CN110669538A - Biochar-heat cogeneration process and device for continuous self-circulation of heat - Google Patents
Biochar-heat cogeneration process and device for continuous self-circulation of heat Download PDFInfo
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Abstract
本发明涉及连续实现热量自循环的生物质炭‑热联产工艺及装置,步骤为:S1对生物质原料进行破碎处理;S2在低氧工况下,对破碎后的生物质原料进行炭化处理,中间产物包括生物质燃气、以气相存在于生物质燃气中的焦油和醋液,最终产物为生物质炭;首次启动的高温烟气通过在燃烧室内通入助燃空气燃烧辅助燃料;生物质燃气、焦油和醋液外排后进行燃烧处理,产生的热量作为碳化处理启动后供热使用,使用后的外排烟气经水冷却和净化处理后,一部分排空处理,另一部分回流用于控制燃烧温度;生物质炭外排后经水冷却处理,形成生物质炭产品;外排烟气水冷却和生物质炭水冷却回流的热水供给用热部位使用,用热后的冷水循环作为冷却水给水使用。本发明投资成本低、无三废污染、低碳排放。
The invention relates to a biomass charcoal-heat co-generation process and device for continuously realizing heat self-circulation. The steps are: S1, crushing biomass raw materials; S2, under low oxygen conditions, carbonizing the crushed biomass raw materials. , the intermediate products include biomass gas, tar and vinegar in the gas phase in the biomass gas, and the final product is biomass charcoal; the high-temperature flue gas that is started for the first time burns auxiliary fuel by introducing combustion-supporting air into the combustion chamber; biomass gas , tar and vinegar liquid are discharged and burned, and the heat generated is used as heating after carbonization treatment is started. After the exhausted flue gas is cooled and purified by water, part of it is evacuated, and the other part is returned for control. Combustion temperature; biomass charcoal is cooled by water after being discharged to form a biomass charcoal product; the hot water supply of the water cooling of the external flue gas and the cooling and returning of the biomass charcoal water is used in the hot part, and the hot cold water circulation is used as cooling Water for water use. The invention has low investment cost, no three waste pollution and low carbon emission.
Description
技术领域technical field
本发明属于生物质炭化生产技术领域,涉及生物炭-热联产工艺及相关装置,具体涉及一种连续实现热量自循环的生物炭-热联产工艺及装置。The invention belongs to the technical field of biomass carbonization production, relates to a biochar-heat co-generation process and related devices, and in particular relates to a bio-char-heat co-generation process and device for continuously realizing heat self-circulation.
背景技术Background technique
近年来,大气污染导致的“雾霾”现象日益严重,2013年,国务院发布《大气污染防治行动方案》(“大气十条”)明确提出5年内全国空气质量总体改善,津京冀地区细颗粒物浓度下降25%。2017年,为了解决农村散煤燃烧取暖给大气造成的污染,京津冀地区首先实施了农村“煤改气”工程。但经过近两年的实践,煤改气实施效果不尽人意。主要原因有两个方面,一是在用气高峰上出现了气源紧张、供不应求的情况;二是天然气价格较高,取暖费用高。此外,还存在用气安全等多方面的问题。In recent years, the phenomenon of "smog" caused by air pollution has become increasingly serious. In 2013, the State Council issued the "Air Pollution Prevention and Control Action Plan" ("Ten Atmospheric Regulations"), which clearly stated that the national air quality will be generally improved within five years, and the concentration of fine particulate matter in the Tianjin-Beijing-Hebei region will be improved. down 25%. In 2017, in order to solve the air pollution caused by the burning of scattered coal in rural areas, the Beijing-Tianjin-Hebei region first implemented the rural "coal-to-gas" project. But after nearly two years of practice, the effect of coal-to-gas implementation is not satisfactory. There are two main reasons. One is that the gas supply is in short supply during the peak of gas consumption; the other is that the price of natural gas is high and the heating cost is high. In addition, there are also many problems such as gas safety.
农村有丰富的生物质资源,就地取材,开发利用生物质能源,不但可以减少农业秸秆等废弃物的环境污染,又可以探索一条农村清洁供暖的新模式。There are abundant biomass resources in rural areas, and the development and utilization of biomass energy can not only reduce the environmental pollution of agricultural straw and other wastes, but also explore a new mode of clean heating in rural areas.
在生物质的利用技术中,能源利用率高、技术相对成熟、可以代替燃煤作为取暖原料的方式有秸秆焚烧发电和秸秆气化发电,这两种方式投资规模大,生产过程复杂,受到规模效益的限制,适合以县区为单位进行工程建设。不适合以农村为单位进行建设。同时,秸秆发电有一定的大气污染,气化发电有一定的焦油和残渣的污染。另外,秸秆焚烧和秸秆气化燃烧都有比较高的炭排放。Among biomass utilization technologies, the energy utilization rate is high, the technology is relatively mature, and the methods that can replace coal as heating raw materials include straw incineration power generation and straw gasification power generation. These two methods have large investment scale and complex production process. Due to the limitation of benefits, it is suitable to carry out engineering construction in units of counties and districts. It is not suitable for construction in rural areas. At the same time, straw power generation has certain air pollution, and gasification power generation has certain tar and residue pollution. In addition, both straw burning and straw gasification burning have relatively high carbon emissions.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于克服现有技术的不足之处,提供一种投资成本低、无三废污染、操作简单、低炭排放特点的连续实现热量自循环的生物质炭-热联产工艺及装置。The purpose of the present invention is to overcome the deficiencies of the prior art, and provide a biomass charcoal-heat cogeneration process and device that continuously realizes self-circulation of heat with low investment cost, no three-waste pollution, simple operation and low carbon emission characteristics.
本发明的上述目的通过如下技术方案来实现:Above-mentioned purpose of the present invention is realized by following technical scheme:
一种连续实现热量自循环的生物质炭-热联产工艺,其特征在于,包括如下步骤:A biomass charcoal-heat co-production process for continuously realizing self-circulation of heat, characterized in that it comprises the following steps:
S1对生物质原料进行破碎处理;S1 crushes biomass raw materials;
S2在低氧工况下,对破碎后的生物质原料进行炭化处理,维持炭化的温度通过在炭化室外的夹腔内流通的高温烟气来提供,炭化处理的中间产物包括生物质燃气、以气相存在于生物质燃气中的焦油和醋液,炭化后的最终产物为生物质炭;S2 is to carbonize the crushed biomass raw materials under low oxygen conditions, and the temperature to maintain carbonization is provided by the high-temperature flue gas circulating in the cavity outside the carbonization chamber. The intermediate products of carbonization treatment include biomass fuel gas, The gas phase exists in the tar and vinegar liquid in the biomass gas, and the final product after carbonization is biomass carbon;
首次启动的高温烟气通过在燃烧室内通入助燃空气燃烧辅助燃料来实现;The high-temperature flue gas at the first start is realized by introducing combustion-supporting air into the combustion chamber to burn auxiliary fuel;
炭化过程中产生的中间产物排出炭化室后,进行燃烧净化处理,燃烧后产生的热量作为炭化处理启动后供热使用,使用后的外排烟气先后经水冷却和净化处理,一部分排空处理,另一部回流用于控制燃烧温度;After the intermediate products produced in the carbonization process are discharged from the carbonization chamber, they are subjected to combustion and purification treatment. The heat generated after combustion is used for heating after the carbonization treatment is started. , and the other recirculation is used to control the combustion temperature;
其中,生物质炭外排后经水冷却处理,形成可用作吸附材料、土壤改良剂、肥料缓释载体和二氧化炭封存剂的生物质炭产品;Among them, the biomass charcoal is cooled by water after being discharged to form a biomass charcoal product that can be used as adsorption material, soil conditioner, fertilizer slow-release carrier and carbon dioxide sequestration agent;
其中,外排烟气水冷却和生物质炭水冷却回流的热水供给用热部位使用,用热后的冷水循环作为冷却水给水使用。Among them, the hot water supply for the cooling of the external flue gas water and the cooling and reflux of the biomass charcoal water is used for the hot part, and the hot cold water circulation is used as the cooling water supply water.
而且的,S2中首次启动高温烟气的方法为:Moreover, the method of starting the high temperature flue gas for the first time in S2 is:
1)先开启燃烧室内的燃烧器点火开关;1) First turn on the ignition switch of the burner in the combustion chamber;
2)然后按照设定的空气量开启助燃空气控制阀;2) Then open the combustion air control valve according to the set air volume;
3)然后全开启辅助燃料控制阀;3) Then fully open the auxiliary fuel control valve;
4)检测燃烧室烟气出口温度,至温度达到设定值;4) Detect the flue gas outlet temperature of the combustion chamber until the temperature reaches the set value;
5)启动生物质炭化处理:生物质在设定进料量下进入炭化室,在设定炭化时间进行炭化,炭化产生的裂解气进入燃烧室与辅助燃料一起燃烧,实现首次启动。5) Start biomass carbonization treatment: The biomass enters the carbonization chamber under the set feed amount, and is carbonized at the set carbonization time. The cracked gas generated by the carbonization enters the combustion chamber and burns with the auxiliary fuel to realize the first start.
而且的,S2中在炭化处理启动后连续供热过程中对炭化室温度进行控制的方法为:Moreover, the method for controlling the temperature of the carbonization chamber during the continuous heating process after the carbonization treatment is started in S2 is:
1)检测炭化室实际温度,与控制系统中设定的温度范围值进行比较;1) Detect the actual temperature of the carbonization chamber and compare it with the temperature range value set in the control system;
2)根据比较结构,进行温度调控,具体为:2) According to the comparative structure, temperature regulation is carried out, specifically:
a、在实际温度超过设定温度范围的情况下,先判断辅助燃料控制阀是否关闭;在未关闭的工况下,逐渐关小辅助燃料控制阀,在该操作过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则进入正常运行,如果不是,则继续关小辅助燃料控制阀,直至炭化室温度及燃烧室的烟气出口温度调节至设定范围内;在辅助燃料控制阀已关闭的工况下,检测外排烟气的回流是否达到最大,如果未达到最大值,则逐渐开启回流风机和回流控制阀,在该操作的过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则停止操作,进入正常运行,如果不是,则继续开大回流风机和烟气回流阀,直至炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内;而在外排烟气的回流已达到最大值的工况下,逐渐减少进入炭化室的生物质进料量并缩短炭化时间,在该操作过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则进入正常运行状态,如果不是,继续逐渐减少进入炭化室的生物质进料量并缩短炭化时间,直至炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内;a. When the actual temperature exceeds the set temperature range, first determine whether the auxiliary fuel control valve is closed; under the condition that it is not closed, gradually close the auxiliary fuel control valve. During this operation, detect the temperature of the carbonization chamber and Whether the flue gas outlet temperature of the combustion chamber is adjusted to the set range, if so, enter normal operation; if not, continue to close the auxiliary fuel control valve until the carbonization chamber temperature and the flue gas outlet temperature of the combustion chamber are adjusted to the set value. within a certain range; under the condition that the auxiliary fuel control valve is closed, check whether the backflow of the external exhaust gas reaches the maximum value. If it does not reach the maximum value, gradually open the backflow fan and the backflow control valve. Check whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted within the set range. If so, stop the operation and enter normal operation. If not, continue to open the return fan and the flue gas return valve until the temperature of the carbonization chamber. and whether the flue gas outlet temperature of the combustion chamber is adjusted to the set range; and under the condition that the backflow of the external exhaust gas has reached the maximum value, gradually reduce the amount of biomass feeding into the carbonization chamber and shorten the carbonization time. During the operation, check whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted within the set range. If so, enter the normal operation state. If not, continue to gradually reduce the amount of biomass feeding into the carbonization chamber and shorten it. Carbonization time until the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted within the set range;
b、在实际温度低于设定温度范围的情况下,判断辅助燃料控制阀是否开至最大;在未开至最大的工况下,逐渐开大辅助燃料控制阀,在该操作过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则进入正常运行,如果不是,则继续开大辅助燃料控制阀,直至炭化室温度及燃烧室的烟气出口温度调节至设定范围内;在辅助燃料控制阀已开至最大的工况下,检测外排烟气的回流是否完全关闭,如果未完全关闭,则逐渐关闭回流风机和回流控制阀,在该操作的过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则停止操作,进入正常运行,如果不是,则继续关闭烟气回流风机和烟气回流阀,直至炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内;而在外排烟气的回流已完全关闭的工况下,逐渐增加进入炭化室的生物质进料量并延长炭化时间,在该操作过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则进入正常运行状态,如果不是,继续逐渐增加进入炭化室的生物质进料量并延长炭化时间,直至炭化室温度及燃烧室的烟气出口温度调节至设定范围内。b. When the actual temperature is lower than the set temperature range, judge whether the auxiliary fuel control valve is opened to the maximum; under the condition that the auxiliary fuel control valve is not opened to the maximum, gradually open the auxiliary fuel control valve. Whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to the set range, if so, enter normal operation; if not, continue to open the auxiliary fuel control valve until the temperature of the carbonization chamber and the flue gas outlet of the combustion chamber Adjust the temperature to within the set range; under the condition that the auxiliary fuel control valve has been opened to the maximum, check whether the return of the external exhaust gas is completely closed, if not, gradually close the return fan and return control valve. During the operation, check whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to the set range. If so, stop the operation and enter normal operation. If not, continue to turn off the flue gas return fan and flue gas return. until the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to within the set range; and under the condition that the backflow of the external exhaust gas has been completely closed, the biomass feed amount into the carbonization chamber is gradually increased and prolonged. Carbonization time. During this operation, check whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to within the set range. If so, enter the normal operation state. If not, continue to gradually increase the biomass entering the carbonization chamber. Increase the amount of feed and prolong the carbonization time until the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to within the set range.
而且的,S2中炭化处理温度为450-550℃。Moreover, the carbonization temperature in S2 is 450-550°C.
而且的,外排烟气的净化处理步骤为:先采用碱性溶液吸收烟气中少量的酸性气体,然后再利用活性炭对烟气进一步净化。Moreover, the purification treatment steps of the exhausted flue gas are as follows: first, an alkaline solution is used to absorb a small amount of acid gas in the flue gas, and then activated carbon is used to further purify the flue gas.
本发明的上述目的通过如下技术方案来实现:Above-mentioned purpose of the present invention is realized by following technical scheme:
一种连续实现热量自循环的生物质炭-热联产装置,其特征在于:包括破碎机、第一锁风器、炭化器、旋风分离器、燃烧室、第二锁风器、生物炭冷却器、第三锁风器、喷淋液循环泵、碱液吸收塔、活性炭吸附层、回流风机、烟气外排设备、烟气冷却器;A biomass charcoal-heat cogeneration device that continuously realizes self-circulation of heat, characterized in that it includes a crusher, a first air lock, a carbonizer, a cyclone separator, a combustion chamber, a second air lock, and a biochar cooling device, the third air lock, the spray liquid circulation pump, the lye absorption tower, the activated carbon adsorption layer, the return fan, the flue gas discharge equipment, and the flue gas cooler;
所述炭化器和生物炭冷却器均为外带夹套的螺旋输送机构,炭化器和生物炭冷却器的驱动机构均由变频电机和减速机连接构成,其中炭化器的外夹套内形成高温烟气通过腔,生物炭冷却器的外夹套内形成冷却水通过腔;所述活性炭吸附层设置于碱液吸收塔内的上层;Both the carbonizer and the biochar cooler are screw conveying mechanisms with outer jackets, and the drive mechanisms of the carbonizer and the biochar cooler are both connected by a frequency conversion motor and a reducer, and a high temperature is formed in the outer jacket of the carbonizer. The flue gas passes through the cavity, and the cooling water pass cavity is formed in the outer jacket of the bio-char cooler; the activated carbon adsorption layer is arranged on the upper layer of the lye absorption tower;
破碎机位于第一锁风器上方,破碎机的出料口通过管路与第一锁风器相连;炭化器位于第一锁风器下方,炭化器的物料进口与第一锁风器相连;第二锁风器位于炭化器的生物炭出料端下方、并与炭化器的生物炭出料口相连;生物炭冷却器位于第二锁风器的下方,其物料进口与第二锁风器相连;第三锁风器位于生物炭冷却器的下方,并与生物炭冷却器的生物炭出料口相连;旋风分离器的进气口通过管道与炭化器的出气口相连,旋风分离器的出气口通过管道与燃烧室的燃烧器相连,并在该段管路上设置有止回阀;辅助燃料通过燃料输入管路及阀门与燃烧器相连,助燃空气通过空气输入管路及阀门与燃烧器相连;燃烧室的烟气出口通过管路与炭化器物料进口一侧的外夹套上的进气口相连,该外夹套的出气口位于生物炭出料口一侧、并通过管路与烟气冷却器的进气口相连,烟气冷却器的出气口通过管路与碱液吸收塔的进气口相连,碱液吸收塔的出气口经管路并行连接回流风机的进气口和烟气外排设备的进气口,回流风机的出气口通过管路和阀门与燃烧室上的回流口连接;外排设备的出气口排空设置;喷淋液循环泵的出液口通过喷淋液输入管路与碱液吸收塔上的喷淋液入口相连,喷淋液循环泵的回液口通过喷淋液回流管路与碱液吸收塔上的喷淋回流口相连;The crusher is located above the first air lock, and the material outlet of the crusher is connected to the first air lock through a pipeline; the carbonizer is located below the first air lock, and the material inlet of the carbonizer is connected to the first air lock; The second air lock is located below the biochar discharge end of the carbonizer and is connected to the biochar discharge port of the carbonizer; the biochar cooler is located below the second air lock, and its material inlet is connected to the second air lock The third air lock is located below the biochar cooler and is connected to the biochar outlet of the biochar cooler; the air inlet of the cyclone separator is connected to the air outlet of the carbonizer through a pipeline, and the The air outlet is connected to the burner of the combustion chamber through a pipeline, and a check valve is set on this section of the pipeline; the auxiliary fuel is connected to the burner through the fuel input pipeline and the valve, and the combustion-supporting air is connected to the burner through the air input pipeline and the valve. Connected; the flue gas outlet of the combustion chamber is connected to the air inlet on the outer jacket on the material inlet side of the carbonizer through a pipeline, and the air outlet of the outer jacket is located on the side of the biochar outlet, and is connected to the carbonizer through a pipeline. The air inlet of the flue gas cooler is connected, the air outlet of the flue gas cooler is connected with the air inlet of the lye absorption tower through the pipeline, and the air outlet of the lye absorption tower is connected in parallel with the air inlet of the return fan and the smoke through the pipeline. The air inlet of the air exhaust equipment and the air outlet of the return fan are connected to the return port on the combustion chamber through pipes and valves; the air outlet of the external exhaust equipment is emptied; the liquid outlet of the spray liquid circulating pump is sprayed The liquid input pipeline is connected with the spray liquid inlet on the alkali liquid absorption tower, and the liquid return port of the spray liquid circulation pump is connected with the spray liquid return port on the alkali liquid absorption tower through the spray liquid return pipeline;
包括外部水冷系统,外部水冷系统的冷却水中的一个分支管路与烟气冷却器的冷却水进口相连,并经烟气冷却器的水路出口和一个回水支路与回水总管相连;冷却水的另一分支管路与生物炭冷却器的冷却水入口相连,并经生物炭冷却器的冷却水出口和另一回水支路与回水总管路相连;经烟气冷却器和生物炭冷却器加热后的冷却水汇总到回水主管路后流向用热部位,用热后的冷水循环作为冷却水给水。Including an external water cooling system, a branch pipe in the cooling water of the external water cooling system is connected to the cooling water inlet of the flue gas cooler, and is connected to the return water main pipe through the water outlet of the flue gas cooler and a return water branch; the cooling water The other branch pipeline of the biochar cooler is connected to the cooling water inlet of the biochar cooler, and is connected to the return water main pipeline through the cooling water outlet of the biochar cooler and another return water branch; it is cooled by the flue gas cooler and biochar. The cooling water heated by the heater is collected into the main return water pipeline and then flows to the hot part, and the heated cold water is circulated as the cooling water supply water.
而且的,所述破碎机为剪切式破碎机。Furthermore, the crusher is a shearing crusher.
而且的,在旋风分离器内设置有导流片。Moreover, a guide vane is provided in the cyclone.
而且的,在炭化器上进一步设置有用于检测外夹套内高温烟气温度的第一温度传感器、用于检测炭化室内前端温度的第二温度传感器和用于检测炭化室内后端温度的第三传感器;在旋风分离器的进气口与炭化器的出气口相连的管路上进一步设置有第四温度传感器;在燃烧室的烟气出口与炭化器物料进口一侧的外夹套上的进风口相连的管路上进一步设置有第五温度传感器;在生物炭冷却器的生物炭出料口与第三锁风器位相连的管路上进一步设置有第六温度传感器;在旋风分离器的出气口与燃烧室的燃烧器相连的管路上设置有第一流量计,在燃料输入管路和空气输入管路上分别设置有第二流量计和第三流量计。Moreover, the carbonizer is further provided with a first temperature sensor for detecting the temperature of the high-temperature flue gas in the outer jacket, a second temperature sensor for detecting the temperature of the front end of the carbonization chamber, and a third temperature sensor for detecting the temperature of the rear end of the carbonization chamber. Sensor; a fourth temperature sensor is further arranged on the pipeline connecting the air inlet of the cyclone separator with the air outlet of the carbonizer; the air inlet on the outer jacket on the side of the flue gas outlet of the combustion chamber and the material inlet of the carbonizer A fifth temperature sensor is further arranged on the connected pipeline; a sixth temperature sensor is further arranged on the pipeline connecting the biochar outlet of the biochar cooler with the third air lock; the air outlet of the cyclone separator is connected to the A first flow meter is arranged on the pipeline connecting the burners of the combustion chamber, and a second flow meter and a third flow meter are respectively arranged on the fuel input pipeline and the air input pipeline.
本发明具有的优点和积极效果:The advantages and positive effects that the present invention has:
1、本发明将生物质炭化、裂解气燃烧、烟气热量回收、烟气净化、生物炭冷却及余热产生热水等工艺进行有机的组合,实现了生物炭生产的同时,热水用于取暖,达到了生物质炭-热联产的目的。1. The present invention organically combines processes such as biomass carbonization, pyrolysis gas combustion, flue gas heat recovery, flue gas purification, biochar cooling, and waste heat production of hot water, so as to realize the production of biochar, and the hot water is used for heating. , to achieve the purpose of biomass charcoal-heat cogeneration.
2、本装置可以有效净化在炭化过程中产生的焦油成分,避免了由于焦油等处理不当对环境的污染和对管路、设备的堵塞、腐蚀等现象。2. The device can effectively purify the tar components produced in the carbonization process, and avoid the pollution of the environment and the blockage and corrosion of pipelines and equipment due to improper treatment of tar.
2、本发明实现了低炭排放,在煤燃烧取暖及生物质燃烧取暖中,产生热量的主要是C元素,即其中的C元素转化为CO2而成为炭排放的主要贡献之一。在本炭-热联产工艺中,燃烧物主要是生物质中的易挥发的有机成分,大部分的C元素固定在生物炭中,从而最大程度减小了生物质利用中的炭排放。2. The present invention realizes low carbon emission. In coal combustion heating and biomass combustion heating, the main source of heat is C element, that is, the C element is converted into CO2 and becomes one of the main contributions of carbon emission. In this carbon-heat cogeneration process, the combustion products are mainly volatile organic components in biomass, and most of the C elements are fixed in the biochar, thereby minimizing the carbon emission in biomass utilization.
3、本发明装置为集成装置,相比于其他秸秆集中处理模式,设备紧凑,操作简单,而且其经济可行性基本不受处理规模的制约,特别适合以村落为单位用于取暖及生产生物质炭。3. The device of the present invention is an integrated device. Compared with other centralized processing modes of straw, the device is compact and simple to operate, and its economic feasibility is basically not restricted by the processing scale, and is especially suitable for heating and biomass production in villages. carbon.
4、本发明利用生物质制备过程中的裂解气作为燃料,对其进行燃烧,并以燃烧后的烟气作为生物质炭的制备热源,正常情况下,除非必要的小功率动力消耗外,炭化过程及供暖过程不需要其他能量消耗,是能源的利用过程。4. The present invention uses the pyrolysis gas in the biomass preparation process as fuel, burns it, and uses the combustion flue gas as the heat source for the preparation of biomass charcoal. The process and heating process do not require other energy consumption and are the energy utilization process.
5、为了控制炭化温度在要求的范围内,通过调整烟气回流量及补充燃料量等参数,而调整烟气的温度,进而调整生物质炭的裂解温度。5. In order to control the carbonization temperature within the required range, adjust the temperature of the flue gas by adjusting the parameters such as the return flow of the flue gas and the amount of supplementary fuel, and then adjust the pyrolysis temperature of the biomass char.
6、本工艺做到了烟气余热回收热生物炭的热量回收,可以为生产场地提高热水供暖。6. This process achieves heat recovery of waste heat from flue gas and biochar, which can improve hot water heating for production sites.
7、本发明工艺采用碱性溶液吸收烟气中少量的酸性气体,并利用活性炭对烟气进一步净化,从而做到了环境友好。7. The process of the present invention adopts an alkaline solution to absorb a small amount of acid gas in the flue gas, and uses activated carbon to further purify the flue gas, thereby achieving environmental friendliness.
8、本装置中旋风分离器的进口通过管道炭化室的出气口连接,旋风分离器的出气口通过管道与燃烧室的燃烧器相连接,管路和设备均设置有保温层。目的是保证在炭化温度下(450-550℃),裂解成分中的焦油及醋液等在进入燃烧室前不会冷凝成液体(焦油等成分的冷凝温度为200℃-300℃)而堵塞管路和设备。旋风分离器可以有效截留在气相输送中携带的生物炭颗粒,对进入炭化室的可燃成分进行净化,减少燃烧后烟气中的灰尘量。8. In this device, the inlet of the cyclone separator is connected through the gas outlet of the carbonization chamber of the pipeline, and the gas outlet of the cyclone separator is connected with the burner of the combustion chamber through the pipeline, and the pipeline and equipment are provided with an insulating layer. The purpose is to ensure that under the carbonization temperature (450-550℃), the tar and vinegar in the cracked components will not condense into liquid before entering the combustion chamber (the condensation temperature of tar and other components is 200℃-300℃) and block the pipe road and equipment. The cyclone separator can effectively intercept the biochar particles carried in the gas phase transportation, purify the combustible components entering the carbonization chamber, and reduce the amount of dust in the flue gas after combustion.
9、本装置中的旋风分离器的进气口通过管道与炭化器的出气口相连,旋风分离器的出气口通过管道与燃烧室的燃烧器相连,燃烧室的热风出口通过管路与炭化器物料进口一侧的外夹套上的进风口相连,采用上述连接结构,在生物质炭化过程产生的裂解气燃烧后生产高温烟气,高温烟气通过炭化器的外夹腔,提供炭化所需的热量,从而实现了自产燃气燃烧利用,另外,在裂解气燃烧的过程中,焦油被焚烧转化成二氧化炭和水,从而避免了焦油产物外排,解决了炭化中木焦油的净化问题和对管路的堵塞问题。9. The air inlet of the cyclone separator in this device is connected to the air outlet of the carbonizer through a pipeline, the air outlet of the cyclone separator is connected to the burner of the combustion chamber through a pipeline, and the hot air outlet of the combustion chamber is connected to the carbonizer through a pipeline. The air inlets on the outer jacket on the inlet side of the material are connected, and the above-mentioned connection structure is used to produce high-temperature flue gas after the pyrolysis gas generated in the biomass carbonization process is burned. In addition, in the process of pyrolysis gas combustion, tar is incinerated and converted into carbon dioxide and water, thus avoiding the efflux of tar products and solving the problem of purification of wood tar in carbonization. and blockage of pipes.
10、本装置中在炭化器的物料进口和生物炭出料口均连接锁风器,使炭化过程中处于低氧工况下,可以做到与空气最大程度的隔离,从而避免了的生物炭的燃烧,提高了生物炭的产量和生物质炭的炭化品质。10. In this device, the material inlet of the carbonizer and the discharge port of the biochar are connected with an air lock, so that the carbonization process is in a low oxygen condition, which can be isolated from the air to the greatest extent, thereby avoiding the occurrence of biochar The combustion of biomass charcoal improves the yield of biochar and the carbonization quality of biomass charcoal.
11、本装置中与生物炭冷却器和烟气冷却器连接的外部水冷系统,冷却加热后的水流向用热部位,实现了烟气余热回收和热生物炭的热量回收利用。11. The external water cooling system connected with the biochar cooler and the flue gas cooler in this device, the water after cooling and heating flows to the heat-using part, realizing the recovery of the waste heat of the flue gas and the heat recovery and utilization of the hot biochar.
附图说明Description of drawings
图1是本发明的工艺路线图;Fig. 1 is the process route diagram of the present invention;
图2是本发明炭化处理初次启动的控制流程图;Fig. 2 is the control flow chart of initial start-up of carbonization treatment of the present invention;
图3是本发明当炭化室温度超过设定温度时的自动调节控制流程图;Fig. 3 is the automatic adjustment control flow chart of the present invention when the carbonization chamber temperature exceeds the set temperature;
图4是本发明当炭化温度低于设定温度时自动调节流程图;Fig. 4 is the automatic adjustment flow chart of the present invention when the carbonization temperature is lower than the set temperature;
图5是本发明设备的结构示意;Fig. 5 is the structural representation of the device of the present invention;
图6是本发明傅里叶变换红外光谱分析结果图。Fig. 6 is the analysis result of Fourier transform infrared spectrum of the present invention.
具体实施方式Detailed ways
下面结合附图并通过具体实施例对本发明作进一步详述,以下实施例只是描述性的,不是限定性的,不能以此限定本发明的保护范围。The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments. The following embodiments are only descriptive, not restrictive, and cannot limit the protection scope of the present invention.
一种连续实现热量自循环的生物质炭-热联产工艺,请参见图1,其发明点为,包括如下步骤:A biomass charcoal-heat cogeneration process that continuously realizes self-circulation of heat, please refer to Figure 1, and its invention is that it includes the following steps:
S1对生物质原料进行破碎处理,主要是针对产量大的秸秆类的生物质原料,对于稻壳,锯末等可以不经过破碎处理环节;S1 crushes biomass raw materials, mainly for biomass raw materials such as straws with large output. For rice husks, sawdust, etc., the crushing process is not required;
S2在低氧工况下,对破碎后的生物质原料进行炭化处理,维持炭化的温度通过在炭化室外的夹腔内流通的高温烟气来提供,炭化处理的中间产物包括生物质燃气、以气相存在于生物质燃气中的焦油和醋液,炭化后的最终产物为生物质炭;S2 is to carbonize the crushed biomass raw materials under low oxygen conditions, and the temperature to maintain carbonization is provided by the high-temperature flue gas circulating in the cavity outside the carbonization chamber. The intermediate products of carbonization treatment include biomass fuel gas, The gas phase exists in the tar and vinegar liquid in the biomass gas, and the final product after carbonization is biomass carbon;
首次启动的高温烟气通过在燃烧室内通入助燃空气燃烧辅助燃料来实现;The high-temperature flue gas at the first start is realized by introducing combustion-supporting air into the combustion chamber to burn auxiliary fuel;
炭化过程中产生的中间产物排出炭化室后,进行燃烧净化处理,燃烧后产生的热量作为炭化处理启动后供热使用,使用后的外排烟气先后经水冷却和净化处理,一部分排空处理,另一部回流用于控制燃烧温度;After the intermediate products produced in the carbonization process are discharged from the carbonization chamber, they are subjected to combustion and purification treatment. The heat generated after combustion is used for heating after the carbonization treatment is started. , and the other recirculation is used to control the combustion temperature;
其中,生物质炭外排后经水冷却处理,形成可用作吸附材料、土壤改良剂、肥料缓释载体和二氧化炭封存剂的生物质炭产品;Among them, the biomass charcoal is cooled by water after being discharged to form a biomass charcoal product that can be used as adsorption material, soil conditioner, fertilizer slow-release carrier and carbon dioxide sequestration agent;
其中,外排烟气水冷却和生物质炭水冷却回流的热水供给用热部位使用,用热后的冷水循环作为冷却水给水使用。Among them, the hot water supply for the cooling of the external flue gas water and the cooling and reflux of the biomass charcoal water is used for the hot part, and the hot cold water circulation is used as the cooling water supply water.
上述生物质炭-热联产工艺中,S2中首次启动高温烟气的方法,请参见图2,具体为:In the above-mentioned biomass charcoal-heat cogeneration process, the method of starting high-temperature flue gas in S2 for the first time is shown in Fig. 2, specifically:
1)先开启燃烧室内的燃烧器点火开关;1) First turn on the ignition switch of the burner in the combustion chamber;
2)然后按照设定的空气量开启助燃空气控制阀;2) Then open the combustion air control valve according to the set air volume;
3)然后全开启辅助燃料控制阀;3) Then fully open the auxiliary fuel control valve;
4)检测燃烧室烟气出口温度,至温度达到设定值;4) Detect the flue gas outlet temperature of the combustion chamber until the temperature reaches the set value;
5)启动生物质炭化处理:生物质在设定进料量下进入炭化室,在设定炭化时间进行炭化,炭化产生的裂解气进入燃烧室与辅助燃料一起燃烧,实现首次启动。5) Start biomass carbonization treatment: The biomass enters the carbonization chamber under the set feed amount, and is carbonized at the set carbonization time. The cracked gas generated by the carbonization enters the combustion chamber and burns with the auxiliary fuel to realize the first start.
上述生物质炭-热联产工艺中,S2中在炭化处理启动后连续供热过程中对炭化室温度进行控制的方法为:In the above-mentioned biomass charcoal-heat cogeneration process, the method for controlling the temperature of the carbonization chamber in the continuous heating process after the carbonization treatment is started in S2 is:
1)检测炭化室实际温度,与控制系统中设定的温度范围值进行比较;1) Detect the actual temperature of the carbonization chamber and compare it with the temperature range value set in the control system;
2)根据比较结构,进行温度调控,具体为:2) According to the comparative structure, temperature regulation is carried out, specifically:
a、在实际温度超过设定温度范围的情况下,判断辅助燃料控制阀是否关闭;在未关闭的工况下,逐渐关小辅助燃料控制阀,在该操作过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则进入正常运行,如果不是,则继续关小辅助燃料控制阀,直至炭化室温度及燃烧室的烟气出口温度调节至设定范围内;在辅助燃料控制阀已关闭的工况下,检测外排烟气的回流是否达到最大,如果未达到最大值,则逐渐开启回流风机和回流控制阀,在该操作的过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则停止操作,进入正常运行,如果不是,则继续开大回流风机和烟气回流阀,直至炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内;而在外排烟气的回流已达到最大值的工况下,逐渐减少进入炭化室的生物质进料量并缩短炭化时间,在该操作过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则进入正常运行状态,如果不是,继续逐渐减少进入炭化室的生物质进料量并缩短炭化时间,直至炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内;该温度调控过程参见图3。a. When the actual temperature exceeds the set temperature range, determine whether the auxiliary fuel control valve is closed; under the condition that it is not closed, gradually close the auxiliary fuel control valve. During this operation, detect the temperature of the carbonization chamber and the combustion Check whether the flue gas outlet temperature of the chamber is adjusted to within the set range, if so, enter normal operation, if not, continue to close the auxiliary fuel control valve until the temperature of the carbonization chamber and the flue gas outlet temperature of the combustion chamber are adjusted to the set value When the auxiliary fuel control valve is closed, check whether the backflow of the external exhaust gas reaches the maximum value. If it does not reach the maximum value, gradually open the backflow fan and the backflow control valve. Whether the temperature of the carbonization chamber and the flue gas outlet temperature of the combustion chamber are adjusted within the set range, if so, stop the operation and enter normal operation; if not, continue to open the return fan and flue gas return valve until the temperature of the carbonization chamber reaches Whether the flue gas outlet temperature of the combustion chamber is adjusted to the set range; and under the condition that the backflow of the external exhaust flue gas has reached the maximum value, gradually reduce the amount of biomass feed into the carbonization chamber and shorten the carbonization time. During the process, check whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted within the set range. If so, enter the normal operation state. If not, continue to gradually reduce the biomass feed into the carbonization chamber and shorten the carbonization. time until the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted within the set range; the temperature control process is shown in Figure 3.
b、在实际温度低于设定温度范围的情况下,判断辅助燃料控制阀是否开至最大;在未开至最大的工况下,逐渐开大辅助燃料控制阀,在该操作过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则进入正常运行,如果不是,则继续开大辅助燃料控制阀,直至炭化室温度及燃烧室的烟气出口温度调节至设定范围内;在辅助燃料控制阀已开至最大的工况下,检测外排烟气的回流是否完全关闭,如果未完全关闭,则逐渐关闭回流风机和回流控制阀,在该操作的过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则停止操作,进入正常运行,如果不是,则继续关闭烟气回流风机和烟气回流阀,直至炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内;而在外排烟气的回流已完全关闭的工况下,逐渐增加进入炭化室的生物质进料量并延长炭化时间,在该操作过程中,检测炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内,如果是,则进入正常运行状态,如果不是,继续逐渐增加进入炭化室的生物质进料量并延长炭化时间,直至炭化室温度及燃烧室的烟气出口温度是否调节至设定范围内。该温度调控过程参见图4。b. When the actual temperature is lower than the set temperature range, judge whether the auxiliary fuel control valve is opened to the maximum; under the condition that the auxiliary fuel control valve is not opened to the maximum, gradually open the auxiliary fuel control valve. Whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to the set range, if so, enter normal operation; if not, continue to open the auxiliary fuel control valve until the temperature of the carbonization chamber and the flue gas outlet of the combustion chamber Adjust the temperature to within the set range; under the condition that the auxiliary fuel control valve has been opened to the maximum, check whether the return of the external exhaust gas is completely closed, if not, gradually close the return fan and return control valve. During the operation, check whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to the set range. If so, stop the operation and enter normal operation. If not, continue to turn off the flue gas return fan and flue gas return. until the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to within the set range; and under the condition that the backflow of the external exhaust gas has been completely closed, the biomass feed amount into the carbonization chamber is gradually increased and prolonged. Carbonization time. During this operation, check whether the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted to within the set range. If so, enter the normal operation state. If not, continue to gradually increase the biomass entering the carbonization chamber. Increase the amount of feed and prolong the carbonization time until the temperature of the carbonization chamber and the temperature of the flue gas outlet of the combustion chamber are adjusted within the set range. The temperature regulation process is shown in Figure 4.
本生物质炭-热联产工艺的特点是:经破碎后的生物质原料在设定的炭化温度下进行裂解,裂解的可燃气及裂解过程中产生的木焦油等作为燃料燃烧,产生的热量部分用于供给炭化装置的热量,完成热量的自循环,其余热量加热热水用于供暖等用热部分使用。The characteristics of this biomass charcoal-heat cogeneration process are: the crushed biomass raw materials are cracked at the set carbonization temperature, and the cracked combustible gas and wood tar produced in the cracking process are burned as fuel, and the heat generated Part of the heat is used to supply the carbonization device to complete the self-circulation of heat, and the rest of the heat is used to heat the hot water for heating and other heat-consuming parts.
以1kg生物质的应用基为基准,对上述过程进行热量和质量平衡计算,生物质的低位热值约为17MJ/kg生物质,生物质炭收率约为33%,用于热裂解的热量为4.3MJ/kg生物质,理论余热量为4.86MJ/kg生物质,占生物质能的27.3%。Based on the application base of 1kg biomass, the heat and mass balance of the above process are calculated. The low calorific value of biomass is about 17MJ/kg biomass, and the biomass char yield is about 33%. The heat used for thermal cracking It is 4.3MJ/kg biomass, and the theoretical waste heat is 4.86MJ/kg biomass, accounting for 27.3% of biomass energy.
考虑10%的热损失后,上述理论计算结果与中试装置的实际情况相吻合。After considering the heat loss of 10%, the above theoretical calculation results are in good agreement with the actual situation of the pilot plant.
采用该技术工艺的已有工程中,秸秆的处理量为6吨/d,每天生产生物质炭2吨,为3600平方米的面积供暖(供暖标准为每平米80w)。In the existing projects using this technology, the processing capacity of straw is 6 tons/d, the production of biomass charcoal is 2 tons per day, and the area of 3600 square meters is heated (the heating standard is 80w per square meter).
该过程中的污染控制措施及原理Pollution control measures and principles in the process
(1)木焦油等液体成分的产生及净化措施(1) Production and purification measures of liquid components such as wood tar
炭-热联产的炭化温度为450-550℃之间,在此温度下生物质慢速热解,裂解气气体产物为生物质燃气,主要成分为H2、CO、CH4、C2H4等;液体产物常温下为焦油和醋液。其中焦油和木醋液等成分的冷凝点为200度左右,在炭化温度下,以气相的存在于可燃气中,并随同可燃气直接送至燃烧室进行燃烧,生产二氧化炭和水,因此,炭-热联产方式不会有焦油遗留在燃烧后的烟气中。The carbonization temperature of carbon-heat co-production is between 450-550℃. At this temperature, biomass is pyrolyzed slowly, and the pyrolysis gas product is biomass gas, the main components are H2, CO, CH4, C2H4, etc.; liquid product It is tar and vinegar liquid at room temperature. Among them, the condensation point of tar and wood vinegar is about 200 degrees. At the carbonization temperature, they exist in the gas phase in the combustible gas, and are directly sent to the combustion chamber together with the combustible gas for combustion to produce carbon dioxide and water. Therefore, , the carbon-heat cogeneration method will not leave tar in the flue gas after combustion.
(2)SO2的产生及净化(2) Production and purification of SO2
生物质中的S含量较低,同时炭-热联产的炭化过程是在缺氧情况下发生的(目的是防止C的燃烧),以此,生物质中的S仅仅会产生很少量的SO2,可以通过外排烟气净化处理过程中采用简单的碱性中和而消除,不会造成对环境的影响The content of S in the biomass is low, and the carbonization process of carbon-heat cogeneration occurs in the absence of oxygen (the purpose is to prevent the burning of C), so that only a small amount of S in the biomass will be produced. SO2 can be eliminated by simple alkaline neutralization during the purification process of the external exhaust flue gas, without causing any impact on the environment
(3)氮氧化物的产生及净化(3) Generation and purification of nitrogen oxides
在可燃气燃烧的过程中,空气中的N2和生物质中的N元素会生成以NO为主要成分的氮氧化物,但由于燃烧温度不高,控制好空气的进给量结合采用烟气二次燃烧的方式,同时配合简单的净化手段(脱硫)可以得到有效的控制。In the process of combustible combustion, the N2 in the air and the N element in the biomass will generate nitrogen oxides with NO as the main component, but because the combustion temperature is not high, control the air feed and use flue gas two The method of secondary combustion, and at the same time with simple purification means (desulfurization) can be effectively controlled.
(4)粉尘的产生及净化(4) Generation and purification of dust
由于燃烧介质为可燃性气体,因此,不同于秸秆直接燃烧,该过程中产生的粉尘污染微不足道的,即便有少量炭粒携带燃烧后形成飞灰,也会在随后外排烟气净化处理过程中的碱液喷淋脱硫的过程得到净化脱除。Since the combustion medium is flammable gas, the dust pollution generated in this process is negligible, unlike the direct combustion of straw. The lye spray desulfurization process is purified and removed.
为实现本连续实现热量自循环的生物质炭-热联产工艺,进一步发明了如下装置:In order to realize the biomass charcoal-heat cogeneration process that continuously realizes self-circulation of heat, the following devices were further invented:
一种连续实现热量自循环的生物质炭-热联产装置,请参见图5,其发明点为:A biomass charcoal-heat cogeneration device that continuously realizes self-circulation of heat, please refer to Figure 5, and its invention points are:
包括破碎机32、第一锁风器31、炭化器30、旋风分离器13、燃烧室3、第二锁风器14、生物炭冷却器15、第三锁风器17、喷淋液循环泵23、碱液吸收塔24、活性炭吸附层25、回流风机26、烟气外排设备27(可采用烟囱)、烟气冷却器21。Including
所述炭化器和生物炭冷却器均为外带夹套的螺旋输送机构,内部为炭化室,炭化器和生物炭冷却器的驱动机构均由变频电机和减速机连接构成,其中炭化器的外夹套内形成高温烟气通过腔,生物炭冷却器的外夹套内形成冷却水通过腔。所述活性炭吸附层设置于碱液吸收塔内的上层。The carbonizer and the bio-char cooler are both screw conveying mechanisms with outer jackets, and the inside is a carbonization chamber. A high temperature flue gas passing cavity is formed in the jacket, and a cooling water passing cavity is formed in the outer jacket of the biochar cooler. The activated carbon adsorption layer is arranged on the upper layer in the alkali liquor absorption tower.
破碎机位于第一锁风器上方,破碎机的出料口通过管路与第一锁风器相连。炭化器位于第一锁风器下方,炭化器的物料进口与第一锁风器相连。第二锁风器位于炭化器的生物炭出料端下方、并与炭化器的生物炭出料口相连。生物炭冷却器位于第二锁风器的下方,其物料进口与第二锁风器相连。第三锁风器位于生物炭冷却器的下方,并与生物炭冷却器的生物炭出料口相连。旋风分离器的进气口通过管道与炭化器的出气口相连,旋风分离器的出气口通过管道与燃烧室的燃烧器4相连,并在该段管路上设置有止回阀10。辅助燃料通过燃料输入管路及阀门7与燃烧器相连,助燃空气通过空气输入管路及阀门6与燃烧器相连。燃烧室的烟气出口通过管路与炭化器物料进口一侧的外夹套上的进气口相连,该外夹套的出气口位于生物炭出料口一侧、并通过管路与烟气冷却器的进气口相连,烟气冷却器的出气口通过管路与碱液吸收塔的进气口相连,碱液吸收塔的出气口经管路并行连接回流风机的进气口和烟气外排设备的进气口,回流风机的出气口通过管路和阀门28与燃烧室上的回流口连接。外排设备的出气口排空设置。喷淋液循环泵的出液口通过喷淋液输入管路与碱液吸收塔上的喷淋液入口相连,喷淋液循环泵的回液口通过喷淋液回流管路与碱液吸收塔上的喷淋回流口相连。The crusher is located above the first air lock, and the outlet of the crusher is connected to the first air lock through a pipeline. The carbonizer is located below the first air lock, and the material inlet of the carbonizer is connected to the first air lock. The second air lock is located below the biochar discharge end of the carbonizer, and is connected to the biochar discharge port of the carbonizer. The biochar cooler is located below the second air lock, and its material inlet is connected to the second air lock. The third air lock is located below the biochar cooler and is connected with the biochar outlet of the biochar cooler. The air inlet of the cyclone separator is connected to the air outlet of the carbonizer through a pipeline, and the air outlet of the cyclone separator is connected to the burner 4 of the combustion chamber through a pipeline, and a
包括外部水冷系统,外部水冷系统的冷却水中的一个分支管路22与烟气冷却器的冷却水进口相连,并经烟气冷却器的水路出口和一个回水支路19与回水总管相连。冷却水的另一分支管路20与生物炭冷却器的冷却水入口相连,并经生物炭冷却器的冷却水出口和另一回水支路18与回水总管路相连。经烟气冷却器和生物炭冷却器加热后的冷却水汇总到回水主管路后流向用热部位,用热后的冷水循环作为冷却水给水。It includes an external water cooling system. A branch pipe 22 in the cooling water of the external water cooling system is connected to the cooling water inlet of the flue gas cooler, and is connected to the return water main pipe through the water outlet of the flue gas cooler and a return water branch 19 . Another branch pipe 20 of cooling water is connected to the cooling water inlet of the biochar cooler, and is connected to the return water main pipe via the cooling water outlet of the biochar cooler and another return water branch 18 . The cooling water heated by the flue gas cooler and the biochar cooler is collected into the main return water pipeline and then flows to the heat-using part, and the heated cold water is circulated as the cooling water supply water.
上述结构中,所述破碎机优选采用剪切式破碎机。In the above structure, the crusher preferably adopts a shearing type crusher.
上述结构中,在旋风分离器内设置有导流片。In the above structure, the guide vanes are provided in the cyclone.
上述结构中,在炭化器上进一步设置有用于检测外夹套内高温烟气温度的第一温度传感器1、用于检测炭化室内前端温度的第二温度传感器33和用于检测炭化室内后端温度的第三传感器9,可以根据温度的反馈自动调整燃烧室的可燃气体进气阀门的开度,从而调整烟气的温度。在旋风分离器的进气口与炭化器的出气口相连的管路上进一步设置有第四温度传感器12。在燃烧室的热风出口与炭化器物料进口一侧的外夹套上的进风口相连的管路上进一步设置有第五温度传感器2。在生物炭冷却器的生物炭出料口与第三锁风器位相连的管路上进一步设置有第六温度传感器16。在旋风分离器的出气口与燃烧室的燃烧器相连的管路上设置有第一流量计11,在燃料输入管路和空气输入管路上分别设置有第二流量计8和第三流量计5。In the above structure, the carbonizer is further provided with a first temperature sensor 1 for detecting the temperature of the high-temperature flue gas in the outer jacket, a
本无焦油产生的生物炭-热联产装置的工作原理为:The working principle of this tar-free biochar-heat cogeneration device is:
秸秆类生物质原料经破碎机破碎预处理后(稻壳,锯末等可以不经过破碎环节)后,经第一锁风器进入螺旋炭化器,并在炭化器驱动设备作用下,边输送边搅拌,同时在其夹套高温烟气提供的热量下依次完成干燥、裂解和炭化过程。通过控制燃烧装置的燃气供给量来调整炭化器的温度,使其在450-550℃之间,由于炭化器相对密闭,因此炭化过程中处于缺氧状态,裂解气中主要是一氧化炭、氢气和甲烷气体及焦油成分,在裂解温度下,裂解气以气体状态经过旋风分离器,将其中携带的生物质炭粒分离下来,高温气体进入燃烧器,并与空气混合,利用燃烧器的点火器将其点燃,燃烧后的烟气进入炭化器夹套,提供炭化所需的热量,之后,烟气经烟气冷却器进行降温后,进入碱液吸收塔进行酸性气体的净化吸收,并进一步降温。然后进入活性炭吸附层,进一步吸附净化,之后一部分由排空烟气外排设备排空,另一部分经回流风机回流至燃烧室,实现烟气温度调控。After being crushed and pretreated by the crusher (rice husks, sawdust, etc. can not go through the crushing link), the straw biomass raw materials enter the spiral carbonizer through the first air lock, and are stirred while conveying under the action of the carbonizer drive equipment. At the same time, the drying, cracking and carbonization processes are completed sequentially under the heat provided by the high temperature flue gas of its jacket. By controlling the gas supply of the combustion device, the temperature of the carbonizer is adjusted to be between 450-550°C. Since the carbonizer is relatively closed, it is in an oxygen-deficient state during the carbonization process. The pyrolysis gas is mainly carbon monoxide and hydrogen. and methane gas and tar components, at the pyrolysis temperature, the pyrolysis gas passes through the cyclone in a gaseous state to separate the biomass carbon particles carried in it, and the high-temperature gas enters the burner and is mixed with air. The igniter of the burner is used. It is ignited, and the burned flue gas enters the carbonizer jacket to provide the heat required for carbonization. After that, the flue gas is cooled by the flue gas cooler, and then enters the lye absorption tower to purify and absorb the acid gas, and further cool down. . Then it enters the activated carbon adsorption layer for further adsorption and purification. After that, part of it is evacuated by the exhaust gas exhaust equipment, and the other part is returned to the combustion chamber through the return fan to realize the temperature control of the flue gas.
生物质炭化后形成的生物质炭经第二锁风器进入生物炭冷却器,该冷却器在夹套冷却水的作用下,边输送边降低生物质炭的温度,避免遇到空气后复燃。之后,经第三锁风器进行卸料包装。The biomass carbon formed after biomass carbonization enters the biochar cooler through the second air lock. Under the action of the jacket cooling water, the cooler lowers the temperature of the biomass carbon while conveying, so as to avoid re-ignition after encountering air. . After that, the third air lock is used for unloading and packaging.
烟气冷却器的冷却水和生物质炭冷却装置的冷却水为循环用水,经热交换后,热水用于给用户取暖。The cooling water of the flue gas cooler and the cooling water of the biomass charcoal cooling device are circulating water. After heat exchange, the hot water is used for heating the user.
本技术首次启动及非正常的情况下,需要采用液化气(或柴油)进行助燃,其基本过程是以液化气为燃料,利用燃烧室上的燃烧器进行燃烧,形成烟气,通入炭化器夹套,使炭化器内输送的生物质进行裂解和炭化,待炭化中产生的裂解气体可以满足燃烧需要时,再逐渐关闭液化石油气,进入能量自循环状态。When this technology is started for the first time or abnormally, it is necessary to use liquefied gas (or diesel) for combustion. The jacket is used to crack and carbonize the biomass transported in the carbonizer. When the cracked gas generated in the carbonization can meet the needs of combustion, the liquefied petroleum gas is gradually closed to enter the energy self-circulation state.
本装置中的炭化器和生物炭冷却器均为外带夹套的螺旋输送机构,其驱动机构由变频电机和减速机组成,可以通过改变电机的转速从而调整炭化器和生物炭冷却器中的物料输送速度,进而方便的改变生物质原料的炭化时间和生物质炭的冷却时间,使其达到最佳的工艺参数。The carbonizer and biochar cooler in this device are both screw conveying mechanisms with outer jackets, and the driving mechanism is composed of a frequency conversion motor and a reducer. The speed of the motor can be changed to adjust the carbonizer and biochar cooler. The material conveying speed can easily change the carbonization time of biomass raw materials and the cooling time of biomass charcoal to achieve the best process parameters.
本装置中的第一锁风器的作用:在生物质物料进入炭化器时完成炭化器与环境的相对隔离,第二锁风器的作用是:生物炭出料时完成是完成炭化器与环境的相对隔离,以便使炭化过程中处于低氧工况而提高生物质炭的炭化品质。第三锁风器的作用是:完成生物炭冷却器与空气的相对隔离,以避免生物质炭在温度较高时遇到空气发生复燃。三个锁风器的转动由电机驱动,改变电机的转速可以改变进出料的速度,使其与处理过程相匹配。The function of the first air lock in this device is to complete the relative isolation between the carbonizer and the environment when the biomass material enters the carbonizer, and the function of the second air lock is to complete the carbonizer and the environment when the biochar is discharged. The relative isolation of biomass charcoal can improve the carbonization quality of biomass charcoal by making it in low oxygen condition during the carbonization process. The function of the third air lock is to complete the relative isolation of the biochar cooler from the air, so as to avoid the reburning of the biochar when the temperature is high. The rotation of the three air locks is driven by the motor, and changing the speed of the motor can change the speed of the material in and out to match the processing process.
为了防止助燃液化气和生物质裂解气在输送过程中返回炭化器而发生回火,在裂解气输送管路上设置有单向阀,为了检测各个工序中的温度,在烟气管路,裂解气管路和生物炭冷却器相应部位设置有上述温度传感器。In order to prevent the combustion-supporting liquefied gas and biomass pyrolysis gas from returning to the carbonizer during the transportation process, a check valve is set on the pyrolysis gas transportation pipeline. Corresponding parts of the road and the biochar cooler are provided with the above temperature sensors.
综上,本装置的主要技术特点如下:To sum up, the main technical features of this device are as follows:
1、破碎装置采用剪切式破碎工艺,可以针对不同形态的生物质原料进行预处理。1. The crushing device adopts shear crushing process, which can pretreat different forms of biomass raw materials.
2、炭化器为连续式螺旋推进装置,可以通过改变转速,方便的延长或缩短炭化时间,从而适应不同的生物质物料进行炭化,制备生物质炭。2. The carbonizer is a continuous screw propulsion device, which can easily extend or shorten the carbonization time by changing the rotational speed, so as to adapt to different biomass materials for carbonization to prepare biomass carbon.
3、螺旋炭化器为筒体外加夹套结构,夹套内通入高温烟气,筒体内生物质物料边推进边加热,螺旋既有推送物料的作用,同时也起到对物料的搅拌混合作用,从而有利于热量传递。3. The spiral carbonizer has a jacket structure outside the barrel. High temperature flue gas is introduced into the jacket. The biomass material in the barrel is heated while advancing. The screw not only pushes the material, but also plays the role of stirring and mixing the material. , which facilitates heat transfer.
4、炭化器前后有锁风器,用于生物质的加载和活性炭的卸载,有效的实现了炭化装置内与环境的相对隔离和低氧环境。4. There are air locks before and after the carbonizer, which are used for biomass loading and activated carbon unloading, which effectively realizes the relative isolation and low oxygen environment in the carbonization device from the environment.
5、生物炭冷却器也采用夹套螺旋输送机构,在输送的同时实现了活性炭的冷却降温。5. The biochar cooler also adopts a jacketed screw conveying mechanism, which realizes the cooling and cooling of the activated carbon while conveying.
6、旋风分离装置中设置有导流片,从而提高了分离效率。6. The cyclone separation device is provided with a guide vane, thereby improving the separation efficiency.
7、炭化器上设置有温度传感器,可以根据温度的反馈自动调整燃烧室的可燃气体进气阀门的开度,从而调整烟气的温度。7. There is a temperature sensor on the carbonizer, which can automatically adjust the opening of the combustible gas intake valve of the combustion chamber according to the temperature feedback, thereby adjusting the temperature of the flue gas.
8、燃烧室上配备有初次启动的辅助燃料入口,以便在停车后重新启动时,给炭化装置提供高温烟气。8. The combustion chamber is equipped with an auxiliary fuel inlet for initial start-up, so as to provide high-temperature flue gas to the carbonization device when restarting after stopping.
以下面实施例说明本无焦油产生的生物炭-热联产装置的实施效果:The implementation effect of the tar-free biochar-heat cogeneration device will be described with the following examples:
采用本装置,以稻壳和椰壳为作为生物质原料制备生物质炭,正常运行后,炭化室出口温度,控制在520℃,炭化装置转速为10rpm,控制原料在炭化室的炭化时间为1小时,得到的生物炭的物化性质如下:Using this device, rice husks and coconut husks are used as biomass raw materials to prepare biomass charcoal. After normal operation, the outlet temperature of the carbonization chamber is controlled at 520 ° C, the rotation speed of the carbonization device is 10 rpm, and the carbonization time of the raw materials in the carbonization chamber is controlled to be 1 The physicochemical properties of the obtained biochar are as follows:
(1)元素分析数据(1) Elemental analysis data
(2)比表面积孔径分布数据(2) Specific surface area pore size distribution data
(3)傅里叶变换红外光谱分析结果,见附图3(3) Fourier transform infrared spectroscopy analysis results, see Figure 3
本发明连续实现热量自循环的生物质炭-热联产装置的其中一关键点为:自动实现连续操作方式下的热量平衡及热量自循环,理由如下:One of the key points of the biomass charcoal-heat cogeneration device that continuously realizes the self-circulation of heat in the present invention is that the heat balance and the self-circulation of heat under the continuous operation mode are automatically realized, and the reasons are as follows:
炭—热联产技术是在获得生物炭的同时生产热量。该技术中生物质炭化所产生的气、液成分不再进行分离,而是直接作为燃料燃烧并为生物炭化过程提供热量。由于裂解气燃烧后产生的热量多于生物质炭化中所需的热量,进行热量自循环后,可以产生余热。因此该类技术成为炭热联产技术。The charcoal-heat cogeneration technology produces heat while obtaining biochar. In this technology, the gas and liquid components produced by biomass carbonization are no longer separated, but are directly burned as fuel and provide heat for the biocarbonization process. Since the heat generated by the combustion of the pyrolysis gas is more than the heat required in the biomass carbonization, after the self-circulation of heat, waste heat can be generated. Therefore, this type of technology becomes a carbon-heat cogeneration technology.
炭—热联产技术核心问题是即炭化中产生的部分热量用于进行炭化,要实现这个目标,必须连续地完成产炭、产气、燃烧三个基本环节,一个环节中止就不能实现热量循环。因此该炭化装置必须是连续式操作的装置。外带夹套的螺旋输送机构可以在夹套传热的同时,实现生物质的连续进、出料,实现生物质炭化、裂解,产生裂解气,并在连续状态下,将裂解气在燃烧室内燃烧,燃烧后的高温烟气供给炭化装置的夹套对生物质进行加热。在该连续过程中,炭化温度是一个关键指标,为了保证生物质炭的炭化效率,该温度不能低于400℃,炭化温度低,产气量减少,裂解气提供给炭化装置的热量减少,炭化温度会越来越低,最终难以完成炭化过程。如果炭化温度超过了设定的温度,但随着炭化温度的提高,产气量会上升,产炭量会下降。产气量上升,裂解气燃烧后,形成热量会增多,利用该热量为炭化装置加温后,炭化温度又将升高,过高的炭化温度不仅会减低生物炭的收率,温度不断升高还会最终失去平衡,甚至超出了燃烧室的控制温度;因此,炭化温度需要控制在合理的范围之内。The core problem of carbon-heat cogeneration technology is that part of the heat generated in carbonization is used for carbonization. To achieve this goal, the three basic links of carbon production, gas production and combustion must be continuously completed. If one link is suspended, the heat cycle cannot be realized. . Therefore, the carbonization unit must be a continuously operated unit. The screw conveying mechanism with an outer jacket can realize the continuous feeding and discharging of biomass while transferring heat from the jacket, realize the carbonization and cracking of biomass, generate cracked gas, and in a continuous state, put the cracked gas in the combustion chamber. Combustion, the high-temperature flue gas after combustion is supplied to the jacket of the carbonization device to heat the biomass. In this continuous process, the carbonization temperature is a key indicator. In order to ensure the carbonization efficiency of biomass carbon, the temperature cannot be lower than 400 °C, the carbonization temperature is low, the gas production is reduced, the heat provided by the cracked gas to the carbonization device is reduced, and the carbonization temperature will become lower and lower, and eventually it will be difficult to complete the carbonization process. If the carbonization temperature exceeds the set temperature, but with the increase of the carbonization temperature, the gas production will increase and the carbon production will decrease. The amount of gas produced increases, and after the pyrolysis gas is burned, the amount of heat formed will increase. After using this heat to heat the carbonization device, the carbonization temperature will increase again. Too high carbonization temperature will not only reduce the yield of biochar, but also increase the temperature. It will eventually lose balance and even exceed the control temperature of the combustion chamber; therefore, the carbonization temperature needs to be controlled within a reasonable range.
已有的相关专利在如何控制温度,从而连续的实现热量循环和热量平衡这个关键问题上,没有披露相关技术措施。The existing relevant patents do not disclose relevant technical measures on the key issue of how to control the temperature so as to continuously realize the heat cycle and heat balance.
本发明专利所采用的基本技术手段是通过调节烟气的温度,来控制炭化温度,使其处于正常的范围之内。降低烟气温度的主要方法是将低温烟气回流到燃烧室,降低燃烧强度及烟气的温度;提高烟气温度的主要措施是补充辅助燃料加强燃烧。该过程全部通过自动控制和自动调节来实现,保证烟气温度处于正常的范围内(800℃-1000℃之间)The basic technical means adopted by the patent of the present invention is to control the carbonization temperature by adjusting the temperature of the flue gas, so that it is within the normal range. The main method to reduce the flue gas temperature is to return the low-temperature flue gas to the combustion chamber to reduce the combustion intensity and the temperature of the flue gas; the main measure to increase the flue gas temperature is to supplement auxiliary fuel to strengthen the combustion. The process is all realized through automatic control and automatic adjustment, to ensure that the flue gas temperature is within the normal range (between 800°C and 1000°C)
1、上述实现热量平衡及热量自循环的工艺控制方案为:1. The above process control scheme for realizing heat balance and heat self-circulation is:
生物质在炭化进行炭化,炭化温度的高低与三个因素有关系:一是夹套中的烟气温度,烟气温度高,利用烟气加热的炭化装置中物料的温度即炭化温度就高;烟气温度低,炭化温度就低。二是一定的加料量下,生物质在炭化室中的运动速度,运动速度快,接受夹套传热的时间短(但该炭化时间必须保证在相应的温度下完成充分的炭化),运动速度慢,加热时间长,相应的炭化温度就高;三是加料的速度,加料速度快,生物质的量多,同样的炭化温度和炭化时间下,生物质产生的裂解气量就大,烟气温度就高;加料速度慢,生物质的裂解气量小,烟气温度就降低。Biomass is carbonized during carbonization, and the carbonization temperature is related to three factors: First, the temperature of the flue gas in the jacket, the temperature of the flue gas is high, and the temperature of the material in the carbonization device heated by the flue gas, that is, the carbonization temperature is high; The lower the flue gas temperature, the lower the carbonization temperature. Second, under a certain feeding amount, the moving speed of biomass in the carbonization chamber is fast, and the time for receiving heat transfer from the jacket is short (but the carbonization time must ensure that sufficient carbonization is completed at the corresponding temperature), and the moving speed is short. slow, the heating time is long, and the corresponding carbonization temperature is high; the third is the feeding speed, the feeding speed is fast, and the amount of biomass is large. Under the same carbonization temperature and carbonization time, the amount of pyrolysis gas generated by biomass is large, and the flue gas temperature is high; the feeding speed is slow, the amount of pyrolysis gas of biomass is small, and the temperature of flue gas is reduced.
生物质烟气的温度的高低与裂解气的多少以及裂解成分的组成有关,一般情况下,炭化温度越高,裂解气产生量就越高,裂解气燃烧后的烟气温度就越高。但此时生物炭的产率会降低。如果,裂解气由于产生量太小,不能满足烟气的温度进而不能满足正常的炭化温度,本发明采用补充辅助燃料的方式,加强燃烧强调,提高烟气的温度使其,达到正常的范围。The temperature of biomass flue gas is related to the amount of pyrolysis gas and the composition of pyrolysis components. In general, the higher the carbonization temperature, the higher the amount of pyrolysis gas produced, and the higher the temperature of the flue gas after the pyrolysis gas is burned. However, the yield of biochar will decrease at this time. If the pyrolysis gas is too small to meet the temperature of the flue gas and thus cannot meet the normal carbonization temperature, the present invention adopts the method of supplementing auxiliary fuel to strengthen the combustion emphasis and increase the temperature of the flue gas to reach the normal range.
另外影响烟气的温度的另一主要因素是燃烧时空气的补充量,鉴于过量的空气量对于烟气的低氮控制有一定的负面影响。本专利在一定的空气进给量下,采用烟气的回流来控制燃烧室烟气的出口温度,经过冷却后的烟气的回流量越大,燃烧室出口的烟气温度就越低。In addition, another major factor affecting the temperature of flue gas is the supplementary amount of air during combustion. In view of the excessive amount of air, it has a certain negative impact on the low nitrogen control of flue gas. This patent uses the backflow of flue gas to control the outlet temperature of the flue gas in the combustion chamber under a certain air feed rate.
本专利采用自动控制的方法,实现辅助燃料的补充量,烟气的温度,冷却烟气的回来量,炭化温度,生物质进料量和炭化时间之间的联动协调。使其相互匹配,实现热量条件,达到温度平衡。This patent adopts the method of automatic control to realize the linkage and coordination among the supplementary amount of auxiliary fuel, the temperature of flue gas, the return amount of cooling flue gas, the carbonization temperature, the biomass feed amount and the carbonization time. Make them match each other, achieve thermal conditions, and achieve temperature equilibrium.
2、采用的配套设备及仪表2. The supporting equipment and instruments used
回流风机26、烟气回流自动调节阀门28、炭化室螺旋变频驱动电机29、第一锁风器31、用于测量燃烧室烟气温度的第五温度传感器2、助燃空气自动调节阀门6、测量助燃空气流量的第三流量计5、辅助燃料自动调节阀7;测量辅助燃料流量的第二流量计8、测量裂解气流的第一流量计11;测量裂解气温度的第三温度传感器9;第二锁风器14。此外所需PLC系统,电磁阀等硬件以及必要的控制软件。Return fan 26, flue gas return
上述硬件在温度控制及调节中的作用:The role of the above hardware in temperature control and regulation:
回流风机和烟气回流自动调节阀门的作用是调节进入燃烧室的烟气回流量进而调节燃烧室出口烟气的温度;炭化室螺旋变频驱动电机是调节螺旋输送器的转速进而调节生物质的炭化时间;第一锁风器及变第二锁风器的作用是调节生物质的进、出料量。第五温度传感器的作用是测量烟气的温度并将温度信号传输给PLC;助燃空气自动调节阀是根据一定的空气过量系数,配合燃烧气体(包括裂解气和辅助燃料)流量的大小自动进行流量调节阀门;第三流量计测量助燃空气流量并为PLC提供流量信号的仪表,辅助燃料自动调节供给阀门作用是调节辅助燃料的供给量;第二流量计测量助燃气流量并为PLC提供流量信号的仪表,第一流量计是测量裂解气流量并为PLC提供流量信号的仪表,第三温度传感器的作用是测量裂解气的温度并将温度参数传输给PLC。The function of the return fan and the automatic adjustment valve of the flue gas return is to adjust the return flow of the flue gas entering the combustion chamber and then adjust the temperature of the flue gas at the exit of the combustion chamber; the spiral frequency conversion drive motor of the carbonization chamber is to adjust the speed of the screw conveyor to adjust the carbonization of biomass. Time; the function of the first air lock and the second air lock is to adjust the input and output of biomass. The function of the fifth temperature sensor is to measure the temperature of the flue gas and transmit the temperature signal to the PLC; the combustion air automatic regulating valve is based on a certain air excess coefficient, and the flow rate of the combustion gas (including cracking gas and auxiliary fuel) is automatically adjusted. Adjusting valve; the third flow meter measures the flow of combustion air and provides a flow signal to the PLC. The function of the auxiliary fuel automatic adjustment supply valve is to adjust the supply of auxiliary fuel; the second flow meter measures the flow of combustion air and provides a flow signal to the PLC. Instrument, the first flow meter is an instrument that measures the flow rate of cracked gas and provides flow signals for PLC, and the function of the third temperature sensor is to measure the temperature of cracked gas and transmit temperature parameters to PLC.
3、本专利炭化温度自动调节的控制流程包括初次启动、当炭化室温度超过设定温度时的自动调节控制及当炭化室温度低于设定温度时自动调节控制,分别参见图2、图3和图4。3. The control process of the automatic adjustment of the carbonization temperature in this patent includes the initial startup, the automatic adjustment control when the temperature of the carbonization chamber exceeds the set temperature, and the automatic adjustment control when the temperature of the carbonization chamber is lower than the set temperature. See Figure 2 and Figure 3 respectively. and Figure 4.
本专利设计项目具有远大的应用前景,主要基于以下几个方面:This patented design project has great application prospects, mainly based on the following aspects:
1、石化资源的有限性和环保污染局限性,决定了作为新能源的生物质能源的开发利用成为国家主要能源战略之一。1. The limitations of petrochemical resources and environmental pollution have determined that the development and utilization of biomass energy as a new energy has become one of the main energy strategies of the country.
2、以秸秆为代表的农业固体废弃物对环境的污染成为制约生态文明建设和新农村建设中急需解决问题之一。2. The pollution of agricultural solid waste represented by straw to the environment has become one of the urgent problems to be solved in restricting the construction of ecological civilization and the construction of new countryside.
3、农村集中供暖,是提高农村生态文明和农民生活水平的一件民生大事。3. Central heating in rural areas is a major livelihood event to improve rural ecological civilization and farmers' living standards.
4、煤改气工程存在安全,价格,资源等方面的不足,实际推行起来有一定的问题。4. The coal-to-gas project has shortcomings in terms of safety, price, and resources, and there are certain problems in its actual implementation.
5、炭-热联产技术具有就近取材,资源封面,无污染,低炭排放,炭-热具用,规模灵活、投资方便,操作简单(可以做到安全自控操作),不需要对农户的原有暖气设施进行专门改造等诸多优点特别适合以村为单位的集中供暖工程。5. The carbon-heat cogeneration technology has the advantages of nearby materials, resource cover, no pollution, low carbon emission, carbon-heat tools, flexible scale, convenient investment, simple operation (safe and self-control operation can be achieved), and no need for farmers. The original heating facilities are specially transformed and many other advantages are especially suitable for the central heating project with the village as the unit.
6、生物质炭以其用途广泛而成为生物质资源化利用的主要方向之一,炭-热联产技术在生产生物质炭产品的基础之上,利用大量的余热作为供暖热源,具有较好的经济性。6. Biomass carbon has become one of the main directions of biomass resource utilization due to its wide range of uses. On the basis of producing biomass carbon products, the carbon-heat cogeneration technology uses a large amount of waste heat as a heating heat source, which has better economy.
尽管为说明目的公开了本发明的实施例和附图,但是本领域的技术人员可以理解:在不脱离本发明及所附权利要求的精神和范围内,各种替换、变化和修改都是可能的,因此,本发明的范围不局限于实施例和附图所公开的内容。Although the embodiments and drawings of the present invention are disclosed for illustrative purposes, those skilled in the art will appreciate that various substitutions, changes and modifications are possible without departing from the spirit and scope of the invention and the appended claims Therefore, the scope of the present invention is not limited to the contents disclosed in the embodiments and drawings.
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