 | 云大科技股份有限公司 | Plant growth regulating agent mixture containing brassinolide like compound and its application |
| CN104872130A (en) * | 2015-04-07 | 2015-09-02 | 河南中天恒信生物化学科技有限公司 | Composite plant growth regulator containing choline chloride, cloprop and naphthylacetic acid |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116806834A (en) * | 2023-08-29 | 2023-09-29 | 江苏惠利生物科技有限公司 | Plant growth regulator |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110720463B (en) | 2023-06-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI398218B (en) | Use of prolines for improving growth and/or yield | |
| US6180569B1 (en) | Use of tryptophan and analogs as plant growth regulators | |
| CN107105642A (en) | Plant growth regulator and the non-aqueous solution of polarity and/or semi-polarity organic solvent | |
| CN109221125B (en) | Rice anti-aging and lodging-resistant agent and application method thereof | |
| CN110461320B (en) | 1-amino-1-cyclopropanecarboxylic acid formulations | |
| CN118975563A (en) | A polysaccharide and oligopeptide composition and its application in promoting plant growth | |
| CN101361489B (en) | Corn ear-enlargement grain-increasing lodging resistant production-increasing regulator, preparation method and use thereof | |
| Yu | Parthenocarpy induced by N-(2-chloro-4-pyridyl)-N′-phenylurea (CPPU) prevents flower abortion in Chinese white-flowered gourd (Lagenaria leucantha) | |
| CN110720463A (en) | Plant growth regulating composition and regulator thereof | |
| EP0063194B1 (en) | Plant growth regulation | |
| AU2002239130B2 (en) | Plant growth regulator for increasing crop yield comprising polyprenol and extraction method thereof | |
| EP0220514B1 (en) | Composition for increasing the quantity and quality of fruits and flowers of plants | |
| US2322759A (en) | Composition and method | |
| CN107156132B (en) | A kind of Herbicidal combinations and application thereof of packet containing chlorine fluorine pyridine ester and benzobicylon | |
| AU2018297986B2 (en) | A synergistic agricultural formula comprising diacyl or diaryl urea and at least one plant growth regulator | |
| EP4120837B1 (en) | Inhibitors of cytokinin oxidase derived from 2-(3-phenylureido)benzamide, use thereof and preparations containing these derivatives | |
| US4959091A (en) | Method for increasing the yield of crops | |
| CN103694129B (en) | Beet alkaline plant growth regulator containing cinnamamide groups | |
| JP2024091096A (en) | Growth promoter for grasses | |
| JP2024122928A (en) | Plant activators | |
| JP2024018662A (en) | Plant activator for soybeans | |
| CN106748979A (en) | A kind of 2,4,6 trichlorophenyl pyridine ethyl ether plant growth regulator | |
| JP2024122739A (en) | Plant (except soybean) activators | |
| CN105248420A (en) | Rice regulator with stress resistance, high photosynthetic efficiency, lodging resistance and yield increase function as well as preparation method and application of rice regulator | |
| JP2024018664A (en) | plant activator |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20230421 Address after: Room 301, Unit 1, Building 3, Fenghuang Community, Fenghuang Road, Yangling District, Xianyang City, Shaanxi Province, 712000 Applicant after: Guo Xucheng Address before: 712000 Luli Incubation Park, East Section of Wuhu Road, Yangling Demonstration Zone, Xianyang City, Shaanxi Province Applicant before: Shaanxi Dacheng crop protection Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230913 Address after: Room 420, 4th Floor, Building 6, Yabulun Industrial Park, Yazhou Bay Science and Technology City, Yazhou District, Sanya City, Hainan Province, 572024 Patentee after: Zhongjin Group (Hainan) Co.,Ltd. Address before: Room 301, Unit 1, Building 3, Fenghuang Community, Fenghuang Road, Yangling District, Xianyang City, Shaanxi Province, 712000 Patentee before: Guo Xucheng |